JP4482334B2 - エネルギー蓄積装置用高分子修飾電極、および該高分子修飾電極を基礎とした電気化学スーパーキャパシタ - Google Patents
エネルギー蓄積装置用高分子修飾電極、および該高分子修飾電極を基礎とした電気化学スーパーキャパシタ Download PDFInfo
- Publication number
- JP4482334B2 JP4482334B2 JP2003565005A JP2003565005A JP4482334B2 JP 4482334 B2 JP4482334 B2 JP 4482334B2 JP 2003565005 A JP2003565005 A JP 2003565005A JP 2003565005 A JP2003565005 A JP 2003565005A JP 4482334 B2 JP4482334 B2 JP 4482334B2
- Authority
- JP
- Japan
- Prior art keywords
- polymer
- transition metal
- metal
- redox
- electrodes
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 238000004146 energy storage Methods 0.000 title claims description 12
- 229920000642 polymer Polymers 0.000 claims description 125
- 229910052751 metal Inorganic materials 0.000 claims description 36
- 150000001875 compounds Chemical class 0.000 claims description 35
- 239000002184 metal Substances 0.000 claims description 33
- 239000000178 monomer Substances 0.000 claims description 31
- 229910052723 transition metal Inorganic materials 0.000 claims description 26
- 150000003624 transition metals Chemical class 0.000 claims description 23
- 239000002131 composite material Substances 0.000 claims description 19
- 150000004696 coordination complex Chemical class 0.000 claims description 17
- 239000000463 material Substances 0.000 claims description 17
- 239000003792 electrolyte Substances 0.000 claims description 16
- 238000007254 oxidation reaction Methods 0.000 claims description 13
- 230000003647 oxidation Effects 0.000 claims description 12
- 239000002262 Schiff base Substances 0.000 claims description 11
- 239000003990 capacitor Substances 0.000 claims description 11
- 239000002585 base Substances 0.000 claims description 10
- WEVYAHXRMPXWCK-UHFFFAOYSA-N Acetonitrile Chemical compound CC#N WEVYAHXRMPXWCK-UHFFFAOYSA-N 0.000 claims description 9
- 150000004753 Schiff bases Chemical class 0.000 claims description 9
- 150000002500 ions Chemical class 0.000 claims description 9
- 239000000758 substrate Substances 0.000 claims description 9
- 229910052742 iron Inorganic materials 0.000 claims description 5
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 claims description 4
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 4
- 229910052799 carbon Inorganic materials 0.000 claims description 4
- 239000002905 metal composite material Substances 0.000 claims description 4
- 229910052759 nickel Inorganic materials 0.000 claims description 4
- 239000003960 organic solvent Substances 0.000 claims description 4
- 229910052763 palladium Inorganic materials 0.000 claims description 4
- 239000002861 polymer material Substances 0.000 claims description 4
- 239000004020 conductor Substances 0.000 claims description 3
- 229910052802 copper Inorganic materials 0.000 claims description 3
- 150000003839 salts Chemical class 0.000 claims description 3
- HLZSFYMNDQDMLG-UHFFFAOYSA-N 2-hydroxybenzaldehyde;n,n,n',n'-tetramethylethane-1,2-diamine Chemical compound CN(C)CCN(C)C.OC1=CC=CC=C1C=O.OC1=CC=CC=C1C=O HLZSFYMNDQDMLG-UHFFFAOYSA-N 0.000 claims description 2
- PWRSNLQOHLSQCA-UHFFFAOYSA-N benzene-1,2-diamine;2-hydroxybenzaldehyde Chemical compound NC1=CC=CC=C1N.OC1=CC=CC=C1C=O.OC1=CC=CC=C1C=O PWRSNLQOHLSQCA-UHFFFAOYSA-N 0.000 claims description 2
- 239000000203 mixture Substances 0.000 claims description 2
- RUOJZAUFBMNUDX-UHFFFAOYSA-N propylene carbonate Chemical compound CC1COC(=O)O1 RUOJZAUFBMNUDX-UHFFFAOYSA-N 0.000 claims description 2
- 239000002904 solvent Substances 0.000 claims description 2
- DZLFLBLQUQXARW-UHFFFAOYSA-N tetrabutylammonium Chemical class CCCC[N+](CCCC)(CCCC)CCCC DZLFLBLQUQXARW-UHFFFAOYSA-N 0.000 claims description 2
- QEMXHQIAXOOASZ-UHFFFAOYSA-N tetramethylammonium Chemical class C[N+](C)(C)C QEMXHQIAXOOASZ-UHFFFAOYSA-N 0.000 claims description 2
- 239000002562 thickening agent Substances 0.000 claims description 2
- 239000002253 acid Chemical class 0.000 claims 2
- HXFYGSOGECBSOY-UHFFFAOYSA-N 2-[[2-[(2-hydroxyphenyl)methylideneamino]phenyl]iminomethyl]phenol Chemical group OC1=CC=CC=C1C=NC1=CC=CC=C1N=CC1=CC=CC=C1O HXFYGSOGECBSOY-UHFFFAOYSA-N 0.000 claims 1
- 239000006261 foam material Substances 0.000 claims 1
- WGHUNMFFLAMBJD-UHFFFAOYSA-N perchloric acid;tetraethylazanium Chemical compound OCl(=O)(=O)=O.CC[N+](CC)(CC)CC WGHUNMFFLAMBJD-UHFFFAOYSA-N 0.000 claims 1
- PNGLEYLFMHGIQO-UHFFFAOYSA-M sodium;3-(n-ethyl-3-methoxyanilino)-2-hydroxypropane-1-sulfonate;dihydrate Chemical compound O.O.[Na+].[O-]S(=O)(=O)CC(O)CN(CC)C1=CC=CC(OC)=C1 PNGLEYLFMHGIQO-UHFFFAOYSA-M 0.000 claims 1
- 239000003381 stabilizer Substances 0.000 claims 1
- 238000000034 method Methods 0.000 description 22
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 19
- 230000008569 process Effects 0.000 description 18
- 229920001940 conductive polymer Polymers 0.000 description 12
- 230000002829 reductive effect Effects 0.000 description 12
- 239000012634 fragment Substances 0.000 description 9
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 8
- -1 metal complex compound Chemical class 0.000 description 7
- 230000007935 neutral effect Effects 0.000 description 7
- KMBSSXSNDSJXCG-UHFFFAOYSA-N 1-[2-(2-hydroxyundecylamino)ethylamino]undecan-2-ol Chemical compound CCCCCCCCCC(O)CNCCNCC(O)CCCCCCCCC KMBSSXSNDSJXCG-UHFFFAOYSA-N 0.000 description 6
- 238000010586 diagram Methods 0.000 description 6
- 125000002524 organometallic group Chemical group 0.000 description 6
- 125000001424 substituent group Chemical group 0.000 description 6
- 238000012546 transfer Methods 0.000 description 6
- KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 description 5
- 238000004519 manufacturing process Methods 0.000 description 5
- 229910044991 metal oxide Inorganic materials 0.000 description 5
- 150000004706 metal oxides Chemical class 0.000 description 5
- 239000000126 substance Substances 0.000 description 5
- 230000007704 transition Effects 0.000 description 5
- VEUMANXWQDHAJV-UHFFFAOYSA-N 2-[2-[(2-hydroxyphenyl)methylideneamino]ethyliminomethyl]phenol Chemical compound OC1=CC=CC=C1C=NCCN=CC1=CC=CC=C1O VEUMANXWQDHAJV-UHFFFAOYSA-N 0.000 description 4
- 230000015572 biosynthetic process Effects 0.000 description 4
- 230000008859 change Effects 0.000 description 4
- 239000003446 ligand Substances 0.000 description 4
- 230000007246 mechanism Effects 0.000 description 4
- 150000002739 metals Chemical class 0.000 description 4
- 229910052697 platinum Inorganic materials 0.000 description 4
- 238000006479 redox reaction Methods 0.000 description 4
- 230000009467 reduction Effects 0.000 description 4
- 238000006722 reduction reaction Methods 0.000 description 4
- 239000003575 carbonaceous material Substances 0.000 description 3
- 238000013461 design Methods 0.000 description 3
- 239000008151 electrolyte solution Substances 0.000 description 3
- 229920002521 macromolecule Polymers 0.000 description 3
- 229910052707 ruthenium Inorganic materials 0.000 description 3
- 238000003860 storage Methods 0.000 description 3
- IWZAEAAZXRSXPX-UHFFFAOYSA-N 2-(4-ethenylpyridin-2-yl)-4-methylpyridine Chemical group CC1=CC=NC(C=2N=CC=C(C=C)C=2)=C1 IWZAEAAZXRSXPX-UHFFFAOYSA-N 0.000 description 2
- 229910006148 NiII Inorganic materials 0.000 description 2
- 239000002322 conducting polymer Substances 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 229910052736 halogen Inorganic materials 0.000 description 2
- 150000002367 halogens Chemical class 0.000 description 2
- 230000003993 interaction Effects 0.000 description 2
- 229910052762 osmium Inorganic materials 0.000 description 2
- 230000000737 periodic effect Effects 0.000 description 2
- 229920006254 polymer film Polymers 0.000 description 2
- 238000006116 polymerization reaction Methods 0.000 description 2
- 239000002994 raw material Substances 0.000 description 2
- 238000011946 reduction process Methods 0.000 description 2
- 230000002441 reversible effect Effects 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- 239000000243 solution Substances 0.000 description 2
- DKPSSMOJHLISJI-UHFFFAOYSA-N 1,10-phenanthrolin-5-amine Chemical compound C1=CC=C2C(N)=CC3=CC=CN=C3C2=N1 DKPSSMOJHLISJI-UHFFFAOYSA-N 0.000 description 1
- NAZZKEZTSOOCSZ-UHFFFAOYSA-N 4-methyl-1,10-phenanthroline Chemical compound C1=CC2=CC=CN=C2C2=C1C(C)=CC=N2 NAZZKEZTSOOCSZ-UHFFFAOYSA-N 0.000 description 1
- XDUUQOQFSWSZSM-UHFFFAOYSA-N 5-chloro-1,10-phenanthroline Chemical compound C1=CC=C2C(Cl)=CC3=CC=CN=C3C2=N1 XDUUQOQFSWSZSM-UHFFFAOYSA-N 0.000 description 1
- 229920000049 Carbon (fiber) Polymers 0.000 description 1
- VEQPNABPJHWNSG-UHFFFAOYSA-N Nickel(2+) Chemical compound [Ni+2] VEQPNABPJHWNSG-UHFFFAOYSA-N 0.000 description 1
- KJTLSVCANCCWHF-UHFFFAOYSA-N Ruthenium Chemical compound [Ru] KJTLSVCANCCWHF-UHFFFAOYSA-N 0.000 description 1
- 229910021607 Silver chloride Inorganic materials 0.000 description 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- HSFWRNGVRCDJHI-UHFFFAOYSA-N alpha-acetylene Natural products C#C HSFWRNGVRCDJHI-UHFFFAOYSA-N 0.000 description 1
- 238000004458 analytical method Methods 0.000 description 1
- 150000001450 anions Chemical class 0.000 description 1
- 239000003125 aqueous solvent Substances 0.000 description 1
- 238000006664 bond formation reaction Methods 0.000 description 1
- 229910052793 cadmium Inorganic materials 0.000 description 1
- BDOSMKKIYDKNTQ-UHFFFAOYSA-N cadmium atom Chemical compound [Cd] BDOSMKKIYDKNTQ-UHFFFAOYSA-N 0.000 description 1
- 239000004917 carbon fiber Substances 0.000 description 1
- 150000001768 cations Chemical class 0.000 description 1
- 238000007385 chemical modification Methods 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 239000002482 conductive additive Substances 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 238000009792 diffusion process Methods 0.000 description 1
- 238000007599 discharging Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000006056 electrooxidation reaction Methods 0.000 description 1
- 239000006260 foam Substances 0.000 description 1
- 230000003100 immobilizing effect Effects 0.000 description 1
- 230000009878 intermolecular interaction Effects 0.000 description 1
- 229910021645 metal ion Inorganic materials 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 150000002902 organometallic compounds Chemical class 0.000 description 1
- 230000033116 oxidation-reduction process Effects 0.000 description 1
- 230000001590 oxidative effect Effects 0.000 description 1
- 230000036961 partial effect Effects 0.000 description 1
- 230000035515 penetration Effects 0.000 description 1
- 229920001197 polyacetylene Polymers 0.000 description 1
- 229920000767 polyaniline Polymers 0.000 description 1
- 229920000128 polypyrrole Polymers 0.000 description 1
- 229920000123 polythiophene Polymers 0.000 description 1
- 230000027756 respiratory electron transport chain Effects 0.000 description 1
- 229910001925 ruthenium oxide Inorganic materials 0.000 description 1
- WOCIAKWEIIZHES-UHFFFAOYSA-N ruthenium(iv) oxide Chemical compound O=[Ru]=O WOCIAKWEIIZHES-UHFFFAOYSA-N 0.000 description 1
- 229910052709 silver Inorganic materials 0.000 description 1
- 239000004332 silver Substances 0.000 description 1
- HKZLPVFGJNLROG-UHFFFAOYSA-M silver monochloride Chemical compound [Cl-].[Ag+] HKZLPVFGJNLROG-UHFFFAOYSA-M 0.000 description 1
- 239000011232 storage material Substances 0.000 description 1
- 239000003115 supporting electrolyte Substances 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- KBLZDCFTQSIIOH-UHFFFAOYSA-M tetrabutylazanium;perchlorate Chemical compound [O-]Cl(=O)(=O)=O.CCCC[N+](CCCC)(CCCC)CCCC KBLZDCFTQSIIOH-UHFFFAOYSA-M 0.000 description 1
- WGHUNMFFLAMBJD-UHFFFAOYSA-M tetraethylazanium;perchlorate Chemical compound [O-]Cl(=O)(=O)=O.CC[N+](CC)(CC)CC WGHUNMFFLAMBJD-UHFFFAOYSA-M 0.000 description 1
- 230000036962 time dependent Effects 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
Images
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M6/00—Primary cells; Manufacture thereof
- H01M6/30—Deferred-action cells
- H01M6/36—Deferred-action cells containing electrolyte and made operational by physical means, e.g. thermal cells
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01G—CAPACITORS; CAPACITORS, RECTIFIERS, DETECTORS, SWITCHING DEVICES, LIGHT-SENSITIVE OR TEMPERATURE-SENSITIVE DEVICES OF THE ELECTROLYTIC TYPE
- H01G11/00—Hybrid capacitors, i.e. capacitors having different positive and negative electrodes; Electric double-layer [EDL] capacitors; Processes for the manufacture thereof or of parts thereof
- H01G11/02—Hybrid capacitors, i.e. capacitors having different positive and negative electrodes; Electric double-layer [EDL] capacitors; Processes for the manufacture thereof or of parts thereof using combined reduction-oxidation reactions, e.g. redox arrangement or solion
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01G—CAPACITORS; CAPACITORS, RECTIFIERS, DETECTORS, SWITCHING DEVICES, LIGHT-SENSITIVE OR TEMPERATURE-SENSITIVE DEVICES OF THE ELECTROLYTIC TYPE
- H01G11/00—Hybrid capacitors, i.e. capacitors having different positive and negative electrodes; Electric double-layer [EDL] capacitors; Processes for the manufacture thereof or of parts thereof
- H01G11/22—Electrodes
- H01G11/26—Electrodes characterised by their structure, e.g. multi-layered, porosity or surface features
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01G—CAPACITORS; CAPACITORS, RECTIFIERS, DETECTORS, SWITCHING DEVICES, LIGHT-SENSITIVE OR TEMPERATURE-SENSITIVE DEVICES OF THE ELECTROLYTIC TYPE
- H01G11/00—Hybrid capacitors, i.e. capacitors having different positive and negative electrodes; Electric double-layer [EDL] capacitors; Processes for the manufacture thereof or of parts thereof
- H01G11/22—Electrodes
- H01G11/30—Electrodes characterised by their material
- H01G11/48—Conductive polymers
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01G—CAPACITORS; CAPACITORS, RECTIFIERS, DETECTORS, SWITCHING DEVICES, LIGHT-SENSITIVE OR TEMPERATURE-SENSITIVE DEVICES OF THE ELECTROLYTIC TYPE
- H01G9/00—Electrolytic capacitors, rectifiers, detectors, switching devices, light-sensitive or temperature-sensitive devices; Processes of their manufacture
- H01G9/004—Details
- H01G9/022—Electrolytes; Absorbents
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01G—CAPACITORS; CAPACITORS, RECTIFIERS, DETECTORS, SWITCHING DEVICES, LIGHT-SENSITIVE OR TEMPERATURE-SENSITIVE DEVICES OF THE ELECTROLYTIC TYPE
- H01G9/00—Electrolytic capacitors, rectifiers, detectors, switching devices, light-sensitive or temperature-sensitive devices; Processes of their manufacture
- H01G9/004—Details
- H01G9/04—Electrodes or formation of dielectric layers thereon
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01G—CAPACITORS; CAPACITORS, RECTIFIERS, DETECTORS, SWITCHING DEVICES, LIGHT-SENSITIVE OR TEMPERATURE-SENSITIVE DEVICES OF THE ELECTROLYTIC TYPE
- H01G9/00—Electrolytic capacitors, rectifiers, detectors, switching devices, light-sensitive or temperature-sensitive devices; Processes of their manufacture
- H01G9/22—Devices using combined reduction and oxidation, e.g. redox arrangement or solion
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/05—Accumulators with non-aqueous electrolyte
- H01M10/056—Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes
- H01M10/0564—Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes the electrolyte being constituted of organic materials only
- H01M10/0566—Liquid materials
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/13—Electrodes for accumulators with non-aqueous electrolyte, e.g. for lithium-accumulators; Processes of manufacture thereof
- H01M4/137—Electrodes based on electro-active polymers
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/36—Selection of substances as active materials, active masses, active liquids
- H01M4/60—Selection of substances as active materials, active masses, active liquids of organic compounds
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/36—Selection of substances as active materials, active masses, active liquids
- H01M4/60—Selection of substances as active materials, active masses, active liquids of organic compounds
- H01M4/602—Polymers
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/36—Selection of substances as active materials, active masses, active liquids
- H01M4/60—Selection of substances as active materials, active masses, active liquids of organic compounds
- H01M4/602—Polymers
- H01M4/606—Polymers containing aromatic main chain polymers
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/10—Energy storage using batteries
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/13—Energy storage using capacitors
Landscapes
- Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Power Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Microelectronics & Electronic Packaging (AREA)
- Materials Engineering (AREA)
- Manufacturing & Machinery (AREA)
- Inorganic Chemistry (AREA)
- General Physics & Mathematics (AREA)
- Condensed Matter Physics & Semiconductors (AREA)
- Physics & Mathematics (AREA)
- Electric Double-Layer Capacitors Or The Like (AREA)
- Secondary Cells (AREA)
- Cell Electrode Carriers And Collectors (AREA)
- Battery Electrode And Active Subsutance (AREA)
Description
2)酸化還元高分子━主に高分子鎖の隣接片間における酸化還元反応により電子移動が内部で生ずる化合物
“有機金属”の代表例として、ポリアセチレン、ポリピロール、ポリチオフェン、及びポリアニリンなどがある。部分的に酸化した形態においてこれらの高分子はさらに高い導電性を示す。そのため、これらの高分子は、高分子の正“イオン”とその構造全体に均一に分布する対イオンとで構成される塩と見なすことができる(これらの対イオンは、システム全体を電気的に中性に保つ働きをする)。
Me=Co,Fe,Ru,Os;
v−bpy=4−ビニル-4’-メチル−2,2’−ビピリジン;
L=v−bpy(4−ビニル−4’−メチル−2,2’−ビピリジン),フェナントロリン−5,6−ジオン,4−メチルフェナントロリン,5−アミノフェナントロリン,5−クロロフェナントロリン;(x+y=3)。
1. これらの高分子は本質的に導電性を持つため、電流供給用の基質が不要となる。
2. 高分子素材の価格は、スーパーキャパシタで使用される大部分の酸化還元素材に比べて少なくとも一桁安価である。
3. 多くの中間合成手順を経ることなく、導電性高分子素材を電極表面上で直接形成できる。
4. 導電性高分子素材を用いることで、(二重電極層での充電/放電過程に基づく)容量性スーパーキャパシタまたは“二重層”スーパーキャパシタ、および(電極上に固定化された電気的に活性化した物質の酸化/還元過程に基づく)“擬似容量性”スーパーキャパシタまたはファラデー過程によるスーパーキャパシタの、既知の両タイプのスーパーキャパシタが製造可能となる。
5. 安定度では酸化素材に劣るものの、高分子を用いて使用寿命の長い(最長105−106サイクル)エネルギー蓄積システムを製造することが可能となる。
2. 特許文献4
3. 特許文献5
4. 非特許文献1 p. 319, 320, 321
5. 非特許文献6
構造のYに対して、
R=OC2H5,R’=H,単量体[Me(C2H5−Salphen)],またはN,N’−フェニレン−ビス(3−エトキシサリチリデン−イミナト)金属(II);
R=OCH3,R’=H,単量体[Me(CH3O−Salphen)],またはN,N’−フェニレン−ビス(3−メトキシサリチリデン−イミナト)金属(II);
R=H,R’=Cl,単量体[Me(Cl−Salphen)],またはN,N’−フェニレン−ビス(5−クロロサリチリデン−イミナト)金属(II);
R=H,R’=Br,単量体[Me(Br−Salphen)],またはN,N’−フェニレン−ビス(5−ブロムサリチリデン−イミナト)金属(II);
R,R’=H,単量体[Me(SalEn)],またはN,N’−フェニレン−ビス(サリチリデン−イミナト)金属(II);
構造のYに対して、
━CH2━CH2━
以下をRおよびR’として使用可能である:
R=OC2H5,R’=H,単量体[Me(C2H5O−SalEn)],またはN,N’−エチレン−ビス(3−エトキシサリチリデン−イミナト)金属(II);
R=OCH3,R’=H,単量体[Me(CH3O−SalEn)],またはN,N’−エチレン−ビス(3−メトキシサリチリデン−イミナト)金属(II);
R=H,R’=Cl,単量体[Me(Cl−SalEn)],またはN,N’−エチレン−ビス(5−クロロサリチリデン−イミナト)金属(II);
R=H,R’=Br,単量体[Me(Br−SalEn)],またはN,N’−エチレン−ビス(5−ブロモサリチリデン−イミナト)金属(II);
R,R’=H,単量体[Me(SalEn)],またはN,N’−エチレン−ビス(サリチリデン−イミナト)金属(II);
構造のYに対して、
R=OC2H5,R’=H,単量体[Me(C2H5O−Saltmen)],またはN,N’−テトラメチルエチレン−ビス(3−エトキシサリチリデン−イミナト)金属(II);
R=OCH3,R’=H,単量体[Me(CH3O−Saltmen)],またはN,N’−テトラメチルエチレン−ビス(3−メトキシサリチリデン−イミナト)金属(II);
R=H,R’=Cl,単量体[Me(Cl−Saltmen)],またはN,N’−テトラメチルエチレン−ビス(5−クロロサリチリデン−イミナト)金属(II);
R=H,R’=Br,単量体[Me(Br−Saltmen)],またはN,N’−テトラメチルエチレン−ビス(5−ブロモサリチリデン−イミナト)金属(II);
R,R’=H,単量体[Me(Saltmen)],またはN,N’−テトラメチルエチレン−ビス(サリチリデン−イミナト)金属(II);
置換基を有する四座配位シッフ塩基を持つ高分子金属錯体は、遷移金属の該高分子複合化合物として使用可能である。
例えば、poly−[Me(R,R’−Salen)]のグループに属する化合物は、
ここで: Me−遷移金属;
Salen−シッフ塩基中のビス−(サリチルアルデヒド)−エチレンジアミンの残留物;
R=Hまたは電子供与性置換基、例:CH3O−,C2H5O−,HO−または−CH3;
R’=HまたはHlg(ハロゲン)、である
そのような高分子金属錯体として使用可能で、この化合物は以下のような構造をとる:
この化合物は以下のような構造をとる:
この化合物は以下のような構造をとる:
Ni2+−中性状態;
Ni3+−酸化状態;
Ni+−還元状態。
種類I:両電極が同一(すなわち、1つの同一高分子がそれらの電極基材上に塗布されている−例:poly−[Ni(CH3O−Salen)])完全に充電された状態では、一方の電極が完全に酸化され(Ni3+)、他方の電極は帯電していない(中性)状態となる(Ni2+)。
種類 II :2つの異なる電極(すなわち、異なる高分子がそれらの表面に塗布されている−例:poly−[Ni(CH3O−Salen)] が負電極(アノード)表面に塗布され、poly−[Pd(CH3O−Salen)]が正電極(カソード)表面に塗布される)
種類 III:酸化形態の高分子が一方の電極に塗布され、還元形態の同一高分子が他方の電極に塗布される−例:poly−[Ni(CH3O−Salen)。完全に充電された状態では、一方の電極が完全に酸化され(Ni3+)、他方の電極は完全に還元されている(Ni+)。
Claims (20)
- 導電基材と、該導電基材上のエネルギー集積酸化還元高分子層で、該酸化還元高分子に少なくとも2つの異なった酸化度を有する遷移金属高分子複合化合物を含み、該高分子複合化合物が積層遷移金属複合単量体で形成された該高分子層を有する該電極を少なくとも1つ備える、少なくとも2つの電極を含むエネルギー蓄積装置であって、
該遷移金属高分子複合化合物は、ポリ−[Me(R,R’−Saltmen)]のグループに属する化合物が置換基を有する四座配位シッフ塩基を持つ該高分子金属錯体およびポリ−[Me(R,R’−Salphen)]のグループに属する化合物が置換基を有する四座配位シッフ塩基を持つ該高分子金属錯体からなる群から選択される遷移金属高分子複合化合物であり、
ここで、該ポリ−[Me(R,R’−Saltmen)]のグループに属する化合物が置換基を有する四座配位シッフ塩基を持つ該高分子金属錯体にあっては、遷移金属をMe、シッフ塩基中のビス−(サリチルアルデヒド)−テトラメチルエチレンジアミンの残基をSaltmen、とし、CH 3 O−またはC 2 H 5 O−、HO−、−CH 3 を例とする電子供与性置換基またはHをRとし、HまたはHlgをR’とし、
ここで該化合物は下記の式を有し、n=2ないし200000であり、
ここで該化合物は下記の式を有し、n=2ないし200000である
- 請求項1に従う装置に於いて、該遷移金属高分子複合化合物が平面から0.1nm以上ははずれない平面構造および共役したπ結合の側鎖システムを備えた積層遷移金属複合単量体を持つ装置。
- 請求項1に従う装置に於いて、該エネルギー集積酸化還元高分子層の厚さが1nmから20μmの範囲内である装置。
- 請求項2に従う装置に於いて、遷移金属の該高分子複合化合物が置換基をもつ四座配位シッフ塩基を有する高分子金属錯体を持つ装置。
- 請求項1に従う装置に於いて、Ni,Pd,Co,Cu,Feのグループに属する金属が該高分子複合化合物内の遷移金属として使用されている装置。
- 請求項1に従う装置に於いて、該導電基材が炭素を素材としており、平坦または処理された表面を持つ装置。
- 請求項1に従う装置に於いて、該導電基材が炭素を素材としており、コーティングされていないか金属によりコーティングされている平面または処理された表面を持つ装置。
- 請求項1に従う装置に於いて、該導電基材が金属を素材としており、平面または処理された表面を持つ装置。
- 請求項1に従う装置に於いて、該導電基材がフィルム状または多孔質構造、発泡材の誘電性高分子素材としている装置。
- 請求項1に従う装置に於いて、ケーシングおよび該ケーシング内に間隔を置いて設置された前記1つの該電極とそれ以外のもの、該電極間を満たす電解質を含む電気化学キャパシタまたは電池を備える装置。
- 請求項10に従う装置に於いて、導電基材および、該導電基材上のエネルギー集積酸化還元高分子層で、該酸化還元高分子に少なくとも2通りの酸化度を持つ遷移金属高分子複合化合物を含み、該高分子複合化合物が積層遷移金属複合単量体で形成された該高分子層からなる、2つの該電極以外のものを備える装置。
- 請求項10に従う装置に於いて、その電解質が−3.0から+1.5Vの電位差において電気化学的に不活性であり、またその電解質は有機溶媒中の濃度が0.01mol/lを下回らない溶液であり個々の直径が0.6nm以下であるイオンを含んでいる装置。
- 請求項12に従う装置に於いて、テトラブチルアンモニウムまたはテトラメチルアンモニウム、またはテトラエチルアンモニウムの過塩素酸もしくはテトラフルオロホウ酸、もしくは六フッ化リン酸のグループに属する酸の塩のイオンが電解質中の該イオンとして使用されている装置。
- 請求項12に従う装置に於いて、アセトニトリル、ジメチルケトン、炭酸プロピレンのグループに属する該溶媒が該有機溶媒として使用されている装置。
- 請求項10に従う装置に於いて、該電解質の構成物に安定剤をさらに含む装置。
- 請求項10に従う装置に於いて、電解質をゲル状態に変換する濃厚剤をさらに含む装置。
- 請求項10に従う装置に於いて、電極間をカソード空間とアノード空間に分離する隔膜をさらに含む装置。
- 請求項10に従う装置に於いて、該キャパシタのケーシングが耐電解質の材料を素材としている装置。
- 請求項10に従う装置に於いて、該キャパシタのケーシングに設置され、電解質を注ぐためと圧力の解放を補助する構成要素をさらに含む装置。
- 請求項10に従う装置に於いて、該2電極の前記以外のものが導電性の素材で形成されている装置。
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US35168102P | 2002-01-25 | 2002-01-25 | |
PCT/US2003/001918 WO2003065536A2 (en) | 2002-01-25 | 2003-01-23 | Polymer-modified electrode for energy storage devices and electrochemical supercapacitor based on said polymer-modified electrode |
Publications (2)
Publication Number | Publication Date |
---|---|
JP2005516424A JP2005516424A (ja) | 2005-06-02 |
JP4482334B2 true JP4482334B2 (ja) | 2010-06-16 |
Family
ID=27663014
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP2003565005A Expired - Fee Related JP4482334B2 (ja) | 2002-01-25 | 2003-01-23 | エネルギー蓄積装置用高分子修飾電極、および該高分子修飾電極を基礎とした電気化学スーパーキャパシタ |
Country Status (9)
Country | Link |
---|---|
US (1) | US6795293B2 (ja) |
EP (1) | EP1500151B1 (ja) |
JP (1) | JP4482334B2 (ja) |
KR (1) | KR101128198B1 (ja) |
AU (1) | AU2003205280A1 (ja) |
CA (1) | CA2474484C (ja) |
DK (1) | DK1500151T3 (ja) |
SI (1) | SI1500151T1 (ja) |
WO (1) | WO2003065536A2 (ja) |
Families Citing this family (26)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
KR100755284B1 (ko) | 2002-09-25 | 2007-09-05 | 젠쓰리 파트너스 인코포레이티드 | 에너지 저장 장치용 전극의 제조방법 |
AU2003269310A1 (en) * | 2002-10-07 | 2004-04-23 | Gen3 Partners, Incl. | Method of manufacture of an electrode for electrochemical devices |
US7084053B2 (en) * | 2003-09-30 | 2006-08-01 | Intel Corporation | Unidirectionally conductive materials for interconnection |
DK1678728T3 (da) | 2003-10-14 | 2009-12-14 | Gen3 Partners Inc | Elektrode til energilagringsindretninger og elektrokemisk superkondensator baseret på denne elektrode |
WO2005084378A2 (en) * | 2004-03-05 | 2005-09-15 | Board Of Regents Of University Of Texas System | Material and device properties modification by electrochemical charge injection in the absence of contacting electrolyte for either local spatial or final states |
US7429404B2 (en) * | 2004-07-30 | 2008-09-30 | University Of Utah Research Foundation | Methods of selectively incorporating metals onto substrates |
EP1807889A4 (en) * | 2004-09-30 | 2009-12-16 | Nippon Chemicon | PROCESS FOR PRODUCING ELECTRODE MATERIAL |
JP4783632B2 (ja) * | 2004-09-30 | 2011-09-28 | 日本ケミコン株式会社 | 電極材料および電気化学素子 |
EP1889270A4 (en) * | 2005-06-10 | 2010-05-26 | Nippon Chemicon | METHODS FOR PRODUCING ELECTRODE FOR ELECTROCHEMICAL CELL AND THEREOF WITH ELECTRODE |
WO2007112075A2 (en) * | 2006-03-24 | 2007-10-04 | Gen 3 Partners, Inc. | Method for manufacturing an energy storage device |
JP5151108B2 (ja) * | 2006-09-29 | 2013-02-27 | 日本ケミコン株式会社 | 電極活物質 |
JP5109323B2 (ja) * | 2006-09-29 | 2012-12-26 | 日本ケミコン株式会社 | 電気化学素子用電極及びその製造方法、並びに電気化学素子 |
JP5282259B2 (ja) * | 2007-02-16 | 2013-09-04 | 国立大学法人名古屋大学 | 分子クラスター二次電池 |
US8084735B2 (en) * | 2008-09-25 | 2011-12-27 | Ut-Battelle, Llc | Pulsed voltage electrospray ion source and method for preventing analyte electrolysis |
US8003937B2 (en) * | 2008-09-25 | 2011-08-23 | Ut-Battelle | Electrospray ion source with reduced analyte electrochemistry |
US20100208413A1 (en) * | 2008-12-04 | 2010-08-19 | Lumimove, Inc., D/B/A Crosslink | Intrinsically conductive polymers |
JP5800467B2 (ja) * | 2010-05-10 | 2015-10-28 | ダイハツ工業株式会社 | 酸素還元触媒および燃料電池 |
US9208952B2 (en) | 2011-07-11 | 2015-12-08 | Ihi Corporation | Electric double layer capacitor material |
JP2014063824A (ja) * | 2012-09-20 | 2014-04-10 | Murata Mfg Co Ltd | 電気二重層コンデンサ |
KR20170047279A (ko) * | 2014-08-19 | 2017-05-04 | 파워머스 인코포레이티드 | 다공성 금속-탄소 재료의 제조 방법 |
JP6439490B2 (ja) * | 2015-02-20 | 2018-12-19 | 株式会社豊田中央研究所 | 蓄電デバイス |
RU2618232C1 (ru) * | 2015-12-28 | 2017-05-03 | Пауэрмерс Инк. | Катод для металло-воздушных источников тока и металло-воздушный источник тока, включающий этот катод |
EP3282461B1 (en) | 2016-08-12 | 2020-05-06 | Commissariat à l'Energie Atomique et aux Energies Alternatives | Electrode coated with redox polymers containing dione units, preparation method and uses thereof |
JP6982244B2 (ja) * | 2018-05-18 | 2021-12-17 | 日本電信電話株式会社 | リチウム二次電池 |
RU2762028C2 (ru) * | 2018-12-05 | 2021-12-14 | Федеральное государственное бюджетное образовательное учреждение высшего образования "Санкт-Петербургский государственный университет" (СПбГУ) | Электроактивный полимер, способ его получения и электрод для энергозапасающих устройств на его основе |
BR102021002013A2 (pt) * | 2021-02-03 | 2022-08-16 | Universidade Estadual Paulista Julio De Mesquita Filho | Hipercapacitor molecular |
Family Cites Families (14)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR2527844B1 (fr) * | 1982-06-01 | 1986-01-24 | Thomson Csf | Dispositif electrochromique pouvant servir au stockage d'energie et systeme d'affichage electrochromique |
US4451270A (en) * | 1982-06-30 | 1984-05-29 | Bend Research, Inc. | Absorption process for producing oxygen and nitrogen and solution therefor |
DE3244900A1 (de) * | 1982-12-04 | 1984-06-07 | Basf Ag, 6700 Ludwigshafen | Batterie oder elektrochemischer speicher auf basis von elektrochemisch oxidierbaren und/oder reduzierbaren polymeren |
DE3406472A1 (de) * | 1984-02-23 | 1985-08-29 | Basf Ag, 6700 Ludwigshafen | Elektrochemische zelle oder batterie |
JPS60180064A (ja) | 1984-02-24 | 1985-09-13 | Tdk Corp | 2次電池 |
US5527640A (en) * | 1992-11-25 | 1996-06-18 | The Regents Of The University Of California, Office Of Technology Transfer | Electrochemical supercapacitors |
US5340368A (en) * | 1993-08-04 | 1994-08-23 | Valence Technology, Inc. | Method for in situ preparation of an electrode composition |
EP0699349B1 (fr) * | 1994-03-21 | 2007-10-10 | Centre National De La Recherche Scientifique (Cnrs) | Materiau a conduction ionique presentant de bonnes proprietes anti-corrosion |
US5968745A (en) * | 1995-06-27 | 1999-10-19 | The University Of North Carolina At Chapel Hill | Polymer-electrodes for detecting nucleic acid hybridization and method of use thereof |
US5840443A (en) * | 1995-07-31 | 1998-11-24 | Midwest Research Institute | Redox polymer electrodes for advanced batteries |
EP0850933A1 (fr) * | 1996-12-30 | 1998-07-01 | Centre National De La Recherche Scientifique (Cnrs) | Sels d'anions pentacycliques ou dérivés de tétrazapentalène, et leurs utilisations comme matériaux à conduction ionique |
US5729427A (en) * | 1997-01-08 | 1998-03-17 | Motorola, Inc. | Macrocyclic complex modified electrodes and capacitors made therefrom |
US5875092A (en) * | 1997-02-07 | 1999-02-23 | The United States Of America As Represented By The Secretary Of The Army | Proton inserted ruthenium oxide electrode material for electrochemical capacitors |
US5948562A (en) * | 1997-11-03 | 1999-09-07 | Motorola, Inc. | Energy storage device |
-
2003
- 2003-01-23 AU AU2003205280A patent/AU2003205280A1/en not_active Abandoned
- 2003-01-23 DK DK03703955.9T patent/DK1500151T3/da active
- 2003-01-23 JP JP2003565005A patent/JP4482334B2/ja not_active Expired - Fee Related
- 2003-01-23 KR KR1020047011538A patent/KR101128198B1/ko not_active IP Right Cessation
- 2003-01-23 CA CA2474484A patent/CA2474484C/en not_active Expired - Fee Related
- 2003-01-23 US US10/350,167 patent/US6795293B2/en not_active Expired - Lifetime
- 2003-01-23 WO PCT/US2003/001918 patent/WO2003065536A2/en active Application Filing
- 2003-01-23 SI SI200332367T patent/SI1500151T1/sl unknown
- 2003-01-23 EP EP03703955.9A patent/EP1500151B1/en not_active Expired - Lifetime
Also Published As
Publication number | Publication date |
---|---|
KR20040088042A (ko) | 2004-10-15 |
US20040057191A1 (en) | 2004-03-25 |
JP2005516424A (ja) | 2005-06-02 |
EP1500151A2 (en) | 2005-01-26 |
AU2003205280A1 (en) | 2003-09-02 |
KR101128198B1 (ko) | 2012-03-23 |
CA2474484C (en) | 2013-03-26 |
WO2003065536A2 (en) | 2003-08-07 |
DK1500151T3 (en) | 2014-07-21 |
SI1500151T1 (sl) | 2014-08-29 |
WO2003065536A3 (en) | 2004-01-29 |
EP1500151A4 (en) | 2009-02-11 |
US6795293B2 (en) | 2004-09-21 |
EP1500151B1 (en) | 2014-04-30 |
CA2474484A1 (en) | 2003-08-07 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
JP4482334B2 (ja) | エネルギー蓄積装置用高分子修飾電極、および該高分子修飾電極を基礎とした電気化学スーパーキャパシタ | |
US7382603B2 (en) | Electrode for energy storage devices and electrochemical supercapacitor based on said electrode | |
Kurra et al. | All conducting polymer electrodes for asymmetric solid-state supercapacitors | |
Krishnamoorthy et al. | A high‐energy aqueous sodium‐ion capacitor with nickel hexacyanoferrate and graphene electrodes | |
US20050008934A1 (en) | Redox active reversible electrode and novel battery using the same | |
Wu et al. | Criteria appointing the highest acceptable cell voltage of asymmetric supercapacitors | |
JP2007508709A5 (ja) | ||
Lee et al. | Pen lithography for flexible microsupercapacitors with layer-by-layer assembled graphene flake/PEDOT nanocomposite electrodes | |
Chepurnaya et al. | Redox-conducting polymers based on metal-salen complexes for energy storage applications | |
EP3439086B1 (en) | Aqueous secondary cell | |
Zhang et al. | Shape-tailorable high-energy asymmetric micro-supercapacitors based on plasma reduced and nitrogen-doped graphene oxide and MoO 2 nanoparticles | |
Palaniappan et al. | Novel chemically synthesized polyaniline electrodes containing a fluoroboric acid dopant for supercapacitors | |
JP4553732B2 (ja) | 電気化学装置用電極の製造方法 | |
Ega et al. | Designing quinone-dopamine-based conjugates as six electron system for high-performance hybrid electrode | |
Sahalianov et al. | Volumetric double-layer charge storage in composites based on conducting polymer PEDOT and cellulose | |
Chidembo et al. | Electrochemical capacitive behaviour of multiwalled carbon nanotubes modified with electropolymeric films of nickel tetraaminophthalocyanine | |
US7508650B1 (en) | Electrode for electrochemical capacitor | |
US7888229B2 (en) | Method for manufacturing an energy storage device | |
JP4553731B2 (ja) | 電気化学コンデンサ及びその使用方法 | |
JP6242577B2 (ja) | レドックスポリマーエネルギー貯蔵システム | |
Lee et al. | Self-assembled Prussian blue–polypyrrole nanocomposites for energy storage application | |
WO2024147239A1 (ja) | 二次電池用電解液および二次電池 | |
JP2000315527A (ja) | 非水電気化学キャパシタ | |
JP2005311392A (ja) | 分極性電極 | |
WO2024102092A1 (en) | An electrode providing high energy density and operating potential, and a capacitor comprising said electrode |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
A621 | Written request for application examination |
Free format text: JAPANESE INTERMEDIATE CODE: A621 Effective date: 20060112 |
|
A977 | Report on retrieval |
Free format text: JAPANESE INTERMEDIATE CODE: A971007 Effective date: 20080723 |
|
A131 | Notification of reasons for refusal |
Free format text: JAPANESE INTERMEDIATE CODE: A131 Effective date: 20080902 |
|
A02 | Decision of refusal |
Free format text: JAPANESE INTERMEDIATE CODE: A02 Effective date: 20090821 |
|
A521 | Request for written amendment filed |
Free format text: JAPANESE INTERMEDIATE CODE: A523 Effective date: 20091221 |
|
RD13 | Notification of appointment of power of sub attorney |
Free format text: JAPANESE INTERMEDIATE CODE: A7433 Effective date: 20091222 |
|
A521 | Request for written amendment filed |
Free format text: JAPANESE INTERMEDIATE CODE: A821 Effective date: 20091222 |
|
A911 | Transfer to examiner for re-examination before appeal (zenchi) |
Free format text: JAPANESE INTERMEDIATE CODE: A911 Effective date: 20100120 |
|
TRDD | Decision of grant or rejection written | ||
A01 | Written decision to grant a patent or to grant a registration (utility model) |
Free format text: JAPANESE INTERMEDIATE CODE: A01 Effective date: 20100305 |
|
A01 | Written decision to grant a patent or to grant a registration (utility model) |
Free format text: JAPANESE INTERMEDIATE CODE: A01 |
|
A61 | First payment of annual fees (during grant procedure) |
Free format text: JAPANESE INTERMEDIATE CODE: A61 Effective date: 20100319 |
|
FPAY | Renewal fee payment (event date is renewal date of database) |
Free format text: PAYMENT UNTIL: 20130326 Year of fee payment: 3 |
|
R150 | Certificate of patent or registration of utility model |
Ref document number: 4482334 Country of ref document: JP Free format text: JAPANESE INTERMEDIATE CODE: R150 Free format text: JAPANESE INTERMEDIATE CODE: R150 |
|
FPAY | Renewal fee payment (event date is renewal date of database) |
Free format text: PAYMENT UNTIL: 20130326 Year of fee payment: 3 |
|
FPAY | Renewal fee payment (event date is renewal date of database) |
Free format text: PAYMENT UNTIL: 20140326 Year of fee payment: 4 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
S111 | Request for change of ownership or part of ownership |
Free format text: JAPANESE INTERMEDIATE CODE: R313113 |
|
R350 | Written notification of registration of transfer |
Free format text: JAPANESE INTERMEDIATE CODE: R350 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
LAPS | Cancellation because of no payment of annual fees |