JP5586581B2 - 気相酸化反応器の始動方法 - Google Patents
気相酸化反応器の始動方法 Download PDFInfo
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- JP5586581B2 JP5586581B2 JP2011503424A JP2011503424A JP5586581B2 JP 5586581 B2 JP5586581 B2 JP 5586581B2 JP 2011503424 A JP2011503424 A JP 2011503424A JP 2011503424 A JP2011503424 A JP 2011503424A JP 5586581 B2 JP5586581 B2 JP 5586581B2
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- 238000000034 method Methods 0.000 title claims description 22
- 238000007254 oxidation reaction Methods 0.000 title claims description 16
- 230000003647 oxidation Effects 0.000 title claims description 15
- 239000003054 catalyst Substances 0.000 claims description 134
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical group CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 claims description 46
- 239000011149 active material Substances 0.000 claims description 35
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims description 33
- 229940078552 o-xylene Drugs 0.000 claims description 23
- GNTDGMZSJNCJKK-UHFFFAOYSA-N divanadium pentaoxide Chemical compound O=[V](=O)O[V](=O)=O GNTDGMZSJNCJKK-UHFFFAOYSA-N 0.000 claims description 22
- 238000012546 transfer Methods 0.000 claims description 16
- 230000000694 effects Effects 0.000 claims description 14
- 238000011144 upstream manufacturing Methods 0.000 claims description 14
- LGRFSURHDFAFJT-UHFFFAOYSA-N Phthalic anhydride Natural products C1=CC=C2C(=O)OC(=O)C2=C1 LGRFSURHDFAFJT-UHFFFAOYSA-N 0.000 claims description 12
- JHIWVOJDXOSYLW-UHFFFAOYSA-N butyl 2,2-difluorocyclopropane-1-carboxylate Chemical compound CCCCOC(=O)C1CC1(F)F JHIWVOJDXOSYLW-UHFFFAOYSA-N 0.000 claims description 12
- 239000004408 titanium dioxide Substances 0.000 claims description 12
- 230000008569 process Effects 0.000 claims description 6
- 230000001590 oxidative effect Effects 0.000 claims description 2
- 239000007789 gas Substances 0.000 description 33
- 238000012856 packing Methods 0.000 description 23
- ADCOVFLJGNWWNZ-UHFFFAOYSA-N antimony trioxide Chemical compound O=[Sb]O[Sb]=O ADCOVFLJGNWWNZ-UHFFFAOYSA-N 0.000 description 14
- 238000006243 chemical reaction Methods 0.000 description 14
- 239000000463 material Substances 0.000 description 11
- 150000003839 salts Chemical class 0.000 description 11
- 239000000203 mixture Substances 0.000 description 9
- 239000011230 binding agent Substances 0.000 description 7
- KOPBYBDAPCDYFK-UHFFFAOYSA-N caesium oxide Chemical class [O-2].[Cs+].[Cs+] KOPBYBDAPCDYFK-UHFFFAOYSA-N 0.000 description 7
- 229910001942 caesium oxide Inorganic materials 0.000 description 7
- 229910052783 alkali metal Inorganic materials 0.000 description 6
- 150000001340 alkali metals Chemical class 0.000 description 6
- 239000000047 product Substances 0.000 description 6
- 230000009466 transformation Effects 0.000 description 6
- 230000000052 comparative effect Effects 0.000 description 5
- YWEUIGNSBFLMFL-UHFFFAOYSA-N diphosphonate Chemical compound O=P(=O)OP(=O)=O YWEUIGNSBFLMFL-UHFFFAOYSA-N 0.000 description 5
- 238000004519 manufacturing process Methods 0.000 description 5
- DLYUQMMRRRQYAE-UHFFFAOYSA-N phosphorus pentoxide Inorganic materials O1P(O2)(=O)OP3(=O)OP1(=O)OP2(=O)O3 DLYUQMMRRRQYAE-UHFFFAOYSA-N 0.000 description 5
- WNZQDUSMALZDQF-UHFFFAOYSA-N 2-benzofuran-1(3H)-one Chemical compound C1=CC=C2C(=O)OCC2=C1 WNZQDUSMALZDQF-UHFFFAOYSA-N 0.000 description 4
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 4
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 4
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 4
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 4
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 description 4
- 239000003513 alkali Substances 0.000 description 4
- 230000015572 biosynthetic process Effects 0.000 description 4
- 238000001354 calcination Methods 0.000 description 4
- 230000003197 catalytic effect Effects 0.000 description 4
- 229930195733 hydrocarbon Natural products 0.000 description 4
- 150000002430 hydrocarbons Chemical class 0.000 description 4
- XOLBLPGZBRYERU-UHFFFAOYSA-N tin dioxide Chemical compound O=[Sn]=O XOLBLPGZBRYERU-UHFFFAOYSA-N 0.000 description 4
- MYMOFIZGZYHOMD-UHFFFAOYSA-N Dioxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 description 3
- 150000001299 aldehydes Chemical class 0.000 description 3
- 239000011248 coating agent Substances 0.000 description 3
- 238000000576 coating method Methods 0.000 description 3
- 238000001816 cooling Methods 0.000 description 3
- 229910001882 dioxygen Inorganic materials 0.000 description 3
- HCWCAKKEBCNQJP-UHFFFAOYSA-N magnesium orthosilicate Chemical compound [Mg+2].[Mg+2].[O-][Si]([O-])([O-])[O-] HCWCAKKEBCNQJP-UHFFFAOYSA-N 0.000 description 3
- 239000000391 magnesium silicate Substances 0.000 description 3
- 229910052919 magnesium silicate Inorganic materials 0.000 description 3
- 235000019792 magnesium silicate Nutrition 0.000 description 3
- HBMJWWWQQXIZIP-UHFFFAOYSA-N silicon carbide Chemical compound [Si+]#[C-] HBMJWWWQQXIZIP-UHFFFAOYSA-N 0.000 description 3
- 229910010271 silicon carbide Inorganic materials 0.000 description 3
- 239000000243 solution Substances 0.000 description 3
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 description 2
- 229910018072 Al 2 O 3 Inorganic materials 0.000 description 2
- 239000004215 Carbon black (E152) Substances 0.000 description 2
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 2
- YKTSYUJCYHOUJP-UHFFFAOYSA-N [O--].[Al+3].[Al+3].[O-][Si]([O-])([O-])[O-] Chemical compound [O--].[Al+3].[Al+3].[O-][Si]([O-])([O-])[O-] YKTSYUJCYHOUJP-UHFFFAOYSA-N 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 2
- 229910052787 antimony Inorganic materials 0.000 description 2
- 150000004945 aromatic hydrocarbons Chemical class 0.000 description 2
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 2
- 239000006227 byproduct Substances 0.000 description 2
- 229910052792 caesium Inorganic materials 0.000 description 2
- 239000001569 carbon dioxide Substances 0.000 description 2
- 229910002092 carbon dioxide Inorganic materials 0.000 description 2
- 150000001735 carboxylic acids Chemical class 0.000 description 2
- 239000012876 carrier material Substances 0.000 description 2
- JIHMVMRETUQLFD-UHFFFAOYSA-N cerium(3+);dioxido(oxo)silane Chemical compound [Ce+3].[Ce+3].[O-][Si]([O-])=O.[O-][Si]([O-])=O.[O-][Si]([O-])=O JIHMVMRETUQLFD-UHFFFAOYSA-N 0.000 description 2
- 239000007795 chemical reaction product Substances 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 238000009826 distribution Methods 0.000 description 2
- 238000011049 filling Methods 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- 230000001771 impaired effect Effects 0.000 description 2
- 229910052742 iron Inorganic materials 0.000 description 2
- 239000000395 magnesium oxide Substances 0.000 description 2
- CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 description 2
- AXZKOIWUVFPNLO-UHFFFAOYSA-N magnesium;oxygen(2-) Chemical compound [O-2].[Mg+2] AXZKOIWUVFPNLO-UHFFFAOYSA-N 0.000 description 2
- 229910052757 nitrogen Inorganic materials 0.000 description 2
- 229910052760 oxygen Inorganic materials 0.000 description 2
- 239000001301 oxygen Substances 0.000 description 2
- 239000002245 particle Substances 0.000 description 2
- 229910052573 porcelain Inorganic materials 0.000 description 2
- 239000012495 reaction gas Substances 0.000 description 2
- 239000011541 reaction mixture Substances 0.000 description 2
- 239000000725 suspension Substances 0.000 description 2
- 238000011282 treatment Methods 0.000 description 2
- 229910052720 vanadium Inorganic materials 0.000 description 2
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 1
- 239000005977 Ethylene Substances 0.000 description 1
- 229920000663 Hydroxyethyl cellulose Polymers 0.000 description 1
- 239000004354 Hydroxyethyl cellulose Substances 0.000 description 1
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 description 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
- XHCLAFWTIXFWPH-UHFFFAOYSA-N [O-2].[O-2].[O-2].[O-2].[O-2].[V+5].[V+5] Chemical compound [O-2].[O-2].[O-2].[O-2].[O-2].[V+5].[V+5] XHCLAFWTIXFWPH-UHFFFAOYSA-N 0.000 description 1
- 230000004913 activation Effects 0.000 description 1
- 239000004480 active ingredient Substances 0.000 description 1
- 239000013543 active substance Substances 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 150000001339 alkali metal compounds Chemical class 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
- 150000001558 benzoic acid derivatives Chemical class 0.000 description 1
- 238000009529 body temperature measurement Methods 0.000 description 1
- 150000001244 carboxylic acid anhydrides Chemical class 0.000 description 1
- 238000002485 combustion reaction Methods 0.000 description 1
- 229920001577 copolymer Polymers 0.000 description 1
- 239000003085 diluting agent Substances 0.000 description 1
- 238000010790 dilution Methods 0.000 description 1
- 239000012895 dilution Substances 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- POULHZVOKOAJMA-UHFFFAOYSA-M dodecanoate Chemical compound CCCCCCCCCCCC([O-])=O POULHZVOKOAJMA-UHFFFAOYSA-M 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 235000019447 hydroxyethyl cellulose Nutrition 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 239000003112 inhibitor Substances 0.000 description 1
- 238000009434 installation Methods 0.000 description 1
- 230000002427 irreversible effect Effects 0.000 description 1
- 229940070765 laurate Drugs 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 229910001947 lithium oxide Inorganic materials 0.000 description 1
- 238000011068 loading method Methods 0.000 description 1
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- BTFQKIATRPGRBS-UHFFFAOYSA-N o-tolualdehyde Chemical compound CC1=CC=CC=C1C=O BTFQKIATRPGRBS-UHFFFAOYSA-N 0.000 description 1
- 239000011236 particulate material Substances 0.000 description 1
- 125000005506 phthalide group Chemical group 0.000 description 1
- 229910001950 potassium oxide Inorganic materials 0.000 description 1
- 239000012041 precatalyst Substances 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 230000002441 reversible effect Effects 0.000 description 1
- 238000004904 shortening Methods 0.000 description 1
- 238000007086 side reaction Methods 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- -1 sodium- and rubidium oxides Chemical class 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 229910052717 sulfur Inorganic materials 0.000 description 1
- 239000011593 sulfur Substances 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 1
- 229910001935 vanadium oxide Inorganic materials 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
- GFQYVLUOOAAOGM-UHFFFAOYSA-N zirconium(iv) silicate Chemical compound [Zr+4].[O-][Si]([O-])([O-])[O-] GFQYVLUOOAAOGM-UHFFFAOYSA-N 0.000 description 1
Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
- C07C51/16—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
- C07C51/21—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen
- C07C51/255—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of compounds containing six-membered aromatic rings without ring-splitting
- C07C51/265—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of compounds containing six-membered aromatic rings without ring-splitting having alkyl side chains which are oxidised to carboxyl groups
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D307/00—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom
- C07D307/77—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom ortho- or peri-condensed with carbocyclic rings or ring systems
- C07D307/87—Benzo [c] furans; Hydrogenated benzo [c] furans
- C07D307/89—Benzo [c] furans; Hydrogenated benzo [c] furans with two oxygen atoms directly attached in positions 1 and 3
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Catalysts (AREA)
- Furan Compounds (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP08154169 | 2008-04-07 | ||
| EP08154169.0 | 2008-04-07 | ||
| PCT/EP2009/054168 WO2009124946A1 (de) | 2008-04-07 | 2009-04-07 | Verfahren zum anfahren eines gasphasenoxidationsreaktors |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| JP2011519825A JP2011519825A (ja) | 2011-07-14 |
| JP2011519825A5 JP2011519825A5 (enExample) | 2012-05-31 |
| JP5586581B2 true JP5586581B2 (ja) | 2014-09-10 |
Family
ID=40897595
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2011503424A Expired - Fee Related JP5586581B2 (ja) | 2008-04-07 | 2009-04-07 | 気相酸化反応器の始動方法 |
Country Status (8)
| Country | Link |
|---|---|
| US (1) | US8492566B2 (enExample) |
| EP (1) | EP2280921B1 (enExample) |
| JP (1) | JP5586581B2 (enExample) |
| KR (1) | KR101581063B1 (enExample) |
| CN (1) | CN102056886B (enExample) |
| BR (1) | BRPI0910946A2 (enExample) |
| TW (1) | TWI453190B (enExample) |
| WO (1) | WO2009124946A1 (enExample) |
Families Citing this family (14)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| SI2027102T1 (sl) * | 2006-05-19 | 2010-08-31 | Basf Se | Proizvodnja ftalnega anhidrida s pomoäśjo plinske fazne oksidacije o-ksilola v primarnem in sekundarnem reaktorju |
| EP2024351B1 (de) * | 2006-05-19 | 2011-03-09 | Basf Se | Herstellung von phthalsäureanhydrid durch gasphasenoxidation von o-xylol |
| JP5300738B2 (ja) | 2006-12-21 | 2013-09-25 | ビーエーエスエフ ソシエタス・ヨーロピア | 前方層を使用して気相酸化するための触媒系及び方法 |
| CN102015609A (zh) * | 2008-04-07 | 2011-04-13 | 巴斯夫欧洲公司 | 起动含有催化活性银钒氧化物青铜的气相氧化反应器的方法 |
| CN102099346A (zh) * | 2008-07-14 | 2011-06-15 | 巴斯夫欧洲公司 | 制备环氧乙烷的方法 |
| WO2010072723A2 (de) | 2008-12-22 | 2010-07-01 | Basf Se | Katalysator und verfahren zur herstellung von maleinsäureanhydrid |
| WO2011061132A1 (de) * | 2009-11-20 | 2011-05-26 | Basf Se | Mehrlagenkatalysator zur herstellung von carbonsäuren und/oder carbonsäureanhydriden mit vanadiumantimonat in wenigstens einer katalysatorlage und verfahren zur herstellung von phthalsäureanhydrid mit niedriger hotspottemperatur |
| US8609906B2 (en) * | 2009-12-15 | 2013-12-17 | Basf Se | Process for preparing C1-C4-oxygenates by partial oxidation of hydrocarbons |
| US20110230668A1 (en) * | 2010-03-19 | 2011-09-22 | Basf Se | Catalyst for gas phase oxidations based on low-sulfur and low-calcium titanium dioxide |
| TW201206896A (en) | 2010-04-13 | 2012-02-16 | Basf Se | Process for controlling a gas phase oxidation reactor for preparation of phthalic anhydride |
| US8859459B2 (en) | 2010-06-30 | 2014-10-14 | Basf Se | Multilayer catalyst for preparing phthalic anhydride and process for preparing phthalic anhydride |
| US9212157B2 (en) | 2010-07-30 | 2015-12-15 | Basf Se | Catalyst for the oxidation of o-xylene and/or naphthalene to phthalic anhydride |
| CN105339338B (zh) * | 2013-06-26 | 2017-11-21 | 巴斯夫欧洲公司 | 起动气相氧化反应器的方法 |
| CN116134024A (zh) * | 2020-07-14 | 2023-05-16 | 科莱恩国际有限公司 | 启动用于制备邻苯二甲酸酐的反应器的方法 |
Family Cites Families (32)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE2005969A1 (en) | 1970-02-10 | 1971-08-26 | Badische Anilin & Soda Fabrik AG, 6700 Ludwigshafen | Dicarboxylic acids/and acid anhydridespreparation by isothe - process |
| DE2546268C3 (de) | 1975-10-16 | 1983-11-24 | Basf Ag, 6700 Ludwigshafen | Verfahren zur Herstellung von Phthalsäureanhydrid aus o-Xylol oder Naphthalin |
| JPS603307B2 (ja) | 1978-11-29 | 1985-01-26 | 株式会社日本触媒 | 無水フタル酸の製造方法 |
| CA1261860A (en) | 1984-05-21 | 1989-09-26 | Yoshiyuki Nakanishi | Method for the preparation of pyromellitic acid or its anhydride |
| JPS63253080A (ja) | 1987-04-10 | 1988-10-20 | Nippon Steel Chem Co Ltd | 無水フタル酸の製造方法 |
| US5860017A (en) | 1996-06-28 | 1999-01-12 | Intel Corporation | Processor and method for speculatively executing instructions from multiple instruction streams indicated by a branch instruction |
| SE507313C2 (sv) | 1997-02-25 | 1998-05-11 | Neste Oy | Förfarande för framställning av ftalsyraanhydrid |
| DE19823262A1 (de) | 1998-05-26 | 1999-12-02 | Basf Ag | Verfahren zur Herstellung von Phthalsäureanhydrid |
| US7265250B2 (en) | 2003-12-26 | 2007-09-04 | Lg Chem, Ltd. | Method of producing unsaturated aldehyde and/or unsaturated fatty acid |
| DE102005031465A1 (de) * | 2005-07-04 | 2007-01-11 | Basf Ag | Verfahren zum Anfahren von Oxidationskatalysatoren |
| CN101421036A (zh) | 2006-04-12 | 2009-04-29 | 巴斯夫欧洲公司 | 制备羧酸和/或羧酸酐的催化剂体系 |
| CN101448804A (zh) | 2006-04-21 | 2009-06-03 | 巴斯夫欧洲公司 | 在微通道反应器中制备环氧乙烷的方法 |
| EP1852413A1 (de) * | 2006-04-27 | 2007-11-07 | Basf Aktiengesellschaft | Verfahren zur Gasphasenoxidation unter Verwendung einer Moderatorlage |
| EP2021125A1 (de) | 2006-04-28 | 2009-02-11 | Basf Se | Neuer trägerkatalysator für die ammonoxidation |
| US20070270597A1 (en) | 2006-05-18 | 2007-11-22 | Basf Aktiengesellschaft | Process for preparing maleic anhydride in a microchannel reactor |
| US20090163726A1 (en) | 2006-05-19 | 2009-06-25 | Basf Se | Catalyst system for preparing carboxylic acids and/or carboxylic anhydrides |
| SI2027102T1 (sl) | 2006-05-19 | 2010-08-31 | Basf Se | Proizvodnja ftalnega anhidrida s pomoäśjo plinske fazne oksidacije o-ksilola v primarnem in sekundarnem reaktorju |
| EP2024351B1 (de) | 2006-05-19 | 2011-03-09 | Basf Se | Herstellung von phthalsäureanhydrid durch gasphasenoxidation von o-xylol |
| EP2035138A1 (de) | 2006-06-20 | 2009-03-18 | Basf Se | Katalysatorsystem und verfahren zur herstellung von carbonsäuren und/oder carbonsäureanhydriden |
| WO2008022911A1 (de) | 2006-08-23 | 2008-02-28 | Basf Se | KATALYSATOREN AUS VPO-VORSTUFEN MIT DEFINIERTER TEILCHENGRÖßENVERTEILUNG, DEREN HERSTELLUNG UND VERWENDUNG |
| EP2056963A1 (de) | 2006-08-23 | 2009-05-13 | Basf Se | Eingebettete katalysatoren basierend auf vpo-vorstufen und siliciumdioxid, deren herstellung und verwendung |
| JP5300738B2 (ja) | 2006-12-21 | 2013-09-25 | ビーエーエスエフ ソシエタス・ヨーロピア | 前方層を使用して気相酸化するための触媒系及び方法 |
| KR101392580B1 (ko) | 2007-01-19 | 2014-05-21 | 바스프 에스이 | 그의 활성 덩어리가 다원소 산화물인 촉매 성형체의 제조 방법 |
| DE102007010422A1 (de) | 2007-03-01 | 2008-09-04 | Basf Se | Verfahren zur Herstellung eines Katalysators bestehend aus einem Trägerkörper und einer auf der Oberfläche des Trägerkörpers aufgebrachten katalytisch aktiven Masse |
| DE102007028332A1 (de) | 2007-06-15 | 2008-12-18 | Basf Se | Verfahren zum Beschicken eines Reaktors mit einem Katalysatorfestbett, das wenigstens ringförmige Katalysatorformkörper K umfasst |
| DE102007028333A1 (de) | 2007-06-15 | 2008-12-18 | Basf Se | Verfahren zum Einbringen einer wenigstens einer Produktionscharge von ringförmigen Schalenkatalysatoren K entnommenen Teilmenge in ein Reaktionsrohr eines Rohrbündelreaktors |
| DE102007038157A1 (de) | 2007-08-13 | 2009-02-19 | Basf Se | Schüttungs-Tragrost |
| CN102015609A (zh) | 2008-04-07 | 2011-04-13 | 巴斯夫欧洲公司 | 起动含有催化活性银钒氧化物青铜的气相氧化反应器的方法 |
| CN102099346A (zh) | 2008-07-14 | 2011-06-15 | 巴斯夫欧洲公司 | 制备环氧乙烷的方法 |
| DE102008042061A1 (de) | 2008-09-12 | 2010-03-18 | Basf Se | Verfahren zur Herstellung von geometrischen Katalysatorformkörpern |
| DE102008042064A1 (de) | 2008-09-12 | 2010-03-18 | Basf Se | Verfahren zur Herstellung von geometrischen Katalysatorformkörpern |
| WO2011061132A1 (de) | 2009-11-20 | 2011-05-26 | Basf Se | Mehrlagenkatalysator zur herstellung von carbonsäuren und/oder carbonsäureanhydriden mit vanadiumantimonat in wenigstens einer katalysatorlage und verfahren zur herstellung von phthalsäureanhydrid mit niedriger hotspottemperatur |
-
2009
- 2009-04-07 TW TW098111525A patent/TWI453190B/zh not_active IP Right Cessation
- 2009-04-07 US US12/936,807 patent/US8492566B2/en not_active Expired - Fee Related
- 2009-04-07 EP EP09731418.1A patent/EP2280921B1/de not_active Not-in-force
- 2009-04-07 CN CN2009801210451A patent/CN102056886B/zh not_active Expired - Fee Related
- 2009-04-07 JP JP2011503424A patent/JP5586581B2/ja not_active Expired - Fee Related
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Also Published As
| Publication number | Publication date |
|---|---|
| KR20110014580A (ko) | 2011-02-11 |
| EP2280921B1 (de) | 2014-07-30 |
| EP2280921A1 (de) | 2011-02-09 |
| US8492566B2 (en) | 2013-07-23 |
| KR101581063B1 (ko) | 2015-12-30 |
| CN102056886A (zh) | 2011-05-11 |
| JP2011519825A (ja) | 2011-07-14 |
| TW200948773A (en) | 2009-12-01 |
| TWI453190B (zh) | 2014-09-21 |
| US20110034707A1 (en) | 2011-02-10 |
| CN102056886B (zh) | 2013-10-09 |
| WO2009124946A1 (de) | 2009-10-15 |
| BRPI0910946A2 (pt) | 2016-01-05 |
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