CN1219798C - 用于α-烯烃(共)聚合的双金属催化剂 - Google Patents

用于α-烯烃(共)聚合的双金属催化剂 Download PDF

Info

Publication number
CN1219798C
CN1219798C CNB008055483A CN00805548A CN1219798C CN 1219798 C CN1219798 C CN 1219798C CN B008055483 A CNB008055483 A CN B008055483A CN 00805548 A CN00805548 A CN 00805548A CN 1219798 C CN1219798 C CN 1219798C
Authority
CN
China
Prior art keywords
titanium
solid catalyst
catalyst component
solid
hafnium
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
CNB008055483A
Other languages
English (en)
Chinese (zh)
Other versions
CN1345339A (zh
Inventor
F·曼寇尼
G·肯缇
A·扎尼拉托
A·默阿里
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Versalis SpA
Original Assignee
Polimeri Europa SpA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Polimeri Europa SpA filed Critical Polimeri Europa SpA
Publication of CN1345339A publication Critical patent/CN1345339A/zh
Application granted granted Critical
Publication of CN1219798C publication Critical patent/CN1219798C/zh
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Images

Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62Refractory metals or compounds thereof
    • C08F4/64Titanium, zirconium, hafnium or compounds thereof
    • C08F4/65Pretreating the metal or compound covered by group C08F4/64 before the final contacting with the metal or compound covered by group C08F4/44
    • C08F4/652Pretreating with metals or metal-containing compounds
    • C08F4/658Pretreating with metals or metal-containing compounds with metals or metal-containing compounds, not provided for in a single group of groups C08F4/653 - C08F4/657
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/16Copolymers of ethene with alpha-alkenes, e.g. EP rubbers

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
CNB008055483A 1999-03-25 2000-03-20 用于α-烯烃(共)聚合的双金属催化剂 Expired - Lifetime CN1219798C (zh)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
ITMI99A000609 1999-03-25
IT1999MI000609A IT1311978B1 (it) 1999-03-25 1999-03-25 Catalizzatore bimetallico per la (co) polimerizzazione dellealfa-olefine.

Publications (2)

Publication Number Publication Date
CN1345339A CN1345339A (zh) 2002-04-17
CN1219798C true CN1219798C (zh) 2005-09-21

Family

ID=11382433

Family Applications (1)

Application Number Title Priority Date Filing Date
CNB008055483A Expired - Lifetime CN1219798C (zh) 1999-03-25 2000-03-20 用于α-烯烃(共)聚合的双金属催化剂

Country Status (17)

Country Link
US (1) US6723809B1 (https=)
EP (1) EP1171479B1 (https=)
JP (1) JP4813662B2 (https=)
KR (1) KR100659418B1 (https=)
CN (1) CN1219798C (https=)
AT (1) ATE266678T1 (https=)
AU (1) AU3813700A (https=)
BR (1) BR0009305B1 (https=)
CA (1) CA2367762C (https=)
DE (1) DE60010689T2 (https=)
DK (1) DK1171479T3 (https=)
ES (1) ES2220445T3 (https=)
HK (1) HK1044551A1 (https=)
IT (1) IT1311978B1 (https=)
PT (1) PT1171479E (https=)
RU (1) RU2241006C2 (https=)
WO (1) WO2000058368A1 (https=)

Families Citing this family (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20040152590A1 (en) * 2001-12-24 2004-08-05 Gianni Collina Ziegler natra catalyst for the polymerization of olefins
US7208436B2 (en) * 2002-06-13 2007-04-24 Basell Poliolenfine Italia S.R.L. Catalyst components for the polymerization of olefins
CA2545785C (en) 2003-11-14 2014-01-28 Polimeri Europa S.P.A. Improved solid catalyst component and process for the (co) polymerization of ethylene
US20060281879A1 (en) * 2005-06-13 2006-12-14 Univation Technologies, Llc Catalyst compositions comprising small silica support materials and methods of use in polymerization reactions
CA2629550C (en) * 2008-04-21 2015-03-31 Nova Chemicals Corporation Magnesium-titanium-hafnium for high temperature polymerization
US20110245070A1 (en) * 2008-12-24 2011-10-06 Basell Poliolefine Italia S.R.L. Catalyst Components for the Polymerization of Olefins and Catalysts Therefrom Obtained
IT1397080B1 (it) * 2009-11-23 2012-12-28 Polimeri Europa Spa Catalizzatore di tipo ziegler-natta per la (co)polimerizzazione delle alfa-olefine con elevata produttivita'
IT1403278B1 (it) * 2010-12-20 2013-10-17 Polimeri Europa Spa Precursore di catalizzatore e catalizzatore per la (co)polimerizzazione delle alfa-olefine ad alta temperatura
KR102402009B1 (ko) * 2014-07-31 2022-05-24 베르살리스 에스.피.에이. α-올레핀의 (공)중합을 위한 고체 촉매 및 이를 제조하는 방법
US9481748B2 (en) * 2014-08-12 2016-11-01 Nova Chemicals (International) S.A. Ziegler-Natta catalyst for high temperature polymerization
CN104448066B (zh) * 2014-12-16 2017-07-07 华东理工大学 一种负载型多金属烯烃聚合催化剂及其制备方法与应用
CA3007381C (en) 2018-06-06 2025-10-07 Nova Chemicals Corporation PREPARATION OF A ZIEGLER-NATTA CATALYST WITHOUT A FILTER (OFFLINE)
FR3103485B1 (fr) * 2019-11-26 2023-03-24 Ifp Energies Now Procédé de séparation d’un effluent issu d’une étape d’oligomérisation

Family Cites Families (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
IT1176299B (it) * 1984-06-22 1987-08-18 Anic Spa Metodo per la preparazione di un catalizzatore a base di zirconio o afnio e processo di polimerizzazione o copolimerizzazione di composti insaturi impiegante lo stesso
IT1240613B (it) * 1990-03-26 1993-12-17 Enichem Anic Spa Catalizzatore supportato per la polimerizzazione e la copolimerizzazione di composti olefinicamente insaturi, e procedimento di (co) polimerizzazione impiegante lo stesso
IT1251462B (it) * 1991-07-12 1995-05-15 Enichem Polimeri Componente solido di catalizzatore per la (co)polimerizzazione dell'etilene e delle alfa olefine.
EP0861853A1 (en) 1997-02-27 1998-09-02 ENICHEM S.p.A. Catalyst and process for the syndiotactic polymerization of vinylaromatic compounds

Also Published As

Publication number Publication date
ATE266678T1 (de) 2004-05-15
IT1311978B1 (it) 2002-03-22
HK1044551A1 (zh) 2002-10-25
WO2000058368A1 (en) 2000-10-05
PT1171479E (pt) 2004-09-30
JP4813662B2 (ja) 2011-11-09
RU2241006C2 (ru) 2004-11-27
KR100659418B1 (ko) 2006-12-18
CA2367762A1 (en) 2000-10-05
BR0009305A (pt) 2001-12-18
EP1171479B1 (en) 2004-05-12
ES2220445T3 (es) 2004-12-16
DE60010689D1 (de) 2004-06-17
JP2002540259A (ja) 2002-11-26
AU3813700A (en) 2000-10-16
DE60010689T2 (de) 2005-05-19
EP1171479A1 (en) 2002-01-16
DK1171479T3 (da) 2004-09-20
US6723809B1 (en) 2004-04-20
CN1345339A (zh) 2002-04-17
KR20020005629A (ko) 2002-01-17
ITMI990609A1 (it) 2000-09-25
BR0009305B1 (pt) 2010-11-03
CA2367762C (en) 2010-10-12

Similar Documents

Publication Publication Date Title
CN1092672C (zh) 乙烯共聚物,乙烯基聚合物制备方法及所用的催化剂体系
CN1206247C (zh) 聚合方法
CN1302028C (zh) 用茚并吲哚基催化剂使烯烃聚合的方法
CN1138792C (zh) 双反应器乙烯聚合方法
CN1032540C (zh) 用于乙烯聚合反应的钛催化剂组份以及乙烯聚合反应催化剂
CN1301271C (zh) 双位烯烃聚合催化剂组合物
CN1726230A (zh) 烯烃聚合用催化剂组分
CN1160378C (zh) 用于烯烃聚合的催化剂组分和由此获得的催化剂
CN1487907A (zh) 低聚或聚合乙烯的方法
CN1219798C (zh) 用于α-烯烃(共)聚合的双金属催化剂
CN1692129A (zh) 催化剂体系和其在聚合方法中的应用
CN1187207A (zh) 不相容的聚合催化剂之间的转换方法
CN1134710A (zh) 烯烃聚合催化剂组分和催化剂
CN1382162A (zh) 催化剂体系及其在聚合反应方法中的应用
CN1691979A (zh) 具有高活性的双金属催化剂
CN1307594A (zh) 负载型烯烃聚合催化剂组合物
CN1146583C (zh) 载体上的二齿和三齿催化剂组合物及使用该组合物的烯烃聚合
CN100339403C (zh) 用于烯烃聚合的卤代催化剂体系
CN1142788A (zh) 烯烃聚合反应的催化剂及其制造方法
CN1596271A (zh) 用非单中心/单中心催化剂结合物制备的乙烯/α-烯烃共聚物及其制备方法和用途
CN1029607C (zh) 生产氯化镁微粒的方法
CN1168745C (zh) 烯烃聚合方法
CN1238359C (zh) 混合金属烷氧基配合物及由其制备的聚合催化剂
CN87103866A (zh) 一种制备低或中密度的直链聚乙烯的方法以及适合于该目的催化剂
CN1481280A (zh) 催化剂负载方法及用负载催化剂的聚合

Legal Events

Date Code Title Description
C10 Entry into substantive examination
SE01 Entry into force of request for substantive examination
C06 Publication
PB01 Publication
C14 Grant of patent or utility model
GR01 Patent grant
REG Reference to a national code

Ref country code: HK

Ref legal event code: WD

Ref document number: 1044551

Country of ref document: HK

CX01 Expiry of patent term
CX01 Expiry of patent term

Granted publication date: 20050921