JP5091142B2 - 有機遷移金属錯体触媒を分離する方法 - Google Patents
有機遷移金属錯体触媒を分離する方法 Download PDFInfo
- Publication number
- JP5091142B2 JP5091142B2 JP2008532709A JP2008532709A JP5091142B2 JP 5091142 B2 JP5091142 B2 JP 5091142B2 JP 2008532709 A JP2008532709 A JP 2008532709A JP 2008532709 A JP2008532709 A JP 2008532709A JP 5091142 B2 JP5091142 B2 JP 5091142B2
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- Prior art keywords
- membrane
- hydroformylation
- separation step
- pressure
- reaction mixture
- Prior art date
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Classifications
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D61/00—Processes of separation using semi-permeable membranes, e.g. dialysis, osmosis or ultrafiltration; Apparatus, accessories or auxiliary operations specially adapted therefor
- B01D61/02—Reverse osmosis; Hyperfiltration ; Nanofiltration
- B01D61/027—Nanofiltration
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J38/00—Regeneration or reactivation of catalysts, in general
- B01J38/48—Liquid treating or treating in liquid phase, e.g. dissolved or suspended
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/22—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by diffusion
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D61/00—Processes of separation using semi-permeable membranes, e.g. dialysis, osmosis or ultrafiltration; Apparatus, accessories or auxiliary operations specially adapted therefor
- B01D61/02—Reverse osmosis; Hyperfiltration ; Nanofiltration
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
- B01J31/1845—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms the ligands containing phosphorus
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2311/00—Details relating to membrane separation process operations and control
- B01D2311/26—Further operations combined with membrane separation processes
- B01D2311/2653—Degassing
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2313/00—Details relating to membrane modules or apparatus
- B01D2313/14—Specific spacers
- B01D2313/143—Specific spacers on the feed side
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2325/00—Details relating to properties of membranes
- B01D2325/30—Chemical resistance
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2325/00—Details relating to properties of membranes
- B01D2325/38—Hydrophobic membranes
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
- B01J2231/30—Addition reactions at carbon centres, i.e. to either C-C or C-X multiple bonds
- B01J2231/32—Addition reactions to C=C or C-C triple bonds
- B01J2231/321—Hydroformylation, metalformylation, carbonylation or hydroaminomethylation
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/80—Complexes comprising metals of Group VIII as the central metal
- B01J2531/82—Metals of the platinum group
- B01J2531/822—Rhodium
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/582—Recycling of unreacted starting or intermediate materials
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Water Supply & Treatment (AREA)
- Nanotechnology (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- General Chemical & Material Sciences (AREA)
- Analytical Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Catalysts (AREA)
- Separation Using Semi-Permeable Membranes (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE102005046250.2A DE102005046250B4 (de) | 2005-09-27 | 2005-09-27 | Anlage zur Abtrennung von organischen Übergangsmetallkomplexkatalysatoren |
| DE102005046250.2 | 2005-09-27 | ||
| PCT/EP2006/066181 WO2007036424A1 (de) | 2005-09-27 | 2006-09-08 | Verfahren zur abtrennung von organischen übergangsmetallkomplexkatalysatoren |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| JP2009513320A JP2009513320A (ja) | 2009-04-02 |
| JP2009513320A5 JP2009513320A5 (https=) | 2011-09-29 |
| JP5091142B2 true JP5091142B2 (ja) | 2012-12-05 |
Family
ID=37635694
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2008532709A Active JP5091142B2 (ja) | 2005-09-27 | 2006-09-08 | 有機遷移金属錯体触媒を分離する方法 |
Country Status (11)
| Country | Link |
|---|---|
| US (1) | US8226829B2 (https=) |
| EP (1) | EP1931472B1 (https=) |
| JP (1) | JP5091142B2 (https=) |
| KR (1) | KR101337117B1 (https=) |
| CN (1) | CN101272860B (https=) |
| AT (1) | ATE419917T1 (https=) |
| DE (2) | DE102005046250B4 (https=) |
| ES (1) | ES2320698T3 (https=) |
| PL (1) | PL1931472T3 (https=) |
| TW (1) | TWI418396B (https=) |
| WO (1) | WO2007036424A1 (https=) |
Families Citing this family (42)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE102006003618A1 (de) * | 2006-01-26 | 2007-08-02 | Oxeno Olefinchemie Gmbh | Verfahren zur Abtrennung von Metall-Komplexkatalysatoren aus Telomerisationsgemischen |
| DE102007054885A1 (de) * | 2007-11-15 | 2009-05-20 | Evonik Degussa Gmbh | Verfahren zur Fraktionierung oxidischer Nanopartikel durch Querstrom-Membranfiltration |
| DE102008020688B3 (de) * | 2008-04-24 | 2009-11-05 | Evonik Stockhausen Gmbh | Verfahren zur Herstellung und Aufreinigung wässriger Phasen |
| DE102008002188A1 (de) | 2008-06-03 | 2009-12-10 | Evonik Oxeno Gmbh | Verfahren zur Abtrennung von 1-Buten aus C4-haltigen Kohlenwasserstoffströmen durch Hydroformylierung |
| DE102008044946B4 (de) * | 2008-08-29 | 2022-06-15 | Evonik Superabsorber Gmbh | Einsatz von Schaumkörpern in Oxidations-Reaktoren zur Herstellung ungesättigter Carbonsäuren |
| DE102009026819A1 (de) | 2008-09-08 | 2010-03-11 | Evonik Röhm Gmbh | Monomermischung, Polymer, Beschichtungsmittel und Verfahren zur Herstellung einer Beschichtung |
| DE102008043422B3 (de) | 2008-11-03 | 2010-01-07 | Evonik Degussa Gmbh | Verfahren zur Aufreinigung niedermolekularer Hydridosilane |
| DE102008060888A1 (de) | 2008-12-09 | 2010-06-10 | Evonik Stockhausen Gmbh | Verfahren zur Herstellung von Acrolein umfassend die Aufarbeitung einer Rohglycerin-Phase |
| DE102009001225A1 (de) * | 2009-02-27 | 2010-09-02 | Evonik Oxeno Gmbh | Verfahren zur Anreicherung eines Homogenkatalysators aus einem Prozessstrom |
| DE102009001230A1 (de) * | 2009-02-27 | 2010-09-02 | Evonik Oxeno Gmbh | Verfahren zur Abtrennung und teilweiser Rückführung von Übergangsmetallen bzw. deren katalytisch wirksamen Komplexverbindungen aus Prozessströmen |
| DE102009016652A1 (de) * | 2009-04-07 | 2010-10-14 | Oxea Gmbh | Verfahren zur Aufarbeitung eines flüssigen Hydroformylierungsaustrags |
| US20120123079A1 (en) | 2009-07-23 | 2012-05-17 | Evonik Fibres Gmbh | Polyimide membranes made of polymerization solutions |
| DE102009029050A1 (de) | 2009-08-31 | 2011-03-03 | Evonik Oxeno Gmbh | Organophosphorverbindungen basierend auf Tetraphenol(TP)-substituierten Strukturen |
| DE102009047351A1 (de) | 2009-12-01 | 2011-06-09 | Evonik Goldschmidt Gmbh | Komposit-Siliconmembranen mit hoher Trennwirkung |
| EP2363402A1 (de) * | 2010-03-01 | 2011-09-07 | Evonik Oxeno GmbH | Polyhedrale Oligomere Silsesquioxan (POSS)-verbundene Liganden und deren Verwendung |
| DE102011082441A1 (de) | 2011-09-09 | 2013-03-14 | Evonik Oxeno Gmbh | Strahlschlaufenreaktor mit Nanofiltration |
| CA2858351C (en) | 2011-12-20 | 2016-11-22 | Dow Technology Investments Llc | A hydroformylation process |
| WO2013107902A1 (en) * | 2012-01-20 | 2013-07-25 | Dsm Ip Assets B.V. | Process for the separation of a dissolved catalyst system from an alkoxycarbonylation reaction mixture |
| DE102012202779A1 (de) * | 2012-02-23 | 2013-08-29 | Evonik Oxeno Gmbh | Verfahren und Vorrichtung zur technischen Hydroformylierung von Isobuten und zum Auftrennen des Produktgemisches |
| US10214499B2 (en) | 2012-04-20 | 2019-02-26 | Vlaamse Instelling Voor Technologisch Onderzoek (Vito) | Dilute chemical reaction process with membrane separation step |
| EP2906573B1 (de) | 2012-10-12 | 2016-11-23 | Evonik Degussa GmbH | Gemisch von bisphosphiten und dessen verwendung als katalysatorgemisch in der hydroformylierung |
| DE102012223572A1 (de) * | 2012-12-18 | 2014-06-18 | Evonik Industries Ag | Steuerung der Viskosität von Reaktionslösungen in Hydroformylierungverfahren |
| DE102013203117A1 (de) * | 2013-02-26 | 2014-08-28 | Evonik Industries Ag | Optimierte Trenntechnik zur Aufarbeitung von homogen katalysierten Hydroformylierungsmischungen |
| DE102013208759A1 (de) * | 2013-05-13 | 2014-11-13 | Evonik Industries Ag | Abtrennung von Homogenkatalysatoren mittels einer geregelten Membrantrenneinheit |
| DE102013215004A1 (de) * | 2013-07-31 | 2015-02-05 | Evonik Industries Ag | Membrankaskade mit sinkender Trenntemperatur |
| DE102013221708A1 (de) | 2013-10-25 | 2015-04-30 | Evonik Industries Ag | Strahlschlaufenreaktor mit Nanofiltration und Gasseparator |
| DE102014002103B4 (de) | 2014-02-15 | 2020-10-22 | Oxea Gmbh | Verfahren zur Regenerierung gebrauchter Hydroformylierungskatalysatoren |
| US10155200B2 (en) * | 2015-02-18 | 2018-12-18 | Evonik Degussa Gmbh | Separation off of a homogeneous catalyst from a reaction mixture with the help of organophilic nanofiltration |
| EP3222344A1 (de) * | 2016-03-21 | 2017-09-27 | Evonik Degussa GmbH | Kontinuierliches verfahren zur herstellung einer chemischen verbindung |
| CN107473957A (zh) * | 2017-06-08 | 2017-12-15 | 赢创特种化学(上海)有限公司 | 从均相的有机液体组合物中富集铬化合物的方法 |
| US10654784B2 (en) * | 2018-10-05 | 2020-05-19 | Evonik Operations Gmbh | Process for hydroformylating short-chain olefins in the gas phase |
| US11401251B2 (en) | 2019-03-18 | 2022-08-02 | Novomer, Inc. | Membrane separation system, and uses thereof |
| US11440863B2 (en) * | 2019-06-12 | 2022-09-13 | Evonik Operations Gmbh | Process for preparing an alcohol from hydrocarbons |
| US11365171B2 (en) * | 2019-06-12 | 2022-06-21 | Evonik Operations Gmbh | Process for preparing an ester by alkoxycarbonylation |
| EP3945088A1 (de) | 2020-07-30 | 2022-02-02 | Röhm GmbH | Vorgehen zur minimierung des aktivitätsverlusts bei im kreislaufbetrieb ausgeführten reaktionsschritten |
| ES2974422T3 (es) * | 2020-07-30 | 2024-06-27 | Evonik Oxeno Gmbh & Co Kg | Procedimiento para la preparación de aldehídos y separación del sistema catalítico mediante separación por membrana |
| US20250137091A1 (en) * | 2021-11-11 | 2025-05-01 | Dow Technology Investments Llc | Processes for recovering rhodium from hydroformylation processes |
| CN113996340B (zh) * | 2021-11-16 | 2023-12-19 | 万华化学集团股份有限公司 | 一种用于氢甲酰化反应的新型催化剂体系及氢甲酰化反应方法 |
| ES2992645T3 (en) | 2021-11-19 | 2024-12-16 | Evonik Oxeno Gmbh & Co Kg | Process for producing aldehydes and cooling a mass flow |
| ES2992663T3 (en) | 2021-11-19 | 2024-12-16 | Evonik Oxeno Gmbh & Co Kg | Process for producing aldehydes and cooling a mass flow |
| CN114160205A (zh) * | 2021-12-13 | 2022-03-11 | 浙江迪萧科技有限公司 | 一种有机料液中络合物催化剂的浓缩回收方法 |
| EP4223737A1 (de) * | 2022-02-08 | 2023-08-09 | Evonik Operations GmbH | Optimierte thermische trennung durch vorherigen gasaustausch |
Family Cites Families (23)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB1312076A (en) * | 1970-05-15 | 1973-04-04 | Bp Chem Int Ltd | Hydroformylation process |
| ZA78147B (en) * | 1977-01-25 | 1978-11-29 | Union Carbide Corp | Improved hydroformylation process |
| US5215667A (en) * | 1991-08-20 | 1993-06-01 | Exxon Chemical Patents Inc. | Method for separating water soluble noble metal catalyst from a noble metal catalyzed hydroformylation reaction |
| US5395979A (en) * | 1993-02-25 | 1995-03-07 | Exxon Chemical Patents Inc. | Method for separating catalyst from a hydroformylation reaction product using alkylated ligands |
| US5298669A (en) * | 1993-03-23 | 1994-03-29 | Exxon Chemical Patent Inc. | Perstraction sweep stream for a membrane reactor |
| KR970703805A (ko) * | 1995-05-01 | 1997-08-09 | 유니온 카바이드 케미칼즈 앤드 플라스틱스 테크놀러지 코포레이션 | 막 분리방법(Membrane Separation) |
| US5731472A (en) * | 1995-12-06 | 1998-03-24 | Union Carbide Chemicals & Plastics Technology Corporation | Metal-ligand complex catalyzed processes |
| EP0839787A1 (en) * | 1996-11-04 | 1998-05-06 | Dsm N.V. | Process for the preparation of an aldehyde |
| CA2204676A1 (en) * | 1996-05-15 | 1997-11-15 | Helmut Bahrmann | Process for preparing aldehydes |
| DE19801437A1 (de) * | 1998-01-16 | 1999-07-22 | Basf Ag | Verfahren zur Herstellung von Aldehyden |
| US6090987A (en) * | 1998-07-06 | 2000-07-18 | Union Carbide Chemicals & Plastics Technology Corporation | Metal-ligand complex catalyzed processes |
| US6252123B1 (en) * | 1998-07-09 | 2001-06-26 | Union Carbide Chemicals & Plastics Technology Corporation | Membrane separation process for metal complex catalysts |
| EP1103303A1 (en) * | 1999-11-23 | 2001-05-30 | Dsm N.V. | Process to separate a rhodium/phosphite ligand complex and free phosphite ligand complex from a hydroformylation mixture |
| US6610891B1 (en) * | 1999-12-03 | 2003-08-26 | Mitsubishi Chemical Corporation | Method of producing aldehydes |
| AU2001281886A1 (en) * | 2000-06-26 | 2002-01-08 | Basf Aktiengesellschaft | Phosphacyclohexanes and the use thereof in the hydroformylation of olefins |
| DE10048301A1 (de) * | 2000-09-29 | 2002-04-11 | Oxeno Olefinchemie Gmbh | Stabilisierung von Rhodiumkatalysatoren für die Hydroformylierung von Olefinen |
| DE10128144A1 (de) * | 2001-06-09 | 2002-12-12 | Oxeno Olefinchemie Gmbh | Verfahren zur Telomerisation von nicht cyclischen Olefinen |
| JP2003080036A (ja) * | 2001-09-07 | 2003-03-18 | Mitsubishi Heavy Ind Ltd | 純水製造方法 |
| DE10312829A1 (de) * | 2002-06-29 | 2004-01-22 | Oxeno Olefinchemie Gmbh | Verfahren zur Telomerisation von nicht cyclischen Olefinen |
| DE102004013514A1 (de) * | 2004-03-19 | 2005-10-06 | Oxeno Olefinchemie Gmbh | Verfahren zur Hydroformylierung von Olefinen in Anwesenheit von neuen phosphororganischen Verbindungen |
| DE102005036038A1 (de) * | 2004-08-28 | 2006-03-02 | Oxeno Olefinchemie Gmbh | Verfahren zur Telomerisation von nicht cyclischen Olefinen |
| DE102005036039A1 (de) * | 2004-08-28 | 2006-03-02 | Oxeno Olefinchemie Gmbh | Verfahren zur Herstellung von 2,7-Octadienylderivaten |
| US7353316B2 (en) * | 2006-03-24 | 2008-04-01 | Micron Technology, Inc. | System and method for re-routing signals between memory system components |
-
2005
- 2005-09-27 DE DE102005046250.2A patent/DE102005046250B4/de not_active Expired - Fee Related
-
2006
- 2006-09-08 WO PCT/EP2006/066181 patent/WO2007036424A1/de not_active Ceased
- 2006-09-08 US US12/088,041 patent/US8226829B2/en active Active
- 2006-09-08 CN CN2006800358000A patent/CN101272860B/zh active Active
- 2006-09-08 KR KR1020087007298A patent/KR101337117B1/ko active Active
- 2006-09-08 JP JP2008532709A patent/JP5091142B2/ja active Active
- 2006-09-08 PL PL06778422T patent/PL1931472T3/pl unknown
- 2006-09-08 ES ES06778422T patent/ES2320698T3/es active Active
- 2006-09-08 DE DE502006002616T patent/DE502006002616D1/de active Active
- 2006-09-08 AT AT06778422T patent/ATE419917T1/de not_active IP Right Cessation
- 2006-09-08 EP EP06778422A patent/EP1931472B1/de active Active
- 2006-09-21 TW TW095134974A patent/TWI418396B/zh active
Also Published As
| Publication number | Publication date |
|---|---|
| DE102005046250A1 (de) | 2007-03-29 |
| ATE419917T1 (de) | 2009-01-15 |
| PL1931472T3 (pl) | 2009-06-30 |
| JP2009513320A (ja) | 2009-04-02 |
| US8226829B2 (en) | 2012-07-24 |
| DE502006002616D1 (de) | 2009-02-26 |
| KR101337117B1 (ko) | 2013-12-05 |
| TW200719947A (en) | 2007-06-01 |
| EP1931472A1 (de) | 2008-06-18 |
| TWI418396B (zh) | 2013-12-11 |
| US20080251456A1 (en) | 2008-10-16 |
| ES2320698T3 (es) | 2009-05-27 |
| WO2007036424A1 (de) | 2007-04-05 |
| CN101272860A (zh) | 2008-09-24 |
| CN101272860B (zh) | 2010-11-17 |
| KR20080053476A (ko) | 2008-06-13 |
| DE102005046250B4 (de) | 2020-10-08 |
| EP1931472B1 (de) | 2009-01-07 |
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