JP5986070B2 - 混成ポリエステル−ポリエーテルポリオール - Google Patents
混成ポリエステル−ポリエーテルポリオール Download PDFInfo
- Publication number
- JP5986070B2 JP5986070B2 JP2013508099A JP2013508099A JP5986070B2 JP 5986070 B2 JP5986070 B2 JP 5986070B2 JP 2013508099 A JP2013508099 A JP 2013508099A JP 2013508099 A JP2013508099 A JP 2013508099A JP 5986070 B2 JP5986070 B2 JP 5986070B2
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- Prior art keywords
- reactor
- acid
- catalyst
- polyether polyol
- pressure
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/40—High-molecular-weight compounds
- C08G18/42—Polycondensates having carboxylic or carbonic ester groups in the main chain
- C08G18/4244—Polycondensates having carboxylic or carbonic ester groups in the main chain containing oxygen in the form of ether groups
- C08G18/4261—Polycondensates having carboxylic or carbonic ester groups in the main chain containing oxygen in the form of ether groups prepared by oxyalkylation of polyesterpolyols
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/40—High-molecular-weight compounds
- C08G18/48—Polyethers
- C08G18/4866—Polyethers having a low unsaturation value
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
- C08G63/02—Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds
- C08G63/12—Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds derived from polycarboxylic acids and polyhydroxy compounds
- C08G63/40—Polyesters derived from ester-forming derivatives of polycarboxylic acids or of polyhydroxy compounds, other than from esters thereof
- C08G63/42—Cyclic ethers; Cyclic carbonates; Cyclic sulfites; Cyclic orthoesters
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
- C08G63/66—Polyesters containing oxygen in the form of ether groups
- C08G63/668—Polyesters containing oxygen in the form of ether groups derived from polycarboxylic acids and polyhydroxy compounds
- C08G63/672—Dicarboxylic acids and dihydroxy compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
- C08G63/91—Polymers modified by chemical after-treatment
- C08G63/914—Polymers modified by chemical after-treatment derived from polycarboxylic acids and polyhydroxy compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G65/00—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
- C08G65/02—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring
- C08G65/26—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers and other compounds
- C08G65/2603—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers and other compounds the other compounds containing oxygen
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G65/00—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
- C08G65/02—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring
- C08G65/26—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers and other compounds
- C08G65/2642—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers and other compounds characterised by the catalyst used
- C08G65/2645—Metals or compounds thereof, e.g. salts
- C08G65/2663—Metal cyanide catalysts, i.e. DMC's
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G65/00—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
- C08G65/02—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring
- C08G65/26—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers and other compounds
- C08G65/2642—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers and other compounds characterised by the catalyst used
- C08G65/2669—Non-metals or compounds thereof
- C08G65/2672—Nitrogen or compounds thereof
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G65/00—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
- C08G65/02—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring
- C08G65/26—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers and other compounds
- C08G65/2642—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers and other compounds characterised by the catalyst used
- C08G65/2669—Non-metals or compounds thereof
- C08G65/2678—Sulfur or compounds thereof
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
- C08J9/04—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent
- C08J9/12—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a physical blowing agent
- C08J9/14—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a physical blowing agent organic
- C08J9/141—Hydrocarbons
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G2110/00—Foam properties
- C08G2110/0025—Foam properties rigid
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2375/00—Characterised by the use of polyureas or polyurethanes; Derivatives of such polymers
- C08J2375/04—Polyurethanes
- C08J2375/06—Polyurethanes from polyesters
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Toxicology (AREA)
- General Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Polyurethanes Or Polyureas (AREA)
- Polyethers (AREA)
- Polyesters Or Polycarbonates (AREA)
Applications Claiming Priority (5)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US32921910P | 2010-04-29 | 2010-04-29 | |
| US61/329,219 | 2010-04-29 | ||
| US201161453152P | 2011-03-16 | 2011-03-16 | |
| US61/453,152 | 2011-03-16 | ||
| PCT/US2011/033346 WO2011137011A1 (en) | 2010-04-29 | 2011-04-21 | Hybrid polyester-polyether polyols |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| JP2013525573A JP2013525573A (ja) | 2013-06-20 |
| JP2013525573A5 JP2013525573A5 (enExample) | 2014-06-19 |
| JP5986070B2 true JP5986070B2 (ja) | 2016-09-06 |
Family
ID=44279117
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2013508099A Active JP5986070B2 (ja) | 2010-04-29 | 2011-04-21 | 混成ポリエステル−ポリエーテルポリオール |
Country Status (8)
| Country | Link |
|---|---|
| US (1) | US8680211B2 (enExample) |
| EP (1) | EP2563834B1 (enExample) |
| JP (1) | JP5986070B2 (enExample) |
| CN (1) | CN102869696B (enExample) |
| ES (1) | ES2719589T3 (enExample) |
| MX (1) | MX2012012617A (enExample) |
| PL (1) | PL2563834T3 (enExample) |
| WO (1) | WO2011137011A1 (enExample) |
Families Citing this family (45)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE102009031584A1 (de) * | 2009-07-03 | 2011-01-05 | Bayer Materialscience Ag | Verfahren zur Herstellung von Polyetherpolyolen mit primären Hydroxyl-Endgruppen |
| JP5731651B2 (ja) * | 2010-08-20 | 2015-06-10 | ビーエーエスエフ ソシエタス・ヨーロピアBasf Se | ポリエーテルエステルポリオールの製造方法 |
| WO2012091968A1 (en) | 2010-12-27 | 2012-07-05 | Dow Global Technologies Llc | Alkylene oxide polymerization using a double metal cyanide catalyst complex and a magnesium, group 3-group 15 metal or lanthanide series metal compound |
| BR112013021671A2 (pt) | 2011-02-23 | 2016-11-01 | Council Scient Ind Res | processo para a preparação de um campo de poliéster hiper-ramificado da invenção |
| WO2013024107A1 (de) * | 2011-08-16 | 2013-02-21 | Bayer Intellectual Property Gmbh | Verfahren zur herstellung eines polyurethan-polyisocyanurat-hartschaums |
| EP2766406B1 (en) * | 2011-10-14 | 2020-11-25 | Dow Global Technologies LLC | Hybrid polyester-polyether polyols for improved demold expansion in polyurethane rigid foams |
| KR102008546B1 (ko) * | 2011-12-18 | 2019-08-07 | 다우 글로벌 테크놀로지스 엘엘씨 | 하이브리드 폴리에스테르-폴리에테르 폴리올의 제조 방법 |
| CN104619736B (zh) | 2012-07-31 | 2017-08-18 | 科思创德国股份有限公司 | 使用乳化发泡剂制备聚氨酯泡沫的方法 |
| CN103193953B (zh) * | 2013-03-18 | 2014-10-29 | 江苏利田科技股份有限公司 | 一种12 官能度聚氨酯丙烯酸酯及其制备方法和应用 |
| EP2984116B1 (de) * | 2013-04-11 | 2018-07-25 | Covestro Deutschland AG | Polyesterpolyole mit langkettigen polyetherpolyol-bausteinen und deren verwendung in pur-/pir-hartschaumstoffen |
| CN103242507B (zh) * | 2013-04-23 | 2015-02-11 | 江苏利田科技股份有限公司 | 一种8官能度聚氨酯丙烯酸酯及其制备方法和应用 |
| CN103242508B (zh) * | 2013-04-23 | 2015-10-28 | 江苏利田科技股份有限公司 | 一种4官能度聚氨酯丙烯酸酯及其制备方法和应用 |
| WO2014193623A1 (en) | 2013-05-30 | 2014-12-04 | Dow Global Technologies Llc | Hybrid polyols |
| US20160096352A1 (en) * | 2013-05-30 | 2016-04-07 | Rohm And Haas Company | Lamination method |
| WO2015042300A1 (en) | 2013-09-19 | 2015-03-26 | Dow Global Technologies Llc | Vacuum assisted process to make closed cell rigid polyurethane foams using mixed blowing agents |
| US10787550B2 (en) * | 2014-06-26 | 2020-09-29 | Covestro Deutschland Ag | Composite components on the basis of hydrophobic polyols |
| JP6598855B2 (ja) * | 2014-10-22 | 2019-10-30 | ダウ グローバル テクノロジーズ エルエルシー | 高い一級ヒドロキシルポリオールのための二重触媒系 |
| HUE060823T2 (hu) * | 2015-08-17 | 2023-04-28 | Evonik Operations Gmbh | Poliuretán rugalmas habok javított keménységgel |
| WO2017058318A1 (en) | 2015-09-29 | 2017-04-06 | Dow Global Technologies Llc | Toluene diisocyanate biuret based prepolymers for polyurethane foams |
| WO2017089417A1 (de) * | 2015-11-26 | 2017-06-01 | Covestro Deutschland Ag | Pur-/pir-hartschäume aus polyadditions-oligoestern |
| US10836882B2 (en) * | 2016-03-11 | 2020-11-17 | Invista North America S.A.R.L. | Polyurethane and polyisocyanurate foams and methods of producing the same |
| CN109642046B (zh) | 2016-06-28 | 2022-01-25 | Ptt全球化学公众有限公司 | 基于天然油多元醇的杂化多元醇 |
| CN107189049B (zh) * | 2017-06-14 | 2019-03-01 | 江南大学 | 一种杂化型聚酯及其制备方法 |
| WO2019099403A1 (en) * | 2017-11-14 | 2019-05-23 | Dow Global Technologies Llc | Composition and synthesis of high molecular weight aromatic polyol polyesters |
| EP3852913B1 (en) * | 2018-09-18 | 2022-10-19 | BYK-Chemie GmbH | An amine functional compound having a urethane group |
| CN109212005B (zh) * | 2018-09-28 | 2020-07-24 | 山东一诺威新材料有限公司 | 利用电位滴定测定聚醚多元醇中伯羟基含量的方法 |
| CN109438690A (zh) * | 2018-11-13 | 2019-03-08 | 耿佃勇 | 新型不饱和聚醚多元醇 |
| CN111307888B (zh) * | 2018-12-11 | 2022-04-12 | 辽宁奥克化学股份有限公司 | 一种嵌段聚醚多元醇中伯羟基含量的检测方法 |
| US12344700B2 (en) | 2019-05-24 | 2025-07-01 | Dow Global Technologies Llc | Storage stable HFO- or HCFO-containing polyol compositions for making flame-resistant rigid polyurethane foams |
| JP7590404B2 (ja) * | 2019-07-12 | 2024-11-26 | ダウ グローバル テクノロジーズ エルエルシー | ポリウレタンポリマーに使用するための金属ポリオール |
| TWI887244B (zh) * | 2019-07-12 | 2025-06-21 | 美商陶氏全球科技有限責任公司 | 基於溶劑之組合物 |
| MX2022002308A (es) | 2019-09-02 | 2022-07-19 | Dow Global Technologies Llc | Espuma de poliuretano rigida fabricada con un agente soplante de hidrocarburo y 1,1,1,4,4,4-hexafluorobut-2-eno. |
| EP4025420A1 (en) | 2019-09-02 | 2022-07-13 | Dow Global Technologies LLC | Apparatus and method for applying a foaming reaction mixture onto a laminator |
| EP3875510A1 (de) | 2020-03-03 | 2021-09-08 | Covestro Deutschland AG | Verfahren zur herstellung eines etheresterols |
| CN111518251A (zh) * | 2020-04-08 | 2020-08-11 | 上海抚佳精细化工有限公司 | 一种聚氨酯硬质泡沫及其制备方法 |
| US20250065544A1 (en) | 2021-12-20 | 2025-02-27 | Dow Global Technologies Llc | Apparatus and method for applying a foaming reaction mixture onto a laminator using a diverging nozzle |
| CN119816407A (zh) | 2022-08-31 | 2025-04-11 | 陶氏环球技术有限责任公司 | 用于制造模制聚合物泡沫的方法 |
| CN120129708A (zh) * | 2022-10-28 | 2025-06-10 | 国际壳牌研究有限公司 | 用于使用双金属氰化物催化剂制备聚醚多元醇的分批方法 |
| CN120917074A (zh) | 2023-04-12 | 2025-11-07 | 斯泰潘公司 | 低残留单体二醇芳香族聚酯多元醇 |
| CN116199855B (zh) * | 2023-05-06 | 2023-07-18 | 成都瑞吉龙科技有限责任公司 | 一种聚醚-聚酯混合型聚氨酯及其制备方法 |
| WO2024253800A1 (en) | 2023-06-08 | 2024-12-12 | Dow Global Technologies Llc | Method for producing corrugated laminated panels using recycled materials |
| WO2024254366A1 (en) | 2023-06-09 | 2024-12-12 | Dow Global Technologies Llc | Method for producing corrugated laminated panels |
| WO2025007333A1 (en) * | 2023-07-06 | 2025-01-09 | Dow Global Technologies Llc | Composites formed using lewis-acid polymerized polyols and methods of preparing same |
| WO2025007334A1 (en) * | 2023-07-06 | 2025-01-09 | Dow Global Technologies Llc | Composites formed using lewis-acid polymerized polyols and methods of preparing same |
| CN119571514A (zh) * | 2025-02-08 | 2025-03-07 | 江苏多来运纺织有限公司 | 一种吸湿透汗雪尼尔纱线及其生产工艺 |
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| US3427256A (en) | 1963-02-14 | 1969-02-11 | Gen Tire & Rubber Co | Double metal cyanide complex compounds |
| US3278459A (en) | 1963-02-14 | 1966-10-11 | Gen Tire & Rubber Co | Method of making a polyether using a double metal cyanide complex compound |
| US3427334A (en) | 1963-02-14 | 1969-02-11 | Gen Tire & Rubber Co | Double metal cyanides complexed with an alcohol aldehyde or ketone to increase catalytic activity |
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| NZ234512A (en) * | 1989-07-19 | 1992-05-26 | Mitsui Toatsu Chemicals | Polyols prepared by adding alkylene oxide onto a compound containing at least one ester and/or amide linkage; polyurethane resins and foams prepared therefrom |
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| US5158922A (en) | 1992-02-04 | 1992-10-27 | Arco Chemical Technology, L.P. | Process for preparing metal cyanide complex catalyst |
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| JP3308411B2 (ja) * | 1994-12-20 | 2002-07-29 | 三井化学株式会社 | エステルポリオールの製造方法 |
| DE19702787A1 (de) * | 1997-01-27 | 1998-07-30 | Bayer Ag | Verfahren zur Herstellung von Polyetherpolyolen |
| US6376645B1 (en) * | 1999-07-09 | 2002-04-23 | The Dow Chemical Company | Complexing agent-modified hexacyanometallate hexanitrometallate catalysts |
| DE19949091A1 (de) * | 1999-10-12 | 2001-04-26 | Basf Ag | Polyester-Polyetherblockcopolymere |
| US6989432B2 (en) | 2002-01-10 | 2006-01-24 | Invista North America S.A.R.L. | Copolymers of tetrahydrofuran, ethylene oxide and an additional cyclic ether |
| DE10243362A1 (de) | 2002-09-18 | 2004-04-01 | Basf Ag | Herstellung von Alkanolalkoxylaten bei optimierten Reaktionstemperaturen |
| WO2005049748A1 (en) * | 2003-11-17 | 2005-06-02 | Bayer Materialscience Llc | Ultraviolet-curable polyols and polyurethane compositions made therefrom |
| US20050107486A1 (en) * | 2003-11-17 | 2005-05-19 | Bi Le-Khac | UV-curable polyols |
| JP4239814B2 (ja) * | 2003-12-22 | 2009-03-18 | 旭硝子株式会社 | ポリエーテル類の製造法 |
| AU2007301112A1 (en) * | 2006-09-27 | 2008-04-03 | Asahi Glass Company, Limited | Method for producing soft polyurethane foam |
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2011
- 2011-04-21 MX MX2012012617A patent/MX2012012617A/es active IP Right Grant
- 2011-04-21 ES ES11717149T patent/ES2719589T3/es active Active
- 2011-04-21 JP JP2013508099A patent/JP5986070B2/ja active Active
- 2011-04-21 EP EP11717149.6A patent/EP2563834B1/en active Active
- 2011-04-21 WO PCT/US2011/033346 patent/WO2011137011A1/en not_active Ceased
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Also Published As
| Publication number | Publication date |
|---|---|
| JP2013525573A (ja) | 2013-06-20 |
| EP2563834B1 (en) | 2019-02-27 |
| ES2719589T3 (es) | 2019-07-11 |
| MX2012012617A (es) | 2012-12-17 |
| US8680211B2 (en) | 2014-03-25 |
| PL2563834T3 (pl) | 2019-07-31 |
| CN102869696A (zh) | 2013-01-09 |
| CN102869696B (zh) | 2015-02-04 |
| EP2563834A1 (en) | 2013-03-06 |
| WO2011137011A1 (en) | 2011-11-03 |
| US20130035467A1 (en) | 2013-02-07 |
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