JP4912561B2 - 光に安定なシリル化ベンゾトリアゾールｕｖ吸収剤及びそれにより安定化された組成物 - Google Patents

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Publication number

JP4912561B2

JP4912561B2 JP2002518227A JP2002518227A JP4912561B2 JP 4912561 B2 JP4912561 B2 JP 4912561B2 JP 2002518227 A JP2002518227 A JP 2002518227A JP 2002518227 A JP2002518227 A JP 2002518227A JP 4912561 B2 JP4912561 B2 JP 4912561B2

Authority

JP

Japan

Prior art keywords

tert

butyl

carbon atoms

benzotriazole

hydroxy

Prior art date

2000-08-03

Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)

Expired - Fee Related

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• 239000000203 mixture Substances 0.000 title claims description 55
• 239000006096 absorbing agent Substances 0.000 title claims description 28
• 239000012964 benzotriazole Substances 0.000 title claims description 26
• QRUDEWIWKLJBPS-UHFFFAOYSA-N benzotriazole Chemical compound C1=CC=C2N[N][N]C2=C1 QRUDEWIWKLJBPS-UHFFFAOYSA-N 0.000 title claims description 18
• -1 alpha-cumyl Chemical group 0.000 claims abstract description 109
• 150000001875 compounds Chemical class 0.000 claims description 126
• 125000004432 carbon atom Chemical group C* 0.000 claims description 96
• 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims description 51
• 125000000217 alkyl group Chemical group 0.000 claims description 43
• 229910052739 hydrogen Inorganic materials 0.000 claims description 33
• 239000001257 hydrogen Substances 0.000 claims description 33
• 239000000654 additive Substances 0.000 claims description 18
• 150000001412 amines Chemical class 0.000 claims description 16
• 125000002947 alkylene group Chemical group 0.000 claims description 10
• 239000011368 organic material Substances 0.000 claims description 7
• 230000015556 catabolic process Effects 0.000 claims description 5
• 238000006731 degradation reaction Methods 0.000 claims description 5
• 125000000999 tert-butyl group Chemical group [H]C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 claims description 5
• 125000004435 hydrogen atom Chemical class [H]* 0.000 claims description 4
• HJIAMFHSAAEUKR-UHFFFAOYSA-N (2-hydroxyphenyl)-phenylmethanone Chemical compound OC1=CC=CC=C1C(=O)C1=CC=CC=C1 HJIAMFHSAAEUKR-UHFFFAOYSA-N 0.000 claims description 3
• WPYMKLBDIGXBTP-UHFFFAOYSA-N benzoic acid Chemical compound OC(=O)C1=CC=CC=C1 WPYMKLBDIGXBTP-UHFFFAOYSA-N 0.000 claims description 3
• 239000002530 phenolic antioxidant Substances 0.000 claims description 3
• JIHQDMXYYFUGFV-UHFFFAOYSA-N 1,3,5-triazine Chemical compound C1=NC=NC=N1 JIHQDMXYYFUGFV-UHFFFAOYSA-N 0.000 claims description 2
• IJVRPNIWWODHHA-UHFFFAOYSA-N 2-cyanoprop-2-enoic acid Chemical compound OC(=O)C(=C)C#N IJVRPNIWWODHHA-UHFFFAOYSA-N 0.000 claims description 2
• FTWUXYZHDFCGSV-UHFFFAOYSA-N n,n'-diphenyloxamide Chemical compound C=1C=CC=CC=1NC(=O)C(=O)NC1=CC=CC=C1 FTWUXYZHDFCGSV-UHFFFAOYSA-N 0.000 claims description 2
• 238000000576 coating method Methods 0.000 abstract description 31
• 229920001296 polysiloxane Polymers 0.000 abstract description 18
• 125000003354 benzotriazolyl group Chemical class N1N=NC2=C1C=CC=C2* 0.000 abstract description 2
• PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 52
• 238000000034 method Methods 0.000 description 40
• 229920001577 copolymer Polymers 0.000 description 35
• 239000000463 material Substances 0.000 description 30
• 229920000642 polymer Polymers 0.000 description 27
• 239000000543 intermediate Substances 0.000 description 25
• 239000007787 solid Substances 0.000 description 24
• YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 22
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• UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 21
• 239000011248 coating agent Substances 0.000 description 21
• VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 20
• 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 20
• 239000010410 layer Substances 0.000 description 19
• 125000003884 phenylalkyl group Chemical group 0.000 description 18
• LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 17
• 150000001565 benzotriazoles Chemical class 0.000 description 17
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• 125000003118 aryl group Chemical group 0.000 description 11
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• 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 10
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• WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 8
• 230000000996 additive effect Effects 0.000 description 8
• KPUWHANPEXNPJT-UHFFFAOYSA-N disiloxane Chemical class [SiH3]O[SiH3] KPUWHANPEXNPJT-UHFFFAOYSA-N 0.000 description 8
• 150000002431 hydrogen Chemical group 0.000 description 8
• 229920001155 polypropylene Polymers 0.000 description 8
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• 150000001993 dienes Chemical class 0.000 description 7
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• 229910052736 halogen Inorganic materials 0.000 description 7
• 229910052751 metal Inorganic materials 0.000 description 7
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• 239000004800 polyvinyl chloride Substances 0.000 description 7
• 239000010453 quartz Substances 0.000 description 7
• 239000003381 stabilizer Substances 0.000 description 7
• 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 7
• 229920000178 Acrylic resin Polymers 0.000 description 6
• WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 6
• VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 6
• 239000004698 Polyethylene Substances 0.000 description 6
• 239000004721 Polyphenylene oxide Substances 0.000 description 6
• KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 6
• HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 6
• 238000005299 abrasion Methods 0.000 description 6
• 238000000862 absorption spectrum Methods 0.000 description 6
• 229920000180 alkyd Polymers 0.000 description 6
• HXBPYFMVGFDZFT-UHFFFAOYSA-N allyl isocyanate Chemical compound C=CCN=C=O HXBPYFMVGFDZFT-UHFFFAOYSA-N 0.000 description 6
• 239000012965 benzophenone Substances 0.000 description 6
• 238000006243 chemical reaction Methods 0.000 description 6
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• 150000002367 halogens Chemical class 0.000 description 6
• 239000004922 lacquer Substances 0.000 description 6
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• 125000001570 methylene group Chemical group [H]C([H])([*:1])[*:2] 0.000 description 6
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• QQQSFSZALRVCSZ-UHFFFAOYSA-N triethoxysilane Chemical compound CCO[SiH](OCC)OCC QQQSFSZALRVCSZ-UHFFFAOYSA-N 0.000 description 6
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• ONHZKWDILKBQLS-UHFFFAOYSA-N 2-(2-phenylpropan-2-yl)-4-(2,4,4-trimethylpentan-2-yl)phenol Chemical compound CC(C)(C)CC(C)(C)C1=CC=C(O)C(C(C)(C)C=2C=CC=CC=2)=C1 ONHZKWDILKBQLS-UHFFFAOYSA-N 0.000 description 5
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• NYGZLYXAPMMJTE-UHFFFAOYSA-M metanil yellow Chemical group [Na+].[O-]S(=O)(=O)C1=CC=CC(N=NC=2C=CC(NC=3C=CC=CC=3)=CC=2)=C1 NYGZLYXAPMMJTE-UHFFFAOYSA-M 0.000 description 5
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