JP5339672B2 - 漂白洗浄剤組成物 - Google Patents
漂白洗浄剤組成物 Download PDFInfo
- Publication number
- JP5339672B2 JP5339672B2 JP2006183947A JP2006183947A JP5339672B2 JP 5339672 B2 JP5339672 B2 JP 5339672B2 JP 2006183947 A JP2006183947 A JP 2006183947A JP 2006183947 A JP2006183947 A JP 2006183947A JP 5339672 B2 JP5339672 B2 JP 5339672B2
- Authority
- JP
- Japan
- Prior art keywords
- bleaching
- composition
- perborate
- acid
- present
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- 239000000203 mixture Substances 0.000 title claims description 64
- 239000007844 bleaching agent Substances 0.000 title description 18
- 238000004140 cleaning Methods 0.000 title description 7
- 238000004061 bleaching Methods 0.000 claims description 92
- JRKICGRDRMAZLK-UHFFFAOYSA-L peroxydisulfate Chemical compound [O-]S(=O)(=O)OOS([O-])(=O)=O JRKICGRDRMAZLK-UHFFFAOYSA-L 0.000 claims description 30
- 239000001257 hydrogen Substances 0.000 claims description 20
- 229910052739 hydrogen Inorganic materials 0.000 claims description 20
- 239000003599 detergent Substances 0.000 claims description 17
- 239000007787 solid Substances 0.000 claims description 16
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 claims description 15
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 14
- -1 Hydrogen persulfate salts Chemical class 0.000 claims description 13
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical group [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 claims description 12
- 150000007522 mineralic acids Chemical class 0.000 claims description 12
- LNOPIUAQISRISI-UHFFFAOYSA-N n'-hydroxy-2-propan-2-ylsulfonylethanimidamide Chemical compound CC(C)S(=O)(=O)CC(N)=NO LNOPIUAQISRISI-UHFFFAOYSA-N 0.000 claims description 10
- HDMGAZBPFLDBCX-UHFFFAOYSA-M potassium;sulfooxy sulfate Chemical group [K+].OS(=O)(=O)OOS([O-])(=O)=O HDMGAZBPFLDBCX-UHFFFAOYSA-M 0.000 claims description 8
- 229910000029 sodium carbonate Inorganic materials 0.000 claims description 6
- 229960001922 sodium perborate Drugs 0.000 claims description 4
- YKLJGMBLPUQQOI-UHFFFAOYSA-M sodium;oxidooxy(oxo)borane Chemical group [Na+].[O-]OB=O YKLJGMBLPUQQOI-UHFFFAOYSA-M 0.000 claims description 4
- BVKZGUZCCUSVTD-UHFFFAOYSA-N carbonic acid Chemical class OC(O)=O BVKZGUZCCUSVTD-UHFFFAOYSA-N 0.000 claims 1
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- 239000000126 substance Substances 0.000 description 11
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 8
- 244000269722 Thea sinensis Species 0.000 description 8
- 239000000460 chlorine Substances 0.000 description 8
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- ROOXNKNUYICQNP-UHFFFAOYSA-N ammonium persulfate Chemical compound [NH4+].[NH4+].[O-]S(=O)(=O)OOS([O-])(=O)=O ROOXNKNUYICQNP-UHFFFAOYSA-N 0.000 description 2
- 239000001110 calcium chloride Substances 0.000 description 2
- 229910001628 calcium chloride Inorganic materials 0.000 description 2
- 235000011148 calcium chloride Nutrition 0.000 description 2
- CJZGTCYPCWQAJB-UHFFFAOYSA-L calcium stearate Chemical class [Ca+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O CJZGTCYPCWQAJB-UHFFFAOYSA-L 0.000 description 2
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- RYYXDZDBXNUPOG-UHFFFAOYSA-N 4,5,6,7-tetrahydro-1,3-benzothiazole-2,6-diamine;dihydrochloride Chemical compound Cl.Cl.C1C(N)CCC2=C1SC(N)=N2 RYYXDZDBXNUPOG-UHFFFAOYSA-N 0.000 description 1
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- MGFYIUFZLHCRTH-UHFFFAOYSA-N nitrilotriacetic acid Chemical compound OC(=O)CN(CC(O)=O)CC(O)=O MGFYIUFZLHCRTH-UHFFFAOYSA-N 0.000 description 1
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- SUKJFIGYRHOWBL-UHFFFAOYSA-N sodium hypochlorite Chemical compound [Na+].Cl[O-] SUKJFIGYRHOWBL-UHFFFAOYSA-N 0.000 description 1
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- QORWJWZARLRLPR-UHFFFAOYSA-H tricalcium bis(phosphate) Chemical compound [Ca+2].[Ca+2].[Ca+2].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O QORWJWZARLRLPR-UHFFFAOYSA-H 0.000 description 1
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Images
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Description
項1.過硫酸塩及び/又は過硫酸水素塩、炭酸塩及び/又は炭酸水素塩、並びに固体の無機酸を含有し、過ホウ酸塩を任意に含有する漂白洗浄剤組成物。
項2.固体の無機酸がスルファミン酸である項1に記載の組成物。
項3.組成物の形態が錠剤である項1又は2に記載の組成物。
項4.過ホウ酸塩を含有する項1〜3のいずれかに記載の組成物。
項5.過硫酸塩含有重量及び過硫酸水素塩含有重量の合計を1とした時の過ホウ酸塩含有重量が0〜1.5である項1〜3のいずれかに記載の組成物。
項6.過硫酸水素塩が過硫酸水素カリウムである項1〜5のいずれかに記載の組成物。
項7.過ホウ酸塩が過ホウ酸ナトリウムである項1〜6のいずれかに記載の組成物。
項8.炭酸塩が炭酸ナトリウムである項1〜7のいずれかに記載の組成物。
各々粉状の漂白剤(オキソン、ペルボン、ハイライト60S等)、固形の酸(スルファミン酸、クエン酸、リンゴ酸、フマル酸、コハク酸)、炭酸塩(炭酸ナトリウム等)、重量調整剤(硫酸ナトリウム(芒硝)等)、結合剤(ポリエチレングリコール6000P等)、必要に応じてその他の成分を所定量混合し、円筒状の杵臼(図1)に25g投入し、油圧ポンプ(面圧900kg/cm2)で上杵を押し下げて打錠し、錠剤を製造した。錠剤は直径約4cm、高さ約1.5cmで上面中央部が窪んだ形状である(図2)。
2L容ビーカーに水道水2Lを入れ15℃に維持する(底面から水面までの高さ約15cm)。3cm角の大きさの紅茶汚染布(EMPA167、日本資材製)を3枚用意し、各々の色差を色彩色差計(CR-300、MINOLTA社製)で測定する。色差を測定した1枚の紅茶汚染布を糸の端に固定したものを3個用意し、糸の他端をつまんで紅茶汚染布を水中に入れて配置する。布の配置は、布が容器底から約1cm上で、容器壁に近いところ、すなわち被験物質の発生する泡の影響が小さいところに位置し、ビーカーを上から見たときに3枚の紅茶汚染布を結ぶ線が正三角形になるようにした。このビーカーに被験物質1個(錠剤25g又は非成形の粉体混合物25g)を底部中央に位置するよう投入し、30分間放置した後、紅茶汚染布を取り出して水道水ですすぐ。この紅茶汚染布を送風低温乾燥機(50℃)内で30分間乾燥させる。30分後乾燥機から布を取り出し、各布の色差を測定する。得られた色差(CDn)と、試験前の紅茶汚染布の色差(CD0)を下記計算式に適用し各布の漂白率を算出する。
なお、以下の表において示した漂白率は、各布の漂白率を合計し布の枚数で除した値、すなわち、3枚の紅茶汚染布の漂白率の平均値である。以下、漂白率と表したときは前述の漂白率の平均値を示す。そして、「相対漂白度」は、塩素系漂白剤の漂白率を100と設定した時の各被験物質の相対的な漂白率をいう。
前述の漂白率の測定の場合よりも希釈された溶液で測定を行う。すなわち、10L容器に水道水6Lを入れ15℃を維持する(底面から水面までの高さ約12cm)。漂白率の測定の場合と同様にして3枚の紅茶汚染布を水中に配置し、被験物質1個(錠剤25g又は非成形の粉体混合物25g)を投入する。被験物質が完全に溶解した時点を0分とし、所定の時間経過後に布を取り出し漂白率の測定の場合と同様に色差を測定し、漂白率を算出する。
漂白率の測定と並行してpHを測定する。被験物質が完全に溶解した時点のpHをpHメーター(D−52、ホリバ社製)で測定する。なお、酸素系漂白剤の分野では、漂白の対象となる汚れの種類によって漂白効果が最大となるpHは異なるが、一般的にはpHが大きいほど漂白力が高くなることが知られている。
漂白率の測定と並行して被験物質が完全に溶解するまでの時間を5秒刻みで測定する。
試験1
表1に示す組成で錠剤を製造し、漂白率、pH及び溶解時間を測定した。
表2に示す組成で錠剤を製造し、漂白率、pH及び溶解時間を測定した。なお、A3及びB2の溶解濃度は上記の漂白率の測定に準じた溶解濃度(25g/2L)であるが、A11〜A13の溶解濃度は各々25g/4L、25g/1L及び25g/0.67Lである。
表3に示す組成で錠剤を製造し、漂白率、pH及び溶解時間を測定した。なお、B4〜B7における酸の量は、錠剤を溶解した溶液のpHが概ね9.1程度となる量とした。
表4に示す組成で錠剤を製造し、溶解時間及び完全溶解後漂白率を測定した。なお、溶解濃度は25g/6Lである。
表5に示す組成で錠剤を製造した。実際に一般家庭(4人家族)において使用され便器掃除を2ヶ月間されていない水洗便器(C730、TOTO社製)の水たまり部にこれらの錠剤を用い便器の喫水面の汚れ並びに水たまり部底面及び側面の汚れに対する漂白洗浄性を評価した。評価は、錠剤投入後2時間放置し、水を1回流した後の汚れ落ちの程度と汚れ残りの有無を目視で確認し、次いでさらに水を1回流した後の汚れ残りの有無を目視で確認し、同様にしてさらに水を1回流した後の汚れ残りの有無を目視で確認することにより行った。評価基準は次のとおりである。
◎:8割以上の汚れが落ちている
○:5割以上8割未満の汚れが落ちている
△:3割以上5割未満の汚れが落ちている
×:汚れ落ちが3割未満である
<汚れ残りの有無>
◎:1回の水洗で汚れがほとんど落ちた
○:2回の水洗で汚れがほとんど落ちた
△:3回の水洗で汚れがほとんど落ちた
×:3回の水洗では汚れがほとんど落ちることはなかった
実施例と同様に表6に示す組成で錠剤形態の漂白洗浄剤組成物を製造した。
Claims (7)
- 過硫酸水素塩、炭酸塩及び/又は炭酸水素塩、固体の無機酸、並びに過ホウ酸塩を含有し、前記過硫酸水素塩含有重量を1とした時の前記過ホウ酸塩含有重量が0.3〜0.8である漂白洗浄剤組成物。
- 固体の無機酸がスルファミン酸である請求項1に記載の組成物。
- 組成物の形態が錠剤である請求項1又は2に記載の組成物。
- 過硫酸水素塩含有重量を1とした時の過ホウ酸塩含有重量が5.58/18.06〜11.16/15.48である請求項1〜3のいずれかに記載の組成物。
- 過硫酸水素塩が過硫酸水素カリウムである請求項1〜4のいずれかに記載の組成物。
- 過ホウ酸塩が過ホウ酸ナトリウムである請求項1〜5のいずれかに記載の組成物。
- 炭酸塩が炭酸ナトリウムである請求項1〜6のいずれかに記載の組成物。
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