JP4658326B2 - 橋架けメタロセン、製造法、触媒系での使用 - Google Patents

橋架けメタロセン、製造法、触媒系での使用 Download PDF

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Publication number
JP4658326B2
JP4658326B2 JP2000583916A JP2000583916A JP4658326B2 JP 4658326 B2 JP4658326 B2 JP 4658326B2 JP 2000583916 A JP2000583916 A JP 2000583916A JP 2000583916 A JP2000583916 A JP 2000583916A JP 4658326 B2 JP4658326 B2 JP 4658326B2
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JP
Japan
Prior art keywords
indenyl
dimethyl
formula
propanediylbis
zirconium dichloride
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
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JP2000583916A
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English (en)
Japanese (ja)
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JP2002530413A5 (enExample
JP2002530413A (ja
Inventor
ダロッコ，チジアノ
ダン，バ，アン
ユゥ，リン−チェン
レスコニ，ルイジ
バルボニ，ダビデ
ボスカラト，アセッシア
シャベリエン，コリン，ジェイ
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Basell Technology Co BV
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Basell Technology Co BV
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Publication of JP2002530413A5 publication Critical patent/JP2002530413A5/ja
Application granted granted Critical
Publication of JP4658326B2 publication Critical patent/JP4658326B2/ja
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F10/02—Ethene
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C13/00—Cyclic hydrocarbons containing rings other than, or in addition to, six-membered aromatic rings
    • C07C13/28—Polycyclic hydrocarbons or acyclic hydrocarbon derivatives thereof
    • C07C13/32—Polycyclic hydrocarbons or acyclic hydrocarbon derivatives thereof with condensed rings
    • C07C13/45—Polycyclic hydrocarbons or acyclic hydrocarbon derivatives thereof with condensed rings with a bicyclo ring system containing nine carbon atoms
    • C07C13/465—Indenes; Completely or partially hydrogenated indenes
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F17/00—Metallocenes
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2602/00—Systems containing two condensed rings
    • C07C2602/02—Systems containing two condensed rings the rings having only two atoms in common
    • C07C2602/04—One of the condensed rings being a six-membered aromatic ring
    • C07C2602/08—One of the condensed rings being a six-membered aromatic ring the other ring being five-membered, e.g. indane
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/02—Ethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65908—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an ionising compound other than alumoxane, e.g. (C6F5)4B-X+
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S526/943—Polymerization with metallocene catalysts

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
JP2000583916A 1998-11-20 1999-11-03 橋架けメタロセン、製造法、触媒系での使用 Expired - Fee Related JP4658326B2 (ja)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
EP98203912.5 1998-11-20
EP98203912 1998-11-20
PCT/EP1999/008378 WO2000031088A1 (en) 1998-11-20 1999-11-03 Bridged metallocenes, preparation, use in catalytic systems

Publications (3)

Publication Number Publication Date
JP2002530413A JP2002530413A (ja) 2002-09-17
JP2002530413A5 JP2002530413A5 (enExample) 2006-12-21
JP4658326B2 true JP4658326B2 (ja) 2011-03-23

Family

ID=8234360

Family Applications (1)

Application Number Title Priority Date Filing Date
JP2000583916A Expired - Fee Related JP4658326B2 (ja) 1998-11-20 1999-11-03 橋架けメタロセン、製造法、触媒系での使用

Country Status (15)

Country Link
US (1) US6433203B1 (enExample)
EP (1) EP1049704B1 (enExample)
JP (1) JP4658326B2 (enExample)
KR (1) KR20010034199A (enExample)
CN (1) CN1293677A (enExample)
AR (1) AR021294A1 (enExample)
AT (1) ATE300549T1 (enExample)
AU (1) AU6476799A (enExample)
BR (1) BR9909744A (enExample)
CA (1) CA2317485A1 (enExample)
DE (1) DE69926339T2 (enExample)
HU (1) HUP0101144A2 (enExample)
IL (1) IL137158A0 (enExample)
WO (1) WO2000031088A1 (enExample)
ZA (1) ZA200003797B (enExample)

Families Citing this family (20)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20060293470A1 (en) * 2005-06-28 2006-12-28 Cao Phuong A Polymerization process using spray-dried catalyst
US8497330B2 (en) * 1997-12-08 2013-07-30 Univation Technologies, Llc Methods for polymerization using spray dried and slurried catalyst
US6242545B1 (en) * 1997-12-08 2001-06-05 Univation Technologies Polymerization catalyst systems comprising substituted hafinocenes
JP2002256012A (ja) * 2001-02-28 2002-09-11 Inst Of Physical & Chemical Res 重合用触媒
US7060765B2 (en) 2001-07-19 2006-06-13 Univation Technologies, Llc Low comonomer incorporating metallocene catalyst compounds
US6936675B2 (en) 2001-07-19 2005-08-30 Univation Technologies, Llc High tear films from hafnocene catalyzed polyethylenes
BR0211286B1 (pt) 2001-07-19 2012-10-02 filmes com propriedades fìsicas aperfeiçoadas.
WO2003008468A2 (en) 2001-07-19 2003-01-30 Univation Technologies, Llc Mixed metallocene catalyst systems containing a poor comonomer incorporator and a good comonomer incorporator
CA2412488C (en) * 2001-12-11 2009-09-08 Crompton Gmbh Process for preparing partial hydrolysates of organometallic compounds or transition metal catalysts immobilized on inert support materials
US6875828B2 (en) 2002-09-04 2005-04-05 Univation Technologies, Llc Bimodal polyolefin production process and films therefrom
US6884748B2 (en) 2002-09-04 2005-04-26 Univation Technologies, Llc Process for producing fluorinated catalysts
US6753390B2 (en) 2002-09-04 2004-06-22 Univation Technologies, Llc Gas phase polymerization process
US6812183B1 (en) * 2003-04-23 2004-11-02 Equistar Chemicals, Lp Triple-decker catalysts based on delocalized dianionic ligands
JP4940649B2 (ja) * 2005-12-19 2012-05-30 東ソー株式会社 エチレン系重合体製造用触媒およびエチレン系重合体の製造方法
EP1964860B1 (en) 2005-12-19 2017-07-05 Tosoh Corporation Ethylene polymer, catalyst for production of ethylene polymer, and process for production of ethylene polymer
KR100864313B1 (ko) * 2007-05-21 2008-10-20 한국화학연구원 불포화 금속자리를 갖는 다공성 유-무기 혼성체 또는메조세공체의 표면 기능화 및 그의 응용
CN101815727B (zh) * 2007-08-27 2013-05-15 保瑞利斯科技公司 催化剂
ATE547439T1 (de) * 2007-10-25 2012-03-15 Lummus Novolen Technology Gmbh Racemoselektive synthese von ansa-metallocen- verbindungen, ansa-metallocen-verbindungen, diese enthaltende katalysatoren, verfahren zur herstellung eines olefinpolymers durch verwendung der katalysatoren und olefinhomopolymere und - copolymere
US8435911B2 (en) 2008-10-16 2013-05-07 Basell Polyolefine Gmbh Hybrid catalyst composition for polymerization of olefins
KR101549206B1 (ko) 2012-05-08 2015-09-02 주식회사 엘지화학 안사-메탈로센 화합물 및 이를 이용한 담지 촉매의 제조방법

Family Cites Families (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
ZA844157B (en) 1983-06-06 1986-01-29 Exxon Research Engineering Co Process and catalyst for polyolefin density and molecular weight control
JPH0745543B2 (ja) 1987-07-31 1995-05-17 チッソ株式会社 オレフィン重合体の製造方法
JPH0725821B2 (ja) 1987-08-03 1995-03-22 チッソ株式会社 ポリオレフィンの製造方法
DE3836059A1 (de) 1988-10-22 1990-05-03 Hoechst Ag Verfahren zur herstellung eines ethylen-propylen-copolymers
DE3916555A1 (de) 1989-05-20 1990-11-22 Hoechst Ag Verfahren zur herstellung von ethylenpolymeren
FR2666142B2 (fr) 1989-10-30 1994-09-16 Lacroix E Tous Artifices Perfectionnements aux sytemes d'arme munis d'un dispositif d'amortissement.
DE4017331A1 (de) * 1990-05-30 1991-12-05 Hoechst Ag Verfahren zur herstellung eines polyolefins
IT1270253B (it) 1994-06-20 1997-04-29 Spherilene Srl Copolimeri dell'etilene e procedimento per la preparazione di polimeri dell'etilene
IT1275777B1 (it) * 1995-07-06 1997-10-17 Enichem Spa Catalizzatore metallocenico per la (co)polimerizzazione delle olefine
US5744415A (en) 1995-12-28 1998-04-28 Union Carbide Chemicals & Plastics Technology Corporation Rare earth metal catalyst for olefin polymerization
IT1283630B1 (it) * 1996-05-09 1998-04-23 Enichem Spa Procedimento per la preparazione di copolimeri elastomerici ep(d)m
EP0914323B1 (en) * 1997-03-29 2003-08-06 Basell Polyolefine GmbH Metallocenes and catalysts for polymerization of olefins
IT1298616B1 (it) * 1998-03-10 2000-01-12 Enichem Spa Complesso metallocenico pontato per la (co) polimerizzazione delle olefine
DE19823168A1 (de) 1998-05-23 1999-11-25 Aventis Res & Tech Gmbh & Co Katalysatorsystem

Also Published As

Publication number Publication date
HUP0101144A2 (hu) 2001-07-30
EP1049704A1 (en) 2000-11-08
IL137158A0 (en) 2001-07-24
WO2000031088A1 (en) 2000-06-02
DE69926339D1 (de) 2005-09-01
DE69926339T2 (de) 2006-01-26
AR021294A1 (es) 2002-07-03
EP1049704B1 (en) 2005-07-27
BR9909744A (pt) 2002-03-26
CN1293677A (zh) 2001-05-02
CA2317485A1 (en) 2000-06-02
AU6476799A (en) 2000-06-13
US6433203B1 (en) 2002-08-13
ATE300549T1 (de) 2005-08-15
JP2002530413A (ja) 2002-09-17
KR20010034199A (ko) 2001-04-25
ZA200003797B (en) 2001-02-07

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