JP4001386B2 - アルケン重合のための有機クロム化合物を含有する触媒およびそれらの使用 - Google Patents

アルケン重合のための有機クロム化合物を含有する触媒およびそれらの使用 Download PDF

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JP4001386B2
JP4001386B2 JP50844998A JP50844998A JP4001386B2 JP 4001386 B2 JP4001386 B2 JP 4001386B2 JP 50844998 A JP50844998 A JP 50844998A JP 50844998 A JP50844998 A JP 50844998A JP 4001386 B2 JP4001386 B2 JP 4001386B2
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alkene
polymerization catalyst
catalyst according
alkene polymerization
thf
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JP50844998A
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JP2000516649A (ja
JP2000516649A5 (enExample
Inventor
ヨリー，ペーター・バルター
ヨナス，クラウス
ベローブニク，グレン・パウル・ヨハネス
デーリング，アルノ
ゲーレ，ヤン
ベーバー，ヤン・クリストフ
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バゼル・ポリオレフィン・ゲゼルシャフト・ミット・ベシュレンクテル・ハフツング
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Priority claimed from DE1996130580 external-priority patent/DE19630580A1/de
Priority claimed from DE19710615A external-priority patent/DE19710615A1/de
Application filed by バゼル・ポリオレフィン・ゲゼルシャフト・ミット・ベシュレンクテル・ハフツング filed Critical バゼル・ポリオレフィン・ゲゼルシャフト・ミット・ベシュレンクテル・ハフツング
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    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F17/00—Metallocenes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/04—Monomers containing three or four carbon atoms
    • C08F110/06—Propene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2420/00—Metallocene catalysts
    • C08F2420/01—Cp or analog bridged to a non-Cp X neutral donor
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/639—Component covered by group C08F4/62 containing a transition metal-carbon bond
    • C08F4/63912—Component covered by group C08F4/62 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/639—Component covered by group C08F4/62 containing a transition metal-carbon bond
    • C08F4/63916—Component covered by group C08F4/62 containing a transition metal-carbon bond supported on a carrier, e.g. silica, MgCl2, polymer
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/639—Component covered by group C08F4/62 containing a transition metal-carbon bond
    • C08F4/6392—Component covered by group C08F4/62 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S526/943—Polymerization with metallocene catalysts

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
JP50844998A 1996-07-30 1997-07-18 アルケン重合のための有機クロム化合物を含有する触媒およびそれらの使用 Expired - Lifetime JP4001386B2 (ja)

Applications Claiming Priority (5)

Application Number Priority Date Filing Date Title
DE1996130580 DE19630580A1 (de) 1996-07-30 1996-07-30 Organochrom-Verbindungen enthaltende Katalysatoren und ihre Verwendung in der Alkenpolymerisation
DE19630580.2 1996-07-30
DE19710615A DE19710615A1 (de) 1997-03-14 1997-03-14 Organochrom-Verbindungen enthaltende Katalysatoren und ihre Verwendung in der Alkenpolymerisation
DE19710615.3 1997-03-14
PCT/EP1997/003868 WO1998004570A1 (de) 1996-07-30 1997-07-18 Organochrom-verbindungen enthaltende katalysatoren und ihre verwendung in der alkenpolymerisation

Publications (3)

Publication Number Publication Date
JP2000516649A JP2000516649A (ja) 2000-12-12
JP2000516649A5 JP2000516649A5 (enExample) 2005-04-07
JP4001386B2 true JP4001386B2 (ja) 2007-10-31

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JP50844998A Expired - Lifetime JP4001386B2 (ja) 1996-07-30 1997-07-18 アルケン重合のための有機クロム化合物を含有する触媒およびそれらの使用

Country Status (5)

Country Link
US (1) US6255418B1 (enExample)
EP (1) EP0915896A1 (enExample)
JP (1) JP4001386B2 (enExample)
CA (1) CA2260003A1 (enExample)
WO (1) WO1998004570A1 (enExample)

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DE50008258D1 (de) 1999-08-13 2004-11-18 Basell Polyolefine Gmbh Copolymere von ethylen mit c3-c9 alpha-olefinen
US6437161B1 (en) * 1999-08-13 2002-08-20 Basf Aktiengesellschaft Monocyclopentadienyl complexes of chromium, molybdenum or tungsten
US6723675B1 (en) 2000-05-25 2004-04-20 Univation Technologies, Llc Catalyst for the production of olefin polymers
DE10028432A1 (de) * 2000-06-13 2001-12-20 Basell Polyolefine Gmbh Auf calciniertes Hydrotalcit geträgerter Katalysatorfeststoff zur Olefinpolymerisation
JP2004501246A (ja) * 2000-06-20 2004-01-15 ビーエーエスエフ　アクチェンゲゼルシャフト 酸化ポリオレフィンワックス
GB0020613D0 (en) 2000-08-21 2000-10-11 Borealis Tech Oy Catalysts
GB0021301D0 (en) * 2000-08-30 2000-10-18 Borealis Tech Oy Supported catalyst
ATE334151T1 (de) * 2000-09-28 2006-08-15 Basell Polyolefine Gmbh Verfahren zur herstellung von hochverzweigten ethylenpolymerisaten
GB0119009D0 (en) 2001-08-03 2001-09-26 Avecia Ltd Compound and process
ATE412016T1 (de) * 2001-09-14 2008-11-15 Basell Polyolefine Gmbh Verfahren zur polymerisation von olefinen
DE10145453A1 (de) * 2001-09-14 2003-06-05 Basell Polyolefine Gmbh Monocyclopentadienylkomplexe mit einem kondensierten Heterocyclus
DE10163154A1 (de) * 2001-12-20 2003-07-03 Basell Polyolefine Gmbh Pyrogene Kieselsäuren enthaltender Katalysatorfeststoff zur Olefinpolymerisation
US20060089253A1 (en) * 2002-08-13 2006-04-27 Shahram Mihan Monocyclopentadienyl complexes
JP2005536566A (ja) 2002-08-22 2005-12-02 バーゼル、ポリオレフィン、ゲゼルシャフト、ミット、ベシュレンクテル、ハフツング モノシクロペンタジエニル錯体
DE60331768D1 (de) * 2002-11-04 2010-04-29 Basell Polyolefine Gmbh Herstellung einer katalysatorzusammensetzung mit vetbesserter aktivität
US7507688B2 (en) * 2002-12-20 2009-03-24 Basell Polyolefine Gmbh Monocyclopentadienyl complexes
ATE503776T1 (de) * 2002-12-20 2011-04-15 Basell Polyolefine Gmbh Copolymere mit alpha-olefinen
EP1608690B1 (en) * 2003-04-03 2007-06-13 Basell Polyolefine GmbH Preparation of polyolefins having high molecular weights in the presence of an organic transition metal compound in a gas-phase fluidized-bed reactor
WO2005058928A1 (en) * 2003-12-16 2005-06-30 Basell Polyolefine Gmbh Monocyclopentadienyl complexes
JP2007514685A (ja) * 2003-12-19 2007-06-07 バーゼル、ポリオレフィン、ゲゼルシャフト、ミット、ベシュレンクテル、ハフツング モノシクロペンタジエニル錯体
BRPI0418130A (pt) * 2003-12-23 2007-04-17 Basell Polyolefine Gmbh sistema catalisador para a polimerização de olefinas
CN100528914C (zh) * 2003-12-23 2009-08-19 巴塞尔聚烯烃股份有限公司 负载型助催化剂的制备
DE102004020524A1 (de) 2004-04-26 2005-11-10 Basell Polyolefine Gmbh Polyethylen und Katalysatorzusammensetzung zu dessen Herstellung
DE102004061618A1 (de) * 2004-12-17 2006-06-22 Basell Polyolefine Gmbh Monocyclopentadienylkomplexe
DE102005014395A1 (de) * 2005-03-24 2006-09-28 Basell Polyolefine Gmbh Monocyclopentadienylkomplexe
DE102005035477A1 (de) * 2005-07-26 2007-02-01 Basell Polyolefine Gmbh Verfahren zur Steuerung der relativen Aktivität der unterschiedlichen aktiven Zentren von Hybridkatalysatoren
CN101287768A (zh) * 2005-10-14 2008-10-15 巴塞尔聚烯烃股份有限公司 担载在卤化镁上的杂化催化剂系统
DE102007017903A1 (de) 2007-04-13 2008-10-16 Basell Polyolefine Gmbh Polyethylen und Katalysatorzusammensetzung und Verfahren zu dessen Herstellung
EP2222720B1 (en) 2007-12-19 2016-02-10 Basell Polyolefine GmbH Mono-hydroindacenyl complexes
WO2016153574A1 (en) * 2015-03-23 2016-09-29 Exxonmobil Chemical Patents Inc. Group 6 transition metal catalyst compound and use thereof
US10329363B2 (en) 2015-03-23 2019-06-25 Exxonmobil Chemical Patents Inc. Group 6 transition metal catalyst compound and use thereof
GB201522437D0 (en) * 2015-12-18 2016-02-03 Univ Leeds Tethered ligands

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US4015059A (en) 1975-12-29 1977-03-29 Union Carbide Corporation Fused ring catalyst and ethylene polymerization process therewith
NZ235032A (en) 1989-08-31 1993-04-28 Dow Chemical Co Constrained geometry complexes of titanium, zirconium or hafnium comprising a substituted cyclopentadiene ligand; use as olefin polymerisation catalyst component
US5418200A (en) * 1991-03-29 1995-05-23 Chevron Chemical Company Cyclopentadienyl group 6B metal α-olefin polymerization catalysts and process for polymerizing α-olefins
US5320996A (en) * 1992-11-06 1994-06-14 Chevron Research And Technology Company Alpha-olefin polymerization catalysts comprising supported cyclopentadienyl group 6b metal oxo, thio, imido and phosphido compounds and process for polymerizing alpha-olefins
DE4416876A1 (de) * 1994-05-13 1995-11-16 Basf Ag Verfahren zur Herstellung von verbrückten Halbsandwichkomplexen
DE4431838A1 (de) * 1994-09-07 1996-03-14 Basf Ag Geträgerte Metallocen-Katalysatorsysteme
EP0789718B1 (en) * 1994-10-31 1998-04-08 Dsm N.V. Catalyst composition and process for the polymerization of an olefin

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US6255418B1 (en) 2001-07-03
JP2000516649A (ja) 2000-12-12
WO1998004570A1 (de) 1998-02-05
CA2260003A1 (en) 1998-02-05
EP0915896A1 (de) 1999-05-19

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