JP2020176213A - 難燃性樹脂組成物、成形体及び樹脂繊維 - Google Patents
難燃性樹脂組成物、成形体及び樹脂繊維 Download PDFInfo
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- JP2020176213A JP2020176213A JP2019079664A JP2019079664A JP2020176213A JP 2020176213 A JP2020176213 A JP 2020176213A JP 2019079664 A JP2019079664 A JP 2019079664A JP 2019079664 A JP2019079664 A JP 2019079664A JP 2020176213 A JP2020176213 A JP 2020176213A
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- AYEKOFBPNLCAJY-UHFFFAOYSA-O thiamine pyrophosphate Chemical compound CC1=C(CCOP(O)(=O)OP(O)(O)=O)SC=[N+]1CC1=CN=C(C)N=C1N AYEKOFBPNLCAJY-UHFFFAOYSA-O 0.000 description 1
- YNJBWRMUSHSURL-UHFFFAOYSA-N trichloroacetic acid Chemical compound OC(=O)C(Cl)(Cl)Cl YNJBWRMUSHSURL-UHFFFAOYSA-N 0.000 description 1
- BIKXLKXABVUSMH-UHFFFAOYSA-N trizinc;diborate Chemical compound [Zn+2].[Zn+2].[Zn+2].[O-]B([O-])[O-].[O-]B([O-])[O-] BIKXLKXABVUSMH-UHFFFAOYSA-N 0.000 description 1
- UGZADUVQMDAIAO-UHFFFAOYSA-L zinc hydroxide Chemical compound [OH-].[OH-].[Zn+2] UGZADUVQMDAIAO-UHFFFAOYSA-L 0.000 description 1
- 229940007718 zinc hydroxide Drugs 0.000 description 1
- 229910021511 zinc hydroxide Inorganic materials 0.000 description 1
- 239000011787 zinc oxide Substances 0.000 description 1
- LRXTYHSAJDENHV-UHFFFAOYSA-H zinc phosphate Chemical compound [Zn+2].[Zn+2].[Zn+2].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O LRXTYHSAJDENHV-UHFFFAOYSA-H 0.000 description 1
- 229910000165 zinc phosphate Inorganic materials 0.000 description 1
- CZPRKINNVBONSF-UHFFFAOYSA-M zinc;dioxido(oxo)phosphanium Chemical compound [Zn+2].[O-][P+]([O-])=O CZPRKINNVBONSF-UHFFFAOYSA-M 0.000 description 1
Landscapes
- Compositions Of Macromolecular Compounds (AREA)
Abstract
Description
(B)非ハロゲン系難燃剤を1〜40質量部含むことを特徴とする。以下、各成分について、詳細に説明する。
本発明の(B)非ハロゲン系難燃剤としては、窒素系難燃剤が好ましく、メラミンシアヌレートが特に好ましい。
特にテトラフルオロエチレンポリマーは成形体が燃焼した際の滴下防止の目的で好適に使用される。
(1)機械特性
引張弾性率および引張強度については、JIS K7161に準じて測定した。
(2)難燃性
UL94の垂直燃焼試験に従い評価した。
(1)ナイロン6(アラミンCM1017、東レ(株)製)
(2)リグノフェノール
杉の木粉をp−クレゾールを含むアセトン溶液に浸漬して、木粉にp−クレゾールを吸着させた後、72質量%の硫酸を添加して激しく撹拌した。撹拌後の液に、ヘキサンを加え、更に撹拌した後に水を加え放置し、上澄みである水層、および油層を除去し、残った固形物を水洗し、メタノールに溶解させた。固形分を分離した後、得られたメタノール溶液に、塩を溶かした水を加えて水晶析してリグノフェノールを析出させた。析出したリグノフェノールを分離し、重曹水を用いて洗浄・ろ過を繰り返した。固形分を水に分散させたときのpHが中性になるまで重曹水での洗浄を繰り返した後、固形分を乾燥したものを使用した。
(3)メラミンシアヌレート(MC−4000、日産化学(株)製)
(4)ポリリン酸メラミン(ホスメル200、日産化学(株)製)
(5)トリフェニルホスフェート(TPP、大八化学工業(株)製)
Claims (5)
- (a1)ポリアミド樹脂97〜40質量%、(a2)リグノフェノール3〜60質量%からなる(A)熱可塑性樹脂組成物100質量部に対し、
(B)非ハロゲン系難燃剤を1〜40質量部含むことを特徴とする難燃性樹脂組成物。 - 前記(B)非ハロゲン系難燃剤が窒素系難燃剤であることを特徴とする請求項1に記載の難燃性樹脂組成物。
- 前記(B)非ハロゲン系難燃剤がメラミンシアヌレートであることを特徴とする請求項1または2に記載の難燃性樹脂組成物。
- 請求項1から3のいずれか1項に記載の難燃性樹脂組成物を成形してなることを特徴とした成形体。
- 請求項1から3のいずれか1項に記載の難燃性樹脂組成物を押出成形してなることを特徴とした樹脂繊維。
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