JP4892149B2 - ガラス−セラミック接合材料および接合方法 - Google Patents

ガラス−セラミック接合材料および接合方法 Download PDF

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JP4892149B2
JP4892149B2 JP2001514265A JP2001514265A JP4892149B2 JP 4892149 B2 JP4892149 B2 JP 4892149B2 JP 2001514265 A JP2001514265 A JP 2001514265A JP 2001514265 A JP2001514265 A JP 2001514265A JP 4892149 B2 JP4892149 B2 JP 4892149B2
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solid
component
joint
mol
ceramic
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Japanese (ja)
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JP2003506304A5 (https=
JP2003506304A (ja
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マインハート，ケリー・ディー
ヴィエナ，ジョン・ディー
アームストロング，ティモシー・アール
ペダーソン，ラリー・アール
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バッテル・メモリアル・インスティチュート
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Priority claimed from PCT/US2000/020534 external-priority patent/WO2001009059A1/en
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    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/02—Details
    • H01M8/0271—Sealing or supporting means around electrodes, matrices or membranes
    • H01M8/028—Sealing means characterised by their material
    • H01M8/0282—Inorganic material
    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C10/00—Devitrified glass ceramics, i.e. glass ceramics having a crystalline phase dispersed in a glassy phase and constituting at least 50% by weight of the total composition
    • C03C10/0036—Devitrified glass ceramics, i.e. glass ceramics having a crystalline phase dispersed in a glassy phase and constituting at least 50% by weight of the total composition containing SiO2, Al2O3 and a divalent metal oxide as main constituents
    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C3/00—Glass compositions
    • C03C3/04—Glass compositions containing silica
    • C03C3/076—Glass compositions containing silica with 40% to 90% silica, by weight
    • C03C3/083—Glass compositions containing silica with 40% to 90% silica, by weight containing aluminium oxide or an iron compound
    • C03C3/085—Glass compositions containing silica with 40% to 90% silica, by weight containing aluminium oxide or an iron compound containing an oxide of a divalent metal
    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C8/00—Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions
    • C03C8/02—Frit compositions, i.e. in a powdered or comminuted form
    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C8/00—Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions
    • C03C8/24—Fusion seal compositions being frit compositions having non-frit additions, i.e. for use as seals between dissimilar materials, e.g. glass and metal; Glass solders
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B37/00—Joining burned ceramic articles with other burned ceramic articles or other articles by heating
    • C04B37/003—Joining burned ceramic articles with other burned ceramic articles or other articles by heating by means of an interlayer consisting of a combination of materials selected from glass, or ceramic material with metals, metal oxides or metal salts
    • C04B37/005—Joining burned ceramic articles with other burned ceramic articles or other articles by heating by means of an interlayer consisting of a combination of materials selected from glass, or ceramic material with metals, metal oxides or metal salts consisting of glass or ceramic material
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B37/00—Joining burned ceramic articles with other burned ceramic articles or other articles by heating
    • C04B37/02—Joining burned ceramic articles with other burned ceramic articles or other articles by heating with metallic articles
    • C04B37/023—Joining burned ceramic articles with other burned ceramic articles or other articles by heating with metallic articles characterised by the interlayer used
    • C04B37/025—Joining burned ceramic articles with other burned ceramic articles or other articles by heating with metallic articles characterised by the interlayer used consisting of glass or ceramic material
    • G—PHYSICS
    • G01—MEASURING; TESTING
    • G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
    • G01N27/00—Investigating or analysing materials by the use of electric, electrochemical, or magnetic means
    • G01N27/26—Investigating or analysing materials by the use of electric, electrochemical, or magnetic means by investigating electrochemical variables; by using electrolysis or electrophoresis
    • G01N27/403—Cells and electrode assemblies
    • G01N27/406—Cells and probes with solid electrolytes
    • G01N27/407—Cells and probes with solid electrolytes for investigating or analysing gases
    • G01N27/4073—Composition or fabrication of the solid electrolyte
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/02—Details
    • H01M8/0202—Collectors; Separators, e.g. bipolar separators; Interconnectors
    • H01M8/0204—Non-porous and characterised by the material
    • H01M8/0215—Glass; Ceramic materials
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/10—Fuel cells with solid electrolytes
    • H01M8/12—Fuel cells with solid electrolytes operating at high temperature, e.g. with stabilised ZrO2 electrolyte
    • H01M8/1213—Fuel cells with solid electrolytes operating at high temperature, e.g. with stabilised ZrO2 electrolyte characterised by the electrode/electrolyte combination or the supporting material
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2237/00—Aspects relating to ceramic laminates or to joining of ceramic articles with other articles by heating
    • C04B2237/02—Aspects relating to interlayers, e.g. used to join ceramic articles with other articles by heating
    • C04B2237/10—Glass interlayers, e.g. frit or flux
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2237/00—Aspects relating to ceramic laminates or to joining of ceramic articles with other articles by heating
    • C04B2237/30—Composition of layers of ceramic laminates or of ceramic or metallic articles to be joined by heating, e.g. Si substrates
    • C04B2237/32—Ceramic
    • C04B2237/34—Oxidic
    • C04B2237/345—Refractory metal oxides
    • C04B2237/348—Zirconia, hafnia, zirconates or hafnates
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2237/00—Aspects relating to ceramic laminates or to joining of ceramic articles with other articles by heating
    • C04B2237/30—Composition of layers of ceramic laminates or of ceramic or metallic articles to be joined by heating, e.g. Si substrates
    • C04B2237/40—Metallic
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2237/00—Aspects relating to ceramic laminates or to joining of ceramic articles with other articles by heating
    • C04B2237/30—Composition of layers of ceramic laminates or of ceramic or metallic articles to be joined by heating, e.g. Si substrates
    • C04B2237/40—Metallic
    • C04B2237/401—Cermets
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2237/00—Aspects relating to ceramic laminates or to joining of ceramic articles with other articles by heating
    • C04B2237/50—Processing aspects relating to ceramic laminates or to the joining of ceramic articles with other articles by heating
    • C04B2237/76—Forming laminates or joined articles comprising at least one member in the form other than a sheet or disc, e.g. two tubes or a tube and a sheet or disc
    • C04B2237/765—Forming laminates or joined articles comprising at least one member in the form other than a sheet or disc, e.g. two tubes or a tube and a sheet or disc at least one member being a tube
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/10—Fuel cells with solid electrolytes
    • H01M8/12—Fuel cells with solid electrolytes operating at high temperature, e.g. with stabilised ZrO2 electrolyte
    • H01M2008/1293—Fuel cells with solid oxide electrolytes
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M2300/00—Electrolytes
    • H01M2300/0017—Non-aqueous electrolytes
    • H01M2300/0065—Solid electrolytes
    • H01M2300/0068—Solid electrolytes inorganic
    • H01M2300/0071—Oxides
    • H01M2300/0074—Ion conductive at high temperature
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/30—Hydrogen technology
    • Y02E60/50—Fuel cells
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P70/00—Climate change mitigation technologies in the production process for final industrial or consumer products
    • Y02P70/50—Manufacturing or production processes characterised by the final manufactured product

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Ceramic Engineering (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • Electrochemistry (AREA)
  • Geochemistry & Mineralogy (AREA)
  • Sustainable Development (AREA)
  • Manufacturing & Machinery (AREA)
  • Sustainable Energy (AREA)
  • Health & Medical Sciences (AREA)
  • Structural Engineering (AREA)
  • Pathology (AREA)
  • General Health & Medical Sciences (AREA)
  • General Physics & Mathematics (AREA)
  • Immunology (AREA)
  • Molecular Biology (AREA)
  • Biochemistry (AREA)
  • Analytical Chemistry (AREA)
  • Physics & Mathematics (AREA)
  • Inorganic Chemistry (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Dispersion Chemistry (AREA)
  • Fuel Cell (AREA)
  • Ceramic Products (AREA)
JP2001514265A 1999-07-30 2000-07-28 ガラス−セラミック接合材料および接合方法 Expired - Lifetime JP4892149B2 (ja)

Applications Claiming Priority (5)

Application Number Priority Date Filing Date Title
US09/365,343 1999-07-30
US09/365,343 US6430966B1 (en) 1999-07-30 1999-07-30 Glass-ceramic material and method of making
US09/562,583 US6532769B1 (en) 1999-07-30 2000-05-01 Glass-ceramic joint and method of joining
US09/562,583 2000-05-01
PCT/US2000/020534 WO2001009059A1 (en) 1999-07-30 2000-07-28 Glass-ceramic joining material and method of joining

Publications (3)

Publication Number Publication Date
JP2003506304A JP2003506304A (ja) 2003-02-18
JP2003506304A5 JP2003506304A5 (https=) 2007-09-13
JP4892149B2 true JP4892149B2 (ja) 2012-03-07

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JP2001514265A Expired - Lifetime JP4892149B2 (ja) 1999-07-30 2000-07-28 ガラス−セラミック接合材料および接合方法

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US (2) US6430966B1 (https=)
JP (1) JP4892149B2 (https=)

Families Citing this family (91)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6878651B2 (en) * 2000-12-01 2005-04-12 Ford Global Technologies, Llc Glass compositions for ceramic electrolyte electrochemical conversion devices
US6974070B2 (en) * 2001-08-07 2005-12-13 University Of Chicago Joining of advanced materials by superplastic deformation
US7258942B2 (en) * 2002-04-26 2007-08-21 Battelle Memorial Institute Multilayer compressive seal for sealing in high temperature devices
US6843406B2 (en) * 2002-09-27 2005-01-18 Battelle Memorial Institute Gas-tight metal/ceramic or metal/metal seals for applications in high temperature electrochemical devices and method of making
WO2004063110A2 (en) * 2003-01-03 2004-07-29 Battelle Memorial Institute Glass-ceramic material and method of making
US7022198B2 (en) * 2003-03-07 2006-04-04 The United States Of America As Represented By The Secretary Of The Navy Microwave assisted reactive brazing of ceramic materials
DE10345807A1 (de) * 2003-09-30 2005-04-21 Bosch Gmbh Robert Festelektrolytmaterial und Verfahren zu dessen Herstellung
DE102004018403B3 (de) * 2004-04-16 2006-02-02 Forschungszentrum Jülich GmbH Gasdichter Elektrolyt für eine Hochtemperatur-Brennstoffzelle sowie Verfahren zur Herstellung desselben
WO2005106999A1 (en) * 2004-04-27 2005-11-10 Battelle Memorial Institute Improved joint with application in electrochemical devices
US7794170B2 (en) * 2005-04-22 2010-09-14 Battelle Memorial Institute Joint with application in electrochemical devices
US20060060633A1 (en) * 2004-09-22 2006-03-23 Battelle Memorial Institute High strength insulating metal-to-ceramic joints for solid oxide fuel cells and other high temperature applications and method of making
US20060063057A1 (en) * 2004-09-22 2006-03-23 Battelle Memorial Institute High strength insulating metal-to-metal joints for solid oxide fuel cells and other high temperature applications and method of making
US7498585B2 (en) * 2006-04-06 2009-03-03 Battelle Memorial Institute Method and apparatus for simultaneous detection and measurement of charged particles at one or more levels of particle flux for analysis of same
US7399720B1 (en) 2004-10-15 2008-07-15 Brow Richard K Glass and glass-ceramic sealant compositions
US7785725B2 (en) * 2004-12-03 2010-08-31 Delphi Technologies, Inc. Compound for a solid oxide fuel cell stack gasket
US7422819B2 (en) * 2004-12-30 2008-09-09 Delphi Technologies, Inc. Ceramic coatings for insulating modular fuel cell cassettes in a solid-oxide fuel cell stack
DE102005002435A1 (de) * 2005-01-19 2006-07-27 Forschungszentrum Jülich GmbH Herstellung einer Glaskeramik sowie dessen Verwendung als Fügematerial für den Hochtemperatureinsatz
US7214441B2 (en) * 2005-02-03 2007-05-08 Corning Incorporated Low alkali sealing frits, and seals and devices utilizing such frits
EP1783107A1 (fr) 2005-11-08 2007-05-09 L'AIR LIQUIDE, Société Anonyme pour l'Etude et l'Exploitation des Procédés Georges Claude Procédé d'élaboration d'un scellement haute température céramique/métal, composition en céramique et verre et ensemble de jonction céramique-métal
US7470640B2 (en) * 2006-04-11 2008-12-30 Corning Incorporated Glass-ceramic seals for use in solid oxide fuel cells
US7378361B2 (en) * 2006-04-11 2008-05-27 Corning Incorporated High thermal expansion cyclosilicate glass-ceramics
JP5679657B2 (ja) * 2006-04-11 2015-03-04 コーニング インコーポレイテッド 固体酸化物燃料電池に使用するためのガラスセラミックシール
US7410921B2 (en) * 2006-04-11 2008-08-12 Corning Incorporated High thermal expansion cyclosilicate glass-ceramics
EP2403044B1 (en) * 2007-04-12 2013-02-20 Corning Incorporated Sealing materials, solid oxide fuel cells utilizing such materials and a method of making such materials
US20090004544A1 (en) * 2007-06-29 2009-01-01 Subhasish Mukerjee Glass seal with ceramic fiber for a solid-oxide fuel cell stack
US20100081032A1 (en) 2007-06-29 2010-04-01 Subhasish Mukerjee Glass Seal Containing Zirconia Powder and Fiber for a Solid Oxide Fuel Cell Stack
JP5365517B2 (ja) * 2007-08-01 2013-12-11 旭硝子株式会社 無鉛ガラス
JP5231569B2 (ja) * 2007-12-21 2013-07-10 サン−ゴバン セラミックス アンド プラスティクス，インコーポレイティド 燃料電池のための多層ガラス−セラミックシール
US7897530B2 (en) * 2008-01-14 2011-03-01 Atomic Energy Council-Institute Of Nuclear Energy Research Glass-ceramic sealant for planar solid oxide fuel cells
US7931997B2 (en) * 2008-03-12 2011-04-26 Bloom Energy Corporation Multi-material high temperature fuel cell seals
US7833314B2 (en) * 2008-04-30 2010-11-16 Praxair Technology, Inc. Purification method and junction for related apparatus
US7989374B2 (en) * 2008-05-15 2011-08-02 Corning Incorporated Non-contaminating, electro-chemically stable glass frit sealing materials and seals and devices using such sealing materials
JP5208622B2 (ja) * 2008-08-27 2013-06-12 日本碍子株式会社 固体酸化物型燃料電池の組立方法
US8691470B2 (en) * 2008-11-12 2014-04-08 Bloom Energy Corporation Seal compositions, methods, and structures for planar solid oxide fuel cells
US10087103B2 (en) * 2008-11-12 2018-10-02 Bloom Energy Corporation Seal compositions, methods, and structures for planar solid oxide fuel cells
US8623569B2 (en) 2008-12-09 2014-01-07 Bloom Energy Corporation Fuel cell seals
DE102009008672A1 (de) * 2009-02-12 2010-08-19 Elringklinger Ag Verfahren zur Herstellung einer elektrisch isolierenden Dichtungsanordnung und Dichtungsanordnung zum Abdichten zwischen zwei Bauteilen eines Brennstoffzellenstacks
AU2010220562B2 (en) * 2009-03-04 2015-06-18 Schott Ag Crystallizing glass solder and use thereof
US8664134B2 (en) 2009-03-04 2014-03-04 Schott Ag Crystallizing glass solders and uses thereof
DE102009011182B4 (de) 2009-03-04 2017-03-23 Schott Ag Kristallisierendes Glaslot, Komposite und dessen Verwendung
US8158261B2 (en) * 2009-04-22 2012-04-17 National Taipei University Technology Glass-ceramic composite encapsulation material
FR2947540B1 (fr) 2009-07-03 2012-01-06 Commissariat Energie Atomique Compositions de verre pour joints d'appareils fonctionnant a de hautes temperatures et procede d'assemblage les utilisant.
CN105174719A (zh) * 2009-12-31 2015-12-23 圣戈本陶瓷及塑料股份有限公司 用于sofc堆叠体的薄细颗粒化的并且全致密的玻璃-陶瓷密封物
DE102010035251B4 (de) * 2010-02-15 2013-09-26 Schott Ag Hochtemperatur-Glaslot und dessen Verwendung
US9296644B2 (en) * 2010-02-15 2016-03-29 Schott Ag High-temperature glass solder and its uses
US8166777B2 (en) 2010-03-22 2012-05-01 Battelle Memorial Institute Glass composition and process for sealing void spaces in electrochemical devices
FR2958283B1 (fr) 2010-04-01 2014-07-04 Commissariat Energie Atomique Compositions de verres vitroceramiques pour joints d'appareils fonctionnant a de hautes temperatures et procede d'assemblage les utilisant.
JP5441176B2 (ja) * 2010-07-07 2014-03-12 日本特殊陶業株式会社 固体酸化物形燃料電池、固体酸化物形燃料電池スタック及び固体酸化物形燃料電池装置
US9561476B2 (en) 2010-12-15 2017-02-07 Praxair Technology, Inc. Catalyst containing oxygen transport membrane
US8420278B2 (en) 2010-12-30 2013-04-16 Delphi Technologies, Inc. Solid oxide fuel cell having a glass composite seal
EP2761060A4 (en) 2011-09-01 2015-07-15 Infinium Inc HIGH CURRENT LINE AT HIGH TEMPERATURE IN OXYGEN AND LIQUID METAL ENVIRONMENT
US9486735B2 (en) 2011-12-15 2016-11-08 Praxair Technology, Inc. Composite oxygen transport membrane
EP2791082B1 (en) 2011-12-15 2021-01-20 Praxair Technology, Inc. Method of producing composite oxygen transport membrane
DE102012206266B3 (de) 2012-04-17 2013-07-11 Schott Ag Barium- und strontiumfreies glasiges oder glaskeramisches Fügematerial und dessen Verwendung
DE102012207405B3 (de) * 2012-05-04 2013-08-14 Schott Ag Glaskeramisches Fügematerial und dessen Verwendung
US20150299026A1 (en) * 2012-09-28 2015-10-22 Danmarks Tekniske Universitet Glass composition for the use as a sealant
EP2935155B1 (en) 2012-12-19 2019-02-13 Praxair Technology Inc. Method for sealing an oxygen transport membrane assembly
US9453644B2 (en) 2012-12-28 2016-09-27 Praxair Technology, Inc. Oxygen transport membrane based advanced power cycle with low pressure synthesis gas slip stream
JP6116037B2 (ja) 2013-03-29 2017-04-19 サン−ゴバン セラミックス アンド プラスティクス，インコーポレイティド 高温用途のためのサンボルナイト系ガラスセラミックシール
CN104124178A (zh) * 2013-04-26 2014-10-29 上海和辉光电有限公司 封装材料的涂布方法及其装置
US9296671B2 (en) 2013-04-26 2016-03-29 Praxair Technology, Inc. Method and system for producing methanol using an integrated oxygen transport membrane based reforming system
US9611144B2 (en) 2013-04-26 2017-04-04 Praxair Technology, Inc. Method and system for producing a synthesis gas in an oxygen transport membrane based reforming system that is free of metal dusting corrosion
US9938145B2 (en) 2013-04-26 2018-04-10 Praxair Technology, Inc. Method and system for adjusting synthesis gas module in an oxygen transport membrane based reforming system
US9212113B2 (en) 2013-04-26 2015-12-15 Praxair Technology, Inc. Method and system for producing a synthesis gas using an oxygen transport membrane based reforming system with secondary reforming and auxiliary heat source
US8968509B2 (en) 2013-05-09 2015-03-03 Bloom Energy Corporation Methods and devices for printing seals for fuel cell stacks
DE102013009001A1 (de) 2013-05-24 2014-11-27 Friedrich-Schiller-Universität Jena Kristallisierende, cristobalitfreie und elektrisch gut isolierende Glaslote mit hohen thermischen Ausdehnungskoeffizienten zum Fügen von Metallen und/oder Keramiken
DE102013209970B3 (de) 2013-05-28 2014-07-24 Schott Ag Glasiges oder zumindest teilkristallines Fügematerial und dessen Verwendung sowie Fügeverbindung
EP3055054A2 (en) 2013-10-07 2016-08-17 Praxair Technology Inc. Ceramic oxygen transport membrane array reactor and reforming method
RU2661581C2 (ru) 2013-10-08 2018-07-17 Праксайр Текнолоджи, Инк. Система и способ регулирования температуры в реакторе на основе кислородпроводящих мембран
CA2926757C (en) 2013-12-02 2020-02-25 Praxair Technology, Inc. Method and system for producing hydrogen using an oxygen transport membrane based reforming system with secondary reforming
CA2937943A1 (en) 2014-02-12 2015-08-20 Praxair Technology, Inc. Oxygen transport membrane reactor based method and system for generating electric power
US10822234B2 (en) 2014-04-16 2020-11-03 Praxair Technology, Inc. Method and system for oxygen transport membrane enhanced integrated gasifier combined cycle (IGCC)
EP3201146A4 (en) * 2014-10-01 2018-06-13 Saint-Gobain Ceramics and Plastics, Inc. Methods of forming a glass composition
WO2016057164A1 (en) 2014-10-07 2016-04-14 Praxair Technology, Inc Composite oxygen ion transport membrane
JP6305315B2 (ja) * 2014-11-05 2018-04-04 株式会社ノリタケカンパニーリミテド 耐熱性ガラス封止材料およびその利用
DE102015207285B4 (de) 2015-04-22 2019-05-02 Schott Ag Glasiges oder zumindest teilweise kristallisiertes Einschmelzmaterial, Fügeverbindung, Sperrschicht, und Schichtsystem mit dem Einschmelzmaterial und dessen Integration in Bauteilen
US10441922B2 (en) 2015-06-29 2019-10-15 Praxair Technology, Inc. Dual function composite oxygen transport membrane
KR20170032856A (ko) * 2015-09-15 2017-03-23 주식회사 엘지화학 고체산화물 연료전지 실링재용 조성물, 이를 이용한 실링재 및 이의 제조방법
US10676389B2 (en) 2015-09-29 2020-06-09 Corning Incorporated Glass article with high coefficient of thermal expansion
US10118823B2 (en) 2015-12-15 2018-11-06 Praxair Technology, Inc. Method of thermally-stabilizing an oxygen transport membrane-based reforming system
WO2017112677A1 (en) * 2015-12-21 2017-06-29 Praxair Technology, Inc. Apparatus including a ceramic component, a metal component, and a glass sealing material and a process of forming the apparatus
US9938146B2 (en) 2015-12-28 2018-04-10 Praxair Technology, Inc. High aspect ratio catalytic reactor and catalyst inserts therefor
JP6636814B2 (ja) * 2016-02-09 2020-01-29 株式会社ノリタケカンパニーリミテド ガラス組成物およびその利用
CN109070014A (zh) 2016-04-01 2018-12-21 普莱克斯技术有限公司 含催化剂的氧气传送膜
WO2017181191A1 (en) 2016-04-15 2017-10-19 The Penn State Research Foundation Advanced ceramics to glass joints
US10873092B2 (en) 2017-02-27 2020-12-22 Bloom Energy Corporation Fuel cell interconnect with reduced voltage degradation and manufacturing method
US11335914B2 (en) 2017-02-27 2022-05-17 Bloom Energy Corporation Fuel cell interconnect with iron rich rib regions and method of making thereof
KR102008063B1 (ko) * 2017-10-23 2019-08-06 엘지전자 주식회사 글래스 프릿 조성물
US11136238B2 (en) 2018-05-21 2021-10-05 Praxair Technology, Inc. OTM syngas panel with gas heated reformer
CN114956581A (zh) 2021-02-26 2022-08-30 康宁股份有限公司 通过玻璃料的增材制造得到的致密玻璃陶瓷制品
EP4092000B1 (en) 2021-05-17 2025-04-16 sunfire GmbH Glass ceramic sealing composition

Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5747777A (en) * 1980-09-03 1982-03-18 Ngk Insulators Ltd Low heat expansion ceramic product and manufacture
JPS57126058A (en) * 1980-12-20 1982-08-05 Soon Iiemuai Ltd Arc tube for discharge lamp
JPS59219850A (ja) * 1983-05-30 1984-12-11 Mitsubishi Electric Corp 封着物質
JPS6258563A (ja) * 1985-09-03 1987-03-14 ソ−ン　イ−エムアイ　ピ−エルシ− 高圧ハロゲン化金属放電ランプおよびその製造方法
JPH02133335A (ja) * 1988-07-12 1990-05-22 Thorn Emi Plc シーリング組成物およびこれを用いた放電ランプ用アークチューブ
JPH0393675A (ja) * 1989-09-05 1991-04-18 Corning Inc セラミック複合物のための結合フリットおよびそれを用いたシール方法
JPH04187571A (ja) * 1990-11-22 1992-07-06 Ngk Insulators Ltd ガラス接合体およびその製造法

Family Cites Families (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB1019821A (en) * 1962-04-03 1966-02-09 Philips Electronic Associated Improvements in methods of bonding refractory bodies
JPS55140732A (en) 1979-04-19 1980-11-04 Chloride Silent Power Ltd Sealing glass
US5298138A (en) * 1992-02-28 1994-03-29 Ceramatec, Inc. Solid electrolyte ion conducting device
US5273837A (en) * 1992-12-23 1993-12-28 Corning Incorporated Solid electrolyte fuel cells
US5453331A (en) 1994-08-12 1995-09-26 University Of Chicago Compliant sealants for solid oxide fuel cells and other ceramics

Patent Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5747777A (en) * 1980-09-03 1982-03-18 Ngk Insulators Ltd Low heat expansion ceramic product and manufacture
JPS57126058A (en) * 1980-12-20 1982-08-05 Soon Iiemuai Ltd Arc tube for discharge lamp
JPS59219850A (ja) * 1983-05-30 1984-12-11 Mitsubishi Electric Corp 封着物質
JPS6258563A (ja) * 1985-09-03 1987-03-14 ソ−ン　イ−エムアイ　ピ−エルシ− 高圧ハロゲン化金属放電ランプおよびその製造方法
JPH02133335A (ja) * 1988-07-12 1990-05-22 Thorn Emi Plc シーリング組成物およびこれを用いた放電ランプ用アークチューブ
JPH0393675A (ja) * 1989-09-05 1991-04-18 Corning Inc セラミック複合物のための結合フリットおよびそれを用いたシール方法
JPH04187571A (ja) * 1990-11-22 1992-07-06 Ngk Insulators Ltd ガラス接合体およびその製造法

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