JP5219641B2 - 水性樹脂組成物、水性塗料組成物及びプラスチック成形品の塗装方法 - Google Patents
水性樹脂組成物、水性塗料組成物及びプラスチック成形品の塗装方法 Download PDFInfo
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- JP5219641B2 JP5219641B2 JP2008157906A JP2008157906A JP5219641B2 JP 5219641 B2 JP5219641 B2 JP 5219641B2 JP 2008157906 A JP2008157906 A JP 2008157906A JP 2008157906 A JP2008157906 A JP 2008157906A JP 5219641 B2 JP5219641 B2 JP 5219641B2
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- 125000002889 tridecyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- JLTRXTDYQLMHGR-UHFFFAOYSA-N trimethylaluminium Chemical compound C[Al](C)C JLTRXTDYQLMHGR-UHFFFAOYSA-N 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
- 239000008096 xylene Substances 0.000 description 1
Description
実施例1
温度計、攪拌装置、還流冷却管を備えた4つ口フラスコを窒素置換させ、その中に「スーパークロンS−851LS」(日本製紙株式会社製、商品名、無水マレイン酸変性塩素化ポリオレフィン)100g、テトラヒドロフラン190gを加え、65℃にて十分に融解させた。次いでその中に1−ブタノール40g、ジメチルエタノールアミン3gを加えて15分間攪拌し、さらに脱イオン水300gを加えて分散させた。次いで65℃で溶剤分を減圧留去することで、酸変性塩素化ポリオレフィンの水性分散体(A−1)を得た。この分散体の固形分濃度は30%で、pHは8.1であった。
実施例1において、重合性単量体混合物の配合組成を表1に記載のとおりに変更する以外は上記実施例1と同様にして、水性樹脂組成物(I−2)〜(I−6)を得た。
温度計、攪拌装置、還流冷却管を備えた4つ口フラスコを窒素置換させ、その中に「スーパークロンS−851LS」(日本製紙株式会社製、商品名、無水マレイン酸変性塩素化ポリオレフィン)100g、シクロヘキサン100gを加え、65℃にて十分に融解させた。次いでその中に「エマノーン1112」(花王ケミカル社製、ポリエチレングリコールモノラウレート)20g、「ニューコール271A」(日本乳化剤社製、アルキルジフェニルエーテルジスルホン酸ナトリウム塩)2gを加えて15分間攪拌し、さらに脱イオン水300gを加えて分散させた。次いで65℃で溶剤分を減圧留去することで、酸変性塩素化ポリオレフィンの水性分散体(A−2)を得た。この分散体の固形分濃度は25%で、pHは8.1であった。
温度計、攪拌装置、還流冷却管を備えた4つ口フラスコを窒素置換させ、その中に「スーパークロンS−851LS」を100g、テトラヒドロフラン190gを加え、65℃にて十分に融解させた。次いでその中にジブチルアミン2.6g、ジメチルエタノールアミン3gを加えて15分間攪拌し、さらに脱イオン水300gを加えて分散させた。次いで65℃で溶媒を減圧留去することで、酸変性塩素化ポリオレフィンの水性分散体(A−3)を得た。この分散体の固形分濃度は30%で、pHは8.2であった。
温度計、攪拌装置、還流冷却管を備えた4つ口フラスコを窒素置換させ、その中に「スーパークロンS−851LS」を100g、テトラヒドロフラン190gを加え、65℃にて十分に融解させた。次いでその中に2−ヒドロキシエチルアクリレート2.3g、ジメチルエタノールアミン3gを加えて15分攪拌し、さらに脱イオン水300gを加えて分散させた。次いで65℃で溶媒を減圧留去することで、酸変性塩素化ポリオレフィンの水性分散体(A−4)を得た。この分散体の固形分濃度は30%で、pHは8.0であった。
実施例9
上記水性樹脂組成物(I−1)を固形分質量で60部、「ユーコートUX310」(三洋化成工業社製、ウレタンディスパージョン)を固形分質量で20部、アクリル樹脂溶液(注1)を固形分質量で20部、「MICRO ACE K−1」(日本タルク社製、微粉タルク)50部、「JR−806」(テイカ社製、チタン白)50部、「MA100」(三菱化学社製、カーボンブラック)2部を、常法に従って配合し、固形分35%となるように脱イオン水で希釈して水性塗料(1)を得た。
実施例9において、配合組成を表2に示す通りとする以外は実施例9と同様に行って各水性塗料(2)〜(17)を得た。
(注1)アクリル樹脂溶液:撹拌機、温度計、還流冷却管を備えた通常のアクリル樹脂反応槽に、エチレングリコールモノブチルエーテル35部を仕込み、加熱撹拌して110℃に保持した。この中に、スチレン10部、メチルメタクリレート40部、n−ブチルメタクリレート25部、2−ヒドロキシエチルメタクリレート10部、メタクリル酸3部、N,N−ジメチルアミノエチルメタクリレート5部(固形分量、脱イオン水10部に溶解して配合)、「NFバイソマーPEM6E」(第一工業製薬(株)製、商品名、ポリエチレングリコールモノメタクリレート、分子量約350)10部、アゾビスイソブチロニトリル4部及びイソブチルアルコール20部からなる混合物を3時間かけて滴下した。滴下終了後、110℃で30分間熟成し、次にエチレングリコールモノブチルエーテル15部及びアゾビスイソブチロニトリル0.5部からなる追加触媒混合液を1時間かけて滴下した。ついで110℃で1時間熟成したのち冷却し、固形分55%のアクリル樹脂溶液を得た。
(注2)「バルカンXC−72」、キャボットスペシャルティケミカルズインク株式会社製、導電性カーボンブラック顔料
実施例21〜26及び比較例7〜9
ポリプロピレン(脱脂処理済)板に、上記の操作により調製した水性塗料を表3に示すように選択し、これを乾燥膜厚で約20μmになるようにスプレー塗装し、80℃で20分間加熱乾燥させて各試験塗装物を作成した。
上記により得られた各試験塗装物を下記性能試験に供した。その結果を表3に示す。
初期付着性:塗膜面に素地に達するようにカッターで切り込み線を入れ、大きさ2mm×2mmのマス目を100個作り、その表面に粘着セロハン(登録商標)テープを貼着し、20℃においてそれを急激に剥離した後のマス目の残存塗膜数を調べた。○は100個(剥離なし)、△は99〜51個、×は50個以下。
実施例27〜32及び比較例10〜11
自動車用バンパーに成形加工したポリプロピレン(脱脂処理済)に、上記の操作により調製した水性塗料をプライマーとして表4に示すように選択し、これを乾燥膜厚で約10μmになるようにスプレー塗装し、80℃で3分間プレヒート後、その上に着色ベースコート塗料として「ソフレックス#420」(関西ペイント社製、溶剤型着色ベースコート塗料)を乾燥膜厚で約15μmとなるように静電塗装し、80℃で3分間プレヒート後、クリヤー塗料として「ソフレックス#450クリヤー」(関西ペイント社製、アクリルウレタン系溶剤型クリヤー塗料)を乾燥膜厚で約30μmとなるように静電塗装して、80℃で30分間加熱乾燥させて各試験塗装物を作成した。
上記により得られた各試験塗装物を下記性能試験に供した。その結果を表4に示す。
初期付着性:塗膜面に素地に達するようにカッターで切り込み線を入れ、大きさ2mm×2mmのマス目を100個作り、その表面に粘着セロハン(登録商標)テープを貼着し、20℃においてそれを急激に剥離した後のマス目の残存塗膜数を調べた。○は100個(剥離なし)、△は99〜51個、×は50個以下。
Claims (7)
- 酸変性ポリオレフィン(a)、エーテル系溶剤と、炭素数3〜5のアルコール又は水酸基含有重合性不飽和単量体と、及びアミン化合物とによって得られる水性樹脂分散体(A)の存在下で、重合性不飽和単量体(B)を用いて乳化重合させることにより得られ、酸変性ポリオレフィン(a)の水性化の際に界面活性剤を使用せず、乳化重合時に反応性乳化剤を用い、乳化重合における酸変性ポリオレフィン(a)と重合性不飽和単量体(B)の使用比が固形分質量比で20/80〜80/20であることを特徴とする水性樹脂組成物。
- 重合性不飽和単量体(B)がカルボニル基含有重合性不飽和単量体を含む請求項1記載の水性樹脂組成物。
- アルコール系溶剤の使用量が、エーテル系溶剤とアルコール系溶剤との合計質量中に5〜30質量%である請求項1記載の水性樹脂組成物。
- 請求項1〜3のいずれか1項記載の水性樹脂組成物を含有する水性塗料組成物。
- さらにヒドラジン誘導体を含有する請求項4記載の水性塗料組成物。
- プラスチック成形品に、請求項4又は5記載の水性塗料組成物を塗装することを特徴とするプラスチック成形品の塗装方法。
- 請求項6記載の塗装方法により得られる塗装物品。
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