JP4141298B2 - ペロブスカイト構造を有する誘電体セラミック粉末の製造方法と、セラミック電子部品の製造方法と、積層セラミックコンデンサの製造方法 - Google Patents
ペロブスカイト構造を有する誘電体セラミック粉末の製造方法と、セラミック電子部品の製造方法と、積層セラミックコンデンサの製造方法 Download PDFInfo
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- JP4141298B2 JP4141298B2 JP2003080407A JP2003080407A JP4141298B2 JP 4141298 B2 JP4141298 B2 JP 4141298B2 JP 2003080407 A JP2003080407 A JP 2003080407A JP 2003080407 A JP2003080407 A JP 2003080407A JP 4141298 B2 JP4141298 B2 JP 4141298B2
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- 239000000843 powder Substances 0.000 title claims description 130
- 239000000919 ceramic Substances 0.000 title claims description 76
- 238000004519 manufacturing process Methods 0.000 title claims description 31
- 239000003985 ceramic capacitor Substances 0.000 title claims description 17
- 238000000034 method Methods 0.000 claims description 51
- 239000007788 liquid Substances 0.000 claims description 29
- 238000010438 heat treatment Methods 0.000 claims description 20
- MUBZPKHOEPUJKR-UHFFFAOYSA-N Oxalic acid Chemical compound OC(=O)C(O)=O MUBZPKHOEPUJKR-UHFFFAOYSA-N 0.000 claims description 13
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 claims description 12
- 238000010532 solid phase synthesis reaction Methods 0.000 claims description 8
- 239000002994 raw material Substances 0.000 claims description 7
- 239000002002 slurry Substances 0.000 claims description 5
- 238000001308 synthesis method Methods 0.000 claims description 5
- 238000010304 firing Methods 0.000 claims description 3
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- 239000002245 particle Substances 0.000 description 55
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- 229910002113 barium titanate Inorganic materials 0.000 description 30
- JRPBQTZRNDNNOP-UHFFFAOYSA-N barium titanate Chemical compound [Ba+2].[Ba+2].[O-][Ti]([O-])([O-])[O-] JRPBQTZRNDNNOP-UHFFFAOYSA-N 0.000 description 29
- VEALVRVVWBQVSL-UHFFFAOYSA-N strontium titanate Chemical compound [Sr+2].[O-][Ti]([O-])=O VEALVRVVWBQVSL-UHFFFAOYSA-N 0.000 description 17
- 229910052788 barium Inorganic materials 0.000 description 13
- 238000003786 synthesis reaction Methods 0.000 description 13
- 239000010936 titanium Substances 0.000 description 13
- DSAJWYNOEDNPEQ-UHFFFAOYSA-N barium atom Chemical compound [Ba] DSAJWYNOEDNPEQ-UHFFFAOYSA-N 0.000 description 12
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- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 6
- RKTYLMNFRDHKIL-UHFFFAOYSA-N copper;5,10,15,20-tetraphenylporphyrin-22,24-diide Chemical compound [Cu+2].C1=CC(C(=C2C=CC([N-]2)=C(C=2C=CC=CC=2)C=2C=CC(N=2)=C(C=2C=CC=CC=2)C2=CC=C3[N-]2)C=2C=CC=CC=2)=NC1=C3C1=CC=CC=C1 RKTYLMNFRDHKIL-UHFFFAOYSA-N 0.000 description 6
- 230000007423 decrease Effects 0.000 description 6
- 238000005259 measurement Methods 0.000 description 6
- 229910052719 titanium Inorganic materials 0.000 description 6
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 5
- 238000006243 chemical reaction Methods 0.000 description 5
- 238000011049 filling Methods 0.000 description 5
- 150000003839 salts Chemical class 0.000 description 5
- AYJRCSIUFZENHW-UHFFFAOYSA-L barium carbonate Chemical compound [Ba+2].[O-]C([O-])=O AYJRCSIUFZENHW-UHFFFAOYSA-L 0.000 description 4
- 239000002003 electrode paste Substances 0.000 description 4
- 239000000463 material Substances 0.000 description 4
- 229910001631 strontium chloride Inorganic materials 0.000 description 4
- AHBGXTDRMVNFER-UHFFFAOYSA-L strontium dichloride Chemical compound [Cl-].[Cl-].[Sr+2] AHBGXTDRMVNFER-UHFFFAOYSA-L 0.000 description 4
- UUCCCPNEFXQJEL-UHFFFAOYSA-L strontium dihydroxide Chemical compound [OH-].[OH-].[Sr+2] UUCCCPNEFXQJEL-UHFFFAOYSA-L 0.000 description 4
- 229910001866 strontium hydroxide Inorganic materials 0.000 description 4
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 3
- RQPZNWPYLFFXCP-UHFFFAOYSA-L barium dihydroxide Chemical compound [OH-].[OH-].[Ba+2] RQPZNWPYLFFXCP-UHFFFAOYSA-L 0.000 description 3
- 229910001863 barium hydroxide Inorganic materials 0.000 description 3
- 238000002474 experimental method Methods 0.000 description 3
- XLYOFNOQVPJJNP-ZSJDYOACSA-N heavy water Substances [2H]O[2H] XLYOFNOQVPJJNP-ZSJDYOACSA-N 0.000 description 3
- 230000007062 hydrolysis Effects 0.000 description 3
- 238000006460 hydrolysis reaction Methods 0.000 description 3
- 238000001027 hydrothermal synthesis Methods 0.000 description 3
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 3
- 229910052751 metal Inorganic materials 0.000 description 3
- 239000002184 metal Substances 0.000 description 3
- 125000000896 monocarboxylic acid group Chemical group 0.000 description 3
- 239000011148 porous material Substances 0.000 description 3
- 239000000243 solution Substances 0.000 description 3
- 230000002194 synthesizing effect Effects 0.000 description 3
- 238000012795 verification Methods 0.000 description 3
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
- 238000003991 Rietveld refinement Methods 0.000 description 2
- 230000002378 acidificating effect Effects 0.000 description 2
- 229910052787 antimony Inorganic materials 0.000 description 2
- WDIHJSXYQDMJHN-UHFFFAOYSA-L barium chloride Chemical compound [Cl-].[Cl-].[Ba+2] WDIHJSXYQDMJHN-UHFFFAOYSA-L 0.000 description 2
- 229910001626 barium chloride Inorganic materials 0.000 description 2
- 229910052791 calcium Inorganic materials 0.000 description 2
- 239000000470 constituent Substances 0.000 description 2
- 239000003989 dielectric material Substances 0.000 description 2
- 238000010828 elution Methods 0.000 description 2
- 230000005621 ferroelectricity Effects 0.000 description 2
- 239000007789 gas Substances 0.000 description 2
- 229910052745 lead Inorganic materials 0.000 description 2
- 229910052758 niobium Inorganic materials 0.000 description 2
- 235000006408 oxalic acid Nutrition 0.000 description 2
- 230000000704 physical effect Effects 0.000 description 2
- 238000000634 powder X-ray diffraction Methods 0.000 description 2
- 229910052761 rare earth metal Inorganic materials 0.000 description 2
- 229920005989 resin Polymers 0.000 description 2
- 239000011347 resin Substances 0.000 description 2
- 229910052718 tin Inorganic materials 0.000 description 2
- 229910052721 tungsten Inorganic materials 0.000 description 2
- 229910052727 yttrium Inorganic materials 0.000 description 2
- 229910052726 zirconium Inorganic materials 0.000 description 2
- MSYNCHLYGJCFFY-UHFFFAOYSA-B 2-hydroxypropane-1,2,3-tricarboxylate;titanium(4+) Chemical compound [Ti+4].[Ti+4].[Ti+4].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O.[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O.[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O.[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O MSYNCHLYGJCFFY-UHFFFAOYSA-B 0.000 description 1
- VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 description 1
- 229910002367 SrTiO Inorganic materials 0.000 description 1
- 235000011114 ammonium hydroxide Nutrition 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 229940006612 barium citrate Drugs 0.000 description 1
- PAVWOHWZXOQYDB-UHFFFAOYSA-H barium(2+);2-hydroxypropane-1,2,3-tricarboxylate Chemical compound [Ba+2].[Ba+2].[Ba+2].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O.[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O PAVWOHWZXOQYDB-UHFFFAOYSA-H 0.000 description 1
- 239000010953 base metal Substances 0.000 description 1
- 239000011230 binding agent Substances 0.000 description 1
- 230000005540 biological transmission Effects 0.000 description 1
- 238000004364 calculation method Methods 0.000 description 1
- 238000002485 combustion reaction Methods 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 239000002270 dispersing agent Substances 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 238000007646 gravure printing Methods 0.000 description 1
- 150000004679 hydroxides Chemical class 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000004014 plasticizer Substances 0.000 description 1
- 229920002037 poly(vinyl butyral) polymer Polymers 0.000 description 1
- -1 polyethylene terephthalate Polymers 0.000 description 1
- 229920000139 polyethylene terephthalate Polymers 0.000 description 1
- 239000005020 polyethylene terephthalate Substances 0.000 description 1
- 238000007639 printing Methods 0.000 description 1
- 238000010298 pulverizing process Methods 0.000 description 1
- 238000007650 screen-printing Methods 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- RXSHXLOMRZJCLB-UHFFFAOYSA-L strontium;diacetate Chemical compound [Sr+2].CC([O-])=O.CC([O-])=O RXSHXLOMRZJCLB-UHFFFAOYSA-L 0.000 description 1
- 238000005979 thermal decomposition reaction Methods 0.000 description 1
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 1
- XJDNKRIXUMDJCW-UHFFFAOYSA-J titanium tetrachloride Chemical compound Cl[Ti](Cl)(Cl)Cl XJDNKRIXUMDJCW-UHFFFAOYSA-J 0.000 description 1
- 239000012808 vapor phase Substances 0.000 description 1
- 239000011800 void material Substances 0.000 description 1
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- C04B2235/50—Constituents or additives of the starting mixture chosen for their shape or used because of their shape or their physical appearance
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- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
- C04B2235/50—Constituents or additives of the starting mixture chosen for their shape or used because of their shape or their physical appearance
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- C04B2235/60—Aspects relating to the preparation, properties or mechanical treatment of green bodies or pre-forms
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Priority Applications (9)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2003080407A JP4141298B2 (ja) | 2003-03-24 | 2003-03-24 | ペロブスカイト構造を有する誘電体セラミック粉末の製造方法と、セラミック電子部品の製造方法と、積層セラミックコンデンサの製造方法 |
| CNB2004100086418A CN100344579C (zh) | 2003-03-24 | 2004-03-12 | 具有钙钛矿结构的陶瓷粉末及其制法、电子部件及电容器 |
| CNA2006101538962A CN1951867A (zh) | 2003-03-24 | 2004-03-12 | 具有钙钛矿结构的陶瓷粉末 |
| TW093106841A TW200420524A (en) | 2003-03-24 | 2004-03-15 | Perovskite ceramic powder and electronic component using same and manufacturing methods thereof, laminated ceramic capacitor and method for producing same |
| KR1020040019675A KR100707646B1 (ko) | 2003-03-24 | 2004-03-23 | 퍼로브스카이트 구조를 갖는 세라믹 분말의 제조 방법과,퍼로브스카이트 구조를 갖는 세라믹 분말과 세라믹 전자부품 및 그 제조 방법과 적층 세라믹 콘덴서 및 그 제조방법 |
| US10/807,157 US7271114B2 (en) | 2003-03-24 | 2004-03-24 | Perovskite ceramic powder and electronic component using same and manufacturing methods thereof |
| HK04110374.1A HK1066975B (en) | 2003-03-24 | 2004-12-31 | Ceramic powder with perovskite structure, manufacturing methods thereof and electronic component and capacitor |
| US11/606,102 US7566439B2 (en) | 2003-03-24 | 2006-11-30 | Perovskite ceramic powder and electronic component using same and manufacturing methods thereof |
| US11/606,108 US7572406B2 (en) | 2003-03-24 | 2006-11-30 | Perovskite ceramic powder and electronic component using same and manufacturing methods thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2003080407A JP4141298B2 (ja) | 2003-03-24 | 2003-03-24 | ペロブスカイト構造を有する誘電体セラミック粉末の製造方法と、セラミック電子部品の製造方法と、積層セラミックコンデンサの製造方法 |
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| KR (1) | KR100707646B1 (enExample) |
| CN (2) | CN100344579C (enExample) |
| TW (1) | TW200420524A (enExample) |
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| JP2005272295A (ja) * | 2004-02-26 | 2005-10-06 | Dowa Mining Co Ltd | 正方晶チタン酸バリウム粒子およびその製造方法並びにセラミックコンデンサ |
| CN101014538B (zh) * | 2004-08-13 | 2012-07-04 | 堺化学工业株式会社 | 钙钛矿化合物粉末的制备方法 |
| JP4766910B2 (ja) * | 2005-04-26 | 2011-09-07 | 京セラ株式会社 | チタン酸バリウム粉末の製法、チタン酸バリウム粉末、およびチタン酸バリウム焼結体 |
| JP4827011B2 (ja) * | 2006-03-10 | 2011-11-30 | Tdk株式会社 | セラミック粉末及びこれを用いた誘電体ペースト、積層セラミック電子部品、その製造方法 |
| US8184426B2 (en) * | 2006-12-25 | 2012-05-22 | National Institute For Materials Science | Dielectric element and method for producing the dielectric element |
| JP5184333B2 (ja) * | 2008-12-25 | 2013-04-17 | サムソン エレクトロ−メカニックス カンパニーリミテッド. | 誘電体セラミックス材料の製造方法 |
| JP5233763B2 (ja) * | 2009-03-13 | 2013-07-10 | 株式会社村田製作所 | チタン酸バリウム系誘電体原料粉末、その製造方法、セラミックグリーンシートの製造方法、および積層セラミックコンデンサの製造方法 |
| JP5820373B2 (ja) * | 2009-06-25 | 2015-11-24 | イーストー,インコーポレイティド | 石英ガラス横型炉および組立体 |
| JP5445412B2 (ja) * | 2010-09-17 | 2014-03-19 | 株式会社村田製作所 | 複合酸化物粉末の製造方法 |
| JP2012072037A (ja) * | 2010-09-29 | 2012-04-12 | Tdk Corp | 誘電体磁器組成物およびその製造方法ならびにセラミック電子部品 |
| CN102074351A (zh) * | 2010-11-12 | 2011-05-25 | 无锡索垠飞科技有限公司 | 电容式储能电池及其制造方法 |
| CN102035265B (zh) * | 2010-12-06 | 2013-11-20 | 南京科孚纳米技术有限公司 | 电容器储能电池无线充电系统 |
| KR101218979B1 (ko) | 2010-12-10 | 2013-01-04 | 삼성전기주식회사 | 페롭스카이트 분말의 제조방법, 그 방법으로 제조한 페롭스카이트 분말 및 적층 세라믹 전자부품 |
| KR20130038695A (ko) * | 2011-10-10 | 2013-04-18 | 삼성전기주식회사 | 페롭스카이트 분말, 이의 제조방법 및 이를 이용한 적층 세라믹 전자부품 |
| JP5484506B2 (ja) | 2012-03-30 | 2014-05-07 | 太陽誘電株式会社 | セラミック粉末及び積層セラミックコンデンサ |
| JP5629719B2 (ja) * | 2012-03-30 | 2014-11-26 | 太陽誘電株式会社 | セラミック粉末及び積層セラミックコンデンサ |
| JP5566434B2 (ja) * | 2012-09-25 | 2014-08-06 | 太陽誘電株式会社 | 積層セラミックコンデンサ |
| CN102886934A (zh) * | 2012-10-29 | 2013-01-23 | 哈尔滨工业大学 | 一种结晶完全且无杂相产生的多铁性薄膜及其制备方法 |
| JP2015109410A (ja) * | 2013-10-25 | 2015-06-11 | 株式会社村田製作所 | セラミック電子部品及びセラミック電子部品の製造方法 |
| JP5975370B2 (ja) * | 2013-11-18 | 2016-08-23 | 株式会社村田製作所 | バリスタ機能付き積層型半導体セラミックコンデンサとその製造方法 |
| CN104045341A (zh) * | 2014-06-24 | 2014-09-17 | 天津大学 | 无铅高介电常数多层陶瓷电容器介质材料及其制备方法 |
| JP5874798B2 (ja) * | 2014-09-30 | 2016-03-02 | 株式会社村田製作所 | チタン酸バリウム系セラミック粉末 |
| CN104387088A (zh) * | 2014-10-29 | 2015-03-04 | 安徽省皖捷液压科技有限公司 | 一种废橡胶轮胎颗粒/氮化硅复合的陶瓷喷嘴及其制作方法 |
| JP7523922B2 (ja) * | 2020-03-03 | 2024-07-29 | 太陽誘電株式会社 | セラミック電子部品の製造方法、および金属導電ペースト |
| CN112919529A (zh) * | 2021-03-31 | 2021-06-08 | 成渝钒钛科技有限公司 | 一种利用含钛高炉渣制备钛酸钡的方法 |
| CN118164751B (zh) * | 2022-12-08 | 2025-10-21 | 福建贝思科电子材料股份有限公司 | 一种钛酸钡钙粉体、其制备方法及应用 |
Family Cites Families (11)
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|---|---|---|---|---|
| US2166221A (en) * | 1937-06-29 | 1939-07-18 | Du Pont | Process for producing pigment titanates |
| BE478147A (enExample) * | 1944-04-04 | |||
| US2976116A (en) * | 1958-03-03 | 1961-03-21 | Walter W Malinofsky | Method of preparation of barium titanate powder |
| US4874598A (en) * | 1987-01-20 | 1989-10-17 | Mitsubishi Petrochemical Co., Ltd. | Process for producing perovskite-type oxides of the ABO3 type |
| JP3302627B2 (ja) * | 1997-07-31 | 2002-07-15 | 太陽誘電株式会社 | セラミック粉末の製造方法 |
| EP1017625B1 (en) * | 1998-07-01 | 2002-09-11 | Cabot Corporation | Hydrothermal process for making barium titanate powders |
| JP3780851B2 (ja) * | 2000-03-02 | 2006-05-31 | 株式会社村田製作所 | チタン酸バリウムおよびその製造方法ならびに誘電体セラミックおよびセラミック電子部品 |
| CN1219725C (zh) * | 2000-05-12 | 2005-09-21 | 中国科学院大连化学物理研究所 | 一种制备高性能复合氧化物粉体的方法 |
| US6409983B1 (en) * | 2000-07-11 | 2002-06-25 | Korea Institute Of Science And Technology | Process for preparing crystalline barium titanate powder |
| JP4660935B2 (ja) | 2001-02-05 | 2011-03-30 | 株式会社村田製作所 | 正方晶ペロブスカイト構造を有するチタン酸バリウム系セラミック粉末の製造方法 |
| CN1172874C (zh) * | 2002-07-10 | 2004-10-27 | 清华大学 | 制备四方相钛酸钡纳米粉体的方法 |
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- 2004-03-12 CN CNB2004100086418A patent/CN100344579C/zh not_active Expired - Lifetime
- 2004-03-12 CN CNA2006101538962A patent/CN1951867A/zh active Pending
- 2004-03-15 TW TW093106841A patent/TW200420524A/zh not_active IP Right Cessation
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Also Published As
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|---|---|
| US7572406B2 (en) | 2009-08-11 |
| US7566439B2 (en) | 2009-07-28 |
| CN1951867A (zh) | 2007-04-25 |
| US20070104640A1 (en) | 2007-05-10 |
| TWI304056B (enExample) | 2008-12-11 |
| JP2004284897A (ja) | 2004-10-14 |
| CN100344579C (zh) | 2007-10-24 |
| TW200420524A (en) | 2004-10-16 |
| KR100707646B1 (ko) | 2007-04-13 |
| US7271114B2 (en) | 2007-09-18 |
| HK1066975A1 (zh) | 2005-03-18 |
| US20070104970A1 (en) | 2007-05-10 |
| KR20040084725A (ko) | 2004-10-06 |
| CN1532167A (zh) | 2004-09-29 |
| US20040188002A1 (en) | 2004-09-30 |
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