JP4384354B2 - 塗料剤および多層ラッカーコーティングの製造におけるその使用 - Google Patents
塗料剤および多層ラッカーコーティングの製造におけるその使用 Download PDFInfo
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- JP4384354B2 JP4384354B2 JP2000535713A JP2000535713A JP4384354B2 JP 4384354 B2 JP4384354 B2 JP 4384354B2 JP 2000535713 A JP2000535713 A JP 2000535713A JP 2000535713 A JP2000535713 A JP 2000535713A JP 4384354 B2 JP4384354 B2 JP 4384354B2
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- 239000004922 lacquer Substances 0.000 title claims description 85
- 238000000576 coating method Methods 0.000 title claims description 25
- 238000004519 manufacturing process Methods 0.000 title claims description 21
- 239000003973 paint Substances 0.000 title description 2
- 239000008199 coating composition Substances 0.000 claims abstract description 75
- 239000007787 solid Substances 0.000 claims abstract description 32
- 229920006243 acrylic copolymer Polymers 0.000 claims abstract description 28
- 229920000728 polyester Polymers 0.000 claims abstract description 25
- 239000002253 acid Substances 0.000 claims abstract description 23
- 229920005989 resin Polymers 0.000 claims abstract description 19
- 239000011347 resin Substances 0.000 claims abstract description 19
- 239000011230 binding agent Substances 0.000 claims abstract description 17
- 239000000049 pigment Substances 0.000 claims abstract description 16
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 14
- 239000003431 cross linking reagent Substances 0.000 claims abstract description 14
- 229920000642 polymer Polymers 0.000 claims abstract description 14
- 229920005862 polyol Polymers 0.000 claims abstract description 12
- 150000003077 polyols Chemical class 0.000 claims abstract description 12
- 238000007665 sagging Methods 0.000 claims abstract description 10
- 150000003672 ureas Chemical class 0.000 claims abstract description 9
- 239000004606 Fillers/Extenders Substances 0.000 claims abstract description 7
- 239000003960 organic solvent Substances 0.000 claims abstract description 6
- 239000000654 additive Substances 0.000 claims abstract description 5
- -1 urea compound Chemical class 0.000 claims description 51
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 claims description 44
- 239000004202 carbamide Substances 0.000 claims description 34
- 239000004971 Cross linker Substances 0.000 claims description 31
- 239000004593 Epoxy Substances 0.000 claims description 28
- 239000011248 coating agent Substances 0.000 claims description 16
- 238000000034 method Methods 0.000 claims description 12
- 150000001412 amines Chemical class 0.000 claims description 9
- 239000006185 dispersion Substances 0.000 claims description 7
- 239000012948 isocyanate Substances 0.000 claims description 7
- 239000002904 solvent Substances 0.000 claims description 6
- 239000002245 particle Substances 0.000 claims description 3
- 230000008569 process Effects 0.000 claims description 3
- 101100001669 Emericella variicolor andD gene Proteins 0.000 abstract 1
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- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 26
- 239000000178 monomer Substances 0.000 description 26
- 239000005056 polyisocyanate Substances 0.000 description 24
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- 239000000243 solution Substances 0.000 description 24
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 description 21
- 238000006243 chemical reaction Methods 0.000 description 20
- 239000000203 mixture Substances 0.000 description 17
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- 229920001577 copolymer Polymers 0.000 description 14
- 238000003756 stirring Methods 0.000 description 13
- JOYRKODLDBILNP-UHFFFAOYSA-N urethane group Chemical group NC(=O)OCC JOYRKODLDBILNP-UHFFFAOYSA-N 0.000 description 13
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- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 11
- 238000002360 preparation method Methods 0.000 description 11
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- 239000000047 product Substances 0.000 description 10
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 9
- 230000015572 biosynthetic process Effects 0.000 description 9
- IQPQWNKOIGAROB-UHFFFAOYSA-N isocyanate group Chemical group [N-]=C=O IQPQWNKOIGAROB-UHFFFAOYSA-N 0.000 description 9
- IISBACLAFKSPIT-UHFFFAOYSA-N bisphenol A Chemical compound C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 IISBACLAFKSPIT-UHFFFAOYSA-N 0.000 description 8
- RRAMGCGOFNQTLD-UHFFFAOYSA-N hexamethylene diisocyanate Chemical compound O=C=NCCCCCCN=C=O RRAMGCGOFNQTLD-UHFFFAOYSA-N 0.000 description 8
- XNGIFLGASWRNHJ-UHFFFAOYSA-N phthalic acid Chemical compound OC(=O)C1=CC=CC=C1C(O)=O XNGIFLGASWRNHJ-UHFFFAOYSA-N 0.000 description 8
- XSQUKJJJFZCRTK-UHFFFAOYSA-N urea group Chemical group NC(=O)N XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 8
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 7
- 229920003270 Cymel® Polymers 0.000 description 7
- 239000005057 Hexamethylene diisocyanate Substances 0.000 description 7
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 7
- 150000002596 lactones Chemical class 0.000 description 7
- JDSHMPZPIAZGSV-UHFFFAOYSA-N melamine Chemical compound NC1=NC(N)=NC(N)=N1 JDSHMPZPIAZGSV-UHFFFAOYSA-N 0.000 description 7
- 150000003254 radicals Chemical class 0.000 description 7
- 239000012429 reaction media Substances 0.000 description 7
- VZCYOOQTPOCHFL-OWOJBTEDSA-N Fumaric acid Chemical compound OC(=O)\C=C\C(O)=O VZCYOOQTPOCHFL-OWOJBTEDSA-N 0.000 description 6
- 125000001931 aliphatic group Chemical group 0.000 description 6
- 239000013078 crystal Substances 0.000 description 6
- 125000005442 diisocyanate group Chemical group 0.000 description 6
- 125000003700 epoxy group Chemical group 0.000 description 6
- 238000000265 homogenisation Methods 0.000 description 6
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 6
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Natural products CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 5
- 229920000877 Melamine resin Polymers 0.000 description 5
- OFOBLEOULBTSOW-UHFFFAOYSA-N Propanedioic acid Natural products OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 5
- ZJCCRDAZUWHFQH-UHFFFAOYSA-N Trimethylolpropane Chemical compound CCC(CO)(CO)CO ZJCCRDAZUWHFQH-UHFFFAOYSA-N 0.000 description 5
- 150000007513 acids Chemical class 0.000 description 5
- 150000001298 alcohols Chemical class 0.000 description 5
- 150000001244 carboxylic acid anhydrides Chemical class 0.000 description 5
- 239000007795 chemical reaction product Substances 0.000 description 5
- 238000001962 electrophoresis Methods 0.000 description 5
- 150000002148 esters Chemical class 0.000 description 5
- 125000003055 glycidyl group Chemical group C(C1CO1)* 0.000 description 5
- 239000003999 initiator Substances 0.000 description 5
- 239000000126 substance Substances 0.000 description 5
- 238000003786 synthesis reaction Methods 0.000 description 5
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 4
- KKEYFWRCBNTPAC-UHFFFAOYSA-N Terephthalic acid Chemical compound OC(=O)C1=CC=C(C(O)=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-N 0.000 description 4
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 4
- WNLRTRBMVRJNCN-UHFFFAOYSA-N adipic acid Chemical compound OC(=O)CCCCC(O)=O WNLRTRBMVRJNCN-UHFFFAOYSA-N 0.000 description 4
- 150000001735 carboxylic acids Chemical class 0.000 description 4
- 239000011247 coating layer Substances 0.000 description 4
- 230000000694 effects Effects 0.000 description 4
- 125000000524 functional group Chemical group 0.000 description 4
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 4
- 150000002513 isocyanates Chemical class 0.000 description 4
- ZFSLODLOARCGLH-UHFFFAOYSA-N isocyanuric acid Chemical group OC1=NC(O)=NC(O)=N1 ZFSLODLOARCGLH-UHFFFAOYSA-N 0.000 description 4
- DNIAPMSPPWPWGF-UHFFFAOYSA-N monopropylene glycol Natural products CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 4
- 238000005507 spraying Methods 0.000 description 4
- LDHQCZJRKDOVOX-UHFFFAOYSA-N trans-crotonic acid Natural products CC=CC(O)=O LDHQCZJRKDOVOX-UHFFFAOYSA-N 0.000 description 4
- ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 description 3
- DKPFZGUDAPQIHT-UHFFFAOYSA-N Butyl acetate Natural products CCCCOC(C)=O DKPFZGUDAPQIHT-UHFFFAOYSA-N 0.000 description 3
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 3
- 239000005058 Isophorone diisocyanate Substances 0.000 description 3
- 239000004640 Melamine resin Substances 0.000 description 3
- 150000001252 acrylic acid derivatives Chemical class 0.000 description 3
- 125000005907 alkyl ester group Chemical group 0.000 description 3
- 125000003118 aryl group Chemical group 0.000 description 3
- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 3
- 125000000113 cyclohexyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])(*)C([H])([H])C1([H])[H] 0.000 description 3
- GYZLOYUZLJXAJU-UHFFFAOYSA-N diglycidyl ether Chemical compound C1OC1COCC1CO1 GYZLOYUZLJXAJU-UHFFFAOYSA-N 0.000 description 3
- 150000002170 ethers Chemical class 0.000 description 3
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 3
- 239000001530 fumaric acid Substances 0.000 description 3
- FUZZWVXGSFPDMH-UHFFFAOYSA-N hexanoic acid Chemical compound CCCCCC(O)=O FUZZWVXGSFPDMH-UHFFFAOYSA-N 0.000 description 3
- RAXXELZNTBOGNW-UHFFFAOYSA-N imidazole Natural products C1=CNC=N1 RAXXELZNTBOGNW-UHFFFAOYSA-N 0.000 description 3
- 125000000959 isobutyl group Chemical group [H]C([H])([H])C([H])(C([H])([H])[H])C([H])([H])* 0.000 description 3
- NIMLQBUJDJZYEJ-UHFFFAOYSA-N isophorone diisocyanate Chemical compound CC1(C)CC(N=C=O)CC(C)(CN=C=O)C1 NIMLQBUJDJZYEJ-UHFFFAOYSA-N 0.000 description 3
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 description 3
- 239000011976 maleic acid Substances 0.000 description 3
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 3
- 150000002763 monocarboxylic acids Chemical class 0.000 description 3
- 229920000647 polyepoxide Polymers 0.000 description 3
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- HJWLCRVIBGQPNF-UHFFFAOYSA-N prop-2-enylbenzene Chemical compound C=CCC1=CC=CC=C1 HJWLCRVIBGQPNF-UHFFFAOYSA-N 0.000 description 3
- 125000000467 secondary amino group Chemical group [H]N([*:1])[*:2] 0.000 description 3
- SRPWOOOHEPICQU-UHFFFAOYSA-N trimellitic anhydride Chemical compound OC(=O)C1=CC=C2C(=O)OC(=O)C2=C1 SRPWOOOHEPICQU-UHFFFAOYSA-N 0.000 description 3
- JYEUMXHLPRZUAT-UHFFFAOYSA-N 1,2,3-triazine Chemical compound C1=CN=NN=C1 JYEUMXHLPRZUAT-UHFFFAOYSA-N 0.000 description 2
- MYRTYDVEIRVNKP-UHFFFAOYSA-N 1,2-Divinylbenzene Chemical compound C=CC1=CC=CC=C1C=C MYRTYDVEIRVNKP-UHFFFAOYSA-N 0.000 description 2
- OAYXUHPQHDHDDZ-UHFFFAOYSA-N 2-(2-butoxyethoxy)ethanol Chemical compound CCCCOCCOCCO OAYXUHPQHDHDDZ-UHFFFAOYSA-N 0.000 description 2
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- JAHNSTQSQJOJLO-UHFFFAOYSA-N 2-(3-fluorophenyl)-1h-imidazole Chemical compound FC1=CC=CC(C=2NC=CN=2)=C1 JAHNSTQSQJOJLO-UHFFFAOYSA-N 0.000 description 2
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- IFDVQVHZEKPUSC-UHFFFAOYSA-N cyclohex-3-ene-1,2-dicarboxylic acid Chemical compound OC(=O)C1CCC=CC1C(O)=O IFDVQVHZEKPUSC-UHFFFAOYSA-N 0.000 description 2
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- 125000004051 hexyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 2
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Classifications
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D163/00—Coating compositions based on epoxy resins; Coating compositions based on derivatives of epoxy resins
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D167/00—Coating compositions based on polyesters obtained by reactions forming a carboxylic ester link in the main chain; Coating compositions based on derivatives of such polymers
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Paints Or Removers (AREA)
- Laminated Bodies (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE19810220.8 | 1998-03-10 | ||
| DE19810220A DE19810220C2 (de) | 1998-03-10 | 1998-03-10 | Überzugsmittel und deren Verwendung zur Herstellung von Mehrschichtlackierungen |
| PCT/EP1999/001552 WO1999046345A1 (de) | 1998-03-10 | 1999-03-05 | Überzugsmittel und deren verwendung zur herstellung von mehrschichtlackierungen |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| JP2002506113A JP2002506113A (ja) | 2002-02-26 |
| JP2002506113A5 JP2002506113A5 (enExample) | 2006-04-20 |
| JP4384354B2 true JP4384354B2 (ja) | 2009-12-16 |
Family
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2000535713A Expired - Lifetime JP4384354B2 (ja) | 1998-03-10 | 1999-03-05 | 塗料剤および多層ラッカーコーティングの製造におけるその使用 |
Country Status (6)
| Country | Link |
|---|---|
| US (1) | US6437056B1 (enExample) |
| EP (1) | EP1062287B1 (enExample) |
| JP (1) | JP4384354B2 (enExample) |
| AT (1) | ATE220091T1 (enExample) |
| DE (2) | DE19810220C2 (enExample) |
| WO (1) | WO1999046345A1 (enExample) |
Families Citing this family (16)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE19945574A1 (de) * | 1999-09-23 | 2001-04-05 | Basf Coatings Ag | Verwendung assoziativer Verdickungsmittel auf Polyurethanbasis und/oder von Dipropylenglykolmonoalkylethern zur Unterdrückung optischer Fehlstellen in farb- und/oder effektgebenden Mehrschichtlackierungen oder deren Reparaturlackierungen |
| ATE356842T1 (de) * | 2002-02-01 | 2007-04-15 | Basf Corp | Oligomere kettenverlängerer zur behandlung und nachbehandlung sowie dem recycling von kondensationspolymeren, darauf basierende zusammensetzungen und anwendungen derselben |
| JP2006505639A (ja) * | 2002-11-07 | 2006-02-16 | サーフェース スペシャリティーズ、エス．エイ． | 粉末塗装組成物 |
| EP1443059A1 (en) * | 2003-02-02 | 2004-08-04 | Solutia Italy S.r.l. | Resins for powder coating compositions |
| TW200530352A (en) * | 2004-02-09 | 2005-09-16 | Nippon Paint Co Ltd | Metallic base coating composition and process for producing a composite film |
| US20050255081A1 (en) * | 2004-05-11 | 2005-11-17 | Kenneth Tseng | Stabilizers for hydrolyzable organic binders |
| JP2009525384A (ja) * | 2006-02-03 | 2009-07-09 | イー・アイ・デュポン・ドウ・ヌムール・アンド・カンパニー | 非水性液体コーティング組成物 |
| WO2008030437A2 (en) * | 2006-09-05 | 2008-03-13 | E. I. Du Pont De Nemours And Company | Aqueous compositions of sagging control agents |
| US20100022712A1 (en) * | 2008-07-25 | 2010-01-28 | Merritt William H | Coating Composition and Cured Film Formed Therefrom |
| CN102844336B (zh) * | 2009-07-21 | 2015-07-15 | 巴斯夫公司 | 通过反应器内扩链生产缩聚物的方法及其产物 |
| DE102009060803A1 (de) * | 2009-12-31 | 2011-07-07 | BASF Coatings GmbH, 48165 | Wasserfreie Zusammensetzung als Beschichtungsmittel für Funktionsschichten einer Mehrschichtlackierung |
| CN103998513A (zh) * | 2011-12-09 | 2014-08-20 | 巴斯夫涂料有限公司 | 高固体涂料和涂覆方法 |
| MX2021009820A (es) * | 2019-02-15 | 2021-09-08 | Kansai Paint Co Ltd | Agente de control de reologia y composicion de pintura. |
| WO2020166198A1 (ja) * | 2019-02-15 | 2020-08-20 | 関西ペイント株式会社 | 塗料組成物 |
| JP7434286B2 (ja) * | 2019-03-26 | 2024-02-20 | 関西ペイント株式会社 | 塗料組成物 |
| US11760897B2 (en) | 2019-07-30 | 2023-09-19 | Axalta Coating Systems Ip Co., Llc | Coating compositions including a sag control agent and wax |
Family Cites Families (14)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CA1006284A (en) * | 1972-12-11 | 1977-03-01 | August Merckens Nachf. Kommanditgesellschaft | Thixotropic coating agent, process for the preparation and use |
| US3893956A (en) * | 1972-12-11 | 1975-07-08 | August Merckens Nachfolger Kom | Thixotropic coating agents based on urea adduct of polyamine and diisocyanates |
| NL176864C (nl) * | 1976-11-25 | 1985-06-17 | Akzo Nv | Werkwijze voor de bereiding van een thixotrope bekledingssamenstelling. |
| DE3022996C2 (de) * | 1980-06-20 | 1982-02-04 | Basf Farben + Fasern Ag, 2000 Hamburg | Einbrennlack |
| NL8500475A (nl) * | 1985-02-20 | 1986-09-16 | Akzo Nv | Thixotrope bekledingssamenstelling. |
| NL8500476A (nl) * | 1985-02-20 | 1986-09-16 | Akzo Nv | Thixotrope bekledingssamenstelling. |
| DE4004060A1 (de) * | 1990-02-10 | 1991-08-14 | Hoechst Ag | Antiabsetzmittel fuer fluessige, haertbare mischungen |
| JPH05132636A (ja) * | 1991-11-12 | 1993-05-28 | Dainippon Ink & Chem Inc | 被覆膜の形成方法 |
| JP2974491B2 (ja) * | 1992-03-05 | 1999-11-10 | 共栄社化学株式会社 | 非水系塗料用垂れ防止剤 |
| DE4236901A1 (de) * | 1992-10-31 | 1994-05-05 | Herberts Gmbh | Als Rheologie-Beeinflusser geeignete Zusammensetzung, Verfahren zu deren Herstellung und deren Verwendung in Überzugsmitteln |
| DE4237658A1 (de) * | 1992-11-07 | 1994-05-11 | Herberts Gmbh | Bindemittelzusammensetzung, diese enthaltende Überzugsmittel, deren Herstellung und Verwendung |
| DE4310413A1 (de) * | 1993-03-31 | 1994-10-06 | Basf Lacke & Farben | Nichtwäßriger Lack und Verfahren zur Herstellung einer zweischichtigen Decklackierung |
| AU2236295A (en) * | 1994-04-04 | 1995-10-23 | Ppg Industries, Inc. | Non-aqueous dispersions of carboxylic acid-functional polymeric microparticles used for flow control in polyepoxide-polyacid based coating compositions |
| ATE224777T1 (de) * | 1996-06-12 | 2002-10-15 | Du Pont | Verfahren zur herstellung von mehrschichtlackierungen auf elektrisch leitfähigen substraten |
-
1998
- 1998-03-10 DE DE19810220A patent/DE19810220C2/de not_active Expired - Fee Related
-
1999
- 1999-03-05 AT AT99914504T patent/ATE220091T1/de not_active IP Right Cessation
- 1999-03-05 DE DE59901924T patent/DE59901924D1/de not_active Expired - Fee Related
- 1999-03-05 WO PCT/EP1999/001552 patent/WO1999046345A1/de not_active Ceased
- 1999-03-05 EP EP99914504A patent/EP1062287B1/de not_active Expired - Lifetime
- 1999-03-05 US US09/622,757 patent/US6437056B1/en not_active Expired - Fee Related
- 1999-03-05 JP JP2000535713A patent/JP4384354B2/ja not_active Expired - Lifetime
Also Published As
| Publication number | Publication date |
|---|---|
| DE59901924D1 (de) | 2002-08-08 |
| DE19810220A1 (de) | 1999-09-16 |
| US6437056B1 (en) | 2002-08-20 |
| WO1999046345A1 (de) | 1999-09-16 |
| EP1062287B1 (de) | 2002-07-03 |
| JP2002506113A (ja) | 2002-02-26 |
| EP1062287A1 (de) | 2000-12-27 |
| DE19810220C2 (de) | 2001-04-19 |
| ATE220091T1 (de) | 2002-07-15 |
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