JP4979243B2 - ポリマー電解質膜とその製造方法および燃料電池 - Google Patents
ポリマー電解質膜とその製造方法および燃料電池 Download PDFInfo
- Publication number
- JP4979243B2 JP4979243B2 JP2006050638A JP2006050638A JP4979243B2 JP 4979243 B2 JP4979243 B2 JP 4979243B2 JP 2006050638 A JP2006050638 A JP 2006050638A JP 2006050638 A JP2006050638 A JP 2006050638A JP 4979243 B2 JP4979243 B2 JP 4979243B2
- Authority
- JP
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- Prior art keywords
- electrolyte membrane
- polymer electrolyte
- group
- producing
- ion conductive
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- 239000012528 membrane Substances 0.000 title claims description 80
- 239000005518 polymer electrolyte Substances 0.000 title claims description 77
- 238000004519 manufacturing process Methods 0.000 title claims description 15
- 239000000446 fuel Substances 0.000 title description 39
- 150000002500 ions Chemical class 0.000 claims description 53
- 238000000576 coating method Methods 0.000 claims description 39
- 239000011159 matrix material Substances 0.000 claims description 39
- 229920000642 polymer Polymers 0.000 claims description 39
- 150000001875 compounds Chemical class 0.000 claims description 37
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical group OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 claims description 36
- 239000011248 coating agent Substances 0.000 claims description 34
- 229920001940 conductive polymer Polymers 0.000 claims description 23
- 125000000524 functional group Chemical group 0.000 claims description 21
- -1 C20 alkylamine Chemical class 0.000 claims description 19
- 239000003431 cross linking reagent Substances 0.000 claims description 17
- 239000000203 mixture Substances 0.000 claims description 17
- 239000000835 fiber Substances 0.000 claims description 15
- 239000000178 monomer Substances 0.000 claims description 13
- 239000004014 plasticizer Substances 0.000 claims description 12
- 230000002378 acidificating effect Effects 0.000 claims description 11
- 239000011148 porous material Substances 0.000 claims description 11
- KGIGUEBEKRSTEW-UHFFFAOYSA-N 2-vinylpyridine Chemical group C=CC1=CC=CC=N1 KGIGUEBEKRSTEW-UHFFFAOYSA-N 0.000 claims description 10
- 239000003792 electrolyte Substances 0.000 claims description 10
- 238000006116 polymerization reaction Methods 0.000 claims description 10
- 239000010419 fine particle Substances 0.000 claims description 9
- 125000000542 sulfonic acid group Chemical group 0.000 claims description 9
- MYRTYDVEIRVNKP-UHFFFAOYSA-N 1,2-Divinylbenzene Chemical compound C=CC1=CC=CC=C1C=C MYRTYDVEIRVNKP-UHFFFAOYSA-N 0.000 claims description 8
- 239000004925 Acrylic resin Substances 0.000 claims description 8
- 229920000178 Acrylic resin Polymers 0.000 claims description 8
- 229920001223 polyethylene glycol Polymers 0.000 claims description 8
- 238000000034 method Methods 0.000 claims description 7
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 claims description 7
- 229920002554 vinyl polymer Polymers 0.000 claims description 7
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims description 6
- DAKWPKUUDNSNPN-UHFFFAOYSA-N Trimethylolpropane triacrylate Chemical compound C=CC(=O)OCC(CC)(COC(=O)C=C)COC(=O)C=C DAKWPKUUDNSNPN-UHFFFAOYSA-N 0.000 claims description 6
- 238000001704 evaporation Methods 0.000 claims description 6
- WHNWPMSKXPGLAX-UHFFFAOYSA-N N-Vinyl-2-pyrrolidone Chemical group C=CN1CCCC1=O WHNWPMSKXPGLAX-UHFFFAOYSA-N 0.000 claims description 5
- 229920002873 Polyethylenimine Chemical group 0.000 claims description 5
- 125000002843 carboxylic acid group Chemical group 0.000 claims description 5
- NLVXSWCKKBEXTG-UHFFFAOYSA-N vinylsulfonic acid Chemical compound OS(=O)(=O)C=C NLVXSWCKKBEXTG-UHFFFAOYSA-N 0.000 claims description 5
- OSSNTDFYBPYIEC-UHFFFAOYSA-N 1-ethenylimidazole Chemical compound C=CN1C=CN=C1 OSSNTDFYBPYIEC-UHFFFAOYSA-N 0.000 claims description 4
- AGBXYHCHUYARJY-UHFFFAOYSA-N 2-phenylethenesulfonic acid Chemical compound OS(=O)(=O)C=CC1=CC=CC=C1 AGBXYHCHUYARJY-UHFFFAOYSA-N 0.000 claims description 4
- NQBKGCYEPYTVBQ-UHFFFAOYSA-N C(C=C)(=O)O.C(C=C)(=O)[O-].[PH4+] Chemical compound C(C=C)(=O)O.C(C=C)(=O)[O-].[PH4+] NQBKGCYEPYTVBQ-UHFFFAOYSA-N 0.000 claims description 4
- CERQOIWHTDAKMF-UHFFFAOYSA-M Methacrylate Chemical compound CC(=C)C([O-])=O CERQOIWHTDAKMF-UHFFFAOYSA-M 0.000 claims description 4
- 150000003973 alkyl amines Chemical class 0.000 claims description 4
- CQEYYJKEWSMYFG-UHFFFAOYSA-N butyl acrylate Chemical compound CCCCOC(=O)C=C CQEYYJKEWSMYFG-UHFFFAOYSA-N 0.000 claims description 4
- JHRWWRDRBPCWTF-OLQVQODUSA-N captafol Chemical group C1C=CC[C@H]2C(=O)N(SC(Cl)(Cl)C(Cl)Cl)C(=O)[C@H]21 JHRWWRDRBPCWTF-OLQVQODUSA-N 0.000 claims description 4
- 239000002322 conducting polymer Substances 0.000 claims description 4
- 238000010894 electron beam technology Methods 0.000 claims description 4
- DOMLXBPXLNDFAB-UHFFFAOYSA-N ethoxyethane;methyl prop-2-enoate Chemical compound CCOCC.COC(=O)C=C DOMLXBPXLNDFAB-UHFFFAOYSA-N 0.000 claims description 4
- LNMQRPPRQDGUDR-UHFFFAOYSA-N hexyl prop-2-enoate Chemical compound CCCCCCOC(=O)C=C LNMQRPPRQDGUDR-UHFFFAOYSA-N 0.000 claims description 4
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims description 4
- 125000005462 imide group Chemical group 0.000 claims description 4
- 229920001427 mPEG Polymers 0.000 claims description 4
- CKRUTZWZFOQMKG-UHFFFAOYSA-N n-(1-cyanocyclohexyl)-n-methylbutanamide Chemical compound CCCC(=O)N(C)C1(C#N)CCCCC1 CKRUTZWZFOQMKG-UHFFFAOYSA-N 0.000 claims description 4
- RIZPLDXMQXJTTJ-UHFFFAOYSA-N phosphane;prop-2-enoic acid Chemical compound [PH4+].[O-]C(=O)C=C RIZPLDXMQXJTTJ-UHFFFAOYSA-N 0.000 claims description 4
- QTECDUFMBMSHKR-UHFFFAOYSA-N prop-2-enyl prop-2-enoate Chemical compound C=CCOC(=O)C=C QTECDUFMBMSHKR-UHFFFAOYSA-N 0.000 claims description 4
- 125000000565 sulfonamide group Chemical group 0.000 claims description 4
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims description 3
- XHJGXOOOMKCJPP-UHFFFAOYSA-N 2-[tert-butyl(2-hydroxyethyl)amino]ethanol Chemical compound OCCN(C(C)(C)C)CCO XHJGXOOOMKCJPP-UHFFFAOYSA-N 0.000 claims description 3
- 238000001771 vacuum deposition Methods 0.000 claims description 3
- 230000001678 irradiating effect Effects 0.000 claims description 2
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 18
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 16
- 229910052739 hydrogen Inorganic materials 0.000 description 7
- 239000001257 hydrogen Substances 0.000 description 7
- 239000002033 PVDF binder Substances 0.000 description 6
- 239000004810 polytetrafluoroethylene Substances 0.000 description 6
- 229920001343 polytetrafluoroethylene Polymers 0.000 description 6
- 229920002981 polyvinylidene fluoride Polymers 0.000 description 6
- 239000007789 gas Substances 0.000 description 5
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 5
- 229910019142 PO4 Inorganic materials 0.000 description 4
- 239000004693 Polybenzimidazole Substances 0.000 description 4
- 239000004698 Polyethylene Substances 0.000 description 4
- 239000004743 Polypropylene Substances 0.000 description 4
- JUJWROOIHBZHMG-UHFFFAOYSA-N Pyridine Chemical compound C1=CC=NC=C1 JUJWROOIHBZHMG-UHFFFAOYSA-N 0.000 description 4
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 4
- 230000014759 maintenance of location Effects 0.000 description 4
- 239000000463 material Substances 0.000 description 4
- 229910052760 oxygen Inorganic materials 0.000 description 4
- 239000001301 oxygen Substances 0.000 description 4
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 4
- 239000010452 phosphate Substances 0.000 description 4
- 229920002480 polybenzimidazole Polymers 0.000 description 4
- 229920000573 polyethylene Polymers 0.000 description 4
- 229920001155 polypropylene Polymers 0.000 description 4
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 3
- 238000004132 cross linking Methods 0.000 description 3
- 230000007423 decrease Effects 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- RAXXELZNTBOGNW-UHFFFAOYSA-N imidazole Natural products C1=CNC=N1 RAXXELZNTBOGNW-UHFFFAOYSA-N 0.000 description 3
- 238000005470 impregnation Methods 0.000 description 3
- 229920000554 ionomer Polymers 0.000 description 3
- 239000007800 oxidant agent Substances 0.000 description 3
- 230000001590 oxidative effect Effects 0.000 description 3
- 229920000557 Nafion® Polymers 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
- 150000001412 amines Chemical class 0.000 description 2
- 125000003277 amino group Chemical group 0.000 description 2
- 239000007864 aqueous solution Substances 0.000 description 2
- 150000007514 bases Chemical class 0.000 description 2
- 239000003054 catalyst Substances 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- 125000004386 diacrylate group Chemical group 0.000 description 2
- 230000008020 evaporation Effects 0.000 description 2
- GPRLSGONYQIRFK-UHFFFAOYSA-N hydron Chemical compound [H+] GPRLSGONYQIRFK-UHFFFAOYSA-N 0.000 description 2
- 239000010416 ion conductor Substances 0.000 description 2
- 238000010248 power generation Methods 0.000 description 2
- 230000001737 promoting effect Effects 0.000 description 2
- UMJSCPRVCHMLSP-UHFFFAOYSA-N pyridine Natural products COC1=CC=CN=C1 UMJSCPRVCHMLSP-UHFFFAOYSA-N 0.000 description 2
- 238000002407 reforming Methods 0.000 description 2
- 150000003335 secondary amines Chemical class 0.000 description 2
- UEBSKCCBDHSYDA-UHFFFAOYSA-N 2-[tert-butyl(methyl)amino]ethyl prop-2-enoate Chemical compound CC(C)(C)N(C)CCOC(=O)C=C UEBSKCCBDHSYDA-UHFFFAOYSA-N 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 description 1
- 239000004593 Epoxy Substances 0.000 description 1
- QYKIQEUNHZKYBP-UHFFFAOYSA-N Vinyl ether Chemical class C=COC=C QYKIQEUNHZKYBP-UHFFFAOYSA-N 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 229910052783 alkali metal Inorganic materials 0.000 description 1
- 150000001340 alkali metals Chemical class 0.000 description 1
- 125000002947 alkylene group Chemical group 0.000 description 1
- 230000000903 blocking effect Effects 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- ZBCBWPMODOFKDW-UHFFFAOYSA-N diethanolamine Chemical compound OCCNCCO ZBCBWPMODOFKDW-UHFFFAOYSA-N 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- UQSQSQZYBQSBJZ-UHFFFAOYSA-N fluorosulfonic acid Chemical compound OS(F)(=O)=O UQSQSQZYBQSBJZ-UHFFFAOYSA-N 0.000 description 1
- 150000002431 hydrogen Chemical class 0.000 description 1
- 230000002209 hydrophobic effect Effects 0.000 description 1
- 150000002466 imines Chemical class 0.000 description 1
- 238000011065 in-situ storage Methods 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 229910052744 lithium Inorganic materials 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 239000004745 nonwoven fabric Substances 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- PNJWIWWMYCMZRO-UHFFFAOYSA-N pent‐4‐en‐2‐one Natural products CC(=O)CC=C PNJWIWWMYCMZRO-UHFFFAOYSA-N 0.000 description 1
- 229920000090 poly(aryl ether) Polymers 0.000 description 1
- 229920005597 polymer membrane Polymers 0.000 description 1
- 230000000379 polymerizing effect Effects 0.000 description 1
- HNJBEVLQSNELDL-UHFFFAOYSA-N pyrrolidin-2-one Chemical compound O=C1CCCN1 HNJBEVLQSNELDL-UHFFFAOYSA-N 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
- 150000003457 sulfones Chemical class 0.000 description 1
- 125000000999 tert-butyl group Chemical group [H]C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 description 1
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/10—Fuel cells with solid electrolytes
- H01M8/1016—Fuel cells with solid electrolytes characterised by the electrolyte material
- H01M8/1018—Polymeric electrolyte materials
- H01M8/1041—Polymer electrolyte composites, mixtures or blends
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C14/00—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material
- C23C14/06—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material characterised by the coating material
- C23C14/12—Organic material
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C14/00—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material
- C23C14/58—After-treatment
- C23C14/5806—Thermal treatment
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C14/00—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material
- C23C14/58—After-treatment
- C23C14/5846—Reactive treatment
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/10—Fuel cells with solid electrolytes
- H01M8/1016—Fuel cells with solid electrolytes characterised by the electrolyte material
- H01M8/1018—Polymeric electrolyte materials
- H01M8/1058—Polymeric electrolyte materials characterised by a porous support having no ion-conducting properties
- H01M8/106—Polymeric electrolyte materials characterised by a porous support having no ion-conducting properties characterised by the chemical composition of the porous support
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/10—Fuel cells with solid electrolytes
- H01M8/1016—Fuel cells with solid electrolytes characterised by the electrolyte material
- H01M8/1018—Polymeric electrolyte materials
- H01M8/1069—Polymeric electrolyte materials characterised by the manufacturing processes
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/10—Fuel cells with solid electrolytes
- H01M2008/1095—Fuel cells with polymeric electrolytes
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/10—Fuel cells with solid electrolytes
- H01M8/1009—Fuel cells with solid electrolytes with one of the reactants being liquid, solid or liquid-charged
- H01M8/1011—Direct alcohol fuel cells [DAFC], e.g. direct methanol fuel cells [DMFC]
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/30—Hydrogen technology
- Y02E60/50—Fuel cells
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P70/00—Climate change mitigation technologies in the production process for final industrial or consumer products
- Y02P70/50—Manufacturing or production processes characterised by the final manufactured product
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Manufacturing & Machinery (AREA)
- Electrochemistry (AREA)
- Organic Chemistry (AREA)
- Sustainable Development (AREA)
- Life Sciences & Earth Sciences (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Sustainable Energy (AREA)
- Composite Materials (AREA)
- Physics & Mathematics (AREA)
- Thermal Sciences (AREA)
- Fuel Cell (AREA)
- Conductive Materials (AREA)
- Manufacture Of Macromolecular Shaped Articles (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| KR10-2005-0126916 | 2005-12-21 | ||
| KR1020050126916A KR100723389B1 (ko) | 2005-12-21 | 2005-12-21 | 폴리머 전해질막 및 이를 채용한 연료전지 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JP2007173196A JP2007173196A (ja) | 2007-07-05 |
| JP4979243B2 true JP4979243B2 (ja) | 2012-07-18 |
Family
ID=38183564
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2006050638A Active JP4979243B2 (ja) | 2005-12-21 | 2006-02-27 | ポリマー電解質膜とその製造方法および燃料電池 |
Country Status (3)
| Country | Link |
|---|---|
| JP (1) | JP4979243B2 (zh) |
| KR (1) | KR100723389B1 (zh) |
| CN (1) | CN1986613B (zh) |
Families Citing this family (18)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP2144319A1 (de) * | 2008-07-09 | 2010-01-13 | Micronas GmbH | Verfahren zum Herstellen einer protonenleitfähigen, strukturierten Elektrolytmembran |
| JP5948243B2 (ja) | 2009-08-26 | 2016-07-06 | エヴォクア ウォーター テクノロジーズ ピーティーイー リミテッド | イオン交換膜 |
| CN103237591B (zh) | 2010-10-15 | 2016-04-13 | 伊沃夸水处理技术有限责任公司 | 制备用于制造阳离子交换膜的单体溶液的方法 |
| CN103237600B (zh) | 2010-10-15 | 2016-07-13 | 伊沃夸水处理技术有限责任公司 | 阴离子交换膜及制造方法 |
| WO2012125138A1 (en) | 2011-03-11 | 2012-09-20 | Utc Power Corporation | Unitized electrode assembly with high equivalent weight ionomer |
| WO2014055123A1 (en) | 2012-10-04 | 2014-04-10 | Evoqua Water Technologies Llc | High-performance anion exchange membranes and methods of making same |
| AU2013330438B2 (en) | 2012-10-11 | 2017-06-01 | Evoqua Water Technologies Llc | Coated ion exchange membranes |
| JP6165878B2 (ja) * | 2012-12-21 | 2017-07-19 | アウディ アクチェンゲゼルシャフトＡｕｄｉ Ａｇ | 電解質膜、分散体、および分散方法 |
| TWI579333B (zh) * | 2015-12-28 | 2017-04-21 | 財團法人工業技術研究院 | 離子交換膜 |
| FR3054078B1 (fr) * | 2016-07-13 | 2018-09-07 | Institut Polytechnique De Grenoble | Materiau a conduction ionique pour generateur electrochimique et procedes de fabrication |
| KR101836410B1 (ko) | 2016-08-30 | 2018-03-09 | 한국화학연구원 | 가소제를 함유한 스티렌계-tert-부틸스티렌계 양이온교환 복합막 및 이의 제조방법 |
| JP6885780B2 (ja) * | 2017-05-10 | 2021-06-16 | トヨタ自動車株式会社 | 固体高分子電解質膜 |
| CN109400786B (zh) * | 2017-08-16 | 2020-12-29 | 东莞东阳光科研发有限公司 | 一种高分子聚合物、其制备方法及包含其的电解液 |
| KR102287767B1 (ko) | 2018-01-18 | 2021-08-10 | 주식회사 엘지에너지솔루션 | 이차 전지용 분리막 및 이를 포함하는 리튬 이차 전지 |
| JP7460530B2 (ja) * | 2018-03-15 | 2024-04-02 | インテグリス・インコーポレーテッド | フッ素化フィルター膜、フィルターおよび方法 |
| KR102400192B1 (ko) * | 2020-06-26 | 2022-05-20 | 광주과학기술원 | 전도성 나노 다공성 멤브레인 및 이의 제조 방법 |
| CN112332029B (zh) * | 2020-11-10 | 2022-08-05 | 江苏厚生新能源科技有限公司 | 一种能够捕捉氢氟酸的锂电池隔膜及其制备方法 |
| CN116870236A (zh) * | 2023-05-16 | 2023-10-13 | 帝斯博（常州）医疗用品股份有限公司 | 一种外科止血胶及其制备方法 |
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| JPH0768377B2 (ja) * | 1987-07-20 | 1995-07-26 | 東燃株式会社 | 電解質薄膜 |
| GB9211993D0 (en) * | 1992-06-05 | 1992-07-22 | British Nuclear Fuels Plc | Fuel cells |
| CN1038562C (zh) * | 1994-06-20 | 1998-06-03 | 中国科学院化学研究所 | 聚丙烯微孔膜为基膜的离子交换膜及其制法 |
| US6258276B1 (en) * | 1996-10-18 | 2001-07-10 | Mcmaster University | Microporous membranes and uses thereof |
| US6248469B1 (en) * | 1997-08-29 | 2001-06-19 | Foster-Miller, Inc. | Composite solid polymer electrolyte membranes |
| JP4621344B2 (ja) * | 2000-09-06 | 2011-01-26 | 日東電工株式会社 | プロトン伝導性膜又はフィルムとそれらを用いてなる燃料電池 |
| AU2002241654A1 (en) | 2000-12-21 | 2002-07-01 | Moltech Corporation | Lithium anodes for electrochemical cells |
| US20020127474A1 (en) * | 2001-01-09 | 2002-09-12 | E.C.R.-Electro-Chemical Research Ltd. | Proton-selective conducting membranes |
| ITMI20010383A1 (it) * | 2001-02-26 | 2002-08-26 | Ausimont Spa | Membrane idrofiliche porose |
| KR100453680B1 (ko) * | 2001-11-10 | 2004-10-20 | 한국과학기술연구원 | 가교된 이온 교환 막 및 그 제조방법 |
| DK1483316T3 (da) | 2002-03-06 | 2007-12-27 | Pemeas Gmbh | Protonledende elektrolytmembran med reduceret methanolpermeabilitet og anvendelse deraf til brændselsceller |
| JP4435560B2 (ja) * | 2002-12-26 | 2010-03-17 | 株式会社トクヤマ | イオン交換膜及びその製造方法 |
| JP2004253336A (ja) * | 2003-02-21 | 2004-09-09 | Toagosei Co Ltd | 電解質膜および当該電解質膜を用いた燃料電池 |
| KR100508639B1 (ko) * | 2003-06-04 | 2005-08-17 | 주식회사 협진아이엔씨 | 비수계 고분자 전해질막 및 이를 이용한 연료전지 |
| CN101656318A (zh) * | 2004-12-03 | 2010-02-24 | 日东电工株式会社 | 电解质膜的制造方法、电解质膜以及使用该电解质膜的固体高分子型燃料电池 |
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