JP5656826B2 - メタン及びメタン含有混合物を脱水素芳香族化するための触媒 - Google Patents
メタン及びメタン含有混合物を脱水素芳香族化するための触媒 Download PDFInfo
- Publication number
- JP5656826B2 JP5656826B2 JP2011503431A JP2011503431A JP5656826B2 JP 5656826 B2 JP5656826 B2 JP 5656826B2 JP 2011503431 A JP2011503431 A JP 2011503431A JP 2011503431 A JP2011503431 A JP 2011503431A JP 5656826 B2 JP5656826 B2 JP 5656826B2
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- Prior art keywords
- catalyst
- ammonium
- zeolite
- group
- zsm
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- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
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Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
- B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- B01J29/40—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively
- B01J29/48—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively containing arsenic, antimony, bismuth, vanadium, niobium tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
- B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- B01J29/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65
- B01J29/78—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65 containing arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J29/7876—MWW-type, e.g. MCM-22, ERB-1, ITQ-1, PSH-3 or SSZ-25
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
- C07C2/76—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by condensation of hydrocarbons with partial elimination of hydrogen
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
- B01J2229/10—After treatment, characterised by the effect to be obtained
- B01J2229/16—After treatment, characterised by the effect to be obtained to increase the Si/Al ratio; Dealumination
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
- B01J2229/10—After treatment, characterised by the effect to be obtained
- B01J2229/18—After treatment, characterised by the effect to be obtained to introduce other elements into or onto the molecular sieve itself
- B01J2229/186—After treatment, characterised by the effect to be obtained to introduce other elements into or onto the molecular sieve itself not in framework positions
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
- B01J2229/30—After treatment, characterised by the means used
- B01J2229/42—Addition of matrix or binder particles
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
- B01J35/61—Surface area
- B01J35/615—100-500 m2/g
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2529/00—Catalysts comprising molecular sieves
- C07C2529/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites, pillared clays
- C07C2529/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- C07C2529/40—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11
- C07C2529/48—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11 containing arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Crystallography & Structural Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Catalysts (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Applications Claiming Priority (5)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP08154195.5 | 2008-04-08 | ||
| EP08154195 | 2008-04-08 | ||
| EP08172159.9 | 2008-12-18 | ||
| EP08172159 | 2008-12-18 | ||
| PCT/EP2009/054201 WO2009124960A1 (de) | 2008-04-08 | 2009-04-08 | Katalysator zur dehydroaromatisierung von methan und methanhaltigen gemischen |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| JP2011518660A JP2011518660A (ja) | 2011-06-30 |
| JP2011518660A5 JP2011518660A5 (enExample) | 2012-06-07 |
| JP5656826B2 true JP5656826B2 (ja) | 2015-01-21 |
Family
ID=40791629
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2011503431A Expired - Fee Related JP5656826B2 (ja) | 2008-04-08 | 2009-04-08 | メタン及びメタン含有混合物を脱水素芳香族化するための触媒 |
Country Status (4)
| Country | Link |
|---|---|
| US (1) | US8742189B2 (enExample) |
| EP (1) | EP2276566A1 (enExample) |
| JP (1) | JP5656826B2 (enExample) |
| WO (1) | WO2009124960A1 (enExample) |
Families Citing this family (46)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US8779228B2 (en) | 2008-11-19 | 2014-07-15 | Basf Se | Oligomerisation of olefins |
| DE102008063308B4 (de) | 2008-12-29 | 2013-03-07 | Basf Se | Verfahren zur Herstellung von Toluylendiamin durch Hydrierung von Dinitrotoluol |
| WO2010099649A1 (en) | 2009-03-03 | 2010-09-10 | Basf Se | Process for preparation of pillared silicates |
| ES2589108T5 (es) | 2009-04-06 | 2022-03-02 | Basf Se | Procedimiento para la separación electroquímica de hidrógeno de una mezcla de reacción |
| US8487152B2 (en) | 2009-04-06 | 2013-07-16 | Basf Se | Process for converting natural gas to aromatics with electrochemical removal of hydrogen to generate electrical power and obtain hydrogen |
| WO2010115747A1 (de) | 2009-04-06 | 2010-10-14 | Basf Se | Verfahren zur umsetzung von erdgas zu aromaten mit elektrochemischer abtrennung von wasserstoff und elektrochemischer umsetzung des wasserstoffs zu wasser |
| JP5797637B2 (ja) | 2009-04-06 | 2015-10-21 | ビーエーエスエフ ソシエタス・ヨーロピアBasf Se | 電気化学的に水素を除去することによって、天然ガスを芳香族化合物に変換する方法 |
| WO2011003964A2 (de) | 2009-07-10 | 2011-01-13 | Basf Se | Verfahren zur direktaminierung von kohlenwasserstoffen zu aminokohlenwasserstoffen mit elektrochemischer abtrennung von wasserstoff |
| ES2533702T3 (es) | 2009-07-10 | 2015-04-14 | Basf Se | Procedimiento para la aminación directa de hidrocarburos para dar aminohidrocarburos con separación electroquímica de hidrógeno y conversión electroquímica del hidrógeno en agua |
| KR20120082889A (ko) | 2009-09-03 | 2012-07-24 | 바스프 에스이 | 메탄으로부터 벤젠을 제조하는 방법 |
| US9486796B2 (en) * | 2009-10-08 | 2016-11-08 | Basf Se | Process for producing an si-bonded fluidized-bed catalyst |
| PL2512667T3 (pl) | 2009-12-18 | 2018-04-30 | Basf Se | Zawierający żelazo zeolit, sposób wytwarzania zawierających żelazo zeolitów i sposób katalitycznej redukcji tlenków azotu |
| BR112012028770A2 (pt) * | 2010-05-12 | 2017-07-11 | Shell Int Research | catalisador de aromatização de metano, e, processos para preparar um catalisador de aromatização de metano e para produzir hidrocarbonetos aromáticos |
| US9580660B2 (en) * | 2010-06-18 | 2017-02-28 | The Texas A&M University System | Deoxygenation of biomass derived oxygenates to hydrocarbons via direct methane intervention |
| JP2012012340A (ja) | 2010-07-01 | 2012-01-19 | Meidensha Corp | 芳香族炭化水素製造方法 |
| US9339802B2 (en) * | 2011-01-26 | 2016-05-17 | Shell Oil Company | Zinc containing methane aromatization catalyst, method of making a method of using the catalyst |
| US9133079B2 (en) | 2012-01-13 | 2015-09-15 | Siluria Technologies, Inc. | Process for separating hydrocarbon compounds |
| US9969660B2 (en) | 2012-07-09 | 2018-05-15 | Siluria Technologies, Inc. | Natural gas processing and systems |
| AU2013355038B2 (en) | 2012-12-07 | 2017-11-02 | Lummus Technology Llc | Integrated processes and systems for conversion of methane to multiple higher hydrocarbon products |
| WO2014181241A1 (en) * | 2013-05-06 | 2014-11-13 | Saudi Basic Industries Corporation | Promoted molybdenum-based supported catalyst composition for high selectivity for converting by methane to an aromatic compound |
| US10047020B2 (en) | 2013-11-27 | 2018-08-14 | Siluria Technologies, Inc. | Reactors and systems for oxidative coupling of methane |
| EP3092286A4 (en) | 2014-01-08 | 2017-08-09 | Siluria Technologies, Inc. | Ethylene-to-liquids systems and methods |
| US10377682B2 (en) | 2014-01-09 | 2019-08-13 | Siluria Technologies, Inc. | Reactors and systems for oxidative coupling of methane |
| EP3097068A4 (en) | 2014-01-09 | 2017-08-16 | Siluria Technologies, Inc. | Oxidative coupling of methane implementations for olefin production |
| US9334204B1 (en) | 2015-03-17 | 2016-05-10 | Siluria Technologies, Inc. | Efficient oxidative coupling of methane processes and systems |
| US10793490B2 (en) | 2015-03-17 | 2020-10-06 | Lummus Technology Llc | Oxidative coupling of methane methods and systems |
| US20160289143A1 (en) | 2015-04-01 | 2016-10-06 | Siluria Technologies, Inc. | Advanced oxidative coupling of methane |
| WO2016196517A1 (en) * | 2015-05-29 | 2016-12-08 | The Board Of Regents For Oklahoma State University | Synergistic co-pyrolysis of biomass and methane for hydrocarbon fuels and chemicals production |
| US9328297B1 (en) | 2015-06-16 | 2016-05-03 | Siluria Technologies, Inc. | Ethylene-to-liquids systems and methods |
| CN105016947B (zh) * | 2015-07-15 | 2017-01-18 | 河南师范大学 | 羧甲基纤维素铜(ii)催化端基炔类化合物合成1,3‑丁二炔类化合物的方法 |
| CN106423257B (zh) * | 2015-08-12 | 2019-06-11 | 中国石油化工股份有限公司 | 由乙酸乙酯和苯合成乙苯的催化剂 |
| CN106423254B (zh) * | 2015-08-12 | 2019-05-14 | 中国石油化工股份有限公司 | 由乙酸和苯合成乙苯的催化剂 |
| US9796643B2 (en) | 2015-09-25 | 2017-10-24 | Exxonmobil Chemical Patents Inc. | Hydrocarbon dehydrocyclization in the presence of carbon dioxide |
| EP3786138A1 (en) | 2015-10-16 | 2021-03-03 | Lummus Technology LLC | Oxidative coupling of methane |
| US10531548B2 (en) * | 2015-12-10 | 2020-01-07 | Signify Holding B.V. | Dynamic light effect based on an image |
| CA3019396A1 (en) | 2016-04-13 | 2017-10-19 | Siluria Technologies, Inc. | Oxidative coupling of methane for olefin production |
| US10843981B2 (en) * | 2016-04-25 | 2020-11-24 | Exxonmobil Chemical Patents Inc. | Catalytic aromatization |
| EP3554672A4 (en) | 2016-12-19 | 2020-08-12 | Siluria Technologies, Inc. | PROCEDURES AND SYSTEMS FOR CHEMICAL DEPOSITION |
| US20180229198A1 (en) | 2017-02-16 | 2018-08-16 | Exxonmobil Research And Engineering Company | Fixed bed radial flow reactor for light paraffin conversion |
| WO2018217924A1 (en) | 2017-05-23 | 2018-11-29 | Siluria Technologies, Inc. | Integration of oxidative coupling of methane processes |
| EP3649097A4 (en) | 2017-07-07 | 2021-03-24 | Lummus Technology LLC | SYSTEMS AND PROCESSES FOR THE OXIDATIVE COUPLING OF METHANE |
| KR102496526B1 (ko) * | 2017-09-20 | 2023-02-03 | 고려대학교 산학협력단 | 메탄 및 c2 내지 c4 알칸 화합물의 공동 탈수소방향족화 반응에 의한 방향족 화합물 제조용 이종금속 담지 촉매 및 이를 이용한 방향족 화합물의 제조방법 |
| CN111151292B (zh) * | 2020-01-13 | 2021-03-05 | 中国科学院山西煤炭化学研究所 | 一种芳构化催化剂及其制备方法与应用 |
| CN118302400A (zh) | 2021-08-31 | 2024-07-05 | 鲁玛斯科技有限责任公司 | 用于进行甲烷氧化偶联的方法和系统 |
| CN117983261A (zh) * | 2022-11-02 | 2024-05-07 | 中国科学院大连化学物理研究所 | 一种用于环己烷脱氢制备苯的催化剂及其制备方法和应用 |
| WO2024243137A1 (en) * | 2023-05-19 | 2024-11-28 | Surendhran Roshaan | Process for encapsulation of zeolite encapsulated transition metal particles |
Family Cites Families (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4259537A (en) | 1980-03-17 | 1981-03-31 | Mobil Oil Corporation | Shape selective reactions with group via modified zeolite catalysts |
| WO2002010099A2 (en) * | 2000-07-27 | 2002-02-07 | Conoco Inc. | Catalyst and process for aromatic hydrocarbons production from methane |
| AU2003278771A1 (en) * | 2003-09-08 | 2005-04-21 | Uop Llc | A process for preparing a catalyst with a non-acidic binder and a process for using the catalyst to produce aromatics |
| JP4790356B2 (ja) * | 2005-09-16 | 2011-10-12 | 勝 市川 | 低級炭化水素改質触媒 |
| CN101460431B (zh) * | 2006-04-21 | 2013-09-11 | 埃克森美孚化学专利公司 | 用于甲烷转化的方法 |
| WO2009124902A1 (de) | 2008-04-08 | 2009-10-15 | Basf Se | Katalysator zur dehydroaromatisierung von aliphatischen kohlenwasserstoffen mit siliziumhaltigem bindemittel |
| DE102008063308B4 (de) | 2008-12-29 | 2013-03-07 | Basf Se | Verfahren zur Herstellung von Toluylendiamin durch Hydrierung von Dinitrotoluol |
-
2009
- 2009-04-08 JP JP2011503431A patent/JP5656826B2/ja not_active Expired - Fee Related
- 2009-04-08 EP EP09730456A patent/EP2276566A1/de not_active Withdrawn
- 2009-04-08 US US12/937,062 patent/US8742189B2/en not_active Expired - Fee Related
- 2009-04-08 WO PCT/EP2009/054201 patent/WO2009124960A1/de not_active Ceased
Also Published As
| Publication number | Publication date |
|---|---|
| EP2276566A1 (de) | 2011-01-26 |
| WO2009124960A1 (de) | 2009-10-15 |
| US8742189B2 (en) | 2014-06-03 |
| JP2011518660A (ja) | 2011-06-30 |
| US20110124933A1 (en) | 2011-05-26 |
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