JP4359147B2 - セルロース繊維材料の紫外線防護指数を改善する方法 - Google Patents
セルロース繊維材料の紫外線防護指数を改善する方法 Download PDFInfo
- Publication number
- JP4359147B2 JP4359147B2 JP2003568152A JP2003568152A JP4359147B2 JP 4359147 B2 JP4359147 B2 JP 4359147B2 JP 2003568152 A JP2003568152 A JP 2003568152A JP 2003568152 A JP2003568152 A JP 2003568152A JP 4359147 B2 JP4359147 B2 JP 4359147B2
- Authority
- JP
- Japan
- Prior art keywords
- formula
- weight
- fiber material
- compound
- alkyl
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 239000002657 fibrous material Substances 0.000 title claims description 30
- 238000000034 method Methods 0.000 title claims description 28
- 230000006750 UV protection Effects 0.000 title claims description 6
- 150000001875 compounds Chemical class 0.000 claims description 29
- 239000006096 absorbing agent Substances 0.000 claims description 22
- 229910052739 hydrogen Inorganic materials 0.000 claims description 11
- 239000001257 hydrogen Substances 0.000 claims description 11
- 125000004435 hydrogen atom Chemical class [H]* 0.000 claims description 10
- 229920003043 Cellulose fiber Polymers 0.000 claims description 9
- 239000000835 fiber Substances 0.000 claims description 9
- -1 alkyl hydrogen Chemical class 0.000 claims description 7
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims description 7
- 125000000547 substituted alkyl group Chemical group 0.000 claims description 7
- 239000000203 mixture Substances 0.000 claims description 6
- 125000001424 substituent group Chemical group 0.000 claims description 5
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 claims description 4
- 229910052783 alkali metal Inorganic materials 0.000 claims description 4
- 150000001340 alkali metals Chemical group 0.000 claims description 4
- 150000001412 amines Chemical class 0.000 claims description 4
- 150000001768 cations Chemical class 0.000 claims description 4
- 125000004573 morpholin-4-yl group Chemical group N1(CCOCC1)* 0.000 claims description 4
- 125000000217 alkyl group Chemical group 0.000 claims description 3
- 125000004642 (C1-C12) alkoxy group Chemical group 0.000 claims description 2
- 125000003118 aryl group Chemical group 0.000 claims description 2
- 125000001309 chloro group Chemical group Cl* 0.000 claims description 2
- 125000001153 fluoro group Chemical group F* 0.000 claims description 2
- 238000006467 substitution reaction Methods 0.000 claims 1
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 12
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 12
- 239000000463 material Substances 0.000 description 12
- 239000006081 fluorescent whitening agent Substances 0.000 description 10
- 239000004744 fabric Substances 0.000 description 9
- 239000011541 reaction mixture Substances 0.000 description 8
- HZAXFHJVJLSVMW-UHFFFAOYSA-N 2-Aminoethan-1-ol Chemical compound NCCO HZAXFHJVJLSVMW-UHFFFAOYSA-N 0.000 description 7
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 7
- 229920000742 Cotton Polymers 0.000 description 6
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 6
- 239000007788 liquid Substances 0.000 description 6
- 230000005855 radiation Effects 0.000 description 6
- 235000017550 sodium carbonate Nutrition 0.000 description 6
- 229910000029 sodium carbonate Inorganic materials 0.000 description 6
- 239000000725 suspension Substances 0.000 description 6
- 239000007864 aqueous solution Substances 0.000 description 4
- 229920002678 cellulose Polymers 0.000 description 4
- 239000001913 cellulose Substances 0.000 description 4
- 235000011121 sodium hydroxide Nutrition 0.000 description 4
- 239000000243 solution Substances 0.000 description 4
- 0 CC(C)=*C(*c1ccc(*=*)c(N=O)c1)=C*C(*)=* Chemical compound CC(C)=*C(*c1ccc(*=*)c(N=O)c1)=C*C(*)=* 0.000 description 3
- 239000004115 Sodium Silicate Substances 0.000 description 3
- MGNCLNQXLYJVJD-UHFFFAOYSA-N cyanuric chloride Chemical compound ClC1=NC(Cl)=NC(Cl)=N1 MGNCLNQXLYJVJD-UHFFFAOYSA-N 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 238000004128 high performance liquid chromatography Methods 0.000 description 3
- 230000003287 optical effect Effects 0.000 description 3
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 3
- 230000004224 protection Effects 0.000 description 3
- 239000011780 sodium chloride Substances 0.000 description 3
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 description 3
- 229910052911 sodium silicate Inorganic materials 0.000 description 3
- 125000003107 substituted aryl group Chemical group 0.000 description 3
- PQJZHMCWDKOPQG-UHFFFAOYSA-N 2-anilino-2-oxoacetic acid Chemical compound OC(=O)C(=O)NC1=CC=CC=C1 PQJZHMCWDKOPQG-UHFFFAOYSA-N 0.000 description 2
- KXDAEFPNCMNJSK-UHFFFAOYSA-N Benzamide Chemical compound NC(=O)C1=CC=CC=C1 KXDAEFPNCMNJSK-UHFFFAOYSA-N 0.000 description 2
- 125000002853 C1-C4 hydroxyalkyl group Chemical group 0.000 description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 2
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 2
- 239000004952 Polyamide Substances 0.000 description 2
- 238000013019 agitation Methods 0.000 description 2
- 239000002518 antifoaming agent Substances 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- YAKFHPREDNNSFX-UHFFFAOYSA-L disodium;5-amino-2-[2-(4-amino-2-sulfonatophenyl)ethenyl]benzenesulfonate Chemical compound [Na+].[Na+].[O-]S(=O)(=O)C1=CC(N)=CC=C1C=CC1=CC=C(N)C=C1S([O-])(=O)=O YAKFHPREDNNSFX-UHFFFAOYSA-L 0.000 description 2
- 238000004043 dyeing Methods 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- 229920002647 polyamide Polymers 0.000 description 2
- BWHMMNNQKKPAPP-UHFFFAOYSA-L potassium carbonate Chemical compound [K+].[K+].[O-]C([O-])=O BWHMMNNQKKPAPP-UHFFFAOYSA-L 0.000 description 2
- 239000000047 product Substances 0.000 description 2
- 150000003839 salts Chemical class 0.000 description 2
- 230000037380 skin damage Effects 0.000 description 2
- VWDWKYIASSYTQR-UHFFFAOYSA-N sodium nitrate Chemical compound [Na+].[O-][N+]([O-])=O VWDWKYIASSYTQR-UHFFFAOYSA-N 0.000 description 2
- 238000010025 steaming Methods 0.000 description 2
- 238000003756 stirring Methods 0.000 description 2
- HJIAMFHSAAEUKR-UHFFFAOYSA-N (2-hydroxyphenyl)-phenylmethanone Chemical compound OC1=CC=CC=C1C(=O)C1=CC=CC=C1 HJIAMFHSAAEUKR-UHFFFAOYSA-N 0.000 description 1
- 125000004769 (C1-C4) alkylsulfonyl group Chemical group 0.000 description 1
- JIHQDMXYYFUGFV-UHFFFAOYSA-N 1,3,5-triazine Chemical compound C1=NC=NC=N1 JIHQDMXYYFUGFV-UHFFFAOYSA-N 0.000 description 1
- 150000000182 1,3,5-triazines Chemical class 0.000 description 1
- YHCGGLXPGFJNCO-UHFFFAOYSA-N 2-(2H-benzotriazol-4-yl)phenol Chemical compound OC1=CC=CC=C1C1=CC=CC2=C1N=NN2 YHCGGLXPGFJNCO-UHFFFAOYSA-N 0.000 description 1
- UAGYXNZCZVTVJG-UHFFFAOYSA-N 3-amino-6-(2-phenylethenyl)benzene-1,2-disulfonic acid Chemical compound OS(=O)(=O)C1=C(S(O)(=O)=O)C(N)=CC=C1C=CC1=CC=CC=C1 UAGYXNZCZVTVJG-UHFFFAOYSA-N 0.000 description 1
- YECHMIOBPCMIGF-UHFFFAOYSA-N 4-amino-n-(2-hydroxyethyl)benzamide Chemical compound NC1=CC=C(C(=O)NCCO)C=C1 YECHMIOBPCMIGF-UHFFFAOYSA-N 0.000 description 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 1
- 241001340526 Chrysoclista linneella Species 0.000 description 1
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 1
- UIIMBOGNXHQVGW-DEQYMQKBSA-M Sodium bicarbonate-14C Chemical compound [Na+].O[14C]([O-])=O UIIMBOGNXHQVGW-DEQYMQKBSA-M 0.000 description 1
- 239000004280 Sodium formate Substances 0.000 description 1
- SAQSTQBVENFSKT-UHFFFAOYSA-M TCA-sodium Chemical compound [Na+].[O-]C(=O)C(Cl)(Cl)Cl SAQSTQBVENFSKT-UHFFFAOYSA-M 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 150000008360 acrylonitriles Chemical class 0.000 description 1
- 125000003277 amino group Chemical group 0.000 description 1
- 125000002490 anilino group Chemical group [H]N(*)C1=C([H])C([H])=C([H])C([H])=C1[H] 0.000 description 1
- 230000001153 anti-wrinkle effect Effects 0.000 description 1
- 239000013011 aqueous formulation Substances 0.000 description 1
- 239000007900 aqueous suspension Substances 0.000 description 1
- 239000011230 binding agent Substances 0.000 description 1
- 230000005540 biological transmission Effects 0.000 description 1
- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 125000004432 carbon atom Chemical group C* 0.000 description 1
- 239000007795 chemical reaction product Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 238000011437 continuous method Methods 0.000 description 1
- 238000010924 continuous production Methods 0.000 description 1
- 239000006071 cream Substances 0.000 description 1
- 125000000753 cycloalkyl group Chemical group 0.000 description 1
- 125000000113 cyclohexyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])(*)C([H])([H])C1([H])[H] 0.000 description 1
- 125000001511 cyclopentyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])(*)C1([H])[H] 0.000 description 1
- 230000006378 damage Effects 0.000 description 1
- 238000007865 diluting Methods 0.000 description 1
- 239000003623 enhancer Substances 0.000 description 1
- 150000002169 ethanolamines Chemical class 0.000 description 1
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
- 239000012065 filter cake Substances 0.000 description 1
- 239000000706 filtrate Substances 0.000 description 1
- 238000005470 impregnation Methods 0.000 description 1
- 238000010348 incorporation Methods 0.000 description 1
- 125000001449 isopropyl group Chemical group [H]C([H])([H])C([H])(*)C([H])([H])[H] 0.000 description 1
- 240000004308 marijuana Species 0.000 description 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
- 125000001280 n-hexyl group Chemical group C(CCCCC)* 0.000 description 1
- 125000004123 n-propyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 125000001624 naphthyl group Chemical group 0.000 description 1
- 230000007935 neutral effect Effects 0.000 description 1
- 230000035515 penetration Effects 0.000 description 1
- HWGNBUXHKFFFIH-UHFFFAOYSA-I pentasodium;[oxido(phosphonatooxy)phosphoryl] phosphate Chemical compound [Na+].[Na+].[Na+].[Na+].[Na+].[O-]P([O-])(=O)OP([O-])(=O)OP([O-])([O-])=O HWGNBUXHKFFFIH-UHFFFAOYSA-I 0.000 description 1
- 229920000728 polyester Polymers 0.000 description 1
- 229910000027 potassium carbonate Inorganic materials 0.000 description 1
- 235000011181 potassium carbonates Nutrition 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 239000002244 precipitate Substances 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 239000000985 reactive dye Substances 0.000 description 1
- 239000004627 regenerated cellulose Substances 0.000 description 1
- 150000003902 salicylic acid esters Chemical class 0.000 description 1
- HLBBKKJFGFRGMU-UHFFFAOYSA-M sodium formate Chemical compound [Na+].[O-]C=O HLBBKKJFGFRGMU-UHFFFAOYSA-M 0.000 description 1
- 235000019254 sodium formate Nutrition 0.000 description 1
- 235000010344 sodium nitrate Nutrition 0.000 description 1
- 239000004317 sodium nitrate Substances 0.000 description 1
- 235000019794 sodium silicate Nutrition 0.000 description 1
- 229910052938 sodium sulfate Inorganic materials 0.000 description 1
- 235000011152 sodium sulphate Nutrition 0.000 description 1
- 235000019832 sodium triphosphate Nutrition 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 125000000020 sulfo group Chemical group O=S(=O)([*])O[H] 0.000 description 1
- 230000000475 sunscreen effect Effects 0.000 description 1
- 239000000516 sunscreening agent Substances 0.000 description 1
- 239000004753 textile Substances 0.000 description 1
- 238000002834 transmittance Methods 0.000 description 1
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 1
- 229920002554 vinyl polymer Polymers 0.000 description 1
- 239000000080 wetting agent Substances 0.000 description 1
- 230000002087 whitening effect Effects 0.000 description 1
- 238000004383 yellowing Methods 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06L—DRY-CLEANING, WASHING OR BLEACHING FIBRES, FILAMENTS, THREADS, YARNS, FABRICS, FEATHERS OR MADE-UP FIBROUS GOODS; BLEACHING LEATHER OR FURS
- D06L4/00—Bleaching fibres, filaments, threads, yarns, fabrics, feathers or made-up fibrous goods; Bleaching leather or furs
- D06L4/60—Optical bleaching or brightening
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
- D06M13/35—Heterocyclic compounds
- D06M13/355—Heterocyclic compounds having six-membered heterocyclic rings
- D06M13/358—Triazines
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D251/00—Heterocyclic compounds containing 1,3,5-triazine rings
- C07D251/02—Heterocyclic compounds containing 1,3,5-triazine rings not condensed with other rings
- C07D251/12—Heterocyclic compounds containing 1,3,5-triazine rings not condensed with other rings having three double bonds between ring members or between ring members and non-ring members
- C07D251/26—Heterocyclic compounds containing 1,3,5-triazine rings not condensed with other rings having three double bonds between ring members or between ring members and non-ring members with only hetero atoms directly attached to ring carbon atoms
- C07D251/40—Nitrogen atoms
- C07D251/54—Three nitrogen atoms
- C07D251/68—Triazinylamino stilbenes
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/26—Organic compounds containing nitrogen
- C11D3/28—Heterocyclic compounds containing nitrogen in the ring
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
- D06M2200/25—Resistance to light or sun, i.e. protection of the textile itself as well as UV shielding materials or treatment compositions therefor; Anti-yellowing treatments
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Life Sciences & Earth Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Artificial Filaments (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP02405118 | 2002-02-18 | ||
| PCT/EP2003/001326 WO2003069047A1 (en) | 2002-02-18 | 2003-02-11 | A process for improving the sun protection factor of cellulosic fibre material |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| JP2005517822A JP2005517822A (ja) | 2005-06-16 |
| JP2005517822A5 JP2005517822A5 (enExample) | 2006-03-30 |
| JP4359147B2 true JP4359147B2 (ja) | 2009-11-04 |
Family
ID=27675792
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2003568152A Expired - Fee Related JP4359147B2 (ja) | 2002-02-18 | 2003-02-11 | セルロース繊維材料の紫外線防護指数を改善する方法 |
Country Status (11)
| Country | Link |
|---|---|
| US (1) | US7425222B2 (enExample) |
| EP (1) | EP1476601A1 (enExample) |
| JP (1) | JP4359147B2 (enExample) |
| KR (1) | KR100966483B1 (enExample) |
| CN (1) | CN1633531A (enExample) |
| AU (1) | AU2003206876A1 (enExample) |
| BR (1) | BR0307736A (enExample) |
| MX (1) | MXPA04007994A (enExample) |
| MY (1) | MY139207A (enExample) |
| TW (1) | TWI304847B (enExample) |
| WO (1) | WO2003069047A1 (enExample) |
Families Citing this family (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| BR0317151A (pt) * | 2002-12-10 | 2005-11-01 | Ciba Sc Holding Ag | Misturas de agentes de branqueamento fluorescentes |
| US7166564B2 (en) * | 2003-08-21 | 2007-01-23 | Ciba Specialty Chemicals Corp. | Optical brighteners |
| JP2009096972A (ja) | 2007-02-20 | 2009-05-07 | Fujifilm Corp | 紫外線吸収剤を含む高分子材料 |
| WO2008123504A1 (ja) | 2007-03-30 | 2008-10-16 | Fujifilm Corporation | 紫外線吸収剤組成物 |
| EP2177524A4 (en) | 2007-08-16 | 2011-12-14 | Fujifilm Corp | HETEROCYCLIC COMPOUND, ULTRAVIOLET RADIATION ABSORBER, AND COMPOSITION COMPRISING THE ULTRAVIOLET RADIATION ABSORBER |
| JP5244437B2 (ja) | 2008-03-31 | 2013-07-24 | 富士フイルム株式会社 | 紫外線吸収剤組成物 |
| JP5250289B2 (ja) | 2008-03-31 | 2013-07-31 | 富士フイルム株式会社 | 紫外線吸収剤組成物 |
| JP2009270062A (ja) | 2008-05-09 | 2009-11-19 | Fujifilm Corp | 紫外線吸収剤組成物 |
| CN104631110B (zh) * | 2013-08-15 | 2018-03-16 | 东丽纤维研究所（中国）有限公司 | 一种防紫外纺织品 |
| CN104695225B (zh) * | 2013-12-04 | 2017-12-19 | 东丽纤维研究所（中国）有限公司 | 一种抗紫外纺织品 |
| CN105332275B (zh) * | 2014-05-30 | 2019-07-12 | 东丽纤维研究所（中国）有限公司 | 一种对位芳纶纤维 |
| CN107354014A (zh) * | 2017-06-28 | 2017-11-17 | 太仓大唐化纤厂 | 一种提高化纤抗紫外线能力的洗涤剂 |
Family Cites Families (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5949537A (ja) * | 1982-09-14 | 1984-03-22 | Konishiroku Photo Ind Co Ltd | ハロゲン化銀写真感光材料の処理方法 |
| GB2291658B (en) * | 1994-07-23 | 1998-08-12 | Ciba Geigy Ag | Aqueous textile treatment compositions containing an ultra-violet absorbing agent |
| TW383324B (en) * | 1994-10-13 | 2000-03-01 | Ciba Sc Holding Ag | UV absorbants and the use |
| US5938793A (en) * | 1995-02-13 | 1999-08-17 | Ciba Specialty Chemicals Corporation | Process for increasing the sun protection factor of cellulosic fibre materials |
| GB9503474D0 (en) * | 1995-02-22 | 1995-04-12 | Ciba Geigy Ag | Compounds and their use |
| GB9611614D0 (en) * | 1996-06-04 | 1996-08-07 | Ciba Geigy Ag | Process for inhibiting the effect of flourescent whitening agents |
| US5888643A (en) * | 1997-05-23 | 1999-03-30 | Eastman Kodak Company | Controlling bending stiffness in photographic paper |
| GB9726365D0 (en) | 1997-12-13 | 1998-02-11 | Ciba Sc Holding Ag | Compounds |
| MXPA01012698A (es) * | 1999-06-11 | 2002-07-02 | Ciba Sc Holding Ag | Uso de uvas para suprimir la fluorescencia de materiales de fibras textiles tratados con agentes blanqueadores fluorescentes. |
| TWI250237B (en) * | 1999-10-25 | 2006-03-01 | Ciba Sc Holding Ag | Mixtures of fluorescent whitening agents |
| TWI252270B (en) * | 2000-07-20 | 2006-04-01 | Ciba Sc Holding Ag | A method for the fluorescent whitening of cotton |
-
2002
- 2002-02-11 US US10/504,945 patent/US7425222B2/en not_active Expired - Fee Related
-
2003
- 2003-02-06 MY MYPI20030399A patent/MY139207A/en unknown
- 2003-02-11 EP EP20030704587 patent/EP1476601A1/en not_active Withdrawn
- 2003-02-11 KR KR1020047012694A patent/KR100966483B1/ko not_active Expired - Fee Related
- 2003-02-11 MX MXPA04007994A patent/MXPA04007994A/es active IP Right Grant
- 2003-02-11 JP JP2003568152A patent/JP4359147B2/ja not_active Expired - Fee Related
- 2003-02-11 AU AU2003206876A patent/AU2003206876A1/en not_active Abandoned
- 2003-02-11 WO PCT/EP2003/001326 patent/WO2003069047A1/en not_active Ceased
- 2003-02-11 BR BR0307736-5A patent/BR0307736A/pt not_active IP Right Cessation
- 2003-02-11 CN CNA03804059XA patent/CN1633531A/zh active Pending
- 2003-02-17 TW TW092103202A patent/TWI304847B/zh not_active IP Right Cessation
Also Published As
| Publication number | Publication date |
|---|---|
| MXPA04007994A (es) | 2004-11-26 |
| AU2003206876A1 (en) | 2003-09-04 |
| WO2003069047A1 (en) | 2003-08-21 |
| TWI304847B (en) | 2009-01-01 |
| EP1476601A1 (en) | 2004-11-17 |
| JP2005517822A (ja) | 2005-06-16 |
| KR100966483B1 (ko) | 2010-06-29 |
| BR0307736A (pt) | 2005-01-25 |
| TW200303950A (en) | 2003-09-16 |
| KR20040089638A (ko) | 2004-10-21 |
| CN1633531A (zh) | 2005-06-29 |
| US20050106114A1 (en) | 2005-05-19 |
| MY139207A (en) | 2009-08-28 |
| US7425222B2 (en) | 2008-09-16 |
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