JP5684282B2 - ポリエステルポリオールの製造方法 - Google Patents

ポリエステルポリオールの製造方法 Download PDF

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Publication number
JP5684282B2
JP5684282B2 JP2012543718A JP2012543718A JP5684282B2 JP 5684282 B2 JP5684282 B2 JP 5684282B2 JP 2012543718 A JP2012543718 A JP 2012543718A JP 2012543718 A JP2012543718 A JP 2012543718A JP 5684282 B2 JP5684282 B2 JP 5684282B2
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acid
polyester polyol
component
polyurethane
reaction mixture
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Expired - Fee Related
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JP2012543718A
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Japanese (ja)
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JP2013514406A5 (enExample
JP2013514406A (ja
Inventor
ジェリンガー,リヨネル
ドゥベンホルスト,イェルン
ラメルス,フィン
ヴィルムス,アクセル
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BASF SE
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BASF SE
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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00Polymeric products of isocyanates or isothiocyanates
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00Polymeric products of isocyanates or isothiocyanates
    • C08G18/06Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/08Processes
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00Polymeric products of isocyanates or isothiocyanates
    • C08G18/06Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40High-molecular-weight compounds
    • C08G18/42Polycondensates having carboxylic or carbonic ester groups in the main chain
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00Polymeric products of isocyanates or isothiocyanates
    • C08G18/06Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40High-molecular-weight compounds
    • C08G18/42Polycondensates having carboxylic or carbonic ester groups in the main chain
    • C08G18/4236Polycondensates having carboxylic or carbonic ester groups in the main chain containing only aliphatic groups
    • C08G18/4238Polycondensates having carboxylic or carbonic ester groups in the main chain containing only aliphatic groups derived from dicarboxylic acids and dialcohols
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00Polymeric products of isocyanates or isothiocyanates
    • C08G18/06Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/65Low-molecular-weight compounds having active hydrogen with high-molecular-weight compounds having active hydrogen
    • C08G18/66Compounds of groups C08G18/42, C08G18/48, or C08G18/52
    • C08G18/6633Compounds of group C08G18/42
    • C08G18/6637Compounds of group C08G18/42 with compounds of group C08G18/32 or polyamines of C08G18/38
    • C08G18/664Compounds of group C08G18/42 with compounds of group C08G18/32 or polyamines of C08G18/38 with compounds of group C08G18/3203
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00Polymeric products of isocyanates or isothiocyanates
    • C08G18/06Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/70Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
    • C08G18/72Polyisocyanates or polyisothiocyanates
    • C08G18/74Polyisocyanates or polyisothiocyanates cyclic
    • C08G18/76Polyisocyanates or polyisothiocyanates cyclic aromatic
    • C08G18/7657Polyisocyanates or polyisothiocyanates cyclic aromatic containing two or more aromatic rings
    • C08G18/7664Polyisocyanates or polyisothiocyanates cyclic aromatic containing two or more aromatic rings containing alkylene polyphenyl groups
    • C08G18/7671Polyisocyanates or polyisothiocyanates cyclic aromatic containing two or more aromatic rings containing alkylene polyphenyl groups containing only one alkylene bisphenyl group
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G63/00Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
    • C08G63/02Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds
    • C08G63/12Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds derived from polycarboxylic acids and polyhydroxy compounds
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G63/00Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
    • C08G63/02Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds
    • C08G63/12Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds derived from polycarboxylic acids and polyhydroxy compounds
    • C08G63/16Dicarboxylic acids and dihydroxy compounds
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G63/00Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
    • C08G63/78Preparation processes
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00Use of organic ingredients
    • C08K5/49Phosphorus-containing compounds
    • C08K5/51Phosphorus bound to oxygen
    • C08K5/52Phosphorus bound to oxygen only
    • C08K5/524Esters of phosphorous acids, e.g. of H3PO3
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/13Hollow or container type article [e.g., tube, vase, etc.]
    • Y10T428/1352Polymer or resin containing [i.e., natural or synthetic]
    • Y10T428/139Open-ended, self-supporting conduit, cylinder, or tube-type article

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Polyurethanes Or Polyureas (AREA)
  • Polyesters Or Polycarbonates (AREA)
JP2012543718A 2009-12-16 2010-12-15 ポリエステルポリオールの製造方法 Expired - Fee Related JP5684282B2 (ja)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
EP09179515 2009-12-16
EP09179515.3 2009-12-16
PCT/EP2010/069749 WO2011083000A1 (de) 2009-12-16 2010-12-15 Verfahren zur herstellung von polyesterpolyolen, die damit hergestellten polyesterpolyole und daraus erhaltene polyurethane

Publications (3)

Publication Number Publication Date
JP2013514406A JP2013514406A (ja) 2013-04-25
JP2013514406A5 JP2013514406A5 (enExample) 2014-01-30
JP5684282B2 true JP5684282B2 (ja) 2015-03-11

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JP2012543718A Expired - Fee Related JP5684282B2 (ja) 2009-12-16 2010-12-15 ポリエステルポリオールの製造方法

Country Status (8)

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US (1) US20120258269A1 (enExample)
EP (1) EP2513189B1 (enExample)
JP (1) JP5684282B2 (enExample)
KR (1) KR101793755B1 (enExample)
CN (1) CN102782006A (enExample)
BR (1) BR112012014686A2 (enExample)
ES (1) ES2557289T3 (enExample)
WO (1) WO2011083000A1 (enExample)

Families Citing this family (29)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US9080259B2 (en) 2009-06-30 2015-07-14 Basf Se Polyamide fibers with dyeable particles and production thereof
JP5604352B2 (ja) * 2010-04-02 2014-10-08 大日精化工業株式会社 バイオポリウレタン樹脂
US20140107311A1 (en) * 2011-06-17 2014-04-17 Lubrizol Advanced Materials, Inc. Thermoplastic Polyurethane With Reduced Tendency To Bloom From A Bio-Based Glycol
BR112014007306A2 (pt) 2011-09-30 2017-04-04 Bayer Ip Gmbh artigos extrudados homogêneos feitos a partir de poliuretanos termoplasticamente processáveis com base em poliéster-dióis formados a partir de ácido succínico e de 1,3-propanodiol
WO2013106193A1 (en) * 2011-12-29 2013-07-18 3M Innovative Properties Company Curable polysiloxane composition
FR2987840B1 (fr) 2012-03-09 2015-05-29 Novance Polyester polyether polyol
JP6486838B2 (ja) 2013-02-25 2019-03-20 ビーエーエスエフ ソシエタス・ヨーロピアBasf Se 脂肪族イソシアネートを取り込むことによるポリマーポリオールを主原料とする熱可塑性ポリウレタンの変色抑制
WO2015000722A1 (de) * 2013-07-02 2015-01-08 Basf Se Polyurethan auf basis von nachwachsenden rohstoffen
US9790399B2 (en) * 2013-07-23 2017-10-17 Axalta Coatings Systems Ip Co. Llc Clear coat component
JP6118461B2 (ja) * 2013-10-11 2017-04-19 ヴェーぺーテー ゲーエムベーハーWPT GmbH 巻回可能なウェブ製品形の弾性床仕上げ材
WO2015061032A1 (en) * 2013-10-22 2015-04-30 Elevance Renewable Sciences, Inc. Polyester polyols and methods of making and using the same
WO2015171433A1 (en) * 2014-05-05 2015-11-12 Resinate Materials Group, Inc. Polyester polyols from thermoplastic polyesters and dimer fatty acids
US20170335047A1 (en) * 2014-11-03 2017-11-23 Basf Se Polyurethane dispersions based on renewable raw materials
KR101720255B1 (ko) * 2015-01-20 2017-03-27 (주)삼호화성 동물성 유지로부터 거대 곁사슬을 가진 폴리에스터 폴리올의 제조방법
CN106397755A (zh) * 2015-08-02 2017-02-15 青岛科技大学 制备含二硫键聚酯多元醇的方法
WO2017085158A1 (en) 2015-11-18 2017-05-26 Basf Se Polyester polyols with enhanced solubility
FR3055335B1 (fr) * 2016-08-24 2020-03-27 Tereos Starch & Sweeteners Belgium Methode de production de polyol polyesters et leur utilisation dans le polyurethane
EP3546493A1 (en) 2018-03-28 2019-10-02 Covestro Deutschland AG Aqueous dispersion
EP3613787A1 (de) * 2018-08-24 2020-02-26 Covestro Deutschland AG Polyurethane mit verbesserter härte
CN111187401B (zh) * 2018-11-15 2021-05-25 中国科学院大连化学物理研究所 一种聚酯多元醇的制备方法
US11845863B2 (en) 2020-05-04 2023-12-19 Carlisle Construction Materials, LLC Polyurethane dispersions and their use to produce coatings and adhesives
WO2022043428A1 (de) 2020-08-28 2022-03-03 Basf Se Geschäumtes granulat aus thermoplastischem polyurethan
CN112661947B (zh) * 2020-12-22 2023-03-17 上海华峰新材料研发科技有限公司 一种聚酯多元醇及其制备方法和应用
CN113912813A (zh) * 2021-10-29 2022-01-11 山东一诺威聚氨酯股份有限公司 无增塑剂型高抗水解tpu及其制备方法
CN114316225B (zh) * 2022-01-11 2024-02-02 万华化学集团股份有限公司 一种聚酯多元醇及其制备方法和应用
TWI831416B (zh) * 2022-10-14 2024-02-01 南亞塑膠工業股份有限公司 聚酯多元醇的製造方法
JPWO2024135690A1 (enExample) * 2022-12-21 2024-06-27
CN116284709A (zh) * 2023-03-15 2023-06-23 河北邦泰氨纶科技有限公司 一种生物基聚酯多元醇、制备方法及其应用
WO2025110733A1 (ko) * 2023-11-21 2025-05-30 지에스칼텍스 주식회사 바이오매스 기반 폴리올, 이의 제조방법 및 정제방법

Family Cites Families (17)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE2901774A1 (de) 1979-01-18 1980-07-24 Elastogran Gmbh Rieselfaehiges, mikrobenbestaendiges farbstoff- und/oder hilfsmittelkonzentrat auf basis eines polyurethan-elastomeren und verfahren zu seiner herstellung
US4677154A (en) 1985-12-18 1987-06-30 Basf Corporation Stabilizer package for polyurethane comprising a substituted cresol and another costabilizer
WO1992000947A1 (en) 1990-07-09 1992-01-23 Henkel Corporation Improved esterification of oxyhydrocarbon polyols and ethers thereof, and products therefrom
JP3783732B2 (ja) 1992-05-29 2006-06-07 昭和高分子株式会社 生分解性高分子量脂肪族ポリエステルの製造方法
JPH07309937A (ja) 1994-05-16 1995-11-28 Kanegafuchi Chem Ind Co Ltd ポリエステルの製造方法
JP3415338B2 (ja) * 1995-08-30 2003-06-09 株式会社日本触媒 生分解性プラスチック材料
US5869582A (en) * 1997-01-22 1999-02-09 Alliedsignal Inc. Diblock polyester copolymer and process for making
JP3449883B2 (ja) * 1997-03-18 2003-09-22 株式会社クラレ エステル系高分子ポリオール組成物およびその製造方法
EP1195395A1 (de) 2000-10-06 2002-04-10 Bayer Ag Thermoplastisch verarbeitbare Polyurethanelastomere mit verbesserter Eigenfarbe
DE10121866A1 (de) 2001-05-05 2002-11-07 Cognis Deutschland Gmbh Verfahren zur Herstellung von Fettsäurepolyolestern
DE50306005D1 (de) 2002-02-23 2007-02-01 Bayer Materialscience Ag Verfahren zur Herstellung von weichen, gut entformbaren thermoplastischen Polyurethanelastomeren mit geringer Schwindung
DE10238112B3 (de) * 2002-08-21 2004-04-22 Bayer Ag Kontinuierliche Herstellung von thermoplastisch verarbeitbaren Polyurethanen
JP2007092048A (ja) * 2005-09-01 2007-04-12 Mitsubishi Chemicals Corp 脂肪族ポリエステル及びその製造方法
CN101535372A (zh) 2006-09-15 2009-09-16 斯蒂茨丁荷兰聚合物学会 基于二失水己糖醇的聚酯的制备方法
SI2109637T1 (sl) 2007-01-16 2018-09-28 Basf Se Hibridni sistemi iz penjenih termoplastičnih elastomerov in poliuretanov
WO2008104541A1 (de) * 2007-02-28 2008-09-04 Basf Se Verfahren zur herstellung von polyesteralkoholen
US8071690B2 (en) * 2008-01-23 2011-12-06 Tate & Lyle Ingredients Americas Llc Lactic acid based compositions with enhanced properties

Also Published As

Publication number Publication date
US20120258269A1 (en) 2012-10-11
EP2513189B1 (de) 2015-10-14
WO2011083000A1 (de) 2011-07-14
ES2557289T3 (es) 2016-01-25
CN102782006A (zh) 2012-11-14
KR101793755B1 (ko) 2017-11-03
KR20120103708A (ko) 2012-09-19
BR112012014686A2 (pt) 2016-04-05
EP2513189A1 (de) 2012-10-24
JP2013514406A (ja) 2013-04-25

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