JP5273723B2 - 畜産汚泥の処理方法 - Google Patents
畜産汚泥の処理方法 Download PDFInfo
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- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 8
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- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims description 8
- SXDBWCPKPHAZSM-UHFFFAOYSA-M bromate Inorganic materials [O-]Br(=O)=O SXDBWCPKPHAZSM-UHFFFAOYSA-M 0.000 claims description 7
- SXDBWCPKPHAZSM-UHFFFAOYSA-N bromic acid Chemical compound OBr(=O)=O SXDBWCPKPHAZSM-UHFFFAOYSA-N 0.000 claims description 7
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- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 claims description 6
- 125000003545 alkoxy group Chemical group 0.000 claims description 6
- 125000000217 alkyl group Chemical group 0.000 claims description 6
- 125000001797 benzyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])* 0.000 claims description 6
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- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 4
- 229910001919 chlorite Inorganic materials 0.000 claims description 3
- 229910052619 chlorite group Inorganic materials 0.000 claims description 3
- QBWCMBCROVPCKQ-UHFFFAOYSA-N chlorous acid Chemical compound OCl=O QBWCMBCROVPCKQ-UHFFFAOYSA-N 0.000 claims description 3
- 125000002947 alkylene group Chemical group 0.000 claims description 2
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical group [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 2
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- ZMANZCXQSJIPKH-UHFFFAOYSA-N Triethylamine Chemical compound CCN(CC)CC ZMANZCXQSJIPKH-UHFFFAOYSA-N 0.000 description 3
- 229910021529 ammonia Inorganic materials 0.000 description 3
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- SUKJFIGYRHOWBL-UHFFFAOYSA-N sodium hypochlorite Chemical compound [Na+].Cl[O-] SUKJFIGYRHOWBL-UHFFFAOYSA-N 0.000 description 3
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- ROSDSFDQCJNGOL-UHFFFAOYSA-N Dimethylamine Chemical compound CNC ROSDSFDQCJNGOL-UHFFFAOYSA-N 0.000 description 2
- QUSNBJAOOMFDIB-UHFFFAOYSA-N Ethylamine Chemical compound CCN QUSNBJAOOMFDIB-UHFFFAOYSA-N 0.000 description 2
- BAVYZALUXZFZLV-UHFFFAOYSA-N Methylamine Chemical compound NC BAVYZALUXZFZLV-UHFFFAOYSA-N 0.000 description 2
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- GETQZCLCWQTVFV-UHFFFAOYSA-N trimethylamine Chemical compound CN(C)C GETQZCLCWQTVFV-UHFFFAOYSA-N 0.000 description 2
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- VILCJCGEZXAXTO-UHFFFAOYSA-N 2,2,2-tetramine Chemical compound NCCNCCNCCN VILCJCGEZXAXTO-UHFFFAOYSA-N 0.000 description 1
- HZAXFHJVJLSVMW-UHFFFAOYSA-N 2-Aminoethan-1-ol Chemical compound NCCO HZAXFHJVJLSVMW-UHFFFAOYSA-N 0.000 description 1
- FVPMLCUKLBYBSV-UHFFFAOYSA-M 2-hydroxypropyl-dimethyl-(prop-2-enoyloxymethyl)azanium;chloride Chemical compound [Cl-].CC(O)C[N+](C)(C)COC(=O)C=C FVPMLCUKLBYBSV-UHFFFAOYSA-M 0.000 description 1
- RIAVQNCBHNMYFJ-UHFFFAOYSA-M 2-hydroxypropyl-dimethyl-[phenyl(prop-2-enoyloxy)methyl]azanium;chloride Chemical compound [Cl-].CC(O)C[N+](C)(C)C(OC(=O)C=C)C1=CC=CC=C1 RIAVQNCBHNMYFJ-UHFFFAOYSA-M 0.000 description 1
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- 208000024827 Alzheimer disease Diseases 0.000 description 1
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 1
- RPNUMPOLZDHAAY-UHFFFAOYSA-N Diethylenetriamine Chemical compound NCCNCCN RPNUMPOLZDHAAY-UHFFFAOYSA-N 0.000 description 1
- BRLQWZUYTZBJKN-UHFFFAOYSA-N Epichlorohydrin Chemical compound ClCC1CO1 BRLQWZUYTZBJKN-UHFFFAOYSA-N 0.000 description 1
- PIICEJLVQHRZGT-UHFFFAOYSA-N Ethylenediamine Chemical compound NCCN PIICEJLVQHRZGT-UHFFFAOYSA-N 0.000 description 1
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 1
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- KCXMKQUNVWSEMD-UHFFFAOYSA-N benzyl chloride Chemical compound ClCC1=CC=CC=C1 KCXMKQUNVWSEMD-UHFFFAOYSA-N 0.000 description 1
- 229940073608 benzyl chloride Drugs 0.000 description 1
- ZGCZDEVLEULNLJ-UHFFFAOYSA-M benzyl-dimethyl-(2-prop-2-enoyloxyethyl)azanium;chloride Chemical compound [Cl-].C=CC(=O)OCC[N+](C)(C)CC1=CC=CC=C1 ZGCZDEVLEULNLJ-UHFFFAOYSA-M 0.000 description 1
- QBZPCMKUFMJWAN-UHFFFAOYSA-N benzyl-dimethyl-[3-(prop-2-enoylamino)propyl]azanium;chloride Chemical compound [Cl-].C=CC(=O)NCCC[N+](C)(C)CC1=CC=CC=C1 QBZPCMKUFMJWAN-UHFFFAOYSA-N 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 230000005591 charge neutralization Effects 0.000 description 1
- 239000000460 chlorine Substances 0.000 description 1
- 229910052801 chlorine Inorganic materials 0.000 description 1
- 230000003749 cleanliness Effects 0.000 description 1
- 238000004581 coalescence Methods 0.000 description 1
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- GQOKIYDTHHZSCJ-UHFFFAOYSA-M dimethyl-bis(prop-2-enyl)azanium;chloride Chemical compound [Cl-].C=CC[N+](C)(C)CC=C GQOKIYDTHHZSCJ-UHFFFAOYSA-M 0.000 description 1
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- LSHROXHEILXKHM-UHFFFAOYSA-N n'-[2-[2-[2-(2-aminoethylamino)ethylamino]ethylamino]ethyl]ethane-1,2-diamine Chemical compound NCCNCCNCCNCCNCCN LSHROXHEILXKHM-UHFFFAOYSA-N 0.000 description 1
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Description
酸化剤群;亜塩素酸塩、次亜塩素酸塩、臭素酸塩、亜臭素酸塩、次亜臭素酸塩、過酸化水素。
R1は水素又はメチル基、R2、R3は炭素数1〜3のアルキル基、アルコキシ基あるいはベンジル基、R4は水素、炭素数1〜3のアルキル基、アルコキシル基あるいはベンジル基であり、同種でも異種でも良い。Aは酸素またはNH、Bは炭素数2〜4のアルキレン基またはアルコキシレン基、X1は陰イオンをそれぞれ表わす。
R5は水素又はメチル基、R6、R7は炭素数1〜3のアルキル基、アルコキシル基あるいはベンジル基、X2は陰イオンをそれぞれ表わす。
R8は水素またはCH2COOY2、QはSO3、C6H4SO3、
CONHC(CH3)2CH2SO3、C6H4COOあるいはCOO、R9は水素、メチル基またはCOOY3であり、Y1、Y2は水素または陽イオンをそれぞれ表わす。
式中R10,R11は水素原子またはメチル基を、X3 - は陰イオンを表わす。
組成はモル%、EM;油中水型エマルジョン、PW;粉末、PL;ペースト、分子量;重量平均分子量
実施例1と同様な試験操作により、無機系酸化剤を添加しない処方(比較1−1)、酸化剤と縮合系カチオン水溶性高分子を併用した処方(比較1−2)およびカチオン水溶性高分子単独処方(比較1−3)に関して試験を行った。結果を表2に示す。
無機酸化剤;対汚泥量ppm、薬剤添加量;対汚泥量ppm、濾液量;mL、
ケーキ含水量;質量%
Claims (3)
- 畜産汚泥に対し、下記酸化剤群より選択される一種以上の無機系酸化剤を添加し消臭処理及び改質処理を施した後、無機凝集剤を添加することなく、重縮合系カチオン性水溶性高分子、ビニル重合系カチオン性水溶性及び/またはビニル重合系両性水溶性高分子をこの順に添加し凝集処理し、その後脱水機により脱水する畜産汚泥の処理方法であり、当該ビニル重合系水溶性カチオン性高分子が、下記一般式(1)および/または下記一般式(2)で表される単量体を20〜100モル%共重合して得られるカチオン性水溶性高分子、下記一般式(4)および/または下記一般式(5)で表される構造単位を10〜90モル%有するカチオン性水溶性高分子から選択される一種以上、前記ビニル重合系両性水溶性高分子が、下記一般式(1)および/または下記一般式(2)で表される単量体を20〜100モル%、下記一般式(3)で表される単量体を5〜50モル%共重合して得られる両性水溶性高分子であることを特徴とする畜産汚泥の処理方法。
酸化剤群;亜塩素酸塩、次亜塩素酸塩、臭素酸塩、亜臭素酸塩、次亜臭素酸塩、過酸化水素。
R1は水素又はメチル基、R2、R3は炭素数1〜3のアルキル基、アルコキシ基あるいはベンジル基、R4は水素、炭素数1〜3のアルキル基、アルコキシル基あるいはベンジル基であり、同種でも異種でも良い。Aは酸素またはNH、Bは炭素数2〜4のアルキレン基またはアルコキシレン基、X1は陰イオンをそれぞれ表わす。
R5は水素又はメチル基、R6、R7は炭素数1〜3のアルキル基、アルコキシル基あるいはベンジル基、X2は陰イオンをそれぞれ表わす。
R8は水素またはCH2COOY2、QはSO3、C6H4SO3、
CONHC(CH3)2CH2SO3、C6H4COOあるいはCOO、R9は水素、メチル基またはCOOY3であり、Y1、Y2は水素または陽イオンをそれぞれ表わす。
式中R10,R11は水素原子またはメチル基を、X3 - は陰イオンを表わす。 - 前記ビニル重合系カチオン性水溶性あるいはビニル重合系両性水溶性高分子の重量平均分子量が300万以上、2000万以下であることを特徴とする請求項1に記載の畜産汚泥の処理方法。
- 前記脱水機がフィルタ−プレスあるいはロータリープレスであることを特徴とする請求項1〜2のいずれかに記載の畜産汚泥の処理方法。
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Publication number | Priority date | Publication date | Assignee | Title |
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JP5224370B2 (ja) * | 2008-12-25 | 2013-07-03 | ハイモ株式会社 | 製紙汚泥の処理方法 |
JP5732818B2 (ja) * | 2010-11-05 | 2015-06-10 | 栗田工業株式会社 | 汚泥脱水剤及び汚泥脱水方法 |
US20180155224A1 (en) * | 2015-05-27 | 2018-06-07 | Mitsubishi Chemical Corporation | Method of treating wastewater |
JP6242436B1 (ja) * | 2016-06-07 | 2017-12-06 | 有限会社日向栄進産業 | 養豚糞尿混合排水処理方法及び循環型養豚糞尿混合排水処理システム |
CN106145607A (zh) * | 2016-07-28 | 2016-11-23 | 中国石油化工股份有限公司 | 一种高盐污泥的无害化处理系统 |
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JPS6253799A (ja) * | 1985-09-03 | 1987-03-09 | Kurita Water Ind Ltd | 有機性汚泥の濃縮方法 |
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JPS62234600A (ja) * | 1986-04-03 | 1987-10-14 | Kurita Water Ind Ltd | 有機性汚泥の濃縮方法 |
JPH0773720B2 (ja) * | 1988-05-25 | 1995-08-09 | 東京都 | 有機性汚泥の農縮方法 |
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JPH08229600A (ja) * | 1994-12-09 | 1996-09-10 | Sankyo Kasei Kogyo Kk | 有機性汚泥の脱水方法 |
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JP2005000764A (ja) * | 2003-06-10 | 2005-01-06 | Ebara Engineering Service Co Ltd | 汚泥スラリーの脱水方法及び装置 |
JP4813081B2 (ja) * | 2005-04-14 | 2011-11-09 | ダイヤニトリックス株式会社 | 畜産廃水の処理方法 |
JP4742367B2 (ja) * | 2006-03-17 | 2011-08-10 | ハイモ株式会社 | 排水あるいは汚泥用消臭剤およびその使用方法 |
JP2008080185A (ja) * | 2006-09-26 | 2008-04-10 | Hymo Corp | 汚泥の脱水方法 |
JP5224370B2 (ja) * | 2008-12-25 | 2013-07-03 | ハイモ株式会社 | 製紙汚泥の処理方法 |
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