JP2022518290A - レオロジー改質剤としてmfcを含む殺有害生物製剤 - Google Patents
レオロジー改質剤としてmfcを含む殺有害生物製剤 Download PDFInfo
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- JP2022518290A JP2022518290A JP2021543292A JP2021543292A JP2022518290A JP 2022518290 A JP2022518290 A JP 2022518290A JP 2021543292 A JP2021543292 A JP 2021543292A JP 2021543292 A JP2021543292 A JP 2021543292A JP 2022518290 A JP2022518290 A JP 2022518290A
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- PJVWKTKQMONHTI-UHFFFAOYSA-N warfarin Chemical compound OC=1C2=CC=CC=C2OC(=O)C=1C(CC(=O)C)C1=CC=CC=C1 PJVWKTKQMONHTI-UHFFFAOYSA-N 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
- 239000002025 wood fiber Substances 0.000 description 1
- 239000008096 xylene Substances 0.000 description 1
- WCJYTPVNMWIZCG-UHFFFAOYSA-N xylylcarb Chemical compound CNC(=O)OC1=CC=C(C)C(C)=C1 WCJYTPVNMWIZCG-UHFFFAOYSA-N 0.000 description 1
- 229940023877 zeatin Drugs 0.000 description 1
- 239000005943 zeta-Cypermethrin Substances 0.000 description 1
- LQUPKVMEAATBSL-UHFFFAOYSA-L zinc;2,3,4-trichlorophenolate Chemical compound [Zn+2].[O-]C1=CC=C(Cl)C(Cl)=C1Cl.[O-]C1=CC=C(Cl)C(Cl)=C1Cl LQUPKVMEAATBSL-UHFFFAOYSA-L 0.000 description 1
Classifications
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- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05B—PHOSPHATIC FERTILISERS
- C05B15/00—Organic phosphatic fertilisers
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- A—HUMAN NECESSITIES
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- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
- A01N25/02—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests containing liquids as carriers, diluents or solvents
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- A—HUMAN NECESSITIES
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- A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
- A01N25/02—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests containing liquids as carriers, diluents or solvents
- A01N25/04—Dispersions, emulsions, suspoemulsions, suspension concentrates or gels
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- A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
- A01N25/26—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests in coated particulate form
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
- A01N25/30—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests characterised by the surfactants
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N53/00—Biocides, pest repellants or attractants, or plant growth regulators containing cyclopropane carboxylic acids or derivatives thereof
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N57/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds
- A01N57/10—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds having phosphorus-to-oxygen bonds or phosphorus-to-sulfur bonds
- A01N57/12—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds having phosphorus-to-oxygen bonds or phosphorus-to-sulfur bonds containing acyclic or cycloaliphatic radicals
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- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05G—MIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
- C05G3/00—Mixtures of one or more fertilisers with additives not having a specially fertilising activity
- C05G3/40—Mixtures of one or more fertilisers with additives not having a specially fertilising activity for affecting fertiliser dosage or release rate; for affecting solubility
- C05G3/44—Mixtures of one or more fertilisers with additives not having a specially fertilising activity for affecting fertiliser dosage or release rate; for affecting solubility for affecting solubility
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- C05—FERTILISERS; MANUFACTURE THEREOF
- C05G—MIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
- C05G3/00—Mixtures of one or more fertilisers with additives not having a specially fertilising activity
- C05G3/60—Biocides or preservatives, e.g. disinfectants, pesticides or herbicides; Pest repellants or attractants
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- C05G—MIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
- C05G5/00—Fertilisers characterised by their form
- C05G5/10—Solid or semi-solid fertilisers, e.g. powders
- C05G5/12—Granules or flakes
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- C05G—MIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
- C05G5/00—Fertilisers characterised by their form
- C05G5/10—Solid or semi-solid fertilisers, e.g. powders
- C05G5/18—Semi-solid fertilisers, e.g. foams or gels
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- C05—FERTILISERS; MANUFACTURE THEREOF
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- C05G5/00—Fertilisers characterised by their form
- C05G5/20—Liquid fertilisers
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- C05—FERTILISERS; MANUFACTURE THEREOF
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- C05G5/00—Fertilisers characterised by their form
- C05G5/20—Liquid fertilisers
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Abstract
Description
[0001]本出願は、それぞれが参照により本明細書に組み込まれる、2019年1月25日に出願した仮特許出願第62/797,124号、2019年9月6日に出願した仮特許出願第62/896,762号、および、2019年10月17日に出願した仮特許出願第62/916,764号の利益を主張する。
[0008]本明細書で使用されている略語は、一般的に化学的および生物学的技術の範囲内でのこれらの従来の意味に適合する。他に具体的に指摘されていない限り、本明細書で使用されているすべての技術的および科学的用語は、当業者により共通して理解されている意味と同じ意味を有する。加えて、本明細書に記載されている方法または材料と類似のまたは同等の任意の方法または材料は、本明細書中に開示される実施形態の実施において使用することができる。本発明の実施形態の目的のため、以下の用語が定義される。
[0032]実施形態では、ミクロフィブリル化セルロースは非修飾ミクロフィブリル化セルロース、例えば、植物材料由来の非修飾ミクロフィブリル化セルロースである。
[0040]本明細書で使用される場合、「非イオン性ポリマー分散剤」とは、ポリマー上にイオン電荷を有さないポリマー分散剤を指す。
[0055]本明細書で使用される場合、「サスポエマルジョン」または「SE」という用語は、水性連続相中で油の微細な小滴のエマルジョンと組み合わせた微粒子の安定した懸濁液を指す。
[0063]本明細書で使用される場合、「ハロアルキル」とは、水素原子の一部またはすべてがハロゲン原子で置き換えられている、上で定義されたようなアルキルを指す。アルキル基に関して、ハロアルキル基は、任意の適切な数の炭素原子、例えば、C1~6を有することができる。例えば、ハロアルキルとして、トリフルオロメチル、フルオロメチル(flouromethyl)などが挙げられる。実施形態では、「パーフルオロ」という用語は、すべての水素がフッ素で置き換えられている化合物または基を定義するために使用することができる。例えば、パーフルオロメチルは、1,1,1-トリフルオロメチルを指す。
[0065]本明細書で使用される場合、「エトキシ化」とは、酸化エチレンが化合物または基質に添加される化学的プロセスを指す。
[0067]本明細書で使用される場合、「ポリ尿素(ポリウレア)」とは、ジイソシアネート化合物をポリアミンと反応することから誘導される種類のポリマーを指す。ポリ尿素は、以下の式:
[0068]本明細書で使用される場合、「ポリイソシアネート」とは、1つより多くのイソシアネート基を含むポリマーの種類を指す。
[0070]本明細書で使用される場合、「ポリアミド」とは、1つより多くのアミド結合を含むポリマーを指す。
[0072]本明細書で使用される場合、「ポリカーボネート」とは、1つより多くのカーボネート基を含むポリマーを指す。
[0074]本明細書で使用される場合、「ポリイミン」とは、1つより多くのイミン基を含むポリマーを指す。
[0079]本明細書で使用される場合、「レオロジー改質剤」とは、液体の粘度およびまたは流速を改質することができる化合物または基質を指す。レオロジー改質剤の種類は、これらに限定されないが、Kelzan S Plus、多糖、キサンタンガム、グアーガム、ローカストガム、粘土、シリカ、デンプン、rheo界面活性剤およびこれらの混合物を含む。
[0084]本明細書で使用される場合、「粘土」とは、ケイ酸塩鉱物を含む細粒化土または岩材料を指す。粘土は、微量の石英および金属酸化物、例えば、酸化アルミニウムおよび酸化マグネシウムを含んでもよい。ある特定の割合で水と混合した場合、粘土は可塑性を示す。
[0086]本明細書で使用される場合、「デンプン」とは、グリコシド結合により共有結合したグルコース単糖を含む炭水化物ポリマーを指す。デンプンは、粘着剤、剛化剤、および/または増粘剤として使用することができる。
[0092]P1.実施形態では、微粒子形態の殺有害生物剤、ポリマー分散剤、およびミクロフィブリル化セルロースを含む懸濁液が提供される。
[0094]P3.実施形態では、固体形態は、約1ミクロン~約15ミクロンの範囲のメジアン粒径を有する。
[0096]P5.実施形態では、微粒子はカプセル剤である。
[0097]P6.実施形態では、カプセル剤は、シクロデキストリン、20~50個の炭素の直鎖および20~90パーセントのエトキシ化を有するアルキルエトキシレート、ポリ尿素、ポリウレタン、ポリカーボネート、ポリアミド、ならびにポリスルホンアミド(これらのいずれかは場合によって架橋されている)ならびにこれらの組合せからなる群から選択される壁内に殺有害生物剤を封入することにより形成される。
[0099]P8.実施形態では、ポリイソシアネートは、ポリ(フェニルイソシアネート)-co-ホルムアルデヒド、テトラメチレンジイソシアネート、ペンタメチレンジイソシアネート、ヘキサメチレンジイソシアネート、トルエンジイソシアネート、ジフェニルメテン-4,4’-ジイソシアネート、ポリメチレンポリフェニレンイソシアネート、2,4,4’-ジフェニルエーテルトリイソシアネート、3,3’-ジメチル-4,4’-ジフェニルジイソシアネート、3,3’-ジメトキシ-4,4’-ジフェニルジイソシアネート、1,5-ナフチレンジイソシアネートおよび4,4’4”-トリフェニルメタントリイソシアネートから選択される。
[0101]P10.実施形態では、ポリアミンは、ジエチレントリアミン、エチレンジアミン、プロピレン-1,3-ジアミン、テトラメチレンジアミン、ペンタメチレンジアミン、1,6-ヘキサメチレンジアミン、ジエチレントリアミン、トリエチレンテトラミン、テトラエチレンペンタミン、ペンタエチレンヘキサミン、4,9-ジオキサドデカン-1,12-ジアミン、1,3-フェニレンジアミン、2,4-および2,6-トルエンジアミンならびに4,4’-ジアミノジフェニルメタンまたはその酸付加塩から選択される。
[0103]P12.実施形態では、ポリアミンはジエチレントリアミンである。
[0106]P15.実施形態では、殺有害生物剤は、クロレトキシホスおよびビフェントリンの組合せである。
[0108]P17.実施形態では、ポリマー分散剤は、アニオン性ポリマー分散剤、リグノスルホネート、アルキルホルムアルデヒド凝縮物、非イオン性ポリマー分散剤、ポリビニルアルコール、アクリルコポリマー、櫛型アクリル分散剤からなる群から選択される。
[0110]P19.実施形態では、ポリマー分散剤はEnvi-Pol871である。
[0111]P20.実施形態では、ミクロフィブリル化セルロースは、懸濁液の約0.05重量%~約3重量%の量で存在する。
[0113]P22.実施形態では、懸濁液はエタノールアミンをさらに含んでもよい。
[0115]P24.実施形態では、懸濁液は殺生物剤をさらに含んでもよい。
[0117]P26.実施形態では、殺生物剤はイソチアゾリノンである。
[0119]P28.実施形態では、殺生物剤は懸濁液の約0.005重量%~約3重量%の量で存在する。
[0121]P30.実施形態では、消泡剤はシリコーン泡止め剤である。
[0122]P31.実施形態では、消泡剤はシリコーンエマルジョンである。
[0124]P33.実施形態では、懸濁液はレオロジー改質剤をさらに含んでもよい。
[0127]P36.実施形態では、ミクロフィブリル化セルロースはExilva F01Vである。
[0129]P38.実施形態では、多糖は、キサンタンガム、グアーガム、ローカストガムからなる群から選択される。
[0131]P40.実施形態では、微粒子形態の封入された殺有害生物剤、ポリマー分散剤、およびミクロフィブリル化セルロースを含む封入懸濁液が提供される。
[0133]P42.実施形態では、封入された懸濁液を作製する方法であって、水中にポリマー分散剤を含む水性混合物を準備するステップと、水性混合物に、有機溶媒中に殺有害生物剤およびポリイソシアネートを含む有機混合物を添加するステップと、水性混合物中の有機混合物を所望の粒径エマルジョンに乳化するステップと、架橋剤をエマルジョンに添加して、封入された殺有害生物剤を得るステップと、ミクロフィブリル化セルロースを含む少なくとも1種のレオロジー改質剤を封入された殺有害生物剤に添加して、懸濁液を形成するステップとを含む方法が提供される。
[0135]P44.実施形態では、レオロジー改質剤はキサンタンガムをさらに含む。
[0137]P46.実施形態では、クロレトキシホスは懸濁液の約25重量パーセントで存在する。
[0139]P48.実施形態では、方法は、乳化剤を、封入された殺有害生物剤に添加するステップをさらに含んでもよい。
A.組成物および製剤
[0141]実施形態では、液相中のクロレトキシホスとビフェントリンの混合物のカプセル懸濁液(CS)であって、この混合物が封入壁内に配置されているカプセル懸濁液(CS)を含み、ポリマー分散剤、ミクロフィブリル化セルロース、および場合によってエタノールアミンをさらに含む組成物が提供される。
[0143]実施形態では、液相は水を含む。
[0144]実施形態では、組成物はエタノールアミンをさらに含んでもよい。
[0148]実施形態では、ミクロフィブリル化セルロースは、湿潤剤または分散剤で前処理され、剪断条件に対象下におかれてもよい。この追加の前処理は、本明細書の組成物を形成する際に損失弾性率(G’)または貯蔵弾性率(G’’)を増加させるために使用することができる。
[0152]実施形態では、農業用薬剤はビフェントリンを含む。
[0153]実施形態では、農業用薬剤は、組成物の約0.1%~約60重量%の量で存在する。
[0155]実施形態では組成物は、アニオン性ポリマー分散剤、リグノスルホネート、アルキルホルムアルデヒド凝縮物、非イオン性ポリマー分散剤、ポリビニルアルコール、アクリルコポリマー、および櫛型アクリル分散剤からなる群から選択されるポリマー分散剤をさらに含んでもよい。
[0157]実施形態では、ポリマー分散剤はアニオン性アクリルポリマーである。
[0158]実施形態では、レオロジー改質剤は、多糖、キサンタンガム、グアーガム、ローカストガム、粘土、シリカ、デンプン、rheo界面活性剤、およびこれらの混合物からなる群から選択される。
[0160]実施形態では、組成物はエタノールアミンをさらに含んでもよい。
[0162]実施形態では、カプセル懸濁液中の農業用薬剤およびミクロフィブリル化セルロースを含む組成物が提供される。
[0164]実施形態では、マイクロエマルジョン中の農業用薬剤およびミクロフィブリル化セルロースを含む組成物が提供される。
[0166]実施形態では、乳化可能な濃縮物中の農業用薬剤およびミクロフィブリル化セルロースを含む組成物が提供される。
[0168]実施形態では、油分散液中の農業用薬剤およびミクロフィブリル化セルロースを含む組成物が提供される。
[0174]実施形態では、組成物は肥料を含んでもよく、肥料は、窒素源、リン源、およびカリウム源のうちの少なくとも1種を含み,窒素源、リン源、およびカリウム源は、0~40:0~50:0~40の間のNPK(窒素-リン-カリウム)値をもたらす量で存在するが、ただし、窒素源、リン、およびカリウム源の値の少なくとも1つはゼロではないものとする。
実施形態では、塩としての農業用活性成分は、グルホシネート、グリホセート、2,4D、ジカンバ、または他のイオン性活性成分からなる群から選択される。
[0188]実施形態では、殺菌剤は、ブロノポール、水酸化銅、クレゾール、ジクロロフェン、ジピリチオン、ドジシン、フェナミノスルフ、ホルムアルデヒド、ヒドラーガフェン、8-ヒドロキシキノリン硫酸塩、カスガマイシン、ニトラピリン、オクチリノン、オキソリン酸、オキシテトラサイクリン、プロベナゾール、ストレプトマイシン、テクロフタラム、またはチオメルサールである。
キナジド、ピロキロン、ナトリウムオルトフェニルフェノキサイド、スピロキサミン、スルトロペン、チシオフェン、トリシクラゾール、ナフテン酸亜鉛、マラカイトグリーン、またはefosite-Al(ALIETTE(登録商標))である。
、タンデックス、モヌロン、ジウロン、ダラポン、フェノキシ酪酸除草剤(例えば、4-(4-クロロフェノキシ)ブタン酸(4-CPB)、(2,4-ジクロロフェノキシ)酪酸(2,4-DB)(BUTAXONE(登録商標))、3,4-DB、4-クロロ-2-メチル-フェノキシ)酪酸(MCPB)(TROPOTOX(登録商標))、または4-(2,4,5-トリクロロフェノキシ)ブタン酸(2,4,5-TB))、α-フェノキシプロピオン酸除草剤(例えば、シルベックス/2(2,4,5-トリクロロフェノキシ)プロピオン酸(WEEDONE(登録商標))、2-(4-クロロフェノキシ)プロパン酸(4-CPP)、ジクロプロプ/α-(2,4-ジクロロフェノキシ)プロピオン酸(2,4-DP(登録商標))(例えば、ジクロプロプ-P)、3,4-DP、フェノプロップ、またはメコプロプ/(4-クロロ-2-メチルフェノキシ)プロピオン酸(MCPP(登録商標))(例えば、メコプロプ-P))、アリールオキシフェノキシプロピオン酸除草剤(例えば、クロラジホップ、クロジナホップ、クロホップ、シハロホップ、ジクロホップ、フェノキサプロプ(例えば、フェノキサプロプ-P)、フェンチアプロップ、フルアジホップ(例えば、フルアジホップ-P)、ハロキシホップ(例えば、ハロキシホップ-P)、イソキサピリホップ、メタミホップ、プロパキザホップ、キザロホップ(例えば、キザロホップ-P)、またはトリホップ)、フェニレンジアミン除草剤(例えば、ジニトラミンまたはプロジアミン)、ピラゾリルオキシアセトフェノン除草剤(例えば、ベンゾフェナプまたはピラゾキシフェン)、ピラゾリルフェニル除草剤(例えば、フルアゾレートまたはピラフルフェン)、ピリダジン除草剤(例えば、クレダジン、ピリダフォル、ピリデート、マレイン酸ヒドラジド(MH)/1,2-ジヒドロピリダジン-3,6-ジオン(RETARD(登録商標)))、ピリダジノン除草剤(例えば、ブロムピラゾン、クロリダゾン、ジミダゾン、フルフェンピル、メトフルラゾン、ノルフルラゾン、オキサピラゾン、またはピダノン)、ピリジン除草剤(例えば、アミノピラリド、クリオジネート、クロピラリド、ジチオピル、フルロキシピル、ハロキシジン、ピクロラム/4-アミノ-3,5,6-トリクロロピコリン酸(piclonic acid)(TORDON(登録商標))、ピコリナフェン、ピリクロール、チアゾピル、またはトリクロピル)、ピリミジンジアミン除草剤(例えば、イプリミダムまたはチオクロリム)、第四級アンモニウム除草剤(例えば、シペルコート、ジエタムコート、ジフェンゾコート、モルファムコート、ジクアット/1,1-エチル-2,2ビピリジリウムジブロミド(REGLON(登録商標))、またはパラコート/1,1-ジメチル-4,4-ビピリジリウムジブロミド(GRAMOXONE(登録商標)))、トリアジン除草剤(例えば、ジプロペトリン、トリアジフラム、トリヒドロキシトリアジン、クロロトリアジン除草剤(例えば、アトラジン/2-クロロ-4-(エチルアミノ)-6-(イソプロピルアミノ)-S-トリアジン(ATRATAF(登録商標)、RESIDOX(登録商標))、クロラジン、シアナジン、シプラジン、エグリナジン、イパジン、メソパジン、プロシアジン、プログリナジン、プロパジン、セブチラジン、シマジン/2-クロロ-4,6-ビス-(エチルアミノ)-S-トリアジン(GESATOP(登録商標))、テルブチラジン、またはトリエタジン)、メトキシトリアジン除草剤(例えば、アトラトン、メトメトン、プロメトン/プロメトン/2,4-ビス(イソプロピルアミノ)-6-メトキシ-S-トリアジン(PRAMITOL(登録商標))、セクブメトン、シメトン、またはターブメトン)、またはメチルチオトリアジン除草剤(例えば、アメトリン/アメトリン/2-(エチルアミノ)-4-(イソプロピル-アミノ)-6-(メチルアミノ)-S-トリアジン(GESAPAX(登録商標))、アジプロトリン、シアナトリン、デスメトリン、ジメタメトリン、メトプロトリン、プロメトリン、シメトリン、またはテルブチリン/テルブチリン/2,4-ビス(イソプロピルアミノ)-6-メトキシ-S-トリアジン(tert-ブチルアミノ)-4(エチルアミノ)-6-(メチルチオ)-S-トリアジン(IGRAN(登録商標)))、トリアジノン除草剤(例えば、アメトリジオン、アミブジン、ヘキサジノン、イソメチオジン、メタミトロン、またはメトリブジン/4-アミノ-6-tert-ブチル3-(メチル-チオ)-S-トリアジン-5(4H)1つの(SENCOR(登録商標)))、トリアゾール除草剤(例えば、アミトロール/3-アミノ-1,2,4-トリアゾール(WEEDAZOL(登録商標))、カフェンストロール、エプロナズ、またはフルポキサム)、トリアゾロン除草剤(例えば、アミカルバゾン、カフェントラゾン、フルカルバゾン、プロポキシカルバゾン、またはスルフェントラゾン)、トリアゾロピリミジン除草剤(例えば、クロランスラム、ジクロスラム、フロラスラム、フルメトスラム、メトスラム、ペノクススラム、ウラシル除草剤、ブタフェナシル、フルプロパシル、イソシル、レナシル、ブロマシル/5-ブロモ-6-メチル1 3,5-ブチルウラシル(HYVAR-X(登録商標))、またはテルバシル/5-クロロ-6-メチル3-Tブチルウラシル(SINBAR(登録商標)))、アミノトリアゾン、アミトロール/3-アミノ-1,2,4-トリアゾール(WEEDAZOL(登録商標))、エンドタール/3,6-エンドキソヘキサヒドロフタル酸/7-オキサビシクロ[2.2.1]ヘプタン-2,3-ジカルボン酸(ENDOTHALL(登録商標))、オキサジアゾン/2-ブチル-4-(2-,4-ジクロロ-5-イソプロピル-1,3,4-オキサジアゾリン5オン-オキシフェノール)(RONSTAR(登録商標))、またはピラゾン/5-アミノ-4-クロロ-2-フェニル3(2H)ピリダジノン(PYRAMIN(登録商標)))、チオカルバメート除草剤(例えば、ブチレート、シクロエート、ジアレート/S-(2,3-ジクロロアリル)ジイソプロピルチオカルバメート(AVADEX(登録商標))、S-エチルジプロピルチオカルバメート(EPTC)(EPTAM(登録商標))、エスプロカルブ、エチオレート、イソポリネート、メチオベンカルブ、モリネート/S-エチルヘキサヒドロ-1H-アザピン1-カルボチオネート(ORDAM-72(登録商標))、オルベンカルブ、ペブレート、プロスルホカルブ、ピリブチカルブ、スルファレート、チオベンカルブ、チオカルバジル、トリアラート/S-(2,3,3-トリクロロアリル)ジイソプロピルチオカルバメート(AVADEX BW(登録商標))、ベルノレート(例えば、ベンチオカーブ/S-(4-クロロベンジル)-N,N-ジエチルチオ-カルバメート(SATURN(登録商標)、BOLERO(登録商標))、2-クロロアリルジエチルジチオカルバメート(CDEC)(VEGADEX(登録商標))、ベンタゾン/ベンタゾン/3-イソプロピル-2,1,3-ベンゾ-チアジアゾン-4-オン-2,2-ジオキシド(BESAGRANBSA-3510(登録商標))、またはパラチオン)、チオカーボネート除草剤(例えば、ジメキサノ、チオペルオキシ二炭酸ジエチルエステル(EXD)、またはプロキサン)、置換尿素除草剤(例えば、ベンズチアズロン、クミルロン、シクルロン、ジクロラル尿素、ジフルフェンゾピル、イソノルロン、イソウロン、メタベンズチアズロン、モニソウロン、ノルロン、メチウロン、アニスロン、ブツロン、リヌロン/3-(3,4-ジクロロフェニル)-1,メトキシ-1-メチル尿素(LOROX(登録商標))、クロルブロムロン/3-(4-ブロモ-3-クロロフェニル)-1-メトキシ-1-メチル尿素(BROMEX(登録商標))、クロレツロン、クロロトルロン、クロロスルフロン、クロロクスロン/3-(p-(p-クロロフェノキシ)フェニル)1,1-ジメチル尿素(TENORON(登録商標))、ジウロン/3-(3,4-ジクロロフェニル)ジメチル尿素(KARMEX(登録商標))、フェヌロンTCA/1,1-ジメチル-3-フェニル-尿素(ureamon)(トリクロロアセテート)(URAB(登録商標))、フルオメツロン/1,1-ジメチル-3-(a,a,a-トリフルオロm-トリル)尿素(COTORON(登録商標))、モヌロン/3(p-クロルフェニル)-1,1-ジメチル尿素(TELVAR(登録商標))、ネブロン/3,4-ジクロロフェニルブチル、メチル尿素(BONUS(登録商標))、ダイムロン、ジフェノキスロン、ジメフロン、フルオチウロン、イソプロツロン、メチウロン、メチルダイムロン、メトベンズロン、メトブロムロン、メトクスロン、モノリニュロン、パラフルロン、フェノベンズロン、シデュロン、テトラフルロン、チアジアズロン、アミドスルフロン、アジムスルフロン、ベンスルフロン、クロリムロン、シクロスルファムロン、エトキシスルフロン、フラザスルフロン、フルセトスルフロン、フルピルスルフロン、フォラムスルフロン、ハロスルフロン、イマゾスルフロン、メソスルフロン、ニコスルフロン、オキサスルフロン、ピリミスルフロン、ピラゾスルフロン、リムスルフロン、スルホメツロン、スルホスルフロン、トリフロキシスルフロン、クロルスルフロン、シノスルフロン、エタメトスルフルロン、ヨードスルフロン、メトスルフロン、プロスルフロン、チフェンスルフロン、トリアスルフロン、トリベヌロン、トリフルスルフロン、トリトスルフロン、ブチウロン、エチジムロン、テブチウロン、チアザフルロン、またはチアジアズロン)、C-288-メタゾール/2-(3,4-ジクロロフェニル)-4-メチル-1,2-4-オキサジアゾリジン-3,5-ジオン(PROBE(登録商標))、パーフルイドン/4-(フェニルスルホニル)-1,1,1-トリフロメチルスルホノ-o-トルイジド(DESTUN(登録商標))、ホスミドマイシン、アクロレイン、アリルアルコール、アザフェニジン、ベナゾリン、ベンゾビシクロン、ビチアゾール、カルシウムシアナミド(CaCN2)(DORMEX(登録商標))、カンベンジクロル、クロルフェナック、クロルフェンプロップ、クロルフルラゾール、クロルフルレノール、シンメチリン、クロマゾン、1-クロロ-N’-(3,4-ジクロロフェニル)-N,N-ジメチルメタンイミドアミド(CPMF)、クレゾール、オルト-ジクロロベンゼン、ジメピペレート、フルオロミジン、フルリドン、フルロクロリドン、フルルタモン、フルチアセット、インダノファン、イソチオシアン酸メチル、ニピラクロフェン、OCH、オキサジアルギル、オキサジクロメホン、ペンタクロロフェノール、ペントキサゾン、酢酸フェニル水銀、ピノキサデン、プロスルファリン、ピラゾキシネート、ピリベンゾキシム、ピリフタリド、キノクラミン、ロデタニル、スルグリカピン、チジアジミン、トリディファン、トリメツロン、トリプロピンダン、またはトリタックである。
[0195]実施形態では、植物生長調節剤は、抗オーキシン(例えば、クロフィブリン酸または2,3,5-トリ-ヨード安息香酸)、オーキシン(例えば、2-(4-クロロフェノキシ)酢酸(4-CPA)、2,4-ジクロロフェノキシ酢酸(2,4-D)、4-(2,4-ジクロロフェノキシ)酪酸(2,4-DB)、2,4-DEP、ジクロプロプ、フェノプロップ、インドール-3-酢酸(IAA)、インドール-3-酪酸(IBA)、ナフタレンアセトアミド、α-ナフタレン酢酸、1-ナフトール、ナフトキシ酢酸、ナフテン酸カリウム、ナフテン酸ナトリウム、または2,4,5-トリクロロフェノキシ酢酸(2,4,5-T))、サイトカイニン(例えば、2iP、ベンジルアデニン、キネチン、またはゼアチン)、枯葉剤(例えば、カルシウムシアナミド、ジメチピン、エンドタール、エテホン、メトクスロン、ペンタクロロフェノール、チアジアズロン、またはトリブホス)、エチレン阻害剤(例えば、アビグリシンまたは1-メチルシクロプロペン)、エチレン放出薬(例えば、1-アミノシクロプロパン-1-カルボン酸(ACC)、エタセラシル、エテホン、またはグリオキシム)、ジベレリン(例えば、ジベレリン酸)、成長阻害剤(例えば、アブシジン酸、アンシミドール、ブトラリン、カルバリル、クロルホニウム、クロルプロファム、ジケグラック、フルメトラリン、フルオリダミド、ホサミン、グリホシン、イソピリモール、ジャスモン酸、マレイン酸ヒドラジド、塩化メピクアット、ピプロクタニル、プロヒドロジャスモン、プロファム、2,3,5-トリ-ヨード安息香酸、モルファクチン(例えば、クロルフルレン、クロルフルレノール、ジクロルフルレノール、またはフルレノール)、成長遅延剤(例えば、塩化クロルメクワット(CYCOCEL(登録商標))、ダミノジド(B-NINE(登録商標))、フルルピリミドール、メフルイジド、パクロブトラゾール、テトシクラシス、またはウニコナゾール)、成長刺激物質(例えば、ブラシノリド、ホルクロルフェヌロン、またはヒメキサゾール)、ベンゾフルオル、ブミナホス、カルボン、シオブチド、クロフェンセット、クロキシホナック、シクラニリド、シクロヘキシミド、エポコレオン、エチクロゼート、エチレン、フェンリダゾン、ヘプトパルギル、ホロスルフ、イナベンフィド、カレタザン、砒酸鉛、メタスルホカルブ、プロヘキサジオン、ピダノン、シントフェン、トリアペンテノール、またはトリネキサパックである。
メチル、ブタチオホス、ジアジノン、エトリムホス、リリンホス、ピリミホス-エチル、ピリミホス-メチル、プリミドホス、ピリミテート、テブピリムホス、キナルホス、キナルホス-メチル、アチダチオン、リチダチオン、メチダチオン、プロチダチオン、イサゾホス、トリアゾホス、アゾトエート、ブロモホス、ブロモホス-エチル、カルボフェノチオン、クロルチオホス、シアノホス、シチオアート、ジカプトン、ジクロフェンチオン、エタホス、ファンファー、フェンクロルホス、フェニトロチオン、フェンスルホチオン、フェンチオン、フェンチオン-エチル、ヘテロホス、ジョードフェンホス、メスルフェンホス、パラチオン、パラチオン-メチル、フェンカプトン、ホスニクロル、プロフェノホス、プロチオホス、スルプロホス、テメホス、トリクロルメタホス-3、トリフェノホス、ブトネート、トリクロルホン、メカルホン、ホノホス、トリクロロナート、シアノフェンホス、O-エチルO-(4-ニトロフェニル)フェニルホスホノチオエート(EPN)、レプトホス、クルホメート、フェナミホス、ホスチエタン、メホスホラン、ホスホラン、ピリメタホス、アセフェート(ORTHENE(登録商標))、イソカルボホス、イソフェンホス、メタミドホス、プロペタンホス、ジメホックス、マジドックス、ミパフォックス、オキサジアジン殺虫剤、またはインドキサカルブ)、フタルイミド殺虫剤(例えば、ジアリホス、フォスメット、またはテトラメトリン)、ピラゾール殺虫剤(例えば、アセトプロール、エチプロール、フィプロニル、テブフェンピラド、トルフェンピラド、またはバニリプロール)、ピレスロイド殺虫剤(例えば、アクリナトリン、アレスリン(例えば、ビオアレトリン)、バルトリン、ビフェントリン、ビオエタノメチリン、シクレトリン、シクロプロトリン、シフルスリン(例えば、β-シフルスリン)、シハロトリン(例えば、ガンマ-シハロトリンまたはラムダ-シハロトリン)、シペルメトリン(例えば、アルファ-シペルメトリン、β-シペルメトリン、シータ-シペルメトリン、またはゼータ-シペルメトリン)、シフェノトリン、デルタメトリン、ジメフルトリン、ジメトリン、エンペントリン、フェンフルトリン、フェンピリトリン、フェンプロパトリン、フェンバレレート(例えば、エスフェンバレレート)、フルシトリネート、フルバリネート(例えば、タウ-フルバリネート(MAVRIK(登録商標)))、フレスリン、イミプロトリン、メトフルトリン、ペルメトリン(例えば、ビオペルメトリンまたはトランスペルメトリン)、フェノトリン、パレトリン、プロフルトリン、ピレスメトリン、レスメトリン(例えば、ビオレスメトリンまたはシスメトリン)、テフルトリン、テラレスリン、テトラメトリン、トラロメトリン、トランスフルトリン、エトフェンプロクス、フルフェンプロックス、ハルフェンプロックス、プロトリフェンビュート、またはシラフルオフェン(silafluofe))、ピリミジンアミン殺虫剤(例えば、フルフェネリムまたはピリミジフェン)、ピロール殺虫剤(例えば、クロルフェナピル)、テトロン酸殺虫剤(例えば、スピロメシフェン)、チオ尿素殺虫剤(例えば、ジアフェンチウロン、尿素殺虫剤、フルコフロン、またはスルコフロン)、クロサンテル、クロタミトン、チオペルオキシ二炭酸ジエチルエステル(EXD)、フェナザフロル、フェノキサクリム、ヒドラメチルノン、イソプロチオラン、マロノベン、メトキサジアゾン、ニフルリジド、ピリダベン、ピリダリル、ラフォキサニド、トリアラテン、トリアザメート、フルオロシリケート、レタン、タナイト、リン化マグネシウム(DETIA GAS-EX-B-FORTE(登録商標))、イミダクロプリド(ADMIRE(登録商標)、MARATHON(登録商標)、RAXIL SECUR(登録商標))、殺虫性石鹸(M-PEDE(登録商標)、SAFER SOAP(登録商標))、またはキノメチオネート(MORESTAN(登録商標))である。
[0201]実施形態では、殺鼠剤は、インダンジオン殺鼠剤(例えば、クロロファシノン、ダイファシノン、またはピンドン)、有機リン殺鼠剤(例えば、ホサセチム)、ピリミジンアミン殺鼠剤(例えば、クリミジン)、γ-グルタミル-カルボキシラーゼ阻害剤(クマリン殺鼠剤)(例えば、ブロジファクム、ブロマジオロン、クマクロル、クマフリル、クマテトラリル、ジフェナクム、ジフェチアロン、フロクマフェン、またはワルファリン)、アコニターゼ阻害剤(例えば、フルオロアセトアミド(fluoracetamide)またはフルオロ酢酸ナトリウム)、無機殺鼠剤(例えば、リン化アルミニウム(CELPHOS(登録商標)、DEGESCH FUMIGATION TABLETS(登録商標)、FUMITOXIN(登録商標))、亜ヒ酸化物、白色または黄色の元素のリン、亜ヒ酸カリウム、亜ヒ酸ナトリウム、または硫酸タリウム)、チオ尿素殺鼠剤(例えば、α-ナフチルチオ尿素(ANTU)(ANTU(登録商標)))、尿素殺鼠剤(例えば、ピリヌロン)、燻蒸剤(例えば、カルシウムシアニド(CaCN2)(CYMAG(登録商標))、一酸化炭素(CO)、二酸化炭素(CO2)、ペトロールクロロホルム、四塩化炭素(CCl4)、ジクロロエタン、二臭化エチレン、ジブロモクロロプロパン、臭化メチル、EDTC混合物、ガンマ-ヘキサクロロシクロヘキサン(ガンマ-HCH)、HC、リンデン、GABAアンタゴニスト(例えば、テトラミン(テトラメチレンジスルホテトラアミン))、電圧ゲーティングしたナトリウムチャネル阻害剤(例えば、ジクロロジフェニルトリクロロエタン(DDT))、ブロメタリン、クロラロース、α-クロロヒドリン、エルゴカルシフェロール、フルプロパジン、シアン化水素、またはノルボミド(RATICATE(登録商標))である。
[0203]実施形態では、摂食阻害剤は、クロルジメホルム、フェンチン、グアザチン、またはピメトロジンである。
[0231]実施形態では、殺生物剤は、イソチアゾリノン、ホルムアルデヒド、およびブチル化ヒドロキシトルエンからなる群から選択される。
[0233]実施形態では、封入された懸濁液を作製する方法であって、水中にポリマー分散剤を含む水性混合物を準備するステップと、水性混合物に、有機溶媒中に農業用薬剤およびポリイソシアネートを含む有機混合物を添加するステップと、水性混合物中の有機混合物を所望の粒径エマルジョンへと乳化するステップと、架橋剤をエマルジョンに添加して、封入された農業用薬剤を得るステップと、ミクロフィブリル化セルロースを含む少なくとも1種のレオロジー改質剤を、封入された農業用薬剤に添加して、安定した懸濁液を形成するステップとを含む方法が提供される。
[0235]実施形態では、農業用薬剤はクロレトキシホスとビフェントリンの混合物を含む。
[0237]実施形態では、方法は、エタノールアミン、トリエタノール、アミン、櫛型アクリルポリマー分散剤、アクリルポリマーまたはこれらの組合せを添加することをさらに含んでもよい。
[0241]実施形態では、ポリイソシアネートは、ポリ(フェニルイソシアネート)-co-ホルムアルデヒド、テトラメチレンジイソシアネート、ペンタメチレンジイソシアネート、ヘキサメチレンジイソシアネート、トルエンジイソシアネート、ジフェニルメテン-4,4’-ジイソシアネート、ポリメチレンポリフェニレンイソシアネート、2,4,4’-ジフェニルエーテルトリイソシアネート、3,3’-ジメチル-4,4’-ジフェニルジイソシアネート、3,3’-ジメトキシ-4,4’-ジフェニルジイソシアネート、1,5-ナフチレンジイソシアネートおよび4,4’4”-トリフェニルメタントリイソシアネートから選択される。
[0243]実施形態では、架橋剤はポリアミンを含む。
[0246]実施形態では、本明細書の実施形態は、封入された懸濁液を作製する方法であって、水中にポリマー分散剤を含む水性混合物を準備するステップと、水性混合物に、有機溶媒中の農業用薬剤およびポリイソシアネートを含む有機混合物を添加するステップと、水性混合物中で有機混合物を所望の粒径エマルジョンに乳化するステップと、架橋剤をエマルジョンに添加して、封入された殺有害生物剤を得るステップと、ミクロフィブリル化セルロースを含む少なくとも1種のレオロジー改質剤を、封入された殺有害生物剤に添加して、安定した懸濁液を形成するステップとを含む方法を提供する。
[0252]実施形態では、作物を処理する方法であって、微粒子形態の農業用薬剤、およびミクロフィブリル化セルロースを含む組成物を準備するステップであって、微粒子形態が液滴、ゲル、またはこれらの組合せからなる群から選択され、微粒子形態の農業用薬剤が、乳化可能な濃縮物(EC)、カプセル懸濁液(CS)、サスポエマルジョン(SE)、マイクロエマルジョン(ME)、または油分散液(OD)の一部であるステップと、組成物に、肥料および/または水を添加して、混合物を得るステップと、混合物を作物に施用するステップとを含む方法が提供される。
[0254]実施形態では、方法は土壌施用に施用することができる。
[0255]実施形態では、方法は根施用に施用することができる。
実施例1
[0256]以下の実施例は、ウェスタン、ノザン、およびサザンコーンルートワーム;ハリガネムシ、ネキリムシ、タネバエ、地虫、サトウキビビートル、グレープコラスピス(grape colapse)およびコムカデの防除に対して定植のトウモロコシ(飼料用トウモロコシ、種トウモロコシ、スウィートトウモロコシおよびポップコーン)で使用することができる液体殺土壌昆虫剤である。この例示的懸濁液はクロレトキシホス(25.8パーセント)およびビフェントリン(4.2%)を活性成分として含有し、カプセル懸濁液タイプの製剤である。当業者により認識されているように、他の殺有害生物剤および活性成分で容易に置き換え可能である。
[0258]A.Fortress Technical
活性成分1の登録番号:EPA Reg.No.5481-492
化学名:(±)-O,O-ジエチルO-(1,2,2,2-テトラクロロエチル)ホスホロチオエート
一般名称:クロレトキシホス
CAS No.54593-83-8
設定濃度:88%
[0259]B.Bifenthrin Technical
活性成分2の登録番号:EPA Reg.NO5481-505
化学名:3-[(1Z)-2-クロロ-3,3,3-トリフルオロ-1-プロペニル]-2,2-ジメチルシクロプロパンカルボン酸(2-メチルビフェニル-3-イル)メチルエステル
一般名称:ビフェントリン
CAS NO.82657-04-3
設定濃度:96.2%
[0260]C. Water
CAS NO.7732-18-5
[0261]D. Aromatic 200
化学名:溶媒ナフサ(石油)、Heavy Aromatic Trade Name:Aromatic 200 ND
CAS NO.64742-94-5
[0262]E.モノエタノールアミン
一般名称:エタノールアミン
CAS NO.141-43-5
[0263]F.1,2-プロパンジオール
CAS NO.57-55-6
商標名:プロピレングリコール
[0264]G.Envi-Pol871
化学名:Envi-Pol 871
CAS NO.独自仕様のブレンド
[0265]H.Proxel(商標)GXL
CAS NO.2634-33-5
追加情報:Proxel GXLは19.3%溶液であり、よって公称は0.048%w/wの1,2-ベンズイソチアゾリン-3-オンと等しい
[0266]I.Xiameter AFE-0010
CAS NO.独自仕様のブレンド
[0267]J.セルロース
化学名:Exilva(10%ペースト)
CAS NO.9004-34-6
[0268]K.キサンタンガム
CAS NO.11138-66-2
商標名:Kelzan S Plus
[0269]L.架橋ポリ尿素タイプの封入ポリマー
製剤の混合中に形成されるポリマー
[0270]製剤手順は以下の通りである:
[0271]乳化アセンブリーを備えた高速ミキサーを有するタンク内で:
[0272]1.適量の水相を添加する。
[0274]3.所望の粒径が得られるまで混合物を乳化する。
[0275]4.パドル混合アセンブリーを使用して、適当な成分を添加して、界面重合を完了する。
[0277]前述の発明は、明確な理解のため、例示および実施例によりいくらか詳細に記載されているが、当業者であれば、ある特定の変化および修正が添付の特許請求の範囲内で実施され得ることは認識している。加えて、本明細書に提供されている各参考文献は、まるで各参考文献が個々に参照により組み込まれているのと同程度に、その全体が参照により組み込まれている。本出願と、本明細書に提供されている参考文献との間に矛盾が存在する場合、本出願が優先されるものとする。
Claims (22)
- 組成物であって、
液相中のクロレトキシホスとビフェントリンの混合物のカプセル懸濁液(CS)であって、前記混合物が封入壁内に配置されている、前記カプセル懸濁液(CS)、
ポリマー分散剤、および
ミクロフィブリル化セルロース、ならびに場合によってエタノールアミン
を含む、前記組成物。 - 前記封入壁がポリ尿素を含む、請求項1に記載の組成物。
- 前記液相が水を含む、請求項1に記載の組成物。
- エタノールアミンをさらに含む、請求項1に記載の組成物。
- 組成物であって
微粒子形態の農業用薬剤、および
ミクロフィブリル化セルロース
を含み、
前記微粒子形態が、液滴、ゲル、またはこれらの組合せからなる群から選択され、
前記微粒子形態の農業用薬剤が、乳化可能な濃縮物(EC)、カプセル懸濁液(CS)、サスポエマルジョン(SE)、マイクロエマルジョン(ME)、または油分散液(OD)の一部である、前記組成物。 - 固体微粒子をさらに含む、請求項5に記載の組成物。
- ポリマー分散剤をさらに含む、請求項5に記載の組成物。
- 前記ミクロフィブリル化セルロースが、湿潤剤または分散剤で前処理されており、剪断条件の対象下におかれる、請求項5に記載の組成物。
- 前記農業用薬剤が、殺有害生物剤、生物学的殺有害生物剤、除草剤、殺虫剤、植物生長調節剤、バイオスティミュラント、UV保護剤、防塵剤、ホルモン、肥料、微量栄養素のうちの1種もしくは複数またはこれらの組合せを含む、請求項5に記載の組成物。
- 前記固体微粒子、メタミクト状態微粒子、またはこれらの組合せが、殺有害生物剤、生物学的殺有害生物剤、除草剤、殺虫剤、植物生長調節剤、バイオスティミュラント、UV保護剤、防塵剤、ホルモン、肥料、微量栄養素のうちの1種もしくは複数またはこれらの組合せを含む、請求項6に記載の組成物。
- 前記農業用薬剤がクロレトキシホスを含む、請求項5に記載の組成物。
- 前記農業用薬剤がビフェントリンを含む、請求項5または11に記載の組成物。
- 前記農業用薬剤が、前記組成物の約0.1重量%~約60重量%の量で存在する、請求項5に記載の組成物。
- 前記ミクロフィブリル化セルロースが、前記組成物の約0.01乾燥重量%~約5乾燥重量%の量で存在する、請求項5に記載の組成物。
- アニオン性ポリマー分散剤、リグノスルホネート、アルキルホルムアルデヒド凝縮物、非イオン性ポリマー分散剤、ポリビニルアルコール、アクリルコポリマー、および櫛型アクリル分散剤からなる群から選択されるポリマー分散剤をさらに含む、請求項5に記載の組成物。
- 前記農業用薬剤がカプセル懸濁液の一部である場合、前記ポリマー分散剤が櫛型アクリルポリマー分散剤である、請求項15に記載の組成物。
- 前記ポリマー分散剤がアニオン性アクリルポリマーである、請求項15に記載の組成物。
- 追加のレオロジー改質剤をさらに含む、請求項5に記載の組成物。
- 前記レオロジー改質剤が、多糖、キサンタンガム、グアーガム、ローカストガム、粘土、シリカ、デンプン、rheo界面活性剤、およびこれらの混合物からなる群から選択される、請求項18に記載の組成物。
- 前記レオロジー改質剤が、前記懸濁液の約0.01重量%~約5重量%の量で存在する、請求項19に記載の組成物。
- エタノールアミンをさらに含む、請求項5に記載の組成物。
- 作物を処理する方法であって、
微粒子形態の農業用薬剤、および
ミクロフィブリル化セルロース
を含む組成物を準備するステップであって、
前記微粒子形態が、液滴、ゲル、またはこれらの組合せからなる群から選択され、
前記微粒子形態の農業用薬剤が、乳化可能な濃縮物(EC)、カプセル懸濁液(CS)、サスポエマルジョン(SE)、マイクロエマルジョン(ME)、または油分散液(OD)の一部である、前記ステップと、
前記組成物に、肥料および/または水を添加して、混合物を得るステップと、
前記混合物を作物に施用するステップと
を含む、前記方法。
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