JP2022548052A - ３ｄプリンティング用途における使用のための高屈折率モノマーを含有する光硬化性組成物 - Google Patents

３ｄプリンティング用途における使用のための高屈折率モノマーを含有する光硬化性組成物 Download PDF

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Publication number
JP2022548052A
JP2022548052A JP2022516133A JP2022516133A JP2022548052A JP 2022548052 A JP2022548052 A JP 2022548052A JP 2022516133 A JP2022516133 A JP 2022516133A JP 2022516133 A JP2022516133 A JP 2022516133A JP 2022548052 A JP2022548052 A JP 2022548052A
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acrylate
meth
photocurable composition
weight
monomer
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JP2022548052A5 (https=
JPWO2021048628A5 (https=
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ヤン・シュトルツ
ノエミ・フェイレ
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Arkema France SA
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Arkema France SA
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/10—Esters
    • C08F220/12—Esters of monohydric alcohols or phenols
    • C08F220/16—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms
    • C08F220/18—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms with acrylic or methacrylic acids
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D11/00—Inks
    • C09D11/02—Printing inks
    • C09D11/10—Printing inks based on artificial resins
    • C09D11/101—Inks specially adapted for printing processes involving curing by wave energy or particle radiation, e.g. with UV-curing following the printing
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C64/00—Additive manufacturing, i.e. manufacturing of three-dimensional [3D] objects by additive deposition, additive agglomeration or additive layering, e.g. by 3D printing, stereolithography or selective laser sintering
    • B29C64/10—Processes of additive manufacturing
    • B29C64/106—Processes of additive manufacturing using only liquids or viscous materials, e.g. depositing a continuous bead of viscous material
    • B29C64/124—Processes of additive manufacturing using only liquids or viscous materials, e.g. depositing a continuous bead of viscous material using layers of liquid which are selectively solidified
    • B29C64/129—Processes of additive manufacturing using only liquids or viscous materials, e.g. depositing a continuous bead of viscous material using layers of liquid which are selectively solidified characterised by the energy source therefor, e.g. by global irradiation combined with a mask
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B33—ADDITIVE MANUFACTURING TECHNOLOGY
    • B33Y—ADDITIVE MANUFACTURING, i.e. MANUFACTURING OF THREE-DIMENSIONAL [3D] OBJECTS BY ADDITIVE DEPOSITION, ADDITIVE AGGLOMERATION OR ADDITIVE LAYERING, e.g. BY 3D PRINTING, STEREOLITHOGRAPHY OR SELECTIVE LASER SINTERING
    • B33Y70/00—Materials specially adapted for additive manufacturing
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B33—ADDITIVE MANUFACTURING TECHNOLOGY
    • B33Y—ADDITIVE MANUFACTURING, i.e. MANUFACTURING OF THREE-DIMENSIONAL [3D] OBJECTS BY ADDITIVE DEPOSITION, ADDITIVE AGGLOMERATION OR ADDITIVE LAYERING, e.g. BY 3D PRINTING, STEREOLITHOGRAPHY OR SELECTIVE LASER SINTERING
    • B33Y70/00—Materials specially adapted for additive manufacturing
    • B33Y70/10—Composites of different types of material, e.g. mixtures of ceramics and polymers or mixtures of metals and biomaterials
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00—Processes of polymerisation
    • C08F2/44—Polymerisation in the presence of compounding ingredients, e.g. plasticisers, dyestuffs, fillers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00—Processes of polymerisation
    • C08F2/46—Polymerisation initiated by wave energy or particle radiation
    • C08F2/48—Polymerisation initiated by wave energy or particle radiation by ultraviolet or visible light
    • C08F2/50—Polymerisation initiated by wave energy or particle radiation by ultraviolet or visible light with sensitising agents
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/10—Esters
    • C08F220/26—Esters containing oxygen in addition to the carboxy oxygen
    • C08F220/30—Esters containing oxygen in addition to the carboxy oxygen containing aromatic rings in the alcohol moiety
    • C08F220/301—Esters containing oxygen in addition to the carboxy oxygen containing aromatic rings in the alcohol moiety and one oxygen in the alcohol moiety
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F226/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a single or double bond to nitrogen or by a heterocyclic ring containing nitrogen
    • C08F226/06—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a single or double bond to nitrogen or by a heterocyclic ring containing nitrogen by a heterocyclic ring containing nitrogen
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F226/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a single or double bond to nitrogen or by a heterocyclic ring containing nitrogen
    • C08F226/06—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a single or double bond to nitrogen or by a heterocyclic ring containing nitrogen by a heterocyclic ring containing nitrogen
    • C08F226/12—N-Vinylcarbazole
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L71/00—Compositions of polyethers obtained by reactions forming an ether link in the main chain; Compositions of derivatives of such polymers
    • C08L71/02—Polyalkylene oxides
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2800/00—Copolymer characterised by the proportions of the comonomers expressed
    • C08F2800/20—Copolymer characterised by the proportions of the comonomers expressed as weight or mass percentages

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Health & Medical Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Manufacturing & Machinery (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Physics & Mathematics (AREA)
  • Mechanical Engineering (AREA)
  • Optics & Photonics (AREA)
  • Ceramic Engineering (AREA)
  • Civil Engineering (AREA)
  • Composite Materials (AREA)
  • Structural Engineering (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Macromonomer-Based Addition Polymer (AREA)
JP2022516133A 2019-09-12 2020-09-11 ３ｄプリンティング用途における使用のための高屈折率モノマーを含有する光硬化性組成物 Pending JP2022548052A (ja)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US201962899182P 2019-09-12 2019-09-12
US62/899,182 2019-09-12
PCT/IB2020/000754 WO2021048628A1 (en) 2019-09-12 2020-09-11 Photo-curable compositions containing high refractive index monomers for use in 3d printing applications

Publications (3)

Publication Number Publication Date
JP2022548052A true JP2022548052A (ja) 2022-11-16
JP2022548052A5 JP2022548052A5 (https=) 2023-08-31
JPWO2021048628A5 JPWO2021048628A5 (https=) 2023-08-31

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JP2022516133A Pending JP2022548052A (ja) 2019-09-12 2020-09-11 ３ｄプリンティング用途における使用のための高屈折率モノマーを含有する光硬化性組成物

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US (1) US12492275B2 (https=)
EP (1) EP4028480A1 (https=)
JP (1) JP2022548052A (https=)
KR (1) KR20220062041A (https=)
CN (1) CN114651049A (https=)
IL (1) IL291203A (https=)
TW (1) TWI842949B (https=)
WO (1) WO2021048628A1 (https=)

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* Cited by examiner, † Cited by third party
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JP2023550694A (ja) * 2020-11-13 2023-12-05 メタ プラットフォームズ テクノロジーズ， リミテッド ライアビリティ カンパニー 体積ブラッググレーティングのための置換モノフェニルコアモノマー及び置換ポリフェニルコアモノマー並びにそれらのポリマー

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CN117280002A (zh) * 2021-05-07 2023-12-22 巴斯夫欧洲公司 产生用于3d光聚合物喷射的支撑子结构的可辐射固化组合物
CN113968734B (zh) * 2021-11-15 2022-08-16 重庆文理学院 一种高致密度氧化锆陶瓷材料的制备方法
CN113896528B (zh) * 2021-11-15 2022-07-26 重庆文理学院 一种dlp-3d打印制备高性能氧化锆陶瓷材料的方法
CN114368972B (zh) * 2022-01-21 2023-02-28 中国地质大学（武汉） 可见光3d打印光固化陶瓷浆料、制备方法及打印方法
CN115385834B (zh) * 2022-08-15 2023-11-03 中国科学院理化技术研究所 一种高折射率树枝状（甲基）丙烯酸酯类单体及其制备方法和应用
TW202421415A (zh) * 2022-09-12 2024-06-01 新加坡國立大學 用於積層製造的漿料
CN115572163B (zh) * 2022-09-27 2023-04-25 河南驼人医疗器械研究院有限公司 一种提高光固化打印精度及力学性能的氧化锆陶瓷浆料及其制备方法
JP2026502083A (ja) * 2022-12-09 2026-01-21 スリーディー システムズ インコーポレーテッド 高い弾性率および分散安定性を有する３ｄプリント用のインク
KR102920961B1 (ko) * 2023-06-30 2026-02-02 국립목포대학교산학협력단 디지털 라이트 프로세싱 3d 프린터용 슬러리 조성물 및 이를 이용한 지르코니아 소결체 제조방법

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Publication number Priority date Publication date Assignee Title
JP2023550694A (ja) * 2020-11-13 2023-12-05 メタ プラットフォームズ テクノロジーズ， リミテッド ライアビリティ カンパニー 体積ブラッググレーティングのための置換モノフェニルコアモノマー及び置換ポリフェニルコアモノマー並びにそれらのポリマー

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TW202115141A (zh) 2021-04-16
KR20220062041A (ko) 2022-05-13
US12492275B2 (en) 2025-12-09
WO2021048628A1 (en) 2021-03-18
CN114651049A (zh) 2022-06-21
IL291203A (en) 2022-05-01
EP4028480A1 (en) 2022-07-20
TWI842949B (zh) 2024-05-21
US20240052081A1 (en) 2024-02-15

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