JP2022185658A - 絶縁シート及びその製造方法、並びに回転電機 - Google Patents
絶縁シート及びその製造方法、並びに回転電機 Download PDFInfo
- Publication number
- JP2022185658A JP2022185658A JP2021093416A JP2021093416A JP2022185658A JP 2022185658 A JP2022185658 A JP 2022185658A JP 2021093416 A JP2021093416 A JP 2021093416A JP 2021093416 A JP2021093416 A JP 2021093416A JP 2022185658 A JP2022185658 A JP 2022185658A
- Authority
- JP
- Japan
- Prior art keywords
- insulating
- resin layer
- thermosetting resin
- insulating sheet
- insulating resin
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 238000009413 insulation Methods 0.000 title claims abstract description 24
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 24
- 238000000034 method Methods 0.000 title claims abstract description 18
- 229920005989 resin Polymers 0.000 claims abstract description 410
- 239000011347 resin Substances 0.000 claims abstract description 410
- 229920001187 thermosetting polymer Polymers 0.000 claims abstract description 198
- 239000000463 material Substances 0.000 claims abstract description 94
- 239000011342 resin composition Substances 0.000 claims abstract description 92
- 239000007788 liquid Substances 0.000 claims abstract description 23
- 239000007787 solid Substances 0.000 claims abstract description 18
- 239000004745 nonwoven fabric Substances 0.000 claims abstract description 15
- 239000004744 fabric Substances 0.000 claims abstract description 14
- 239000000123 paper Substances 0.000 claims description 71
- 239000002245 particle Substances 0.000 claims description 56
- 239000011256 inorganic filler Substances 0.000 claims description 51
- 229910003475 inorganic filler Inorganic materials 0.000 claims description 51
- 239000000758 substrate Substances 0.000 claims description 45
- 239000003795 chemical substances by application Substances 0.000 claims description 38
- 239000000853 adhesive Substances 0.000 claims description 28
- 230000001070 adhesive effect Effects 0.000 claims description 28
- 239000003822 epoxy resin Substances 0.000 claims description 28
- 229920000647 polyepoxide Polymers 0.000 claims description 28
- 239000004760 aramid Substances 0.000 claims description 26
- 229920003235 aromatic polyamide Polymers 0.000 claims description 26
- 239000002002 slurry Substances 0.000 claims description 26
- 238000005520 cutting process Methods 0.000 claims description 25
- 238000002844 melting Methods 0.000 claims description 25
- 230000008018 melting Effects 0.000 claims description 25
- 238000003860 storage Methods 0.000 claims description 25
- 238000005452 bending Methods 0.000 claims description 20
- 238000001035 drying Methods 0.000 claims description 18
- 229920005992 thermoplastic resin Polymers 0.000 claims description 12
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 10
- 230000008569 process Effects 0.000 claims description 8
- 229920006337 unsaturated polyester resin Polymers 0.000 claims description 7
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims description 6
- 229920006351 engineering plastic Polymers 0.000 claims description 5
- 239000003960 organic solvent Substances 0.000 claims description 5
- QGBSISYHAICWAH-UHFFFAOYSA-N dicyandiamide Chemical compound NC(N)=NC#N QGBSISYHAICWAH-UHFFFAOYSA-N 0.000 claims description 4
- 238000010790 dilution Methods 0.000 claims description 4
- 239000012895 dilution Substances 0.000 claims description 4
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical group [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 claims description 3
- 229910052796 boron Inorganic materials 0.000 claims description 3
- 239000005011 phenolic resin Substances 0.000 claims description 3
- 239000000377 silicon dioxide Substances 0.000 claims description 3
- 238000002788 crimping Methods 0.000 claims description 2
- 239000002655 kraft paper Substances 0.000 claims description 2
- 150000007524 organic acids Chemical class 0.000 claims description 2
- 229920001568 phenolic resin Polymers 0.000 claims description 2
- KXGFMDJXCMQABM-UHFFFAOYSA-N 2-methoxy-6-methylphenol Chemical compound [CH]OC1=CC=CC([CH])=C1O KXGFMDJXCMQABM-UHFFFAOYSA-N 0.000 claims 1
- 238000010030 laminating Methods 0.000 claims 1
- 230000002093 peripheral effect Effects 0.000 claims 1
- 230000017525 heat dissipation Effects 0.000 abstract description 15
- 239000010410 layer Substances 0.000 description 242
- 238000001723 curing Methods 0.000 description 93
- 230000000052 comparative effect Effects 0.000 description 35
- 238000010438 heat treatment Methods 0.000 description 31
- 238000012545 processing Methods 0.000 description 25
- 239000002131 composite material Substances 0.000 description 24
- 238000006243 chemical reaction Methods 0.000 description 23
- 239000011148 porous material Substances 0.000 description 20
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical group [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 17
- -1 polyethylene naphthalate Polymers 0.000 description 17
- 239000003085 diluting agent Substances 0.000 description 16
- LNEPOXFFQSENCJ-UHFFFAOYSA-N haloperidol Chemical compound C1CC(O)(C=2C=CC(Cl)=CC=2)CCN1CCCC(=O)C1=CC=C(F)C=C1 LNEPOXFFQSENCJ-UHFFFAOYSA-N 0.000 description 15
- 239000004642 Polyimide Substances 0.000 description 14
- IISBACLAFKSPIT-UHFFFAOYSA-N bisphenol A Chemical compound C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 IISBACLAFKSPIT-UHFFFAOYSA-N 0.000 description 14
- 238000000465 moulding Methods 0.000 description 14
- 229920001721 polyimide Polymers 0.000 description 14
- 230000007423 decrease Effects 0.000 description 13
- 239000011248 coating agent Substances 0.000 description 12
- 150000001451 organic peroxides Chemical class 0.000 description 12
- 238000000576 coating method Methods 0.000 description 11
- 230000000694 effects Effects 0.000 description 11
- 239000000945 filler Substances 0.000 description 11
- 239000000203 mixture Substances 0.000 description 11
- 230000000977 initiatory effect Effects 0.000 description 10
- 238000012360 testing method Methods 0.000 description 10
- 238000011049 filling Methods 0.000 description 9
- 239000011810 insulating material Substances 0.000 description 9
- 238000002156 mixing Methods 0.000 description 9
- 230000015556 catabolic process Effects 0.000 description 8
- 230000008859 change Effects 0.000 description 8
- 238000010586 diagram Methods 0.000 description 7
- 238000011156 evaluation Methods 0.000 description 7
- 239000002994 raw material Substances 0.000 description 7
- 239000002966 varnish Substances 0.000 description 7
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 6
- VCUFZILGIRCDQQ-KRWDZBQOSA-N N-[[(5S)-2-oxo-3-(2-oxo-3H-1,3-benzoxazol-6-yl)-1,3-oxazolidin-5-yl]methyl]-2-[[3-(trifluoromethoxy)phenyl]methylamino]pyrimidine-5-carboxamide Chemical compound O=C1O[C@H](CN1C1=CC2=C(NC(O2)=O)C=C1)CNC(=O)C=1C=NC(=NC=1)NCC1=CC(=CC=C1)OC(F)(F)F VCUFZILGIRCDQQ-KRWDZBQOSA-N 0.000 description 6
- 230000006866 deterioration Effects 0.000 description 6
- 229920003986 novolac Polymers 0.000 description 6
- 230000000704 physical effect Effects 0.000 description 6
- 238000005336 cracking Methods 0.000 description 5
- 238000005259 measurement Methods 0.000 description 5
- 238000006116 polymerization reaction Methods 0.000 description 5
- 239000000047 product Substances 0.000 description 5
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 description 4
- 239000004593 Epoxy Substances 0.000 description 4
- 229910000831 Steel Inorganic materials 0.000 description 4
- 238000004090 dissolution Methods 0.000 description 4
- 238000001879 gelation Methods 0.000 description 4
- 229920001225 polyester resin Polymers 0.000 description 4
- 239000004645 polyester resin Substances 0.000 description 4
- 239000002904 solvent Substances 0.000 description 4
- 239000010959 steel Substances 0.000 description 4
- 238000003756 stirring Methods 0.000 description 4
- 229920001567 vinyl ester resin Polymers 0.000 description 4
- ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 description 3
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
- 229930185605 Bisphenol Natural products 0.000 description 3
- CPLXHLVBOLITMK-UHFFFAOYSA-N Magnesium oxide Chemical compound [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 description 3
- 239000004734 Polyphenylene sulfide Substances 0.000 description 3
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
- PXKLMJQFEQBVLD-UHFFFAOYSA-N bisphenol F Chemical class C1=CC(O)=CC=C1CC1=CC=C(O)C=C1 PXKLMJQFEQBVLD-UHFFFAOYSA-N 0.000 description 3
- WTEOIRVLGSZEPR-UHFFFAOYSA-N boron trifluoride Chemical compound FB(F)F WTEOIRVLGSZEPR-UHFFFAOYSA-N 0.000 description 3
- 229910000019 calcium carbonate Inorganic materials 0.000 description 3
- 239000012466 permeate Substances 0.000 description 3
- 150000002989 phenols Chemical class 0.000 description 3
- 229920006287 phenoxy resin Polymers 0.000 description 3
- 239000013034 phenoxy resin Substances 0.000 description 3
- 229920003207 poly(ethylene-2,6-naphthalate) Polymers 0.000 description 3
- 239000011112 polyethylene naphthalate Substances 0.000 description 3
- 229920000069 polyphenylene sulfide Polymers 0.000 description 3
- 239000000843 powder Substances 0.000 description 3
- 229920002554 vinyl polymer Polymers 0.000 description 3
- 239000011800 void material Substances 0.000 description 3
- 238000004804 winding Methods 0.000 description 3
- AHDSRXYHVZECER-UHFFFAOYSA-N 2,4,6-tris[(dimethylamino)methyl]phenol Chemical compound CN(C)CC1=CC(CN(C)C)=C(O)C(CN(C)C)=C1 AHDSRXYHVZECER-UHFFFAOYSA-N 0.000 description 2
- YAQDPWONDFRAHF-UHFFFAOYSA-N 2-methyl-2-(2-methylpentan-2-ylperoxy)pentane Chemical compound CCCC(C)(C)OOC(C)(C)CCC YAQDPWONDFRAHF-UHFFFAOYSA-N 0.000 description 2
- QTWJRLJHJPIABL-UHFFFAOYSA-N 2-methylphenol;3-methylphenol;4-methylphenol Chemical compound CC1=CC=C(O)C=C1.CC1=CC=CC(O)=C1.CC1=CC=CC=C1O QTWJRLJHJPIABL-UHFFFAOYSA-N 0.000 description 2
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 2
- 229910015900 BF3 Inorganic materials 0.000 description 2
- 241000510672 Cuminum Species 0.000 description 2
- 235000007129 Cuminum cyminum Nutrition 0.000 description 2
- MQJKPEGWNLWLTK-UHFFFAOYSA-N Dapsone Chemical compound C1=CC(N)=CC=C1S(=O)(=O)C1=CC=C(N)C=C1 MQJKPEGWNLWLTK-UHFFFAOYSA-N 0.000 description 2
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 2
- 239000002033 PVDF binder Substances 0.000 description 2
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 2
- 239000004695 Polyether sulfone Substances 0.000 description 2
- 239000004721 Polyphenylene oxide Substances 0.000 description 2
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 2
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 2
- 229920002978 Vinylon Polymers 0.000 description 2
- 230000001133 acceleration Effects 0.000 description 2
- DHKHKXVYLBGOIT-UHFFFAOYSA-N acetaldehyde Diethyl Acetal Natural products CCOC(C)OCC DHKHKXVYLBGOIT-UHFFFAOYSA-N 0.000 description 2
- 229920000122 acrylonitrile butadiene styrene Polymers 0.000 description 2
- 230000004913 activation Effects 0.000 description 2
- 230000002411 adverse Effects 0.000 description 2
- 125000002723 alicyclic group Chemical group 0.000 description 2
- 150000001412 amines Chemical class 0.000 description 2
- 150000004984 aromatic diamines Chemical class 0.000 description 2
- TZCXTZWJZNENPQ-UHFFFAOYSA-L barium sulfate Chemical compound [Ba+2].[O-]S([O-])(=O)=O TZCXTZWJZNENPQ-UHFFFAOYSA-L 0.000 description 2
- 239000004841 bisphenol A epoxy resin Substances 0.000 description 2
- 239000004842 bisphenol F epoxy resin Substances 0.000 description 2
- 239000002981 blocking agent Substances 0.000 description 2
- 238000007906 compression Methods 0.000 description 2
- 230000006835 compression Effects 0.000 description 2
- 238000011109 contamination Methods 0.000 description 2
- 239000007822 coupling agent Substances 0.000 description 2
- 229930003836 cresol Natural products 0.000 description 2
- 229910002026 crystalline silica Inorganic materials 0.000 description 2
- 230000002542 deteriorative effect Effects 0.000 description 2
- ZUOUZKKEUPVFJK-UHFFFAOYSA-N diphenyl Chemical compound C1=CC=CC=C1C1=CC=CC=C1 ZUOUZKKEUPVFJK-UHFFFAOYSA-N 0.000 description 2
- 238000009826 distribution Methods 0.000 description 2
- 229920001971 elastomer Polymers 0.000 description 2
- 238000009472 formulation Methods 0.000 description 2
- 239000005350 fused silica glass Substances 0.000 description 2
- 239000011521 glass Substances 0.000 description 2
- 150000002460 imidazoles Chemical class 0.000 description 2
- 238000005470 impregnation Methods 0.000 description 2
- 230000006698 induction Effects 0.000 description 2
- 230000007774 longterm Effects 0.000 description 2
- 239000000395 magnesium oxide Substances 0.000 description 2
- 230000003287 optical effect Effects 0.000 description 2
- 230000035515 penetration Effects 0.000 description 2
- 230000035699 permeability Effects 0.000 description 2
- 150000002978 peroxides Chemical class 0.000 description 2
- 229920002037 poly(vinyl butyral) polymer Polymers 0.000 description 2
- 229920006122 polyamide resin Polymers 0.000 description 2
- 229920001707 polybutylene terephthalate Polymers 0.000 description 2
- 229920000728 polyester Polymers 0.000 description 2
- 229920000570 polyether Polymers 0.000 description 2
- 229920006393 polyether sulfone Polymers 0.000 description 2
- 229920000139 polyethylene terephthalate Polymers 0.000 description 2
- 239000005020 polyethylene terephthalate Substances 0.000 description 2
- 229920000642 polymer Polymers 0.000 description 2
- 229920006324 polyoxymethylene Polymers 0.000 description 2
- 229920002981 polyvinylidene fluoride Polymers 0.000 description 2
- 238000004062 sedimentation Methods 0.000 description 2
- 238000000926 separation method Methods 0.000 description 2
- 235000012239 silicon dioxide Nutrition 0.000 description 2
- 229920002050 silicone resin Polymers 0.000 description 2
- 125000000999 tert-butyl group Chemical group [H]C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 description 2
- 229920001169 thermoplastic Polymers 0.000 description 2
- 239000004416 thermosoftening plastic Substances 0.000 description 2
- FAQYAMRNWDIXMY-UHFFFAOYSA-N trichloroborane Chemical compound ClB(Cl)Cl FAQYAMRNWDIXMY-UHFFFAOYSA-N 0.000 description 2
- ARCGXLSVLAOJQL-UHFFFAOYSA-N trimellitic acid Chemical compound OC(=O)C1=CC=C(C(O)=O)C(C(O)=O)=C1 ARCGXLSVLAOJQL-UHFFFAOYSA-N 0.000 description 2
- NIDNOXCRFUCAKQ-RNGGSSJXSA-N (1r,2r,3s,4s)-bicyclo[2.2.1]hept-5-ene-2,3-dicarboxylic acid Chemical compound C1[C@@H]2C=C[C@H]1[C@H](C(=O)O)[C@@H]2C(O)=O NIDNOXCRFUCAKQ-RNGGSSJXSA-N 0.000 description 1
- QEQBMZQFDDDTPN-UHFFFAOYSA-N (2-methylpropan-2-yl)oxy benzenecarboperoxoate Chemical compound CC(C)(C)OOOC(=O)C1=CC=CC=C1 QEQBMZQFDDDTPN-UHFFFAOYSA-N 0.000 description 1
- WYTZZXDRDKSJID-UHFFFAOYSA-N (3-aminopropyl)triethoxysilane Chemical compound CCO[Si](OCC)(OCC)CCCN WYTZZXDRDKSJID-UHFFFAOYSA-N 0.000 description 1
- RIPYNJLMMFGZSX-UHFFFAOYSA-N (5-benzoylperoxy-2,5-dimethylhexan-2-yl) benzenecarboperoxoate Chemical compound C=1C=CC=CC=1C(=O)OOC(C)(C)CCC(C)(C)OOC(=O)C1=CC=CC=C1 RIPYNJLMMFGZSX-UHFFFAOYSA-N 0.000 description 1
- BLKRGXCGFRXRNQ-SNAWJCMRSA-N (z)-3-carbonoperoxoyl-4,4-dimethylpent-2-enoic acid Chemical compound OC(=O)/C=C(C(C)(C)C)\C(=O)OO BLKRGXCGFRXRNQ-SNAWJCMRSA-N 0.000 description 1
- FYRCDEARNUVZRG-UHFFFAOYSA-N 1,1,5-trimethyl-3,3-bis(2-methylpentan-2-ylperoxy)cyclohexane Chemical compound CCCC(C)(C)OOC1(OOC(C)(C)CCC)CC(C)CC(C)(C)C1 FYRCDEARNUVZRG-UHFFFAOYSA-N 0.000 description 1
- VBQCFYPTKHCPGI-UHFFFAOYSA-N 1,1-bis(2-methylpentan-2-ylperoxy)cyclohexane Chemical compound CCCC(C)(C)OOC1(OOC(C)(C)CCC)CCCCC1 VBQCFYPTKHCPGI-UHFFFAOYSA-N 0.000 description 1
- VTEYUPDBOLSXCD-UHFFFAOYSA-N 1,1-bis(tert-butylperoxy)-2-methylcyclohexane Chemical compound CC1CCCCC1(OOC(C)(C)C)OOC(C)(C)C VTEYUPDBOLSXCD-UHFFFAOYSA-N 0.000 description 1
- HSLFISVKRDQEBY-UHFFFAOYSA-N 1,1-bis(tert-butylperoxy)cyclohexane Chemical compound CC(C)(C)OOC1(OOC(C)(C)C)CCCCC1 HSLFISVKRDQEBY-UHFFFAOYSA-N 0.000 description 1
- BEQKKZICTDFVMG-UHFFFAOYSA-N 1,2,3,4,6-pentaoxepane-5,7-dione Chemical compound O=C1OOOOC(=O)O1 BEQKKZICTDFVMG-UHFFFAOYSA-N 0.000 description 1
- SSUJUUNLZQVZMO-UHFFFAOYSA-N 1,2,3,4,8,9,10,10a-octahydropyrimido[1,2-a]azepine Chemical compound C1CCC=CN2CCCNC21 SSUJUUNLZQVZMO-UHFFFAOYSA-N 0.000 description 1
- XSZYESUNPWGWFQ-UHFFFAOYSA-N 1-(2-hydroperoxypropan-2-yl)-4-methylcyclohexane Chemical compound CC1CCC(C(C)(C)OO)CC1 XSZYESUNPWGWFQ-UHFFFAOYSA-N 0.000 description 1
- SEULWJSKCVACTH-UHFFFAOYSA-N 1-phenylimidazole Chemical compound C1=NC=CN1C1=CC=CC=C1 SEULWJSKCVACTH-UHFFFAOYSA-N 0.000 description 1
- HQOVXPHOJANJBR-UHFFFAOYSA-N 2,2-bis(tert-butylperoxy)butane Chemical compound CC(C)(C)OOC(C)(CC)OOC(C)(C)C HQOVXPHOJANJBR-UHFFFAOYSA-N 0.000 description 1
- ODBCKCWTWALFKM-UHFFFAOYSA-N 2,5-bis(tert-butylperoxy)-2,5-dimethylhex-3-yne Chemical compound CC(C)(C)OOC(C)(C)C#CC(C)(C)OOC(C)(C)C ODBCKCWTWALFKM-UHFFFAOYSA-N 0.000 description 1
- DMWVYCCGCQPJEA-UHFFFAOYSA-N 2,5-bis(tert-butylperoxy)-2,5-dimethylhexane Chemical compound CC(C)(C)OOC(C)(C)CCC(C)(C)OOC(C)(C)C DMWVYCCGCQPJEA-UHFFFAOYSA-N 0.000 description 1
- IEMBFTKNPXENSE-UHFFFAOYSA-N 2-(2-methylpentan-2-ylperoxy)propan-2-yl hydrogen carbonate Chemical compound CCCC(C)(C)OOC(C)(C)OC(O)=O IEMBFTKNPXENSE-UHFFFAOYSA-N 0.000 description 1
- XMNIXWIUMCBBBL-UHFFFAOYSA-N 2-(2-phenylpropan-2-ylperoxy)propan-2-ylbenzene Chemical compound C=1C=CC=CC=1C(C)(C)OOC(C)(C)C1=CC=CC=C1 XMNIXWIUMCBBBL-UHFFFAOYSA-N 0.000 description 1
- MIRQGKQPLPBZQM-UHFFFAOYSA-N 2-hydroperoxy-2,4,4-trimethylpentane Chemical compound CC(C)(C)CC(C)(C)OO MIRQGKQPLPBZQM-UHFFFAOYSA-N 0.000 description 1
- WFUGQJXVXHBTEM-UHFFFAOYSA-N 2-hydroperoxy-2-(2-hydroperoxybutan-2-ylperoxy)butane Chemical compound CCC(C)(OO)OOC(C)(CC)OO WFUGQJXVXHBTEM-UHFFFAOYSA-N 0.000 description 1
- FRWYFWZENXDZMU-UHFFFAOYSA-N 2-iodoquinoline Chemical compound C1=CC=CC2=NC(I)=CC=C21 FRWYFWZENXDZMU-UHFFFAOYSA-N 0.000 description 1
- LXBGSDVWAMZHDD-UHFFFAOYSA-N 2-methyl-1h-imidazole Chemical compound CC1=NC=CN1 LXBGSDVWAMZHDD-UHFFFAOYSA-N 0.000 description 1
- WXDJDZIIPSOZAH-UHFFFAOYSA-N 2-methylpentan-2-yl benzenecarboperoxoate Chemical compound CCCC(C)(C)OOC(=O)C1=CC=CC=C1 WXDJDZIIPSOZAH-UHFFFAOYSA-N 0.000 description 1
- DTIPOINIRMUSRR-UHFFFAOYSA-N 2-tert-butyldodecaneperoxoic acid Chemical compound CCCCCCCCCCC(C(C)(C)C)C(=O)OO DTIPOINIRMUSRR-UHFFFAOYSA-N 0.000 description 1
- NXAFRGRYHSKXJB-UHFFFAOYSA-N 2-tert-butylperoxy-3,5,5-trimethylhexanoic acid Chemical compound CC(C)(C)CC(C)C(C(O)=O)OOC(C)(C)C NXAFRGRYHSKXJB-UHFFFAOYSA-N 0.000 description 1
- BQARUDWASOOSRH-UHFFFAOYSA-N 2-tert-butylperoxypropan-2-yl hydrogen carbonate Chemical compound CC(C)(C)OOC(C)(C)OC(O)=O BQARUDWASOOSRH-UHFFFAOYSA-N 0.000 description 1
- BIISIZOQPWZPPS-UHFFFAOYSA-N 2-tert-butylperoxypropan-2-ylbenzene Chemical compound CC(C)(C)OOC(C)(C)C1=CC=CC=C1 BIISIZOQPWZPPS-UHFFFAOYSA-N 0.000 description 1
- SESYNEDUKZDRJL-UHFFFAOYSA-N 3-(2-methylimidazol-1-yl)propanenitrile Chemical compound CC1=NC=CN1CCC#N SESYNEDUKZDRJL-UHFFFAOYSA-N 0.000 description 1
- BVYPJEBKDLFIDL-UHFFFAOYSA-N 3-(2-phenylimidazol-1-yl)propanenitrile Chemical compound N#CCCN1C=CN=C1C1=CC=CC=C1 BVYPJEBKDLFIDL-UHFFFAOYSA-N 0.000 description 1
- WVRNUXJQQFPNMN-VAWYXSNFSA-N 3-[(e)-dodec-1-enyl]oxolane-2,5-dione Chemical compound CCCCCCCCCC\C=C\C1CC(=O)OC1=O WVRNUXJQQFPNMN-VAWYXSNFSA-N 0.000 description 1
- VPWNQTHUCYMVMZ-UHFFFAOYSA-N 4,4'-sulfonyldiphenol Chemical compound C1=CC(O)=CC=C1S(=O)(=O)C1=CC=C(O)C=C1 VPWNQTHUCYMVMZ-UHFFFAOYSA-N 0.000 description 1
- RDNMXACGFJLCEM-UHFFFAOYSA-N 4-[2-[4,4-bis(butylperoxy)cyclohexyl]propan-2-yl]-1,1-bis(butylperoxy)cyclohexane Chemical compound C1CC(OOCCCC)(OOCCCC)CCC1C(C)(C)C1CCC(OOCCCC)(OOCCCC)CC1 RDNMXACGFJLCEM-UHFFFAOYSA-N 0.000 description 1
- FUGYGGDSWSUORM-UHFFFAOYSA-N 4-hydroxystyrene Chemical compound OC1=CC=C(C=C)C=C1 FUGYGGDSWSUORM-UHFFFAOYSA-N 0.000 description 1
- ULKLGIFJWFIQFF-UHFFFAOYSA-N 5K8XI641G3 Chemical compound CCC1=NC=C(C)N1 ULKLGIFJWFIQFF-UHFFFAOYSA-N 0.000 description 1
- MWSKJDNQKGCKPA-UHFFFAOYSA-N 6-methyl-3a,4,5,7a-tetrahydro-2-benzofuran-1,3-dione Chemical compound C1CC(C)=CC2C(=O)OC(=O)C12 MWSKJDNQKGCKPA-UHFFFAOYSA-N 0.000 description 1
- RSWGJHLUYNHPMX-UHFFFAOYSA-N Abietic-Saeure Natural products C12CCC(C(C)C)=CC2=CCC2C1(C)CCCC2(C)C(O)=O RSWGJHLUYNHPMX-UHFFFAOYSA-N 0.000 description 1
- 239000004925 Acrylic resin Substances 0.000 description 1
- 229920000178 Acrylic resin Polymers 0.000 description 1
- 229910052582 BN Inorganic materials 0.000 description 1
- PZNSFCLAULLKQX-UHFFFAOYSA-N Boron nitride Chemical compound N#B PZNSFCLAULLKQX-UHFFFAOYSA-N 0.000 description 1
- WVEBJVBQJVZCOR-UHFFFAOYSA-N C1(=CC=CC=C1)O.B(Cl)(Cl)Cl Chemical compound C1(=CC=CC=C1)O.B(Cl)(Cl)Cl WVEBJVBQJVZCOR-UHFFFAOYSA-N 0.000 description 1
- RLBOBRBYUJXSAS-UHFFFAOYSA-N CN(C)CCCCCCCCCCCC.B(Cl)(Cl)Cl Chemical compound CN(C)CCCCCCCCCCCC.B(Cl)(Cl)Cl RLBOBRBYUJXSAS-UHFFFAOYSA-N 0.000 description 1
- LGFYRHHQQBCABH-UHFFFAOYSA-N ClNC1=CC=CC=C1.B(F)(F)F Chemical compound ClNC1=CC=CC=C1.B(F)(F)F LGFYRHHQQBCABH-UHFFFAOYSA-N 0.000 description 1
- 239000004641 Diallyl-phthalate Substances 0.000 description 1
- JOYRKODLDBILNP-UHFFFAOYSA-N Ethyl urethane Chemical compound CCOC(N)=O JOYRKODLDBILNP-UHFFFAOYSA-N 0.000 description 1
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 description 1
- 244000043261 Hevea brasiliensis Species 0.000 description 1
- 229920000106 Liquid crystal polymer Polymers 0.000 description 1
- 239000004977 Liquid-crystal polymers (LCPs) Substances 0.000 description 1
- 229920009204 Methacrylate-butadiene-styrene Polymers 0.000 description 1
- NIBQESCYXKTVMQ-UHFFFAOYSA-N N1CCCCC1.B(Cl)(Cl)Cl Chemical compound N1CCCCC1.B(Cl)(Cl)Cl NIBQESCYXKTVMQ-UHFFFAOYSA-N 0.000 description 1
- 239000004677 Nylon Substances 0.000 description 1
- 229920002302 Nylon 6,6 Polymers 0.000 description 1
- 240000007594 Oryza sativa Species 0.000 description 1
- 235000007164 Oryza sativa Nutrition 0.000 description 1
- LGRFSURHDFAFJT-UHFFFAOYSA-N Phthalic anhydride Natural products C1=CC=C2C(=O)OC(=O)C2=C1 LGRFSURHDFAFJT-UHFFFAOYSA-N 0.000 description 1
- 239000004696 Poly ether ether ketone Substances 0.000 description 1
- 229930182556 Polyacetal Natural products 0.000 description 1
- 239000004952 Polyamide Substances 0.000 description 1
- 239000004962 Polyamide-imide Substances 0.000 description 1
- 239000004697 Polyetherimide Substances 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- 239000004743 Polypropylene Substances 0.000 description 1
- 229920000297 Rayon Polymers 0.000 description 1
- KHPCPRHQVVSZAH-HUOMCSJISA-N Rosin Natural products O(C/C=C/c1ccccc1)[C@H]1[C@H](O)[C@@H](O)[C@@H](O)[C@@H](CO)O1 KHPCPRHQVVSZAH-HUOMCSJISA-N 0.000 description 1
- 229910052581 Si3N4 Inorganic materials 0.000 description 1
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 description 1
- 239000006087 Silane Coupling Agent Substances 0.000 description 1
- 239000004809 Teflon Substances 0.000 description 1
- 229920006362 Teflon® Polymers 0.000 description 1
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 1
- GKXVJHDEWHKBFH-UHFFFAOYSA-N [2-(aminomethyl)phenyl]methanamine Chemical compound NCC1=CC=CC=C1CN GKXVJHDEWHKBFH-UHFFFAOYSA-N 0.000 description 1
- 239000011354 acetal resin Substances 0.000 description 1
- 150000001241 acetals Chemical class 0.000 description 1
- 150000008065 acid anhydrides Chemical class 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 1
- XECAHXYUAAWDEL-UHFFFAOYSA-N acrylonitrile butadiene styrene Chemical compound C=CC=C.C=CC#N.C=CC1=CC=CC=C1 XECAHXYUAAWDEL-UHFFFAOYSA-N 0.000 description 1
- 239000004676 acrylonitrile butadiene styrene Substances 0.000 description 1
- 239000002318 adhesion promoter Substances 0.000 description 1
- 239000002390 adhesive tape Substances 0.000 description 1
- IBVAQQYNSHJXBV-UHFFFAOYSA-N adipic acid dihydrazide Chemical compound NNC(=O)CCCCC(=O)NN IBVAQQYNSHJXBV-UHFFFAOYSA-N 0.000 description 1
- WNROFYMDJYEPJX-UHFFFAOYSA-K aluminium hydroxide Chemical compound [OH-].[OH-].[OH-].[Al+3] WNROFYMDJYEPJX-UHFFFAOYSA-K 0.000 description 1
- 150000008064 anhydrides Chemical class 0.000 description 1
- VWKLICCSBFEWSZ-UHFFFAOYSA-N aniline;trifluoroborane Chemical compound FB(F)F.NC1=CC=CC=C1 VWKLICCSBFEWSZ-UHFFFAOYSA-N 0.000 description 1
- 239000002518 antifoaming agent Substances 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 125000003118 aryl group Chemical group 0.000 description 1
- 239000011324 bead Substances 0.000 description 1
- WPYMKLBDIGXBTP-UHFFFAOYSA-N benzoic acid Chemical compound OC(=O)C1=CC=CC=C1 WPYMKLBDIGXBTP-UHFFFAOYSA-N 0.000 description 1
- LTPBRCUWZOMYOC-UHFFFAOYSA-N beryllium oxide Inorganic materials O=[Be] LTPBRCUWZOMYOC-UHFFFAOYSA-N 0.000 description 1
- 239000004305 biphenyl Substances 0.000 description 1
- 235000010290 biphenyl Nutrition 0.000 description 1
- QUDWYFHPNIMBFC-UHFFFAOYSA-N bis(prop-2-enyl) benzene-1,2-dicarboxylate Chemical compound C=CCOC(=O)C1=CC=CC=C1C(=O)OCC=C QUDWYFHPNIMBFC-UHFFFAOYSA-N 0.000 description 1
- 230000000903 blocking effect Effects 0.000 description 1
- DQXBYHZEEUGOBF-UHFFFAOYSA-N but-3-enoic acid;ethene Chemical compound C=C.OC(=O)CC=C DQXBYHZEEUGOBF-UHFFFAOYSA-N 0.000 description 1
- JHIWVOJDXOSYLW-UHFFFAOYSA-N butyl 2,2-difluorocyclopropane-1-carboxylate Chemical compound CCCCOC(=O)C1CC1(F)F JHIWVOJDXOSYLW-UHFFFAOYSA-N 0.000 description 1
- BXIQXYOPGBXIEM-UHFFFAOYSA-N butyl 4,4-bis(tert-butylperoxy)pentanoate Chemical compound CCCCOC(=O)CCC(C)(OOC(C)(C)C)OOC(C)(C)C BXIQXYOPGBXIEM-UHFFFAOYSA-N 0.000 description 1
- 239000000378 calcium silicate Substances 0.000 description 1
- 229910052918 calcium silicate Inorganic materials 0.000 description 1
- OYACROKNLOSFPA-UHFFFAOYSA-N calcium;dioxido(oxo)silane Chemical compound [Ca+2].[O-][Si]([O-])=O OYACROKNLOSFPA-UHFFFAOYSA-N 0.000 description 1
- 239000001913 cellulose Substances 0.000 description 1
- 229920002678 cellulose Polymers 0.000 description 1
- 235000013339 cereals Nutrition 0.000 description 1
- 239000003638 chemical reducing agent Substances 0.000 description 1
- 239000004927 clay Substances 0.000 description 1
- 229910052570 clay Inorganic materials 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 229920001577 copolymer Polymers 0.000 description 1
- PMHQVHHXPFUNSP-UHFFFAOYSA-M copper(1+);methylsulfanylmethane;bromide Chemical compound Br[Cu].CSC PMHQVHHXPFUNSP-UHFFFAOYSA-M 0.000 description 1
- 150000001896 cresols Chemical class 0.000 description 1
- SPTHWAJJMLCAQF-UHFFFAOYSA-M ctk4f8481 Chemical compound [O-]O.CC(C)C1=CC=CC=C1C(C)C SPTHWAJJMLCAQF-UHFFFAOYSA-M 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 238000005238 degreasing Methods 0.000 description 1
- 238000013461 design Methods 0.000 description 1
- LSXWFXONGKSEMY-UHFFFAOYSA-N di-tert-butyl peroxide Chemical compound CC(C)(C)OOC(C)(C)C LSXWFXONGKSEMY-UHFFFAOYSA-N 0.000 description 1
- 239000012933 diacyl peroxide Substances 0.000 description 1
- 238000000113 differential scanning calorimetry Methods 0.000 description 1
- XXBDWLFCJWSEKW-UHFFFAOYSA-N dimethylbenzylamine Chemical compound CN(C)CC1=CC=CC=C1 XXBDWLFCJWSEKW-UHFFFAOYSA-N 0.000 description 1
- 239000002270 dispersing agent Substances 0.000 description 1
- 239000000806 elastomer Substances 0.000 description 1
- 238000005485 electric heating Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 229920006332 epoxy adhesive Polymers 0.000 description 1
- LZFQGEMBQPYJJJ-UHFFFAOYSA-N ethanamine;trichloroborane Chemical compound CCN.ClB(Cl)Cl LZFQGEMBQPYJJJ-UHFFFAOYSA-N 0.000 description 1
- JDVIRCVIXCMTPU-UHFFFAOYSA-N ethanamine;trifluoroborane Chemical compound CCN.FB(F)F JDVIRCVIXCMTPU-UHFFFAOYSA-N 0.000 description 1
- 229920001038 ethylene copolymer Polymers 0.000 description 1
- 239000005038 ethylene vinyl acetate Substances 0.000 description 1
- 238000000605 extraction Methods 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 239000003063 flame retardant Substances 0.000 description 1
- 239000011737 fluorine Substances 0.000 description 1
- 229910052731 fluorine Inorganic materials 0.000 description 1
- 229920001973 fluoroelastomer Polymers 0.000 description 1
- 230000004907 flux Effects 0.000 description 1
- 230000006870 function Effects 0.000 description 1
- 230000009477 glass transition Effects 0.000 description 1
- 238000013007 heat curing Methods 0.000 description 1
- 125000000623 heterocyclic group Chemical group 0.000 description 1
- 229940042795 hydrazides for tuberculosis treatment Drugs 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 239000003999 initiator Substances 0.000 description 1
- 238000003780 insertion Methods 0.000 description 1
- 230000037431 insertion Effects 0.000 description 1
- 239000011229 interlayer Substances 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 239000012948 isocyanate Substances 0.000 description 1
- 150000002513 isocyanates Chemical class 0.000 description 1
- 150000002576 ketones Chemical class 0.000 description 1
- 238000004898 kneading Methods 0.000 description 1
- 238000003475 lamination Methods 0.000 description 1
- AXZKOIWUVFPNLO-UHFFFAOYSA-N magnesium;oxygen(2-) Chemical compound [O-2].[Mg+2] AXZKOIWUVFPNLO-UHFFFAOYSA-N 0.000 description 1
- YDKNBNOOCSNPNS-UHFFFAOYSA-N methyl 1,3-benzoxazole-2-carboxylate Chemical compound C1=CC=C2OC(C(=O)OC)=NC2=C1 YDKNBNOOCSNPNS-UHFFFAOYSA-N 0.000 description 1
- VYKXQOYUCMREIS-UHFFFAOYSA-N methylhexahydrophthalic anhydride Chemical compound C1CCCC2C(=O)OC(=O)C21C VYKXQOYUCMREIS-UHFFFAOYSA-N 0.000 description 1
- AYEIJQRLYWJQHC-UHFFFAOYSA-N methylsulfanylmethane;trichloroborane Chemical compound CSC.ClB(Cl)Cl AYEIJQRLYWJQHC-UHFFFAOYSA-N 0.000 description 1
- 239000010445 mica Substances 0.000 description 1
- 229910052618 mica group Inorganic materials 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 239000000178 monomer Substances 0.000 description 1
- JKWQIKWWHDGDFT-UHFFFAOYSA-N n,n-dimethyloctan-1-amine;trichloroborane Chemical compound ClB(Cl)Cl.CCCCCCCCN(C)C JKWQIKWWHDGDFT-UHFFFAOYSA-N 0.000 description 1
- KBJFYLLAMSZSOG-UHFFFAOYSA-N n-(3-trimethoxysilylpropyl)aniline Chemical compound CO[Si](OC)(OC)CCCNC1=CC=CC=C1 KBJFYLLAMSZSOG-UHFFFAOYSA-N 0.000 description 1
- STQYDSASXIHUJU-UHFFFAOYSA-N n-ethylethanamine;trifluoroborane Chemical compound FB(F)F.CCNCC STQYDSASXIHUJU-UHFFFAOYSA-N 0.000 description 1
- 239000002121 nanofiber Substances 0.000 description 1
- 229920003052 natural elastomer Polymers 0.000 description 1
- 229920001194 natural rubber Polymers 0.000 description 1
- 239000010680 novolac-type phenolic resin Substances 0.000 description 1
- 229920001778 nylon Polymers 0.000 description 1
- 239000003973 paint Substances 0.000 description 1
- 230000000149 penetrating effect Effects 0.000 description 1
- YRZFHTRSHNGOSR-UHFFFAOYSA-N phenylmethanamine;trifluoroborane Chemical compound FB(F)F.NCC1=CC=CC=C1 YRZFHTRSHNGOSR-UHFFFAOYSA-N 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229920003055 poly(ester-imide) Polymers 0.000 description 1
- 229920001200 poly(ethylene-vinyl acetate) Polymers 0.000 description 1
- 229920002492 poly(sulfone) Polymers 0.000 description 1
- 229920002239 polyacrylonitrile Polymers 0.000 description 1
- 229920002647 polyamide Polymers 0.000 description 1
- 229920002312 polyamide-imide Polymers 0.000 description 1
- 239000004417 polycarbonate Substances 0.000 description 1
- 229920000515 polycarbonate Polymers 0.000 description 1
- 229920002530 polyetherether ketone Polymers 0.000 description 1
- 229920001601 polyetherimide Polymers 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 229920000098 polyolefin Polymers 0.000 description 1
- 229920001955 polyphenylene ether Polymers 0.000 description 1
- 229920001155 polypropylene Polymers 0.000 description 1
- 229920005749 polyurethane resin Polymers 0.000 description 1
- 238000003825 pressing Methods 0.000 description 1
- CIQUNISKQPOPCF-UHFFFAOYSA-N propan-2-amine;trifluoroborane Chemical compound CC(C)N.FB(F)F CIQUNISKQPOPCF-UHFFFAOYSA-N 0.000 description 1
- 239000002964 rayon Substances 0.000 description 1
- 230000003578 releasing effect Effects 0.000 description 1
- 239000011134 resol-type phenolic resin Substances 0.000 description 1
- 235000009566 rice Nutrition 0.000 description 1
- 239000005060 rubber Substances 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 229910000077 silane Inorganic materials 0.000 description 1
- HQVNEWCFYHHQES-UHFFFAOYSA-N silicon nitride Chemical compound N12[Si]34N5[Si]62N3[Si]51N64 HQVNEWCFYHHQES-UHFFFAOYSA-N 0.000 description 1
- 229920002545 silicone oil Polymers 0.000 description 1
- 229920002379 silicone rubber Polymers 0.000 description 1
- 239000004945 silicone rubber Substances 0.000 description 1
- 239000002356 single layer Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- 239000000454 talc Substances 0.000 description 1
- 229910052623 talc Inorganic materials 0.000 description 1
- 238000009864 tensile test Methods 0.000 description 1
- 150000003505 terpenes Chemical class 0.000 description 1
- 235000007586 terpenes Nutrition 0.000 description 1
- SWAXTRYEYUTSAP-UHFFFAOYSA-N tert-butyl ethaneperoxoate Chemical compound CC(=O)OOC(C)(C)C SWAXTRYEYUTSAP-UHFFFAOYSA-N 0.000 description 1
- 150000003512 tertiary amines Chemical class 0.000 description 1
- CIHOLLKRGTVIJN-UHFFFAOYSA-N tert‐butyl hydroperoxide Chemical compound CC(C)(C)OO CIHOLLKRGTVIJN-UHFFFAOYSA-N 0.000 description 1
- 239000002562 thickening agent Substances 0.000 description 1
- 239000004408 titanium dioxide Substances 0.000 description 1
- KHPCPRHQVVSZAH-UHFFFAOYSA-N trans-cinnamyl beta-D-glucopyranoside Natural products OC1C(O)C(O)C(CO)OC1OCC=CC1=CC=CC=C1 KHPCPRHQVVSZAH-UHFFFAOYSA-N 0.000 description 1
- BPSIOYPQMFLKFR-UHFFFAOYSA-N trimethoxy-[3-(oxiran-2-ylmethoxy)propyl]silane Chemical compound CO[Si](OC)(OC)CCCOCC1CO1 BPSIOYPQMFLKFR-UHFFFAOYSA-N 0.000 description 1
- YUYCVXFAYWRXLS-UHFFFAOYSA-N trimethoxysilane Chemical compound CO[SiH](OC)OC YUYCVXFAYWRXLS-UHFFFAOYSA-N 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
- CHJMFFKHPHCQIJ-UHFFFAOYSA-L zinc;octanoate Chemical compound [Zn+2].CCCCCCCC([O-])=O.CCCCCCCC([O-])=O CHJMFFKHPHCQIJ-UHFFFAOYSA-L 0.000 description 1
Images
Classifications
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H19/00—Coated paper; Coating material
- D21H19/10—Coatings without pigments
- D21H19/14—Coatings without pigments applied in a form other than the aqueous solution defined in group D21H19/12
- D21H19/24—Coatings without pigments applied in a form other than the aqueous solution defined in group D21H19/12 comprising macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/06—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material
- B32B27/08—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/06—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material
- B32B27/10—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material of paper or cardboard
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/28—Layered products comprising a layer of synthetic resin comprising synthetic resins not wholly covered by any one of the sub-groups B32B27/30 - B32B27/42
- B32B27/281—Layered products comprising a layer of synthetic resin comprising synthetic resins not wholly covered by any one of the sub-groups B32B27/30 - B32B27/42 comprising polyimides
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/28—Layered products comprising a layer of synthetic resin comprising synthetic resins not wholly covered by any one of the sub-groups B32B27/30 - B32B27/42
- B32B27/285—Layered products comprising a layer of synthetic resin comprising synthetic resins not wholly covered by any one of the sub-groups B32B27/30 - B32B27/42 comprising polyethers
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/36—Layered products comprising a layer of synthetic resin comprising polyesters
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B29/00—Layered products comprising a layer of paper or cardboard
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B33/00—Layered products characterised by particular properties or particular surface features, e.g. particular surface coatings; Layered products designed for particular purposes not covered by another single class
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B37/00—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B37/00—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding
- B32B37/12—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by using adhesives
- B32B37/1284—Application of adhesive
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B38/00—Ancillary operations in connection with laminating processes
- B32B38/16—Drying; Softening; Cleaning
- B32B38/164—Drying
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B7/00—Layered products characterised by the relation between layers; Layered products characterised by the relative orientation of features between layers, or by the relative values of a measurable parameter between layers, i.e. products comprising layers having different physical, chemical or physicochemical properties; Layered products characterised by the interconnection of layers
- B32B7/04—Interconnection of layers
- B32B7/12—Interconnection of layers using interposed adhesives or interposed materials with bonding properties
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J7/00—Chemical treatment or coating of shaped articles made of macromolecular substances
- C08J7/04—Coating
- C08J7/0427—Coating with only one layer of a composition containing a polymer binder
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D163/00—Coating compositions based on epoxy resins; Coating compositions based on derivatives of epoxy resins
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
- D06N3/12—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. gelatine proteins
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
- D06N3/12—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. gelatine proteins
- D06N3/121—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. gelatine proteins with polyesters, polycarbonates, alkyds
- D06N3/123—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. gelatine proteins with polyesters, polycarbonates, alkyds with polyesters
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
- D06N3/12—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. gelatine proteins
- D06N3/14—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. gelatine proteins with polyurethanes
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
- H01B3/00—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties
- H01B3/18—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances
- H01B3/48—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances fibrous materials
- H01B3/52—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances fibrous materials wood; paper; press board
-
- H—ELECTRICITY
- H02—GENERATION; CONVERSION OR DISTRIBUTION OF ELECTRIC POWER
- H02K—DYNAMO-ELECTRIC MACHINES
- H02K3/00—Details of windings
- H02K3/30—Windings characterised by the insulating material
-
- H—ELECTRICITY
- H02—GENERATION; CONVERSION OR DISTRIBUTION OF ELECTRIC POWER
- H02K—DYNAMO-ELECTRIC MACHINES
- H02K3/00—Details of windings
- H02K3/32—Windings characterised by the shape, form or construction of the insulation
- H02K3/34—Windings characterised by the shape, form or construction of the insulation between conductors or between conductor and core, e.g. slot insulation
- H02K3/345—Windings characterised by the shape, form or construction of the insulation between conductors or between conductor and core, e.g. slot insulation between conductor and core, e.g. slot insulation
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B37/00—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding
- B32B37/14—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by the properties of the layers
- B32B37/24—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by the properties of the layers with at least one layer not being coherent before laminating, e.g. made up from granular material sprinkled onto a substrate
- B32B2037/243—Coating
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2255/00—Coating on the layer surface
- B32B2255/10—Coating on the layer surface on synthetic resin layer or on natural or synthetic rubber layer
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2255/00—Coating on the layer surface
- B32B2255/12—Coating on the layer surface on paper layer
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2255/00—Coating on the layer surface
- B32B2255/26—Polymeric coating
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2307/00—Properties of the layers or laminate
- B32B2307/20—Properties of the layers or laminate having particular electrical or magnetic properties, e.g. piezoelectric
- B32B2307/206—Insulating
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2381/00—Characterised by the use of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing sulfur with or without nitrogen, oxygen, or carbon only; Polysulfones; Derivatives of such polymers
- C08J2381/02—Polythioethers; Polythioether-ethers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2463/00—Characterised by the use of epoxy resins; Derivatives of epoxy resins
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
- C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02T—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO TRANSPORTATION
- Y02T10/00—Road transport of goods or passengers
- Y02T10/60—Other road transportation technologies with climate change mitigation effect
- Y02T10/64—Electric machine technologies in electromobility
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Life Sciences & Earth Sciences (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Materials Engineering (AREA)
- Dispersion Chemistry (AREA)
- Textile Engineering (AREA)
- Power Engineering (AREA)
- Spectroscopy & Molecular Physics (AREA)
- Physics & Mathematics (AREA)
- Inorganic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Insulating Of Coils (AREA)
- Insulating Bodies (AREA)
- Insulation, Fastening Of Motor, Generator Windings (AREA)
- Manufacture Of Motors, Generators (AREA)
- Laminated Bodies (AREA)
Abstract
Description
以下に、実施の形態1による絶縁シートについて、図面に基づいて説明する。図1及び図2は、実施の形態1による絶縁シート及び複合絶縁シートの構成例をそれぞれ示している。なお、図中、同一、相当部分には同一符号を付している。
実施の形態2では、絶縁シートの絶縁樹脂層を構成する熱硬化性樹脂組成物について説明する。熱硬化性樹脂組成物は、25℃で固体の熱硬化性樹脂(A)と、25℃で液状の熱硬化性樹脂(B)と、60℃以下で反応不活性な潜在性硬化剤を有する。熱硬化性樹脂組成物は、さらに粒状で複数の無機充填剤を有しても構わない。複数の無機充填剤は、最大粒径が絶縁樹脂層3の厚みよりも小さく、平均粒径が絶縁樹脂層3の厚みの0.5倍よりも小さい。無機充填剤の最大粒径が絶縁樹脂層3の厚み以上になった場合、または無機充填剤の平均粒径が絶縁樹脂層3の厚みの0.5倍以上になった場合、基材2に絶縁樹脂層3を形成するスラリーを塗布した際に絶縁シート1に表面平坦性が得られない。また、絶縁樹脂層3の圧縮は高弾性の無機充填材で停止するため、絶縁樹脂層3が効率よく圧縮されず、絶縁シート1が配置される隙間の細部に絶縁樹脂層3を十分に充填することができなくなる場合、及び固定子鉄心を円筒状に成形する際に、絶縁シート1を固定子に圧縮固定できなくなる場合がある。また、熱硬化性樹脂組成物は、必要に応じて硬化促進剤、製膜性付与剤、粘着付与剤、及び接着付与剤等を含む。なお、以下の説明において、熱硬化性樹脂(A)及び熱硬化性樹脂(B)を特に区別せず両方を指す場合、あるいはこれらの混合樹脂を指す場合は、単に「熱硬化性樹脂」と記す。また、常温を約25℃とする。
実施の形態3では、絶縁樹脂層及び絶縁シートの特性について説明する。絶縁樹脂層は、表面平滑性及び柔軟性が高い方が好ましい。絶縁対象の部材との貼り付け性が良好であって、硬化後の絶縁樹脂層と絶縁対象の部材との間に空気層が発生しないためには、絶縁樹脂層の膜厚の面内分布を平均値の±30%以内とする。
貼り付け作業と絶縁樹脂層3の硬化を効率良く行うために、絶縁樹脂層3の融点は100℃以下で、かつその硬化開始温度は、融点より5℃以上高くすると良い。粘着作業中に絶縁樹脂層3の温度が低下し、粘着性が低下する恐れがある場合、その尤度を配慮した高い温度で絶縁樹脂層3を加温する方が、作業性が良くなるため、融点と硬化開始温度の温度差を10℃以上とすることがより好ましい。絶縁シート1は切断及び成形をして使用することから、絶縁樹脂層3は常温ではタック性が低いことが良いため、融点は、30℃以上100℃以下が好ましく、また、切断及び成形などの常温での作業環境温度が最大40℃まで上昇する可能性があるため、40℃以上100℃以下がより好ましい。融点が30℃未満の場合は、常温での保管に絶縁樹脂層3の粘性が変化し、作業性が低下する。また、100℃を超える場合は、貼り付け温度の設定にもよるが、硬化反応が並行して進行する可能性が高く、貼り付け作業性が低下する。また、この場合、絶縁樹脂層3の硬化開始温度は、融点の5℃以上、より好ましくは10℃以上高い温度で、かつ絶縁樹脂層3のポットライフを確保するため、100℃以上であることがさらに好ましい。硬化開始温度が融点+5℃より低い場合は、絶縁樹脂層3を加温して粘着性を高める作業中に反応が進行し、粘着性の低下を引き起こす。融点は、25℃で固体の熱硬化性樹脂(A)と、25℃で液状の熱硬化性樹脂(B)の配合で制御し、前者を増やすと上昇する傾向がある。また、潜在性硬化剤と硬化促進剤は反応開始温度を有するので、硬化開始温度は、これらの種類の選定と配合量で制御できる。また、貼り付け温度は、熱硬化樹脂組成物により粘着性が異なるが、固定子鉄心など被着体あるいは絶縁シート1を予め、硬化開始温度以下かつ融点±20℃の範囲内で予熱して、貼り付けると良い。絶縁樹脂層1の流動性を高めることで、より粘着力が増すため、貼り付け温度は融点±10℃の範囲内がより好ましい。貼り付け温度が融点より20℃超低い場合、樹脂層3の粘着性が低く、また20℃超高い場合は、絶縁樹脂層3が流動し、貼り付け性が低下する。
実施の形態4では、絶縁シート1の製造方法について説明する。絶縁シートの製造工程は、熱硬化性樹脂組成物のスラリーを作製する第1の工程と、第1の工程で作製したスラリーを基材等に、切断される領域、折り曲げ成形の加工される領域のいずれか一方または両方の領域を除いた部分に塗布し、乾燥させる第2の工程とを含む。
実施の形態5では、絶縁シートの回転電機への使用例について、図6から図10を用いて説明する。図6及び図7は、実施の形態5による回転電機の固定子を説明する斜視図及び断面図、図8から図10は、実施の形態5による回転電機における絶縁シートの使用例を説明する図であり、図9は、図8中、A-Aで示す部分の断面図、図10は、図8中、Bで示す部分の拡大図である。
(1-1)ビスフェノールA型エポキシ樹脂(エポキシ当量950、軟化点95℃)
(1-2)ビスフェノールA型ビニルエステル樹脂(重合平均分子量2500、軟化点95℃)
(2-1)ビスフェノールA型エポキシ樹脂(エポキシ当量190)
(2-2)ネオペンチルグリコールジアクリレート(25℃での粘度6mPa・s)
(3-1)ジシアンジアミド(反応開始温度160℃)
(3-2)キシリレンジアミン(常温で反応活性)
(3-3)t-ブチルクミルパーオキサイド(10時間半減期温度119.5℃)
(4-1)1-シアノエチル-2-フェニルイミダゾール(反応開始温度125℃)
(4-2)1,8-ジアザビシクロ(5,4,0)ウンデセン-7(反応開始温度100℃)
(4―3)オクチル酸亜鉛(反応開始温度105℃)
(4-4)2,4,6-トリス(N,N-ジメチルアミノメチル)フェノール(常温で反応活性)
<熱可塑性樹脂>
(5-1)フェノキシ樹脂(重合平均分子量18万)
(5-2)ポリエステル樹脂(重合平均分子量6.5万)
(6-1)溶融シリカ(最大粒径10μm、最小粒径1μm、平均粒径4μm)
(6-2)結晶シリカ(最大粒径30μm、最小粒径5μm、平均粒径12μm)
(6-3)アルミナ(最大粒径5μm、最小粒径1μm、平均粒径3μm)
(6-4)炭酸カルシウム(最大粒径20μm、最小粒径3μm、平均粒径8μm)
(6-5)炭酸カルシウム(最大粒径120μm、最小粒径10μm、平均粒径60μm)
(7-1)アラミド紙(厚み0.25mm)
(7-2)複合絶縁フィルム:ポリフェニレンサルファイド/ポリエチレンテレフタレート/ポリフェニレンサルファイド(厚み0.13mm。層間接着剤あり)
(7-3)複合絶縁紙:アラミド紙/ポリイミド/アラミド紙(厚み0.17mm、空孔サイズΦ20μm、空隙率40%)
(7-4)ナノファイバー不織布:ポリエーテルエーテルケトン(厚み:0.08mm、空隙サイズ3~25μm、空隙率65%)
(7-5)複合絶縁紙:アラミド紙/ポリイミド/アラミド紙(厚み0.17mm)
(7-6)複合絶縁紙:アラミド紙/ポリイミド/アラミド紙(厚み0.17mm、空孔サイズΦ1.1μm、空孔率60%)
(7-7)複合絶縁紙:アラミド紙/ポリイミド/アラミド紙(厚み0.17mm、空孔サイズΦ3μm、空孔率95%)
(7-8)複合絶縁紙:アラミド紙/ポリイミド/アラミド紙(厚み0.17mm、空孔サイズΦ500μm、空孔率20%)
(7-9)複合絶縁紙:アラミド紙/ポリイミド/アラミド紙(厚み0.17mm、空孔サイズΦ4.5μm、空孔率5%)
(7-10)複合絶縁紙:アラミド紙/ポリイミド/アラミド紙(厚み0.17mm、空孔サイズΦ525μm、空孔率45%)
(7-11)複合絶縁紙:アラミド紙/ポリイミド/アラミド紙(厚み0.17mm、空孔サイズΦ5μm、空孔率96%)
(7-12)複合絶縁紙:アラミド紙/ポリイミド/アラミド紙(厚み0.17mm、空孔サイズΦ0.9μm、空孔率35%)
(7-13)複合絶縁紙:アラミド紙/ポリイミド/アラミド紙(厚み0.17mm、空孔サイズΦ1.5μm、空孔率4.5%)
Claims (24)
- 絶縁紙、絶縁フィルム、不織布、及びメッシュクロスのいずれか1種または2種以上を基材とし、未硬化または半硬化の状態の熱硬化性樹脂組成物からなる絶縁樹脂層が前記基材の片面または両面に形成された絶縁シートであって、
前記熱硬化性樹脂組成物は、25℃で固体の熱硬化性樹脂(A)と、25℃で液状の熱硬化性樹脂(B)と、60℃以下で反応不活性な潜在性硬化剤と、前記熱硬化性樹脂(A)と前記熱硬化性樹脂(B)の合計100質量部に対して、前記熱硬化性樹脂(A)を10質量部から90質量部の範囲とし、
前記絶縁樹脂層は、切断される領域と折り曲げ成形の加工される領域のいずれか一方または両方の領域以外に形成されていることを特徴とする絶縁シート。 - 前記絶縁樹脂層は、切断及び曲げ加工の位置を始点として両側の、10μm~5mmの幅以外の領域に形成されていることを特徴とする請求項1に記載の絶縁シート。
- 前記基材を重ねる場合は、前記基材の重なる領域以外の領域に前記絶縁樹脂層が形成されていることを特徴とする請求項1または請求項2に記載の絶縁シート。
- 前記基材の重なる領域周縁部の、前記基材の重なる領域の境界線から10μm~5mmの範囲以外の領域に前記絶縁樹脂層が形成されていることを特徴とする請求項3に記載の絶縁シート。
- 前記熱硬化性樹脂組成物は、粒状の無機充填剤を有し、
前記無機充填剤は、最大粒径が前記絶縁樹脂層の厚みよりも小さく、平均粒径が前記絶縁樹脂層の厚みの0.5倍よりも小さいことを特徴とする請求項1から請求項4のいずれか一項に記載の絶縁シート。 - 前記基材が、貫通孔を有していることを特徴とする請求項5に記載の絶縁シート。
- 前記貫通孔の前記基材の表面に平行な方向のサイズは、前記無機充填剤の最小粒径よりも大きく、最大粒径の100倍以下であり、かつ、前記貫通孔の前記基材の表面の面内比率は、5%から95%の範囲内であることを特徴とする請求項6に記載の絶縁シート。
- 前記貫通孔の前記基材の表面に平行な方向のサイズは、前記無機充填剤の平均粒径以上であることを特徴とする請求項7に記載の絶縁シート。
- 前記基材は、アラミド紙、クラフト紙、クレープ紙、エンジニアリングプラスチック、スーパーエンジニアリングプラスチック、シリカ、またはアルミナの少なくとも1種類以上から構成される材料からなることを特徴とする請求項1から請求項8のいずれか一項に記載の絶縁シート。
- 前記基材は、前記絶縁紙及び前記絶縁フィルムのいずれか一方または両方が積層されていることを特徴とする請求項1から請求項9のいずれか一項に記載の絶縁シート。
- 複数の前記基材が前記絶縁樹脂層または接着剤を介して積層されており、一端部または両端部の前記基材に前記絶縁樹脂層が形成されていることを特徴とする請求項1から請求項10のいずれか一項に記載の絶縁シート。
- 前記熱硬化性樹脂(A)及び前記熱硬化性樹脂(B)は、エポキシ樹脂、フェノール樹脂、及び不飽和ポリエステル樹脂の少なくとも1つを含むことを特徴とする請求項1から請求項11のいずれか一項に記載の絶縁シート。
- 前記熱硬化性樹脂(A)は、軟化点が50℃から160℃の範囲にあるエポキシ樹脂であることを特徴とする請求項1から請求項12のいずれか一項に記載の絶縁シート。
- 前記潜在性硬化剤は、三フッ化ホウ素-アミン錯体、ジシアンジアミド、有機酸ヒドラジッドのいずれかであることを特徴とする請求項1から請求項13のいずれか一項に記載の絶縁シート。
- 前記熱硬化性樹脂組成物は、重量平均分子量が10,000から100,000の範囲である熱可塑性樹脂を含み、前記熱可塑性樹脂は、前記熱硬化性樹脂(A)と前記熱硬化性樹脂(B)の合計100質量部に対して1質量部から40質量部の範囲であることを特徴とする請求項1から請求項14のいずれか一項に記載の絶縁シート。
- 前記絶縁樹脂層は、前記熱硬化性樹脂組成物の全質量100重量部に対して不揮発分が97質量部以上であることを特徴とする請求項1から請求項15のいずれか一項に記載の絶縁シート。
- 前記絶縁樹脂層は、25℃での貯蔵せん断弾性率が1.0×103Paから5.0×104Paの範囲であり、貯蔵せん断弾性率の最低値が80℃から150℃の範囲にあって10Paから2.0×103Paの範囲であることを特徴とする請求項1から請求項16のいずれか一項に記載の絶縁シート。
- 前記絶縁樹脂層は、25℃での複素粘度が6.0×102Pa・sから1.0×104Pa・sの範囲であり、複素粘度の最低値が80℃から150℃の範囲にあって5.0×102Pa・s以下であることを特徴とする請求項1から請求項17のいずれか一項に記載の絶縁シート。
- 前記絶縁樹脂層の膜厚は、絶縁対象の部材同士の隙間の寸法から前記基材の厚みを差し引いた寸法の1.1倍から2.0倍の範囲に設定されることを特徴とする請求項1から請求項18のいずれか一項に記載の絶縁シート。
- 前記絶縁樹脂層は、融点が100℃以下で、硬化開始温度が前記融点より5℃以上高いことを特徴とする請求項1から請求項19のいずれか一項に記載の絶縁シート。
- 請求項1から請求項20のいずれか一項に記載の絶縁シートが用いられ、固定子鉄心のスロット内に固定子コイルが収納された回転電機であって、
前記絶縁樹脂層をなす前記熱硬化性樹脂組成物が硬化された状態の前記絶縁シートが、前記スロットの内壁と前記固定子コイルとの間に配置され、前記固定子鉄心と前記固定子コイルとを絶縁及び固着していることを特徴とする回転電機。 - 前記絶縁樹脂層は、前記固定子鉄心及び前記固定子コイルとの接着力が20N/m以上であることを特徴とする請求項21記載の回転電機。
- 絶縁紙及び絶縁フィルムのいずれか一方または両方を基材とし、未硬化または半硬化の状態の熱硬化性樹脂組成物からなる絶縁樹脂層が前記基材の片面または両面に形成された絶縁シートの製造方法であって、
25℃で固体の熱硬化性樹脂(A)と、25℃で液状の熱硬化性樹脂(B)と、60℃以下で反応不活性な潜在性硬化剤と、最大粒径が前記絶縁樹脂層の膜厚よりも小さく平均粒径が前記膜厚の0.5倍よりも小さい無機充填剤と、希釈用有機溶剤とを攪拌混合して前記熱硬化性樹脂組成物のスラリーを作製する第1の工程と、
前記スラリーを前記基材または離型紙または離型フィルムに切断される領域、折り曲げ成形の加工される領域のいずれか一方または両方の領域を除く部分に塗布し乾燥させる第2の工程を含み、
前記第1の工程において、前記熱硬化性樹脂組成物は、前記熱硬化性樹脂(A)と前記熱硬化性樹脂(B)の合計100質量部に対して、前記熱硬化性樹脂(A)を10質量部から90質量部の範囲としたことを特徴とする絶縁シートの製造方法。 - 前記第2の工程において前記スラリーを前記離型紙または前記離型フィルムに塗布した場合、前記第2の工程で乾燥させた前記熱硬化性樹脂組成物を未塗布の前記基材の片面または両面に圧着させて貼り付ける第3の工程を行うことを特徴とする請求項23に記載の絶縁シートの製造方法。
Priority Applications (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2021093416A JP7237111B2 (ja) | 2021-06-03 | 2021-06-03 | 絶縁シート及びその製造方法、並びに回転電機 |
CN202210594268.7A CN115506177B (zh) | 2021-06-03 | 2022-05-27 | 绝缘片及其制造方法和旋转电机 |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2021093416A JP7237111B2 (ja) | 2021-06-03 | 2021-06-03 | 絶縁シート及びその製造方法、並びに回転電機 |
Publications (2)
Publication Number | Publication Date |
---|---|
JP2022185658A true JP2022185658A (ja) | 2022-12-15 |
JP7237111B2 JP7237111B2 (ja) | 2023-03-10 |
Family
ID=84441842
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP2021093416A Active JP7237111B2 (ja) | 2021-06-03 | 2021-06-03 | 絶縁シート及びその製造方法、並びに回転電機 |
Country Status (2)
Country | Link |
---|---|
JP (1) | JP7237111B2 (ja) |
CN (1) | CN115506177B (ja) |
Families Citing this family (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN116526239B (zh) * | 2023-07-05 | 2023-09-05 | 广安超达鑫机电制造有限公司 | 潮湿场景用空心杯电机换向片、换向器及空心杯电机 |
Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2004236457A (ja) * | 2003-01-31 | 2004-08-19 | Honda Motor Co Ltd | 固定子および固定子の製造方法 |
JP2006310627A (ja) * | 2005-04-28 | 2006-11-09 | Kyocer Slc Technologies Corp | 配線基板およびその製造方法 |
JP6824372B1 (ja) * | 2019-12-17 | 2021-02-03 | 三菱電機株式会社 | 絶縁シート及びその製造方法、並びに回転電機 |
Family Cites Families (15)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS6127347A (ja) * | 1984-07-17 | 1986-02-06 | Toyoda Autom Loom Works Ltd | 自動変速機付き産業車両におけるインチング制御装置 |
JP5242075B2 (ja) * | 2007-04-12 | 2013-07-24 | 東芝産業機器製造株式会社 | 回転電機の相間絶縁紙及び固定子 |
JP5157296B2 (ja) * | 2007-07-27 | 2013-03-06 | アイシン・エィ・ダブリュ株式会社 | モータ用ステータ及びその製造方法 |
US20100297453A1 (en) * | 2007-09-05 | 2010-11-25 | Hiroshi Maenaka | Insulating sheet and multilayer structure |
JP2010239787A (ja) * | 2009-03-31 | 2010-10-21 | Aisin Aw Co Ltd | コア絶縁部材の製造方法 |
WO2012014875A1 (ja) * | 2010-07-30 | 2012-02-02 | 京セラ株式会社 | 絶縁シート、その製造方法及びその絶縁シートを用いた構造体の製造方法 |
CN105074909B (zh) * | 2013-03-15 | 2017-09-26 | 三菱电机株式会社 | 导热性绝缘片、功率模块及其制造方法 |
JP6069475B2 (ja) * | 2015-12-16 | 2017-02-01 | 株式会社日立製作所 | 回転電機 |
JP6636343B2 (ja) * | 2016-01-21 | 2020-01-29 | 昭和電工パッケージング株式会社 | ラミネート包材 |
KR102448234B1 (ko) * | 2016-11-08 | 2022-09-28 | 듀폰 테이진 어드밴스드 페이퍼 가부시끼가이샤 | 절연 부재 및 그의 제조 방법 |
JP6959778B2 (ja) * | 2017-07-13 | 2021-11-05 | 株式会社デンソー | 回転電機の固定子、及びその固定子の製造方法 |
JP6670279B2 (ja) * | 2017-10-05 | 2020-03-18 | 本田技研工業株式会社 | 絶縁紙及び回転電機のステータ |
JP2019106842A (ja) * | 2017-12-14 | 2019-06-27 | トヨタ自動車株式会社 | 電動機のステータ |
JP7215164B2 (ja) * | 2018-12-28 | 2023-01-31 | 東洋インキScホールディングス株式会社 | 熱伝導性絶縁接着シート、及び該シートの製造方法 |
JP6914309B2 (ja) * | 2019-10-31 | 2021-08-04 | 三菱電機株式会社 | シート型絶縁ワニス及びその製造方法、電気機器、並びに回転電機 |
-
2021
- 2021-06-03 JP JP2021093416A patent/JP7237111B2/ja active Active
-
2022
- 2022-05-27 CN CN202210594268.7A patent/CN115506177B/zh active Active
Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2004236457A (ja) * | 2003-01-31 | 2004-08-19 | Honda Motor Co Ltd | 固定子および固定子の製造方法 |
JP2006310627A (ja) * | 2005-04-28 | 2006-11-09 | Kyocer Slc Technologies Corp | 配線基板およびその製造方法 |
JP6824372B1 (ja) * | 2019-12-17 | 2021-02-03 | 三菱電機株式会社 | 絶縁シート及びその製造方法、並びに回転電機 |
Also Published As
Publication number | Publication date |
---|---|
JP7237111B2 (ja) | 2023-03-10 |
CN115506177B (zh) | 2023-11-14 |
CN115506177A (zh) | 2022-12-23 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
JP6824372B1 (ja) | 絶縁シート及びその製造方法、並びに回転電機 | |
JP6914309B2 (ja) | シート型絶縁ワニス及びその製造方法、電気機器、並びに回転電機 | |
JP6022546B2 (ja) | 硬化性放熱組成物 | |
JP3617417B2 (ja) | 接着剤、接着部材、接着部材を備えた半導体搭載用配線基板及びこれを用いた半導体装置 | |
JP2008244464A (ja) | 熱硬化型ダイボンドフィルム | |
JP2007302881A (ja) | 接着剤組成物及び接着シート | |
JP5390209B2 (ja) | 熱硬化型ダイボンドフィルム | |
JPWO2018008450A1 (ja) | フィルム用樹脂組成物、フィルム、基材付フィルム、金属/樹脂積層体、樹脂硬化物、半導体装置、および、フィルム製造方法 | |
JP6282626B2 (ja) | 中空型電子デバイス封止用シート、及び、中空型電子デバイスパッケージの製造方法 | |
JP7237111B2 (ja) | 絶縁シート及びその製造方法、並びに回転電機 | |
JP5532575B2 (ja) | 接着シート | |
JP7513015B2 (ja) | 接着剤組成物、フィルム状接着剤、接着シート、及び半導体装置の製造方法 | |
JP2008274259A (ja) | 接着シート | |
JP7058704B1 (ja) | 絶縁シート及びその製造方法、並びに回転電機 | |
JP4556472B2 (ja) | 接着剤、接着部材、接着部材を備えた半導体搭載用配線基板及びこれを用いた半導体装置 | |
TWI722115B (zh) | 三次元積體積層電路製造用板片以及三次元積體積層電路之製造方法 | |
TWI701800B (zh) | 三次元積體積層電路製造用板片以及三次元積體積層電路之製造方法 | |
WO2023162068A1 (ja) | シート型絶縁ワニス及びその製造方法、電気機器、並びに回転電機 | |
JP4934895B2 (ja) | 接着剤組成物、接着フィルム、半導体搭載用配線基板及び半導体装置 | |
JP2016190964A (ja) | 接着フィルム | |
KR20190059648A (ko) | 접착제 조성물 및 이를 사용한 접착필름 | |
JP6174293B1 (ja) | 三次元集積積層回路製造用シートおよび三次元集積積層回路の製造方法 | |
JPWO2020075663A1 (ja) | 樹脂組成物、樹脂硬化物および複合成形体 | |
JP2017045934A (ja) | 接着フィルム | |
JP2012246340A (ja) | 接着シート |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
A621 | Written request for application examination |
Free format text: JAPANESE INTERMEDIATE CODE: A621 Effective date: 20210603 |
|
A131 | Notification of reasons for refusal |
Free format text: JAPANESE INTERMEDIATE CODE: A131 Effective date: 20220830 |
|
A521 | Request for written amendment filed |
Free format text: JAPANESE INTERMEDIATE CODE: A523 Effective date: 20221003 |
|
TRDD | Decision of grant or rejection written | ||
A01 | Written decision to grant a patent or to grant a registration (utility model) |
Free format text: JAPANESE INTERMEDIATE CODE: A01 Effective date: 20230131 |
|
A61 | First payment of annual fees (during grant procedure) |
Free format text: JAPANESE INTERMEDIATE CODE: A61 Effective date: 20230228 |
|
R151 | Written notification of patent or utility model registration |
Ref document number: 7237111 Country of ref document: JP Free format text: JAPANESE INTERMEDIATE CODE: R151 |