JP4377408B2 - 剥離紙及び剥離フィルムのための下塗剤におけるシラン官能性ポリビニルアルコールの使用 - Google Patents
剥離紙及び剥離フィルムのための下塗剤におけるシラン官能性ポリビニルアルコールの使用 Download PDFInfo
- Publication number
- JP4377408B2 JP4377408B2 JP2006508176A JP2006508176A JP4377408B2 JP 4377408 B2 JP4377408 B2 JP 4377408B2 JP 2006508176 A JP2006508176 A JP 2006508176A JP 2006508176 A JP2006508176 A JP 2006508176A JP 4377408 B2 JP4377408 B2 JP 4377408B2
- Authority
- JP
- Japan
- Prior art keywords
- silane
- group
- atoms
- polyvinyl alcohol
- vinyl
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 229920002451 polyvinyl alcohol Polymers 0.000 title claims abstract description 28
- 239000004372 Polyvinyl alcohol Substances 0.000 title claims description 26
- 229920001567 vinyl ester resin Polymers 0.000 claims abstract description 18
- 229920000642 polymer Polymers 0.000 claims abstract description 15
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 claims description 34
- 229910000077 silane Inorganic materials 0.000 claims description 33
- 125000004432 carbon atom Chemical group C* 0.000 claims description 22
- -1 alkyl carboxylic acids Chemical class 0.000 claims description 17
- 239000000178 monomer Substances 0.000 claims description 15
- 125000003545 alkoxy group Chemical group 0.000 claims description 13
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 claims description 11
- 150000004756 silanes Chemical class 0.000 claims description 10
- 125000000217 alkyl group Chemical group 0.000 claims description 9
- 230000007062 hydrolysis Effects 0.000 claims description 6
- 238000006460 hydrolysis reaction Methods 0.000 claims description 6
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 claims description 5
- 238000000034 method Methods 0.000 claims description 5
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims description 5
- HETCEOQFVDFGSY-UHFFFAOYSA-N Isopropenyl acetate Chemical compound CC(=C)OC(C)=O HETCEOQFVDFGSY-UHFFFAOYSA-N 0.000 claims description 4
- 150000001735 carboxylic acids Chemical class 0.000 claims description 4
- 239000004447 silicone coating Substances 0.000 claims description 4
- FJKIXWOMBXYWOQ-UHFFFAOYSA-N ethenoxyethane Chemical group CCOC=C FJKIXWOMBXYWOQ-UHFFFAOYSA-N 0.000 claims description 3
- 125000001301 ethoxy group Chemical group [H]C([H])([H])C([H])([H])O* 0.000 claims description 3
- 229920002554 vinyl polymer Polymers 0.000 claims description 3
- 125000006273 (C1-C3) alkyl group Chemical group 0.000 claims description 2
- HRPVXLWXLXDGHG-UHFFFAOYSA-N Acrylamide Chemical compound NC(=O)C=C HRPVXLWXLXDGHG-UHFFFAOYSA-N 0.000 claims description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 2
- 125000002252 acyl group Chemical group 0.000 claims description 2
- 125000002947 alkylene group Chemical group 0.000 claims description 2
- BVCLXNHIJBDDTH-UHFFFAOYSA-N but-1-en-2-yl acetate Chemical compound CCC(=C)OC(C)=O BVCLXNHIJBDDTH-UHFFFAOYSA-N 0.000 claims description 2
- 229920001577 copolymer Polymers 0.000 claims description 2
- 125000001033 ether group Chemical group 0.000 claims description 2
- 229910052736 halogen Inorganic materials 0.000 claims description 2
- 150000002367 halogens Chemical class 0.000 claims description 2
- 125000000623 heterocyclic group Chemical group 0.000 claims description 2
- 125000000956 methoxy group Chemical group [H]C([H])([H])O* 0.000 claims description 2
- 125000004433 nitrogen atom Chemical group N* 0.000 claims description 2
- 125000000962 organic group Chemical group 0.000 claims description 2
- 125000004430 oxygen atom Chemical group O* 0.000 claims description 2
- 238000010526 radical polymerization reaction Methods 0.000 claims description 2
- 238000007334 copolymerization reaction Methods 0.000 claims 3
- 229910052799 carbon Inorganic materials 0.000 claims 1
- 239000007888 film coating Substances 0.000 claims 1
- 238000009501 film coating Methods 0.000 claims 1
- XJRBAMWJDBPFIM-UHFFFAOYSA-N methyl vinyl ether Chemical group COC=C XJRBAMWJDBPFIM-UHFFFAOYSA-N 0.000 claims 1
- 150000003377 silicon compounds Chemical class 0.000 claims 1
- 239000011230 binding agent Substances 0.000 abstract description 4
- 235000019422 polyvinyl alcohol Nutrition 0.000 description 20
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 description 17
- 229920001296 polysiloxane Polymers 0.000 description 10
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 9
- 239000007864 aqueous solution Substances 0.000 description 7
- 238000000576 coating method Methods 0.000 description 7
- 239000000243 solution Substances 0.000 description 7
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 6
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 6
- 239000000203 mixture Substances 0.000 description 6
- 239000003054 catalyst Substances 0.000 description 5
- 239000011248 coating agent Substances 0.000 description 5
- NLXLAEXVIDQMFP-UHFFFAOYSA-N Ammonia chloride Chemical compound [NH4+].[Cl-] NLXLAEXVIDQMFP-UHFFFAOYSA-N 0.000 description 4
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 4
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 4
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 4
- 150000002148 esters Chemical class 0.000 description 4
- 238000006116 polymerization reaction Methods 0.000 description 4
- 238000003860 storage Methods 0.000 description 4
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 3
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 3
- 239000000654 additive Substances 0.000 description 3
- 230000000052 comparative effect Effects 0.000 description 3
- OPQARKPSCNTWTJ-UHFFFAOYSA-L copper(ii) acetate Chemical compound [Cu+2].CC([O-])=O.CC([O-])=O OPQARKPSCNTWTJ-UHFFFAOYSA-L 0.000 description 3
- 238000001035 drying Methods 0.000 description 3
- FWDBOZPQNFPOLF-UHFFFAOYSA-N ethenyl(triethoxy)silane Chemical compound CCO[Si](OCC)(OCC)C=C FWDBOZPQNFPOLF-UHFFFAOYSA-N 0.000 description 3
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 3
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 3
- UKRDPEFKFJNXQM-UHFFFAOYSA-N vinylsilane Chemical class [SiH3]C=C UKRDPEFKFJNXQM-UHFFFAOYSA-N 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 2
- LZMNXXQIQIHFGC-UHFFFAOYSA-N 3-[dimethoxy(methyl)silyl]propyl 2-methylprop-2-enoate Chemical compound CO[Si](C)(OC)CCCOC(=O)C(C)=C LZMNXXQIQIHFGC-UHFFFAOYSA-N 0.000 description 2
- DMZPTAFGSRVFIA-UHFFFAOYSA-N 3-[tris(2-methoxyethoxy)silyl]propyl 2-methylprop-2-enoate Chemical compound COCCO[Si](OCCOC)(OCCOC)CCCOC(=O)C(C)=C DMZPTAFGSRVFIA-UHFFFAOYSA-N 0.000 description 2
- XDLMVUHYZWKMMD-UHFFFAOYSA-N 3-trimethoxysilylpropyl 2-methylprop-2-enoate Chemical compound CO[Si](OC)(OC)CCCOC(=O)C(C)=C XDLMVUHYZWKMMD-UHFFFAOYSA-N 0.000 description 2
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 description 2
- 229920002134 Carboxymethyl cellulose Polymers 0.000 description 2
- RRHGJUQNOFWUDK-UHFFFAOYSA-N Isoprene Chemical compound CC(=C)C=C RRHGJUQNOFWUDK-UHFFFAOYSA-N 0.000 description 2
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 2
- NOZAQBYNLKNDRT-UHFFFAOYSA-N [diacetyloxy(ethenyl)silyl] acetate Chemical compound CC(=O)O[Si](OC(C)=O)(OC(C)=O)C=C NOZAQBYNLKNDRT-UHFFFAOYSA-N 0.000 description 2
- 239000000853 adhesive Substances 0.000 description 2
- 230000001070 adhesive effect Effects 0.000 description 2
- 239000002390 adhesive tape Substances 0.000 description 2
- 235000019270 ammonium chloride Nutrition 0.000 description 2
- 239000001768 carboxy methyl cellulose Substances 0.000 description 2
- 235000010948 carboxy methyl cellulose Nutrition 0.000 description 2
- 239000008112 carboxymethyl-cellulose Substances 0.000 description 2
- 239000012876 carrier material Substances 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- NKSJNEHGWDZZQF-UHFFFAOYSA-N ethenyl(trimethoxy)silane Chemical compound CO[Si](OC)(OC)C=C NKSJNEHGWDZZQF-UHFFFAOYSA-N 0.000 description 2
- MBGQQKKTDDNCSG-UHFFFAOYSA-N ethenyl-diethoxy-methylsilane Chemical compound CCO[Si](C)(C=C)OCC MBGQQKKTDDNCSG-UHFFFAOYSA-N 0.000 description 2
- ZLNAFSPCNATQPQ-UHFFFAOYSA-N ethenyl-dimethoxy-methylsilane Chemical compound CO[Si](C)(OC)C=C ZLNAFSPCNATQPQ-UHFFFAOYSA-N 0.000 description 2
- MABAWBWRUSBLKQ-UHFFFAOYSA-N ethenyl-tri(propan-2-yloxy)silane Chemical compound CC(C)O[Si](OC(C)C)(OC(C)C)C=C MABAWBWRUSBLKQ-UHFFFAOYSA-N 0.000 description 2
- 238000011156 evaluation Methods 0.000 description 2
- 238000009472 formulation Methods 0.000 description 2
- 235000011187 glycerol Nutrition 0.000 description 2
- 239000000049 pigment Substances 0.000 description 2
- 239000004014 plasticizer Substances 0.000 description 2
- 239000000843 powder Substances 0.000 description 2
- UALUSSOHQPEICU-UHFFFAOYSA-N prop-2-enamide;trimethoxy(propyl)silane Chemical compound NC(=O)C=C.CCC[Si](OC)(OC)OC UALUSSOHQPEICU-UHFFFAOYSA-N 0.000 description 2
- 238000001694 spray drying Methods 0.000 description 2
- 238000003756 stirring Methods 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- SGCFZHOZKKQIBU-UHFFFAOYSA-N tributoxy(ethenyl)silane Chemical compound CCCCO[Si](OCCCC)(OCCCC)C=C SGCFZHOZKKQIBU-UHFFFAOYSA-N 0.000 description 2
- UOKUUKOEIMCYAI-UHFFFAOYSA-N trimethoxysilylmethyl 2-methylprop-2-enoate Chemical compound CO[Si](OC)(OC)COC(=O)C(C)=C UOKUUKOEIMCYAI-UHFFFAOYSA-N 0.000 description 2
- DTGKSKDOIYIVQL-WEDXCCLWSA-N (+)-borneol Chemical group C1C[C@@]2(C)[C@@H](O)C[C@@H]1C2(C)C DTGKSKDOIYIVQL-WEDXCCLWSA-N 0.000 description 1
- IDXCKOANSQIPGX-UHFFFAOYSA-N (acetyloxy-ethenyl-methylsilyl) acetate Chemical compound CC(=O)O[Si](C)(C=C)OC(C)=O IDXCKOANSQIPGX-UHFFFAOYSA-N 0.000 description 1
- SKYXLDSRLNRAPS-UHFFFAOYSA-N 1,2,4-trifluoro-5-methoxybenzene Chemical compound COC1=CC(F)=C(F)C=C1F SKYXLDSRLNRAPS-UHFFFAOYSA-N 0.000 description 1
- OZCMOJQQLBXBKI-UHFFFAOYSA-N 1-ethenoxy-2-methylpropane Chemical compound CC(C)COC=C OZCMOJQQLBXBKI-UHFFFAOYSA-N 0.000 description 1
- UZKWTJUDCOPSNM-UHFFFAOYSA-N 1-ethenoxybutane Chemical compound CCCCOC=C UZKWTJUDCOPSNM-UHFFFAOYSA-N 0.000 description 1
- QJJDJWUCRAPCOL-UHFFFAOYSA-N 1-ethenoxyoctadecane Chemical compound CCCCCCCCCCCCCCCCCCOC=C QJJDJWUCRAPCOL-UHFFFAOYSA-N 0.000 description 1
- BDHGFCVQWMDIQX-UHFFFAOYSA-N 1-ethenyl-2-methylimidazole Chemical compound CC1=NC=CN1C=C BDHGFCVQWMDIQX-UHFFFAOYSA-N 0.000 description 1
- JWYVGKFDLWWQJX-UHFFFAOYSA-N 1-ethenylazepan-2-one Chemical compound C=CN1CCCCCC1=O JWYVGKFDLWWQJX-UHFFFAOYSA-N 0.000 description 1
- OSSNTDFYBPYIEC-UHFFFAOYSA-N 1-ethenylimidazole Chemical compound C=CN1C=CN=C1 OSSNTDFYBPYIEC-UHFFFAOYSA-N 0.000 description 1
- KNJOXNMRJUPXJT-UHFFFAOYSA-N 12,12-dimethoxydodecoxy(ethenyl)silane Chemical compound COC(OC)CCCCCCCCCCCO[SiH2]C=C KNJOXNMRJUPXJT-UHFFFAOYSA-N 0.000 description 1
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 1
- OEPOKWHJYJXUGD-UHFFFAOYSA-N 2-(3-phenylmethoxyphenyl)-1,3-thiazole-4-carbaldehyde Chemical compound O=CC1=CSC(C=2C=C(OCC=3C=CC=CC=3)C=CC=2)=N1 OEPOKWHJYJXUGD-UHFFFAOYSA-N 0.000 description 1
- XHZPRMZZQOIPDS-UHFFFAOYSA-N 2-Methyl-2-[(1-oxo-2-propenyl)amino]-1-propanesulfonic acid Chemical compound OS(=O)(=O)CC(C)(C)NC(=O)C=C XHZPRMZZQOIPDS-UHFFFAOYSA-N 0.000 description 1
- PGYJSURPYAAOMM-UHFFFAOYSA-N 2-ethenoxy-2-methylpropane Chemical compound CC(C)(C)OC=C PGYJSURPYAAOMM-UHFFFAOYSA-N 0.000 description 1
- 125000000954 2-hydroxyethyl group Chemical group [H]C([*])([H])C([H])([H])O[H] 0.000 description 1
- FCYVWWWTHPPJII-UHFFFAOYSA-N 2-methylidenepropanedinitrile Chemical compound N#CC(=C)C#N FCYVWWWTHPPJII-UHFFFAOYSA-N 0.000 description 1
- SJECZPVISLOESU-UHFFFAOYSA-N 3-trimethoxysilylpropan-1-amine Chemical compound CO[Si](OC)(OC)CCCN SJECZPVISLOESU-UHFFFAOYSA-N 0.000 description 1
- HMBNQNDUEFFFNZ-UHFFFAOYSA-N 4-ethenoxybutan-1-ol Chemical compound OCCCCOC=C HMBNQNDUEFFFNZ-UHFFFAOYSA-N 0.000 description 1
- FHVDTGUDJYJELY-UHFFFAOYSA-N 6-{[2-carboxy-4,5-dihydroxy-6-(phosphanyloxy)oxan-3-yl]oxy}-4,5-dihydroxy-3-phosphanyloxane-2-carboxylic acid Chemical compound O1C(C(O)=O)C(P)C(O)C(O)C1OC1C(C(O)=O)OC(OP)C(O)C1O FHVDTGUDJYJELY-UHFFFAOYSA-N 0.000 description 1
- SJIBSEBLLOLBMW-UHFFFAOYSA-N 8,8-dimethoxyoctoxy(ethenyl)silane Chemical compound COC(OC)CCCCCCCO[SiH2]C=C SJIBSEBLLOLBMW-UHFFFAOYSA-N 0.000 description 1
- LSNNMFCWUKXFEE-UHFFFAOYSA-M Bisulfite Chemical compound OS([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-M 0.000 description 1
- 229920002799 BoPET Polymers 0.000 description 1
- VNROOHCSOCDWOD-UHFFFAOYSA-N C(C)[Si](OC)(OC)OC.C(C=C)(=O)N Chemical compound C(C)[Si](OC)(OC)OC.C(C=C)(=O)N VNROOHCSOCDWOD-UHFFFAOYSA-N 0.000 description 1
- ILRGKSAHCJNIRU-UHFFFAOYSA-N C(CC)[Si](OC)(C)C.C(C=C)(=O)N Chemical compound C(CC)[Si](OC)(C)C.C(C=C)(=O)N ILRGKSAHCJNIRU-UHFFFAOYSA-N 0.000 description 1
- RADIZGQSFSEOQU-UHFFFAOYSA-N CC(C[Si](OC)(OC)OC)C.C(C=C)(=O)N Chemical compound CC(C[Si](OC)(OC)OC)C.C(C=C)(=O)N RADIZGQSFSEOQU-UHFFFAOYSA-N 0.000 description 1
- LECFJERLKGYDEV-UHFFFAOYSA-N C[Si](OC)(OC)OC.C(C=C)(=O)N Chemical compound C[Si](OC)(OC)OC.C(C=C)(=O)N LECFJERLKGYDEV-UHFFFAOYSA-N 0.000 description 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- GYCMBHHDWRMZGG-UHFFFAOYSA-N Methylacrylonitrile Chemical compound CC(=C)C#N GYCMBHHDWRMZGG-UHFFFAOYSA-N 0.000 description 1
- 229920000881 Modified starch Polymers 0.000 description 1
- WHNWPMSKXPGLAX-UHFFFAOYSA-N N-Vinyl-2-pyrrolidone Chemical compound C=CN1CCCC1=O WHNWPMSKXPGLAX-UHFFFAOYSA-N 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- 239000002202 Polyethylene glycol Substances 0.000 description 1
- 229920003082 Povidone K 90 Polymers 0.000 description 1
- 229920002472 Starch Polymers 0.000 description 1
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical class [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 1
- BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 description 1
- MOOIXEMFUKBQLJ-UHFFFAOYSA-N [1-(ethenoxymethyl)cyclohexyl]methanol Chemical compound C=COCC1(CO)CCCCC1 MOOIXEMFUKBQLJ-UHFFFAOYSA-N 0.000 description 1
- RRHBSCXGHKBTPY-UHFFFAOYSA-N [Cl-].C(CC)[NH3+].C(C=C)(=O)N Chemical compound [Cl-].C(CC)[NH3+].C(C=C)(=O)N RRHBSCXGHKBTPY-UHFFFAOYSA-N 0.000 description 1
- WLAJUHWWAGBCGF-UHFFFAOYSA-N [Cl-].CC(C[NH3+])C.C(C=C)(=O)N Chemical compound [Cl-].CC(C[NH3+])C.C(C=C)(=O)N WLAJUHWWAGBCGF-UHFFFAOYSA-N 0.000 description 1
- XRLWQTOZMISADO-UHFFFAOYSA-N [diacetyloxy(prop-2-enyl)silyl] acetate Chemical compound CC(=O)O[Si](CC=C)(OC(C)=O)OC(C)=O XRLWQTOZMISADO-UHFFFAOYSA-N 0.000 description 1
- KTVHXOHGRUQTPX-UHFFFAOYSA-N [ethenyl(dimethyl)silyl] acetate Chemical compound CC(=O)O[Si](C)(C)C=C KTVHXOHGRUQTPX-UHFFFAOYSA-N 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 230000002378 acidificating effect Effects 0.000 description 1
- 229940072056 alginate Drugs 0.000 description 1
- 235000010443 alginic acid Nutrition 0.000 description 1
- 229920000615 alginic acid Polymers 0.000 description 1
- 125000001931 aliphatic group Chemical group 0.000 description 1
- 150000001447 alkali salts Chemical class 0.000 description 1
- XYLMUPLGERFSHI-UHFFFAOYSA-N alpha-Methylstyrene Chemical compound CC(=C)C1=CC=CC=C1 XYLMUPLGERFSHI-UHFFFAOYSA-N 0.000 description 1
- WNROFYMDJYEPJX-UHFFFAOYSA-K aluminium hydroxide Chemical compound [OH-].[OH-].[OH-].[Al+3] WNROFYMDJYEPJX-UHFFFAOYSA-K 0.000 description 1
- 150000001408 amides Chemical class 0.000 description 1
- 125000003118 aryl group Chemical group 0.000 description 1
- 125000004429 atom Chemical group 0.000 description 1
- 239000002585 base Substances 0.000 description 1
- 125000001797 benzyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])* 0.000 description 1
- 230000001680 brushing effect Effects 0.000 description 1
- 238000012662 bulk polymerization Methods 0.000 description 1
- 239000000969 carrier Substances 0.000 description 1
- 125000002091 cationic group Chemical group 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- YACLQRRMGMJLJV-UHFFFAOYSA-N chloroprene Chemical compound ClC(=C)C=C YACLQRRMGMJLJV-UHFFFAOYSA-N 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 150000004696 coordination complex Chemical class 0.000 description 1
- 238000004132 cross linking Methods 0.000 description 1
- 125000000113 cyclohexyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])(*)C([H])([H])C1([H])[H] 0.000 description 1
- YLJJAVFOBDSYAN-UHFFFAOYSA-N dichloro-ethenyl-methylsilane Chemical compound C[Si](Cl)(Cl)C=C YLJJAVFOBDSYAN-UHFFFAOYSA-N 0.000 description 1
- OTFXLPHXAADAKO-UHFFFAOYSA-N didodecoxy(prop-2-enoxy)silane Chemical compound C(=C)CO[SiH](OCCCCCCCCCCCC)OCCCCCCCCCCCC OTFXLPHXAADAKO-UHFFFAOYSA-N 0.000 description 1
- WNQVUWLKSJJSFK-UHFFFAOYSA-N dihexoxy(prop-2-enoxy)silane Chemical compound C(=C)CO[SiH](OCCCCCC)OCCCCCC WNQVUWLKSJJSFK-UHFFFAOYSA-N 0.000 description 1
- 235000013870 dimethyl polysiloxane Nutrition 0.000 description 1
- QMUOYZCDQUNRJS-UHFFFAOYSA-N dioctoxy(prop-2-enoxy)silane Chemical compound C(=C)CO[SiH](OCCCCCCCC)OCCCCCCCC QMUOYZCDQUNRJS-UHFFFAOYSA-N 0.000 description 1
- 238000007598 dipping method Methods 0.000 description 1
- KPUWHANPEXNPJT-UHFFFAOYSA-N disiloxane Chemical class [SiH3]O[SiH3] KPUWHANPEXNPJT-UHFFFAOYSA-N 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 125000003438 dodecyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 238000007720 emulsion polymerization reaction Methods 0.000 description 1
- YCUBDDIKWLELPD-UHFFFAOYSA-N ethenyl 2,2-dimethylpropanoate Chemical compound CC(C)(C)C(=O)OC=C YCUBDDIKWLELPD-UHFFFAOYSA-N 0.000 description 1
- IGBZOHMCHDADGY-UHFFFAOYSA-N ethenyl 2-ethylhexanoate Chemical compound CCCCC(CC)C(=O)OC=C IGBZOHMCHDADGY-UHFFFAOYSA-N 0.000 description 1
- MEGHWIAOTJPCHQ-UHFFFAOYSA-N ethenyl butanoate Chemical compound CCCC(=O)OC=C MEGHWIAOTJPCHQ-UHFFFAOYSA-N 0.000 description 1
- GLVVKKSPKXTQRB-UHFFFAOYSA-N ethenyl dodecanoate Chemical compound CCCCCCCCCCCC(=O)OC=C GLVVKKSPKXTQRB-UHFFFAOYSA-N 0.000 description 1
- UIWXSTHGICQLQT-UHFFFAOYSA-N ethenyl propanoate Chemical compound CCC(=O)OC=C UIWXSTHGICQLQT-UHFFFAOYSA-N 0.000 description 1
- MLVRYXJUYPBRSQ-UHFFFAOYSA-N ethenyl(trihexoxy)silane Chemical compound CCCCCCO[Si](OCCCCCC)(OCCCCCC)C=C MLVRYXJUYPBRSQ-UHFFFAOYSA-N 0.000 description 1
- KPRMNZFLEVMTKA-UHFFFAOYSA-N ethenyl(trioctoxy)silane Chemical compound CCCCCCCCO[Si](OCCCCCCCC)(OCCCCCCCC)C=C KPRMNZFLEVMTKA-UHFFFAOYSA-N 0.000 description 1
- QZOSZICRWGJQRX-UHFFFAOYSA-N ethenyl-dimethoxy-(2-methylpropyl)silane Chemical compound CO[Si](C=C)(OC)CC(C)C QZOSZICRWGJQRX-UHFFFAOYSA-N 0.000 description 1
- JEWCZPTVOYXPGG-UHFFFAOYSA-N ethenyl-ethoxy-dimethylsilane Chemical compound CCO[Si](C)(C)C=C JEWCZPTVOYXPGG-UHFFFAOYSA-N 0.000 description 1
- NUFVQEIPPHHQCK-UHFFFAOYSA-N ethenyl-methoxy-dimethylsilane Chemical compound CO[Si](C)(C)C=C NUFVQEIPPHHQCK-UHFFFAOYSA-N 0.000 description 1
- WOXXJEVNDJOOLV-UHFFFAOYSA-N ethenyl-tris(2-methoxyethoxy)silane Chemical compound COCCO[Si](OCCOC)(OCCOC)C=C WOXXJEVNDJOOLV-UHFFFAOYSA-N 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- XUCNUKMRBVNAPB-UHFFFAOYSA-N fluoroethene Chemical compound FC=C XUCNUKMRBVNAPB-UHFFFAOYSA-N 0.000 description 1
- 238000004108 freeze drying Methods 0.000 description 1
- 238000007756 gravure coating Methods 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- PBZROIMXDZTJDF-UHFFFAOYSA-N hepta-1,6-dien-4-one Chemical compound C=CCC(=O)CC=C PBZROIMXDZTJDF-UHFFFAOYSA-N 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- 125000000959 isobutyl group Chemical group [H]C([H])([H])C([H])(C([H])([H])[H])C([H])([H])* 0.000 description 1
- 238000004898 kneading Methods 0.000 description 1
- 239000011344 liquid material Substances 0.000 description 1
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 235000019426 modified starch Nutrition 0.000 description 1
- 239000003607 modifier Substances 0.000 description 1
- 150000002763 monocarboxylic acids Chemical class 0.000 description 1
- 125000004108 n-butyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- PNLUGRYDUHRLOF-UHFFFAOYSA-N n-ethenyl-n-methylacetamide Chemical compound C=CN(C)C(C)=O PNLUGRYDUHRLOF-UHFFFAOYSA-N 0.000 description 1
- ZQXSMRAEXCEDJD-UHFFFAOYSA-N n-ethenylformamide Chemical compound C=CNC=O ZQXSMRAEXCEDJD-UHFFFAOYSA-N 0.000 description 1
- 125000001280 n-hexyl group Chemical group C(CCCCC)* 0.000 description 1
- KKFHAJHLJHVUDM-UHFFFAOYSA-N n-vinylcarbazole Chemical compound C1=CC=C2N(C=C)C3=CC=CC=C3C2=C1 KKFHAJHLJHVUDM-UHFFFAOYSA-N 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 229910000510 noble metal Inorganic materials 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 150000001282 organosilanes Chemical class 0.000 description 1
- 125000005375 organosiloxane group Chemical group 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 230000035515 penetration Effects 0.000 description 1
- 229910052697 platinum Inorganic materials 0.000 description 1
- 229920000435 poly(dimethylsiloxane) Polymers 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 229920001223 polyethylene glycol Polymers 0.000 description 1
- 229920001290 polyvinyl ester Polymers 0.000 description 1
- 229920000036 polyvinylpyrrolidone Polymers 0.000 description 1
- 239000001267 polyvinylpyrrolidone Substances 0.000 description 1
- 235000013855 polyvinylpyrrolidone Nutrition 0.000 description 1
- 235000019353 potassium silicate Nutrition 0.000 description 1
- 230000037452 priming Effects 0.000 description 1
- 230000002035 prolonged effect Effects 0.000 description 1
- NOVHGUXJIQPGOV-UHFFFAOYSA-N prop-2-enamide;triethoxy(propyl)silane Chemical compound NC(=O)C=C.CCC[Si](OCC)(OCC)OCC NOVHGUXJIQPGOV-UHFFFAOYSA-N 0.000 description 1
- ARJOQCYCJMAIFR-UHFFFAOYSA-N prop-2-enoyl prop-2-enoate Chemical compound C=CC(=O)OC(=O)C=C ARJOQCYCJMAIFR-UHFFFAOYSA-N 0.000 description 1
- 235000018102 proteins Nutrition 0.000 description 1
- 102000004169 proteins and genes Human genes 0.000 description 1
- 108090000623 proteins and genes Proteins 0.000 description 1
- 238000007761 roller coating Methods 0.000 description 1
- 238000007127 saponification reaction Methods 0.000 description 1
- 150000004760 silicates Chemical class 0.000 description 1
- 229920005573 silicon-containing polymer Polymers 0.000 description 1
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 239000008107 starch Substances 0.000 description 1
- 235000019698 starch Nutrition 0.000 description 1
- 230000003068 static effect Effects 0.000 description 1
- 125000004079 stearyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 239000000725 suspension Substances 0.000 description 1
- 238000010557 suspension polymerization reaction Methods 0.000 description 1
- 238000010345 tape casting Methods 0.000 description 1
- KHJNXCATZZIGAX-UHFFFAOYSA-N tert-butyl 2-ethyl-2-methylheptaneperoxoate Chemical compound CCCCCC(C)(CC)C(=O)OOC(C)(C)C KHJNXCATZZIGAX-UHFFFAOYSA-N 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- 239000004753 textile Substances 0.000 description 1
- 230000007704 transition Effects 0.000 description 1
- GQIUQDDJKHLHTB-UHFFFAOYSA-N trichloro(ethenyl)silane Chemical compound Cl[Si](Cl)(Cl)C=C GQIUQDDJKHLHTB-UHFFFAOYSA-N 0.000 description 1
- FUSUHKVFWTUUBE-UHFFFAOYSA-N vinyl methyl ketone Natural products CC(=O)C=C FUSUHKVFWTUUBE-UHFFFAOYSA-N 0.000 description 1
- 239000005050 vinyl trichlorosilane Substances 0.000 description 1
- 239000012463 white pigment Substances 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H27/00—Special paper not otherwise provided for, e.g. made by multi-step processes
- D21H27/001—Release paper
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H19/00—Coated paper; Coating material
- D21H19/80—Paper comprising more than one coating
- D21H19/82—Paper comprising more than one coating superposed
- D21H19/824—Paper comprising more than one coating superposed two superposed coatings, both being non-pigmented
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/14—Layer or component removable to expose adhesive
- Y10T428/1452—Polymer derived only from ethylenically unsaturated monomer
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/14—Layer or component removable to expose adhesive
- Y10T428/1452—Polymer derived only from ethylenically unsaturated monomer
- Y10T428/1457—Silicon
Landscapes
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Paper (AREA)
- Paints Or Removers (AREA)
- Laminated Bodies (AREA)
Description
a)全ポリマーに対して1〜30モル%の割合が、1〜6個のC原子を有するカルボン酸の1種又は複数種の、アルキル基が1〜6個のC原子を有する1−アルキルビニルエステルである、1〜18個のC原子を有する非分枝鎖状又は分枝鎖状のアルキルカルボン酸の1種又は複数種のビニルエステル、
b)0.01〜10モル%の1種又は複数種のシラン含有エチレン系不飽和モノマー、並びに場合により、
c)これらと共重合可能な他のコモノマー
をラジカル重合させ、そしてこれにより得られたポリマーをけん化させることにより得られ、75〜100モル%の加水分解度を有する完全けん化又は部分けん化されたビニルエステルコポリマーを基礎とする少なくとも1種のシラン含有ポリビニルアルコールを含有する使用である。
実施例1:
充填容量2.5リットルの恒温実験室装置内に、窒素下で、水612g、酢酸銅(II)61.2mg及び5質量%ポリビニルピロリドン(PVP−K90)61.2gを水に溶かした溶液を装入した。t−ブチル−ペル−2−エチルヘキサノエート(TBPEH99%水溶液)620mgと、t−ブチル−ペルネオ−デカノエート(Pergan社製PND95%水溶液)322mgと、ビニルトリエトキシシラン4.9gと、イソプロペニルアセテート48.9gと、イソプロパノール42.8gとをビニルアセテート612g中に溶かした溶液を、撹拌しつつ供給した。反応器を51.5℃まで加熱して、反応の減衰に応じて、徐々に75℃まで加熱した。それをこの温度で更に2時間ほど保持し、次いで冷却した。得られた真珠状ポリマーを吸引分離して、水で十分に洗浄して、そして乾燥させた。2.5lの容量を有する実験室反応器内で、真珠状ポリマー90gをメタノール810g中に50℃で溶解させた。この溶液を30℃まで冷却し、静止した撹拌器で、メタノール500gを積層し、そして直ちにメタノール性NaOH(メタノール90gに溶解された46%NaOH水溶液10g)を混合し、そして撹拌器を稼働させた。この溶液は次第に濁ってきた。ゲル段階の間は、撹拌器を高回転数に調整し、ゲルを粉砕した。ゲル段階の後に更に2時間にわたりなおも反応させ、酢酸で中和し、そして形成された固形物を濾過分離して、洗浄して、そして乾燥させた。28mPasのへプラー粘度を有する、完全けん化ポリビニルアルコール(4%水溶液)が得られた。
25mPasのへプラー粘度を有する、ビニルシラン単位を含有する完全けん化ポリビニルアルコール(4%水溶液)。
25mPasのへプラー粘度を有する、シランを含有しない完全けん化ポリビニルアルコール(4%水溶液)。
実施例及び比較例からの下塗剤を、それぞれ、実験室サイズプレス塗工機を用いて未加工紙上に塗布し、そして適切に乾燥させた(被覆は1.5〜3g/m2)。このように下塗りされた紙の上に、ビニル末端ポリシロキサン(Dehesive 920)100質量部、H含有シロキサン(Vernetzer V90)2.4質量部及びPt触媒(Katalysator OL)1質量部からの剥離層を施与して、そして被覆された紙を150℃で7秒にわたり加熱した。
移行試験:
試験用粘着テープをシリコーン化されたばかりの面に貼り、続いてまた引き剥がした。この粘着テープを粘着表面が接触するように折り曲げた。次いで、この両端部を引き離した(ループ試験)。相互に粘着する層が良好な粘着性を示せば、このことは支持体上でのシリコーン層の良好な付着性を示すことになる。両試験の評価は、1〜6の評定:1=秀、6=不可で実施する。
シリコーン化された表面上を指で強く1回摩擦して、そしてこの位置を斜めに入射する光において観察する。この位置で明度の差又は筋が生ずれば、このシリコーン生成物は最適には付着していないことになる。更に、このシリコーン層を指で繰り返し激しく摩擦して、そして摩耗粒子の量を観察する。両試験の評価は、1〜6の評定により実施する。
Claims (8)
- 剥離紙及び剥離フィルムのための下塗剤におけるシラン官能性ポリビニルアルコールの使用であって、該シラン官能性ポリビニルアルコールが、
a)1〜18個のC原子を有する非分枝鎖状又は分枝鎖状のアルキルカルボン酸の1種又は複数種のビニルエステル(ただし、該ビニルエステルの、全ポリマーに対して1〜30モル%の割合は、1〜6個のC原子を有するカルボン酸の1種又は複数種の、アルキル基が1〜6個のC原子を有する1−アルキルビニルエステルである。)、
b)0.01〜10モル%の1種又は複数種のシラン含有エチレン系不飽和モノマー、並びに場合により、
c)これらと共重合可能な他のコモノマー
をラジカル重合させ、そしてこれにより得られたポリマーをけん化させることにより得られ、75〜100モル%の加水分解度を有する完全けん化又は部分けん化されたビニルエステルコポリマーを基礎とする少なくとも1種のシラン含有ポリビニルアルコールを含有する使用。 - シラン含有ポリビニルアルコールが、ビニルアセテートとの共重合により得られることを特徴とする、請求項1に記載の使用。
- 1−メチルビニルアセテート、1−エチルビニルアセテート、並びに1−プロピルビニルアセテートを含む群からの1種又は複数種の1−アルキルビニルエステルが共重合されることを特徴とする、請求項1又は2に記載の使用。
- シラン含有ポリビニルアルコールが、一般式(I)R1SiR2 0−2(OR3)1−3[式中、R1は、CH2=CR4−(CH2)0−3又はCH2=CR4CO2(CH2)1−3を意味し、R2は、C1〜C3−アルキル基、C1〜C3−アルコキシ基又はハロゲンを意味し、R3は、1〜12個のC原子を有する非分枝鎖状又は分枝鎖状の置換又は非置換のアルキル基であるか若しくは2〜12個のC原子を有するアシル基であり、その際、R3は、エーテル基により中断されているか又は中断されておらず、かつR4はH又はCH3を示す]のエチレン系不飽和ケイ素化合物及び一般式(II)CH2=CR5−CO−NR6−R7−SiR8 m−(R9)3−m[式中、m=0〜2、R5は、H又はメチル基の何れかであり、R6は、H又は1〜5個のC原子を有するアルキル基であり、R7は、1〜5個のC原子を有するアルキレン基若しくは炭素鎖がO原子又はN原子により中断された二価の有機基であり、R8は、1〜5個のC原子を有するアルキル基であり、R9は、1〜40個のC原子を有するアルコキシ基である]で示される、更に複素環で置換又は非置換の、シラン基が含まれるメタ(アクリルアミド)を含む群からの1種又は複数種のエチレン系不飽和シラン含有モノマーの共重合により得られることを特徴とする、請求項1から3までの何れか1項に記載の使用。
- シラン含有ポリビニルアルコールが、γ−アクリル−又はγ−メタクリルオキシプロピルトリ(アルコキシ)シラン、α−メタクリルオキシメチルトリ(アルコキシ)シラン、γ−メタクリルオキシプロピルメチルジ(アルコキシ)シラン、ビニルアルキルジ(アルコキシ)シラン、ビニルトリ(アルコキシ)シランを含む群からの1種又は複数種のエチレン系不飽和シラン含有モノマーの共重合により得られることを特徴とする、請求項4に記載の使用。
- エチレン系不飽和シラン含有モノマーのアルコキシ基として、メトキシ基、エトキシ基、メトキシエチレン基、エトキシエチレン基、メトキシプロピレングリコールエーテル基又はエトキシプロピルレングリコールエーテル基が含まれている請求項5に記載の使用。
- 0.01〜1.5モル%のエチレン系不飽和シラン含有モノマーが共重合されることを特徴とする、請求項1から6までの何れか1項に記載の使用。
- 剥離紙及び剥離フィルムの剥離層塗布法における、請求項1から7までの何れか1項に記載の使用であって、担体上に下塗剤を塗布した後にシリコーン塗膜を施与する使用。
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DE10323203A DE10323203A1 (de) | 2003-05-22 | 2003-05-22 | Verwendung von silanfunktionellen Polyvinylalkoholen in Grundierungsmitteln für Trennpapiere und -folien |
PCT/EP2004/005153 WO2004104297A1 (de) | 2003-05-22 | 2004-05-13 | Verwendung von silanfunktionellen polyvinylalkoholen in grundierungsmitteln für trennpapiere und -folien |
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JP2006526084A JP2006526084A (ja) | 2006-11-16 |
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US (1) | US20060204703A1 (ja) |
EP (1) | EP1625254B1 (ja) |
JP (1) | JP4377408B2 (ja) |
CN (1) | CN100365208C (ja) |
AT (1) | ATE335102T1 (ja) |
DE (2) | DE10323203A1 (ja) |
RU (1) | RU2329289C2 (ja) |
WO (1) | WO2004104297A1 (ja) |
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DE102005000823A1 (de) * | 2005-01-05 | 2006-07-13 | Consortium für elektrochemische Industrie GmbH | Vernetzbare, silanmodifizierte Mischpolymerisate |
DE102008000585A1 (de) * | 2008-03-10 | 2009-09-17 | Wacker Chemie Ag | Binderhaltige kolloidale wässrige Organopolysiloxandispersionen und deren Verwendung |
FI123351B (fi) * | 2008-06-03 | 2013-03-15 | Upm Kymmene Corp | Irrokemateriaalikoostumus, pohjamateriaali ja menetelmä pohjamateriaalin valmistamiseksi, pintakäsittelyaine pohjamateriaalia varten sekä pintakäsittelyaineen käyttö |
DE102009002130A1 (de) * | 2009-04-02 | 2010-10-14 | Wacker Chemie Ag | Membranen auf Basis von Polyvinylalkohol |
FI20095392A0 (fi) * | 2009-04-09 | 2009-04-09 | Upm Kymmene Corp | Menetelmä substraatin pinnan käsittelemiseksi |
AU2009347572B2 (en) * | 2009-06-09 | 2014-10-30 | Tarkett G.D.L. S.A. | Multilayer surface coating with barrier layer |
RU2573901C2 (ru) * | 2010-10-12 | 2016-01-27 | Таркетт Гдл | Способ получения поверхностного покрытия, имеющего защитный слой |
DE102013107329A1 (de) | 2013-07-10 | 2015-01-15 | Kuraray Europe Gmbh | Imprägnierungsmaterialien für Release-Papiere |
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US3436252A (en) * | 1967-04-13 | 1969-04-01 | Stauffer Chemical Co | Paper release composition |
DE76490T1 (de) * | 1981-10-05 | 1983-12-08 | Kuraray Co., Ltd., Kurashiki, Okayama | Mittel zur papierbeschichtung. |
JPS58214596A (ja) * | 1982-06-01 | 1983-12-13 | 株式会社クラレ | 加工用原紙の製造方法 |
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DE3622820A1 (de) * | 1986-07-08 | 1988-01-21 | Wacker Chemie Gmbh | Cobinder fuer streichmassen |
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US5358977A (en) * | 1990-10-23 | 1994-10-25 | Daubert Coated Products, Inc. | Stabilized paper substrate for release liners using aromatic and aliphatic primers, and novel primer coat |
DE69603450T2 (de) * | 1996-04-02 | 2000-03-30 | Kuraray Co | Papierbeschichtungsmittel |
DE19641064A1 (de) * | 1996-10-04 | 1998-04-09 | Wacker Chemie Gmbh | Modifizierte Polyvinylbutyrale mit niederer Lösungsviskosität |
DE10035588A1 (de) * | 2000-07-21 | 2002-02-07 | Wacker Polymer Systems Gmbh | Verfahren zur Herstellung von zweiphasigen Polymerisaten in Form deren wässrigen Polymerdispersionen und in Wasser redispergierbaren Polymerpulver |
DE10232666A1 (de) * | 2002-07-18 | 2004-02-05 | Wacker Polymer Systems Gmbh & Co. Kg | Silan-haltiger Polyvinylalkohol für Papierstreichmassen |
-
2003
- 2003-05-22 DE DE10323203A patent/DE10323203A1/de not_active Withdrawn
-
2004
- 2004-05-13 EP EP04732604A patent/EP1625254B1/de not_active Expired - Lifetime
- 2004-05-13 WO PCT/EP2004/005153 patent/WO2004104297A1/de active IP Right Grant
- 2004-05-13 CN CNB2004800096530A patent/CN100365208C/zh not_active Expired - Fee Related
- 2004-05-13 RU RU2005139921/04A patent/RU2329289C2/ru active
- 2004-05-13 JP JP2006508176A patent/JP4377408B2/ja not_active Expired - Lifetime
- 2004-05-13 AT AT04732604T patent/ATE335102T1/de not_active IP Right Cessation
- 2004-05-13 US US10/552,678 patent/US20060204703A1/en not_active Abandoned
- 2004-05-13 DE DE502004001117T patent/DE502004001117D1/de not_active Expired - Fee Related
Also Published As
Publication number | Publication date |
---|---|
ATE335102T1 (de) | 2006-08-15 |
RU2329289C2 (ru) | 2008-07-20 |
JP2006526084A (ja) | 2006-11-16 |
EP1625254B1 (de) | 2006-08-02 |
US20060204703A1 (en) | 2006-09-14 |
CN100365208C (zh) | 2008-01-30 |
EP1625254A1 (de) | 2006-02-15 |
WO2004104297A1 (de) | 2004-12-02 |
DE502004001117D1 (de) | 2006-09-14 |
CN1771367A (zh) | 2006-05-10 |
DE10323203A1 (de) | 2004-12-23 |
RU2005139921A (ru) | 2007-06-27 |
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