JP4523004B2 - 耐燃焼性芳香族ポリアミド樹脂組成物、およびそれから形成された物品 - Google Patents
耐燃焼性芳香族ポリアミド樹脂組成物、およびそれから形成された物品 Download PDFInfo
- Publication number
- JP4523004B2 JP4523004B2 JP2006534224A JP2006534224A JP4523004B2 JP 4523004 B2 JP4523004 B2 JP 4523004B2 JP 2006534224 A JP2006534224 A JP 2006534224A JP 2006534224 A JP2006534224 A JP 2006534224A JP 4523004 B2 JP4523004 B2 JP 4523004B2
- Authority
- JP
- Japan
- Prior art keywords
- polyamide
- resin composition
- polyamide resin
- flame retardant
- weight percent
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 239000011342 resin composition Substances 0.000 title claims description 26
- 239000004760 aramid Substances 0.000 title claims description 12
- 229920003235 aromatic polyamide Polymers 0.000 title claims description 12
- 238000002485 combustion reaction Methods 0.000 title description 2
- 239000003063 flame retardant Substances 0.000 claims description 34
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 claims description 28
- 239000000203 mixture Substances 0.000 claims description 26
- 229920006122 polyamide resin Polymers 0.000 claims description 25
- -1 aluminum ion Chemical class 0.000 claims description 14
- 125000003118 aryl group Chemical group 0.000 claims description 14
- 229920000642 polymer Polymers 0.000 claims description 11
- 239000012744 reinforcing agent Substances 0.000 claims description 10
- 239000000178 monomer Substances 0.000 claims description 9
- 239000012763 reinforcing filler Substances 0.000 claims description 8
- ACVYVLVWPXVTIT-UHFFFAOYSA-M phosphinate Chemical compound [O-][PH2]=O ACVYVLVWPXVTIT-UHFFFAOYSA-M 0.000 claims description 7
- 229910052782 aluminium Inorganic materials 0.000 claims description 6
- PTFCDOFLOPIGGS-UHFFFAOYSA-N Zinc dication Chemical compound [Zn+2] PTFCDOFLOPIGGS-UHFFFAOYSA-N 0.000 claims description 5
- 125000006832 (C1-C10) alkylene group Chemical group 0.000 claims description 4
- BHPQYMZQTOCNFJ-UHFFFAOYSA-N Calcium cation Chemical compound [Ca+2] BHPQYMZQTOCNFJ-UHFFFAOYSA-N 0.000 claims description 4
- JLVVSXFLKOJNIY-UHFFFAOYSA-N Magnesium ion Chemical compound [Mg+2] JLVVSXFLKOJNIY-UHFFFAOYSA-N 0.000 claims description 4
- 229910001424 calcium ion Inorganic materials 0.000 claims description 4
- 229910001425 magnesium ion Inorganic materials 0.000 claims description 4
- VXAUWWUXCIMFIM-UHFFFAOYSA-M aluminum;oxygen(2-);hydroxide Chemical compound [OH-].[O-2].[Al+3] VXAUWWUXCIMFIM-UHFFFAOYSA-M 0.000 claims description 2
- 229920002292 Nylon 6 Polymers 0.000 description 18
- 239000004952 Polyamide Substances 0.000 description 13
- 229920002647 polyamide Polymers 0.000 description 13
- 229920002302 Nylon 6,6 Polymers 0.000 description 11
- 229920001897 terpolymer Polymers 0.000 description 10
- 229920001577 copolymer Polymers 0.000 description 9
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 8
- 239000003963 antioxidant agent Substances 0.000 description 8
- 229920000877 Melamine resin Polymers 0.000 description 6
- JDSHMPZPIAZGSV-UHFFFAOYSA-N melamine Chemical compound NC1=NC(N)=NC(N)=N1 JDSHMPZPIAZGSV-UHFFFAOYSA-N 0.000 description 6
- 229920000305 Nylon 6,10 Polymers 0.000 description 5
- 238000000465 moulding Methods 0.000 description 5
- 239000000047 product Substances 0.000 description 5
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 4
- 229920000572 Nylon 6/12 Polymers 0.000 description 4
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 4
- KKEYFWRCBNTPAC-UHFFFAOYSA-N Terephthalic acid Chemical compound OC(=O)C1=CC=C(C(O)=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-N 0.000 description 4
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 4
- 239000007859 condensation product Substances 0.000 description 4
- QQVIHTHCMHWDBS-UHFFFAOYSA-N isophthalic acid Chemical compound OC(=O)C1=CC=CC(C(O)=O)=C1 QQVIHTHCMHWDBS-UHFFFAOYSA-N 0.000 description 4
- 239000000463 material Substances 0.000 description 4
- PGGROMGHWHXWJL-UHFFFAOYSA-N 4-(azepane-1-carbonyl)benzamide Chemical compound C1=CC(C(=O)N)=CC=C1C(=O)N1CCCCCC1 PGGROMGHWHXWJL-UHFFFAOYSA-N 0.000 description 3
- 239000004953 Aliphatic polyamide Substances 0.000 description 3
- 229920000299 Nylon 12 Polymers 0.000 description 3
- 229920003231 aliphatic polyamide Polymers 0.000 description 3
- 229910001593 boehmite Inorganic materials 0.000 description 3
- 239000007795 chemical reaction product Substances 0.000 description 3
- 230000000052 comparative effect Effects 0.000 description 3
- 239000003365 glass fiber Substances 0.000 description 3
- 229920001519 homopolymer Polymers 0.000 description 3
- FAHBNUUHRFUEAI-UHFFFAOYSA-M hydroxidooxidoaluminium Chemical compound O[Al]=O FAHBNUUHRFUEAI-UHFFFAOYSA-M 0.000 description 3
- PXHVJJICTQNCMI-UHFFFAOYSA-N nickel Substances [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 3
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 description 3
- BIKXLKXABVUSMH-UHFFFAOYSA-N trizinc;diborate Chemical compound [Zn+2].[Zn+2].[Zn+2].[O-]B([O-])[O-].[O-]B([O-])[O-] BIKXLKXABVUSMH-UHFFFAOYSA-N 0.000 description 3
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N Iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 description 2
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 2
- FDLQZKYLHJJBHD-UHFFFAOYSA-N [3-(aminomethyl)phenyl]methanamine Chemical compound NCC1=CC=CC(CN)=C1 FDLQZKYLHJJBHD-UHFFFAOYSA-N 0.000 description 2
- REBHQKBZDKXDMN-UHFFFAOYSA-M [PH2]([O-])=O.C(C)[Al+]CC Chemical compound [PH2]([O-])=O.C(C)[Al+]CC REBHQKBZDKXDMN-UHFFFAOYSA-M 0.000 description 2
- JMJWMGLCPXGAFU-UHFFFAOYSA-M [PH2]([O-])=O.C[Al+]CC Chemical compound [PH2]([O-])=O.C[Al+]CC JMJWMGLCPXGAFU-UHFFFAOYSA-M 0.000 description 2
- WNLRTRBMVRJNCN-UHFFFAOYSA-N adipic acid Chemical compound OC(=O)CCCCC(O)=O WNLRTRBMVRJNCN-UHFFFAOYSA-N 0.000 description 2
- 230000002411 adverse Effects 0.000 description 2
- 125000001931 aliphatic group Chemical group 0.000 description 2
- AYJRCSIUFZENHW-UHFFFAOYSA-L barium carbonate Chemical compound [Ba+2].[O-]C([O-])=O AYJRCSIUFZENHW-UHFFFAOYSA-L 0.000 description 2
- 229910000019 calcium carbonate Inorganic materials 0.000 description 2
- 238000000354 decomposition reaction Methods 0.000 description 2
- POULHZVOKOAJMA-UHFFFAOYSA-N dodecanoic acid Chemical compound CCCCCCCCCCCC(O)=O POULHZVOKOAJMA-UHFFFAOYSA-N 0.000 description 2
- 238000010292 electrical insulation Methods 0.000 description 2
- 239000011521 glass Substances 0.000 description 2
- NAQMVNRVTILPCV-UHFFFAOYSA-N hexane-1,6-diamine Chemical compound NCCCCCCN NAQMVNRVTILPCV-UHFFFAOYSA-N 0.000 description 2
- AMWRITDGCCNYAT-UHFFFAOYSA-L hydroxy(oxo)manganese;manganese Chemical compound [Mn].O[Mn]=O.O[Mn]=O AMWRITDGCCNYAT-UHFFFAOYSA-L 0.000 description 2
- 150000007974 melamines Chemical class 0.000 description 2
- 239000000155 melt Substances 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 229910052759 nickel Inorganic materials 0.000 description 2
- BDJRBEYXGGNYIS-UHFFFAOYSA-N nonanedioic acid Chemical compound OC(=O)CCCCCCCC(O)=O BDJRBEYXGGNYIS-UHFFFAOYSA-N 0.000 description 2
- 239000002530 phenolic antioxidant Substances 0.000 description 2
- OJMIONKXNSYLSR-UHFFFAOYSA-N phosphorous acid Chemical compound OP(O)O OJMIONKXNSYLSR-UHFFFAOYSA-N 0.000 description 2
- 230000000704 physical effect Effects 0.000 description 2
- 229920005989 resin Polymers 0.000 description 2
- 239000011347 resin Substances 0.000 description 2
- CXMXRPHRNRROMY-UHFFFAOYSA-N sebacic acid Chemical compound OC(=O)CCCCCCCCC(O)=O CXMXRPHRNRROMY-UHFFFAOYSA-N 0.000 description 2
- 239000000377 silicon dioxide Substances 0.000 description 2
- 150000003568 thioethers Chemical class 0.000 description 2
- VXNZUUAINFGPBY-UHFFFAOYSA-N 1-Butene Chemical group CCC=C VXNZUUAINFGPBY-UHFFFAOYSA-N 0.000 description 1
- JZUHIOJYCPIVLQ-UHFFFAOYSA-N 2-methylpentane-1,5-diamine Chemical compound NCC(C)CCCN JZUHIOJYCPIVLQ-UHFFFAOYSA-N 0.000 description 1
- FQLAJSQGBDYBAL-UHFFFAOYSA-N 3-(azepane-1-carbonyl)benzamide Chemical compound NC(=O)C1=CC=CC(C(=O)N2CCCCCC2)=C1 FQLAJSQGBDYBAL-UHFFFAOYSA-N 0.000 description 1
- LKWSTQPRPRGLDP-UHFFFAOYSA-N 4-(azacycloundecane-1-carbonyl)benzamide Chemical compound C1=CC(C(=O)N)=CC=C1C(=O)N1CCCCCCCCCC1 LKWSTQPRPRGLDP-UHFFFAOYSA-N 0.000 description 1
- UQIMSNLNKHJLSY-UHFFFAOYSA-N 5-methyl-3,9-dioxabicyclo[9.2.2]pentadeca-1(13),11,14-triene-2,10-dione Chemical compound C1(C2=CC=C(C(=O)OCCCC(CO1)C)C=C2)=O UQIMSNLNKHJLSY-UHFFFAOYSA-N 0.000 description 1
- 239000005995 Aluminium silicate Substances 0.000 description 1
- 229920000049 Carbon (fiber) Polymers 0.000 description 1
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- QPLDLSVMHZLSFG-UHFFFAOYSA-N Copper oxide Chemical compound [Cu]=O QPLDLSVMHZLSFG-UHFFFAOYSA-N 0.000 description 1
- 239000005751 Copper oxide Substances 0.000 description 1
- 239000004609 Impact Modifier Substances 0.000 description 1
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 description 1
- 229920003189 Nylon 4,6 Polymers 0.000 description 1
- 229910019142 PO4 Inorganic materials 0.000 description 1
- 239000004793 Polystyrene Substances 0.000 description 1
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 1
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 1
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 1
- WGLPBDUCMAPZCE-UHFFFAOYSA-N Trioxochromium Chemical compound O=[Cr](=O)=O WGLPBDUCMAPZCE-UHFFFAOYSA-N 0.000 description 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
- FMRLDPWIRHBCCC-UHFFFAOYSA-L Zinc carbonate Chemical compound [Zn+2].[O-]C([O-])=O FMRLDPWIRHBCCC-UHFFFAOYSA-L 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 239000001361 adipic acid Substances 0.000 description 1
- 235000011037 adipic acid Nutrition 0.000 description 1
- 125000005263 alkylenediamine group Chemical group 0.000 description 1
- IYABWNGZIDDRAK-UHFFFAOYSA-N allene Chemical group C=C=C IYABWNGZIDDRAK-UHFFFAOYSA-N 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 235000012211 aluminium silicate Nutrition 0.000 description 1
- 150000001408 amides Chemical class 0.000 description 1
- 150000001413 amino acids Chemical class 0.000 description 1
- 229910052787 antimony Inorganic materials 0.000 description 1
- WATWJIUSRGPENY-UHFFFAOYSA-N antimony atom Chemical compound [Sb] WATWJIUSRGPENY-UHFFFAOYSA-N 0.000 description 1
- 150000001463 antimony compounds Chemical class 0.000 description 1
- 229910000410 antimony oxide Inorganic materials 0.000 description 1
- 150000004984 aromatic diamines Chemical class 0.000 description 1
- QBLDFAIABQKINO-UHFFFAOYSA-N barium borate Chemical compound [Ba+2].[O-]B=O.[O-]B=O QBLDFAIABQKINO-UHFFFAOYSA-N 0.000 description 1
- 229910052797 bismuth Inorganic materials 0.000 description 1
- JCXGWMGPZLAOME-UHFFFAOYSA-N bismuth atom Chemical compound [Bi] JCXGWMGPZLAOME-UHFFFAOYSA-N 0.000 description 1
- 229910000416 bismuth oxide Inorganic materials 0.000 description 1
- 238000000071 blow moulding Methods 0.000 description 1
- 239000004917 carbon fiber Substances 0.000 description 1
- 229910052804 chromium Inorganic materials 0.000 description 1
- 239000011651 chromium Substances 0.000 description 1
- 229910000423 chromium oxide Inorganic materials 0.000 description 1
- 239000004927 clay Substances 0.000 description 1
- 229910052570 clay Inorganic materials 0.000 description 1
- 229910017052 cobalt Inorganic materials 0.000 description 1
- 239000010941 cobalt Substances 0.000 description 1
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 1
- 229910000428 cobalt oxide Inorganic materials 0.000 description 1
- IVMYJDGYRUAWML-UHFFFAOYSA-N cobalt(ii) oxide Chemical compound [Co]=O IVMYJDGYRUAWML-UHFFFAOYSA-N 0.000 description 1
- 238000013329 compounding Methods 0.000 description 1
- 230000001143 conditioned effect Effects 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- 229910000431 copper oxide Inorganic materials 0.000 description 1
- YQLZOAVZWJBZSY-UHFFFAOYSA-N decane-1,10-diamine Chemical compound NCCCCCCCCCCN YQLZOAVZWJBZSY-UHFFFAOYSA-N 0.000 description 1
- 230000002542 deteriorative effect Effects 0.000 description 1
- 150000004985 diamines Chemical class 0.000 description 1
- TYIXMATWDRGMPF-UHFFFAOYSA-N dibismuth;oxygen(2-) Chemical compound [O-2].[O-2].[O-2].[Bi+3].[Bi+3] TYIXMATWDRGMPF-UHFFFAOYSA-N 0.000 description 1
- NJLLQSBAHIKGKF-UHFFFAOYSA-N dipotassium dioxido(oxo)titanium Chemical compound [K+].[K+].[O-][Ti]([O-])=O NJLLQSBAHIKGKF-UHFFFAOYSA-N 0.000 description 1
- QFTYSVGGYOXFRQ-UHFFFAOYSA-N dodecane-1,12-diamine Chemical compound NCCCCCCCCCCCCN QFTYSVGGYOXFRQ-UHFFFAOYSA-N 0.000 description 1
- 239000000975 dye Substances 0.000 description 1
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
- 238000001125 extrusion Methods 0.000 description 1
- 238000011049 filling Methods 0.000 description 1
- 239000012760 heat stabilizer Substances 0.000 description 1
- 238000001746 injection moulding Methods 0.000 description 1
- 239000011256 inorganic filler Substances 0.000 description 1
- 229910003475 inorganic filler Inorganic materials 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 125000001449 isopropyl group Chemical group [H]C([H])([H])C([H])(*)C([H])([H])[H] 0.000 description 1
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 1
- 150000003951 lactams Chemical class 0.000 description 1
- 239000000314 lubricant Substances 0.000 description 1
- ZLNQQNXFFQJAID-UHFFFAOYSA-L magnesium carbonate Chemical compound [Mg+2].[O-]C([O-])=O ZLNQQNXFFQJAID-UHFFFAOYSA-L 0.000 description 1
- 239000001095 magnesium carbonate Substances 0.000 description 1
- 229910000021 magnesium carbonate Inorganic materials 0.000 description 1
- 239000000395 magnesium oxide Substances 0.000 description 1
- CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 description 1
- AXZKOIWUVFPNLO-UHFFFAOYSA-N magnesium;oxygen(2-) Chemical compound [O-2].[Mg+2] AXZKOIWUVFPNLO-UHFFFAOYSA-N 0.000 description 1
- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 229910044991 metal oxide Inorganic materials 0.000 description 1
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
- 239000006082 mold release agent Substances 0.000 description 1
- 229910052750 molybdenum Inorganic materials 0.000 description 1
- 239000011733 molybdenum Substances 0.000 description 1
- 229910000476 molybdenum oxide Inorganic materials 0.000 description 1
- 125000004108 n-butyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 125000000740 n-pentyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 125000004123 n-propyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 125000004957 naphthylene group Chemical group 0.000 description 1
- SXJVFQLYZSNZBT-UHFFFAOYSA-N nonane-1,9-diamine Chemical compound NCCCCCCCCCN SXJVFQLYZSNZBT-UHFFFAOYSA-N 0.000 description 1
- QGLKJKCYBOYXKC-UHFFFAOYSA-N nonaoxidotritungsten Chemical compound O=[W]1(=O)O[W](=O)(=O)O[W](=O)(=O)O1 QGLKJKCYBOYXKC-UHFFFAOYSA-N 0.000 description 1
- 239000002667 nucleating agent Substances 0.000 description 1
- 150000002894 organic compounds Chemical class 0.000 description 1
- 239000012766 organic filler Substances 0.000 description 1
- VTRUBDSFZJNXHI-UHFFFAOYSA-N oxoantimony Chemical compound [Sb]=O VTRUBDSFZJNXHI-UHFFFAOYSA-N 0.000 description 1
- PQQKPALAQIIWST-UHFFFAOYSA-N oxomolybdenum Chemical compound [Mo]=O PQQKPALAQIIWST-UHFFFAOYSA-N 0.000 description 1
- RVTZCBVAJQQJTK-UHFFFAOYSA-N oxygen(2-);zirconium(4+) Chemical compound [O-2].[O-2].[Zr+4] RVTZCBVAJQQJTK-UHFFFAOYSA-N 0.000 description 1
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 1
- 125000000843 phenylene group Chemical group C1(=C(C=CC=C1)*)* 0.000 description 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 1
- 239000010452 phosphate Substances 0.000 description 1
- ACVYVLVWPXVTIT-UHFFFAOYSA-N phosphinic acid Chemical class O[PH2]=O ACVYVLVWPXVTIT-UHFFFAOYSA-N 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 239000004014 plasticizer Substances 0.000 description 1
- 229920006115 poly(dodecamethylene terephthalamide) Polymers 0.000 description 1
- 229920006128 poly(nonamethylene terephthalamide) Polymers 0.000 description 1
- 229920000728 polyester Polymers 0.000 description 1
- 229920001296 polysiloxane Polymers 0.000 description 1
- 229920002223 polystyrene Polymers 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 238000005728 strengthening Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 239000000454 talc Substances 0.000 description 1
- 229910052623 talc Inorganic materials 0.000 description 1
- 125000000999 tert-butyl group Chemical group [H]C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- DJZKNOVUNYPPEE-UHFFFAOYSA-N tetradecane-1,4,11,14-tetracarboxamide Chemical compound NC(=O)CCCC(C(N)=O)CCCCCCC(C(N)=O)CCCC(N)=O DJZKNOVUNYPPEE-UHFFFAOYSA-N 0.000 description 1
- 238000003856 thermoforming Methods 0.000 description 1
- 229920005992 thermoplastic resin Polymers 0.000 description 1
- 229910052718 tin Inorganic materials 0.000 description 1
- XOLBLPGZBRYERU-UHFFFAOYSA-N tin dioxide Chemical compound O=[Sn]=O XOLBLPGZBRYERU-UHFFFAOYSA-N 0.000 description 1
- 229910001887 tin oxide Inorganic materials 0.000 description 1
- 229910052719 titanium Inorganic materials 0.000 description 1
- 239000010936 titanium Substances 0.000 description 1
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 1
- 150000003918 triazines Chemical class 0.000 description 1
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 description 1
- 229910052721 tungsten Inorganic materials 0.000 description 1
- 239000010937 tungsten Substances 0.000 description 1
- 229910001930 tungsten oxide Inorganic materials 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
- 239000010456 wollastonite Substances 0.000 description 1
- 229910052882 wollastonite Inorganic materials 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
- 239000011667 zinc carbonate Substances 0.000 description 1
- 229910000010 zinc carbonate Inorganic materials 0.000 description 1
- 235000004416 zinc carbonate Nutrition 0.000 description 1
- 239000011787 zinc oxide Substances 0.000 description 1
- PZRXQXJGIQEYOG-UHFFFAOYSA-N zinc;oxido(oxo)borane Chemical compound [Zn+2].[O-]B=O.[O-]B=O PZRXQXJGIQEYOG-UHFFFAOYSA-N 0.000 description 1
- 229910001928 zirconium oxide Inorganic materials 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/49—Phosphorus-containing compounds
- C08K5/51—Phosphorus bound to oxygen
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Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US50850603P | 2003-10-03 | 2003-10-03 | |
| PCT/US2004/032624 WO2005033192A1 (en) | 2003-10-03 | 2004-10-01 | Flame resistant aromatic polyamide resin composition and articles therefrom |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| JP2007507595A JP2007507595A (ja) | 2007-03-29 |
| JP2007507595A5 JP2007507595A5 (enExample) | 2007-11-22 |
| JP4523004B2 true JP4523004B2 (ja) | 2010-08-11 |
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| US (1) | US7294661B2 (enExample) |
| EP (1) | EP1668074B2 (enExample) |
| JP (1) | JP4523004B2 (enExample) |
| CN (1) | CN100451059C (enExample) |
| CA (1) | CA2539773C (enExample) |
| WO (1) | WO2005033192A1 (enExample) |
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| JP2005336473A (ja) * | 2004-04-28 | 2005-12-08 | Ube Ind Ltd | 難燃性樹脂組成物 |
| JP5301828B2 (ja) * | 2004-06-22 | 2013-09-25 | スプレスタ エルエルシー | 熱可塑性ポリマーに使用するリン含有難燃剤 |
| JP4757538B2 (ja) * | 2005-05-24 | 2011-08-24 | 富士電機株式会社 | 難燃性樹脂加工品 |
| WO2005121234A2 (en) * | 2005-08-22 | 2005-12-22 | Solvay Advanced Polymers, L.L.C. | Flame retarded polymer composition with improved thermal stability |
| DE102005041966A1 (de) * | 2005-09-03 | 2007-03-08 | Clariant Produkte (Deutschland) Gmbh | Polymere Formmassen auf Basis von thermoplastischen Polyamiden |
| EP1788026B1 (de) * | 2005-11-18 | 2007-07-18 | EMS-Chemie AG | Verstärkte Polyamidformmassen |
| US8293364B2 (en) * | 2007-04-18 | 2012-10-23 | Kb Seiren, Ltd. | Highly shrinkable fiber |
| US20090030124A1 (en) * | 2007-07-06 | 2009-01-29 | Yige Yin | Flame resistant semiaromatic polyamide resin composition and articles therefrom |
| DE102007037019A1 (de) * | 2007-08-06 | 2009-02-12 | Clariant International Limited | Flammschutzmittelmischung für thermoplastische Polymere sowie flammwidrige Polymere |
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| EP2060596B1 (de) * | 2007-11-16 | 2012-06-13 | Ems-Patent Ag | Gefüllte Polyamidformmassen |
| EP3670590A1 (de) * | 2008-03-03 | 2020-06-24 | Clariant International Ltd | Verfahren zur herstellung flammwidriger, nicht korrosiver und gut fliessfähiger polyamidformmassen |
| KR100894884B1 (ko) * | 2008-04-30 | 2009-04-30 | 제일모직주식회사 | 난연성 열가소성 수지 조성물 |
| US8541489B2 (en) * | 2008-07-01 | 2013-09-24 | E I Du Pont De Nemours And Company | Flame resistant semiaromatic polyamide resin composition including zinc stannate, and articles therefrom |
| JP2010077194A (ja) * | 2008-09-24 | 2010-04-08 | Unitika Ltd | 難燃性ガラス繊維強化ポリアミド樹脂組成物 |
| US7989538B2 (en) * | 2008-10-30 | 2011-08-02 | E. I. Du Pont De Nemours And Company | Flame resistant semiaromatic polyamide resin compositions and processes for the preparation of the compositions exhibiting increased melt flow and articles therefrom |
| KR101323507B1 (ko) * | 2008-12-22 | 2013-10-29 | 미쓰이 가가쿠 가부시키가이샤 | 난연성 폴리아마이드 조성물 |
| FR2941460B1 (fr) * | 2009-01-28 | 2011-02-18 | Arkema France | Composition de polyamide ignifugee et renforcee |
| JP2010222486A (ja) * | 2009-03-24 | 2010-10-07 | Unitika Ltd | 難燃性ガラス繊維強化ポリアミド樹脂組成物 |
| US20100249292A1 (en) * | 2009-03-30 | 2010-09-30 | E. I. Du Pont De Nemours And Company | Flame resistant semicaromatic polyamide resin composition and articles therefrom |
| JP2010254760A (ja) * | 2009-04-22 | 2010-11-11 | Unitika Ltd | 難燃性強化ポリアミド樹脂組成物 |
| JP5496351B2 (ja) * | 2009-10-27 | 2014-05-21 | ビーエーエスエフ ソシエタス・ヨーロピア | 難燃剤を有する耐熱老化性ポリアミド |
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| CN102206411B (zh) * | 2010-03-30 | 2013-08-21 | E.I.内穆尔杜邦公司 | 阻燃性聚酰胺树脂组合物及包含该组合物的制品 |
| JP5717378B2 (ja) * | 2010-08-31 | 2015-05-13 | ユニチカ株式会社 | 難燃性強化ポリアミド樹脂組成物 |
| US20120080640A1 (en) * | 2010-09-30 | 2012-04-05 | E.I. Du Pont De Nemours And Company | Thermally conductive resin composition |
| CN102464881A (zh) * | 2010-11-10 | 2012-05-23 | 杜邦公司 | 无卤的阻燃聚酰胺组合物 |
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| TWI563034B (en) | 2011-05-13 | 2016-12-21 | Dsm Ip Assets Bv | Flame retardant semi-aromatic polyamide composition and moulded products made therefrom |
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| CN103073881B (zh) * | 2012-09-17 | 2014-12-24 | 天津金发新材料有限公司 | 尼龙组合物、制备方法及其应用 |
| KR101805230B1 (ko) | 2013-03-13 | 2017-12-05 | 롯데첨단소재(주) | 난연성 폴리아미드 수지 조성물 및 이를 이용한 성형품 |
| US20140288220A1 (en) | 2013-03-25 | 2014-09-25 | E I Du Pont De Nemours And Company | Heat resistant polyamide compositions |
| CN103214825B (zh) * | 2013-04-01 | 2015-09-23 | 金发科技股份有限公司 | 阻燃性聚酰胺树脂组合物、制备方法及由其制得的制品 |
| KR101570567B1 (ko) | 2013-04-30 | 2015-11-19 | 제일모직주식회사 | 광택성 및 저휨특성이 우수한 폴리아미드 수지조성물 |
| CN103408751B (zh) * | 2013-07-12 | 2016-01-06 | 东华大学 | 一种mca阻燃聚酰胺材料的制备方法 |
| EP3022247B1 (en) * | 2013-07-17 | 2020-03-18 | DSM IP Assets B.V. | Flame retarded thermoplastic moulding composition |
| US9765204B2 (en) | 2013-07-24 | 2017-09-19 | Lanxess Solutions Us Inc. | Halogen free high temperature polyamide compositions comprising phosphorus containing flame retardants |
| KR101735873B1 (ko) * | 2013-08-01 | 2017-05-15 | 롯데첨단소재(주) | 난연성 수지 조성물 |
| ES2767296T3 (es) * | 2013-11-28 | 2020-06-17 | Lanxess Deutschland Gmbh | Composiciones de poliamida |
| CN105829418B (zh) | 2013-12-20 | 2018-02-16 | 帝斯曼知识产权资产管理有限公司 | 细间距连接器插座 |
| WO2019060117A1 (en) | 2017-09-21 | 2019-03-28 | E. I. Du Pont De Nemours And Company | FLAME RETARDANT POLYAMIDE COMPOSITIONS |
| CN108794806B (zh) * | 2018-06-28 | 2019-07-02 | 浙江大学 | 二烷基二硫代次磷酸盐与无机亚磷酸盐协同的无卤阻燃体系及其应用 |
| KR102610650B1 (ko) | 2019-03-28 | 2023-12-05 | 써던 밀즈, 인코포레이티드 | 방염 직물 |
| JP7641950B2 (ja) * | 2019-09-06 | 2025-03-07 | ストラタシス，インコーポレイテッド | 難燃性ポリアミド系３ｄ印刷押出材料 |
| CN112409786B (zh) * | 2020-10-12 | 2022-05-20 | 金发科技股份有限公司 | 一种低模垢无卤阻燃热塑性聚酰胺组合物及其制备方法和应用 |
| CN112724667B (zh) * | 2020-12-16 | 2022-06-14 | 金发科技股份有限公司 | 一种聚酰胺模塑组合物及其制备方法和应用 |
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| JP2004300189A (ja) * | 2003-03-28 | 2004-10-28 | Asahi Kasei Chemicals Corp | ポリアミド難燃樹脂組成物 |
-
2004
- 2004-09-29 US US10/953,681 patent/US7294661B2/en not_active Expired - Lifetime
- 2004-10-01 JP JP2006534224A patent/JP4523004B2/ja not_active Expired - Lifetime
- 2004-10-01 CA CA2539773A patent/CA2539773C/en not_active Expired - Lifetime
- 2004-10-01 EP EP04794099.4A patent/EP1668074B2/en not_active Expired - Lifetime
- 2004-10-01 CN CNB200480028446XA patent/CN100451059C/zh not_active Expired - Lifetime
- 2004-10-01 WO PCT/US2004/032624 patent/WO2005033192A1/en not_active Ceased
Also Published As
| Publication number | Publication date |
|---|---|
| CN1860168A (zh) | 2006-11-08 |
| EP1668074B2 (en) | 2024-02-21 |
| US20050119379A1 (en) | 2005-06-02 |
| CN100451059C (zh) | 2009-01-14 |
| CA2539773C (en) | 2012-04-17 |
| WO2005033192A1 (en) | 2005-04-14 |
| US7294661B2 (en) | 2007-11-13 |
| EP1668074B1 (en) | 2016-08-17 |
| CA2539773A1 (en) | 2005-04-14 |
| JP2007507595A (ja) | 2007-03-29 |
| EP1668074A1 (en) | 2006-06-14 |
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