JP5513495B2 - 農薬製剤 - Google Patents
農薬製剤 Download PDFInfo
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- JP5513495B2 JP5513495B2 JP2011513917A JP2011513917A JP5513495B2 JP 5513495 B2 JP5513495 B2 JP 5513495B2 JP 2011513917 A JP2011513917 A JP 2011513917A JP 2011513917 A JP2011513917 A JP 2011513917A JP 5513495 B2 JP5513495 B2 JP 5513495B2
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- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 description 1
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- USSIUIGPBLPCDF-KEBDBYFISA-N pyriminobac-methyl Chemical group CO\N=C(/C)C1=CC=CC(OC=2N=C(OC)C=C(OC)N=2)=C1C(=O)OC USSIUIGPBLPCDF-KEBDBYFISA-N 0.000 description 1
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- 229910052708 sodium Inorganic materials 0.000 description 1
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- RYYKJJJTJZKILX-UHFFFAOYSA-M sodium octadecanoate Chemical compound [Na+].CCCCCCCCCCCCCCCCCC([O-])=O RYYKJJJTJZKILX-UHFFFAOYSA-M 0.000 description 1
- KZOJQMWTKJDSQJ-UHFFFAOYSA-M sodium;2,3-dibutylnaphthalene-1-sulfonate Chemical compound [Na+].C1=CC=C2C(S([O-])(=O)=O)=C(CCCC)C(CCCC)=CC2=C1 KZOJQMWTKJDSQJ-UHFFFAOYSA-M 0.000 description 1
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- 125000000472 sulfonyl group Chemical group *S(*)(=O)=O 0.000 description 1
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- JXHJNEJVUNHLKO-UHFFFAOYSA-N sulprofos Chemical compound CCCSP(=S)(OCC)OC1=CC=C(SC)C=C1 JXHJNEJVUNHLKO-UHFFFAOYSA-N 0.000 description 1
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- IYMLUHWAJFXAQP-UHFFFAOYSA-N topramezone Chemical compound CC1=C(C(=O)C2=C(N(C)N=C2)O)C=CC(S(C)(=O)=O)=C1C1=NOCC1 IYMLUHWAJFXAQP-UHFFFAOYSA-N 0.000 description 1
- 229910001428 transition metal ion Inorganic materials 0.000 description 1
- REEQLXCGVXDJSQ-UHFFFAOYSA-N trichlopyr Chemical compound OC(=O)COC1=NC(Cl)=C(Cl)C=C1Cl REEQLXCGVXDJSQ-UHFFFAOYSA-N 0.000 description 1
- DQJCHOQLCLEDLL-UHFFFAOYSA-N tricyclazole Chemical compound CC1=CC=CC2=C1N1C=NN=C1S2 DQJCHOQLCLEDLL-UHFFFAOYSA-N 0.000 description 1
- 125000002889 tridecyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- HSMVPDGQOIQYSR-KGENOOAVSA-N triflumizole Chemical compound C1=CN=CN1C(/COCCC)=N/C1=CC=C(Cl)C=C1C(F)(F)F HSMVPDGQOIQYSR-KGENOOAVSA-N 0.000 description 1
- 125000002023 trifluoromethyl group Chemical group FC(F)(F)* 0.000 description 1
- RVKCCVTVZORVGD-UHFFFAOYSA-N trinexapac-ethyl Chemical group O=C1CC(C(=O)OCC)CC(=O)C1=C(O)C1CC1 RVKCCVTVZORVGD-UHFFFAOYSA-N 0.000 description 1
- JARYYMUOCXVXNK-IMTORBKUSA-N validamycin Chemical compound N([C@H]1C[C@@H]([C@H]([C@H](O)[C@H]1O)O[C@H]1[C@@H]([C@@H](O)[C@H](O)[C@@H](CO)O1)O)CO)[C@H]1C=C(CO)[C@H](O)[C@H](O)[C@H]1O JARYYMUOCXVXNK-IMTORBKUSA-N 0.000 description 1
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Classifications
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
- A01N25/08—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests containing solids as carriers or diluents
Description
(a)2〜7のpKaを有する農薬;
(b)水溶性アルミニウム塩;及び
(c)ケイ酸塩鉱物
を含む改良された固体農薬製剤が提供される。
R1は、所望によりC1−6アルキルで置換されている、C1−4アルキル又はC3−6シクロアルキルであり;
R2は、独立して、ハロゲン、ニトロ、シアノ、アミノ、C1−4アルキル、C1−4ハロアルキル、C1−6アルコキシ、C1−6アルコキシ−C1−6アルキル、C1−6アルコキシ−C2−6アルコキシ、C1−6アルコキシ−C2−6−アルコキシ−C1−6アルキル、C1−4ハロアルコキシ、C1−4ハロアルコキシ−C1−4アルキル、−(CR4R5)cS(O)bR6、−S(O)bR6、−OSO2R6及び−N(R7)SO2R6からなる群から選択され;
R3は、C1−4アルキルであり;
R4及びR5は、独立して、水素又はC1−4アルキルであり;
R6は、C1−4アルキルであり;
R7は、水素又はC1−6アルキルであり;
aは、1、2又は3であり;
bは、0、1又は2であり;そして
cは、1又は2である(cが2である場合には、基(CR4R5)は、同一であるか、又は異なっていてよい。)。}の化合物である。
の2−ベンゾイル−1,3−シクロヘキサンジオンである。
66質量部の粘土(NK300、昭和化学(Showa Chemical)社の製品、充填剤)、25質量部のNa−ベントナイト(Kunigel V−I、クニミネ工業(Kunimine Kogyo)社の製品、ケイ酸塩鉱物)、2質量部のデキストリン(デキストリンND−S、ニチデン化学(Nichiden Kagaku)社の製品、バインダー材料)、3質量部のアニオン性界面活性剤(SORPOL5060、東邦化学(Toho Chemical)社の製品)及び1.33質量部のメソトリオン(純度ca.75%、シンジェンタ・クロップ・プロテクション(Syngenta Crop Protection)社の製品、HPPD阻害剤)を、ミキサーを用いて混合し、均一な混合物を得て、それに10質量部のca.30%硫酸アルミニウム水溶液(東振化学(Toshin Kagaku)社の製品)を加え、次に混合して、均一な混合物を得る。次に、水を加え、そして混合物をさらなる混合に供する。加えられた水の量は、加えられた水を含む混合物の全質量を基準として15質量%である。
カラム:4.6mmの直径及び250mmの長さを有する、stain−Jess鋼製チューブ
充填材料:ヌクレオシル(Nucleosil)CIB(粒径5um)
カラム温度:45℃
移動相:0.2%リン酸水溶液/アセトニトリル=50/50
流速:1.0ml/分
検出波長:254nm
射出体積:10ul
放出されたメソトリオン(%)
63質量部の粘土(NK300、昭和化学社の製品、充填剤)、25質量部のNa−ベントナイト(Kunigel V−I、クニミネ工業社の製品、ケイ酸塩鉱物)、2質量部のデキストリン(デキストリンND−S、ニチデン化学社の製品、バインダー材料)、3質量部のアニオン性界面活性剤(SORPOL5060、東邦化学社の製品)及び1.33質量部のメソトリオン(純度ca.75%、シンジェンタ・クロップ・プロテクション社の製品、HPPD阻害剤)を、ミキサーを用いてよく混合し、均一な粉末を得て、それに20質量部のca.30%硫酸アルミニウム水溶液(東振化学社の製品)を加え、次に混合して、均一な混合物を得る。次に、水を加え、そして混合物をさらなる混合に供する。加えられた水の量は、加えられた水を含む混合物の全質量を基準として10質量%である。
61質量部の粘土(NK300、昭和化学社の製品、充填剤)、25質量部のNa−ベントナイト(Kunigel V−I、クニミネ工業社の製品、ケイ酸塩鉱物)、2質量部のデキストリン(デキストリンND−S、ニチデン化学社の製品、バインダー材料)、3質量部のアニオン性界面活性剤(SORPOL5060、東邦化学社の製品)、2質量部のクエン酸(純度ca.99%、メルク(Merck)社の製品)及び1.33質量部のメソトリオン(純度ca.75%、シンジェンタ・クロップ・プロテクション社の製品、HPPD阻害剤)を、ミキサーを用いてよく混合し、均一な粉末を得て、それに20質量部のca.30%塩基性塩化アルミニウム水溶液(東振化学社の製品)を加え、次に混合して、均一な混合物を得る。次に、水を加え、そして混合物をさらなる混合に供する。加えられた水の量は、加えられた水を含む混合物の全質量を基準として15質量%である。
65.5質量部の粘土(NK300、昭和化学社の製品、充填剤)、25質量部のモンモリロナイト(Kunipia F、クニミネ工業社の製品、ケイ酸塩鉱物)、5質量部のデンプン(Amicol C、日殿化学(Nippon Starch Chemical)社の製品、バインダー材料)、0.5質量部のアニオン性界面活性剤(Newkalgen EP70G、竹本油脂(Takemoto Oil & Fat)社の製品)及び1.33質量部のメソトリオン(純度ca.75%、シンジェンタ・クロップ・プロテクション社の製品、HPPD阻害剤)を、ミキサーを用いてよく混合し、均一な粉末を得て、それに10質量部のca.30%ポリアルミニウム塩化物水溶液(東振化学社の製品)を加え、次に混合して、均一な混合物を得る。次に、水を加え、そして混合物をさらなる混合に供する。加えられた水の量は、加えられた水を含む混合物の全質量を基準として10質量%である。
本発明の効果及び利点を確認するために、カチオン性物質とケイ酸塩鉱物の組み合わせの存在しないときのHPPD阻害剤の放出挙動が、次の比較例によって示されるであろう:
93.5質量部の粘土(NK300、昭和化学社の製品、充填剤)、2質量部のデキストリン(デキストリンND−S、ニチデン化学社の製品、バインダー材料)、0.5質量部のアニオン性界面活性剤(Newkalgen EP70G、竹本油脂社の製品)及び1.33質量部のメソトリオン(純度ca.75%、シンジェンタ・クロップ・プロテクション社の製品、HPPD阻害剤)を、ミキサーを用いてよく混合し、均一な粉末を得て、それに10質量部のca.30%硫酸アルミニウム水溶液(東振化学社の製品)を加え、次に混合して、均一な混合物を得る。次に、水を加え、そして混合物をさらなる混合に供する。加えられた水の量は、加えられた水を含む混合物の全質量を基準として15質量%である。
71.5質量部の粘土(NK300、昭和化学社の製品、充填剤)、25質量部のNa−ベントナイト(Kunigel V−I、クニミネ工業社の製品、ケイ酸塩鉱物)、2質量部のデキストリン(デキストリンND−S、ニチデン化学社の製品、バインダー材料)、0.5質量部のアニオン性界面活性剤(Newkalgen EP7OG、竹本油脂社の製品)及び1.33質量部のメソトリオン(純度ca.75%、シンジェンタ・クロップ・プロテクション社の製品、HPPD阻害剤)を、ミキサーを用いてよく混合し、均一な粉末を得て、それに10質量部の水を加え、次に混合して均一な混合物を得る。
59質量部のカオリン粘土(NK300、昭和化学社の製品、充填剤)、25質量部のNa−ベントナイト(Kunigel V−I、クニミネ工業社の製品、ケイ酸塩鉱物)、2質量部のデキストリン(デキストリンND−S、ニチデン化学社の製品、バインダー材料)、3質量部のアニオン性界面活性剤(SORPOL5060、東邦化学社の製品)、10質量部の塩化カルシウム、1.33質量部のメソトリオン(純度ca.75%、シンジェンタ・クロップ・プロテクション社の製品、HPPD阻害剤)及び23質量部の水をミキサーを用いてよく混合し、均一な混合物を得る。次に、そのように調製された混合物を、バスケット型押出機によって、次に乾燥及びふるい分けによって、造粒に供することによって、製剤の全質量を基準として、1質量%の量のメソトリオンを含む粒状製剤を得る。
追加試験を行なって、本発明の制御された製剤を有する他の有効成分の有用性を理解した。試験手順は、既に説明したものと同様であった。下記表は、適用後の所定の時間(日)で、(i)20%ポリアルミニウム塩化物(PAC)を含み、そして(ii)20%硫酸アルミニウム(AS)を含むか、又は(ii)水溶性アルミニウム塩を含まない、製剤から放出された有効成分(%)を示す。表を見ても分かるように、本発明の製剤が使用されるときに、有効成分の放出が遅れる。
Claims (12)
- (a)メソトリオン;
(b)硫酸アルミニウム、塩基性塩化アルミニウム、塩化アルミニウム、硝酸アルミニウム、アルミン酸ナトリウム及びアンモニウムアルミニウム硫酸塩からなる群から選択される、1質量%〜20質量%の水溶性アルミニウム塩;
(c)ケイ酸塩鉱物
を含む固体農薬製剤。 - 水溶性アルミニウム塩が、硫酸アルミニウム又は塩基性塩化アルミニウムである、請求項1に記載の固体除草製剤。
- ケイ酸塩鉱物が、ベントナイト、モンモリロナイト、ゼオライト、セピオライト、パイロフィライト、カオリナイト、タルク及びハイドロタルサイトからなる群から選択される、請求項1又は2に記載の固体除草製剤。
- 追加の殺虫含有物をさらに含む、請求項1〜3のいずれか1項に記載の固体除草製剤。
- 製剤が顆粒である、請求項1〜4のいずれか1項に記載の固体除草剤製剤。
- 制御された量の請求項1に記載の除草製剤を所定の場所に適用する工程を含む、該場所で好ましくない植物を防除する方法。
- 場所が水田である、請求項6に記載の方法。
- 播種の前又は直後のいずれかで、除草製剤を適用する、請求項7に記載の方法。
- 播種前に、除草製剤を適用する、請求項7に記載の方法。
- 播種後であるがコメ作物が出現する前に、除草製剤を適用する、請求項7に記載の方法。
- 0.5gの有効成分(ai)/ヘクタール(ha)〜500gのai/haの割合でHPPD阻害剤を適用する、請求項7に記載の方法。
- 移植の前又は後のいずれかで、除草製剤を適用する、請求項7に記載の方法。
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GB0811079.3 | 2008-06-17 | ||
GB0811079A GB0811079D0 (en) | 2008-06-17 | 2008-06-17 | Herbicide formulation |
PCT/EP2009/004135 WO2010003499A2 (en) | 2008-06-17 | 2009-06-09 | Agrochemical formulation |
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DE1913049C3 (de) * | 1968-03-21 | 1979-10-31 | Minnesota Mining And Manufacturing Co., Saint Paul, Minn. (V.St.A.) | Schädlingsbekämpfungsmittel zur Bekämpfung von Pflanzen in Wasser |
GB1596380A (en) * | 1977-03-28 | 1981-08-26 | Lilly Industries Ltd | Fungicidal combinations |
JPS56152401A (en) * | 1980-04-28 | 1981-11-26 | Asahi Chem Ind Co Ltd | Powdery herbicidal composition and its preparation |
IT8220198A0 (it) * | 1981-03-24 | 1982-03-16 | Rhone Poulenc Agrochimie | Derivati fosforosi e loro composizioni antifunghi a base di applicazione per la protezione dei vegetali. |
IL72364A (en) * | 1983-12-01 | 1989-02-28 | Pennwalt Corp | Controlled release compositions of biologically active materials and their preparation |
JPH0676282B2 (ja) * | 1985-05-29 | 1994-09-28 | クミアイ化学工業株式会社 | 固状農薬組成物 |
JP3061174B2 (ja) * | 1997-01-22 | 2000-07-10 | 多木化学株式会社 | 病害防除資材 |
DE10022989A1 (de) * | 2000-05-11 | 2001-11-22 | Aventis Cropscience Gmbh | Kombinationen von Pflanzenschutzmitteln mit organischen oder anorganischen Trägermaterialien |
CN100477918C (zh) * | 2005-12-08 | 2009-04-15 | 江苏丘陵地区镇江农业科学研究所 | 防治水稻恶苗病的农药及方法 |
CN101278671A (zh) * | 2008-04-09 | 2008-10-08 | 绍兴文理学院 | 延缓除草剂释放的复合凝胶制剂及其制备方法 |
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CN102159069B (zh) | 2015-11-25 |
JP2011524387A (ja) | 2011-09-01 |
WO2010003499A3 (en) | 2011-02-17 |
TW201008489A (en) | 2010-03-01 |
CN102159069A (zh) | 2011-08-17 |
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