JP5485892B2 - 発泡ポリスチレンの製造方法及びその使用 - Google Patents
発泡ポリスチレンの製造方法及びその使用 Download PDFInfo
- Publication number
- JP5485892B2 JP5485892B2 JP2010524302A JP2010524302A JP5485892B2 JP 5485892 B2 JP5485892 B2 JP 5485892B2 JP 2010524302 A JP2010524302 A JP 2010524302A JP 2010524302 A JP2010524302 A JP 2010524302A JP 5485892 B2 JP5485892 B2 JP 5485892B2
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- JP
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- Prior art keywords
- polystyrene
- added
- chain
- radical
- molten
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- 238000004519 manufacturing process Methods 0.000 title claims abstract description 34
- 239000004794 expanded polystyrene Substances 0.000 title claims description 16
- 239000004793 Polystyrene Substances 0.000 claims abstract description 55
- 229920002223 polystyrene Polymers 0.000 claims abstract description 55
- 239000003063 flame retardant Substances 0.000 claims abstract description 46
- -1 nitroxyl radicals Chemical class 0.000 claims abstract description 34
- 150000003254 radicals Chemical class 0.000 claims abstract description 22
- 150000001875 compounds Chemical class 0.000 claims abstract description 12
- 125000003118 aryl group Chemical group 0.000 claims abstract description 8
- 238000000354 decomposition reaction Methods 0.000 claims abstract description 6
- 229920006248 expandable polystyrene Polymers 0.000 claims abstract description 6
- 125000001424 substituent group Chemical group 0.000 claims abstract description 6
- 125000001931 aliphatic group Chemical group 0.000 claims abstract description 4
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims abstract description 4
- 238000010438 heat treatment Methods 0.000 claims abstract description 4
- 125000004433 nitrogen atom Chemical group N* 0.000 claims abstract description 4
- 229910052760 oxygen Inorganic materials 0.000 claims abstract description 4
- 239000001301 oxygen Substances 0.000 claims abstract description 4
- 229920006395 saturated elastomer Polymers 0.000 claims abstract description 4
- 125000000547 substituted alkyl group Chemical group 0.000 claims abstract description 4
- YLFIGGHWWPSIEG-UHFFFAOYSA-N aminoxyl Chemical compound [O]N YLFIGGHWWPSIEG-UHFFFAOYSA-N 0.000 claims abstract description 3
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 3
- 229920006327 polystyrene foam Polymers 0.000 claims abstract 3
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 claims description 40
- 238000000034 method Methods 0.000 claims description 29
- 239000004604 Blowing Agent Substances 0.000 claims description 15
- 239000004088 foaming agent Substances 0.000 claims description 8
- 239000004795 extruded polystyrene foam Substances 0.000 claims description 7
- 238000005469 granulation Methods 0.000 claims description 7
- 230000003179 granulation Effects 0.000 claims description 7
- XMNIXWIUMCBBBL-UHFFFAOYSA-N 2-(2-phenylpropan-2-ylperoxy)propan-2-ylbenzene Chemical compound C=1C=CC=CC=1C(C)(C)OOC(C)(C)C1=CC=CC=C1 XMNIXWIUMCBBBL-UHFFFAOYSA-N 0.000 claims description 6
- 150000002978 peroxides Chemical class 0.000 claims description 6
- 238000002156 mixing Methods 0.000 claims description 5
- 239000002245 particle Substances 0.000 claims description 5
- 230000003068 static effect Effects 0.000 claims description 4
- 239000004215 Carbon black (E152) Substances 0.000 claims description 3
- 125000004122 cyclic group Chemical group 0.000 claims description 3
- 150000008282 halocarbons Chemical class 0.000 claims description 3
- 229910052736 halogen Inorganic materials 0.000 claims description 3
- 150000002367 halogens Chemical class 0.000 claims description 3
- 229930195733 hydrocarbon Natural products 0.000 claims description 3
- 150000002430 hydrocarbons Chemical class 0.000 claims description 3
- 239000000126 substance Substances 0.000 claims description 3
- 239000000654 additive Substances 0.000 claims description 2
- 239000007789 gas Substances 0.000 claims description 2
- 239000011256 inorganic filler Substances 0.000 claims description 2
- 229910003475 inorganic filler Inorganic materials 0.000 claims description 2
- 239000000463 material Substances 0.000 claims description 2
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims description 2
- 239000012766 organic filler Substances 0.000 claims description 2
- 230000005855 radiation Effects 0.000 claims description 2
- 239000013585 weight reducing agent Substances 0.000 claims description 2
- CCNDOQHYOIISTA-UHFFFAOYSA-N 1,2-bis(2-tert-butylperoxypropan-2-yl)benzene Chemical compound CC(C)(C)OOC(C)(C)C1=CC=CC=C1C(C)(C)OOC(C)(C)C CCNDOQHYOIISTA-UHFFFAOYSA-N 0.000 claims 1
- 230000000996 additive effect Effects 0.000 claims 1
- 230000006698 induction Effects 0.000 claims 1
- 239000007788 liquid Substances 0.000 claims 1
- 125000000449 nitro group Chemical group [O-][N+](*)=O 0.000 claims 1
- 150000002894 organic compounds Chemical class 0.000 claims 1
- 238000009827 uniform distribution Methods 0.000 claims 1
- 239000000155 melt Substances 0.000 abstract description 5
- 230000003247 decreasing effect Effects 0.000 abstract 1
- 230000000979 retarding effect Effects 0.000 abstract 1
- 229920000642 polymer Polymers 0.000 description 37
- 230000015556 catabolic process Effects 0.000 description 13
- 238000006731 degradation reaction Methods 0.000 description 13
- 239000002994 raw material Substances 0.000 description 10
- 239000000178 monomer Substances 0.000 description 8
- UZFMOKQJFYMBGY-UHFFFAOYSA-N 4-hydroxy-TEMPO Chemical group CC1(C)CC(O)CC(C)(C)N1[O] UZFMOKQJFYMBGY-UHFFFAOYSA-N 0.000 description 7
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 7
- 238000010557 suspension polymerization reaction Methods 0.000 description 6
- 238000012360 testing method Methods 0.000 description 6
- 238000006116 polymerization reaction Methods 0.000 description 5
- 238000002485 combustion reaction Methods 0.000 description 4
- 238000001125 extrusion Methods 0.000 description 4
- 239000000203 mixture Substances 0.000 description 4
- DEIGXXQKDWULML-UHFFFAOYSA-N 1,2,5,6,9,10-hexabromocyclododecane Chemical compound BrC1CCC(Br)C(Br)CCC(Br)C(Br)CCC1Br DEIGXXQKDWULML-UHFFFAOYSA-N 0.000 description 3
- 239000003963 antioxidant agent Substances 0.000 description 3
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 3
- OFBQJSOFQDEBGM-UHFFFAOYSA-N n-pentane Natural products CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 description 3
- 238000010526 radical polymerization reaction Methods 0.000 description 3
- 238000004904 shortening Methods 0.000 description 3
- 239000003381 stabilizer Substances 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
- HGTUJZTUQFXBIH-UHFFFAOYSA-N (2,3-dimethyl-3-phenylbutan-2-yl)benzene Chemical group C=1C=CC=CC=1C(C)(C)C(C)(C)C1=CC=CC=C1 HGTUJZTUQFXBIH-UHFFFAOYSA-N 0.000 description 2
- MYRTYDVEIRVNKP-UHFFFAOYSA-N 1,2-Divinylbenzene Chemical compound C=CC1=CC=CC=C1C=C MYRTYDVEIRVNKP-UHFFFAOYSA-N 0.000 description 2
- BSYJHYLAMMJNRC-UHFFFAOYSA-N 2,4,4-trimethylpentan-2-ol Chemical compound CC(C)(C)CC(C)(C)O BSYJHYLAMMJNRC-UHFFFAOYSA-N 0.000 description 2
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
- 229940123457 Free radical scavenger Drugs 0.000 description 2
- ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 description 2
- 239000012752 auxiliary agent Substances 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 238000001816 cooling Methods 0.000 description 2
- 238000009826 distribution Methods 0.000 description 2
- 229910002804 graphite Inorganic materials 0.000 description 2
- 239000010439 graphite Substances 0.000 description 2
- 239000003112 inhibitor Substances 0.000 description 2
- 238000002844 melting Methods 0.000 description 2
- 230000008018 melting Effects 0.000 description 2
- 150000004706 metal oxides Chemical class 0.000 description 2
- 239000004033 plastic Substances 0.000 description 2
- 239000002516 radical scavenger Substances 0.000 description 2
- 230000006641 stabilisation Effects 0.000 description 2
- 238000011105 stabilization Methods 0.000 description 2
- AUTSLLHNWAZVLE-UHFFFAOYSA-N 1,1,2,2,3-pentabromo-3-chlorocyclohexane Chemical compound ClC1(Br)CCCC(Br)(Br)C1(Br)Br AUTSLLHNWAZVLE-UHFFFAOYSA-N 0.000 description 1
- VUZNLSBZRVZGIK-UHFFFAOYSA-N 2,2,6,6-Tetramethyl-1-piperidinol Chemical group CC1(C)CCCC(C)(C)N1O VUZNLSBZRVZGIK-UHFFFAOYSA-N 0.000 description 1
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 description 1
- 239000004114 Ammonium polyphosphate Substances 0.000 description 1
- WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical compound [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 description 1
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 1
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 1
- 239000012963 UV stabilizer Substances 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 239000002671 adjuvant Substances 0.000 description 1
- 125000005262 alkoxyamine group Chemical group 0.000 description 1
- XYLMUPLGERFSHI-UHFFFAOYSA-N alpha-Methylstyrene Chemical compound CC(=C)C1=CC=CC=C1 XYLMUPLGERFSHI-UHFFFAOYSA-N 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- WNROFYMDJYEPJX-UHFFFAOYSA-K aluminium hydroxide Chemical compound [OH-].[OH-].[OH-].[Al+3] WNROFYMDJYEPJX-UHFFFAOYSA-K 0.000 description 1
- 235000019826 ammonium polyphosphate Nutrition 0.000 description 1
- 229920001276 ammonium polyphosphate Polymers 0.000 description 1
- 230000033228 biological regulation Effects 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 description 1
- 229910052794 bromium Inorganic materials 0.000 description 1
- 239000001273 butane Substances 0.000 description 1
- 239000006229 carbon black Substances 0.000 description 1
- 210000003850 cellular structure Anatomy 0.000 description 1
- 239000002666 chemical blowing agent Substances 0.000 description 1
- 238000003776 cleavage reaction Methods 0.000 description 1
- 229920001577 copolymer Polymers 0.000 description 1
- LSXWFXONGKSEMY-UHFFFAOYSA-N di-tert-butyl peroxide Chemical compound CC(C)(C)OOC(C)(C)C LSXWFXONGKSEMY-UHFFFAOYSA-N 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 239000000975 dye Substances 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 239000006261 foam material Substances 0.000 description 1
- 238000005187 foaming Methods 0.000 description 1
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 230000003993 interaction Effects 0.000 description 1
- VTHJTEIRLNZDEV-UHFFFAOYSA-L magnesium dihydroxide Chemical compound [OH-].[OH-].[Mg+2] VTHJTEIRLNZDEV-UHFFFAOYSA-L 0.000 description 1
- 239000000347 magnesium hydroxide Substances 0.000 description 1
- 229910001862 magnesium hydroxide Inorganic materials 0.000 description 1
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 description 1
- 238000010297 mechanical methods and process Methods 0.000 description 1
- 230000005226 mechanical processes and functions Effects 0.000 description 1
- 229910044991 metal oxide Inorganic materials 0.000 description 1
- GDOPTJXRTPNYNR-UHFFFAOYSA-N methyl-cyclopentane Natural products CC1CCCC1 GDOPTJXRTPNYNR-UHFFFAOYSA-N 0.000 description 1
- IJDNQMDRQITEOD-UHFFFAOYSA-N n-butane Chemical compound CCCC IJDNQMDRQITEOD-UHFFFAOYSA-N 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 229910017464 nitrogen compound Inorganic materials 0.000 description 1
- 150000002830 nitrogen compounds Chemical class 0.000 description 1
- 229910052755 nonmetal Inorganic materials 0.000 description 1
- 150000002896 organic halogen compounds Chemical class 0.000 description 1
- 150000002903 organophosphorus compounds Chemical class 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 235000019353 potassium silicate Nutrition 0.000 description 1
- 239000001294 propane Substances 0.000 description 1
- 238000005086 pumping Methods 0.000 description 1
- 239000007870 radical polymerization initiator Substances 0.000 description 1
- 239000003507 refrigerant Substances 0.000 description 1
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
- CIHOLLKRGTVIJN-UHFFFAOYSA-N tert‐butyl hydroperoxide Chemical compound CC(C)(C)OO CIHOLLKRGTVIJN-UHFFFAOYSA-N 0.000 description 1
- 238000006276 transfer reaction Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
- C08J9/0014—Use of organic additives
- C08J9/0028—Use of organic additives containing nitrogen
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29B—PREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
- B29B9/00—Making granules
- B29B9/12—Making granules characterised by structure or composition
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/14—Peroxides
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/16—Nitrogen-containing compounds
- C08K5/34—Heterocyclic compounds having nitrogen in the ring
- C08K5/3412—Heterocyclic compounds having nitrogen in the ring having one nitrogen atom in the ring
- C08K5/3432—Six-membered rings
- C08K5/3435—Piperidines
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29B—PREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
- B29B9/00—Making granules
- B29B9/02—Making granules by dividing preformed material
- B29B9/06—Making granules by dividing preformed material in the form of filamentary material, e.g. combined with extrusion
- B29B9/065—Making granules by dividing preformed material in the form of filamentary material, e.g. combined with extrusion under-water, e.g. underwater pelletizers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2201/00—Foams characterised by the foaming process
- C08J2201/02—Foams characterised by the foaming process characterised by mechanical pre- or post-treatments
- C08J2201/03—Extrusion of the foamable blend
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2325/00—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Derivatives of such polymers
- C08J2325/02—Homopolymers or copolymers of hydrocarbons
- C08J2325/04—Homopolymers or copolymers of styrene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/02—Halogenated hydrocarbons
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Manufacture Of Porous Articles, And Recovery And Treatment Of Waste Products (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Processes Of Treating Macromolecular Substances (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Polymerisation Methods In General (AREA)
- Polyurethanes Or Polyureas (AREA)
- Graft Or Block Polymers (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| AT0144707A AT505735A1 (de) | 2007-09-14 | 2007-09-14 | Verfahren zur herstellung von expandierbaren styroloplymerisaten |
| ATA1447/2007 | 2007-09-14 | ||
| PCT/AT2008/000326 WO2009033200A1 (de) | 2007-09-14 | 2008-09-12 | Verfahren zur herstellung von expandierbaren styrolpolymerisaten und deren verwendung |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| JP2010539255A JP2010539255A (ja) | 2010-12-16 |
| JP2010539255A5 JP2010539255A5 (OSRAM) | 2013-12-26 |
| JP5485892B2 true JP5485892B2 (ja) | 2014-05-07 |
Family
ID=40427597
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2010524302A Active JP5485892B2 (ja) | 2007-09-14 | 2008-09-12 | 発泡ポリスチレンの製造方法及びその使用 |
Country Status (13)
| Country | Link |
|---|---|
| US (1) | US20100261802A1 (OSRAM) |
| EP (1) | EP2188329B1 (OSRAM) |
| JP (1) | JP5485892B2 (OSRAM) |
| AT (2) | AT505735A1 (OSRAM) |
| CA (1) | CA2697310C (OSRAM) |
| DE (1) | DE502008002636D1 (OSRAM) |
| DK (1) | DK2188329T3 (OSRAM) |
| ES (1) | ES2371016T3 (OSRAM) |
| HR (1) | HRP20110351T1 (OSRAM) |
| PL (1) | PL2188329T3 (OSRAM) |
| PT (1) | PT2188329E (OSRAM) |
| SI (1) | SI2188329T1 (OSRAM) |
| WO (1) | WO2009033200A1 (OSRAM) |
Families Citing this family (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| AT510311B1 (de) | 2010-08-27 | 2013-02-15 | Sunpor Kunststoff Gmbh | Flammgeschützte, wärmedämmende polymerisate und verfahren zu deren herstellung |
| US8668981B2 (en) | 2010-11-11 | 2014-03-11 | Spirit Aerosystems, Inc. | High temperature shape memory polymer via reactive extrusion |
| US10934409B2 (en) * | 2017-08-18 | 2021-03-02 | Owens Coming Intellectual Capital, LLC | Infrared attenuation agent blends |
| CN111811991A (zh) * | 2020-07-16 | 2020-10-23 | 西安航天化学动力有限公司 | 非接触式测试复合固体推进剂密度的近红外光谱分析方法 |
Family Cites Families (19)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2628951A (en) * | 1951-03-28 | 1953-02-17 | Monsanto Chemicals | Light stable polymers stabilized with amine oxides |
| US3058928A (en) * | 1958-07-24 | 1962-10-16 | Dow Chemical Co | Foamed self-extinguishing alkenyl aromatic resin compositions containing an organic bromide and peroxide; and method of preparation |
| US4136142A (en) | 1977-03-23 | 1979-01-23 | Polysar Limited | Process for extruding stabilized expanded polystyrene composition |
| KR930000892B1 (ko) | 1983-07-11 | 1993-02-11 | 커몬웰스 사이언티픽 앤드 인더스트리얼 리셔치 오가니제이숀 | 신규의 개시제를 사용하여 중합체 또는 공중합체를 제조하는방법 |
| SU1558888A1 (ru) | 1987-12-11 | 1990-04-23 | Всесоюзный Научно-Исследовательский Институт Химических Реактивов И Особочистых Химических Веществ | Способ ингибировани полимеризации стирола |
| JPH01165534A (ja) | 1987-12-22 | 1989-06-29 | Mitsubishi Petrochem Co Ltd | スチレン類の重合防止剤 |
| DE3843536A1 (de) | 1988-12-23 | 1990-06-28 | Basf Ag | Verfahren zur herstellung expandierbarer styrolpolymerisate |
| ES2157245T3 (es) | 1994-02-21 | 2001-08-16 | Sulzer Chemtech Ag | Procedimiento para la preparacion de granulados plasticos expandibles. |
| JP3296153B2 (ja) * | 1995-09-06 | 2002-06-24 | 住友化学工業株式会社 | スチレン系重合体の製造方法、スチレン系樹脂組成物及びその成形品 |
| DE19633996B4 (de) | 1996-08-23 | 2005-10-27 | Krämer, Ulrich, Dr.med. | Gerät zur Demonstration der Eigenschaften und Übertragungsqualitäten unterschiedlicher Hörgeräte |
| DE19640886A1 (de) * | 1996-10-04 | 1998-04-09 | Basf Ag | Halogenfreie Flammschutzmittel enthaltende expandierbare Styrolpolymerisate |
| AU2897997A (en) * | 1997-05-14 | 1998-12-08 | Basf Aktiengesellschaft | Expandable styrene polymers containing graphite particles |
| DE19939031A1 (de) | 1999-08-18 | 2001-02-22 | Basf Ag | N-Oxyl-Radikale |
| FR2824840B1 (fr) * | 2001-05-17 | 2005-05-13 | Atofina | Stabilisateur thermique de peroxydes organiques |
| US7323502B2 (en) * | 2002-03-12 | 2008-01-29 | Ciba Specialty Chemicals Corporation | Flame retardant compositions |
| US20030225191A1 (en) * | 2002-04-12 | 2003-12-04 | Francois Gugumus | Stabilizer mixtures |
| DE102004034516A1 (de) | 2004-07-15 | 2006-02-16 | Basf Ag | Verfahren zur Herstellung von flammgeschütztem, expandierbarem Polystyrol |
| JP2006062274A (ja) * | 2004-08-30 | 2006-03-09 | Kaneka Corp | スチレン系樹脂押出発泡体の製造方法 |
| JP4914000B2 (ja) * | 2004-11-12 | 2012-04-11 | 株式会社ジェイエスピー | ポリスチレン系樹脂押出発泡板 |
-
2007
- 2007-09-14 AT AT0144707A patent/AT505735A1/de not_active Application Discontinuation
-
2008
- 2008-09-12 DE DE502008002636T patent/DE502008002636D1/de active Active
- 2008-09-12 DK DK08782853.9T patent/DK2188329T3/da active
- 2008-09-12 EP EP08782853A patent/EP2188329B1/de active Active
- 2008-09-12 SI SI200830214T patent/SI2188329T1/sl unknown
- 2008-09-12 AT AT08782853T patent/ATE498651T1/de active
- 2008-09-12 PL PL08782853T patent/PL2188329T3/pl unknown
- 2008-09-12 JP JP2010524302A patent/JP5485892B2/ja active Active
- 2008-09-12 US US12/676,593 patent/US20100261802A1/en not_active Abandoned
- 2008-09-12 ES ES08782853T patent/ES2371016T3/es active Active
- 2008-09-12 WO PCT/AT2008/000326 patent/WO2009033200A1/de not_active Ceased
- 2008-09-12 CA CA2697310A patent/CA2697310C/en active Active
- 2008-09-12 PT PT08782853T patent/PT2188329E/pt unknown
- 2008-09-12 HR HR20110351T patent/HRP20110351T1/hr unknown
Also Published As
| Publication number | Publication date |
|---|---|
| HRP20110351T1 (hr) | 2011-06-30 |
| SI2188329T1 (sl) | 2011-05-31 |
| DK2188329T3 (da) | 2011-05-30 |
| CA2697310A1 (en) | 2009-03-19 |
| CA2697310C (en) | 2016-02-16 |
| ES2371016T3 (es) | 2011-12-26 |
| WO2009033200A1 (de) | 2009-03-19 |
| ATE498651T1 (de) | 2011-03-15 |
| EP2188329B1 (de) | 2011-02-16 |
| EP2188329A1 (de) | 2010-05-26 |
| PL2188329T3 (pl) | 2011-07-29 |
| JP2010539255A (ja) | 2010-12-16 |
| US20100261802A1 (en) | 2010-10-14 |
| AT505735A1 (de) | 2009-03-15 |
| DE502008002636D1 (de) | 2011-03-31 |
| PT2188329E (pt) | 2011-04-20 |
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