JP3459272B2 - オレフィンの重合および共重合方法 - Google Patents
オレフィンの重合および共重合方法Info
- Publication number
- JP3459272B2 JP3459272B2 JP01109793A JP1109793A JP3459272B2 JP 3459272 B2 JP3459272 B2 JP 3459272B2 JP 01109793 A JP01109793 A JP 01109793A JP 1109793 A JP1109793 A JP 1109793A JP 3459272 B2 JP3459272 B2 JP 3459272B2
- Authority
- JP
- Japan
- Prior art keywords
- formula
- group
- carbon atoms
- compound
- polymerization
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Ceased
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/619—Component covered by group C08F4/60 containing a transition metal-carbon bond
- C08F4/61912—Component covered by group C08F4/60 containing a transition metal-carbon bond in combination with an organoaluminium compound
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/619—Component covered by group C08F4/60 containing a transition metal-carbon bond
- C08F4/6192—Component covered by group C08F4/60 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
- C08F4/61922—Component covered by group C08F4/60 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
- C08F4/61927—Component covered by group C08F4/60 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not two cyclopentadienyl rings being mutually bridged
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
- Y10S526/943—Polymerization with metallocene catalysts
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE4202163 | 1992-01-27 | ||
DE4202163:4 | 1992-01-27 |
Publications (2)
Publication Number | Publication Date |
---|---|
JPH06122706A JPH06122706A (ja) | 1994-05-06 |
JP3459272B2 true JP3459272B2 (ja) | 2003-10-20 |
Family
ID=6450335
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP01109793A Ceased JP3459272B2 (ja) | 1992-01-27 | 1993-01-26 | オレフィンの重合および共重合方法 |
Country Status (11)
Families Citing this family (14)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH06100614A (ja) * | 1992-08-06 | 1994-04-12 | Mitsui Petrochem Ind Ltd | オレフィン重合用触媒およびこれを用いるオレフィンの重合方法 |
TW298593B (US06818585-20041116-C00001.png) * | 1993-02-12 | 1997-02-21 | Hoechst Ag | |
US6211109B1 (en) * | 1995-07-18 | 2001-04-03 | Fina Technology, Inc. | Process for treating silica with alumoxane |
US6818585B2 (en) | 1998-12-30 | 2004-11-16 | Univation Technologies, Llc | Catalyst compounds, catalyst systems thereof and their use in a polymerization process |
US6034192A (en) * | 1998-12-30 | 2000-03-07 | Univation Technologies, Llc | Germanium bridged metallocenes producing polymers with increased melt strength |
DE19922020A1 (de) * | 1999-05-12 | 2000-11-16 | Targor Gmbh | Übergangsmetallverbindung, Katalysatorsystem, Verfahren zu seiner Herstellung und seine Verwendung zur Polymerisation von Olefinen |
US6444765B1 (en) * | 2000-06-14 | 2002-09-03 | Equistar Chemicals, Lp | Olefin polymerization process for producing broad MWD polymers |
WO2003014166A1 (en) * | 2001-08-07 | 2003-02-20 | Denki Kagaku Kogyo Kabushiki Kaisha | Process for producing polymer |
US7700707B2 (en) | 2002-10-15 | 2010-04-20 | Exxonmobil Chemical Patents Inc. | Polyolefin adhesive compositions and articles made therefrom |
KR101113341B1 (ko) | 2002-10-15 | 2012-09-27 | 엑손모빌 케미칼 패턴츠 인코포레이티드 | 올레핀 중합용 다중 촉매 시스템 및 이로부터 제조된중합체 |
JP2006509898A (ja) | 2002-12-16 | 2006-03-23 | バーゼル、ポリオレフィン、ゲゼルシャフト、ミット、ベシュレンクテル、ハフツング | アルミノキサンを少量含む担持触媒組成物の製造 |
JP5695419B2 (ja) | 2007-08-29 | 2015-04-08 | アルベマール・コーポレーシヨン | ジアルキルアルミニウム陽イオンの前駆剤から生じるアルミノキサン触媒活性剤、同物質の製造方法、ならびにオレフィンの触媒および重合におけるその用途 |
BRPI0703586B1 (pt) | 2007-10-19 | 2018-02-06 | Braskem S.A | Catalisador metaloceno suportado, e, copolímeros de etileno com alfa-olefinas de alto e ultra alto peso molecular |
JP7471726B2 (ja) * | 2020-08-12 | 2024-04-22 | エルジー・ケム・リミテッド | メタロセン担持触媒の製造方法、メタロセン担持触媒およびこれを利用したポリオレフィンの製造方法 |
Family Cites Families (16)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3709853A (en) * | 1971-04-29 | 1973-01-09 | Union Carbide Corp | Polymerization of ethylene using supported bis-(cyclopentadienyl)chromium(ii)catalysts |
DE3443087A1 (de) | 1984-11-27 | 1986-05-28 | Hoechst Ag, 6230 Frankfurt | Verfahren zur herstellung von polyolefinen |
US4701432A (en) * | 1985-11-15 | 1987-10-20 | Exxon Chemical Patents Inc. | Supported polymerization catalyst |
US4794096A (en) * | 1987-04-03 | 1988-12-27 | Fina Technology, Inc. | Hafnium metallocene catalyst for the polymerization of olefins |
JP2538588B2 (ja) * | 1987-04-03 | 1996-09-25 | 三井石油化学工業株式会社 | オレフイン重合用固体触媒の製法 |
US5122491A (en) * | 1987-04-20 | 1992-06-16 | Mitsui Petrochemical Industries, Ltd. | Catalyst for polymerizing an olefin and process for polymerizing an olefin |
DE3726067A1 (de) | 1987-08-06 | 1989-02-16 | Hoechst Ag | Verfahren zur herstellung von 1-olefinpolymeren |
DE3742934A1 (de) | 1987-12-18 | 1989-06-29 | Hoechst Ag | Verfahren zur herstellung einer chiralen, stereorigiden metallocen-verbindung |
DE3743321A1 (de) * | 1987-12-21 | 1989-06-29 | Hoechst Ag | 1-olefinpolymerwachs und verfahren zu seiner herstellung |
DE3907965A1 (de) * | 1989-03-11 | 1990-09-13 | Hoechst Ag | Verfahren zur herstellung eines syndiotaktischen polyolefins |
CA2027145C (en) * | 1989-10-10 | 2002-12-10 | Michael J. Elder | Metallocene catalysts with lewis acids and aluminum alkyls |
JP2927885B2 (ja) * | 1990-05-24 | 1999-07-28 | 三井化学株式会社 | シンジオタクチックポリα―オレフィンの製造方法 |
US5369196A (en) * | 1990-11-30 | 1994-11-29 | Idemitsu Kosan Co., Ltd. | Production process of olefin based polymers |
EP0516458B2 (en) * | 1991-05-31 | 2007-12-19 | Mitsui Chemicals, Inc. | Olefin polymerization solid catalyst, olefin polymerization catalyst and olefin polymerization |
US5308817A (en) * | 1992-05-18 | 1994-05-03 | Fina Technology, Inc. | Metallocene catalyst component with good catalyst efficiency after aging |
US5498582A (en) * | 1993-12-06 | 1996-03-12 | Mobil Oil Corporation | Supported metallocene catalysts for the production of polyolefins |
-
1992
- 1992-12-15 TW TW081110038A patent/TW304963B/zh active
-
1993
- 1993-01-25 KR KR1019930000870A patent/KR100268539B1/ko not_active IP Right Cessation
- 1993-01-25 AU AU31996/93A patent/AU669684B2/en not_active Ceased
- 1993-01-26 ZA ZA93548A patent/ZA93548B/xx unknown
- 1993-01-26 JP JP01109793A patent/JP3459272B2/ja not_active Ceased
- 1993-01-26 ES ES93101116T patent/ES2093287T3/es not_active Expired - Lifetime
- 1993-01-26 DE DE59303908T patent/DE59303908D1/de not_active Expired - Lifetime
- 1993-01-26 AT AT93101116T patent/ATE143384T1/de not_active IP Right Cessation
- 1993-01-26 EP EP93101116A patent/EP0553757B1/de not_active Expired - Lifetime
- 1993-01-26 CA CA002088114A patent/CA2088114A1/en not_active Abandoned
-
1998
- 1998-02-04 US US09/018,497 patent/US5985784A/en not_active Expired - Lifetime
Non-Patent Citations (1)
Title |
---|
J.C.W.CHIEN et.al,Metallocene−Methylalminoxane Catalysts for Olefin ,JOURNAL of POLYMER SCIENCE,米国,Part A/26/11,3089−3102 |
Also Published As
Publication number | Publication date |
---|---|
EP0553757B1 (de) | 1996-09-25 |
KR100268539B1 (ko) | 2000-10-16 |
ATE143384T1 (de) | 1996-10-15 |
ZA93548B (en) | 1993-08-05 |
JPH06122706A (ja) | 1994-05-06 |
ES2093287T3 (es) | 1996-12-16 |
AU3199693A (en) | 1993-07-29 |
US5985784A (en) | 1999-11-16 |
TW304963B (US06818585-20041116-C00001.png) | 1997-05-11 |
KR930016446A (ko) | 1993-08-26 |
CA2088114A1 (en) | 1993-07-28 |
AU669684B2 (en) | 1996-06-20 |
DE59303908D1 (de) | 1996-10-31 |
EP0553757A1 (de) | 1993-08-04 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
A02 | Decision of refusal |
Free format text: JAPANESE INTERMEDIATE CODE: A02 Effective date: 20020528 |
|
A01 | Written decision to grant a patent or to grant a registration (utility model) |
Free format text: JAPANESE INTERMEDIATE CODE: A01 Effective date: 20030701 |
|
RVOP | Cancellation by post-grant opposition | ||
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |