CN101134787B - 用于丁腈橡胶复分解降解的方法 - Google Patents

用于丁腈橡胶复分解降解的方法 Download PDF

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Publication number
CN101134787B
CN101134787B CN2007101425668A CN200710142566A CN101134787B CN 101134787 B CN101134787 B CN 101134787B CN 2007101425668 A CN2007101425668 A CN 2007101425668A CN 200710142566 A CN200710142566 A CN 200710142566A CN 101134787 B CN101134787 B CN 101134787B
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general formula
catalyst
group
alkyl
aryl
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Expired - Fee Related
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Chinese (zh)
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CN101134787A (zh
Inventor
维尔纳·奥布雷赫特
尤利娅·玛丽亚·米勒
奥斯卡·努肯
莫妮卡·克尔纳
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Lanxess Deutschland GmbH
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Lanxess Deutschland GmbH
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08C—TREATMENT OR CHEMICAL MODIFICATION OF RUBBERS
    • C08C2/00—Treatment of rubber solutions
    • C08C2/02—Purification
    • C08C2/04—Removal of catalyst residues
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08C—TREATMENT OR CHEMICAL MODIFICATION OF RUBBERS
    • C08C19/00—Chemical modification of rubber
    • C08C19/02—Hydrogenation
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08C—TREATMENT OR CHEMICAL MODIFICATION OF RUBBERS
    • C08C19/00—Chemical modification of rubber
    • C08C19/08—Depolymerisation
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08C—TREATMENT OR CHEMICAL MODIFICATION OF RUBBERS
    • C08C19/00—Chemical modification of rubber
    • C08C19/24—Incorporating phosphorus atoms into the molecule
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F8/00—Chemical modification by after-treatment
    • C08F8/04—Reduction, e.g. hydrogenation
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F8/00—Chemical modification by after-treatment
    • C08F8/50—Partial depolymerisation
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08C—TREATMENT OR CHEMICAL MODIFICATION OF RUBBERS
    • C08C19/00—Chemical modification of rubber

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  • Chemical & Material Sciences (AREA)
  • General Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Separation, Recovery Or Treatment Of Waste Materials Containing Plastics (AREA)
  • Manufacture Of Porous Articles, And Recovery And Treatment Of Waste Products (AREA)
CN2007101425668A 2006-08-30 2007-08-29 用于丁腈橡胶复分解降解的方法 Expired - Fee Related CN101134787B (zh)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE102006040569.2 2006-08-30
DE102006040569A DE102006040569A1 (de) 2006-08-30 2006-08-30 Verfahren zum Metathese-Abbau von Nitrilkautschuken

Publications (2)

Publication Number Publication Date
CN101134787A CN101134787A (zh) 2008-03-05
CN101134787B true CN101134787B (zh) 2011-08-24

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CN2007101425668A Expired - Fee Related CN101134787B (zh) 2006-08-30 2007-08-29 用于丁腈橡胶复分解降解的方法

Country Status (10)

Country Link
US (1) US7662889B2 (enExample)
EP (1) EP1894946B1 (enExample)
JP (1) JP5393009B2 (enExample)
KR (1) KR101392560B1 (enExample)
CN (1) CN101134787B (enExample)
AT (1) ATE538140T1 (enExample)
BR (1) BRPI0703546A2 (enExample)
DE (1) DE102006040569A1 (enExample)
MX (1) MX2007010296A (enExample)
TW (1) TW200838876A (enExample)

Families Citing this family (28)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE102007039525A1 (de) * 2007-08-21 2009-02-26 Lanxess Deutschland Gmbh Verfahren zum Metathese-Abbau von Nitrilkautschuk
EP2147721A1 (de) * 2008-07-08 2010-01-27 Lanxess Deutschland GmbH Katalysator-Systeme und deren Verwendung für Metathese-Reaktionen
EP2143489A1 (de) * 2008-07-08 2010-01-13 Lanxess Deutschland GmbH Katalysator-Systeme und deren Verwendung für Metathese-Reaktionen
EP2289621A1 (en) * 2009-08-31 2011-03-02 LANXESS Deutschland GmbH Process for the preparation of low molecular weight hydrogenated nitrile rubber
EP2289622A1 (en) * 2009-08-31 2011-03-02 LANXESS Deutschland GmbH Ruthenium based catalysts for the metathesis of nitrile rubbers
EP2289623A1 (en) * 2009-08-31 2011-03-02 LANXESS Deutschland GmbH Metathesis of nitrile rubbers in the presence of transition metal catalysts
KR101405744B1 (ko) * 2009-08-31 2014-06-10 란세스 도이치란트 게엠베하 저분자량의 임의로 수소화된 니트릴 고무를 포함하는 가황성 중합체 조성물
BR112012020146A2 (pt) * 2010-02-12 2020-08-18 Exxonmobil Chemical Patents Inc catalisador de metátese e processos para uso do mesmo.
CA2806424A1 (en) * 2010-07-28 2012-02-02 Lanxess Deutschland Gmbh Hydrogenation of diene-based polymers
EP2418225A1 (de) 2010-08-09 2012-02-15 LANXESS Deutschland GmbH Teilhydrierte Nitrilkautschuke
EP2471852A1 (de) 2010-12-29 2012-07-04 Lanxess Deutschland GmbH Vulkanisierbare Zusammensetzungen auf Basis Epoxygruppen-haltiger Nitrilkautschuke
EP2471851A1 (de) 2010-12-29 2012-07-04 LANXESS Deutschland GmbH Vulkanisierbare Zusammensetzungen auf Basis Epoxygruppen-haltiger Nitrilkautschuke
EP2484700B1 (de) 2011-02-04 2013-10-09 LANXESS Deutschland GmbH Funktionalisierte Nitrilkautschuke und ihre Herstellung
CN102145304B (zh) * 2011-02-24 2012-08-08 华东师范大学 一种负载型格拉布斯催化剂的制备及其应用
EP2581409A1 (de) 2011-10-11 2013-04-17 Lanxess Deutschland GmbH Vulkanisierbare Zusammensetzungen auf Basis Epoxygruppen-haltiger Nitrilkautschuke
WO2013056463A1 (en) * 2011-10-21 2013-04-25 Lanxess Deutschland Gmbh Catalyst compositions and their use for hydrogenation of nitrile rubber
WO2013056461A1 (en) * 2011-10-21 2013-04-25 Lanxess Deutschland Gmbh Catalyst compositions and their use for hydrogenation of nitrile rubber
WO2013056400A1 (en) * 2011-10-21 2013-04-25 Lanxess Deutschland Gmbh Catalyst compositions and their use for hydrogenation of nitrile rubber
CN103890012B (zh) * 2011-10-21 2016-12-14 朗盛德国有限责任公司 催化剂组合物及它们的用于氢化丁腈橡胶的用途
WO2013056459A1 (en) 2011-10-21 2013-04-25 Lanxess Deutschland Gmbh Catalyst compositions and their use for hydrogenation of nitrile rubber
PL400162A1 (pl) * 2012-07-27 2014-02-03 Apeiron Synthesis Spólka Z Ograniczona Odpowiedzialnoscia Nowe kompleksy rutenu, ich zastosowanie w reakcjach metatezy oraz sposób prowadzenia reakcji metatezy
CN105102486B (zh) 2013-03-22 2018-12-28 日本瑞翁株式会社 含腈基共聚物橡胶、交联性橡胶组合物、以及橡胶交联物
FR3012458B1 (fr) * 2013-10-25 2015-10-30 Michelin & Cie Composition de caoutchouc comprenant un additif compose 1,3-dipolaire portant une fonction imidazole
TWI566835B (zh) 2014-12-25 2017-01-21 財團法人工業技術研究院 烯烴複分解觸媒及低分子量丁腈橡膠之製備方法
WO2019110658A1 (de) 2017-12-08 2019-06-13 Arlanxeo Deutschland Gmbh Verfahren zur herstellung von nitrilkautschuken mit ruthenium-komplexkatalysatoren
EP3784390A1 (en) * 2018-04-27 2021-03-03 ARLANXEO Deutschland GmbH Use of ruthenium and osmium catalysts for the metathesis of nitrile rubber
CN111606955B (zh) * 2020-07-06 2023-05-02 长春三友智造科技发展有限公司 一种金属有机膦配合物及其制备方法、应用
CN119144069A (zh) * 2023-06-15 2024-12-17 中国石油化工股份有限公司 氢化丁腈橡胶及其组合物、硫化橡胶

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2005080456A1 (en) * 2004-02-23 2005-09-01 Lanxess Inc. Process for the preparation of low molecular weight hydrogenated nitrile rubber
CN1705710A (zh) * 2002-10-17 2005-12-07 兰科瑟斯有限公司 含低分子量丁腈橡胶的聚合物共混物

Family Cites Families (29)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3700637A (en) 1970-05-08 1972-10-24 Shell Oil Co Diene-nitrile rubbers
JPS5816121B2 (ja) 1974-09-03 1983-03-29 住友金属工業株式会社 レイキヤクバコノ ソンモウソクテイホウホウ
DE2539132C2 (de) 1975-09-03 1987-04-09 Bayer Ag, 5090 Leverkusen Verwendung hydrierter Dien-Copolymere als temperaturbeständige Materialien auf dem Dichtungssektor
JPS5233000A (en) * 1975-09-10 1977-03-12 Hitachi Chem Co Ltd Process for preparing thermoplastic resins
CA1220300A (en) 1982-12-08 1987-04-07 Polysar Limited Polymer hydrogenation process
CA1203047A (en) 1982-12-08 1986-04-08 Hormoz Azizian Polymer hydrogenation process
DE3329974A1 (de) 1983-08-19 1985-02-28 Bayer Ag, 5090 Leverkusen Herstellung von hydrierten nitrilkautschuken
DE3433392A1 (de) 1984-09-12 1986-03-20 Bayer Ag, 5090 Leverkusen Hydrierung nitrilgruppenhaltiger ungesaettigter polymerer
DE3540918A1 (de) 1985-11-19 1987-05-21 Bayer Ag Verfahren zur selektiven hydrierung ungesaettigter verbindungen
DE3541689A1 (de) 1985-11-26 1987-05-27 Bayer Ag Verfahren zur selektiven hydrierung nitrilgruppenhaltiger ungesaettigter polymerer
US4812528A (en) 1987-07-06 1989-03-14 University Of Waterloo Polymer hydrogenation process
DE3932019C1 (enExample) 1989-09-26 1991-05-08 Bayer Ag, 5090 Leverkusen, De
DE4025781A1 (de) 1990-08-15 1992-02-20 Bayer Ag Hydrierte butadien/isopren/(meth-)acrylnitril- copolymerisate
AU691645B2 (en) 1992-04-03 1998-05-21 California Institute Of Technology High activity ruthenium or osmium metal carbene complexes for olefin metathesis reactions and synthesis thereof
US5831108A (en) 1995-08-03 1998-11-03 California Institute Of Technology High metathesis activity ruthenium and osmium metal carbene complexes
US5939504A (en) * 1995-12-07 1999-08-17 Advanced Polymer Technologies Method for extending the pot life of an olefin metathesis polymerization reaction
CA2372746C (en) 1999-05-24 2012-10-02 California Institute Of Technology Imidazolidine-based metal carbene metathesis catalysts
EP1313559B2 (en) 2000-08-10 2012-10-24 Trustees of Boston College Recyclable metathesis catalysts
CA2329844A1 (en) 2000-12-28 2002-06-28 Bayer Inc. Esbo enhanced hydrogenation
RU2289568C2 (ru) * 2001-03-26 2006-12-20 Дау Глобал Текнолоджиз Инк. Способ метатезиса сложных эфиров ненасыщенных жирных кислот или ненасыщенных жирных кислот с низшими олефинами и композиция гетерогенного катализатора, предназначенная для способа метатезиса
CA2350280A1 (en) 2001-06-12 2002-12-12 Bayer Inc. Low molecular weight hydrogenated nitrile rubber
TW593386B (en) 2001-06-12 2004-06-21 Bayer Inc Process for the preparation of low molecular weight hydrogenated nitrile rubber
US6841623B2 (en) 2001-06-29 2005-01-11 Bayer Inc. Low molecular weight nitrile rubber
PL199412B1 (pl) 2002-10-15 2008-09-30 Boehringer Ingelheim Int Nowe kompleksy rutenu jako (pre)katalizatory reakcji metatezy, pochodne 2-alkoksy-5-nitrostyrenu jako związki pośrednie i sposób ich wytwarzania
CA2409429A1 (en) * 2002-10-17 2004-04-17 Bayer Inc. Hydrogenated nitrile rubber composites with improved proccesability
JP4328080B2 (ja) * 2002-10-30 2009-09-09 三菱化学株式会社 固体担持有機リン化合物、遷移金属錯体、及び触媒反応方法
CA2413607A1 (en) 2002-12-05 2004-06-05 Bayer Inc. Process for the preparation of low molecular weight hydrogenated nitrile rubber
ATE538139T1 (de) * 2005-08-30 2012-01-15 Lanxess Deutschland Gmbh Verwendung von katalysatoren für den metatheseabbau von nitrilkautschuk
DE102006008521A1 (de) * 2006-02-22 2007-08-23 Lanxess Deutschland Gmbh Verwendung von Katalysatoren mit erhöhter Aktivität für die NBR-Metathese

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1705710A (zh) * 2002-10-17 2005-12-07 兰科瑟斯有限公司 含低分子量丁腈橡胶的聚合物共混物
WO2005080456A1 (en) * 2004-02-23 2005-09-01 Lanxess Inc. Process for the preparation of low molecular weight hydrogenated nitrile rubber

Also Published As

Publication number Publication date
TW200838876A (en) 2008-10-01
MX2007010296A (es) 2008-10-28
EP1894946B1 (de) 2011-12-21
BRPI0703546A2 (pt) 2009-11-17
KR20080020531A (ko) 2008-03-05
DE102006040569A1 (de) 2008-03-06
JP5393009B2 (ja) 2014-01-22
US20080076881A1 (en) 2008-03-27
CN101134787A (zh) 2008-03-05
EP1894946A2 (de) 2008-03-05
ATE538140T1 (de) 2012-01-15
EP1894946A3 (de) 2009-11-18
KR101392560B1 (ko) 2014-05-21
JP2008056926A (ja) 2008-03-13
US7662889B2 (en) 2010-02-16

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