JP5393009B2 - ニトリルゴムをメタセシス分解する方法 - Google Patents

ニトリルゴムをメタセシス分解する方法 Download PDF

Info

Publication number
JP5393009B2
JP5393009B2 JP2007222823A JP2007222823A JP5393009B2 JP 5393009 B2 JP5393009 B2 JP 5393009B2 JP 2007222823 A JP2007222823 A JP 2007222823A JP 2007222823 A JP2007222823 A JP 2007222823A JP 5393009 B2 JP5393009 B2 JP 5393009B2
Authority
JP
Japan
Prior art keywords
group
phosphane
alkyl
aryl
catalyst
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
JP2007222823A
Other languages
English (en)
Japanese (ja)
Other versions
JP2008056926A5 (enExample
JP2008056926A (ja
Inventor
ヴェルナー・オブレヒト
ユリア・マリア・ミューラー
オスカル・ヌイケン
モニカ・ケルナー
Original Assignee
ランクセス・ドイチュランド・ゲーエムベーハー
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by ランクセス・ドイチュランド・ゲーエムベーハー filed Critical ランクセス・ドイチュランド・ゲーエムベーハー
Publication of JP2008056926A publication Critical patent/JP2008056926A/ja
Publication of JP2008056926A5 publication Critical patent/JP2008056926A5/ja
Application granted granted Critical
Publication of JP5393009B2 publication Critical patent/JP5393009B2/ja
Expired - Fee Related legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08C—TREATMENT OR CHEMICAL MODIFICATION OF RUBBERS
    • C08C2/00—Treatment of rubber solutions
    • C08C2/02—Purification
    • C08C2/04—Removal of catalyst residues
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08C—TREATMENT OR CHEMICAL MODIFICATION OF RUBBERS
    • C08C19/00—Chemical modification of rubber
    • C08C19/02—Hydrogenation
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08C—TREATMENT OR CHEMICAL MODIFICATION OF RUBBERS
    • C08C19/00—Chemical modification of rubber
    • C08C19/08—Depolymerisation
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08C—TREATMENT OR CHEMICAL MODIFICATION OF RUBBERS
    • C08C19/00—Chemical modification of rubber
    • C08C19/24—Incorporating phosphorus atoms into the molecule
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F8/00—Chemical modification by after-treatment
    • C08F8/04—Reduction, e.g. hydrogenation
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F8/00—Chemical modification by after-treatment
    • C08F8/50—Partial depolymerisation
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08C—TREATMENT OR CHEMICAL MODIFICATION OF RUBBERS
    • C08C19/00—Chemical modification of rubber

Landscapes

  • Chemical & Material Sciences (AREA)
  • General Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Separation, Recovery Or Treatment Of Waste Materials Containing Plastics (AREA)
  • Manufacture Of Porous Articles, And Recovery And Treatment Of Waste Products (AREA)
JP2007222823A 2006-08-30 2007-08-29 ニトリルゴムをメタセシス分解する方法 Expired - Fee Related JP5393009B2 (ja)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE102006040569.2 2006-08-30
DE102006040569A DE102006040569A1 (de) 2006-08-30 2006-08-30 Verfahren zum Metathese-Abbau von Nitrilkautschuken

Publications (3)

Publication Number Publication Date
JP2008056926A JP2008056926A (ja) 2008-03-13
JP2008056926A5 JP2008056926A5 (enExample) 2010-07-29
JP5393009B2 true JP5393009B2 (ja) 2014-01-22

Family

ID=38776303

Family Applications (1)

Application Number Title Priority Date Filing Date
JP2007222823A Expired - Fee Related JP5393009B2 (ja) 2006-08-30 2007-08-29 ニトリルゴムをメタセシス分解する方法

Country Status (10)

Country Link
US (1) US7662889B2 (enExample)
EP (1) EP1894946B1 (enExample)
JP (1) JP5393009B2 (enExample)
KR (1) KR101392560B1 (enExample)
CN (1) CN101134787B (enExample)
AT (1) ATE538140T1 (enExample)
BR (1) BRPI0703546A2 (enExample)
DE (1) DE102006040569A1 (enExample)
MX (1) MX2007010296A (enExample)
TW (1) TW200838876A (enExample)

Families Citing this family (28)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE102007039525A1 (de) * 2007-08-21 2009-02-26 Lanxess Deutschland Gmbh Verfahren zum Metathese-Abbau von Nitrilkautschuk
EP2147721A1 (de) * 2008-07-08 2010-01-27 Lanxess Deutschland GmbH Katalysator-Systeme und deren Verwendung für Metathese-Reaktionen
EP2143489A1 (de) * 2008-07-08 2010-01-13 Lanxess Deutschland GmbH Katalysator-Systeme und deren Verwendung für Metathese-Reaktionen
EP2289621A1 (en) * 2009-08-31 2011-03-02 LANXESS Deutschland GmbH Process for the preparation of low molecular weight hydrogenated nitrile rubber
EP2289622A1 (en) * 2009-08-31 2011-03-02 LANXESS Deutschland GmbH Ruthenium based catalysts for the metathesis of nitrile rubbers
EP2289623A1 (en) * 2009-08-31 2011-03-02 LANXESS Deutschland GmbH Metathesis of nitrile rubbers in the presence of transition metal catalysts
KR101405744B1 (ko) * 2009-08-31 2014-06-10 란세스 도이치란트 게엠베하 저분자량의 임의로 수소화된 니트릴 고무를 포함하는 가황성 중합체 조성물
BR112012020146A2 (pt) * 2010-02-12 2020-08-18 Exxonmobil Chemical Patents Inc catalisador de metátese e processos para uso do mesmo.
CA2806424A1 (en) * 2010-07-28 2012-02-02 Lanxess Deutschland Gmbh Hydrogenation of diene-based polymers
EP2418225A1 (de) 2010-08-09 2012-02-15 LANXESS Deutschland GmbH Teilhydrierte Nitrilkautschuke
EP2471852A1 (de) 2010-12-29 2012-07-04 Lanxess Deutschland GmbH Vulkanisierbare Zusammensetzungen auf Basis Epoxygruppen-haltiger Nitrilkautschuke
EP2471851A1 (de) 2010-12-29 2012-07-04 LANXESS Deutschland GmbH Vulkanisierbare Zusammensetzungen auf Basis Epoxygruppen-haltiger Nitrilkautschuke
EP2484700B1 (de) 2011-02-04 2013-10-09 LANXESS Deutschland GmbH Funktionalisierte Nitrilkautschuke und ihre Herstellung
CN102145304B (zh) * 2011-02-24 2012-08-08 华东师范大学 一种负载型格拉布斯催化剂的制备及其应用
EP2581409A1 (de) 2011-10-11 2013-04-17 Lanxess Deutschland GmbH Vulkanisierbare Zusammensetzungen auf Basis Epoxygruppen-haltiger Nitrilkautschuke
WO2013056463A1 (en) * 2011-10-21 2013-04-25 Lanxess Deutschland Gmbh Catalyst compositions and their use for hydrogenation of nitrile rubber
WO2013056461A1 (en) * 2011-10-21 2013-04-25 Lanxess Deutschland Gmbh Catalyst compositions and their use for hydrogenation of nitrile rubber
WO2013056400A1 (en) * 2011-10-21 2013-04-25 Lanxess Deutschland Gmbh Catalyst compositions and their use for hydrogenation of nitrile rubber
CN103890012B (zh) * 2011-10-21 2016-12-14 朗盛德国有限责任公司 催化剂组合物及它们的用于氢化丁腈橡胶的用途
WO2013056459A1 (en) 2011-10-21 2013-04-25 Lanxess Deutschland Gmbh Catalyst compositions and their use for hydrogenation of nitrile rubber
PL400162A1 (pl) * 2012-07-27 2014-02-03 Apeiron Synthesis Spólka Z Ograniczona Odpowiedzialnoscia Nowe kompleksy rutenu, ich zastosowanie w reakcjach metatezy oraz sposób prowadzenia reakcji metatezy
CN105102486B (zh) 2013-03-22 2018-12-28 日本瑞翁株式会社 含腈基共聚物橡胶、交联性橡胶组合物、以及橡胶交联物
FR3012458B1 (fr) * 2013-10-25 2015-10-30 Michelin & Cie Composition de caoutchouc comprenant un additif compose 1,3-dipolaire portant une fonction imidazole
TWI566835B (zh) 2014-12-25 2017-01-21 財團法人工業技術研究院 烯烴複分解觸媒及低分子量丁腈橡膠之製備方法
WO2019110658A1 (de) 2017-12-08 2019-06-13 Arlanxeo Deutschland Gmbh Verfahren zur herstellung von nitrilkautschuken mit ruthenium-komplexkatalysatoren
EP3784390A1 (en) * 2018-04-27 2021-03-03 ARLANXEO Deutschland GmbH Use of ruthenium and osmium catalysts for the metathesis of nitrile rubber
CN111606955B (zh) * 2020-07-06 2023-05-02 长春三友智造科技发展有限公司 一种金属有机膦配合物及其制备方法、应用
CN119144069A (zh) * 2023-06-15 2024-12-17 中国石油化工股份有限公司 氢化丁腈橡胶及其组合物、硫化橡胶

Family Cites Families (31)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3700637A (en) 1970-05-08 1972-10-24 Shell Oil Co Diene-nitrile rubbers
JPS5816121B2 (ja) 1974-09-03 1983-03-29 住友金属工業株式会社 レイキヤクバコノ ソンモウソクテイホウホウ
DE2539132C2 (de) 1975-09-03 1987-04-09 Bayer Ag, 5090 Leverkusen Verwendung hydrierter Dien-Copolymere als temperaturbeständige Materialien auf dem Dichtungssektor
JPS5233000A (en) * 1975-09-10 1977-03-12 Hitachi Chem Co Ltd Process for preparing thermoplastic resins
CA1220300A (en) 1982-12-08 1987-04-07 Polysar Limited Polymer hydrogenation process
CA1203047A (en) 1982-12-08 1986-04-08 Hormoz Azizian Polymer hydrogenation process
DE3329974A1 (de) 1983-08-19 1985-02-28 Bayer Ag, 5090 Leverkusen Herstellung von hydrierten nitrilkautschuken
DE3433392A1 (de) 1984-09-12 1986-03-20 Bayer Ag, 5090 Leverkusen Hydrierung nitrilgruppenhaltiger ungesaettigter polymerer
DE3540918A1 (de) 1985-11-19 1987-05-21 Bayer Ag Verfahren zur selektiven hydrierung ungesaettigter verbindungen
DE3541689A1 (de) 1985-11-26 1987-05-27 Bayer Ag Verfahren zur selektiven hydrierung nitrilgruppenhaltiger ungesaettigter polymerer
US4812528A (en) 1987-07-06 1989-03-14 University Of Waterloo Polymer hydrogenation process
DE3932019C1 (enExample) 1989-09-26 1991-05-08 Bayer Ag, 5090 Leverkusen, De
DE4025781A1 (de) 1990-08-15 1992-02-20 Bayer Ag Hydrierte butadien/isopren/(meth-)acrylnitril- copolymerisate
AU691645B2 (en) 1992-04-03 1998-05-21 California Institute Of Technology High activity ruthenium or osmium metal carbene complexes for olefin metathesis reactions and synthesis thereof
US5831108A (en) 1995-08-03 1998-11-03 California Institute Of Technology High metathesis activity ruthenium and osmium metal carbene complexes
US5939504A (en) * 1995-12-07 1999-08-17 Advanced Polymer Technologies Method for extending the pot life of an olefin metathesis polymerization reaction
CA2372746C (en) 1999-05-24 2012-10-02 California Institute Of Technology Imidazolidine-based metal carbene metathesis catalysts
EP1313559B2 (en) 2000-08-10 2012-10-24 Trustees of Boston College Recyclable metathesis catalysts
CA2329844A1 (en) 2000-12-28 2002-06-28 Bayer Inc. Esbo enhanced hydrogenation
RU2289568C2 (ru) * 2001-03-26 2006-12-20 Дау Глобал Текнолоджиз Инк. Способ метатезиса сложных эфиров ненасыщенных жирных кислот или ненасыщенных жирных кислот с низшими олефинами и композиция гетерогенного катализатора, предназначенная для способа метатезиса
CA2350280A1 (en) 2001-06-12 2002-12-12 Bayer Inc. Low molecular weight hydrogenated nitrile rubber
TW593386B (en) 2001-06-12 2004-06-21 Bayer Inc Process for the preparation of low molecular weight hydrogenated nitrile rubber
US6841623B2 (en) 2001-06-29 2005-01-11 Bayer Inc. Low molecular weight nitrile rubber
PL199412B1 (pl) 2002-10-15 2008-09-30 Boehringer Ingelheim Int Nowe kompleksy rutenu jako (pre)katalizatory reakcji metatezy, pochodne 2-alkoksy-5-nitrostyrenu jako związki pośrednie i sposób ich wytwarzania
CA2409434A1 (en) * 2002-10-17 2004-04-17 Bayer Inc. Polymer blends comprising low molecular weight nitrile rubber
CA2409429A1 (en) * 2002-10-17 2004-04-17 Bayer Inc. Hydrogenated nitrile rubber composites with improved proccesability
JP4328080B2 (ja) * 2002-10-30 2009-09-09 三菱化学株式会社 固体担持有機リン化合物、遷移金属錯体、及び触媒反応方法
CA2413607A1 (en) 2002-12-05 2004-06-05 Bayer Inc. Process for the preparation of low molecular weight hydrogenated nitrile rubber
CA2462005A1 (en) * 2004-02-23 2005-08-23 Bayer Inc. Process for the preparation of low molecular weight hydrogenated nitrile rubber
ATE538139T1 (de) * 2005-08-30 2012-01-15 Lanxess Deutschland Gmbh Verwendung von katalysatoren für den metatheseabbau von nitrilkautschuk
DE102006008521A1 (de) * 2006-02-22 2007-08-23 Lanxess Deutschland Gmbh Verwendung von Katalysatoren mit erhöhter Aktivität für die NBR-Metathese

Also Published As

Publication number Publication date
CN101134787B (zh) 2011-08-24
TW200838876A (en) 2008-10-01
MX2007010296A (es) 2008-10-28
EP1894946B1 (de) 2011-12-21
BRPI0703546A2 (pt) 2009-11-17
KR20080020531A (ko) 2008-03-05
DE102006040569A1 (de) 2008-03-06
US20080076881A1 (en) 2008-03-27
CN101134787A (zh) 2008-03-05
EP1894946A2 (de) 2008-03-05
ATE538140T1 (de) 2012-01-15
EP1894946A3 (de) 2009-11-18
KR101392560B1 (ko) 2014-05-21
JP2008056926A (ja) 2008-03-13
US7662889B2 (en) 2010-02-16

Similar Documents

Publication Publication Date Title
JP5393009B2 (ja) ニトリルゴムをメタセシス分解する方法
JP5618454B2 (ja) 新規な触媒系およびメタセシス反応のためのその使用
JP5618455B2 (ja) ニトリルゴムのメタセシスのための増大された活性を有する触媒の使用
JP5235561B2 (ja) 触媒系およびメタセシス反応のためのその使用
TWI490040B (zh) 製備低分子量氫化腈橡膠之方法
CN101372517B (zh) 用于丁腈橡胶复分解降解的方法
CN102481559B (zh) 用于制备氢化腈橡胶的方法
JP5492997B2 (ja) ニトリルゴムのメタセシス用のルテニウムベース触媒
JP2010058108A (ja) 触媒系およびメタセシス反応のためのその使用
JP2009046681A (ja) 遷移金属錯体触媒存在下におけるニトリルゴムのメタセシス
MXPA06009520A (es) Procedimiento para la preparacion de caucho nitrilo de bajo peso molecular.
KR20140084229A (ko) 촉매 조성물 및 니트릴 고무의 수소화를 위한 그의 용도

Legal Events

Date Code Title Description
A521 Request for written amendment filed

Free format text: JAPANESE INTERMEDIATE CODE: A523

Effective date: 20100615

A621 Written request for application examination

Free format text: JAPANESE INTERMEDIATE CODE: A621

Effective date: 20100615

A977 Report on retrieval

Free format text: JAPANESE INTERMEDIATE CODE: A971007

Effective date: 20121207

A131 Notification of reasons for refusal

Free format text: JAPANESE INTERMEDIATE CODE: A131

Effective date: 20121211

A521 Request for written amendment filed

Free format text: JAPANESE INTERMEDIATE CODE: A523

Effective date: 20130311

A131 Notification of reasons for refusal

Free format text: JAPANESE INTERMEDIATE CODE: A131

Effective date: 20130402

A601 Written request for extension of time

Free format text: JAPANESE INTERMEDIATE CODE: A601

Effective date: 20130702

A602 Written permission of extension of time

Free format text: JAPANESE INTERMEDIATE CODE: A602

Effective date: 20130705

A601 Written request for extension of time

Free format text: JAPANESE INTERMEDIATE CODE: A601

Effective date: 20130730

A602 Written permission of extension of time

Free format text: JAPANESE INTERMEDIATE CODE: A602

Effective date: 20130802

A521 Request for written amendment filed

Free format text: JAPANESE INTERMEDIATE CODE: A523

Effective date: 20130829

TRDD Decision of grant or rejection written
A01 Written decision to grant a patent or to grant a registration (utility model)

Free format text: JAPANESE INTERMEDIATE CODE: A01

Effective date: 20130917

A61 First payment of annual fees (during grant procedure)

Free format text: JAPANESE INTERMEDIATE CODE: A61

Effective date: 20131015

R150 Certificate of patent or registration of utility model

Free format text: JAPANESE INTERMEDIATE CODE: R150

LAPS Cancellation because of no payment of annual fees