JP4299002B2 - シリコアルミノリン酸塩モレキュラーシーブ - Google Patents
シリコアルミノリン酸塩モレキュラーシーブ Download PDFInfo
- Publication number
- JP4299002B2 JP4299002B2 JP2002569738A JP2002569738A JP4299002B2 JP 4299002 B2 JP4299002 B2 JP 4299002B2 JP 2002569738 A JP2002569738 A JP 2002569738A JP 2002569738 A JP2002569738 A JP 2002569738A JP 4299002 B2 JP4299002 B2 JP 4299002B2
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- JP
- Japan
- Prior art keywords
- molecular sieve
- aei
- cha
- silicoaluminophosphate
- range
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- URGAHOPLAPQHLN-UHFFFAOYSA-N sodium aluminosilicate Chemical compound [Na+].[Al+3].[O-][Si]([O-])=O.[O-][Si]([O-])=O URGAHOPLAPQHLN-UHFFFAOYSA-N 0.000 title claims description 105
- 239000002808 molecular sieve Substances 0.000 title claims description 103
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 65
- 239000000203 mixture Substances 0.000 claims description 52
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 claims description 48
- 238000000034 method Methods 0.000 claims description 44
- 238000006243 chemical reaction Methods 0.000 claims description 41
- 239000003054 catalyst Substances 0.000 claims description 37
- 229910018072 Al 2 O 3 Inorganic materials 0.000 claims description 32
- 150000001336 alkenes Chemical class 0.000 claims description 31
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims description 26
- 239000000377 silicon dioxide Substances 0.000 claims description 26
- 229940073455 tetraethylammonium hydroxide Drugs 0.000 claims description 25
- LRGJRHZIDJQFCL-UHFFFAOYSA-M tetraethylazanium;hydroxide Chemical group [OH-].CC[N+](CC)(CC)CC LRGJRHZIDJQFCL-UHFFFAOYSA-M 0.000 claims description 25
- 229910004298 SiO 2 Inorganic materials 0.000 claims description 23
- 238000002425 crystallisation Methods 0.000 claims description 22
- 230000008025 crystallization Effects 0.000 claims description 22
- 238000004458 analytical method Methods 0.000 claims description 19
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 claims description 15
- 238000002441 X-ray diffraction Methods 0.000 claims description 14
- 238000002156 mixing Methods 0.000 claims description 13
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims description 12
- -1 tetraethylammonium compound Chemical class 0.000 claims description 12
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 11
- 239000013078 crystal Substances 0.000 claims description 11
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims description 10
- 239000005977 Ethylene Substances 0.000 claims description 10
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 claims description 9
- 238000002360 preparation method Methods 0.000 claims description 9
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 claims description 9
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 claims description 9
- LCGLNKUTAGEVQW-UHFFFAOYSA-N Dimethyl ether Chemical compound COC LCGLNKUTAGEVQW-UHFFFAOYSA-N 0.000 claims description 8
- ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 claims description 8
- 239000003153 chemical reaction reagent Substances 0.000 claims description 8
- 238000010438 heat treatment Methods 0.000 claims description 8
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 claims description 7
- 229910052710 silicon Inorganic materials 0.000 claims description 7
- 239000010703 silicon Substances 0.000 claims description 7
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 claims description 6
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims description 6
- 229910052698 phosphorus Inorganic materials 0.000 claims description 6
- 239000011574 phosphorus Substances 0.000 claims description 6
- 238000000634 powder X-ray diffraction Methods 0.000 claims description 6
- MXRIRQGCELJRSN-UHFFFAOYSA-N O.O.O.[Al] Chemical compound O.O.O.[Al] MXRIRQGCELJRSN-UHFFFAOYSA-N 0.000 claims description 5
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 claims description 4
- VXAUWWUXCIMFIM-UHFFFAOYSA-M aluminum;oxygen(2-);hydroxide Chemical group [OH-].[O-2].[Al+3] VXAUWWUXCIMFIM-UHFFFAOYSA-M 0.000 claims description 4
- 239000001294 propane Substances 0.000 claims description 4
- 238000003756 stirring Methods 0.000 claims description 4
- 239000011230 binding agent Substances 0.000 claims description 3
- ZAFNJMIOTHYJRJ-UHFFFAOYSA-N Diisopropyl ether Chemical compound CC(C)OC(C)C ZAFNJMIOTHYJRJ-UHFFFAOYSA-N 0.000 claims description 2
- XOBKSJJDNFUZPF-UHFFFAOYSA-N Methoxyethane Chemical compound CCOC XOBKSJJDNFUZPF-UHFFFAOYSA-N 0.000 claims description 2
- IEJIGPNLZYLLBP-UHFFFAOYSA-N dimethyl carbonate Chemical compound COC(=O)OC IEJIGPNLZYLLBP-UHFFFAOYSA-N 0.000 claims description 2
- WSFSSNUMVMOOMR-NJFSPNSNSA-N methanone Chemical compound O=[14CH2] WSFSSNUMVMOOMR-NJFSPNSNSA-N 0.000 claims description 2
- BDERNNFJNOPAEC-UHFFFAOYSA-N propan-1-ol Chemical compound CCCO BDERNNFJNOPAEC-UHFFFAOYSA-N 0.000 claims description 2
- 241000269350 Anura Species 0.000 claims 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 36
- 239000000047 product Substances 0.000 description 28
- 239000012071 phase Substances 0.000 description 26
- 229910001868 water Inorganic materials 0.000 description 21
- 239000002002 slurry Substances 0.000 description 20
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 18
- 239000008367 deionised water Substances 0.000 description 15
- 229910021641 deionized water Inorganic materials 0.000 description 15
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 14
- 239000010457 zeolite Substances 0.000 description 11
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 10
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 9
- 229910001220 stainless steel Inorganic materials 0.000 description 9
- 239000010935 stainless steel Substances 0.000 description 9
- 230000003197 catalytic effect Effects 0.000 description 8
- 238000001816 cooling Methods 0.000 description 8
- 230000000737 periodic effect Effects 0.000 description 8
- ZZBAGJPKGRJIJH-UHFFFAOYSA-N 7h-purine-2-carbaldehyde Chemical compound O=CC1=NC=C2NC=NC2=N1 ZZBAGJPKGRJIJH-UHFFFAOYSA-N 0.000 description 7
- 241000640882 Condea Species 0.000 description 7
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 7
- 239000006227 byproduct Substances 0.000 description 7
- 239000007789 gas Substances 0.000 description 7
- 238000004519 manufacturing process Methods 0.000 description 7
- 239000000463 material Substances 0.000 description 7
- 229910052757 nitrogen Inorganic materials 0.000 description 7
- 239000001301 oxygen Substances 0.000 description 7
- 229910052760 oxygen Inorganic materials 0.000 description 7
- 229910021536 Zeolite Inorganic materials 0.000 description 6
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 description 6
- 230000008929 regeneration Effects 0.000 description 6
- 238000011069 regeneration method Methods 0.000 description 6
- 239000000126 substance Substances 0.000 description 6
- 238000006555 catalytic reaction Methods 0.000 description 5
- 239000003085 diluting agent Substances 0.000 description 5
- 229930195733 hydrocarbon Natural products 0.000 description 5
- 150000002430 hydrocarbons Chemical class 0.000 description 5
- 229920000098 polyolefin Polymers 0.000 description 5
- 150000001875 compounds Chemical class 0.000 description 4
- 239000007791 liquid phase Substances 0.000 description 4
- 239000000843 powder Substances 0.000 description 4
- 239000011541 reaction mixture Substances 0.000 description 4
- 239000004215 Carbon black (E152) Substances 0.000 description 3
- 125000004432 carbon atom Chemical group C* 0.000 description 3
- 239000000571 coke Substances 0.000 description 3
- 230000000052 comparative effect Effects 0.000 description 3
- 230000007547 defect Effects 0.000 description 3
- 238000010335 hydrothermal treatment Methods 0.000 description 3
- 230000003647 oxidation Effects 0.000 description 3
- 238000007254 oxidation reaction Methods 0.000 description 3
- 239000011148 porous material Substances 0.000 description 3
- 239000000725 suspension Substances 0.000 description 3
- 238000003786 synthesis reaction Methods 0.000 description 3
- HGINCPLSRVDWNT-UHFFFAOYSA-N Acrolein Chemical compound C=CC=O HGINCPLSRVDWNT-UHFFFAOYSA-N 0.000 description 2
- 229910017090 AlO 2 Inorganic materials 0.000 description 2
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 description 2
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 2
- YNQLUTRBYVCPMQ-UHFFFAOYSA-N Ethylbenzene Chemical compound CCC1=CC=CC=C1 YNQLUTRBYVCPMQ-UHFFFAOYSA-N 0.000 description 2
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 2
- MCMNRKCIXSYSNV-UHFFFAOYSA-N Zirconium dioxide Chemical compound O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 description 2
- 230000004913 activation Effects 0.000 description 2
- 238000013019 agitation Methods 0.000 description 2
- 150000001299 aldehydes Chemical class 0.000 description 2
- 229910052782 aluminium Inorganic materials 0.000 description 2
- SMZOGRDCAXLAAR-UHFFFAOYSA-N aluminium isopropoxide Chemical compound [Al+3].CC(C)[O-].CC(C)[O-].CC(C)[O-] SMZOGRDCAXLAAR-UHFFFAOYSA-N 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 238000001354 calcination Methods 0.000 description 2
- 238000004364 calculation method Methods 0.000 description 2
- 238000005119 centrifugation Methods 0.000 description 2
- 238000012512 characterization method Methods 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- RWGFKTVRMDUZSP-UHFFFAOYSA-N cumene Chemical compound CC(C)C1=CC=CC=C1 RWGFKTVRMDUZSP-UHFFFAOYSA-N 0.000 description 2
- 238000001914 filtration Methods 0.000 description 2
- 238000005243 fluidization Methods 0.000 description 2
- 229910021485 fumed silica Inorganic materials 0.000 description 2
- 230000036571 hydration Effects 0.000 description 2
- 238000006703 hydration reaction Methods 0.000 description 2
- 239000003701 inert diluent Substances 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 239000003921 oil Substances 0.000 description 2
- 150000002894 organic compounds Chemical class 0.000 description 2
- 239000012188 paraffin wax Substances 0.000 description 2
- 229910052761 rare earth metal Inorganic materials 0.000 description 2
- 150000002910 rare earth metals Chemical class 0.000 description 2
- 238000001878 scanning electron micrograph Methods 0.000 description 2
- 230000035945 sensitivity Effects 0.000 description 2
- 230000003068 static effect Effects 0.000 description 2
- DNIAPMSPPWPWGF-GSVOUGTGSA-N (R)-(-)-Propylene glycol Chemical compound C[C@@H](O)CO DNIAPMSPPWPWGF-GSVOUGTGSA-N 0.000 description 1
- WSLDOOZREJYCGB-UHFFFAOYSA-N 1,2-Dichloroethane Chemical compound ClCCCl WSLDOOZREJYCGB-UHFFFAOYSA-N 0.000 description 1
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 1
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 description 1
- 229910002012 Aerosil® Inorganic materials 0.000 description 1
- 229910017119 AlPO Inorganic materials 0.000 description 1
- OSDWBNJEKMUWAV-UHFFFAOYSA-N Allyl chloride Chemical compound ClCC=C OSDWBNJEKMUWAV-UHFFFAOYSA-N 0.000 description 1
- 239000005995 Aluminium silicate Substances 0.000 description 1
- 241000408939 Atalopedes campestris Species 0.000 description 1
- 239000002028 Biomass Substances 0.000 description 1
- 229920002799 BoPET Polymers 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 description 1
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 description 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- OTMSDBZUPAUEDD-UHFFFAOYSA-N Ethane Chemical compound CC OTMSDBZUPAUEDD-UHFFFAOYSA-N 0.000 description 1
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 1
- 229920000181 Ethylene propylene rubber Polymers 0.000 description 1
- 241000282326 Felis catus Species 0.000 description 1
- 239000005041 Mylar™ Substances 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- 239000004743 Polypropylene Substances 0.000 description 1
- GOOHAUXETOMSMM-UHFFFAOYSA-N Propylene oxide Chemical compound CC1CO1 GOOHAUXETOMSMM-UHFFFAOYSA-N 0.000 description 1
- 238000003917 TEM image Methods 0.000 description 1
- BOTDANWDWHJENH-UHFFFAOYSA-N Tetraethyl orthosilicate Chemical compound CCO[Si](OCC)(OCC)OCC BOTDANWDWHJENH-UHFFFAOYSA-N 0.000 description 1
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 description 1
- BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 description 1
- 239000003377 acid catalyst Substances 0.000 description 1
- 239000011149 active material Substances 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 150000001335 aliphatic alkanes Chemical class 0.000 description 1
- 125000001931 aliphatic group Chemical group 0.000 description 1
- 230000029936 alkylation Effects 0.000 description 1
- 238000005804 alkylation reaction Methods 0.000 description 1
- 125000002947 alkylene group Chemical group 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- ILRRQNADMUWWFW-UHFFFAOYSA-K aluminium phosphate Chemical compound O1[Al]2OP1(=O)O2 ILRRQNADMUWWFW-UHFFFAOYSA-K 0.000 description 1
- 235000012211 aluminium silicate Nutrition 0.000 description 1
- ANBBXQWFNXMHLD-UHFFFAOYSA-N aluminum;sodium;oxygen(2-) Chemical compound [O-2].[O-2].[Na+].[Al+3] ANBBXQWFNXMHLD-UHFFFAOYSA-N 0.000 description 1
- 229910052786 argon Inorganic materials 0.000 description 1
- 239000012298 atmosphere Substances 0.000 description 1
- 238000002453 autothermal reforming Methods 0.000 description 1
- 229910001593 boehmite Inorganic materials 0.000 description 1
- 239000001569 carbon dioxide Substances 0.000 description 1
- 229910002092 carbon dioxide Inorganic materials 0.000 description 1
- 229910002091 carbon monoxide Inorganic materials 0.000 description 1
- 239000003575 carbonaceous material Substances 0.000 description 1
- 150000001728 carbonyl compounds Chemical class 0.000 description 1
- 150000001732 carboxylic acid derivatives Chemical class 0.000 description 1
- 238000004517 catalytic hydrocracking Methods 0.000 description 1
- 239000003245 coal Substances 0.000 description 1
- 238000004590 computer program Methods 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- 238000005336 cracking Methods 0.000 description 1
- 239000002178 crystalline material Substances 0.000 description 1
- 238000003795 desorption Methods 0.000 description 1
- 239000000539 dimer Substances 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 238000007323 disproportionation reaction Methods 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000000635 electron micrograph Methods 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 238000000855 fermentation Methods 0.000 description 1
- 230000004151 fermentation Effects 0.000 description 1
- 239000011888 foil Substances 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 239000001307 helium Substances 0.000 description 1
- 229910052734 helium Inorganic materials 0.000 description 1
- SWQJXJOGLNCZEY-UHFFFAOYSA-N helium atom Chemical compound [He] SWQJXJOGLNCZEY-UHFFFAOYSA-N 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 125000004435 hydrogen atom Chemical class [H]* 0.000 description 1
- FAHBNUUHRFUEAI-UHFFFAOYSA-M hydroxidooxidoaluminium Chemical compound O[Al]=O FAHBNUUHRFUEAI-UHFFFAOYSA-M 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 238000006317 isomerization reaction Methods 0.000 description 1
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 1
- 150000002576 ketones Chemical class 0.000 description 1
- 238000013178 mathematical model Methods 0.000 description 1
- 239000012968 metallocene catalyst Substances 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- 239000003345 natural gas Substances 0.000 description 1
- 229910052605 nesosilicate Inorganic materials 0.000 description 1
- 239000003027 oil sand Substances 0.000 description 1
- 150000004762 orthosilicates Chemical class 0.000 description 1
- 125000004430 oxygen atom Chemical group O* 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 239000003208 petroleum Substances 0.000 description 1
- 239000006069 physical mixture Substances 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 229920001155 polypropylene Polymers 0.000 description 1
- 239000010453 quartz Substances 0.000 description 1
- 230000005855 radiation Effects 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 238000004064 recycling Methods 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 150000004760 silicates Chemical class 0.000 description 1
- RMAQACBXLXPBSY-UHFFFAOYSA-N silicic acid Chemical compound O[Si](O)(O)O RMAQACBXLXPBSY-UHFFFAOYSA-N 0.000 description 1
- 238000004088 simulation Methods 0.000 description 1
- 229910001388 sodium aluminate Inorganic materials 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 238000010561 standard procedure Methods 0.000 description 1
- 238000000629 steam reforming Methods 0.000 description 1
- HWCKGOZZJDHMNC-UHFFFAOYSA-M tetraethylammonium bromide Chemical compound [Br-].CC[N+](CC)(CC)CC HWCKGOZZJDHMNC-UHFFFAOYSA-M 0.000 description 1
- YMBCJWGVCUEGHA-UHFFFAOYSA-M tetraethylammonium chloride Chemical compound [Cl-].CC[N+](CC)(CC)CC YMBCJWGVCUEGHA-UHFFFAOYSA-M 0.000 description 1
- GTCDARUMAMVCRO-UHFFFAOYSA-M tetraethylazanium;acetate Chemical compound CC([O-])=O.CC[N+](CC)(CC)CC GTCDARUMAMVCRO-UHFFFAOYSA-M 0.000 description 1
- QSUJAUYJBJRLKV-UHFFFAOYSA-M tetraethylazanium;fluoride Chemical compound [F-].CC[N+](CC)(CC)CC QSUJAUYJBJRLKV-UHFFFAOYSA-M 0.000 description 1
- AJPPAKACCOFNEN-UHFFFAOYSA-K tetraethylazanium;phosphate Chemical compound [O-]P([O-])([O-])=O.CC[N+](CC)(CC)CC.CC[N+](CC)(CC)CC.CC[N+](CC)(CC)CC AJPPAKACCOFNEN-UHFFFAOYSA-K 0.000 description 1
- 125000000383 tetramethylene group Chemical group [H]C([H])([*:1])C([H])([H])C([H])([H])C([H])([H])[*:2] 0.000 description 1
- DQWPFSLDHJDLRL-UHFFFAOYSA-N triethyl phosphate Chemical compound CCOP(=O)(OCC)OCC DQWPFSLDHJDLRL-UHFFFAOYSA-N 0.000 description 1
- 239000013638 trimer Substances 0.000 description 1
- 239000004711 α-olefin Substances 0.000 description 1
Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B39/00—Compounds having molecular sieve and base-exchange properties, e.g. crystalline zeolites; Their preparation; After-treatment, e.g. ion-exchange or dealumination
- C01B39/54—Phosphates, e.g. APO or SAPO compounds
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B37/00—Compounds having molecular sieve properties but not having base-exchange properties
- C01B37/06—Aluminophosphates containing other elements, e.g. metals, boron
- C01B37/08—Silicoaluminophosphates [SAPO compounds], e.g. CoSAPO
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/005—Mixtures of molecular sieves comprising at least one molecular sieve which is not an aluminosilicate zeolite, e.g. from groups B01J29/03 - B01J29/049 or B01J29/82 - B01J29/89
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/82—Phosphates
- B01J29/84—Aluminophosphates containing other elements, e.g. metals, boron
- B01J29/85—Silicoaluminophosphates [SAPO compounds]
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/0009—Use of binding agents; Moulding; Pressing; Powdering; Granulating; Addition of materials ameliorating the mechanical properties of the product catalyst
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C1/00—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon
- C07C1/20—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon starting from organic compounds containing only oxygen atoms as heteroatoms
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G3/00—Production of liquid hydrocarbon mixtures from oxygen-containing organic materials, e.g. fatty oils, fatty acids
- C10G3/42—Catalytic treatment
- C10G3/44—Catalytic treatment characterised by the catalyst used
- C10G3/48—Catalytic treatment characterised by the catalyst used further characterised by the catalyst support
- C10G3/49—Catalytic treatment characterised by the catalyst used further characterised by the catalyst support containing crystalline aluminosilicates, e.g. molecular sieves
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G2400/00—Products obtained by processes covered by groups C10G9/00 - C10G69/14
- C10G2400/20—C2-C4 olefins
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P30/00—Technologies relating to oil refining and petrochemical industry
- Y02P30/20—Technologies relating to oil refining and petrochemical industry using bio-feedstock
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P30/00—Technologies relating to oil refining and petrochemical industry
- Y02P30/40—Ethylene production
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Description
P2O5 :Al2O3 0.6:1乃至1.2:1
SiO2:Al2O3 0.005:1乃至0.35:1
H2O :Al2O3 10:1乃至40:1
を有し、及び、前記鋳型はテトラエチルアンモニウム化合物である。本発明の実施態様では、構造指示有機試薬は、水酸化テトラエチルアンモニウムである。
本発明は、AEI及びCHA骨格タイプを有するモレキュラーシーブの少なくとも1の連晶相(intergrown phase)を含むシリコアルミノリン酸塩モレキュラーシーブに関するものであり、ここで、連晶相は、当該シリコアルミノリン酸塩モレキュラーシーブの焼成試料についての粉末X線回折パターンを用いるDIFFaX分析によって約5/95乃至40/60のAEI/CHA比を有する。
b)工程a)で調製した混合物を、結晶化温度まで連続的に混合及び加熱する工程;
c)2乃至150時間の攪拌の下で、混合物を結晶化温度に維持する工程;
d)シリコアルミノリン酸塩モレキュラーシーブの結晶を回収する工程、
ここで、工程a)において調製される混合物は、以下に示す範囲のモル組成
P2O5 :Al2O3 0.6:1乃至1.2:1
SiO2:Al2O3 0.005:1乃至0.35:1
H2O :Al2O3 10:1乃至40:1
を有し、及び、前記鋳型はテトラエチルアンモニウム化合物である。
P2O5 :Al2O3 0.8:1乃至1.1:1
SiO2:Al2O3 0.01:1乃至0.3:1、
最も好ましくは0.015:1乃至0.25:1
H2O :Al2O3 10:1乃至40:1
を有する。
33.55グラムのリン酸(水中85%)、32.13グラムの脱イオン水、及び61.4グラムのTEAOH溶液(水中35%)を含む溶液をガラスビーカーに調製した。この溶液に、3.32グラムのLudox AS 40(40%シリカ)を添加した。19.85グラムのアルミナ(Condea Pural SB)を添加し、モル比で以下の組成
0.15SiO2/P2O5/Al2O3/TEAOH/35H2O
を有するスラリーを得た。当該スラリーは、均一になるまで混合し、150mlのステンレス製オートクレーブに移した。このオートクレーブを、オーブンの回転軸の上に取付けた。当該軸を60rpmで回転させ、オーブンは8時間175℃まで加熱した。オートクレーブを48時間この温度に保った。室温まで冷却した後、サンプルを取り出し、洗浄後、乾燥させた。X線回折パターンを得た。DIFFaX分析により、AEI/CHA比は15/85(AEI/CHA=0.18)であった。シリカ対アルミナのモル比(SiO2/Al2O3)は、0.15であった。当該試料は、今後、試料Aと記載する。
67.51グラムのリン酸(水中85%、Aldrich社より市販)を、67.29グラムの脱イオン水で希釈した。この溶液に、123.33グラムの水酸化テトラエチルアンモニウム溶液(水中35%、Eastern社より市販)を添加した。その後、2.23グラムのLudox AS 40(40%シリカ、Dupont社)を当該溶液に添加した。最後に、39.84グラムのアルミナ(Condea Pural SB)を添加し、スラリーを得た。当該混合物の組成は、以下のモル比
0.05SiO2/P2O5/Al2O3/TEAOH/35H2O
で表わすことができる。当該スラリーは、均一になるまで混合し、150mlのステンレス製オートクレーブに移した。このオートクレーブを、オーブンの回転軸の上に取付けた。当該軸を60rpmで回転させ、オーブンは8時間175℃まで加熱した。オートクレーブを48時間この温度に保った。室温まで冷却した後、サンプルを取り出して、洗浄後、乾燥させ、X線回折パターンを得た。DIFFaX分析により、AEI/CHA比は25/75(AEI/CHA=0.33)であった。シリカ対アルミナのモル比(SiO2/Al2O3)は、0.06であった。当該試料は、今後、試料Bと記載する。
191.23グラムのリン酸溶液(水中85%、Aldrich社)と214.25グラムの脱イオン水を、ミキシングボウル中で混合した。この溶液に、348.71グラムの水酸化テトラエチルアンモニウム溶液(水中35%、Sachem社)をビュレットで添加した。混合物が均一になった後、6.04グラムのLudox AS 40(40%シリカ、Dupont社)を当該溶液に添加した。その後、122.33グラムのアルミナ(Condea Pural SB)を添加し、当該混合物を15分間攪拌した。その後、163.46グラムの水酸化テトラエチルアンモニウム溶液(水中35%)及び10.13グラムの脱イオン水を添加した。モル比で以下の組成
0.045SiO2/0.92P2O5/Al2O3/1.35TEAOH/41H2O
を有するスラリーを得た。
437.92グラムのリン酸溶液(水中85%)と350.56グラムの脱イオン水を、ミキシングボウル中で混合した。この溶液に、28.49グラムのLudox AS 40(40%シリカ)を添加し、濁った溶液を得た。その後、799.09グラムの水酸化テトラエチルアンモニウム溶液(水中35%)をビュレットで添加し、全てのTEAOHを添加したときに透明な溶液を得た。この溶液に、258.29グラムのアルミナ(Condea Pural SB)、及び42.45グラムの脱イオン水を慎重に添加した。モル比で以下の組成
0.1SiO2/P2O5/Al2O3/TEAOH/34H2O
を有するスラリーを得た。当該スラリーは、均一になるまで混合し、外壁にジャケット(jacket)が溶接された2リットルのPARRステンレス製オートクレーブ(T316SS)に移した。外部熱浴から二重壁(double wall)を経て加熱オイルを流すことにより、反応器を加熱した。ステンレス製攪拌器は、標準的なPARR馬蹄型攪拌器と標準的なタービン型羽根車の組合せからなる。結晶化の間、混合物を170rpmで攪拌した。オートクレーブは8時間175℃まで加熱した。当該オートクレーブを36時間この温度に保った。室温まで冷却した後、当該スラリーを洗浄及び乾燥し、X線回折パターンを得た。DIFFaX分析により、AEI/CHA比は30/70(AEI/CHA=0.43)であった。シリカ対アルミナのモル比(SiO2/Al2O3)は、0.14であった。当該試料は、今後、試料Dと記載する。
434.19グラムのリン酸溶液(水中85%)と347.58グラムの脱イオン水を、ミキシングボウル中で混合した。この溶液に、28.25グラムのLudox AS 40(40%シリカ)を添加し、濁った溶液を得た。その後、792.24グラムの水酸化テトラエチルアンモニウム溶液(水中35%)をビュレットで添加し、全てのTEAOHを添加したときに透明な溶液を得た。この溶液に、256.08グラムのアルミナ(Condea Pural SB)を慎重に添加した後、脱イオン水10グラム中に0.761グラムのSAPO−34粉末を有する懸濁液を添加した(シードの懸濁液は、10分間超音波バスに入れた)。また、42.07グラムの脱イオン水を混合物に添加した。モル比で以下の組成
0.1SiO2/P2O5/Al2O3/TEAOH/34H2O、及び、
0.04重量%のSAPO−34シード
を有するスラリーを得た。当該スラリーは、均一になるまで混合し、2リットルのステンレス製PARRオートクレーブに移し、結晶化の間、混合物を170rpmで攪拌した。オートクレーブは8時間175℃まで加熱した。当該オートクレーブを36時間この温度に保った。室温まで冷却した後、結晶化物質をオートクレーブから除去し、洗浄し、及び120℃で乾燥し、X線回折パターンを得た。DIFFaX分析により、AEI/CHA比は30/70(AEI/CHA=0.43)であった。シリカ対アルミナのモル比(SiO2/Al2O3)は、0.12であった。当該試料は、今後、試料Eと記載する。
184.36グラムのリン酸溶液(水中85%)と176.29グラムの脱イオン水を、ミキシングボウル中で混合した。この溶液に、13.33グラムのLudox AS 40(40%シリカ)を添加し、濁った溶液を得た。その後、373.79グラムの水酸化テトラエチルアンモニウム溶液(水中35%)をビュレットで添加し、全てのTEAOHを添加したときに透明な溶液を得た。この溶液に、120.82グラムのアルミナ(Condea Pural SB)、及び31.42グラムの脱イオン水を慎重に添加した。モル比で以下の組成
0.1SiO2/0.9P2O5/Al2O3/TEAOH/35H2O
を有するスラリーを得た。当該スラリーは、均一になるまで混合し、1リットルのステンレス製PARRオートクレーブに移し、結晶化の間、混合物を170rpmで攪拌した。オートクレーブは8時間175℃まで加熱した。当該オートクレーブを48時間この温度に保った。室温まで冷却した後、当該スラリーを洗浄及び乾燥し、X線回折パターンを得た。DIFFaX分析により、AEI/CHA比は20/80(AEI/CHA=0.25)であった。シリカ対アルミナのモル比(SiO2/Al2O3)は、0.16であった。当該試料は、今後、試料Fと記載する。
411.23グラムのリン酸溶液(水中85%)と329.18グラムの脱イオン水を、ミキシングボウル中で混合した。この溶液に、26.75グラムのLudox AS 40(40%シリカ)を添加し、濁った溶液を得た。その後、750.35グラムの水酸化テトラエチルアンモニウム溶液(水中35%)をビュレットで添加し、全てのTEAOHを添加したときに透明な溶液を得た。この溶液に、242.59グラムのアルミナ(Condea Pural SB)、及び39.86グラムの脱イオン水を慎重に添加した。モル比で以下の組成
0.1SiO2/P2O5/Al2O3/TEAOH/34H2O
を有するスラリーを得た。当該スラリーは、均一になるまで混合し、2リットルのステンレス製PARRオートクレーブに移し、結晶化の間、混合物を170rpmで攪拌した。オートクレーブは12時間170℃まで加熱した。当該オートクレーブを24時間この温度に保った。室温まで冷却した後、当該試料を取り出して、洗浄及び乾燥し、X線回折パターンを得た。DIFFaX分析により、AEI/CHA比は40/60(AEI/CHA=0.67)であった。シリカ対アルミナのモル比(SiO2/Al2O3)は、0.13であった。当該試料は、今後、試料Gと記載する。
当該実施例は、AEI/CHA比が本発明の範囲に含まれないようなAEI及びCHAモレキュラーシーブの連晶についての触媒性能を例証するための比較例として、提示するものである。
0.1SiO2/P2O5/Al2O3/TEAOH/56.9H2O
を有するスラリーを得た。当該スラリーは、均一になるまで混合し、300mlのステンレス製オートクレーブに移した。当該オートクレーブは6時間150℃まで加熱した。当該オートクレーブを133時間この温度に保った。結晶化は、静的条件下で行った。室温まで冷却した後、当該試料を取り出して、洗浄及び乾燥し、X線回折パターンを得た。DIFFaX分析により、AEI/CHA比は80/20(AEI/CHA=4.0)であった。シリカ対アルミナのモル比(SiO2/Al2O3)は、0.10であった。当該試料は、今後、比較例2と記載する。
メタノールのオレフィンへの転化は、生成物の分析のためのオンラインガスクロマトグラフを備えた、管状の固定床反応器において行った。試験試料の一部を、窒素下650℃で5時間焼成し、その後、空気中650℃で3時間加熱した。焼成したモレキュラーシーブを反応器に添加し、450℃の温度、25hr−1の重量時間空間速度(WHSV)、及び25psigの圧力において、メタノールを含有する供給原料と接触させた。エチレンとプロピレン生成物の総合的選択性、及びプロパン選択性を表3に示す。当該表において、選択性とは、供給原料中のメタノール重量に対する、所定の生成物又は生成物グループmについての重量平均生成物選択性を意味するものである。これは、以下の数式
Claims (21)
- AEI及びCHA骨格タイプを有するモレキュラーシーブの少なくとも1の連晶相を含むシリコアルミノリン酸塩モレキュラーシーブであって、
当該モレキュラーシーブが、0.01乃至0.25の範囲の、アルミナに対するシリカのモル比を有し、
当該連晶相が、当該シリコアルミノリン酸塩モレキュラーシーブの焼成試料についての粉末X線回折パターンを用いるDIFFaX分析によって測定される5/95乃至40/60のAEI/CHA比を有し、
当該X線回折パターンが、9.8乃至12.0(2θ)の範囲に反射ピークを有しない、
シリコアルミノリン酸塩モレキュラーシーブ。 - CHA骨格タイプを有するモレキュラーシーブがSAPO−34である、請求項1に記載のシリコアルミノリン酸塩モレキュラーシーブ。
- AEI骨格タイプを有するモレキュラーシーブがSAPO−18、ALPO−18、又はSAPO−18とALPO−18の混合物である、請求項1又は請求項2に記載のシリコアルミノリン酸塩モレキュラーシーブ。
- X線回折パターンが、16.9(2θ)に中心のある幅広いピークを有しない、請求項1乃至4のいずれか1に記載のシリコアルミノリン酸塩モレキュラーシーブ。
- 全ての回折パターンを20.5乃至20.7(2θ)の範囲における反射ピークの強度値に対して正規化した場合において、17.7乃至18.1(2θ)の範囲における反射ピークが、SAPO−34の回折パターンにおける17.9(2θ)の反射ピークに対して0.09乃至0.40の相対強度を有する、請求項4乃至5のいずれか1に記載のシリコアルミノリン酸塩モレキュラーシーブ。
- 前記シリコアルミノリン酸塩モレキュラーシーブ中のアルミナに対するシリカのモル比(SiO2/Al2O3)が0.01乃至0.25の範囲である、請求項5又は請求項6に記載のシリコアルミノリン酸塩モレキュラーシーブ。
- モレキュラーシーブが、結晶性のプレート、プレートレット、又は積層プレートレットから構成される、請求項1乃至7のいずれか1に記載のシリコアルミノリン酸塩モレキュラーシーブ。
- 平均最小結晶寸法が0.1ミクロン未満である、請求項1乃至8のいずれか1に記載のシリコアルミノリン酸塩モレキュラーシーブ。
- 請求項1乃至9のいずれか1に記載のシリコアルミノリン酸塩モレキュラーシーブ及び結合剤を含む、含酸素化合物供給原料からオレフィン生成物を製造するための触媒。
- 含酸素化合物供給原料を請求項10に記載の触媒と接触させる工程を含む、含酸素化合物供給原料からオレフィン生成物を製造する方法。
- 含酸素化合物が、メタノール、エタノール、n−プロパノール、イソプロパノール、C4−C20のアルコール、メチルエチルエーテル、ジメチルエーテル、ジエチルエーテル、ジイソプロピルエーテル、ホルムアルデヒド、炭酸ジメチル、ジメチルケトン、酢酸、及びそれらの混合物から選択される、請求項11に記載の方法。
- エチレン及びプロピレンに対する選択性が75.0%以上である、請求項11又は請求項12に記載の方法。
- プロピレンに対するエチレンの比が0.75以上である、請求項11乃至13のいずれか1に記載の方法。
- プロパンに対する選択性が1.0%以下である、請求項11乃至14のいずれか1に記載の方法。
- a)構造指示有機試薬(鋳型)の存在下において、ケイ素の反応源、リンの反応源、及び水和アルミニウム酸化物を混合し、混合物を形成する工程、
b)工程a)で調製した混合物を、結晶化温度まで連続的に混合及び加熱する工程、
c)少なくとも60rpmで2乃至150時間の攪拌の下で、混合物を結晶化温度に維持する工程、
d)シリコアルミノリン酸塩モレキュラーシーブの結晶を回収する工程、
を含み、工程a)において調製される混合物は、以下に示す範囲のモル組成:
P2O5 :Al2O3 0.6:1乃至1.2:1
SiO2:Al2O3 0.005:1乃至0.35:1
H2O :Al2O3 10:1乃至40:1
を有し、前記鋳型はテトラエチルアンモニウム化合物である、請求項1乃至9のいずれか1に記載のモレキュラーシーブを調製する方法。 - 結晶化温度が、120℃乃至250℃である、請求項16に記載のモレキュラーシーブ調製方法。
- 工程b)が、5乃至16時間の間実施される、請求項16又は請求項17に記載のモレキュラーシーブ調製方法。
- 鋳型が水酸化テトラエチルアンモニウムである、請求項16乃至18のいずれか1に記載のモレキュラーシーブ調製方法。
- 水和アルミニウム酸化物が擬ベーマイトである、請求項16乃至19のいずれか1に記載のモレキュラーシーブ調製方法。
- SAPO−34シードが、ケイ素の反応源、リンの反応源、水和アルミニウム酸化物、及び構造指示有機試薬(鋳型)と混合される、請求項16乃至20のいずれか1に記載のモレキュラーシーブ調製方法。
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US09/924,016 US6812372B2 (en) | 2001-03-01 | 2001-08-07 | Silicoaluminophosphate molecular sieve |
PCT/US2002/003334 WO2002070407A1 (en) | 2001-03-01 | 2002-02-04 | Silicoaluminophosphate molecular sieve |
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JP (2) | JP4299002B2 (ja) |
KR (1) | KR100868844B1 (ja) |
CN (1) | CN1227159C (ja) |
AR (1) | AR032707A1 (ja) |
AT (1) | ATE377575T1 (ja) |
AU (1) | AU2002247078B2 (ja) |
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CA (1) | CA2438146C (ja) |
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ES (1) | ES2295327T3 (ja) |
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Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2013176227A1 (ja) | 2012-05-24 | 2013-11-28 | 東ソー株式会社 | シリコアルミノリン酸塩、その製造方法及びそれを含む固体酸触媒 |
Families Citing this family (102)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US20050096214A1 (en) * | 2001-03-01 | 2005-05-05 | Janssen Marcel J. | Silicoaluminophosphate molecular sieve |
US7009086B2 (en) | 2002-10-29 | 2006-03-07 | Exxonmobil Chemical Patents Inc. | Use of molecular sieves for the conversion of oxygenates to olefins |
US6812373B2 (en) | 2002-12-12 | 2004-11-02 | Exxonmobil Chemical Patents Inc. | Modified metalloaluminophosphate molecular sieves |
US6906233B2 (en) | 2002-12-12 | 2005-06-14 | Exxon Mobil Chemical Patents Inc. | Modified metalloaluminophosphate molecular sieves |
US7071136B2 (en) | 2003-05-21 | 2006-07-04 | Exxonmobil Chemical Patents Inc | Attrition resistant molecular sieve catalysts |
WO2005063624A1 (en) * | 2003-12-23 | 2005-07-14 | Exxonmobil Chemical Patents Inc. | Aei-type zeolite, its synthesis and its use in the conversion of oxygenates to olefins |
JP4842143B2 (ja) * | 2003-12-23 | 2011-12-21 | エクソンモービル・ケミカル・パテンツ・インク | カバサイト含有モレキュラーシーブ、その合成及びオイシジェネートからオレフィンへの変換におけるその使用 |
US7033971B2 (en) * | 2004-02-09 | 2006-04-25 | Exxonmobil Chemical Patents Inc. | Method for using stabilizing catalyst activity during MTO unit operation |
EP1733004B1 (en) * | 2004-04-05 | 2012-09-12 | ExxonMobil Chemical Patents Inc. | Crystalline intergrowth material, its synthesis and its use in the conversion of oxygenates to olefins |
US7518026B2 (en) * | 2004-10-01 | 2009-04-14 | Exxonmobil Chemical Patents Inc. | Catalyst and process for the conversion of oxygenates to olefins |
US20060079397A1 (en) * | 2004-10-12 | 2006-04-13 | Mertens Machteld M | Catalyst and process for the conversion of oxygenates to olefins |
US7090814B2 (en) * | 2004-11-10 | 2006-08-15 | Exxonmobil Chemical Patents Inc. | Method of synthesizing silicoaluminophosphate molecular sieves |
US7067095B1 (en) * | 2004-12-09 | 2006-06-27 | Exxonmobil Chemical Patents Inc. | Synthesis of silicoaluminophosphate molecular sieves |
CN101084065B (zh) * | 2004-12-22 | 2011-09-14 | 埃克森美孚化学专利公司 | 硅铝磷酸盐分子筛的合成 |
US7528201B2 (en) | 2004-12-22 | 2009-05-05 | Exxonmobil Chemical Patents Inc. | Synthesis of silicoaluminophosphate molecular sieves |
US20060149109A1 (en) * | 2004-12-30 | 2006-07-06 | Ruziska Philip A | Converting methanol and ethanol to light olefins |
US7456330B2 (en) | 2005-01-31 | 2008-11-25 | Exxonmobil Chemical Patents Inc. | Molecular sieve catalyst composition, its making and use in conversion processes |
US7453020B2 (en) | 2005-01-31 | 2008-11-18 | Exxonmobil Chemical Patents Inc. | Molecular sieve catalyst composition, its making and use in conversion processes |
EP1850958B1 (en) | 2005-01-31 | 2018-07-04 | ExxonMobil Chemical Patents Inc. | Molecular sieve catalyst composition, its making and use in conversion processes |
US7498475B2 (en) * | 2005-02-25 | 2009-03-03 | Exxonmobil Chemical Patents Inc. | Molecular sieve mixtures for olefin formation |
WO2007001730A1 (en) * | 2005-06-27 | 2007-01-04 | Exxonmobil Chemical Patents Inc. | Process for manufacture of silicoaluminophosphate molecular sieves |
US8048402B2 (en) * | 2005-08-18 | 2011-11-01 | Exxonmobil Chemical Patents Inc. | Synthesis of molecular sieves having the chabazite framework type and their use in the conversion of oxygenates to olefins |
US20070059236A1 (en) * | 2005-09-09 | 2007-03-15 | Broach Robert W | Molecular sieves with high selectivity towards light olefins in methanol to olefin conversion |
US7670589B2 (en) * | 2005-10-31 | 2010-03-02 | Exxonmobil Chemical Patents Inc. | Synthesis of chabazite-containing molecular sieves and their use in the conversion of oxygenates to olefins |
US7754187B2 (en) * | 2005-10-31 | 2010-07-13 | Exxonmobil Chemical Patents Inc. | Synthesis of chabazite-containing molecular sieves and their use in the conversion of oxygenates to olefins |
US7807122B2 (en) * | 2005-11-02 | 2010-10-05 | Exxonmobil Chemical Patents Inc. | Metalloaluminophosphate molecular sieves, their synthesis and use |
WO2007100418A1 (en) * | 2006-02-27 | 2007-09-07 | Exxonmobil Chemical Patents Inc. | Method of making and process for using molecular sieve catalyst |
US7335621B2 (en) * | 2006-04-19 | 2008-02-26 | Exxonmobil Chemical Patents Inc. | Catalyst compositions and preparation thereof |
US7544851B2 (en) | 2006-04-25 | 2009-06-09 | Exxonmobil Chemical Patents Inc. | Method of synthesizing aluminophosphate and silicoaluminophosphate molecular sieves |
US7906099B2 (en) | 2006-06-09 | 2011-03-15 | Exxonmobil Chemical Patents Inc. | Intergrown molecular sieve, its synthesis and its use in the conversion of oxygenates to olefins |
US8415518B2 (en) * | 2006-08-03 | 2013-04-09 | Exxonmobil Chemical Patents Inc. | Production of light olefins |
CN101121145B (zh) * | 2006-08-08 | 2010-10-20 | 中国科学院大连化学物理研究所 | 一种含氧化合物转化制烯烃微球催化剂及其制备方法 |
EP1970350A1 (en) * | 2007-03-13 | 2008-09-17 | Total Petrochemicals Research Feluy | Metalloaluminophosphate molecular sieves with lamellar crystal morphology and their preparation |
EP1970361A1 (en) * | 2007-03-13 | 2008-09-17 | Total Petrochemicals Research Feluy | MTO process based on MeAPO molecular sieves combined with an OCP process to make olefins |
EP1970351A1 (en) * | 2007-03-13 | 2008-09-17 | Total Petrochemicals Research Feluy | Method of preparing metalloaluminophosphate (Meapo) molecular sieve |
WO2009009248A1 (en) * | 2007-07-12 | 2009-01-15 | Exxonmobil Chemical Patents Inc. | Synthesis of chabazite structure-containing molecular sieves and their use in the conversion of oxygenates to olefins |
EP2082803A1 (en) * | 2008-01-25 | 2009-07-29 | Total Petrochemicals Research Feluy | Process for obtaining catalyst composites comprising MeAPO and their use in conversion of organics to olefins |
EP2238093A1 (en) * | 2008-02-07 | 2010-10-13 | Total Petrochemicals Research Feluy | Dehydration of alcohols in the presence of an inert component |
EP2108636A1 (en) * | 2008-04-11 | 2009-10-14 | Total Petrochemicals Research Feluy | Dehydration of alcohols in the presence of an inert component. |
US7622417B2 (en) * | 2008-03-21 | 2009-11-24 | Exxonmobil Chemical Patents Inc. | Synthesis and use of AEI structure-type molecular sieves |
US7901664B2 (en) * | 2008-03-31 | 2011-03-08 | Exxonmobil Chemical Patents Inc. | Synthesis of aluminophosphate and metalloaluminophosphate molecular sieves |
US8268277B2 (en) | 2008-07-25 | 2012-09-18 | Exxonmobil Chemical Patents Inc. | Synthesis of chabazite-containing molecular sieves and their use in the conversion of oxygenates to olefins |
US8304586B2 (en) | 2010-02-02 | 2012-11-06 | Celanese International Corporation | Process for purifying ethanol |
US8471075B2 (en) | 2008-07-31 | 2013-06-25 | Celanese International Corporation | Processes for making ethanol from acetic acid |
US8637714B2 (en) | 2008-07-31 | 2014-01-28 | Celanese International Corporation | Process for producing ethanol over catalysts containing platinum and palladium |
US8680317B2 (en) | 2008-07-31 | 2014-03-25 | Celanese International Corporation | Processes for making ethyl acetate from acetic acid |
US8501652B2 (en) | 2008-07-31 | 2013-08-06 | Celanese International Corporation | Catalysts for making ethanol from acetic acid |
US8338650B2 (en) | 2008-07-31 | 2012-12-25 | Celanese International Corporation | Palladium catalysts for making ethanol from acetic acid |
US8546622B2 (en) | 2008-07-31 | 2013-10-01 | Celanese International Corporation | Process for making ethanol from acetic acid using acidic catalysts |
US8309773B2 (en) | 2010-02-02 | 2012-11-13 | Calanese International Corporation | Process for recovering ethanol |
US8309772B2 (en) | 2008-07-31 | 2012-11-13 | Celanese International Corporation | Tunable catalyst gas phase hydrogenation of carboxylic acids |
US20100030002A1 (en) * | 2008-07-31 | 2010-02-04 | Johnston Victor J | Ethylene production from acetic acid utilizing dual reaction zone process |
US20100030001A1 (en) * | 2008-07-31 | 2010-02-04 | Laiyuan Chen | Process for catalytically producing ethylene directly from acetic acid in a single reaction zone |
US7820853B2 (en) * | 2008-12-31 | 2010-10-26 | Celanese International Corporation | Integrated process for the production of vinyl acetate from acetic acid via ethyl acetate |
JP5756461B2 (ja) | 2009-06-12 | 2015-07-29 | アルベマール・ユーロプ・エスピーアールエル | Sapo分子篩触媒と、その調製および使用 |
US8450535B2 (en) | 2009-07-20 | 2013-05-28 | Celanese International Corporation | Ethanol production from acetic acid utilizing a cobalt catalyst |
US8710277B2 (en) | 2009-10-26 | 2014-04-29 | Celanese International Corporation | Process for making diethyl ether from acetic acid |
US8680321B2 (en) | 2009-10-26 | 2014-03-25 | Celanese International Corporation | Processes for making ethanol from acetic acid using bimetallic catalysts |
US8211821B2 (en) | 2010-02-01 | 2012-07-03 | Celanese International Corporation | Processes for making tin-containing catalysts |
US8680343B2 (en) | 2010-02-02 | 2014-03-25 | Celanese International Corporation | Process for purifying ethanol |
US8222466B2 (en) | 2010-02-02 | 2012-07-17 | Celanese International Corporation | Process for producing a water stream from ethanol production |
US8747492B2 (en) | 2010-02-02 | 2014-06-10 | Celanese International Corporation | Ethanol/fuel blends for use as motor fuels |
US8728179B2 (en) | 2010-02-02 | 2014-05-20 | Celanese International Corporation | Ethanol compositions |
BR112012019418A2 (pt) | 2010-02-02 | 2018-03-20 | Celanese Int Corp | preparação e uso em um catalsiador para produção de etanol compreendendo um modificador de suporte cristalino |
US8932372B2 (en) | 2010-02-02 | 2015-01-13 | Celanese International Corporation | Integrated process for producing alcohols from a mixed acid feed |
US8668750B2 (en) | 2010-02-02 | 2014-03-11 | Celanese International Corporation | Denatured fuel ethanol compositions for blending with gasoline or diesel fuel for use as motor fuels |
US8344186B2 (en) | 2010-02-02 | 2013-01-01 | Celanese International Corporation | Processes for producing ethanol from acetaldehyde |
US8541633B2 (en) | 2010-02-02 | 2013-09-24 | Celanese International Corporation | Processes for producing anhydrous ethanol compositions |
US8314272B2 (en) | 2010-02-02 | 2012-11-20 | Celanese International Corporation | Process for recovering ethanol with vapor separation |
US8460405B2 (en) | 2010-02-02 | 2013-06-11 | Celanese International Corporation | Ethanol compositions |
US8858659B2 (en) | 2010-02-02 | 2014-10-14 | Celanese International Corporation | Processes for producing denatured ethanol |
BR112012021655A2 (pt) | 2010-03-11 | 2016-09-20 | Johnson Matthey Plc | catalisador, método para reduzir nox, e, dispositivo para reduzir nox |
US8680342B2 (en) | 2010-05-07 | 2014-03-25 | Celanese International Corporation | Process for recovering alcohol produced by hydrogenating an acetic acid feed stream comprising water |
US8754267B2 (en) | 2010-05-07 | 2014-06-17 | Celanese International Corporation | Process for separating acetaldehyde from ethanol-containing mixtures |
US8569551B2 (en) | 2010-05-07 | 2013-10-29 | Celanese International Corporation | Alcohol production process integrating acetic acid feed stream comprising water from carbonylation process |
CN102372291A (zh) * | 2010-08-23 | 2012-03-14 | 中国石油化工股份有限公司 | Sapo-18/sapo-34共生分子筛的制备方法 |
US8350098B2 (en) | 2011-04-04 | 2013-01-08 | Celanese International Corporation | Ethanol production from acetic acid utilizing a molybdenum carbide catalyst |
US8536382B2 (en) | 2011-10-06 | 2013-09-17 | Celanese International Corporation | Processes for hydrogenating alkanoic acids using catalyst comprising tungsten |
US8658843B2 (en) | 2011-10-06 | 2014-02-25 | Celanese International Corporation | Hydrogenation catalysts prepared from polyoxometalate precursors and process for using same to produce ethanol while minimizing diethyl ether formation |
US8703868B2 (en) | 2011-11-28 | 2014-04-22 | Celanese International Corporation | Integrated process for producing polyvinyl alcohol or a copolymer thereof and ethanol |
US9233899B2 (en) | 2011-12-22 | 2016-01-12 | Celanese International Corporation | Hydrogenation catalysts having an amorphous support |
US9000234B2 (en) | 2011-12-22 | 2015-04-07 | Celanese International Corporation | Calcination of modified support to prepare hydrogenation catalysts |
US8907142B2 (en) | 2011-12-29 | 2014-12-09 | Celanese International Corporation | Process for promoting catalyst activity for ethyl acetate conversion |
JP5983290B2 (ja) * | 2012-10-18 | 2016-08-31 | 東ソー株式会社 | シリコアルミノリン酸塩及びこれを用いた窒素酸化物還元触媒 |
US8772553B2 (en) | 2012-10-26 | 2014-07-08 | Celanese International Corporation | Hydrogenation reaction conditions for producing ethanol |
US8853469B2 (en) | 2012-11-20 | 2014-10-07 | Celanese International Corporation | Combined column for separating products of different hydrogenation reactors |
US8957262B2 (en) | 2012-11-20 | 2015-02-17 | Celanese International Corporation | Olefin hydration for hydrogenation processes |
CN103196931B (zh) * | 2013-04-27 | 2015-06-03 | 神华集团有限责任公司 | 一种催化剂催化活性的检测方法 |
JP6278561B2 (ja) * | 2013-07-10 | 2018-02-14 | 国立大学法人広島大学 | 結晶性アルミノシリケート及びその製造方法 |
CN108439426A (zh) | 2013-10-31 | 2018-08-24 | 庄信万丰股份有限公司 | Aei沸石合成 |
WO2015094696A1 (en) | 2013-12-20 | 2015-06-25 | Exxonmobil Chemical Patents Inc. | Process for converting oxygenates to aromatic hydrocarbons |
CN107428628B (zh) | 2015-03-31 | 2021-03-02 | 埃克森美孚化学专利公司 | 氧化烃转化的分区方法 |
CN106365992B (zh) * | 2015-07-20 | 2019-01-01 | 中国科学院大连化学物理研究所 | 一种制备缩醛羰化物的方法 |
MY186254A (en) * | 2015-09-01 | 2021-06-30 | Tosoh Corp | Method for producing aei zeolite |
JP6965163B2 (ja) | 2015-11-25 | 2021-11-10 | 三菱ケミカル株式会社 | ゼオライト触媒及び低級オレフィンの製造方法 |
CN108349742A (zh) * | 2015-11-27 | 2018-07-31 | 三菱化学株式会社 | 八元氧环沸石和aei型沸石的制造方法 |
EP3323785A1 (en) | 2016-11-18 | 2018-05-23 | Umicore AG & Co. KG | Crystalline zeolites with eri/cha intergrowth framework type |
JP7244502B2 (ja) * | 2018-01-24 | 2023-03-22 | シェブロン ユー.エス.エー. インコーポレイテッド | モレキュラーシーブssz-110、その合成および使用 |
CN111099637B (zh) * | 2018-10-25 | 2023-03-03 | 中国石油化工股份有限公司 | 硅磷铝分子筛及其制备方法 |
CN113474290B (zh) | 2019-03-28 | 2023-12-29 | 庄信万丰股份有限公司 | 具有“sfw-GME尾部”的cha和aft的分子筛共生物、制备和使用方法 |
KR20220008872A (ko) | 2019-05-15 | 2022-01-21 | 바스프 에스이 | Cha-aft 제올라이트 연정 coe-10의 제조 방법 및 비균질 촉매작용에서의 이의 용도 |
US11851339B2 (en) | 2021-03-04 | 2023-12-26 | Johnson Matthey Public Limited Company | JMZ-12, a disordered AEI/CHA family of zeolites, its synthesis and use |
Family Cites Families (23)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4076698A (en) | 1956-03-01 | 1978-02-28 | E. I. Du Pont De Nemours And Company | Hydrocarbon interpolymer compositions |
NZ126521A (ja) | 1959-06-06 | |||
US3305538A (en) | 1961-11-22 | 1967-02-21 | Montedison Spa | Polymerization process |
US3364190A (en) | 1964-04-27 | 1968-01-16 | Standard Oil Co | Process for polymerizing propylene to syndiotactic polypropylene |
CA849081A (en) | 1967-03-02 | 1970-08-11 | Du Pont Of Canada Limited | PRODUCTION OF ETHYLENE/.alpha.-OLEFIN COPOLYMERS OF IMPROVED PHYSICAL PROPERTIES |
US3635803A (en) | 1970-09-30 | 1972-01-18 | Interoxo Ag | Preparation of olefin oxide from an olefin |
CA1086426A (en) | 1975-10-13 | 1980-09-23 | Shunji Minami | Analog voltage memory device |
US4302565A (en) | 1978-03-31 | 1981-11-24 | Union Carbide Corporation | Impregnated polymerization catalyst, process for preparing, and use for ethylene copolymerization |
US4243691A (en) | 1979-05-18 | 1981-01-06 | The Procter & Gamble Company | Sodium-free salt substitute |
US4440871A (en) | 1982-07-26 | 1984-04-03 | Union Carbide Corporation | Crystalline silicoaluminophosphates |
US4499327A (en) | 1982-10-04 | 1985-02-12 | Union Carbide Corporation | Production of light olefins |
US5324800A (en) | 1983-06-06 | 1994-06-28 | Exxon Chemical Patents Inc. | Process and catalyst for polyolefin density and molecular weight control |
US4659685A (en) | 1986-03-17 | 1987-04-21 | The Dow Chemical Company | Heterogeneous organometallic catalysts containing a supported titanium compound and at least one other supported organometallic compound |
US5279810A (en) | 1990-12-20 | 1994-01-18 | Mobil Oil Corporation | Method of preparing silicoaluminophosphate compositions using a reagent containing both phosphorus and silicon reactive sites in the same molecule |
DE4131268A1 (de) * | 1991-09-20 | 1993-03-25 | Basf Ag | Verfahren zur herstellung von alumo- und silicoalumophosphaten mit ael-struktur unter verwendung von 1,2-bis(4-pyridyl)ethan |
NO300012B1 (no) | 1993-08-17 | 1997-03-17 | Polymers Holding As | Mikroporost krystallinsk silikoaluminofosfat, fremgangsmate for fremstilling av dette, samt anvendelse derav |
DE4402558A1 (de) | 1994-01-28 | 1995-08-03 | Gerd Elger | Wasserstrahlantrieb für Wasserfahrzeuge mit Steuerelementen zur Richtungsänderung des Vortrieb liefernden Wasserstrahles |
JPH0812320A (ja) * | 1994-07-05 | 1996-01-16 | Nippon Kayaku Co Ltd | 結晶質シリコアルミノリン酸塩の製造方法 |
NO304108B1 (no) | 1996-10-09 | 1998-10-26 | Polymers Holding As | En mikroporos silikoaluminofosfat-sammensetning, katalytisk materiale som omfatter denne sammensetningen og fremgangsmate for fremstilling derav, og bruken av disse for a fremstille olefiner fra metanol |
RO114524B1 (ro) * | 1997-10-02 | 1999-05-28 | Sc Zecasin Sa | Procedeu de fabricare a oleofinelor cu greutate moleculara mica prin conversia catalitica in strat fluidizat a metanolului |
US5892079A (en) | 1997-10-17 | 1999-04-06 | Sri International | Metallocene catalysts and associated methods of preparation and use |
US6238550B1 (en) * | 1998-05-26 | 2001-05-29 | Exxon Research And Engineering Company | Silicoaluminophosphates having AEL structure, a method for their preparation and their use as catalysts for the hydroprocessing of hydrocarbon feedstocks |
WO2001025150A1 (en) * | 1999-10-01 | 2001-04-12 | Pop, Grigore | Process for the synthesis of silicoaluminophosphate molecular sieves |
-
2001
- 2001-08-07 US US09/924,016 patent/US6812372B2/en not_active Expired - Lifetime
-
2002
- 2002-02-04 WO PCT/US2002/003334 patent/WO2002070407A1/en active IP Right Grant
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- 2002-02-04 MX MXPA03007807A patent/MXPA03007807A/es active IP Right Grant
- 2002-02-04 CN CNB028057724A patent/CN1227159C/zh not_active Expired - Lifetime
- 2002-02-04 CA CA2438146A patent/CA2438146C/en not_active Expired - Fee Related
- 2002-02-04 AU AU2002247078A patent/AU2002247078B2/en not_active Ceased
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Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2013176227A1 (ja) | 2012-05-24 | 2013-11-28 | 東ソー株式会社 | シリコアルミノリン酸塩、その製造方法及びそれを含む固体酸触媒 |
KR20150024818A (ko) | 2012-05-24 | 2015-03-09 | 도소 가부시키가이샤 | 실리코알루미노인산염, 그 제조 방법 및 그것을 함유하는 고체산 촉매 |
US9637392B2 (en) | 2012-05-24 | 2017-05-02 | Tosoh Corporation | Silicoaluminophosphate, method for producing the same, and solid acid catalyst comprising the same |
Also Published As
Publication number | Publication date |
---|---|
AR032707A1 (es) | 2003-11-19 |
CA2438146A1 (en) | 2002-09-12 |
EA006851B1 (ru) | 2006-04-28 |
WO2002070407A1 (en) | 2002-09-12 |
US6812372B2 (en) | 2004-11-02 |
DE60223344D1 (de) | 2007-12-20 |
NO20033845L (no) | 2003-10-17 |
EP1886973A3 (en) | 2008-06-11 |
EA200300870A1 (ru) | 2004-12-30 |
US20020165089A1 (en) | 2002-11-07 |
CN1525940A (zh) | 2004-09-01 |
ES2295327T3 (es) | 2008-04-16 |
ZA200306195B (en) | 2005-02-23 |
MY138795A (en) | 2009-07-31 |
NO20033845D0 (no) | 2003-08-29 |
EP1886973A2 (en) | 2008-02-13 |
ATE377575T1 (de) | 2007-11-15 |
CN1227159C (zh) | 2005-11-16 |
DE60223344T2 (de) | 2008-08-28 |
EP1365992A1 (en) | 2003-12-03 |
MXPA03007807A (es) | 2004-03-16 |
JP2008230966A (ja) | 2008-10-02 |
EP1886973B1 (en) | 2018-11-21 |
JP5162342B2 (ja) | 2013-03-13 |
JP2004524252A (ja) | 2004-08-12 |
BR0207788A (pt) | 2004-03-23 |
TW583140B (en) | 2004-04-11 |
KR20040012726A (ko) | 2004-02-11 |
CA2438146C (en) | 2010-03-23 |
KR100868844B1 (ko) | 2008-11-14 |
EP1365992B1 (en) | 2007-11-07 |
AU2002247078B2 (en) | 2006-11-16 |
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