JP4106305B2

JP4106305B2 - 有機凝結剤及び高分子凝集剤

有機凝結剤及び高分子凝集剤 Download PDF

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Publication number: JP4106305B2
Authority: JP; Japan
Prior art keywords: acid; less; ammonium; polymer flocculant; group
Prior art date: 2003-05-26
Legal status : Expired - Fee Related

Application number

JP2003147127A

Other languages

English (en)

Japanese (ja)

Other versions

JP2004344829A (ja

JP2004344829A5 (enExample

Inventor

一充鈴木

Current Assignee

Sanyo Chemical Industries Ltd

Original Assignee

Sanyo Chemical Industries Ltd

Priority date

2003-05-26

Filing date

2003-05-26

Publication date

2008-06-25

2003-05-26 Application filed by Sanyo Chemical Industries Ltd filed Critical Sanyo Chemical Industries Ltd

2003-05-26 Priority to JP2003147127A priority Critical patent/JP4106305B2/ja

2004-12-09 Publication of JP2004344829A publication Critical patent/JP2004344829A/ja

2006-04-27 Publication of JP2004344829A5 publication Critical patent/JP2004344829A5/ja

2008-06-25 Application granted granted Critical

2008-06-25 Publication of JP4106305B2 publication Critical patent/JP4106305B2/ja

2023-05-26 Anticipated expiration legal-status Critical

Status Expired - Fee Related legal-status Critical Current

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229920000642 polymer Polymers 0.000 title claims description 100
239000000701 coagulant Substances 0.000 title claims description 62
239000008394 flocculating agent Substances 0.000 title description 4
239000002351 wastewater Substances 0.000 claims description 51
238000000034 method Methods 0.000 claims description 50
125000004432 carbon atom Chemical group C* 0.000 claims description 47
239000010802 sludge Substances 0.000 claims description 24
125000001931 aliphatic group Chemical group 0.000 claims description 20
239000010801 sewage sludge Substances 0.000 claims description 17
235000014113 dietary fatty acids Nutrition 0.000 claims description 15
239000000194 fatty acid Substances 0.000 claims description 15
229930195729 fatty acid Natural products 0.000 claims description 15
229920003169 water-soluble polymer Polymers 0.000 claims description 12
239000007788 liquid Substances 0.000 claims description 11
QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 claims description 10
150000004665 fatty acids Chemical class 0.000 claims description 10
238000000926 separation method Methods 0.000 claims description 10
ABLZXFCXXLZCGV-UHFFFAOYSA-N Phosphorous acid Chemical compound OP(O)=O ABLZXFCXXLZCGV-UHFFFAOYSA-N 0.000 claims description 9
150000001450 anions Chemical class 0.000 claims description 9
229910052736 halogen Inorganic materials 0.000 claims description 7
150000002367 halogens Chemical class 0.000 claims description 7
150000003242 quaternary ammonium salts Chemical class 0.000 claims description 6
150000003014 phosphoric acid esters Chemical class 0.000 claims description 4
125000001183 hydrocarbyl group Chemical group 0.000 claims 2
BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 claims 1
-1 sulfuric acid ester Chemical class 0.000 description 90
238000006116 polymerization reaction Methods 0.000 description 50
239000000178 monomer Substances 0.000 description 46
239000007864 aqueous solution Substances 0.000 description 45
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 35
NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 description 30
150000003839 salts Chemical class 0.000 description 28
238000003756 stirring Methods 0.000 description 22
QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 20
239000000706 filtrate Substances 0.000 description 20
NLXLAEXVIDQMFP-UHFFFAOYSA-N Ammonia chloride Chemical compound [NH4+].[Cl-] NLXLAEXVIDQMFP-UHFFFAOYSA-N 0.000 description 19
QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 19
125000000217 alkyl group Chemical group 0.000 description 18
235000012970 cakes Nutrition 0.000 description 18
239000002253 acid Substances 0.000 description 16
LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 15
230000000694 effects Effects 0.000 description 15
239000000203 mixture Substances 0.000 description 15
239000004744 fabric Substances 0.000 description 14
239000000243 solution Substances 0.000 description 14
HRPVXLWXLXDGHG-UHFFFAOYSA-N Acrylamide Chemical compound NC(=O)C=C HRPVXLWXLXDGHG-UHFFFAOYSA-N 0.000 description 13
125000002091 cationic group Chemical group 0.000 description 13
239000000084 colloidal system Substances 0.000 description 13
239000007787 solid Substances 0.000 description 13
HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 12
NEHMKBQYUWJMIP-UHFFFAOYSA-N chloromethane Chemical class ClC NEHMKBQYUWJMIP-UHFFFAOYSA-N 0.000 description 12
125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 description 12
LSNNMFCWUKXFEE-UHFFFAOYSA-M Bisulfite Chemical compound OS([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-M 0.000 description 11
208000005156 Dehydration Diseases 0.000 description 11
230000018044 dehydration Effects 0.000 description 11
238000006297 dehydration reaction Methods 0.000 description 11
238000004519 manufacturing process Methods 0.000 description 11
OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 10
239000000654 additive Substances 0.000 description 10
229910052799 carbon Inorganic materials 0.000 description 10
239000003795 chemical substances by application Substances 0.000 description 10
150000002430 hydrocarbons Chemical group 0.000 description 10
238000005259 measurement Methods 0.000 description 10
238000010557 suspension polymerization reaction Methods 0.000 description 10
RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 9
VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 9
229910019142 PO4 Inorganic materials 0.000 description 9
150000001412 amines Chemical class 0.000 description 9
235000019270 ammonium chloride Nutrition 0.000 description 9
150000003863 ammonium salts Chemical class 0.000 description 9
150000001875 compounds Chemical class 0.000 description 9
238000004042 decolorization Methods 0.000 description 9
239000002245 particle Substances 0.000 description 9
239000010452 phosphate Substances 0.000 description 9
239000004094 surface-active agent Substances 0.000 description 9
NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 8
229910052751 metal Inorganic materials 0.000 description 8
239000002184 metal Substances 0.000 description 8
125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 8
229910052757 nitrogen Inorganic materials 0.000 description 8
GHKOFFNLGXMVNJ-UHFFFAOYSA-N Didodecyl thiobispropanoate Chemical compound CCCCCCCCCCCCOC(=O)CCSCCC(=O)OCCCCCCCCCCCC GHKOFFNLGXMVNJ-UHFFFAOYSA-N 0.000 description 7
LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 7
CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 7
125000000129 anionic group Chemical group 0.000 description 7
239000002612 dispersion medium Substances 0.000 description 7
238000007720 emulsion polymerization reaction Methods 0.000 description 7
150000002148 esters Chemical class 0.000 description 7
244000144992 flock Species 0.000 description 7
238000010528 free radical solution polymerization reaction Methods 0.000 description 7
239000003999 initiator Substances 0.000 description 7
238000010526 radical polymerization reaction Methods 0.000 description 7
239000010865 sewage Substances 0.000 description 7
238000012360 testing method Methods 0.000 description 7
CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 6
KIWBPDUYBMNFTB-UHFFFAOYSA-N Ethyl hydrogen sulfate Chemical compound CCOS(O)(=O)=O KIWBPDUYBMNFTB-UHFFFAOYSA-N 0.000 description 6
KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 6
OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 6
KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 6
230000002776 aggregation Effects 0.000 description 6
239000003963 antioxidant agent Substances 0.000 description 6
235000006708 antioxidants Nutrition 0.000 description 6
KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 6
238000005189 flocculation Methods 0.000 description 6
230000016615 flocculation Effects 0.000 description 6
239000011521 glass Substances 0.000 description 6
239000003921 oil Substances 0.000 description 6
150000007524 organic acids Chemical class 0.000 description 6
229920001451 polypropylene glycol Polymers 0.000 description 6
BWHMMNNQKKPAPP-UHFFFAOYSA-L potassium carbonate Chemical compound [K+].[K+].[O-]C([O-])=O BWHMMNNQKKPAPP-UHFFFAOYSA-L 0.000 description 6
239000002244 precipitate Substances 0.000 description 6
SSOLNOMRVKKSON-UHFFFAOYSA-N proguanil Chemical compound CC(C)\N=C(/N)N=C(N)NC1=CC=C(Cl)C=C1 SSOLNOMRVKKSON-UHFFFAOYSA-N 0.000 description 6
239000000126 substance Substances 0.000 description 6
150000003460 sulfonic acids Chemical class 0.000 description 6
229920002554 vinyl polymer Polymers 0.000 description 6
VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 5
DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 5
ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 5
229910052783 alkali metal Inorganic materials 0.000 description 5
KCXMKQUNVWSEMD-UHFFFAOYSA-N benzyl chloride Chemical compound ClCC1=CC=CC=C1 KCXMKQUNVWSEMD-UHFFFAOYSA-N 0.000 description 5
229940073608 benzyl chloride Drugs 0.000 description 5
UAUGRLPXPATLOX-UHFFFAOYSA-N benzyl-didodecyl-methylazanium Chemical compound CCCCCCCCCCCC[N+](C)(CCCCCCCCCCCC)CC1=CC=CC=C1 UAUGRLPXPATLOX-UHFFFAOYSA-N 0.000 description 5
JMEWIEXZXNOKHY-UHFFFAOYSA-N benzyl-methyl-di(tetradecyl)azanium Chemical compound CCCCCCCCCCCCCC[N+](C)(CCCCCCCCCCCCCC)CC1=CC=CC=C1 JMEWIEXZXNOKHY-UHFFFAOYSA-N 0.000 description 5
JAUVCBJVIFFHEI-UHFFFAOYSA-N benzyl-methyl-dioctadecylazanium Chemical compound CCCCCCCCCCCCCCCCCC[N+](C)(CCCCCCCCCCCCCCCCCC)CC1=CC=CC=C1 JAUVCBJVIFFHEI-UHFFFAOYSA-N 0.000 description 5
150000001768 cations Chemical class 0.000 description 5
230000000052 comparative effect Effects 0.000 description 5
238000009833 condensation Methods 0.000 description 5
230000005494 condensation Effects 0.000 description 5
SWSFKKWJEHRFFP-UHFFFAOYSA-N dihexadecyl(dimethyl)azanium Chemical compound CCCCCCCCCCCCCCCC[N+](C)(C)CCCCCCCCCCCCCCCC SWSFKKWJEHRFFP-UHFFFAOYSA-N 0.000 description 5
125000000118 dimethyl group Chemical group [H]C([H])([H])* 0.000 description 5
OGQYPPBGSLZBEG-UHFFFAOYSA-N dimethyl(dioctadecyl)azanium Chemical compound CCCCCCCCCCCCCCCCCC[N+](C)(C)CCCCCCCCCCCCCCCCCC OGQYPPBGSLZBEG-UHFFFAOYSA-N 0.000 description 5
CJBMLKNLJXFFGD-UHFFFAOYSA-N dimethyl-di(tetradecyl)azanium Chemical compound CCCCCCCCCCCCCC[N+](C)(C)CCCCCCCCCCCCCC CJBMLKNLJXFFGD-UHFFFAOYSA-N 0.000 description 5
229940093915 gynecological organic acid Drugs 0.000 description 5
239000010800 human waste Substances 0.000 description 5
KUFYUMSBZMUWAN-UHFFFAOYSA-N n-methyl-n-tetradecyltetradecan-1-amine Chemical compound CCCCCCCCCCCCCCN(C)CCCCCCCCCCCCCC KUFYUMSBZMUWAN-UHFFFAOYSA-N 0.000 description 5
QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 5
235000019198 oils Nutrition 0.000 description 5
235000005985 organic acids Nutrition 0.000 description 5
150000002978 peroxides Chemical class 0.000 description 5
239000011591 potassium Substances 0.000 description 5
229910052700 potassium Inorganic materials 0.000 description 5
230000009467 reduction Effects 0.000 description 5
239000011734 sodium Substances 0.000 description 5
229910052708 sodium Inorganic materials 0.000 description 5
125000000542 sulfonic acid group Chemical group 0.000 description 5
FRBBCWMXKIOLII-PLNGDYQASA-N (Z)-18,18-dimethylnonadec-9-enoic acid Chemical compound CC(CCCCCCC\C=C/CCCCCCCC(=O)O)(C)C FRBBCWMXKIOLII-PLNGDYQASA-N 0.000 description 4
BLOQISMXYPADKL-UHFFFAOYSA-N 1-prop-2-enoyloxypropane-1-sulfonic acid Chemical compound CCC(S(O)(=O)=O)OC(=O)C=C BLOQISMXYPADKL-UHFFFAOYSA-N 0.000 description 4
JKNCOURZONDCGV-UHFFFAOYSA-N 2-(dimethylamino)ethyl 2-methylprop-2-enoate Chemical compound CN(C)CCOC(=O)C(C)=C JKNCOURZONDCGV-UHFFFAOYSA-N 0.000 description 4
QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 4
ROSDSFDQCJNGOL-UHFFFAOYSA-N Dimethylamine Chemical compound CNC ROSDSFDQCJNGOL-UHFFFAOYSA-N 0.000 description 4
ZRALSGWEFCBTJO-UHFFFAOYSA-N Guanidine Chemical compound NC(N)=N ZRALSGWEFCBTJO-UHFFFAOYSA-N 0.000 description 4
WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 description 4
CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 4
230000002378 acidificating effect Effects 0.000 description 4
229910000147 aluminium phosphate Inorganic materials 0.000 description 4
125000003277 amino group Chemical group 0.000 description 4
230000003078 antioxidant effect Effects 0.000 description 4
JRKKBONBQMSTDC-UHFFFAOYSA-N benzyl-di(docosyl)-methylazanium Chemical compound CCCCCCCCCCCCCCCCCCCCCC[N+](C)(CCCCCCCCCCCCCCCCCCCCCC)CC1=CC=CC=C1 JRKKBONBQMSTDC-UHFFFAOYSA-N 0.000 description 4
DEOSEFTVDAEGAD-UHFFFAOYSA-N benzyl-dihexadecyl-methylazanium Chemical compound CCCCCCCCCCCCCCCC[N+](C)(CCCCCCCCCCCCCCCC)CC1=CC=CC=C1 DEOSEFTVDAEGAD-UHFFFAOYSA-N 0.000 description 4
FWLORMQUOWCQPO-UHFFFAOYSA-N benzyl-dimethyl-octadecylazanium Chemical compound CCCCCCCCCCCCCCCCCC[N+](C)(C)CC1=CC=CC=C1 FWLORMQUOWCQPO-UHFFFAOYSA-N 0.000 description 4
NFEHZPZLFITKMM-UHFFFAOYSA-N benzyl-docosyl-dimethylazanium Chemical compound CCCCCCCCCCCCCCCCCCCCCC[N+](C)(C)CC1=CC=CC=C1 NFEHZPZLFITKMM-UHFFFAOYSA-N 0.000 description 4
XADRYJFRYRBPFB-UHFFFAOYSA-N benzyl-icosyl-dimethylazanium Chemical compound CCCCCCCCCCCCCCCCCCCC[N+](C)(C)CC1=CC=CC=C1 XADRYJFRYRBPFB-UHFFFAOYSA-N 0.000 description 4
239000012986 chain transfer agent Substances 0.000 description 4
CXVSBABSEYWIJS-UHFFFAOYSA-N di(docosyl)-dimethylazanium Chemical compound CCCCCCCCCCCCCCCCCCCCCC[N+](C)(C)CCCCCCCCCCCCCCCCCCCCCC CXVSBABSEYWIJS-UHFFFAOYSA-N 0.000 description 4
150000004662 dithiols Chemical class 0.000 description 4
125000003438 dodecyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 4
239000000839 emulsion Substances 0.000 description 4
238000001704 evaporation Methods 0.000 description 4
230000008020 evaporation Effects 0.000 description 4
LPTIRUACFKQDHZ-UHFFFAOYSA-N hexadecyl sulfate;hydron Chemical compound CCCCCCCCCCCCCCCCOS(O)(=O)=O LPTIRUACFKQDHZ-UHFFFAOYSA-N 0.000 description 4
238000005342 ion exchange Methods 0.000 description 4
229910052744 lithium Inorganic materials 0.000 description 4
239000011976 maleic acid Substances 0.000 description 4
JZMJDSHXVKJFKW-UHFFFAOYSA-M methyl sulfate(1-) Chemical compound COS([O-])(=O)=O JZMJDSHXVKJFKW-UHFFFAOYSA-M 0.000 description 4
125000004433 nitrogen atom Chemical group N* 0.000 description 4
150000002989 phenols Chemical class 0.000 description 4
229920000768 polyamine Polymers 0.000 description 4
239000000843 powder Substances 0.000 description 4
235000011121 sodium hydroxide Nutrition 0.000 description 4
CWERGRDVMFNCDR-UHFFFAOYSA-N thioglycolic acid Chemical compound OC(=O)CS CWERGRDVMFNCDR-UHFFFAOYSA-N 0.000 description 4
VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 4
125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 4
239000007762 w/o emulsion Substances 0.000 description 4
AZRYOLWUVTYFIE-ARJAWSKDSA-N (Z)-N-benzyl-18-methylnonadec-9-en-1-amine Chemical compound CC(C)CCCCCCC\C=C/CCCCCCCCNCc1ccccc1 AZRYOLWUVTYFIE-ARJAWSKDSA-N 0.000 description 3
SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 3
DPBJAVGHACCNRL-UHFFFAOYSA-N 2-(dimethylamino)ethyl prop-2-enoate Chemical compound CN(C)CCOC(=O)C=C DPBJAVGHACCNRL-UHFFFAOYSA-N 0.000 description 3
UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
GCORHVJDVFERBG-VXPUYCOJSA-N CCCCCCCC/C(=C(/C)\CCCCCCC(CC)C(=O)O)/C Chemical compound CCCCCCCC/C(=C(/C)\CCCCCCC(CC)C(=O)O)/C GCORHVJDVFERBG-VXPUYCOJSA-N 0.000 description 3
OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 3
ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 3
RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical class S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 description 3
FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 3
LSDPWZHWYPCBBB-UHFFFAOYSA-N Methanethiol Chemical compound SC LSDPWZHWYPCBBB-UHFFFAOYSA-N 0.000 description 3
229910002651 NO3 Inorganic materials 0.000 description 3
NHNBFGGVMKEFGY-UHFFFAOYSA-N Nitrate Chemical compound [O-][N+]([O-])=O NHNBFGGVMKEFGY-UHFFFAOYSA-N 0.000 description 3
MUBZPKHOEPUJKR-UHFFFAOYSA-N Oxalic acid Chemical compound OC(=O)C(O)=O MUBZPKHOEPUJKR-UHFFFAOYSA-N 0.000 description 3
235000019482 Palm oil Nutrition 0.000 description 3
229920003171 Poly (ethylene oxide) Polymers 0.000 description 3
OFOBLEOULBTSOW-UHFFFAOYSA-N Propanedioic acid Natural products OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 3
DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 3
GOOHAUXETOMSMM-UHFFFAOYSA-N Propylene oxide Chemical compound CC1CO1 GOOHAUXETOMSMM-UHFFFAOYSA-N 0.000 description 3
YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
ZMANZCXQSJIPKH-UHFFFAOYSA-N Triethylamine Chemical compound CCN(CC)CC ZMANZCXQSJIPKH-UHFFFAOYSA-N 0.000 description 3
XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Natural products NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 3
238000002835 absorbance Methods 0.000 description 3
150000003926 acrylamides Chemical class 0.000 description 3
150000001252 acrylic acid derivatives Chemical class 0.000 description 3
NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 3
230000000996 additive effect Effects 0.000 description 3
238000005054 agglomeration Methods 0.000 description 3
238000004220 aggregation Methods 0.000 description 3
239000003513 alkali Substances 0.000 description 3
229910052784 alkaline earth metal Inorganic materials 0.000 description 3
125000005210 alkyl ammonium group Chemical group 0.000 description 3
125000001204 arachidyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 3
JUHBAUUOCQWJRU-UHFFFAOYSA-N benzyl-didecyl-methylazanium Chemical compound CCCCCCCCCC[N+](C)(CCCCCCCCCC)CC1=CC=CC=C1 JUHBAUUOCQWJRU-UHFFFAOYSA-N 0.000 description 3
OZISYDUERWIGSU-UHFFFAOYSA-M benzyl-didodecyl-methylazanium;chloride Chemical compound [Cl-].CCCCCCCCCCCC[N+](C)(CCCCCCCCCCCC)CC1=CC=CC=C1 OZISYDUERWIGSU-UHFFFAOYSA-M 0.000 description 3
JLSSEXVNHGDLNN-UHFFFAOYSA-M benzyl-methyl-dioctadecylazanium;chloride Chemical compound [Cl-].CCCCCCCCCCCCCCCCCC[N+](C)(CCCCCCCCCCCCCCCCCC)CC1=CC=CC=C1 JLSSEXVNHGDLNN-UHFFFAOYSA-M 0.000 description 3
230000033228 biological regulation Effects 0.000 description 3
239000011575 calcium Substances 0.000 description 3
229910052791 calcium Inorganic materials 0.000 description 3
BVKZGUZCCUSVTD-UHFFFAOYSA-N carbonic acid Chemical compound OC(O)=O BVKZGUZCCUSVTD-UHFFFAOYSA-N 0.000 description 3
150000001735 carboxylic acids Chemical class 0.000 description 3
229920006317 cationic polymer Polymers 0.000 description 3
QDYLMAYUEZBUFO-UHFFFAOYSA-N cetalkonium chloride Chemical compound CCCCCCCCCCCCCCCC[N+](C)(C)CC1=CC=CC=C1 QDYLMAYUEZBUFO-UHFFFAOYSA-N 0.000 description 3
239000002738 chelating agent Substances 0.000 description 3
238000006243 chemical reaction Methods 0.000 description 3
239000003638 chemical reducing agent Substances 0.000 description 3
239000000460 chlorine Substances 0.000 description 3
229910052801 chlorine Inorganic materials 0.000 description 3
NEHMKBQYUWJMIP-NJFSPNSNSA-N chloro(114C)methane Chemical compound [14CH3]Cl NEHMKBQYUWJMIP-NJFSPNSNSA-N 0.000 description 3
238000005352 clarification Methods 0.000 description 3
238000005345 coagulation Methods 0.000 description 3
230000015271 coagulation Effects 0.000 description 3
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YBRBMKDOPFTVDT-UHFFFAOYSA-N tert-butylamine Chemical compound CC(C)(C)N YBRBMKDOPFTVDT-UHFFFAOYSA-N 0.000 description 1
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229960002447 thiram Drugs 0.000 description 1
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229910052723 transition metal Inorganic materials 0.000 description 1
BDZBKCUKTQZUTL-UHFFFAOYSA-N triethyl phosphite Chemical compound CCOP(OCC)OCC BDZBKCUKTQZUTL-UHFFFAOYSA-N 0.000 description 1
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UNXRWKVEANCORM-UHFFFAOYSA-N triphosphoric acid Chemical compound OP(O)(=O)OP(O)(=O)OP(O)(O)=O UNXRWKVEANCORM-UHFFFAOYSA-N 0.000 description 1
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NLVXSWCKKBEXTG-UHFFFAOYSA-N vinylsulfonic acid Chemical compound OS(=O)(=O)C=C NLVXSWCKKBEXTG-UHFFFAOYSA-N 0.000 description 1
239000002699 waste material Substances 0.000 description 1
238000005303 weighing Methods 0.000 description 1
238000004260 weight control Methods 0.000 description 1
239000008096 xylene Substances 0.000 description 1