JP4694344B2 - 室温硬化性ポリオルガノシロキサン組成物の製造方法 - Google Patents
室温硬化性ポリオルガノシロキサン組成物の製造方法 Download PDFInfo
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- 239000000203 mixture Substances 0.000 title claims description 47
- 238000004519 manufacturing process Methods 0.000 title claims description 8
- -1 polyol compound Chemical class 0.000 claims description 23
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 15
- 238000002156 mixing Methods 0.000 claims description 13
- 229920005862 polyol Polymers 0.000 claims description 8
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims description 7
- 239000003054 catalyst Substances 0.000 claims description 6
- 239000003431 cross linking reagent Substances 0.000 claims description 5
- 229910021485 fumed silica Inorganic materials 0.000 claims description 5
- 125000003808 silyl group Chemical group [H][Si]([H])([H])[*] 0.000 claims description 5
- 229920002379 silicone rubber Polymers 0.000 description 11
- 230000000694 effects Effects 0.000 description 10
- 150000001875 compounds Chemical class 0.000 description 9
- 239000004945 silicone rubber Substances 0.000 description 9
- 229920001451 polypropylene glycol Polymers 0.000 description 7
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 description 6
- 230000000052 comparative effect Effects 0.000 description 6
- 238000000034 method Methods 0.000 description 6
- 229910000077 silane Inorganic materials 0.000 description 6
- 239000003795 chemical substances by application Substances 0.000 description 5
- 229920001971 elastomer Polymers 0.000 description 5
- 238000004898 kneading Methods 0.000 description 5
- 239000000377 silicon dioxide Substances 0.000 description 5
- OGZPYBBKQGPQNU-DABLZPOSSA-N (e)-n-[bis[[(e)-butan-2-ylideneamino]oxy]-methylsilyl]oxybutan-2-imine Chemical compound CC\C(C)=N\O[Si](C)(O\N=C(/C)CC)O\N=C(/C)CC OGZPYBBKQGPQNU-DABLZPOSSA-N 0.000 description 4
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 3
- UKLDJPRMSDWDSL-UHFFFAOYSA-L [dibutyl(dodecanoyloxy)stannyl] dodecanoate Chemical compound CCCCCCCCCCCC(=O)O[Sn](CCCC)(CCCC)OC(=O)CCCCCCCCCCC UKLDJPRMSDWDSL-UHFFFAOYSA-L 0.000 description 3
- 239000012975 dibutyltin dilaurate Substances 0.000 description 3
- BFXIKLCIZHOAAZ-UHFFFAOYSA-N methyltrimethoxysilane Chemical compound CO[Si](C)(OC)OC BFXIKLCIZHOAAZ-UHFFFAOYSA-N 0.000 description 3
- 230000002265 prevention Effects 0.000 description 3
- 230000003449 preventive effect Effects 0.000 description 3
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 description 2
- KHLRJDNGHBXOSV-UHFFFAOYSA-N 5-trimethoxysilylpentane-1,3-diamine Chemical compound CO[Si](OC)(OC)CCC(N)CCN KHLRJDNGHBXOSV-UHFFFAOYSA-N 0.000 description 2
- 239000004215 Carbon black (E152) Substances 0.000 description 2
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- 239000004944 Liquid Silicone Rubber Substances 0.000 description 2
- BOTDANWDWHJENH-UHFFFAOYSA-N Tetraethyl orthosilicate Chemical compound CCO[Si](OCC)(OCC)OCC BOTDANWDWHJENH-UHFFFAOYSA-N 0.000 description 2
- PXAJQJMDEXJWFB-UHFFFAOYSA-N acetone oxime Chemical compound CC(C)=NO PXAJQJMDEXJWFB-UHFFFAOYSA-N 0.000 description 2
- 125000000217 alkyl group Chemical group 0.000 description 2
- 230000000740 bleeding effect Effects 0.000 description 2
- 238000001816 cooling Methods 0.000 description 2
- 229920001577 copolymer Polymers 0.000 description 2
- 239000004205 dimethyl polysiloxane Substances 0.000 description 2
- 235000013870 dimethyl polysiloxane Nutrition 0.000 description 2
- KPUWHANPEXNPJT-UHFFFAOYSA-N disiloxane Chemical class [SiH3]O[SiH3] KPUWHANPEXNPJT-UHFFFAOYSA-N 0.000 description 2
- 239000003063 flame retardant Substances 0.000 description 2
- 229930195733 hydrocarbon Natural products 0.000 description 2
- 150000002430 hydrocarbons Chemical class 0.000 description 2
- 239000004014 plasticizer Substances 0.000 description 2
- 229920000435 poly(dimethylsiloxane) Polymers 0.000 description 2
- 150000003077 polyols Chemical class 0.000 description 2
- 239000000047 product Substances 0.000 description 2
- 238000007789 sealing Methods 0.000 description 2
- 239000003566 sealing material Substances 0.000 description 2
- 238000000926 separation method Methods 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- 238000003860 storage Methods 0.000 description 2
- 229910052719 titanium Inorganic materials 0.000 description 2
- 239000010936 titanium Substances 0.000 description 2
- VXUYXOFXAQZZMF-UHFFFAOYSA-N titanium(IV) isopropoxide Chemical compound CC(C)O[Ti](OC(C)C)(OC(C)C)OC(C)C VXUYXOFXAQZZMF-UHFFFAOYSA-N 0.000 description 2
- OVSGBKZKXUMMHS-VGKOASNMSA-L (z)-4-oxopent-2-en-2-olate;propan-2-olate;titanium(4+) Chemical compound [Ti+4].CC(C)[O-].CC(C)[O-].C\C([O-])=C\C(C)=O.C\C([O-])=C\C(C)=O OVSGBKZKXUMMHS-VGKOASNMSA-L 0.000 description 1
- TYKCBTYOMAUNLH-MTOQALJVSA-J (z)-4-oxopent-2-en-2-olate;titanium(4+) Chemical compound [Ti+4].C\C([O-])=C\C(C)=O.C\C([O-])=C\C(C)=O.C\C([O-])=C\C(C)=O.C\C([O-])=C\C(C)=O TYKCBTYOMAUNLH-MTOQALJVSA-J 0.000 description 1
- 125000003903 2-propenyl group Chemical group [H]C([*])([H])C([H])=C([H])[H] 0.000 description 1
- SXFJDZNJHVPHPH-UHFFFAOYSA-N 3-methylpentane-1,5-diol Chemical compound OCCC(C)CCO SXFJDZNJHVPHPH-UHFFFAOYSA-N 0.000 description 1
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 description 1
- ALQSHHUCVQOPAS-UHFFFAOYSA-N Pentane-1,5-diol Chemical compound OCCCCCO ALQSHHUCVQOPAS-UHFFFAOYSA-N 0.000 description 1
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 1
- 239000002202 Polyethylene glycol Substances 0.000 description 1
- 239000004743 Polypropylene Substances 0.000 description 1
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 1
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 description 1
- JJLKTTCRRLHVGL-UHFFFAOYSA-L [acetyloxy(dibutyl)stannyl] acetate Chemical compound CC([O-])=O.CC([O-])=O.CCCC[Sn+2]CCCC JJLKTTCRRLHVGL-UHFFFAOYSA-L 0.000 description 1
- CQQXCSFSYHAZOO-UHFFFAOYSA-L [acetyloxy(dioctyl)stannyl] acetate Chemical compound CCCCCCCC[Sn](OC(C)=O)(OC(C)=O)CCCCCCCC CQQXCSFSYHAZOO-UHFFFAOYSA-L 0.000 description 1
- NOZAQBYNLKNDRT-UHFFFAOYSA-N [diacetyloxy(ethenyl)silyl] acetate Chemical compound CC(=O)O[Si](OC(C)=O)(OC(C)=O)C=C NOZAQBYNLKNDRT-UHFFFAOYSA-N 0.000 description 1
- TVJPBVNWVPUZBM-UHFFFAOYSA-N [diacetyloxy(methyl)silyl] acetate Chemical compound CC(=O)O[Si](C)(OC(C)=O)OC(C)=O TVJPBVNWVPUZBM-UHFFFAOYSA-N 0.000 description 1
- NBJODVYWAQLZOC-UHFFFAOYSA-L [dibutyl(octanoyloxy)stannyl] octanoate Chemical compound CCCCCCCC(=O)O[Sn](CCCC)(CCCC)OC(=O)CCCCCCC NBJODVYWAQLZOC-UHFFFAOYSA-L 0.000 description 1
- XQBCVRSTVUHIGH-UHFFFAOYSA-L [dodecanoyloxy(dioctyl)stannyl] dodecanoate Chemical compound CCCCCCCCCCCC(=O)O[Sn](CCCCCCCC)(CCCCCCCC)OC(=O)CCCCCCCCCCC XQBCVRSTVUHIGH-UHFFFAOYSA-L 0.000 description 1
- 125000003668 acetyloxy group Chemical group [H]C([H])([H])C(=O)O[*] 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 239000002318 adhesion promoter Substances 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- 125000003342 alkenyl group Chemical group 0.000 description 1
- 125000003545 alkoxy group Chemical group 0.000 description 1
- 229940121375 antifungal agent Drugs 0.000 description 1
- 239000003429 antifungal agent Substances 0.000 description 1
- 229910052787 antimony Inorganic materials 0.000 description 1
- WATWJIUSRGPENY-UHFFFAOYSA-N antimony atom Chemical compound [Sb] WATWJIUSRGPENY-UHFFFAOYSA-N 0.000 description 1
- 229920005601 base polymer Polymers 0.000 description 1
- 229910052797 bismuth Inorganic materials 0.000 description 1
- JCXGWMGPZLAOME-UHFFFAOYSA-N bismuth atom Chemical compound [Bi] JCXGWMGPZLAOME-UHFFFAOYSA-N 0.000 description 1
- FPCJKVGGYOAWIZ-UHFFFAOYSA-N butan-1-ol;titanium Chemical compound [Ti].CCCCO.CCCCO.CCCCO.CCCCO FPCJKVGGYOAWIZ-UHFFFAOYSA-N 0.000 description 1
- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 150000007942 carboxylates Chemical class 0.000 description 1
- 239000013522 chelant Substances 0.000 description 1
- 239000007795 chemical reaction product Substances 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 238000013329 compounding Methods 0.000 description 1
- 238000006482 condensation reaction Methods 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- NHWNGVQMIQXKCB-UHFFFAOYSA-N dimethoxy(dimethyl)stannane Chemical compound CO[Sn](C)(C)OC NHWNGVQMIQXKCB-UHFFFAOYSA-N 0.000 description 1
- 229920005645 diorganopolysiloxane polymer Polymers 0.000 description 1
- 230000005611 electricity Effects 0.000 description 1
- NKSJNEHGWDZZQF-UHFFFAOYSA-N ethenyl(trimethoxy)silane Chemical compound CO[Si](OC)(OC)C=C NKSJNEHGWDZZQF-UHFFFAOYSA-N 0.000 description 1
- WOXXJEVNDJOOLV-UHFFFAOYSA-N ethenyl-tris(2-methoxyethoxy)silane Chemical compound COCCO[Si](OCCOC)(OCCOC)C=C WOXXJEVNDJOOLV-UHFFFAOYSA-N 0.000 description 1
- UWCPZRQFZJPWBK-UHFFFAOYSA-N ethyl 3-oxobutanoate titanium Chemical compound [Ti].C(C)OC(CC(=O)C)=O.[Ti] UWCPZRQFZJPWBK-UHFFFAOYSA-N 0.000 description 1
- WIEGKKSLPGLWRN-UHFFFAOYSA-N ethyl 3-oxobutanoate;titanium Chemical compound [Ti].CCOC(=O)CC(C)=O WIEGKKSLPGLWRN-UHFFFAOYSA-N 0.000 description 1
- XYIBRDXRRQCHLP-UHFFFAOYSA-N ethyl acetoacetate Chemical compound CCOC(=O)CC(C)=O XYIBRDXRRQCHLP-UHFFFAOYSA-N 0.000 description 1
- 229940093858 ethyl acetoacetate Drugs 0.000 description 1
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 125000006038 hexenyl group Chemical group 0.000 description 1
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 1
- 230000001771 impaired effect Effects 0.000 description 1
- 239000003112 inhibitor Substances 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 229940049920 malate Drugs 0.000 description 1
- BJEPYKJPYRNKOW-UHFFFAOYSA-N malic acid Chemical compound OC(=O)C(O)CC(O)=O BJEPYKJPYRNKOW-UHFFFAOYSA-N 0.000 description 1
- 229910052748 manganese Inorganic materials 0.000 description 1
- 239000011572 manganese Substances 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
- QFWAHMAYYWUGTI-UHFFFAOYSA-N methyl-tris(prop-1-enoxy)silane Chemical compound CC=CO[Si](C)(OC=CC)OC=CC QFWAHMAYYWUGTI-UHFFFAOYSA-N 0.000 description 1
- 125000002347 octyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 125000000962 organic group Chemical group 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 150000001367 organochlorosilanes Chemical class 0.000 description 1
- 150000002923 oximes Chemical class 0.000 description 1
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 1
- 229920001223 polyethylene glycol Polymers 0.000 description 1
- 229920001155 polypropylene Polymers 0.000 description 1
- 229920001296 polysiloxane Polymers 0.000 description 1
- 238000004382 potting Methods 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- YNKIIBQOKMXIGH-UHFFFAOYSA-N propan-2-yl 3-oxohexaneperoxoate;titanium Chemical compound [Ti].CCCC(=O)CC(=O)OOC(C)C.CCCC(=O)CC(=O)OOC(C)C YNKIIBQOKMXIGH-UHFFFAOYSA-N 0.000 description 1
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 239000012779 reinforcing material Substances 0.000 description 1
- 238000007665 sagging Methods 0.000 description 1
- 125000004469 siloxy group Chemical group [SiH3]O* 0.000 description 1
- 125000000547 substituted alkyl group Chemical group 0.000 description 1
- ZQZCOBSUOFHDEE-UHFFFAOYSA-N tetrapropyl silicate Chemical compound CCCO[Si](OCCC)(OCCC)OCCC ZQZCOBSUOFHDEE-UHFFFAOYSA-N 0.000 description 1
- 239000013008 thixotropic agent Substances 0.000 description 1
- 229910052718 tin Inorganic materials 0.000 description 1
- KSBAEPSJVUENNK-UHFFFAOYSA-L tin(ii) 2-ethylhexanoate Chemical compound [Sn+2].CCCCC(CC)C([O-])=O.CCCCC(CC)C([O-])=O KSBAEPSJVUENNK-UHFFFAOYSA-L 0.000 description 1
- 150000003609 titanium compounds Chemical class 0.000 description 1
- 125000003944 tolyl group Chemical group 0.000 description 1
- OLTVTFUBQOLTND-UHFFFAOYSA-N tris(2-methoxyethoxy)-methylsilane Chemical compound COCCO[Si](C)(OCCOC)OCCOC OLTVTFUBQOLTND-UHFFFAOYSA-N 0.000 description 1
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 1
- 229910052726 zirconium Inorganic materials 0.000 description 1
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- Processes Of Treating Macromolecular Substances (AREA)
- Sealing Material Composition (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Description
(A)両末端が水酸基または/および反応性の加水分解性シリル基で封鎖された、25℃における粘度が5〜100Pa・sのポリオルガノシロキサン100重量部
(B)比表面積が50m2/g以上のヒュームドシリカ5〜20重量部
(C)分子量が100〜270の有機ポリオール化合物0.1〜0.9重量部
(D)架橋剤0.1〜10重量部
(E)硬化触媒0.01〜5重量部
を含有する室温硬化性ポリオルガノシロキサン組成物の製造方法であって、
(E)成分を配合する前の時点に(C)成分を40〜200℃に加熱した状態で混合することを特徴とする室温硬化性ポリオルガノシロキサン組成物の製造方法である。
HO(CH2CH2O)nH(n=2〜5) (式1)
(式2)、(式3)で示されるポリオキシプロピレングリコール
HO(CH2CH2CH2O)pH(p=2〜4) (式2)
HO(CH2C(CH3)HO)pH(p=2〜4) (式3)
実施例1
粘度17Pa・sのα、ω−ジヒドロキシメチルポリシロキサン100部に、メチルトリス(メチルエチルケトオキシム)シラン5部、ビニルトリス(メチルエチルケトオキシムシラン1部、分子量250のポリプロピレングリコール0.5部、比表面積200m2/gのテトラマー処理乾式シリカ14部を添加し、釜温60℃で30分間減圧加熱混練りを行った。その後、エクソールD(エクソン社製、炭化水素系溶剤)を10部添加し、30分室温付近まで冷却した後、γ−(2−アミノエチル)アミノプロピルトリメトキシシラン1部、メチルトリス(メチルエチルケトオキシム)シラン2部、ジブチルスズジラウレート0.05部を均一に混合し、組成物を調製した。
実施例2
粘度40Pa・sの両末端メチルジメトキシシリル基メチルポリシロキサン100部に、ジメチルポリシロキサンを10部、分子量200のポリエチレングリコール0.5部、比表面積200m2/gのテトラマー処理乾式シリカ14部を添加し、釜温40℃で30分間減圧加熱混練りを行った後、メチルトリメトキシシラン5部、チタンエチルアセトアセテート2部、メチルトリメトキシシラン5部を均一に混合し、その後15分室温付近まで冷却混練した後、組成物を取り出した。
比較例1
実施例1において、分子量250のポリプロピレングリコールに代えて分子量2000のものを用いた以外は同様にして組成物を調製した。
比較例2
実施例1において、分子量250のポリプロピレングリコールに代えてモノオール化合物CH3(C3H6O)2OHを用いた以外は同様にして組成物を調製した。
比較例3
実施例1において、分子量250のポリプロピレングリコールを加熱混練りせずに、γ−(2−アミノエチル)アミノプロピルトリメトキシシラン1部、メチルトリス(メチルエチルケトオキシム)シラン2部、ジブチルスズジラウレート0.05部と一緒に混合し、組成物を調製した。
比較例4
実施例1において、分子量250のポリプロピレングリコールの配合量を1部とした以外は同様にして組成物を調製した。
比較例5
実施例1において、分子量250のポリプロピレングリコールに代えて粘度17Pa・sのα、ω−ジヒドロキシジメチルポリシロキサンを用いた以外は同様にして組成物を調製した。
Claims (1)
- (A)両末端が水酸基または/および反応性の加水分解性シリル基で封鎖された、25℃における粘度が5〜100Pa・sのポリオルガノシロキサン100重量部
(B)比表面積が50m2/g以上のヒュームドシリカ5〜20重量部
(C)分子量が100〜270の有機ポリオール化合物0.1〜0.9重量部
(D)架橋剤0.1〜10重量部
(E)硬化触媒0.01〜5重量部
を含有する室温硬化性ポリオルガノシロキサン組成物の製造方法であって、
(E)成分を配合する前の時点に(C)成分を40〜200℃に加熱した状態で混合することを特徴とする室温硬化性ポリオルガノシロキサン組成物の製造方法。
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CN104487519B (zh) * | 2012-07-27 | 2016-09-28 | 迈图高新材料日本合同公司 | 室温固化性聚有机硅氧烷组合物和电气·电子装置 |
HUE064593T2 (hu) | 2015-05-27 | 2024-03-28 | Univ Danmarks Tekniske | Szilikon elasztomerek, ezek elõállítása és alkalmazása |
US20190390083A1 (en) * | 2017-01-30 | 2019-12-26 | Dow Toray Co., Ltd. | Coating agent for concrete structures |
US20200268932A1 (en) * | 2019-02-22 | 2020-08-27 | Arsenal Aaa, Llc. | Crosslinkable polymer compositions |
Citations (7)
Publication number | Priority date | Publication date | Assignee | Title |
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JPS56853A (en) * | 1979-04-30 | 1981-01-07 | Gen Electric | Silicone composition* its manufacture and use |
JPS6018545A (ja) * | 1983-07-11 | 1985-01-30 | Toshiba Silicone Co Ltd | 接着性ポリオルガノシロキサン組成物 |
JPH0198686A (ja) * | 1987-10-13 | 1989-04-17 | Toshiba Silicone Co Ltd | シーリング材の低温時の硬化性を改良する方法 |
JPH0241361A (ja) * | 1988-07-30 | 1990-02-09 | Toshiba Silicone Co Ltd | 室温硬化性ポリオルガノシロキサン組成物の製造方法 |
JPH0543803A (ja) * | 1982-02-17 | 1993-02-23 | General Electric Co <Ge> | 低モジユラス1成分型rtv組成物およびその製造方法 |
JPH111617A (ja) * | 1997-06-13 | 1999-01-06 | Shin Etsu Chem Co Ltd | 室温硬化性シリコーンゴム組成物の連続的製造方法 |
JP2005213487A (ja) * | 2004-02-02 | 2005-08-11 | Ge Toshiba Silicones Co Ltd | 室温硬化性ポリオルガノシロキサン組成物 |
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JPS56853A (en) * | 1979-04-30 | 1981-01-07 | Gen Electric | Silicone composition* its manufacture and use |
JPH0543803A (ja) * | 1982-02-17 | 1993-02-23 | General Electric Co <Ge> | 低モジユラス1成分型rtv組成物およびその製造方法 |
JPS6018545A (ja) * | 1983-07-11 | 1985-01-30 | Toshiba Silicone Co Ltd | 接着性ポリオルガノシロキサン組成物 |
JPH0198686A (ja) * | 1987-10-13 | 1989-04-17 | Toshiba Silicone Co Ltd | シーリング材の低温時の硬化性を改良する方法 |
JPH0241361A (ja) * | 1988-07-30 | 1990-02-09 | Toshiba Silicone Co Ltd | 室温硬化性ポリオルガノシロキサン組成物の製造方法 |
JPH111617A (ja) * | 1997-06-13 | 1999-01-06 | Shin Etsu Chem Co Ltd | 室温硬化性シリコーンゴム組成物の連続的製造方法 |
JP2005213487A (ja) * | 2004-02-02 | 2005-08-11 | Ge Toshiba Silicones Co Ltd | 室温硬化性ポリオルガノシロキサン組成物 |
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