JP5595120B2 - 発光素子、発光装置、電子機器、及び照明装置 - Google Patents
発光素子、発光装置、電子機器、及び照明装置 Download PDFInfo
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- JP5595120B2 JP5595120B2 JP2010118073A JP2010118073A JP5595120B2 JP 5595120 B2 JP5595120 B2 JP 5595120B2 JP 2010118073 A JP2010118073 A JP 2010118073A JP 2010118073 A JP2010118073 A JP 2010118073A JP 5595120 B2 JP5595120 B2 JP 5595120B2
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- 239000000126 substance Substances 0.000 claims description 195
- 239000000463 material Substances 0.000 claims description 77
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- 238000005286 illumination Methods 0.000 claims description 21
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- 239000002184 metal Substances 0.000 claims description 19
- PQQKPALAQIIWST-UHFFFAOYSA-N oxomolybdenum Chemical group [Mo]=O PQQKPALAQIIWST-UHFFFAOYSA-N 0.000 claims description 19
- 229910000476 molybdenum oxide Inorganic materials 0.000 claims description 15
- 229910052783 alkali metal Inorganic materials 0.000 claims description 10
- 150000001340 alkali metals Chemical class 0.000 claims description 10
- 229910052784 alkaline earth metal Inorganic materials 0.000 claims description 10
- 150000001342 alkaline earth metals Chemical class 0.000 claims description 10
- 125000002080 perylenyl group Chemical group C1(=CC=C2C=CC=C3C4=CC=CC5=CC=CC(C1=C23)=C45)* 0.000 claims description 8
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- 230000000737 periodic effect Effects 0.000 claims description 5
- 150000001339 alkali metal compounds Chemical class 0.000 claims description 2
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- PJXISJQVUVHSOJ-UHFFFAOYSA-N indium(iii) oxide Chemical compound [O-2].[O-2].[O-2].[In+3].[In+3] PJXISJQVUVHSOJ-UHFFFAOYSA-N 0.000 description 8
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- IYZMXHQDXZKNCY-UHFFFAOYSA-N 1-n,1-n-diphenyl-4-n,4-n-bis[4-(n-phenylanilino)phenyl]benzene-1,4-diamine Chemical compound C1=CC=CC=C1N(C=1C=CC(=CC=1)N(C=1C=CC(=CC=1)N(C=1C=CC=CC=1)C=1C=CC=CC=1)C=1C=CC(=CC=1)N(C=1C=CC=CC=1)C=1C=CC=CC=1)C1=CC=CC=C1 IYZMXHQDXZKNCY-UHFFFAOYSA-N 0.000 description 5
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- SPDPTFAJSFKAMT-UHFFFAOYSA-N 1-n-[4-[4-(n-[4-(3-methyl-n-(3-methylphenyl)anilino)phenyl]anilino)phenyl]phenyl]-4-n,4-n-bis(3-methylphenyl)-1-n-phenylbenzene-1,4-diamine Chemical compound CC1=CC=CC(N(C=2C=CC(=CC=2)N(C=2C=CC=CC=2)C=2C=CC(=CC=2)C=2C=CC(=CC=2)N(C=2C=CC=CC=2)C=2C=CC(=CC=2)N(C=2C=C(C)C=CC=2)C=2C=C(C)C=CC=2)C=2C=C(C)C=CC=2)=C1 SPDPTFAJSFKAMT-UHFFFAOYSA-N 0.000 description 3
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- OYQCBJZGELKKPM-UHFFFAOYSA-N zinc indium(3+) oxygen(2-) Chemical compound [O-2].[Zn+2].[O-2].[In+3] OYQCBJZGELKKPM-UHFFFAOYSA-N 0.000 description 1
- GWDUZCIBPDVBJM-UHFFFAOYSA-L zinc;2-(2-hydroxyphenyl)-3h-1,3-benzothiazole-2-carboxylate Chemical compound [Zn+2].OC1=CC=CC=C1C1(C([O-])=O)SC2=CC=CC=C2N1.OC1=CC=CC=C1C1(C([O-])=O)SC2=CC=CC=C2N1 GWDUZCIBPDVBJM-UHFFFAOYSA-L 0.000 description 1
- QEPMORHSGFRDLW-UHFFFAOYSA-L zinc;2-(2-hydroxyphenyl)-3h-1,3-benzoxazole-2-carboxylate Chemical compound [Zn+2].OC1=CC=CC=C1C1(C([O-])=O)OC2=CC=CC=C2N1.OC1=CC=CC=C1C1(C([O-])=O)OC2=CC=CC=C2N1 QEPMORHSGFRDLW-UHFFFAOYSA-L 0.000 description 1
- HTPBWAPZAJWXKY-UHFFFAOYSA-L zinc;quinolin-8-olate Chemical compound [Zn+2].C1=CN=C2C([O-])=CC=CC2=C1.C1=CN=C2C([O-])=CC=CC2=C1 HTPBWAPZAJWXKY-UHFFFAOYSA-L 0.000 description 1
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Description
本実施の形態では、発光素子の一態様について図1を用いて説明する。
本実施の形態では、実施の形態1に示した発光素子の一例について示す。具体的には、実施の形態1で示した発光素子が有する電子注入バッファー層104が、ドナー性物質の単層によって構成される場合について、図2(A)、(B)を用いて説明する。
本実施の形態では、実施の形態1に示した発光素子の一例について示す。具体的には、実施の形態1で示した発光素子が有する電子注入バッファー層104が、電子輸送性物質と、ドナー性物質とを含んで構成される場合について、図3(A)、(B)を用いて説明する。
本実施の形態では、実施の形態1に示した発光素子の一例について示す。具体的には、実施の形態1で示した発光素子が有する電荷発生層106の構成について、図4(A)、(B)を用いて説明する。
本実施の形態では、実施の形態1に示した発光素子の一例について示す。具体的には、実施の形態1で示した発光素子の一例について、図5(A)、(B)を用いて説明する。
本実施の形態では、実施の形態1乃至5で示した発光素子を含む発光装置の一態様について、図6を用いて説明する。図6は、当該発光装置の断面図である。
本実施の形態では、実施の形態6で一例を示した発光装置を含む電子機器について説明する。
本実施の形態では、実施の形態6で一例を示した発光装置を含む照明装置について説明する。
11 トランジスタ
12 発光素子
13 電極
14 電極
15 有機化合物を含む層
16a 層間絶縁膜
16b 層間絶縁膜
16c 層間絶縁膜
17 配線
18 隔壁層
19a 層間絶縁膜
19b 層間絶縁膜
101 陽極
102 陰極
103 EL層
103a 第1の発光層
103b 第2の発光層
104 電子注入バッファー層
105 電子リレー層
106 電荷発生層
106a 正孔輸送性物質を含む層
106b アクセプター性物質を含む層
107 EL層
107a 第3の発光層
107b 第4の発光層
108 電子輸送層
111 陽極のフェルミ準位
112 陰極のフェルミ準位
113 第1のEL層のLUMO準位
114 電子リレー層におけるドナー性物質のドナー準位
115 電子リレー層における電子輸送性物質のLUMO準位
116 電荷発生層におけるアクセプター性物質のアクセプター準位
117 第2のEL層のLUMO準位
330 第1の発光
340 第2の発光
800 携帯情報端末機器
801 筐体
802 表示部
803 筐体
805 キーボード
807 連結部
810 デジタルビデオカメラ
811 筐体
812 表示部
820 携帯電話機
821 筐体
822 筐体
823 連結部
824 表示部
825 操作キー
830 コンピュータ
831 筐体
832 表示部
833 キーボード
834 筐体
840 テレビジョン
841 筐体
842 表示部
843 スタンド
850 リモコン操作機
851 操作キー
852 表示部
900 卓上照明装置
901 照明部
910 天井用照明装置
911 照明部
920 ロール型照明装置
921 照明部
951 基板
952 電極
953 絶縁層
954 隔壁層
955 発光素子
956 電極
1000 信号機
1001 照明部
1002 照明部
1003 照明部
1010 避難口誘導灯
1021 支持体
1022 照明部
1023 電柱
1024 送電線
1031 装着部
1032 照明部
1041 筐体
1042 照明部
1043 スイッチ
2100 基板
2101 電極
2102 電極
2103 EL層
2103a 電荷発生層
2103b 正孔輸送層
2103c 発光層
2103d 電子輸送層
2104 電子注入バッファー層
2105 電子リレー層
2106 電荷発生層
2107 EL層
2107a 正孔輸送層
2107b 発光層
2107c 電子輸送層
2107d 電子注入層
Claims (11)
- 陽極と陰極の間にn(nは2以上の自然数)層のEL層を有し、
前記陽極からm(mは自然数、1≦m≦n−1)番目のEL層とm+1番目のEL層の間には、
前記m番目のEL層と接する、第1の電子輸送性物質及び第1のドナー性物質を含む第1の層と、
前記第1の層と接する、前記第1の電子輸送性物質よりも最低空分子軌道準位が低い第2の電子輸送性物質及び第2のドナー性物質を含む第2の層と、
前記第2の層及び前記m+1番目のEL層と接する、正孔輸送性物質及びアクセプター性物質を含む第3の層と、を有する発光素子。 - 請求項1において、
前記第1の層が、前記第1の電子輸送性物質に対して質量比で、0.001以上0.1以下の比率で前記第1のドナー性物質を添加した層である発光素子。 - 請求項1または請求項2において、
前記第2の電子輸送性物質のLUMO準位が−5.0eV以上である発光素子。 - 請求項1乃至請求項3のいずれか一項において、
前記第2の電子輸送性物質は、ペリレン誘導体又は含窒素縮合芳香族化合物である発光素子。 - 請求項1乃至請求項4のいずれか一項において、
前記第1のドナー性物質及び前記第2のドナー性物質が、アルカリ金属、アルカリ土類金属、希土類金属、アルカリ金属化合物、アルカリ土類金属化合物、または希土類金属化合物である発光素子。 - 請求項1乃至請求項5のいずれか一項において、
前記第3の層が、前記正孔輸送性物質に対して質量比で、0.1以上4.0以下の比率で前記アクセプター性物質を添加した層である発光素子。 - 請求項1乃至請求項6のいずれか一項において、
前記アクセプター性物質は、元素周期表における第4族乃至第8族に属する金属の酸化物である発光素子。 - 請求項1乃至請求項6のいずれか一において、
前記アクセプター性物質は、酸化モリブデンである発光素子。 - 請求項1乃至請求項8のいずれか一項に記載の発光素子を用いて作製された発光装置。
- 請求項9に記載の発光装置を含む電子機器。
- 請求項9に記載の発光装置を含む照明装置。
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