JP4607317B2 - 一次電池 - Google Patents
一次電池 Download PDFInfo
- Publication number
- JP4607317B2 JP4607317B2 JP2000524833A JP2000524833A JP4607317B2 JP 4607317 B2 JP4607317 B2 JP 4607317B2 JP 2000524833 A JP2000524833 A JP 2000524833A JP 2000524833 A JP2000524833 A JP 2000524833A JP 4607317 B2 JP4607317 B2 JP 4607317B2
- Authority
- JP
- Japan
- Prior art keywords
- primary battery
- salt
- additive
- battery according
- electrolyte
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 239000000654 additive Substances 0.000 claims description 28
- 239000003792 electrolyte Substances 0.000 claims description 26
- 230000000996 additive effect Effects 0.000 claims description 23
- 150000003839 salts Chemical class 0.000 claims description 22
- -1 alkaline earth metal salt Chemical class 0.000 claims description 20
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 claims description 11
- 229910052744 lithium Inorganic materials 0.000 claims description 11
- 229910052784 alkaline earth metal Inorganic materials 0.000 claims description 8
- 150000002500 ions Chemical class 0.000 claims description 7
- 150000001450 anions Chemical class 0.000 claims description 6
- 229920000642 polymer Polymers 0.000 claims description 6
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 claims description 5
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims description 5
- KMTRUDSVKNLOMY-UHFFFAOYSA-N Ethylene carbonate Chemical compound O=C1OCCO1 KMTRUDSVKNLOMY-UHFFFAOYSA-N 0.000 claims description 5
- 150000002894 organic compounds Chemical class 0.000 claims description 5
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 claims description 4
- 239000003513 alkali Substances 0.000 claims description 4
- 239000010406 cathode material Substances 0.000 claims description 4
- 239000007791 liquid phase Substances 0.000 claims description 4
- VLTRZXGMWDSKGL-UHFFFAOYSA-M perchlorate Inorganic materials [O-]Cl(=O)(=O)=O VLTRZXGMWDSKGL-UHFFFAOYSA-M 0.000 claims description 4
- VLTRZXGMWDSKGL-UHFFFAOYSA-N perchloric acid Chemical compound OCl(=O)(=O)=O VLTRZXGMWDSKGL-UHFFFAOYSA-N 0.000 claims description 4
- 150000003242 quaternary ammonium salts Chemical class 0.000 claims description 4
- XTHFKEDIFFGKHM-UHFFFAOYSA-N Dimethoxyethane Chemical compound COCCOC XTHFKEDIFFGKHM-UHFFFAOYSA-N 0.000 claims description 3
- 229910019142 PO4 Inorganic materials 0.000 claims description 3
- 125000000217 alkyl group Chemical group 0.000 claims description 3
- 150000003863 ammonium salts Chemical class 0.000 claims description 3
- IEJIGPNLZYLLBP-UHFFFAOYSA-N dimethyl carbonate Chemical compound COC(=O)OC IEJIGPNLZYLLBP-UHFFFAOYSA-N 0.000 claims description 3
- 239000003960 organic solvent Substances 0.000 claims description 3
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 claims description 3
- 239000010452 phosphate Substances 0.000 claims description 3
- RUOJZAUFBMNUDX-UHFFFAOYSA-N propylene carbonate Chemical compound CC1COC(=O)O1 RUOJZAUFBMNUDX-UHFFFAOYSA-N 0.000 claims description 3
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 claims description 2
- OIFBSDVPJOWBCH-UHFFFAOYSA-N Diethyl carbonate Chemical compound CCOC(=O)OCC OIFBSDVPJOWBCH-UHFFFAOYSA-N 0.000 claims description 2
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 2
- RAXXELZNTBOGNW-UHFFFAOYSA-O Imidazolium Chemical compound C1=C[NH+]=CN1 RAXXELZNTBOGNW-UHFFFAOYSA-O 0.000 claims description 2
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 claims description 2
- 229920003171 Poly (ethylene oxide) Polymers 0.000 claims description 2
- 239000002202 Polyethylene glycol Substances 0.000 claims description 2
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 claims description 2
- 229910052791 calcium Inorganic materials 0.000 claims description 2
- 239000011575 calcium Substances 0.000 claims description 2
- 150000005676 cyclic carbonates Chemical class 0.000 claims description 2
- 125000004122 cyclic group Chemical group 0.000 claims description 2
- JBTWLSYIZRCDFO-UHFFFAOYSA-N ethyl methyl carbonate Chemical compound CCOC(=O)OC JBTWLSYIZRCDFO-UHFFFAOYSA-N 0.000 claims description 2
- 229910052749 magnesium Inorganic materials 0.000 claims description 2
- 239000011777 magnesium Substances 0.000 claims description 2
- 229920001223 polyethylene glycol Polymers 0.000 claims description 2
- 229910052700 potassium Inorganic materials 0.000 claims description 2
- 239000011591 potassium Substances 0.000 claims description 2
- 229910052708 sodium Inorganic materials 0.000 claims description 2
- 239000011734 sodium Substances 0.000 claims description 2
- 239000007787 solid Substances 0.000 claims description 2
- YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 claims description 2
- BTBUEUYNUDRHOZ-UHFFFAOYSA-N Borate Chemical compound [O-]B([O-])[O-] BTBUEUYNUDRHOZ-UHFFFAOYSA-N 0.000 claims 2
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 claims 2
- 150000001342 alkaline earth metals Chemical class 0.000 claims 1
- 239000000463 material Substances 0.000 description 11
- 230000000694 effects Effects 0.000 description 8
- NUJOXMJBOLGQSY-UHFFFAOYSA-N manganese dioxide Chemical compound O=[Mn]=O NUJOXMJBOLGQSY-UHFFFAOYSA-N 0.000 description 8
- 239000000243 solution Substances 0.000 description 7
- 239000002904 solvent Substances 0.000 description 6
- 239000000126 substance Substances 0.000 description 6
- 239000011149 active material Substances 0.000 description 4
- 239000011888 foil Substances 0.000 description 4
- 229910013063 LiBF 4 Inorganic materials 0.000 description 3
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 3
- OWBTYPJTUOEWEK-UHFFFAOYSA-N butane-2,3-diol Chemical compound CC(O)C(C)O OWBTYPJTUOEWEK-UHFFFAOYSA-N 0.000 description 3
- BTVWZWFKMIUSGS-UHFFFAOYSA-N dimethylethyleneglycol Natural products CC(C)(O)CO BTVWZWFKMIUSGS-UHFFFAOYSA-N 0.000 description 3
- 239000007772 electrode material Substances 0.000 description 3
- 239000007788 liquid Substances 0.000 description 3
- ITMCEJHCFYSIIV-UHFFFAOYSA-M triflate Chemical compound [O-]S(=O)(=O)C(F)(F)F ITMCEJHCFYSIIV-UHFFFAOYSA-M 0.000 description 3
- NLXLAEXVIDQMFP-UHFFFAOYSA-N Ammonia chloride Chemical compound [NH4+].[Cl-] NLXLAEXVIDQMFP-UHFFFAOYSA-N 0.000 description 2
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 2
- WCUXLLCKKVVCTQ-UHFFFAOYSA-M Potassium chloride Chemical compound [Cl-].[K+] WCUXLLCKKVVCTQ-UHFFFAOYSA-M 0.000 description 2
- 229910052782 aluminium Inorganic materials 0.000 description 2
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 2
- 239000010405 anode material Substances 0.000 description 2
- 125000003118 aryl group Chemical group 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 230000007423 decrease Effects 0.000 description 2
- 238000009792 diffusion process Methods 0.000 description 2
- 229910044991 metal oxide Inorganic materials 0.000 description 2
- 150000004706 metal oxides Chemical class 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 239000000178 monomer Substances 0.000 description 2
- XXQBEVHPUKOQEO-UHFFFAOYSA-N potassium superoxide Chemical compound [K+].[K+].[O-][O-] XXQBEVHPUKOQEO-UHFFFAOYSA-N 0.000 description 2
- 150000003871 sulfonates Chemical class 0.000 description 2
- 238000012360 testing method Methods 0.000 description 2
- JDOJFSVGXRJFLL-UHFFFAOYSA-N 1-ethyl-3-methylimidazol-3-ium;nitrate Chemical compound [O-][N+]([O-])=O.CCN1C=C[N+](C)=C1 JDOJFSVGXRJFLL-UHFFFAOYSA-N 0.000 description 1
- ZPTRYWVRCNOTAS-UHFFFAOYSA-M 1-ethyl-3-methylimidazol-3-ium;trifluoromethanesulfonate Chemical compound CC[N+]=1C=CN(C)C=1.[O-]S(=O)(=O)C(F)(F)F ZPTRYWVRCNOTAS-UHFFFAOYSA-M 0.000 description 1
- BMQZYMYBQZGEEY-UHFFFAOYSA-M 1-ethyl-3-methylimidazolium chloride Chemical compound [Cl-].CCN1C=C[N+](C)=C1 BMQZYMYBQZGEEY-UHFFFAOYSA-M 0.000 description 1
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 1
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 description 1
- XDTMQSROBMDMFD-UHFFFAOYSA-N Cyclohexane Chemical compound C1CCCCC1 XDTMQSROBMDMFD-UHFFFAOYSA-N 0.000 description 1
- 229920002943 EPDM rubber Polymers 0.000 description 1
- 239000002000 Electrolyte additive Substances 0.000 description 1
- HBBGRARXTFLTSG-UHFFFAOYSA-N Lithium ion Chemical compound [Li+] HBBGRARXTFLTSG-UHFFFAOYSA-N 0.000 description 1
- 229910002651 NO3 Inorganic materials 0.000 description 1
- NHNBFGGVMKEFGY-UHFFFAOYSA-N Nitrate Chemical compound [O-][N+]([O-])=O NHNBFGGVMKEFGY-UHFFFAOYSA-N 0.000 description 1
- UCKMPCXJQFINFW-UHFFFAOYSA-N Sulphide Chemical compound [S-2] UCKMPCXJQFINFW-UHFFFAOYSA-N 0.000 description 1
- 125000001931 aliphatic group Chemical group 0.000 description 1
- 229910052783 alkali metal Inorganic materials 0.000 description 1
- 125000002947 alkylene group Chemical group 0.000 description 1
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 1
- 235000019270 ammonium chloride Nutrition 0.000 description 1
- 239000003125 aqueous solvent Substances 0.000 description 1
- 239000011230 binding agent Substances 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 229910052796 boron Inorganic materials 0.000 description 1
- 150000001642 boronic acid derivatives Chemical class 0.000 description 1
- 239000006229 carbon black Substances 0.000 description 1
- 239000001569 carbon dioxide Substances 0.000 description 1
- 229910002092 carbon dioxide Inorganic materials 0.000 description 1
- 150000001768 cations Chemical class 0.000 description 1
- 239000013626 chemical specie Substances 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 230000008878 coupling Effects 0.000 description 1
- 238000010168 coupling process Methods 0.000 description 1
- 238000005859 coupling reaction Methods 0.000 description 1
- 150000003983 crown ethers Chemical class 0.000 description 1
- 230000005611 electricity Effects 0.000 description 1
- 239000008151 electrolyte solution Substances 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 150000002170 ethers Chemical class 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 230000014509 gene expression Effects 0.000 description 1
- 238000009830 intercalation Methods 0.000 description 1
- 230000002687 intercalation Effects 0.000 description 1
- 239000002608 ionic liquid Substances 0.000 description 1
- 229910001416 lithium ion Inorganic materials 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 229910052976 metal sulfide Inorganic materials 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 239000011255 nonaqueous electrolyte Substances 0.000 description 1
- 239000012071 phase Substances 0.000 description 1
- 239000002985 plastic film Substances 0.000 description 1
- 229920006255 plastic film Polymers 0.000 description 1
- 230000010287 polarization Effects 0.000 description 1
- 239000001103 potassium chloride Substances 0.000 description 1
- 235000011164 potassium chloride Nutrition 0.000 description 1
- 125000001453 quaternary ammonium group Chemical group 0.000 description 1
- UKHVLWKBNNSRRR-UHFFFAOYSA-M quaternium-15 Chemical compound [Cl-].C1N(C2)CN3CN2C[N+]1(CC=CCl)C3 UKHVLWKBNNSRRR-UHFFFAOYSA-M 0.000 description 1
- 230000009257 reactivity Effects 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 239000002002 slurry Substances 0.000 description 1
- 125000005207 tetraalkylammonium group Chemical group 0.000 description 1
- 238000012546 transfer Methods 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Images
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01G—CAPACITORS; CAPACITORS, RECTIFIERS, DETECTORS, SWITCHING DEVICES, LIGHT-SENSITIVE OR TEMPERATURE-SENSITIVE DEVICES OF THE ELECTROLYTIC TYPE
- H01G9/00—Electrolytic capacitors, rectifiers, detectors, switching devices, light-sensitive or temperature-sensitive devices; Processes of their manufacture
- H01G9/004—Details
- H01G9/022—Electrolytes; Absorbents
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/05—Accumulators with non-aqueous electrolyte
- H01M10/052—Li-accumulators
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/05—Accumulators with non-aqueous electrolyte
- H01M10/054—Accumulators with insertion or intercalation of metals other than lithium, e.g. with magnesium or aluminium
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/05—Accumulators with non-aqueous electrolyte
- H01M10/056—Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes
- H01M10/0564—Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes the electrolyte being constituted of organic materials only
- H01M10/0566—Liquid materials
- H01M10/0567—Liquid materials characterised by the additives
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M6/00—Primary cells; Manufacture thereof
- H01M6/14—Cells with non-aqueous electrolyte
- H01M6/16—Cells with non-aqueous electrolyte with organic electrolyte
- H01M6/162—Cells with non-aqueous electrolyte with organic electrolyte characterised by the electrolyte
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M6/00—Primary cells; Manufacture thereof
- H01M6/14—Cells with non-aqueous electrolyte
- H01M6/16—Cells with non-aqueous electrolyte with organic electrolyte
- H01M6/162—Cells with non-aqueous electrolyte with organic electrolyte characterised by the electrolyte
- H01M6/168—Cells with non-aqueous electrolyte with organic electrolyte characterised by the electrolyte by additives
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M6/00—Primary cells; Manufacture thereof
- H01M6/14—Cells with non-aqueous electrolyte
- H01M6/16—Cells with non-aqueous electrolyte with organic electrolyte
- H01M6/162—Cells with non-aqueous electrolyte with organic electrolyte characterised by the electrolyte
- H01M6/164—Cells with non-aqueous electrolyte with organic electrolyte characterised by the electrolyte by the solvent
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/10—Energy storage using batteries
Landscapes
- Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Manufacturing & Machinery (AREA)
- Power Engineering (AREA)
- Materials Engineering (AREA)
- Microelectronics & Electronic Packaging (AREA)
- Physics & Mathematics (AREA)
- Condensed Matter Physics & Semiconductors (AREA)
- General Physics & Mathematics (AREA)
- Inorganic Chemistry (AREA)
- Primary Cells (AREA)
- Secondary Cells (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GBGB9726008.7A GB9726008D0 (en) | 1997-12-10 | 1997-12-10 | Eletrolyte |
| GB9726008.7 | 1997-12-10 | ||
| PCT/GB1998/003615 WO1999030379A1 (en) | 1997-12-10 | 1998-12-08 | Electrochemical cell comprising a liquid organic electrolyte with a conductive additive |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| JP2001526450A JP2001526450A (ja) | 2001-12-18 |
| JP2001526450A5 JP2001526450A5 (enExample) | 2006-02-02 |
| JP4607317B2 true JP4607317B2 (ja) | 2011-01-05 |
Family
ID=10823324
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2000524833A Expired - Fee Related JP4607317B2 (ja) | 1997-12-10 | 1998-12-08 | 一次電池 |
Country Status (8)
| Country | Link |
|---|---|
| US (1) | US6596441B1 (enExample) |
| EP (1) | EP1055262B1 (enExample) |
| JP (1) | JP4607317B2 (enExample) |
| DE (1) | DE69804356T2 (enExample) |
| DK (1) | DK1055262T3 (enExample) |
| ES (1) | ES2171053T3 (enExample) |
| GB (2) | GB9726008D0 (enExample) |
| WO (1) | WO1999030379A1 (enExample) |
Families Citing this family (14)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2803951B1 (fr) * | 2000-01-14 | 2002-04-26 | Centre Nat Rech Scient | Compositions d'electrolytes, procede de fabrication et applications electrochimiques |
| US6635387B2 (en) | 2000-03-20 | 2003-10-21 | Johan C. Fitter | Method and apparatus for achieving prolonged battery life |
| US6899978B2 (en) | 2000-12-18 | 2005-05-31 | Johan Christiaan Fitter | Electrochemical cell |
| US7241535B2 (en) * | 2001-10-15 | 2007-07-10 | Samsung Sdi Co., Ltd. | Electrolyte for lithium-sulfur batteries and lithium-sulfur batteries comprising the same |
| KR100477744B1 (ko) * | 2001-10-31 | 2005-03-18 | 삼성에스디아이 주식회사 | 유기 전해액 및 이를 채용한 리튬 2차전지 |
| CN100397698C (zh) * | 2002-11-29 | 2008-06-25 | 株式会社杰士汤浅 | 非水电解质和非水电解质电池 |
| DE602005017837D1 (de) * | 2004-01-15 | 2010-01-07 | Panasonic Corp | Nichtwässriger Elektrolyt für elektrochemische Vorrichtungen |
| JP4746392B2 (ja) * | 2005-09-26 | 2011-08-10 | 株式会社東芝 | 非水電解質二次電池および電池パック |
| KR101098213B1 (ko) * | 2007-03-06 | 2011-12-27 | 주식회사 엘지화학 | 고온 저장 특성이 우수한 리튬 이차전지용 비수계 전해액 |
| US8475688B2 (en) * | 2007-09-20 | 2013-07-02 | Uchicago Argonne, Llc | Lithium batteries using poly(ethylene oxide)-based non-aqueous electrolytes |
| US20090269676A1 (en) * | 2008-04-29 | 2009-10-29 | Barbarich Thomas J | Non-aqueous electrolytes for lithium electrochemical cells |
| US8822078B2 (en) * | 2008-09-29 | 2014-09-02 | Rochester Institute Of Technology | Freestanding carbon nanotube paper, methods of its making, and devices containing the same |
| US9692083B2 (en) * | 2012-07-31 | 2017-06-27 | Prieto Battery, Inc. | Lithium-ion battery having organic-inorganic hybrid solid electrolyte |
| US20160006089A1 (en) * | 2013-01-23 | 2016-01-07 | Yiying Wu | Potassium-Oxygen Batteries Based on Potassium Superoxide |
Family Cites Families (23)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3997362A (en) | 1975-10-14 | 1976-12-14 | Exxon Research And Engineering Company | Polyhalide high energy density cells |
| US4132837A (en) | 1978-03-30 | 1979-01-02 | University Patents, Inc. | Electrochemical cells with non-aqueous electrolytes containing macroheterocyclic compounds |
| SE445000B (sv) | 1981-10-08 | 1986-05-20 | Inst Fiz Khim Pisarzhev An | Elektrokemiskt batteri |
| US4526846A (en) * | 1982-06-14 | 1985-07-02 | Duracell Inc. | Corrosion prevention additive |
| CA1242483A (en) | 1983-10-26 | 1988-09-27 | Toshikazu Shishikura | Secondary battery |
| JPS63301467A (ja) * | 1987-06-02 | 1988-12-08 | Matsushita Electric Ind Co Ltd | 有機電解質電池 |
| JP2599763B2 (ja) * | 1988-03-24 | 1997-04-16 | 三菱化学株式会社 | ゲル状電解液 |
| JPH0334270A (ja) * | 1989-06-30 | 1991-02-14 | Nippon Kagaku Sangyo Kk | 二次電池用電解液および二次電池 |
| JP2977252B2 (ja) * | 1990-08-31 | 1999-11-15 | 株式会社東芝 | 非水電解液二次電池 |
| US5085955A (en) * | 1990-11-21 | 1992-02-04 | The Dow Chemical Company | Non-aqueous electrochemical cell |
| JP3075766B2 (ja) * | 1991-05-27 | 2000-08-14 | 株式会社東芝 | リチウム電池 |
| CA2083001C (en) | 1991-12-17 | 1996-12-17 | Yuzuru Takahashi | Lithium secondary battery using a non-aqueous solvent |
| FR2704099B1 (fr) * | 1993-04-15 | 1995-07-07 | Centre Nat Etd Spatiales | Electrolyte pour accumulateur electrique. |
| WO1995018456A1 (fr) * | 1993-12-29 | 1995-07-06 | Ecole Polytechnique Federale De Lausanne | Pile photo-electrochimique et electrolyte pour cette pile |
| WO1995026056A1 (fr) * | 1994-03-21 | 1995-09-28 | Centre National De La Recherche Scientifique | Materiau a conduction ionique presentant de bonnes proprietes anti-corrosion |
| US5514493A (en) | 1995-03-06 | 1996-05-07 | Minnesota Mining And Manufacturing Company | Perfluoroalkylsulfonates, sulfonimides, and sulfonyl methides, and electrolytes containing them |
| JPH08245493A (ja) * | 1995-03-07 | 1996-09-24 | Mitsubishi Chem Corp | 常温溶融塩 |
| JP3751048B2 (ja) * | 1995-05-26 | 2006-03-01 | 松下電器産業株式会社 | 電解液およびそれを用いた電気化学素子 |
| JP3220623B2 (ja) * | 1995-07-31 | 2001-10-22 | 松下電器産業株式会社 | 電解液およびそれを用いた電気化学素子 |
| JP3756232B2 (ja) | 1996-01-17 | 2006-03-15 | 宇部興産株式会社 | 非水電解質二次電池 |
| GB9619133D0 (en) * | 1996-09-13 | 1996-10-23 | Secr Defence | An electrolyte |
| EP0850933A1 (fr) * | 1996-12-30 | 1998-07-01 | Centre National De La Recherche Scientifique (Cnrs) | Sels d'anions pentacycliques ou dérivés de tétrazapentalène, et leurs utilisations comme matériaux à conduction ionique |
| US5965054A (en) * | 1997-08-12 | 1999-10-12 | Covalent Associates, Inc. | Nonaqueous electrolyte for electrical storage devices |
-
1997
- 1997-12-10 GB GBGB9726008.7A patent/GB9726008D0/en not_active Ceased
-
1998
- 1998-12-08 US US09/530,998 patent/US6596441B1/en not_active Expired - Fee Related
- 1998-12-08 JP JP2000524833A patent/JP4607317B2/ja not_active Expired - Fee Related
- 1998-12-08 GB GB0010773A patent/GB2346256B/en not_active Expired - Fee Related
- 1998-12-08 ES ES98959000T patent/ES2171053T3/es not_active Expired - Lifetime
- 1998-12-08 EP EP98959000A patent/EP1055262B1/en not_active Expired - Lifetime
- 1998-12-08 WO PCT/GB1998/003615 patent/WO1999030379A1/en not_active Ceased
- 1998-12-08 DK DK98959000T patent/DK1055262T3/da active
- 1998-12-08 DE DE69804356T patent/DE69804356T2/de not_active Expired - Lifetime
Also Published As
| Publication number | Publication date |
|---|---|
| GB2346256B (en) | 2001-08-22 |
| GB9726008D0 (en) | 1998-02-04 |
| ES2171053T3 (es) | 2002-08-16 |
| EP1055262B1 (en) | 2002-03-20 |
| GB0010773D0 (en) | 2000-06-28 |
| EP1055262A1 (en) | 2000-11-29 |
| GB2346256A (en) | 2000-08-02 |
| DE69804356D1 (de) | 2002-04-25 |
| DK1055262T3 (da) | 2002-07-08 |
| US6596441B1 (en) | 2003-07-22 |
| JP2001526450A (ja) | 2001-12-18 |
| DE69804356T2 (de) | 2002-10-31 |
| WO1999030379A1 (en) | 1999-06-17 |
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