JP3466228B2 - 1,3−プロパンジオールの製法 - Google Patents
1,3−プロパンジオールの製法Info
- Publication number
- JP3466228B2 JP3466228B2 JP13023593A JP13023593A JP3466228B2 JP 3466228 B2 JP3466228 B2 JP 3466228B2 JP 13023593 A JP13023593 A JP 13023593A JP 13023593 A JP13023593 A JP 13023593A JP 3466228 B2 JP3466228 B2 JP 3466228B2
- Authority
- JP
- Japan
- Prior art keywords
- hydrogenation
- catalyst
- propanediol
- temperature
- hpa
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
- C07C29/132—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group
- C07C29/136—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH
- C07C29/14—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH of a —CHO group
- C07C29/141—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH of a —CHO group with hydrogen or hydrogen-containing gases
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Catalysts (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE4218282.4 | 1992-06-03 | ||
| DE4218282A DE4218282A1 (de) | 1992-06-03 | 1992-06-03 | Verfahren zur Herstellung von 1,3-Propandiol |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPH0640973A JPH0640973A (ja) | 1994-02-15 |
| JP3466228B2 true JP3466228B2 (ja) | 2003-11-10 |
Family
ID=6460294
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP13023593A Expired - Fee Related JP3466228B2 (ja) | 1992-06-03 | 1993-06-01 | 1,3−プロパンジオールの製法 |
Country Status (6)
| Country | Link |
|---|---|
| US (1) | US5334778A (enExample) |
| EP (1) | EP0572812B1 (enExample) |
| JP (1) | JP3466228B2 (enExample) |
| DE (2) | DE4218282A1 (enExample) |
| SG (1) | SG45290A1 (enExample) |
| TW (1) | TW284752B (enExample) |
Families Citing this family (91)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE4238492C2 (de) * | 1992-11-14 | 1995-06-14 | Degussa | Verfahren zur Herstellung von 1,2- und 1,3-Propandiol |
| US5463144A (en) * | 1994-09-30 | 1995-10-31 | Shell Oil Company | Process for preparing 1,3-propanediol |
| US5545767A (en) * | 1994-09-30 | 1996-08-13 | Shell Oil Company | Process for preparing 1,3-propanediol |
| US5463146A (en) * | 1994-09-30 | 1995-10-31 | Shell Oil Company | Process for preparing 1,3-propanediol |
| US5527973A (en) * | 1994-12-16 | 1996-06-18 | Kelsey; Donald R. | Purification of 1,3-propanediol |
| US5888923A (en) * | 1996-04-15 | 1999-03-30 | Dairen Chemical Corporation | Modified Raney nickel catalyst and a process for preparing diols by using the same |
| US5786524A (en) * | 1996-05-30 | 1998-07-28 | Shell Oil Company | Process for preparation of 1,3-propanediol via hydrogenation of 3-hydroxypropanal |
| DE19737190A1 (de) * | 1997-06-18 | 1999-01-21 | Du Pont | Verfahren zur Herstellung von 1,3-Propandiol durch Hydrieren von Hydroxypropionaldehyd |
| US6232511B1 (en) * | 1997-06-18 | 2001-05-15 | E. I. Du Pont De Nemours And Company | Process for the production of 1,3-propanediol by hydrogenating 3-hydroxypropionaldehyde |
| WO1998057913A1 (en) * | 1997-06-18 | 1998-12-23 | E.I. Du Pont De Nemours And Company | Process for the production of 1,3-propanediol by hydrogenating 3 -hydroxypropionaldehyde |
| DE19840277A1 (de) * | 1998-09-04 | 2000-03-09 | Degussa | Verfahren zur Reduzierung des Gehalts an Acetalen oder Ketalen in alkoholischen Reaktionsgemischen |
| CN1178884C (zh) * | 1998-09-04 | 2004-12-08 | 纳幕尔杜邦公司 | 关于通过3-羟基丙醛的催化氢化反应制备1,3-丙二醇的两步方法 |
| US5945570A (en) | 1998-10-29 | 1999-08-31 | Arhancet; Juan Pedro | Catalyst and process for preparing 1,3-propanediol |
| US6245879B1 (en) | 1999-01-29 | 2001-06-12 | Shell Oil Company | Purification of 1,3-propanediol in carbonyl-containing stream |
| US6331264B1 (en) | 1999-03-31 | 2001-12-18 | E. I. Du Pont De Nemours And Company | Low emission polymer compositions |
| JP4570786B2 (ja) * | 1999-03-31 | 2010-10-27 | ダイセル化学工業株式会社 | 高純度1,3−プロパンジオール誘導体系溶媒、その製造方法、及び用途 |
| US6284930B1 (en) | 1999-07-30 | 2001-09-04 | E.I. Du Pont De Nemours And Company | Process for the preparation of 3-hydroxypropanal |
| US6342646B1 (en) * | 1999-07-30 | 2002-01-29 | E. I. Du Pont De Nemours And Company | Catalytic hydrogenation of 3-hydroxypropanal to 1,3-propanediol |
| US6455742B1 (en) | 1999-09-02 | 2002-09-24 | Wisconsin Alumni Research Foundation | Method for catalytically reducing carboxylic acid groups to hydroxyl groups in hydroxycarboxylic acids |
| TWI266760B (en) | 2000-03-20 | 2006-11-21 | Kvaerner Process Tech Ltd | Process for the preparation of propane-1,3-diol |
| US6380438B1 (en) * | 2000-07-13 | 2002-04-30 | Ttc Labs, Inc. | Process for the production of 3-hydroxypropanal |
| MY140801A (en) | 2002-10-03 | 2010-01-15 | Shell Int Research | Reduction of the viscosity of reactive heavy byproducts during the production of 1,3-propanediol |
| CN1662683B (zh) * | 2002-12-23 | 2012-11-07 | 纳幕尔杜邦公司 | 聚对苯二甲酸丙二醇酯双组分纤维工艺 |
| US7323539B2 (en) | 2003-05-06 | 2008-01-29 | E. I. Du Pont De Nemours And Company | Polytrimethylene ether glycol and polytrimethylene ether ester with excellent quality |
| US7084311B2 (en) * | 2003-05-06 | 2006-08-01 | E. I. Du Pont De Nemours And Company | Hydrogenation of chemically derived 1,3-propanediol |
| CN100448826C (zh) * | 2003-05-06 | 2009-01-07 | 纳幕尔杜邦公司 | 化学衍生1,3-丙二醇的氢化 |
| CA2522928C (en) | 2003-05-06 | 2013-09-24 | E.I. Du Pont De Nemours And Company | Purification of biologically-produced 1,3-propanediol |
| US7342142B2 (en) * | 2003-05-06 | 2008-03-11 | E.I. Du Pont De Nemours And Company | Hydrogenation of polytrimethylene ether glycol |
| US20040225107A1 (en) * | 2003-05-06 | 2004-11-11 | Sunkara Hari Babu | Polytrimethylene ether glycol with excellent quality from biochemically-derived 1,3-propanediol |
| US20070035057A1 (en) * | 2003-06-26 | 2007-02-15 | Chang Jing C | Poly(trimethylene terephthalate) bicomponent fiber process |
| MXPA06003819A (es) * | 2003-10-07 | 2006-08-11 | Shell Int Research | Proceso para la produccion de 1,3-propanodiol por hidrogenacion catalitica de 3-hidroxipropanal en la presencia de un co-catalizador de hidratacion. |
| TW200536821A (en) | 2004-02-05 | 2005-11-16 | Showa Denko Kk | Production process of 3-alkoxy-1-propanols, and 3-alkoxy-1-propanols obtained by the production process |
| US20080103217A1 (en) * | 2006-10-31 | 2008-05-01 | Hari Babu Sunkara | Polyether ester elastomer composition |
| US7074969B2 (en) * | 2004-06-18 | 2006-07-11 | E.I. Du Pont De Nemours And Company | Process for preparation of polytrimethylene ether glycols |
| US20060041039A1 (en) * | 2004-08-20 | 2006-02-23 | Gyorgyi Fenyvesi | Fluorescent poly(alkylene terephthalate) compositions |
| US20060070918A1 (en) * | 2004-10-01 | 2006-04-06 | Mayis Seapan | Method to extend the utilization of a catalyst in a multistage reactor system |
| US7358211B2 (en) * | 2004-11-24 | 2008-04-15 | E.I. Du Pont De Nemours And Company | Catalyst for the production of 1,3-propanediol by catalytic hydrogenation of 3-hydroxypropanal |
| EP2270065A3 (en) | 2004-12-21 | 2011-03-09 | E. I. du Pont de Nemours and Company | Poly(trimethylene terephthalate) composition and shaped articles prepared therefrom |
| US7396896B2 (en) * | 2004-12-21 | 2008-07-08 | E.I. Dupont De Nemours And Company | Poly(trimethylene terephthalate) composition and shaped articles prepared therefrom |
| US20060189711A1 (en) * | 2005-02-23 | 2006-08-24 | Ng Howard C | Silicon-containing polytrimethylene homo- or copolyether composition |
| US7629396B2 (en) * | 2005-02-23 | 2009-12-08 | E.I. Du Pont De Nemours And Company | Silicon-containing polytrimethylene homo- for copolyether composition |
| KR20080005564A (ko) * | 2005-04-21 | 2008-01-14 | 셀 인터나쵸나아레 레사아치 마아츠샤피 비이부이 | 수소화 촉매 및 수소화 방법 |
| US20060247378A1 (en) * | 2005-05-02 | 2006-11-02 | Sunkara Hari B | Thermoplastic elastomer blend, method of manufacture and use thereof |
| US7244790B2 (en) * | 2005-05-02 | 2007-07-17 | E.I. Du Pont De Nemours And Company | Thermoplastic elastomer blend, method of manufacture and use thereof |
| US7157607B1 (en) | 2005-08-16 | 2007-01-02 | E. I. Du Pont De Nemours And Company | Manufacture of polytrimethylene ether glycol |
| US7161045B1 (en) | 2005-08-16 | 2007-01-09 | E. I. Du Pont De Nemours And Company | Process for manufacture of polytrimethylene ether glycol |
| US7357985B2 (en) * | 2005-09-19 | 2008-04-15 | E.I. Du Pont De Nemours And Company | High crimp bicomponent fibers |
| US20070129524A1 (en) * | 2005-12-06 | 2007-06-07 | Sunkara Hari B | Thermoplastic polyurethanes comprising polytrimethylene ether soft segments |
| US20070128459A1 (en) * | 2005-12-07 | 2007-06-07 | Kurian Joseph V | Poly(trimethylene terephthalate)/poly(alpha-hydroxy acid) films |
| US7666501B2 (en) * | 2005-12-07 | 2010-02-23 | E. I. Du Pont De Nemours And Company | Poly(trimethylene terephthalate)/poly(alpha-hydroxy acid) bi-constituent filaments |
| US20070129503A1 (en) * | 2005-12-07 | 2007-06-07 | Kurian Joseph V | Poly(trimethylene terephthalate)/poly(alpha-hydroxy acid) molded, shaped articles |
| US7388115B2 (en) * | 2006-01-20 | 2008-06-17 | E. I. Du Pont De Nemours And Company | Manufacture of polytrimethylene ether glycol |
| US7164046B1 (en) | 2006-01-20 | 2007-01-16 | E. I. Du Pont De Nemours And Company | Manufacture of polytrimethylene ether glycol |
| US20070203371A1 (en) * | 2006-01-23 | 2007-08-30 | Sunkara Hari B | Process for producing polytrimethylene ether glycol |
| JP2009525760A (ja) | 2006-02-10 | 2009-07-16 | デユポン・テイト・アンド・ライル・バイオ・プロダクツ・カンパニー・エルエルシー | 再生ベースの生分解性1,3−プロパンジオールを含む生分解性組成物 |
| CN105175257A (zh) | 2006-02-10 | 2015-12-23 | 杜邦塔特和莱尔生物产品有限责任公司 | 包括生物学基1,3-丙二醇的单酯和二酯的组合物 |
| KR20080112373A (ko) * | 2006-04-13 | 2008-12-24 | 셀 인터나쵸나아레 레사아치 마아츠샤피 비이부이 | 알데하이드의 수소화 방법 |
| US20080039582A1 (en) * | 2006-07-28 | 2008-02-14 | Hari Babu Sunkara | Polytrimethylene ether-based polyurethane ionomers |
| US7531593B2 (en) * | 2006-10-31 | 2009-05-12 | E.I. Du Pont De Nemours And Company | Thermoplastic elastomer blend composition |
| US20080108845A1 (en) * | 2006-11-07 | 2008-05-08 | Hari Babu Sunkara | Polytrimethylene ether glycol esters |
| US20080135662A1 (en) * | 2006-12-06 | 2008-06-12 | Chang Jing C | Melt-spun elastoester multifilament yarns |
| US7714174B2 (en) * | 2007-03-27 | 2010-05-11 | E. I. Du Pont De Nemours And Company | Lower-color polytrimethylene ether glycol using hydride compounds |
| US7943792B2 (en) * | 2007-04-02 | 2011-05-17 | Inventure Chemical Inc. | Production of biodiesel, cellulosic sugars, and peptides from the simultaneous esterification and alcoholysis/hydrolysis of materials with oil-containing substituents including phospholipids and peptidic content |
| WO2008122029A1 (en) * | 2007-04-02 | 2008-10-09 | Inventure Chemical, Inc. | Simultaneous esterification and alcohol ysis/hydrolysis of oil-containing materials with cellulosic and peptidic content |
| DE102007027006A1 (de) | 2007-06-08 | 2008-12-11 | Evonik Degussa Gmbh | Mikrobiologische Herstellung von Aldehyden, insbesondere von 3-Hydroxypropionaldehyd |
| EP2181182A1 (en) * | 2007-08-24 | 2010-05-05 | E. I. du Pont de Nemours and Company | Lubrication oil compositions |
| AU2008293746A1 (en) * | 2007-08-24 | 2009-03-05 | E. I. Du Pont De Nemours And Company | Lubrication oil compositions |
| BRPI0815314A2 (pt) * | 2007-08-24 | 2017-05-09 | Du Pont | coposição de óleo lubrificante |
| US8703681B2 (en) | 2007-08-24 | 2014-04-22 | E I Du Pont De Nemours And Company | Lubrication oil compositions |
| EP2181181A1 (en) * | 2007-08-24 | 2010-05-05 | E. I. du Pont de Nemours and Company | Lubrication oil compositions |
| US7919017B2 (en) * | 2007-11-12 | 2011-04-05 | E. I. Du Pont De Nemours And Company | Electrical insulation fluids for use in electrical apparatus |
| US7777085B2 (en) * | 2008-10-01 | 2010-08-17 | Inventure Chemical, Inc. | Method for conversion of oil-containing algae to 1,3-propanediol |
| US20100267994A1 (en) * | 2009-04-16 | 2010-10-21 | E. I. Du Pont De Nemours And Company | Processes for preparing polytrimethylene glycol using ion exchange resins |
| DE102009002811A1 (de) | 2009-05-05 | 2010-11-11 | Evonik Degussa Gmbh | Enzymatisches Verfahren zur Herstellung von Aldehyden |
| US8247526B2 (en) | 2010-12-20 | 2012-08-21 | E I Du Pont De Nemours And Company | Process for the preparation of polyalkylene ether glycol |
| WO2012148849A2 (en) | 2011-04-26 | 2012-11-01 | E. I. Du Pont De Nemours And Company | Processes for preparing polytrimethylene ether glycol |
| US8759559B2 (en) | 2012-04-18 | 2014-06-24 | E I Du Pont De Nemours And Company | Processes for preparing polytrimethylene ether glycol esters |
| JP2014097956A (ja) * | 2012-11-14 | 2014-05-29 | Hitachi Ltd | 1,3−プロパンジオールの製造方法および製造装置 |
| US9527953B2 (en) | 2012-11-19 | 2016-12-27 | Samsung Electronics Co., Ltd. | Continuous preparation for polyester |
| US9056824B2 (en) | 2013-01-31 | 2015-06-16 | Eastman Chemical Company | Preparation of hydroxy aldehydes |
| US8710278B1 (en) | 2013-01-31 | 2014-04-29 | Eastman Chemical Company | Process for producing polyols |
| KR102737311B1 (ko) * | 2016-01-07 | 2024-12-03 | 토프쉐 에이/에스 | 당으로부터 에틸렌글리콜의 제조를 위한 과정 |
| AU2017205691B2 (en) | 2016-01-07 | 2021-06-17 | Haldor Topsøe A/S | Process for the preparation of ethylene glycol from sugars |
| WO2019029808A1 (en) * | 2017-08-09 | 2019-02-14 | Symrise Ag | 1,2-ALKANEDIOLS AND PROCESSES FOR PRODUCING THE SAME |
| CN108358750A (zh) * | 2018-03-23 | 2018-08-03 | 王鹏飞 | 1,3-丙二醇的制备方法 |
| CN114867362A (zh) | 2019-11-01 | 2022-08-05 | 杜邦塔特和莱尔生物产品有限责任公司 | 1,3-丙二醇用于改善味道和/或异味品质的用途和方法 |
| CN113713817B (zh) * | 2020-05-26 | 2023-06-27 | 中国科学院大连化学物理研究所 | 一种采用镍基催化剂催化丙醛加氢制正丙醇的方法 |
| WO2022099488A1 (zh) * | 2020-11-11 | 2022-05-19 | 中国科学院宁波材料技术与工程研究所 | 一种贵金属负载的蛋壳型催化剂及其制备方法与应用 |
| CN114318414B (zh) * | 2021-12-02 | 2023-05-05 | 中国科学院大连化学物理研究所 | 一种二氧化钛基金属催化剂及其制备方法和应用 |
| AU2023341158A1 (en) | 2022-09-16 | 2025-03-27 | Primient Covation Llc | Compositions comprising and methods of using 1,3-propanediol to improve sweetness and/or reduce bitterness of sweeteners |
| CN117362152B (zh) * | 2023-10-09 | 2025-10-17 | 江苏扬农化工集团有限公司 | 1,3-丙二醇的制备方法和产品 |
Family Cites Families (16)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CA703211A (en) * | 1965-02-02 | R. Skinner John | Polyol production | |
| US2434110A (en) * | 1942-08-24 | 1948-01-06 | Shell Dev | Process for hydrating olefinic aldehydes |
| US2421451A (en) * | 1943-03-19 | 1947-06-03 | Air Reduction | Production of 1, 3-butylene glycol |
| US2419300A (en) * | 1944-08-10 | 1947-04-22 | Air Reduction | Production of 1, 3-butylene glycol |
| NL78454C (enExample) * | 1949-12-07 | |||
| FR1335323A (fr) * | 1962-09-25 | 1963-08-16 | Shell Int Research | Procédé de préparation des polyols |
| DE2054601C3 (de) * | 1970-11-06 | 1980-02-14 | Ruhrchemie Ag, 4200 Oberhausen- Holten | Verfahren zur Herstellung von zweiwertigen Alkoholen |
| JPS51138607A (en) * | 1975-05-27 | 1976-11-30 | Mitsubishi Gas Chem Co Inc | Process for preparing neopentylglycol |
| DE3027890A1 (de) * | 1980-07-23 | 1982-03-04 | Basf Ag, 6700 Ludwigshafen | Hydrierkatalysatoren fuer die herstellung von propandiolen und verfahren zur herstellung von propandiolen mit solchen katalysatoren |
| US4393251A (en) * | 1981-06-17 | 1983-07-12 | Basf Aktiengesellschaft | Preparation of propanediols using a copper-and zinc containing hydrogenation catalyst |
| JPH01299239A (ja) * | 1988-05-25 | 1989-12-04 | Mitsubishi Gas Chem Co Inc | ネオペンチルグリコールの製造方法 |
| DE3926136A1 (de) * | 1989-08-08 | 1991-02-14 | Degussa | Verfahren zur herstellung von 1,3-propandiol |
| DE4038192A1 (de) * | 1990-11-30 | 1992-06-04 | Degussa | Verfahren zur herstellung von 1,3-propandiol |
| DE4132663C2 (de) * | 1991-10-01 | 1993-10-14 | Degussa | Verfahren zum Herstellen von 1,3-Propandiol durch Hydrieren von Hydroxypropionaldehyd |
| DE4138982A1 (de) * | 1991-11-27 | 1993-06-03 | Degussa | Verfahren zur herstellung von 3-hydroxyalkanalen |
| DE4138981A1 (de) * | 1991-11-27 | 1993-06-03 | Degussa | Verfahren zur herstellung von 3-hydroxyalkanalen |
-
1992
- 1992-06-03 DE DE4218282A patent/DE4218282A1/de not_active Withdrawn
-
1993
- 1993-04-29 TW TW082103352A patent/TW284752B/zh active
- 1993-05-05 SG SG1996002795A patent/SG45290A1/en unknown
- 1993-05-05 DE DE59301845T patent/DE59301845D1/de not_active Expired - Lifetime
- 1993-05-05 EP EP93107248A patent/EP0572812B1/de not_active Expired - Lifetime
- 1993-05-19 US US08/063,317 patent/US5334778A/en not_active Expired - Lifetime
- 1993-06-01 JP JP13023593A patent/JP3466228B2/ja not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| US5334778A (en) | 1994-08-02 |
| EP0572812A1 (de) | 1993-12-08 |
| TW284752B (enExample) | 1996-09-01 |
| JPH0640973A (ja) | 1994-02-15 |
| EP0572812B1 (de) | 1996-03-13 |
| DE4218282A1 (de) | 1993-12-09 |
| DE59301845D1 (de) | 1996-04-18 |
| SG45290A1 (en) | 1998-01-16 |
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