JP5619443B2

JP5619443B2 - 光硬化性熱硬化性樹脂組成物、そのドライフィルム及び硬化物並びにそれらを用いたプリント配線板

光硬化性熱硬化性樹脂組成物、そのドライフィルム及び硬化物並びにそれらを用いたプリント配線板 Download PDF

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Publication number: JP5619443B2
Authority: JP; Japan
Prior art keywords: group; resin; carboxyl group; compound; parts
Prior art date: 2010-03-18
Legal status : Active

Application number

JP2010062742A

Other languages

English (en)

Japanese (ja)

Other versions

JP2011197269A (ja

Inventor

貴大吉田

有馬　聖夫

聖夫有馬

Current Assignee

Taiyo Holdings Co Ltd

Original Assignee

Taiyo Holdings Co Ltd

Priority date

2010-03-18

Filing date

2010-03-18

Publication date

2014-11-05

2010-03-18 Application filed by Taiyo Holdings Co Ltd filed Critical Taiyo Holdings Co Ltd

2010-03-18 Priority to JP2010062742A priority Critical patent/JP5619443B2/ja

2011-03-15 Priority to PCT/JP2011/056034 priority patent/WO2011115100A1/ja

2011-03-15 Priority to CN201180014603.1A priority patent/CN102812401B/zh

2011-03-15 Priority to KR1020127024161A priority patent/KR101419161B1/ko

2011-03-17 Priority to TW100109123A priority patent/TWI506356B/zh

2011-10-06 Publication of JP2011197269A publication Critical patent/JP2011197269A/ja

2014-11-05 Application granted granted Critical

2014-11-05 Publication of JP5619443B2 publication Critical patent/JP5619443B2/ja

Status Active legal-status Critical Current

2030-03-18 Anticipated expiration legal-status Critical

Links

229920001187 thermosetting polymer Polymers 0.000 title claims description 74
239000011342 resin composition Substances 0.000 title claims description 54
-1 cyclic carbonate compound Chemical class 0.000 claims description 117
229920005989 resin Polymers 0.000 claims description 104
239000011347 resin Substances 0.000 claims description 104
125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 claims description 88
229920000647 polyepoxide Polymers 0.000 claims description 70
239000003822 epoxy resin Substances 0.000 claims description 68
150000001875 compounds Chemical class 0.000 claims description 59
238000006243 chemical reaction Methods 0.000 claims description 39
125000002887 hydroxy group Chemical group [H]O* 0.000 claims description 33
239000003999 initiator Substances 0.000 claims description 28
239000000047 product Substances 0.000 claims description 21
238000001035 drying Methods 0.000 claims description 19
239000002253 acid Substances 0.000 claims description 18
IQPQWNKOIGAROB-UHFFFAOYSA-N isocyanate group Chemical group [N-]=C=O IQPQWNKOIGAROB-UHFFFAOYSA-N 0.000 claims description 18
239000007864 aqueous solution Substances 0.000 claims description 17
NIXOWILDQLNWCW-UHFFFAOYSA-M acrylate group Chemical group C(C=C)(=O)[O-] NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 claims description 15
230000015572 biosynthetic process Effects 0.000 claims description 15
ISWSIDIOOBJBQZ-UHFFFAOYSA-N phenol group Chemical group C1(=CC=CC=C1)O ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 claims description 15
238000003786 synthesis reaction Methods 0.000 claims description 14
229920002803 thermoplastic polyurethane Polymers 0.000 claims description 14
239000003513 alkali Substances 0.000 claims description 12
239000007795 chemical reaction product Substances 0.000 claims description 12
125000001624 naphthyl group Chemical group 0.000 claims description 12
150000008065 acid anhydrides Chemical class 0.000 claims description 11
125000003647 acryloyl group Chemical group O=C([*])C([H])=C([H])[H] 0.000 claims description 10
229920005862 polyol Polymers 0.000 claims description 8
150000004292 cyclic ethers Chemical group 0.000 claims description 7
125000005442 diisocyanate group Chemical group 0.000 claims description 7
125000003700 epoxy group Chemical group 0.000 claims description 7
125000002947 alkylene group Chemical group 0.000 claims description 6
239000007858 starting material Substances 0.000 claims description 6
238000000016 photochemical curing Methods 0.000 claims description 5
239000005011 phenolic resin Substances 0.000 claims description 4
150000007519 polyprotic acids Polymers 0.000 claims description 4
238000007334 copolymerization reaction Methods 0.000 claims description 3
AHHWIHXENZJRFG-UHFFFAOYSA-N oxetane Chemical compound C1COC1 AHHWIHXENZJRFG-UHFFFAOYSA-N 0.000 claims description 3
CERQOIWHTDAKMF-UHFFFAOYSA-M Methacrylate Chemical group CC(=C)C([O-])=O CERQOIWHTDAKMF-UHFFFAOYSA-M 0.000 claims description 2
229920001225 polyester resin Polymers 0.000 claims description 2
239000004645 polyester resin Substances 0.000 claims description 2
150000002763 monocarboxylic acids Chemical class 0.000 claims 2
150000001735 carboxylic acids Chemical class 0.000 claims 1
239000010408 film Substances 0.000 description 100
239000000049 pigment Substances 0.000 description 93
238000000576 coating method Methods 0.000 description 42
239000011248 coating agent Substances 0.000 description 39
239000000758 substrate Substances 0.000 description 37
229910000679 solder Inorganic materials 0.000 description 34
239000000203 mixture Substances 0.000 description 32
239000004593 Epoxy Substances 0.000 description 25
239000000243 solution Substances 0.000 description 22
KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 21
238000011156 evaluation Methods 0.000 description 21
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229910052757 nitrogen Inorganic materials 0.000 description 18
238000011161 development Methods 0.000 description 17
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239000000126 substance Substances 0.000 description 17
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125000004432 carbon atom Chemical group C* 0.000 description 15
239000005056 polyisocyanate Substances 0.000 description 15
229920001228 polyisocyanate Polymers 0.000 description 15
RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 14
239000002981 blocking agent Substances 0.000 description 14
230000000052 comparative effect Effects 0.000 description 14
LNEPOXFFQSENCJ-UHFFFAOYSA-N haloperidol Chemical compound C1CC(O)(C=2C=CC(Cl)=CC=2)CCN1CCCC(=O)C1=CC=C(F)C=C1 LNEPOXFFQSENCJ-UHFFFAOYSA-N 0.000 description 14
RAXXELZNTBOGNW-UHFFFAOYSA-N imidazole Natural products C1=CNC=N1 RAXXELZNTBOGNW-UHFFFAOYSA-N 0.000 description 14
229920003986 novolac Polymers 0.000 description 14
229920000642 polymer Polymers 0.000 description 14
239000002904 solvent Substances 0.000 description 14
RIOQSEWOXXDEQQ-UHFFFAOYSA-N triphenylphosphine Chemical compound C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1 RIOQSEWOXXDEQQ-UHFFFAOYSA-N 0.000 description 14
125000000217 alkyl group Chemical group 0.000 description 13
239000003795 chemical substances by application Substances 0.000 description 13
239000012948 isocyanate Substances 0.000 description 13
238000012360 testing method Methods 0.000 description 13
IISBACLAFKSPIT-UHFFFAOYSA-N bisphenol A Chemical compound C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 IISBACLAFKSPIT-UHFFFAOYSA-N 0.000 description 12
239000003054 catalyst Substances 0.000 description 12
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 12
DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 11
229910052802 copper Inorganic materials 0.000 description 11
239000010949 copper Substances 0.000 description 11
239000013039 cover film Substances 0.000 description 10
238000007747 plating Methods 0.000 description 10
239000007787 solid Substances 0.000 description 10
LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 9
QIGBRXMKCJKVMJ-UHFFFAOYSA-N Hydroquinone Chemical compound OC1=CC=C(O)C=C1 QIGBRXMKCJKVMJ-UHFFFAOYSA-N 0.000 description 9
238000000034 method Methods 0.000 description 9
229910000029 sodium carbonate Inorganic materials 0.000 description 9
NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 8
PYKYMHQGRFAEBM-UHFFFAOYSA-N anthraquinone Natural products CCC(=O)c1c(O)c2C(=O)C3C(C=CC=C3O)C(=O)c2cc1CC(=O)OC PYKYMHQGRFAEBM-UHFFFAOYSA-N 0.000 description 8
125000004122 cyclic group Chemical group 0.000 description 8
230000007423 decrease Effects 0.000 description 8
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238000010438 heat treatment Methods 0.000 description 8
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NWVVVBRKAWDGAB-UHFFFAOYSA-N p-methoxyphenol Chemical compound COC1=CC=C(O)C=C1 NWVVVBRKAWDGAB-UHFFFAOYSA-N 0.000 description 8
KCTAWXVAICEBSD-UHFFFAOYSA-N prop-2-enoyloxy prop-2-eneperoxoate Chemical compound C=CC(=O)OOOC(=O)C=C KCTAWXVAICEBSD-UHFFFAOYSA-N 0.000 description 8
XTQHKBHJIVJGKJ-UHFFFAOYSA-N sulfur monoxide Chemical group S=O XTQHKBHJIVJGKJ-UHFFFAOYSA-N 0.000 description 8
230000008961 swelling Effects 0.000 description 8
FPZWZCWUIYYYBU-UHFFFAOYSA-N 2-(2-ethoxyethoxy)ethyl acetate Chemical compound CCOCCOCCOC(C)=O FPZWZCWUIYYYBU-UHFFFAOYSA-N 0.000 description 7
SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 7
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238000013329 compounding Methods 0.000 description 7
239000000806 elastomer Substances 0.000 description 7
PXHVJJICTQNCMI-UHFFFAOYSA-N nickel Substances [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 7
239000012321 sodium triacetoxyborohydride Substances 0.000 description 7
KMOUUZVZFBCRAM-OLQVQODUSA-N (3as,7ar)-3a,4,7,7a-tetrahydro-2-benzofuran-1,3-dione Chemical compound C1C=CC[C@@H]2C(=O)OC(=O)[C@@H]21 KMOUUZVZFBCRAM-OLQVQODUSA-N 0.000 description 6
YXIWHUQXZSMYRE-UHFFFAOYSA-N 1,3-benzothiazole-2-thiol Chemical compound C1=CC=C2SC(S)=NC2=C1 YXIWHUQXZSMYRE-UHFFFAOYSA-N 0.000 description 6
ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 description 6
QTWJRLJHJPIABL-UHFFFAOYSA-N 2-methylphenol;3-methylphenol;4-methylphenol Chemical compound CC1=CC=C(O)C=C1.CC1=CC=CC(O)=C1.CC1=CC=CC=C1O QTWJRLJHJPIABL-UHFFFAOYSA-N 0.000 description 6
VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 6
RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 6
IAZDPXIOMUYVGZ-UHFFFAOYSA-N Dimethylsulphoxide Chemical compound CS(C)=O IAZDPXIOMUYVGZ-UHFFFAOYSA-N 0.000 description 6
UFWIBTONFRDIAS-UHFFFAOYSA-N Naphthalene Chemical compound C1=CC=CC2=CC=CC=C21 UFWIBTONFRDIAS-UHFFFAOYSA-N 0.000 description 6
239000007983 Tris buffer Substances 0.000 description 6
125000002723 alicyclic group Chemical group 0.000 description 6
125000003545 alkoxy group Chemical group 0.000 description 6
150000004056 anthraquinones Chemical class 0.000 description 6
239000003963 antioxidant agent Substances 0.000 description 6
125000003118 aryl group Chemical group 0.000 description 6
PXKLMJQFEQBVLD-UHFFFAOYSA-N bisphenol F Chemical compound C1=CC(O)=CC=C1CC1=CC=C(O)C=C1 PXKLMJQFEQBVLD-UHFFFAOYSA-N 0.000 description 6
239000003086 colorant Substances 0.000 description 6
239000011889 copper foil Substances 0.000 description 6
XCJYREBRNVKWGJ-UHFFFAOYSA-N copper(II) phthalocyanine Chemical compound [Cu+2].C12=CC=CC=C2C(N=C2[N-]C(C3=CC=CC=C32)=N2)=NC1=NC([C]1C=CC=CC1=1)=NC=1N=C1[C]3C=CC=CC3=C2[N-]1 XCJYREBRNVKWGJ-UHFFFAOYSA-N 0.000 description 6
229930003836 cresol Natural products 0.000 description 6
125000004663 dialkyl amino group Chemical group 0.000 description 6
239000012535 impurity Substances 0.000 description 6
QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 description 6
229910052753 mercury Inorganic materials 0.000 description 6
229910052751 metal Inorganic materials 0.000 description 6
239000002184 metal Substances 0.000 description 6
OKKJLVBELUTLKV-UHFFFAOYSA-N methanol Natural products OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 6
239000003960 organic solvent Substances 0.000 description 6
125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 6
150000003077 polyols Chemical class 0.000 description 6
238000007650 screen-printing Methods 0.000 description 6
239000007921 spray Substances 0.000 description 6
CWERGRDVMFNCDR-UHFFFAOYSA-M thioglycolate(1-) Chemical compound [O-]C(=O)CS CWERGRDVMFNCDR-UHFFFAOYSA-M 0.000 description 6
CNHDIAIOKMXOLK-UHFFFAOYSA-N toluquinol Chemical compound CC1=CC(O)=CC=C1O CNHDIAIOKMXOLK-UHFFFAOYSA-N 0.000 description 6
239000002966 varnish Substances 0.000 description 6
239000004925 Acrylic resin Substances 0.000 description 5
CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 5
GOOHAUXETOMSMM-UHFFFAOYSA-N Propylene oxide Chemical compound CC1CO1 GOOHAUXETOMSMM-UHFFFAOYSA-N 0.000 description 5
150000001252 acrylic acid derivatives Chemical class 0.000 description 5
125000003277 amino group Chemical group 0.000 description 5
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PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 5
229910052737 gold Inorganic materials 0.000 description 5
239000010931 gold Substances 0.000 description 5
NYGZLYXAPMMJTE-UHFFFAOYSA-M metanil yellow Chemical group [Na+].[O-]S(=O)(=O)C1=CC=CC(N=NC=2C=CC(NC=3C=CC=CC=3)=CC=2)=C1 NYGZLYXAPMMJTE-UHFFFAOYSA-M 0.000 description 5
229910052759 nickel Inorganic materials 0.000 description 5
230000035515 penetration Effects 0.000 description 5
239000003208 petroleum Substances 0.000 description 5
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238000003756 stirring Methods 0.000 description 5
150000003553 thiiranes Chemical class 0.000 description 5
238000012546 transfer Methods 0.000 description 5
HEQOJEGTZCTHCF-UHFFFAOYSA-N 2-amino-1-phenylethanone Chemical compound NCC(=O)C1=CC=CC=C1 HEQOJEGTZCTHCF-UHFFFAOYSA-N 0.000 description 4
IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 4
239000005058 Isophorone diisocyanate Substances 0.000 description 4
239000004721 Polyphenylene oxide Substances 0.000 description 4
VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 4
YTPLMLYBLZKORZ-UHFFFAOYSA-N Thiophene Chemical compound C=1C=CSC=1 YTPLMLYBLZKORZ-UHFFFAOYSA-N 0.000 description 4
238000010521 absorption reaction Methods 0.000 description 4
WNLRTRBMVRJNCN-UHFFFAOYSA-N adipic acid Chemical compound OC(=O)CCCCC(O)=O WNLRTRBMVRJNCN-UHFFFAOYSA-N 0.000 description 4
125000001931 aliphatic group Chemical group 0.000 description 4
150000001412 amines Chemical class 0.000 description 4
150000004945 aromatic hydrocarbons Chemical class 0.000 description 4
ZYGHJZDHTFUPRJ-UHFFFAOYSA-N benzo-alpha-pyrone Natural products C1=CC=C2OC(=O)C=CC2=C1 ZYGHJZDHTFUPRJ-UHFFFAOYSA-N 0.000 description 4
ISAOCJYIOMOJEB-UHFFFAOYSA-N benzoin Chemical class C=1C=CC=CC=1C(O)C(=O)C1=CC=CC=C1 ISAOCJYIOMOJEB-UHFFFAOYSA-N 0.000 description 4
WQAQPCDUOCURKW-UHFFFAOYSA-N butanethiol Chemical compound CCCCS WQAQPCDUOCURKW-UHFFFAOYSA-N 0.000 description 4
229920001577 copolymer Polymers 0.000 description 4
150000004294 cyclic thioethers Chemical group 0.000 description 4
125000000664 diazo group Chemical group [N-]=[N+]=[*] 0.000 description 4
238000004090 dissolution Methods 0.000 description 4
239000011521 glass Substances 0.000 description 4
VOZRXNHHFUQHIL-UHFFFAOYSA-N glycidyl methacrylate Chemical compound CC(=C)C(=O)OCC1CO1 VOZRXNHHFUQHIL-UHFFFAOYSA-N 0.000 description 4
239000003112 inhibitor Substances 0.000 description 4
NIMLQBUJDJZYEJ-UHFFFAOYSA-N isophorone diisocyanate Chemical compound CC1(C)CC(N=C=O)CC(C)(CN=C=O)C1 NIMLQBUJDJZYEJ-UHFFFAOYSA-N 0.000 description 4
239000007788 liquid Substances 0.000 description 4
JDSHMPZPIAZGSV-UHFFFAOYSA-N melamine Chemical compound NC1=NC(N)=NC(N)=N1 JDSHMPZPIAZGSV-UHFFFAOYSA-N 0.000 description 4
QWVGKYWNOKOFNN-UHFFFAOYSA-N o-cresol Chemical compound CC1=CC=CC=C1O QWVGKYWNOKOFNN-UHFFFAOYSA-N 0.000 description 4
150000002921 oxetanes Chemical class 0.000 description 4
XNGIFLGASWRNHJ-UHFFFAOYSA-N phthalic acid Chemical compound OC(=O)C1=CC=CC=C1C(O)=O XNGIFLGASWRNHJ-UHFFFAOYSA-N 0.000 description 4
230000009257 reactivity Effects 0.000 description 4
239000004065 semiconductor Substances 0.000 description 4
230000035945 sensitivity Effects 0.000 description 4
230000035939 shock Effects 0.000 description 4
239000011973 solid acid Substances 0.000 description 4
238000012719 thermal polymerization Methods 0.000 description 4
239000006097 ultraviolet radiation absorber Substances 0.000 description 4
POILWHVDKZOXJZ-ARJAWSKDSA-M (z)-4-oxopent-2-en-2-olate Chemical class C\C([O-])=C\C(C)=O POILWHVDKZOXJZ-ARJAWSKDSA-M 0.000 description 3
WJFKNYWRSNBZNX-UHFFFAOYSA-N 10H-phenothiazine Chemical compound C1=CC=C2NC3=CC=CC=C3SC2=C1 WJFKNYWRSNBZNX-UHFFFAOYSA-N 0.000 description 3
PTBDIHRZYDMNKB-UHFFFAOYSA-N 2,2-Bis(hydroxymethyl)propionic acid Chemical compound OCC(C)(CO)C(O)=O PTBDIHRZYDMNKB-UHFFFAOYSA-N 0.000 description 3
VPWNQTHUCYMVMZ-UHFFFAOYSA-N 4,4'-sulfonyldiphenol Chemical compound C1=CC(O)=CC=C1S(=O)(=O)C1=CC=C(O)C=C1 VPWNQTHUCYMVMZ-UHFFFAOYSA-N 0.000 description 3
GZVHEAJQGPRDLQ-UHFFFAOYSA-N 6-phenyl-1,3,5-triazine-2,4-diamine Chemical class NC1=NC(N)=NC(C=2C=CC=CC=2)=N1 GZVHEAJQGPRDLQ-UHFFFAOYSA-N 0.000 description 3
KWOLFJPFCHCOCG-UHFFFAOYSA-N Acetophenone Natural products CC(=O)C1=CC=CC=C1 KWOLFJPFCHCOCG-UHFFFAOYSA-N 0.000 description 3
BRLQWZUYTZBJKN-UHFFFAOYSA-N Epichlorohydrin Chemical compound ClCC1CO1 BRLQWZUYTZBJKN-UHFFFAOYSA-N 0.000 description 3
XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 3
JOYRKODLDBILNP-UHFFFAOYSA-N Ethyl urethane Chemical compound CCOC(N)=O JOYRKODLDBILNP-UHFFFAOYSA-N 0.000 description 3
IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 3
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SJRJJKPEHAURKC-UHFFFAOYSA-N N-Methylmorpholine Chemical compound CN1CCOCC1 SJRJJKPEHAURKC-UHFFFAOYSA-N 0.000 description 3
239000002202 Polyethylene glycol Substances 0.000 description 3
BAPJBEWLBFYGME-UHFFFAOYSA-N acrylic acid methyl ester Natural products COC(=O)C=C BAPJBEWLBFYGME-UHFFFAOYSA-N 0.000 description 3
125000003282 alkyl amino group Chemical group 0.000 description 3
150000008366 benzophenones Chemical class 0.000 description 3
IOJUPLGTWVMSFF-UHFFFAOYSA-N benzothiazole Chemical class C1=CC=C2SC=NC2=C1 IOJUPLGTWVMSFF-UHFFFAOYSA-N 0.000 description 3
238000007664 blowing Methods 0.000 description 3
230000008859 change Effects 0.000 description 3
229910052804 chromium Inorganic materials 0.000 description 3
229960000956 coumarin Drugs 0.000 description 3
235000001671 coumarin Nutrition 0.000 description 3
GDVKFRBCXAPAQJ-UHFFFAOYSA-A dialuminum;hexamagnesium;carbonate;hexadecahydroxide Chemical compound [OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Al+3].[Al+3].[O-]C([O-])=O GDVKFRBCXAPAQJ-UHFFFAOYSA-A 0.000 description 3
XXBDWLFCJWSEKW-UHFFFAOYSA-N dimethylbenzylamine Chemical compound CN(C)CC1=CC=CC=C1 XXBDWLFCJWSEKW-UHFFFAOYSA-N 0.000 description 3
150000002009 diols Chemical class 0.000 description 3
238000002845 discoloration Methods 0.000 description 3
239000000975 dye Substances 0.000 description 3
230000000694 effects Effects 0.000 description 3
238000010828 elution Methods 0.000 description 3
230000007613 environmental effect Effects 0.000 description 3
DNJIEGIFACGWOD-UHFFFAOYSA-N ethyl mercaptane Natural products CCS DNJIEGIFACGWOD-UHFFFAOYSA-N 0.000 description 3
230000006870 function Effects 0.000 description 3
125000003055 glycidyl group Chemical group C(C1CO1)* 0.000 description 3
229910001701 hydrotalcite Inorganic materials 0.000 description 3
229960001545 hydrotalcite Drugs 0.000 description 3
XEEYBQQBJWHFJM-UHFFFAOYSA-N iron Substances [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 3
229910052742 iron Inorganic materials 0.000 description 3
230000031700 light absorption Effects 0.000 description 3
229910052748 manganese Inorganic materials 0.000 description 3
150000007974 melamines Chemical class 0.000 description 3
229910001510 metal chloride Inorganic materials 0.000 description 3
125000003566 oxetanyl group Chemical group 0.000 description 3
WXZMFSXDPGVJKK-UHFFFAOYSA-N pentaerythritol Chemical compound OCC(CO)(CO)CO WXZMFSXDPGVJKK-UHFFFAOYSA-N 0.000 description 3
150000002978 peroxides Chemical class 0.000 description 3
125000002080 perylenyl group Chemical group C1(=CC=C2C=CC=C3C4=CC=CC5=CC=CC(C1=C23)=C45)* 0.000 description 3
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