DK1483316T3 - Protonledende elektrolytmembran med reduceret methanolpermeabilitet og anvendelse deraf til brændselsceller - Google Patents

Protonledende elektrolytmembran med reduceret methanolpermeabilitet og anvendelse deraf til brændselsceller

Info

Publication number
DK1483316T3
DK1483316T3 DK03743390T DK03743390T DK1483316T3 DK 1483316 T3 DK1483316 T3 DK 1483316T3 DK 03743390 T DK03743390 T DK 03743390T DK 03743390 T DK03743390 T DK 03743390T DK 1483316 T3 DK1483316 T3 DK 1483316T3
Authority
DK
Denmark
Prior art keywords
electrolyte membrane
fuel cells
proton conductive
conductive electrolyte
methanol permeability
Prior art date
Application number
DK03743390T
Other languages
English (en)
Inventor
Joachim Kiefer
Oemer Uensal
Gordon Calundann
James Crivello
Original Assignee
Pemeas Gmbh
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from DE10209685A external-priority patent/DE10209685A1/de
Priority claimed from DE10210499A external-priority patent/DE10210499A1/de
Application filed by Pemeas Gmbh filed Critical Pemeas Gmbh
Application granted granted Critical
Publication of DK1483316T3 publication Critical patent/DK1483316T3/da

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Classifications

    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00Fuel cells; Manufacture thereof
    • H01M8/10Fuel cells with solid electrolytes
    • H01M8/1016Fuel cells with solid electrolytes characterised by the electrolyte material
    • H01M8/1018Polymeric electrolyte materials
    • H01M8/102Polymeric electrolyte materials characterised by the chemical structure of the main chain of the ion-conducting polymer
    • H01M8/1023Polymeric electrolyte materials characterised by the chemical structure of the main chain of the ion-conducting polymer having only carbon, e.g. polyarylenes, polystyrenes or polybutadiene-styrenes
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D71/00Semi-permeable membranes for separation processes or apparatus characterised by the material; Manufacturing processes specially adapted therefor
    • B01D71/06Organic material
    • B01D71/66Polymers having sulfur in the main chain, with or without nitrogen, oxygen or carbon only
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J5/00Manufacture of articles or shaped materials containing macromolecular substances
    • C08J5/20Manufacture of shaped structures of ion-exchange resins
    • C08J5/22Films, membranes or diaphragms
    • C08J5/2206Films, membranes or diaphragms based on organic and/or inorganic macromolecular compounds
    • C08J5/2218Synthetic macromolecular compounds
    • C08J5/2231Synthetic macromolecular compounds based on macromolecular compounds obtained by reactions involving unsaturated carbon-to-carbon bonds
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J7/00Chemical treatment or coating of shaped articles made of macromolecular substances
    • C08J7/12Chemical modification
    • C08J7/16Chemical modification with polymerisable compounds
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00Fuel cells; Manufacture thereof
    • H01M8/04Auxiliary arrangements, e.g. for control of pressure or for circulation of fluids
    • H01M8/04082Arrangements for control of reactant parameters, e.g. pressure or concentration
    • H01M8/04197Preventing means for fuel crossover
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00Fuel cells; Manufacture thereof
    • H01M8/10Fuel cells with solid electrolytes
    • H01M8/1009Fuel cells with solid electrolytes with one of the reactants being liquid, solid or liquid-charged
    • H01M8/1011Direct alcohol fuel cells [DAFC], e.g. direct methanol fuel cells [DMFC]
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00Fuel cells; Manufacture thereof
    • H01M8/10Fuel cells with solid electrolytes
    • H01M8/1016Fuel cells with solid electrolytes characterised by the electrolyte material
    • H01M8/1018Polymeric electrolyte materials
    • H01M8/102Polymeric electrolyte materials characterised by the chemical structure of the main chain of the ion-conducting polymer
    • H01M8/1025Polymeric electrolyte materials characterised by the chemical structure of the main chain of the ion-conducting polymer having only carbon and oxygen, e.g. polyethers, sulfonated polyetheretherketones [S-PEEK], sulfonated polysaccharides, sulfonated celluloses or sulfonated polyesters
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00Fuel cells; Manufacture thereof
    • H01M8/10Fuel cells with solid electrolytes
    • H01M8/1016Fuel cells with solid electrolytes characterised by the electrolyte material
    • H01M8/1018Polymeric electrolyte materials
    • H01M8/1039Polymeric electrolyte materials halogenated, e.g. sulfonated polyvinylidene fluorides
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00Fuel cells; Manufacture thereof
    • H01M8/10Fuel cells with solid electrolytes
    • H01M8/1016Fuel cells with solid electrolytes characterised by the electrolyte material
    • H01M8/1018Polymeric electrolyte materials
    • H01M8/1041Polymer electrolyte composites, mixtures or blends
    • H01M8/1044Mixtures of polymers, of which at least one is ionically conductive
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00Fuel cells; Manufacture thereof
    • H01M8/10Fuel cells with solid electrolytes
    • H01M8/1016Fuel cells with solid electrolytes characterised by the electrolyte material
    • H01M8/1018Polymeric electrolyte materials
    • H01M8/1058Polymeric electrolyte materials characterised by a porous support having no ion-conducting properties
    • H01M8/106Polymeric electrolyte materials characterised by a porous support having no ion-conducting properties characterised by the chemical composition of the porous support
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00Fuel cells; Manufacture thereof
    • H01M8/10Fuel cells with solid electrolytes
    • H01M8/1016Fuel cells with solid electrolytes characterised by the electrolyte material
    • H01M8/1018Polymeric electrolyte materials
    • H01M8/1069Polymeric electrolyte materials characterised by the manufacturing processes
    • H01M8/1072Polymeric electrolyte materials characterised by the manufacturing processes by chemical reactions, e.g. insitu polymerisation or insitu crosslinking
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2325/00Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Derivatives of such polymers
    • C08J2325/02Homopolymers or copolymers of hydrocarbons
    • C08J2325/04Homopolymers or copolymers of styrene
    • C08J2325/08Copolymers of styrene
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M2300/00Electrolytes
    • H01M2300/0017Non-aqueous electrolytes
    • H01M2300/0065Solid electrolytes
    • H01M2300/0082Organic polymers
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/30Hydrogen technology
    • Y02E60/50Fuel cells
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P70/00Climate change mitigation technologies in the production process for final industrial or consumer products
    • Y02P70/50Manufacturing or production processes characterised by the final manufactured product

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • General Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Electrochemistry (AREA)
  • Sustainable Energy (AREA)
  • Sustainable Development (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Organic Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Medicinal Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Composite Materials (AREA)
  • Materials Engineering (AREA)
  • Fuel Cell (AREA)
  • Conductive Materials (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Manufacture Of Macromolecular Shaped Articles (AREA)
  • Treatments Of Macromolecular Shaped Articles (AREA)
  • Polymerisation Methods In General (AREA)
  • Graft Or Block Polymers (AREA)
DK03743390T 2002-03-06 2003-03-04 Protonledende elektrolytmembran med reduceret methanolpermeabilitet og anvendelse deraf til brændselsceller DK1483316T3 (da)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
DE10209685A DE10209685A1 (de) 2002-03-06 2002-03-06 Verfahren zur Herstellung einer Polymerelektrolytmembran und deren Anwendung in Brennstoffzellen
DE10210499A DE10210499A1 (de) 2002-03-11 2002-03-11 Verfahren zur Herstellung einer Polymerelektrolytmembran und deren Anwendung in Brennstoffzellen
PCT/EP2003/002397 WO2003074597A1 (de) 2002-03-06 2003-03-04 Protonenleitende elektrolytmembran mit geringer methanoldurchlässigkeit und deren anwendung in brennstoffzellen

Publications (1)

Publication Number Publication Date
DK1483316T3 true DK1483316T3 (da) 2007-12-27

Family

ID=27789731

Family Applications (1)

Application Number Title Priority Date Filing Date
DK03743390T DK1483316T3 (da) 2002-03-06 2003-03-04 Protonledende elektrolytmembran med reduceret methanolpermeabilitet og anvendelse deraf til brændselsceller

Country Status (11)

Country Link
US (1) US7846982B2 (da)
EP (1) EP1483316B1 (da)
JP (2) JP2005519428A (da)
KR (1) KR100993157B1 (da)
CN (1) CN1277869C (da)
AT (1) ATE373690T1 (da)
CA (1) CA2478530A1 (da)
DE (1) DE50308216D1 (da)
DK (1) DK1483316T3 (da)
ES (1) ES2292993T3 (da)
WO (1) WO2003074597A1 (da)

Families Citing this family (37)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE10117686A1 (de) * 2001-04-09 2002-10-24 Celanese Ventures Gmbh Protonenleitende Membran und deren Verwendung
US7494733B2 (en) * 2001-06-11 2009-02-24 Honda Giken Kogyo Kabushiki Kaisha Electrode structure for solid polymer fuel cell, its production method, and solid polymer fuel cell
US7318972B2 (en) 2001-09-07 2008-01-15 Itm Power Ltd. Hydrophilic polymers and their use in electrochemical cells
DE10209419A1 (de) * 2002-03-05 2003-09-25 Celanese Ventures Gmbh Verfahren zur Herstellung einer Polymerelektrolytmembran und deren Anwendung in Brennstoffzellen
WO2003074597A1 (de) 2002-03-06 2003-09-12 Pemeas Gmbh Protonenleitende elektrolytmembran mit geringer methanoldurchlässigkeit und deren anwendung in brennstoffzellen
US20050118478A1 (en) * 2002-03-06 2005-06-02 Joachim Kiefer Mixture comprising sulphonic acid containing vinyl, polymer electrolyte membrane comprising polyvinylsulphonic acid and the use thereof in fuel cells
DE10213540A1 (de) * 2002-03-06 2004-02-19 Celanese Ventures Gmbh Lösung aus Vinylphosphonsäure, Verfahren zur Herstellung einer Polymerelektrolytmembran aus Polyvinylphosphaonsäure und deren Anwendung in Brennstoffzellen
DE10234236A1 (de) 2002-07-27 2004-02-05 Celanese Ventures Gmbh Verfahren zur Behandlung von Polyazolfolien
DE10235358A1 (de) * 2002-08-02 2004-02-12 Celanese Ventures Gmbh Protonenleitende Polymermembran umfassend Phosphonsäuregruppen enthaltende Polymere und deren Anwendung in Brennstoffzellen
DE10242708A1 (de) * 2002-09-13 2004-05-19 Celanese Ventures Gmbh Protonenleitende Membranen und deren Verwendung
DE10246461A1 (de) * 2002-10-04 2004-04-15 Celanese Ventures Gmbh Protonenleitende Polymermembran enthaltend Polyazolblends und deren Anwendung in Brennstoffzellen
DE10246372A1 (de) * 2002-10-04 2004-04-15 Celanese Ventures Gmbh Mit einer Katalysatorschicht beschichtete protonenleitende Polymermembran enthaltend Polyazole und deren Anwendung in Brennstoffzellen
US7820314B2 (en) * 2003-07-27 2010-10-26 Basf Fuel Cell Research Gmbh Proton-conducting membrane and use thereof
JP4979179B2 (ja) * 2003-08-22 2012-07-18 株式会社豊田中央研究所 固体高分子型燃料電池およびその製造方法
DE10340929A1 (de) * 2003-09-04 2005-04-07 Celanese Ventures Gmbh Protonenleitende Polymermembran umfassend mindestens ein poröses Trägermaterial und deren Anwendung in Brennstoffzellen
DE10340928A1 (de) * 2003-09-04 2005-04-07 Celanese Ventures Gmbh Mit einer Katalysatorschicht beschichtete protonenleitende Polymermembran enthaltend Phosphonensäuregruppen umfassende Polymere, Membran-Elektroden-Einheit und deren Anwendung in Brennstoffzellen
DE10361932A1 (de) 2003-12-30 2005-07-28 Celanese Ventures Gmbh Protonenleitende Membran und deren Verwendung
DE10361832A1 (de) * 2003-12-30 2005-07-28 Celanese Ventures Gmbh Protonenleitende Membran und deren Verwendung
DE10361833A1 (de) * 2003-12-30 2005-08-04 Celanese Ventures Gmbh Protonenleitende Membran und deren Verwendung
EP1747248A1 (de) * 2004-05-14 2007-01-31 Pemeas GmbH Anisotroper formkörper, verfahren zur herstellung und verwendung von anisotropen formkörpern
KR100723389B1 (ko) 2005-12-21 2007-05-30 삼성에스디아이 주식회사 폴리머 전해질막 및 이를 채용한 연료전지
JP2006216531A (ja) * 2004-12-03 2006-08-17 Nitto Denko Corp 電解質膜及びそれを用いた固体高分子型燃料電池
EP1833111A4 (en) * 2004-12-03 2010-03-17 Nitto Denko Corp ELECTROLYTE MEMBRANE AND FESTPOLYMER FUEL CELL THEREWITH
DE102005020604A1 (de) * 2005-05-03 2006-11-16 Pemeas Gmbh Brennstoffzellen mit geringerem Gewicht und Volumen
CA2613269A1 (en) * 2005-06-27 2007-01-04 Itm Power (Research) Ltd. Membrane electrode assemblies
DK1902484T3 (da) * 2005-07-01 2017-12-18 Industrie De Nora Spa Fremgangsmåde til fremstilling af gasdiffusionselektroder
US8945736B2 (en) * 2005-09-10 2015-02-03 Basf Fuel Cell Gmbh Method for conditioning membrane-electrode-units for fuel cells
DE102005051887A1 (de) * 2005-10-29 2007-05-03 Pemeas Gmbh Membran für Brennstoffzellen, enthaltend Polymere, die Phosphonsäure-und/oder Sulfonsäuregruppen umfassen, Membran-Elektroden-Einheit und deren Anwendung in Brennstoffzellen
DE102005052378A1 (de) * 2005-10-31 2007-05-03 Pemeas Gmbh Verbesserte Membran-Elektrodeneinheiten und Brennstoffzellen mit hoher Lebensdauer
JP5286646B2 (ja) * 2006-04-19 2013-09-11 トヨタ自動車株式会社 スルホン基含有モノマーの重合方法
US7638877B2 (en) * 2006-06-30 2009-12-29 Intel Corporation Alternative to desmear for build-up roughening and copper adhesion promotion
DE102007011424A1 (de) * 2007-03-08 2008-09-11 Lanxess Deutschland Gmbh Polymerelektrolytmembran mit funktionalisierten Nanopartikeln
US8476324B2 (en) 2007-04-19 2013-07-02 Kurita Water Industries Ltd. Method for manufacturing anion exchange resin, anion exchange resin, method for manufacturing cation exchange resin, cation exchange resin, mixed bed resin, and method for manufacturing ultrapure water for washing electronic component material
CN103996865A (zh) * 2013-02-19 2014-08-20 中国科学院上海有机化学研究所 高阻醇聚合物电解质膜及其制备方法
FR3080958A1 (fr) * 2018-05-04 2019-11-08 Universite de Bordeaux Pile a combustible a electrolyte ameliore
CN109273747A (zh) * 2018-09-14 2019-01-25 汪青霞 一种聚吡咯增强质子交换膜及其制备方法
CN116063877B (zh) * 2021-10-29 2023-12-08 未势能源科技有限公司 膜电极涂布设备调试用的碳粉墨水及其制备方法

Family Cites Families (67)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
NL257772A (da) 1959-11-18
NL268724A (da) 1960-08-31
US3313783A (en) 1962-07-20 1967-04-11 Teijin Ltd Process for preparation of polybenzimidazoles
JPS501707B1 (da) 1969-12-20 1975-01-21
US3808305A (en) 1971-07-27 1974-04-30 H Gregor Crosslinked,interpolymer fixed-charge membranes
US4187333A (en) * 1973-05-23 1980-02-05 California Institute Of Technology Ion-exchange hollow fibers
DE2450670A1 (de) 1974-10-25 1976-04-29 Benckiser Gmbh Joh A Verfahren zur abtrennung von citrat oder citronensaeure aus fermentationsloesungen
US4012303A (en) 1974-12-23 1977-03-15 Hooker Chemicals & Plastics Corporation Trifluorostyrene sulfonic acid membranes
JPS5397988A (en) 1977-02-08 1978-08-26 Toyo Soda Mfg Co Ltd Production of cation exchange membrane
FR2485395B1 (fr) 1980-06-24 1986-04-11 Commissariat Energie Atomique Membrane echangeuse de cations, son procede de fabrication et son application en tant qu'electrolyte solide
US4634530A (en) 1980-09-29 1987-01-06 Celanese Corporation Chemical modification of preformed polybenzimidazole semipermeable membrane
US4622276A (en) 1983-12-16 1986-11-11 Stauffer Chemical Company Fuel cell electrolyte
US4775215A (en) 1986-10-31 1988-10-04 Hoechst Celanese Corporation Nonlinear optical devices
US5098985A (en) 1988-10-11 1992-03-24 The Dow Chemical Company Copolymers containing polybenzoxazole, polybenzothiazole and polybenzimidazole moieties
US5218076A (en) 1989-08-31 1993-06-08 The Dow Chemical Company Branch polybenzazole polymer and method of preparation
US5091500A (en) 1990-09-21 1992-02-25 The Dow Chemical Company Polybenzazole polymer containing perfluorocyclobutane rings
US5211984A (en) 1991-02-19 1993-05-18 The Regents Of The University Of California Membrane catalyst layer for fuel cells
KR960700297A (ko) 1993-01-15 1996-01-19 로날드 에이. 블리이커 이온 교환막 및 그 제조방법
US5312895A (en) 1993-03-12 1994-05-17 The United States Of America As Represented By The Secretary Of The Air Force Benzobisazole copolymer system soluble in aprotic solvents
KR100306676B1 (ko) 1993-04-28 2001-11-30 샬크비즈크 피이터 코르넬리스; 페트귄터 피리도비스이미다졸성분의강성막대형중합체
CH691209A5 (de) 1993-09-06 2001-05-15 Scherrer Inst Paul Herstellungsverfahren für einen Polmerelektrolyten und elektrochemische Zelle mit diesem Polymerelektrolyten.
US5633337A (en) 1995-01-26 1997-05-27 The United States Of America As Represented By The Secretary Of The Air Force Aromatic benzobisazole polymers and copolymers incorporating diphenylamino moieties
US5492996A (en) 1995-02-21 1996-02-20 The United States Of America As Represented By The Secretary Of The Air Force Alcohol soluble benzazole polymers
US5599639A (en) 1995-08-31 1997-02-04 Hoechst Celanese Corporation Acid-modified polybenzimidazole fuel cell elements
DE19548421B4 (de) 1995-12-22 2004-06-03 Celanese Ventures Gmbh Verfahren zur kontinuierlichen Herstellung von Membranelektrodeneinheiten
DE19632285A1 (de) 1996-08-09 1998-02-19 Hoechst Ag Protonenleiter mit einer Temperaturbeständigkeit in einem weiten Bereich und guten Protonenleitfähigkeiten
DE19650478A1 (de) 1996-12-05 1998-06-10 Daimler Benz Ag Lackiertes metallisches Substrat mit einer korrosionsschützenden Haftschicht auf Basis von Polysäuren und Verfahren zum Aufbringen der Haftschicht
DE19653484A1 (de) 1996-12-20 1998-06-25 Fraunhofer Ges Forschung Verfahren zur Herstellung von Membran-Elektroden-Einheiten und eine so hergestellte Membran-Elektroden-Einheit
DE19727554A1 (de) * 1997-06-28 1999-01-07 Huels Chemische Werke Ag Verfahren zur Hydrophilierung der Oberfläche polymerer Substrate mit einem Makroinitiator als Primer
EP0893165A3 (de) 1997-06-28 2000-09-20 Degussa-Hüls Aktiengesellschaft Bioaktive Beschichtung von Oberflächen unter Verwendung von Makroinitiatoren
US6248469B1 (en) 1997-08-29 2001-06-19 Foster-Miller, Inc. Composite solid polymer electrolyte membranes
CA2300934C (en) * 1997-08-29 2008-08-26 Foster-Miller, Inc. Composite solid polymer electrolyte membranes
US6030718A (en) 1997-11-20 2000-02-29 Avista Corporation Proton exchange membrane fuel cell power system
US6110616A (en) 1998-01-30 2000-08-29 Dais-Analytic Corporation Ion-conducting membrane for fuel cell
US6087032A (en) 1998-08-13 2000-07-11 Asahi Glass Company Ltd. Solid polymer electrolyte type fuel cell
FI107932B (fi) 1999-02-16 2001-10-31 Mikael Paronen Polymeerikalvo ja menetelmä sen valmistamiseksi
AU2831000A (en) * 1999-03-08 2000-09-28 Center For Advanced Science And Technology Incubation, Ltd. Electrolytic membrane for fuel cell and its manufacturing method, and fuel cell and its manufacturing method
US6517962B1 (en) 1999-08-23 2003-02-11 Ballard Power Systems Inc. Fuel cell anode structures for voltage reversal tolerance
JP3656244B2 (ja) * 1999-11-29 2005-06-08 株式会社豊田中央研究所 高耐久性固体高分子電解質及びその高耐久性固体高分子電解質を用いた電極−電解質接合体並びにその電極−電解質接合体を用いた電気化学デバイス
EP1110992B1 (en) 1999-11-29 2006-08-02 Kabushiki Kaisha Toyota Chuo Kenkyusho Solid polymer electrolyte having high-durability
US6471850B2 (en) 1999-12-16 2002-10-29 Proton Energy Systems, Inc. Low gravity electrochemical cell
GB0006429D0 (en) 2000-03-17 2000-05-03 Johnson Matthey Plc Electrochemical cell
GB0006428D0 (en) 2000-03-17 2000-05-03 Johnson Matthey Plc Electrochemical cell
JP2003535940A (ja) 2000-06-02 2003-12-02 エスアールアイ インターナショナル 高分子組成物
DE10052242A1 (de) 2000-10-21 2002-05-02 Celanese Ventures Gmbh Mit Säure dotierte, ein- oder mehrschichtige Kunststoffmembran mit Schichten aufweisend Polymerblends umfassend Polymere mit wiederkehrenden Azoleinheiten, Verfahren zur Herstellung solche Kunststoffmembranen sowie deren Verwendung
CN100358938C (zh) 2000-11-13 2008-01-02 东洋纺织株式会社 具有磺酸基和/或膦酸基的聚吲哚类化合物、固体电解质膜/电极催化剂层复合体及其制造方法
JP2002146014A (ja) 2000-11-15 2002-05-22 Toyobo Co Ltd イオン伝導性ホスホン酸含有ポリアゾール
DE10109829A1 (de) 2001-03-01 2002-09-05 Celanese Ventures Gmbh Polymermembran, Verfahren zu deren Herstellung sowie deren Verwendung
DE10117686A1 (de) 2001-04-09 2002-10-24 Celanese Ventures Gmbh Protonenleitende Membran und deren Verwendung
DE10117687A1 (de) 2001-04-09 2002-10-17 Celanese Ventures Gmbh Protonenleitende Membran und deren Verwendung
DE10129458A1 (de) 2001-06-19 2003-01-02 Celanese Ventures Gmbh Verbesserte Polymerfolien auf Basis von Polyazolen
JP2003022709A (ja) 2001-07-09 2003-01-24 Toyobo Co Ltd ブレンドポリマー電解質、該電解質を主成分とする電解質膜、及び該電解質を用いた膜/電極接合体
DE10133738A1 (de) 2001-07-11 2003-02-06 Joerg Mueller Verfahren zur Herstellung einer plasmapolymerisierten Polymer-Elektrolytmembran
DE10144815A1 (de) 2001-09-12 2003-03-27 Celanese Ventures Gmbh Protonenleitende Membran und deren Verwendung
DE10148131B4 (de) 2001-09-28 2010-07-01 Gkss-Forschungszentrum Geesthacht Gmbh Verfahren zur Herstellung eines Polymers, Polymer und protonenleitfähige Membran für elektrochemische Anwendungen
DE10209419A1 (de) 2002-03-05 2003-09-25 Celanese Ventures Gmbh Verfahren zur Herstellung einer Polymerelektrolytmembran und deren Anwendung in Brennstoffzellen
DE10213540A1 (de) 2002-03-06 2004-02-19 Celanese Ventures Gmbh Lösung aus Vinylphosphonsäure, Verfahren zur Herstellung einer Polymerelektrolytmembran aus Polyvinylphosphaonsäure und deren Anwendung in Brennstoffzellen
US20050118478A1 (en) 2002-03-06 2005-06-02 Joachim Kiefer Mixture comprising sulphonic acid containing vinyl, polymer electrolyte membrane comprising polyvinylsulphonic acid and the use thereof in fuel cells
CA2477863A1 (en) * 2002-03-06 2003-09-12 Pemeas Gmbh Mixtures comprising vinyl-containing sulphonic acid, polymer electrolyte membranes comprising polyvinylsulphonic acid and their use in fuel cells
WO2003074597A1 (de) 2002-03-06 2003-09-12 Pemeas Gmbh Protonenleitende elektrolytmembran mit geringer methanoldurchlässigkeit und deren anwendung in brennstoffzellen
DE10220818A1 (de) 2002-05-10 2003-11-20 Celanese Ventures Gmbh Verfahren zur Herstellung einer gepfropften Polymerelektrolytmembran und deren Anwendung in Brennstoffzellen
DE10228657A1 (de) 2002-06-27 2004-01-15 Celanese Ventures Gmbh Protonenleitende Membran und deren Verwendung
JP2005537384A (ja) 2002-08-29 2005-12-08 ペメアス ゲーエムベーハー プロトン伝導性ポリマー膜の製造方法、改良されたポリマー膜、および燃料電池におけるその使用
DE10242708A1 (de) 2002-09-13 2004-05-19 Celanese Ventures Gmbh Protonenleitende Membranen und deren Verwendung
US7820314B2 (en) 2003-07-27 2010-10-26 Basf Fuel Cell Research Gmbh Proton-conducting membrane and use thereof
DE10340928A1 (de) * 2003-09-04 2005-04-07 Celanese Ventures Gmbh Mit einer Katalysatorschicht beschichtete protonenleitende Polymermembran enthaltend Phosphonensäuregruppen umfassende Polymere, Membran-Elektroden-Einheit und deren Anwendung in Brennstoffzellen
DE102005051887A1 (de) * 2005-10-29 2007-05-03 Pemeas Gmbh Membran für Brennstoffzellen, enthaltend Polymere, die Phosphonsäure-und/oder Sulfonsäuregruppen umfassen, Membran-Elektroden-Einheit und deren Anwendung in Brennstoffzellen

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EP1483316A1 (de) 2004-12-08
CA2478530A1 (en) 2003-09-12
JP2005519428A (ja) 2005-06-30
CN1639239A (zh) 2005-07-13
DE50308216D1 (de) 2007-10-31
ES2292993T3 (es) 2008-03-16
EP1483316B1 (de) 2007-09-19
WO2003074597A1 (de) 2003-09-12
JP2011138782A (ja) 2011-07-14
CN1277869C (zh) 2006-10-04
KR100993157B1 (ko) 2010-11-09
KR20050002844A (ko) 2005-01-10
US7846982B2 (en) 2010-12-07
ATE373690T1 (de) 2007-10-15

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