JP4813662B2 - α−オレフィンの重合又は共重合用バイメタル触媒 - Google Patents
α−オレフィンの重合又は共重合用バイメタル触媒 Download PDFInfo
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- JP4813662B2 JP4813662B2 JP2000608660A JP2000608660A JP4813662B2 JP 4813662 B2 JP4813662 B2 JP 4813662B2 JP 2000608660 A JP2000608660 A JP 2000608660A JP 2000608660 A JP2000608660 A JP 2000608660A JP 4813662 B2 JP4813662 B2 JP 4813662B2
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- Prior art keywords
- catalyst
- titanium
- polymerization
- solid component
- copolymerization
- Prior art date
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- Expired - Lifetime
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- 239000003054 catalyst Substances 0.000 title claims abstract description 108
- 238000006116 polymerization reaction Methods 0.000 title claims abstract description 47
- 239000004711 α-olefin Substances 0.000 title claims abstract description 27
- 238000007334 copolymerization reaction Methods 0.000 title claims description 29
- 239000010936 titanium Substances 0.000 claims abstract description 139
- 239000007787 solid Substances 0.000 claims abstract description 109
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims abstract description 69
- 229910052719 titanium Inorganic materials 0.000 claims abstract description 68
- 238000000034 method Methods 0.000 claims abstract description 63
- 239000011777 magnesium Substances 0.000 claims abstract description 33
- 239000000460 chlorine Substances 0.000 claims abstract description 32
- 230000008569 process Effects 0.000 claims abstract description 30
- 125000004432 carbon atom Chemical group C* 0.000 claims abstract description 28
- 229910052782 aluminium Inorganic materials 0.000 claims abstract description 25
- 229910052735 hafnium Inorganic materials 0.000 claims abstract description 23
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims abstract description 21
- VBJZVLUMGGDVMO-UHFFFAOYSA-N hafnium atom Chemical compound [Hf] VBJZVLUMGGDVMO-UHFFFAOYSA-N 0.000 claims abstract description 21
- 229910052749 magnesium Inorganic materials 0.000 claims abstract description 19
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 claims abstract description 16
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 claims abstract description 15
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- 239000002184 metal Substances 0.000 claims description 16
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 claims description 15
- 229910052726 zirconium Chemical group 0.000 claims description 14
- 125000005234 alkyl aluminium group Chemical group 0.000 claims description 13
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical group [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 claims description 12
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- ZRHOFLXFAAEXEE-UHFFFAOYSA-J butanoate;titanium(4+) Chemical compound [Ti+4].CCCC([O-])=O.CCCC([O-])=O.CCCC([O-])=O.CCCC([O-])=O ZRHOFLXFAAEXEE-UHFFFAOYSA-J 0.000 description 9
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- LIKMAJRDDDTEIG-UHFFFAOYSA-N 1-hexene Chemical compound CCCCC=C LIKMAJRDDDTEIG-UHFFFAOYSA-N 0.000 description 6
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- TVMXDCGIABBOFY-UHFFFAOYSA-N octane Chemical compound CCCCCCCC TVMXDCGIABBOFY-UHFFFAOYSA-N 0.000 description 4
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- 239000012299 nitrogen atmosphere Substances 0.000 description 1
- ZCYXXKJEDCHMGH-UHFFFAOYSA-N nonane Chemical compound CCCC[CH]CCCC ZCYXXKJEDCHMGH-UHFFFAOYSA-N 0.000 description 1
- BKIMMITUMNQMOS-UHFFFAOYSA-N normal nonane Natural products CCCCCCCCC BKIMMITUMNQMOS-UHFFFAOYSA-N 0.000 description 1
- WWZKQHOCKIZLMA-UHFFFAOYSA-N octanoic acid Chemical group CCCCCCCC(O)=O WWZKQHOCKIZLMA-UHFFFAOYSA-N 0.000 description 1
- 238000011017 operating method Methods 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- SOQBVABWOPYFQZ-UHFFFAOYSA-N oxygen(2-);titanium(4+) Chemical class [O-2].[O-2].[Ti+4] SOQBVABWOPYFQZ-UHFFFAOYSA-N 0.000 description 1
- 150000002978 peroxides Chemical class 0.000 description 1
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 1
- 239000010452 phosphate Substances 0.000 description 1
- 125000002467 phosphate group Chemical group [H]OP(=O)(O[H])O[*] 0.000 description 1
- IUGYQRQAERSCNH-UHFFFAOYSA-N pivalic acid Chemical group CC(C)(C)C(O)=O IUGYQRQAERSCNH-UHFFFAOYSA-N 0.000 description 1
- 229920001155 polypropylene Polymers 0.000 description 1
- 229920002223 polystyrene Polymers 0.000 description 1
- 239000012255 powdered metal Substances 0.000 description 1
- 230000001376 precipitating effect Effects 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 238000011002 quantification Methods 0.000 description 1
- 238000004445 quantitative analysis Methods 0.000 description 1
- 230000005855 radiation Effects 0.000 description 1
- 239000002516 radical scavenger Substances 0.000 description 1
- 150000003254 radicals Chemical class 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 229930195734 saturated hydrocarbon Natural products 0.000 description 1
- 238000007086 side reaction Methods 0.000 description 1
- 150000004760 silicates Chemical class 0.000 description 1
- 229910052710 silicon Inorganic materials 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- LIVNPJMFVYWSIS-UHFFFAOYSA-N silicon monoxide Chemical class [Si-]#[O+] LIVNPJMFVYWSIS-UHFFFAOYSA-N 0.000 description 1
- 229910052814 silicon oxide Inorganic materials 0.000 description 1
- HKZLPVFGJNLROG-UHFFFAOYSA-M silver monochloride Chemical compound [Cl-].[Ag+] HKZLPVFGJNLROG-UHFFFAOYSA-M 0.000 description 1
- URGAHOPLAPQHLN-UHFFFAOYSA-N sodium aluminosilicate Chemical compound [Na+].[Al+3].[O-][Si]([O-])=O.[O-][Si]([O-])=O URGAHOPLAPQHLN-UHFFFAOYSA-N 0.000 description 1
- 238000002798 spectrophotometry method Methods 0.000 description 1
- 238000004611 spectroscopical analysis Methods 0.000 description 1
- 125000001424 substituent group Chemical group 0.000 description 1
- 150000003512 tertiary amines Chemical class 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 1
- XJDNKRIXUMDJCW-UHFFFAOYSA-J titanium tetrachloride Chemical compound Cl[Ti](Cl)(Cl)Cl XJDNKRIXUMDJCW-UHFFFAOYSA-J 0.000 description 1
- ZWYDDDAMNQQZHD-UHFFFAOYSA-L titanium(ii) chloride Chemical compound [Cl-].[Cl-].[Ti+2] ZWYDDDAMNQQZHD-UHFFFAOYSA-L 0.000 description 1
- 238000000954 titration curve Methods 0.000 description 1
- 150000003623 transition metal compounds Chemical class 0.000 description 1
- 229920001862 ultra low molecular weight polyethylene Polymers 0.000 description 1
- ZDPHROOEEOARMN-UHFFFAOYSA-N undecanoic acid Chemical group CCCCCCCCCCC(O)=O ZDPHROOEEOARMN-UHFFFAOYSA-N 0.000 description 1
- GPPXJZIENCGNKB-UHFFFAOYSA-N vanadium Chemical compound [V]#[V] GPPXJZIENCGNKB-UHFFFAOYSA-N 0.000 description 1
- 229910052720 vanadium Inorganic materials 0.000 description 1
- PXXNTAGJWPJAGM-UHFFFAOYSA-N vertaline Natural products C1C2C=3C=C(OC)C(OC)=CC=3OC(C=C3)=CC=C3CCC(=O)OC1CC1N2CCCC1 PXXNTAGJWPJAGM-UHFFFAOYSA-N 0.000 description 1
- 229920001866 very low density polyethylene Polymers 0.000 description 1
- 239000008096 xylene Substances 0.000 description 1
- 150000003755 zirconium compounds Chemical class 0.000 description 1
- DUNKXUFBGCUVQW-UHFFFAOYSA-J zirconium tetrachloride Chemical compound Cl[Zr](Cl)(Cl)Cl DUNKXUFBGCUVQW-UHFFFAOYSA-J 0.000 description 1
Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/65—Pretreating the metal or compound covered by group C08F4/64 before the final contacting with the metal or compound covered by group C08F4/44
- C08F4/652—Pretreating with metals or metal-containing compounds
- C08F4/658—Pretreating with metals or metal-containing compounds with metals or metal-containing compounds, not provided for in a single group of groups C08F4/653 - C08F4/657
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
Applications Claiming Priority (4)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| ITMI99A000609 | 1999-03-25 | ||
| IT1999MI000609A IT1311978B1 (it) | 1999-03-25 | 1999-03-25 | Catalizzatore bimetallico per la (co) polimerizzazione dellealfa-olefine. |
| IT99A000609 | 1999-07-12 | ||
| PCT/EP2000/002471 WO2000058368A1 (en) | 1999-03-25 | 2000-03-20 | BIMETAL CATALYST FOR THE (CO)POLYMERIZATION OF α-OLEFINS |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| JP2002540259A JP2002540259A (ja) | 2002-11-26 |
| JP2002540259A5 JP2002540259A5 (https=) | 2007-05-24 |
| JP4813662B2 true JP4813662B2 (ja) | 2011-11-09 |
Family
ID=11382433
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2000608660A Expired - Lifetime JP4813662B2 (ja) | 1999-03-25 | 2000-03-20 | α−オレフィンの重合又は共重合用バイメタル触媒 |
Country Status (17)
| Country | Link |
|---|---|
| US (1) | US6723809B1 (https=) |
| EP (1) | EP1171479B1 (https=) |
| JP (1) | JP4813662B2 (https=) |
| KR (1) | KR100659418B1 (https=) |
| CN (1) | CN1219798C (https=) |
| AT (1) | ATE266678T1 (https=) |
| AU (1) | AU3813700A (https=) |
| BR (1) | BR0009305B1 (https=) |
| CA (1) | CA2367762C (https=) |
| DE (1) | DE60010689T2 (https=) |
| DK (1) | DK1171479T3 (https=) |
| ES (1) | ES2220445T3 (https=) |
| HK (1) | HK1044551A1 (https=) |
| IT (1) | IT1311978B1 (https=) |
| PT (1) | PT1171479E (https=) |
| RU (1) | RU2241006C2 (https=) |
| WO (1) | WO2000058368A1 (https=) |
Families Citing this family (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20040152590A1 (en) * | 2001-12-24 | 2004-08-05 | Gianni Collina | Ziegler natra catalyst for the polymerization of olefins |
| US7208436B2 (en) * | 2002-06-13 | 2007-04-24 | Basell Poliolenfine Italia S.R.L. | Catalyst components for the polymerization of olefins |
| CA2545785C (en) | 2003-11-14 | 2014-01-28 | Polimeri Europa S.P.A. | Improved solid catalyst component and process for the (co) polymerization of ethylene |
| US20060281879A1 (en) * | 2005-06-13 | 2006-12-14 | Univation Technologies, Llc | Catalyst compositions comprising small silica support materials and methods of use in polymerization reactions |
| CA2629550C (en) * | 2008-04-21 | 2015-03-31 | Nova Chemicals Corporation | Magnesium-titanium-hafnium for high temperature polymerization |
| US20110245070A1 (en) * | 2008-12-24 | 2011-10-06 | Basell Poliolefine Italia S.R.L. | Catalyst Components for the Polymerization of Olefins and Catalysts Therefrom Obtained |
| IT1397080B1 (it) * | 2009-11-23 | 2012-12-28 | Polimeri Europa Spa | Catalizzatore di tipo ziegler-natta per la (co)polimerizzazione delle alfa-olefine con elevata produttivita' |
| IT1403278B1 (it) * | 2010-12-20 | 2013-10-17 | Polimeri Europa Spa | Precursore di catalizzatore e catalizzatore per la (co)polimerizzazione delle alfa-olefine ad alta temperatura |
| KR102402009B1 (ko) * | 2014-07-31 | 2022-05-24 | 베르살리스 에스.피.에이. | α-올레핀의 (공)중합을 위한 고체 촉매 및 이를 제조하는 방법 |
| US9481748B2 (en) * | 2014-08-12 | 2016-11-01 | Nova Chemicals (International) S.A. | Ziegler-Natta catalyst for high temperature polymerization |
| CN104448066B (zh) * | 2014-12-16 | 2017-07-07 | 华东理工大学 | 一种负载型多金属烯烃聚合催化剂及其制备方法与应用 |
| CA3007381C (en) | 2018-06-06 | 2025-10-07 | Nova Chemicals Corporation | PREPARATION OF A ZIEGLER-NATTA CATALYST WITHOUT A FILTER (OFFLINE) |
| FR3103485B1 (fr) * | 2019-11-26 | 2023-03-24 | Ifp Energies Now | Procédé de séparation d’un effluent issu d’une étape d’oligomérisation |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS6114202A (ja) * | 1984-06-22 | 1986-01-22 | エニーヘム・ポリメーリ・エセ・ピ・ア | 触媒の製法 |
| JPH05194662A (ja) * | 1991-07-12 | 1993-08-03 | Ecp Enichem Polimeri Sarl | エチレンおよびα−オレフィンの（共）重合用触媒の固体成分 |
Family Cites Families (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| IT1240613B (it) * | 1990-03-26 | 1993-12-17 | Enichem Anic Spa | Catalizzatore supportato per la polimerizzazione e la copolimerizzazione di composti olefinicamente insaturi, e procedimento di (co) polimerizzazione impiegante lo stesso |
| EP0861853A1 (en) | 1997-02-27 | 1998-09-02 | ENICHEM S.p.A. | Catalyst and process for the syndiotactic polymerization of vinylaromatic compounds |
-
1999
- 1999-03-25 IT IT1999MI000609A patent/IT1311978B1/it active
-
2000
- 2000-03-20 US US09/926,214 patent/US6723809B1/en not_active Expired - Lifetime
- 2000-03-20 CA CA2367762A patent/CA2367762C/en not_active Expired - Lifetime
- 2000-03-20 RU RU2001126053/04A patent/RU2241006C2/ru active
- 2000-03-20 EP EP00916984A patent/EP1171479B1/en not_active Expired - Lifetime
- 2000-03-20 AT AT00916984T patent/ATE266678T1/de active
- 2000-03-20 KR KR1020017012170A patent/KR100659418B1/ko not_active Expired - Lifetime
- 2000-03-20 JP JP2000608660A patent/JP4813662B2/ja not_active Expired - Lifetime
- 2000-03-20 BR BRPI0009305-0A patent/BR0009305B1/pt not_active IP Right Cessation
- 2000-03-20 WO PCT/EP2000/002471 patent/WO2000058368A1/en not_active Ceased
- 2000-03-20 DK DK00916984T patent/DK1171479T3/da active
- 2000-03-20 PT PT00916984T patent/PT1171479E/pt unknown
- 2000-03-20 ES ES00916984T patent/ES2220445T3/es not_active Expired - Lifetime
- 2000-03-20 DE DE60010689T patent/DE60010689T2/de not_active Expired - Lifetime
- 2000-03-20 AU AU38137/00A patent/AU3813700A/en not_active Abandoned
- 2000-03-20 CN CNB008055483A patent/CN1219798C/zh not_active Expired - Lifetime
- 2000-03-20 HK HK02106209.2A patent/HK1044551A1/zh unknown
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS6114202A (ja) * | 1984-06-22 | 1986-01-22 | エニーヘム・ポリメーリ・エセ・ピ・ア | 触媒の製法 |
| JPH05194662A (ja) * | 1991-07-12 | 1993-08-03 | Ecp Enichem Polimeri Sarl | エチレンおよびα−オレフィンの（共）重合用触媒の固体成分 |
Also Published As
| Publication number | Publication date |
|---|---|
| ATE266678T1 (de) | 2004-05-15 |
| IT1311978B1 (it) | 2002-03-22 |
| CN1219798C (zh) | 2005-09-21 |
| HK1044551A1 (zh) | 2002-10-25 |
| WO2000058368A1 (en) | 2000-10-05 |
| PT1171479E (pt) | 2004-09-30 |
| RU2241006C2 (ru) | 2004-11-27 |
| KR100659418B1 (ko) | 2006-12-18 |
| CA2367762A1 (en) | 2000-10-05 |
| BR0009305A (pt) | 2001-12-18 |
| EP1171479B1 (en) | 2004-05-12 |
| ES2220445T3 (es) | 2004-12-16 |
| DE60010689D1 (de) | 2004-06-17 |
| JP2002540259A (ja) | 2002-11-26 |
| AU3813700A (en) | 2000-10-16 |
| DE60010689T2 (de) | 2005-05-19 |
| EP1171479A1 (en) | 2002-01-16 |
| DK1171479T3 (da) | 2004-09-20 |
| US6723809B1 (en) | 2004-04-20 |
| CN1345339A (zh) | 2002-04-17 |
| KR20020005629A (ko) | 2002-01-17 |
| ITMI990609A1 (it) | 2000-09-25 |
| BR0009305B1 (pt) | 2010-11-03 |
| CA2367762C (en) | 2010-10-12 |
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