JP2022123062A - カプセル封入された光吸収剤を含む眼鏡用レンズ - Google Patents
カプセル封入された光吸収剤を含む眼鏡用レンズ Download PDFInfo
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Abstract
Description
- モノマー又はオリゴマーの重合を開始するための触媒の存在下で、少なくとも1種のアリル又は非アリルモノマー又はオリゴマーを重合することによって得られるマトリックス;並びに
- 少なくとも1種の光吸収剤を含むナノ粒子であって前記マトリックスの中に分散されているナノ粒子;
を含有する複合基材を含む眼鏡用レンズであって:
- ナノ粒子が光吸収剤をカプセル封入している眼鏡用レンズである。
a)マトリックスを調製することができるモノマー又はオリゴマーを準備する工程;
b)モノマー又はオリゴマーの中に分散可能な粉末の形態であるか、モノマー又はオリゴマーの中に分散可能な液体中のナノ粒子の分散液の形態のいずれかで、光吸収剤をカプセル封入しているナノ粒子を調製する工程;
c)前記モノマー又はオリゴマーの重合を開始するための触媒を準備する工程;
d)ナノ粒子が分散されている重合性液体組成物を得るために、モノマー又はオリゴマーと、ナノ粒子と、触媒とを混合する工程;
e)任意選択的に重合性液体組成物を基材上に堆積させる工程;
f)重合性液体組成物を硬化させる工程;
を含む、本発明の眼鏡用レンズの作製方法である。
・ アルキル(メタ)アクリレート、特には
-アダマンチン、ノルボルネン、イソボルネン、シクロペンタジエン、又はジシクロペンタジエンから誘導された(メタ)アクリレート、
-メチル(メタ)アクリレート及びエチル(メタ)アクリレートなどのC1~C4アルキル(メタ)アクリレート;
・ ベンジル(メタ)アクリレート、フェノキシ(メタ)アクリレート、又はフルオレン(メタ)アクリレートなどの芳香族(メタ)アクリレート;
・ ビスフェノールから、特にはビスフェノールAから誘導される(メタ)アクリレート;
・ ポリエトキシル化ビスフェノレートジ(メタ)アクリレート、ポリエトキシル化フェノール(メタ)アクリレートなどのポリアルコキシル化芳香族(メタ)アクリレート;
・ ポリチオ(メタ)アクリレート;
・ アルキル(メタ)アクリル酸とポリオール又はエポキシとのエステル化生成物;
・ 並びにこれらの混合物。
a)少なくとも1種のモノマー又はオリゴマー、
b)前記モノマー又はオリゴマーの重合を開始するための少なくとも1種の触媒;
c)前記モノマー又はオリゴマー中に分散されているナノ粒子に含まれる少なくとも1種の光吸収剤;
を含有する。
本発明による眼鏡用レンズの作製を行うための方法は:
a)マトリックスを調製することができるモノマー又はオリゴマーを準備する工程;
b)モノマー又はオリゴマーの中に分散可能な粉末の形態であるか、モノマー又はオリゴマーの中に分散可能な液体中のナノ粒子の分散液の形態のいずれかで、光吸収剤をカプセル封入しているナノ粒子を調製する工程;
c)前記モノマー又はオリゴマーの重合を開始するための触媒を準備する工程;
d)ナノ粒子が分散されている重合性液体組成物を得るために、モノマー又はオリゴマーと、ナノ粒子と、触媒とを混合する工程;
e)任意選択的に重合性液体組成物を基材上に堆積させる工程;
f)重合性液体組成物を硬化させる工程;
を含む。
本発明は、モノマー又はオリゴマーの重合を開始するための触媒による前記光吸収剤の分解を防止するためにナノ粒子中に含まれている光吸収剤の使用にも関する。触媒による光吸収剤の分解の防止は、重合前の組成物の吸収スペクトルを重合後の眼鏡用レンズのものと比較することによって評価することができる。吸収スペクトルが光吸収剤の最大吸収波長で同じ透過率の低下を示す場合、光吸収剤は重合中に触媒によって分解されないとみなすことができる。
以降の測定は、イソプロピルアルコールで洗浄された、中心の厚さが2mmのレンズに対して行う。
実施例では次の化合物を使用する:
メチルメタクリレートとエチレングリコールジメタクリレートとから50:50の重量比でモノマーブレンド物(5g)を調製し、このモノマーブレンド物の中にOMNISTAB(商標)47(10mg、Deltachem Co.Ltdから入手可能)を溶解させる。このブレンド物を、窒素雰囲気下、80℃でSDS(0.5g)及びAIVN(0.05g)を含有する50mlの水溶液に滴下する。モノマーブレンド物の添加が完了した後、混合物を更に2時間、80℃で更に混合し、次いで遠心分離し、エタノールで洗浄し、乾燥する。ナノ粒子は、200nm~1000nmの範囲のサイズ及び1.5の屈折率を有する。
実施例2a:シクロヘキサン(7.5ml)、n-ヘキサノール(1.8ml)、Triton X-100(1.5g)、OMNISTAB(商標)47(40mg、Deltachem Co;Ltdから入手可能)、TEOS(0.1ml)、及び水酸化アンモニウム30%(0.06ml)の混合物を24時間混合する。その後、アセトンを添加し、粒子を遠心分離によって回収し、エタノールで洗浄して乾燥させる。ナノ粒子は、100nmを中心とする単分散のサイズ、及び約1.47の沈降シリカに対応する屈折率を有する。
実施例3a:実施例2cで得たナノ粒子を36.5重量%のテトラブチルオルトチタネート(TBOT)の水溶液の中に入れる。
384mLのメタノールを1000mlの瓶に入れる。次いで、96mlのNH4OH(30重量%水溶液)及び6.4mlのメチレンブルー(CAS:61-73-4、2重量%の脱イオン水溶液)を添加する。混合物を400rpmで10分間撹拌する(磁気撹拌)。その後、3.2mlのTEOSを滴下し、800rpmで2時間撹拌する。
実施例4で得たナノ粒子を36.5重量%のテトラブチルオルトチタネート(TBOT)の水溶液の中に入れる。
Claims (13)
- - モノマー又はオリゴマーの重合を開始するための触媒の存在下で、少なくとも1種のアリル又は非アリルモノマー又はオリゴマーを重合することによって得られるマトリックス;並びに
- 少なくとも1種の光吸収剤を含むナノ粒子であって前記マトリックスの中に分散されているナノ粒子;
を含有する複合基材を含む眼鏡用レンズであって;
- 前記ナノ粒子が光吸収剤をカプセル封入しており、
- 前記光吸収剤がフォトクロミック染料ではない、眼鏡用レンズ。 - 前記マトリックスが、ポリアミド、ポリイミド、ポリスルホン、ポリカーボネート、ポリエチレンテレフタレート、ポリ(メチル(メタ)アクリレート)、セルローストリアセテート、又はこれらのコポリマーなどの熱可塑性樹脂から選択される、あるいは環状オレフィンコポリマー、アリルエステルのホモポリマー又はコポリマー、直鎖又は分岐の脂肪族又は芳香族ポリオールの炭酸アリルのホモポリマー又はコポリマー、(メタ)アクリル酸及びそのエステルのホモポリマー又はコポリマー、チオ(メタ)アクリル酸及びそのエステルのホモポリマー又はコポリマー、ウレタン及びチオウレタンのホモポリマー又はコポリマー、エポキシのホモポリマー又はコポリマー、スルフィドのホモポリマー又はコポリマー、ジスルフィドのホモポリマー又はコポリマー、エピスルフィドのホモポリマー又はコポリマー、チオール及びイソシアネートのホモポリマー又はコポリマーなどの熱硬化性樹脂、並びにこれらの組み合わせから選択される、請求項1に記載の眼鏡用レンズ。
- 前記光吸収剤が、染料又は顔料などの着色剤、無色の光吸収剤、又はこれらの混合物から選択される、請求項1又は2に記載の眼鏡用レンズ。
- 前記光吸収剤のモル吸光係数が5000より大きい、請求項1~3のいずれか1項に記載の眼鏡用レンズ。
- 前記ナノ粒子が、内側から外側まで均質な組成を有し、その中に前記光吸収剤が均一に分布している、請求項1~4のいずれか1項に記載の眼鏡用レンズ。
- 前記ナノ粒子が、前記光吸収剤を含有するコアと前記コアを囲むシェルとを有する、請求項1~5のいずれか1項に記載の眼鏡用レンズ。
- 前記ナノ粒子が有機化合物を全く含まない外表面を示す、請求項1~6のいずれか1項に記載の眼鏡用レンズ。
- 前記ナノ粒子が、SiO2、TiO2、ZrO2、Al2O3、又はこれらの混合物などの無機酸化物を含む、請求項1~7のいずれか1項に記載の眼鏡用レンズ。
- ISO489:1999に従って測定される前記ナノ粒子の屈折率が1.47~1.74であり、好ましくは前記ナノ粒子の屈折率が前記ポリマーマトリックスの屈折率と同一である、請求項1~8のいずれか1項に記載の眼鏡用レンズ。
- 動的光散乱法に従って測定される前記ナノ粒子のサイズが1nm~10μm、好ましくは10nm~5μmである、請求項1~9のいずれか1項に記載の眼鏡用レンズ。
- 前記ナノ粒子中の前記光吸収剤の量が、前記ナノ粒子の総重量を基準として0.0001~90重量%、特には0.01~50重量%、より具体的には0.1~10重量%である、請求項1~10のいずれか1項に記載の眼鏡用レンズ。
- 前記ポリマーマトリックス中の前記ナノ粒子の量が、前記ポリマーマトリックスの重量を基準として0.01~2重量%、好ましくは0.05~1重量%である、請求項1~11のいずれか1項に記載の眼鏡用レンズ。
- a)マトリックスを調製することができるモノマー又はオリゴマーを準備する工程;
b)前記モノマー又はオリゴマーの中に分散可能な粉末の形態であるか、前記モノマー又はオリゴマーの中に分散可能な液体中のナノ粒子の分散液の形態のいずれかで、光吸収剤をカプセル封入しているナノ粒子を調製する工程;
c)前記モノマー又はオリゴマーの重合を開始するための触媒を準備する工程;
d)前記ナノ粒子が分散されている重合性液体組成物を得るために、前記モノマー又はオリゴマーと、前記ナノ粒子と、前記触媒とを混合する工程;
e)任意選択的に前記重合性液体組成物を基材上に堆積させる工程;
f)前記重合性液体組成物を硬化させる工程;
を含む、請求項1~12のいずれか1項に記載の眼鏡用レンズの作製方法。
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