JP2019535887A - ポリブタジエンとポリイソプレンとの高シス−1,4ブロックコポリマー - Google Patents
ポリブタジエンとポリイソプレンとの高シス−1,4ブロックコポリマー Download PDFInfo
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- JP2019535887A JP2019535887A JP2019545907A JP2019545907A JP2019535887A JP 2019535887 A JP2019535887 A JP 2019535887A JP 2019545907 A JP2019545907 A JP 2019545907A JP 2019545907 A JP2019545907 A JP 2019545907A JP 2019535887 A JP2019535887 A JP 2019535887A
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- JP
- Japan
- Prior art keywords
- block copolymer
- monomer
- lanthanide
- neodymium
- chloride
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- 229920001400 block copolymer Polymers 0.000 title claims abstract description 103
- 239000005062 Polybutadiene Substances 0.000 title claims abstract description 54
- 229920002857 polybutadiene Polymers 0.000 title claims abstract description 33
- 229920001195 polyisoprene Polymers 0.000 title claims abstract description 31
- 239000000203 mixture Substances 0.000 claims abstract description 172
- 229920001971 elastomer Polymers 0.000 claims abstract description 98
- 239000005060 rubber Substances 0.000 claims abstract description 87
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 41
- 239000000945 filler Substances 0.000 claims abstract description 18
- 239000003054 catalyst Substances 0.000 claims description 118
- 150000001875 compounds Chemical class 0.000 claims description 117
- -1 aluminum hydride compound Chemical class 0.000 claims description 106
- 239000000178 monomer Substances 0.000 claims description 96
- 229910052747 lanthanoid Inorganic materials 0.000 claims description 95
- 150000002602 lanthanoids Chemical class 0.000 claims description 89
- 229920000642 polymer Polymers 0.000 claims description 77
- 238000006116 polymerization reaction Methods 0.000 claims description 76
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 claims description 65
- RRHGJUQNOFWUDK-UHFFFAOYSA-N Isoprene Chemical compound CC(=C)C=C RRHGJUQNOFWUDK-UHFFFAOYSA-N 0.000 claims description 51
- 238000000034 method Methods 0.000 claims description 45
- 229910052736 halogen Inorganic materials 0.000 claims description 35
- 150000002367 halogens Chemical class 0.000 claims description 35
- 229910052782 aluminium Inorganic materials 0.000 claims description 21
- 150000002430 hydrocarbons Chemical group 0.000 claims description 15
- 229910052799 carbon Inorganic materials 0.000 claims description 14
- 125000004432 carbon atom Chemical group C* 0.000 claims description 13
- 150000007942 carboxylates Chemical group 0.000 claims description 11
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical group [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 8
- 238000004519 manufacturing process Methods 0.000 claims description 8
- 150000004703 alkoxides Chemical group 0.000 claims description 7
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims description 7
- 230000000379 polymerizing effect Effects 0.000 claims description 6
- 125000000962 organic group Chemical group 0.000 claims description 5
- 239000003381 stabilizer Substances 0.000 claims 2
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 71
- 229910052779 Neodymium Inorganic materials 0.000 description 60
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 60
- QEFYFXOXNSNQGX-UHFFFAOYSA-N neodymium atom Chemical compound [Nd] QEFYFXOXNSNQGX-UHFFFAOYSA-N 0.000 description 52
- 239000000243 solution Substances 0.000 description 29
- 239000000377 silicon dioxide Substances 0.000 description 28
- 150000001450 anions Chemical class 0.000 description 27
- 239000002168 alkylating agent Substances 0.000 description 26
- 229940100198 alkylating agent Drugs 0.000 description 26
- 239000002904 solvent Substances 0.000 description 24
- 125000001183 hydrocarbyl group Chemical group 0.000 description 19
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 18
- 239000003921 oil Substances 0.000 description 18
- 235000019198 oils Nutrition 0.000 description 18
- 238000006243 chemical reaction Methods 0.000 description 17
- 229920003052 natural elastomer Polymers 0.000 description 16
- 229920001194 natural rubber Polymers 0.000 description 16
- 244000043261 Hevea brasiliensis Species 0.000 description 15
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 15
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 14
- 239000006229 carbon black Substances 0.000 description 14
- 229920013730 reactive polymer Polymers 0.000 description 14
- 229930195733 hydrocarbon Natural products 0.000 description 13
- 238000001723 curing Methods 0.000 description 12
- 125000005843 halogen group Chemical group 0.000 description 12
- CPOFMOWDMVWCLF-UHFFFAOYSA-N methyl(oxo)alumane Chemical compound C[Al]=O CPOFMOWDMVWCLF-UHFFFAOYSA-N 0.000 description 12
- ACVYVLVWPXVTIT-UHFFFAOYSA-M phosphinate Chemical compound [O-][PH2]=O ACVYVLVWPXVTIT-UHFFFAOYSA-M 0.000 description 12
- 150000003512 tertiary amines Chemical class 0.000 description 12
- 239000000806 elastomer Substances 0.000 description 11
- 238000002156 mixing Methods 0.000 description 11
- 239000002243 precursor Substances 0.000 description 11
- 125000001204 arachidyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 10
- 229920001577 copolymer Polymers 0.000 description 10
- 150000001993 dienes Chemical class 0.000 description 10
- 150000002901 organomagnesium compounds Chemical class 0.000 description 10
- SIPUZPBQZHNSDW-UHFFFAOYSA-N bis(2-methylpropyl)aluminum Chemical compound CC(C)C[Al]CC(C)C SIPUZPBQZHNSDW-UHFFFAOYSA-N 0.000 description 9
- YNLAOSYQHBDIKW-UHFFFAOYSA-M diethylaluminium chloride Chemical compound CC[Al](Cl)CC YNLAOSYQHBDIKW-UHFFFAOYSA-M 0.000 description 9
- 125000003903 2-propenyl group Chemical group [H]C([*])([H])C([H])=C([H])[H] 0.000 description 8
- 239000004594 Masterbatch (MB) Substances 0.000 description 8
- 230000032683 aging Effects 0.000 description 8
- 229940088990 ammonium stearate Drugs 0.000 description 8
- JPNZKPRONVOMLL-UHFFFAOYSA-N azane;octadecanoic acid Chemical compound [NH4+].CCCCCCCCCCCCCCCCCC([O-])=O JPNZKPRONVOMLL-UHFFFAOYSA-N 0.000 description 8
- 150000001721 carbon Chemical group 0.000 description 8
- 125000000392 cycloalkenyl group Chemical group 0.000 description 8
- 125000000524 functional group Chemical group 0.000 description 8
- 238000005227 gel permeation chromatography Methods 0.000 description 8
- 239000003999 initiator Substances 0.000 description 8
- 239000004215 Carbon black (E152) Substances 0.000 description 7
- 125000003118 aryl group Chemical class 0.000 description 7
- 239000006232 furnace black Substances 0.000 description 7
- 239000000126 substance Substances 0.000 description 7
- 238000004073 vulcanization Methods 0.000 description 7
- 230000015572 biosynthetic process Effects 0.000 description 6
- 238000005516 engineering process Methods 0.000 description 6
- 238000009472 formulation Methods 0.000 description 6
- 230000009477 glass transition Effects 0.000 description 6
- 229910052749 magnesium Inorganic materials 0.000 description 6
- 238000002360 preparation method Methods 0.000 description 6
- IMNFDUFMRHMDMM-UHFFFAOYSA-N N-Heptane Chemical compound CCCCCCC IMNFDUFMRHMDMM-UHFFFAOYSA-N 0.000 description 5
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 5
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical group [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 5
- AZDRQVAHHNSJOQ-UHFFFAOYSA-N alumane Chemical compound [AlH3] AZDRQVAHHNSJOQ-UHFFFAOYSA-N 0.000 description 5
- 239000007795 chemical reaction product Substances 0.000 description 5
- 125000005842 heteroatom Chemical group 0.000 description 5
- 239000003960 organic solvent Substances 0.000 description 5
- 125000004437 phosphorous atom Chemical group 0.000 description 5
- 230000008569 process Effects 0.000 description 5
- MCULRUJILOGHCJ-UHFFFAOYSA-N triisobutylaluminium Chemical compound CC(C)C[Al](CC(C)C)CC(C)C MCULRUJILOGHCJ-UHFFFAOYSA-N 0.000 description 5
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 5
- UZGARMTXYXKNQR-UHFFFAOYSA-K 7,7-dimethyloctanoate;neodymium(3+) Chemical compound [Nd+3].CC(C)(C)CCCCCC([O-])=O.CC(C)(C)CCCCCC([O-])=O.CC(C)(C)CCCCCC([O-])=O UZGARMTXYXKNQR-UHFFFAOYSA-K 0.000 description 4
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 4
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical group [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 description 4
- CPELXLSAUQHCOX-UHFFFAOYSA-M Bromide Chemical compound [Br-] CPELXLSAUQHCOX-UHFFFAOYSA-M 0.000 description 4
- NLZUEZXRPGMBCV-UHFFFAOYSA-N Butylhydroxytoluene Chemical compound CC1=CC(C(C)(C)C)=C(O)C(C(C)(C)C)=C1 NLZUEZXRPGMBCV-UHFFFAOYSA-N 0.000 description 4
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 4
- 238000005481 NMR spectroscopy Methods 0.000 description 4
- 229910019142 PO4 Inorganic materials 0.000 description 4
- 239000004793 Polystyrene Substances 0.000 description 4
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 4
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 4
- 125000003342 alkenyl group Chemical group 0.000 description 4
- 125000002877 alkyl aryl group Chemical group 0.000 description 4
- 125000000217 alkyl group Chemical group 0.000 description 4
- 125000000304 alkynyl group Chemical group 0.000 description 4
- 125000003277 amino group Chemical group 0.000 description 4
- 125000003710 aryl alkyl group Chemical group 0.000 description 4
- 239000012298 atmosphere Substances 0.000 description 4
- 239000011324 bead Substances 0.000 description 4
- 238000009835 boiling Methods 0.000 description 4
- 238000012662 bulk polymerization Methods 0.000 description 4
- 235000010354 butylated hydroxytoluene Nutrition 0.000 description 4
- 150000001768 cations Chemical class 0.000 description 4
- 239000004568 cement Substances 0.000 description 4
- 239000006231 channel black Substances 0.000 description 4
- 239000013066 combination product Substances 0.000 description 4
- 239000012967 coordination catalyst Substances 0.000 description 4
- 125000000753 cycloalkyl group Chemical group 0.000 description 4
- AFABGHUZZDYHJO-UHFFFAOYSA-N dimethyl butane Natural products CCCC(C)C AFABGHUZZDYHJO-UHFFFAOYSA-N 0.000 description 4
- 238000001035 drying Methods 0.000 description 4
- 239000011521 glass Substances 0.000 description 4
- 150000004820 halides Chemical class 0.000 description 4
- 239000003112 inhibitor Substances 0.000 description 4
- 230000003993 interaction Effects 0.000 description 4
- QWTDNUCVQCZILF-UHFFFAOYSA-N isopentane Chemical compound CCC(C)C QWTDNUCVQCZILF-UHFFFAOYSA-N 0.000 description 4
- 239000011777 magnesium Substances 0.000 description 4
- 229910052751 metal Inorganic materials 0.000 description 4
- 239000002184 metal Substances 0.000 description 4
- 125000001117 oleyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])/C([H])=C([H])\C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 4
- NFHFRUOZVGFOOS-UHFFFAOYSA-N palladium;triphenylphosphane Chemical compound [Pd].C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1.C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1.C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1.C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1 NFHFRUOZVGFOOS-UHFFFAOYSA-N 0.000 description 4
- 235000021317 phosphate Nutrition 0.000 description 4
- 150000003013 phosphoric acid derivatives Chemical class 0.000 description 4
- 229920002223 polystyrene Polymers 0.000 description 4
- 238000011084 recovery Methods 0.000 description 4
- 125000005346 substituted cycloalkyl group Chemical group 0.000 description 4
- 229920002554 vinyl polymer Polymers 0.000 description 4
- LQIIEHBULBHJKX-UHFFFAOYSA-N 2-methylpropylalumane Chemical compound CC(C)C[AlH2] LQIIEHBULBHJKX-UHFFFAOYSA-N 0.000 description 3
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
- KXDHJXZQYSOELW-UHFFFAOYSA-M Carbamate Chemical compound NC([O-])=O KXDHJXZQYSOELW-UHFFFAOYSA-M 0.000 description 3
- OFBQJSOFQDEBGM-UHFFFAOYSA-N Pentane Chemical compound CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 description 3
- ABLZXFCXXLZCGV-UHFFFAOYSA-N Phosphorous acid Chemical class OP(O)=O ABLZXFCXXLZCGV-UHFFFAOYSA-N 0.000 description 3
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 3
- 238000005299 abrasion Methods 0.000 description 3
- 150000001338 aliphatic hydrocarbons Chemical class 0.000 description 3
- 150000001336 alkenes Chemical class 0.000 description 3
- 125000000129 anionic group Chemical group 0.000 description 3
- 150000004945 aromatic hydrocarbons Chemical class 0.000 description 3
- 239000011230 binding agent Substances 0.000 description 3
- 238000012512 characterization method Methods 0.000 description 3
- 239000000460 chlorine Substances 0.000 description 3
- 238000010924 continuous production Methods 0.000 description 3
- 239000002270 dispersing agent Substances 0.000 description 3
- MGDOJPNDRJNJBK-UHFFFAOYSA-N ethylaluminum Chemical compound [Al].C[CH2] MGDOJPNDRJNJBK-UHFFFAOYSA-N 0.000 description 3
- UAIZDWNSWGTKFZ-UHFFFAOYSA-L ethylaluminum(2+);dichloride Chemical compound CC[Al](Cl)Cl UAIZDWNSWGTKFZ-UHFFFAOYSA-L 0.000 description 3
- 238000007306 functionalization reaction Methods 0.000 description 3
- 150000002500 ions Chemical class 0.000 description 3
- 150000002601 lanthanoid compounds Chemical class 0.000 description 3
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 3
- 229910052757 nitrogen Inorganic materials 0.000 description 3
- IJGRMHOSHXDMSA-UHFFFAOYSA-N nitrogen Substances N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 3
- 125000004433 nitrogen atom Chemical group N* 0.000 description 3
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 3
- ZQPPMHVWECSIRJ-KTKRTIGZSA-M oleate Chemical compound CCCCCCCC\C=C/CCCCCCCC([O-])=O ZQPPMHVWECSIRJ-KTKRTIGZSA-M 0.000 description 3
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- 230000003647 oxidation Effects 0.000 description 3
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- UEZVMMHDMIWARA-UHFFFAOYSA-M phosphonate Chemical compound [O-]P(=O)=O UEZVMMHDMIWARA-UHFFFAOYSA-M 0.000 description 3
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- 241000894007 species Species 0.000 description 3
- 125000003107 substituted aryl group Chemical group 0.000 description 3
- 229910052717 sulfur Inorganic materials 0.000 description 3
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- 229920003051 synthetic elastomer Polymers 0.000 description 3
- 238000012546 transfer Methods 0.000 description 3
- JLTRXTDYQLMHGR-UHFFFAOYSA-N trimethylaluminium Chemical compound C[Al](C)C JLTRXTDYQLMHGR-UHFFFAOYSA-N 0.000 description 3
- 239000012991 xanthate Substances 0.000 description 3
- LWNGJAHMBMVCJR-UHFFFAOYSA-N (2,3,4,5,6-pentafluorophenoxy)boronic acid Chemical compound OB(O)OC1=C(F)C(F)=C(F)C(F)=C1F LWNGJAHMBMVCJR-UHFFFAOYSA-N 0.000 description 2
- KVNYFPKFSJIPBJ-UHFFFAOYSA-N 1,2-diethylbenzene Chemical compound CCC1=CC=CC=C1CC KVNYFPKFSJIPBJ-UHFFFAOYSA-N 0.000 description 2
- CBXRMKZFYQISIV-UHFFFAOYSA-N 1-n,1-n,1-n',1-n',2-n,2-n,2-n',2-n'-octamethylethene-1,1,2,2-tetramine Chemical compound CN(C)C(N(C)C)=C(N(C)C)N(C)C CBXRMKZFYQISIV-UHFFFAOYSA-N 0.000 description 2
- SDJHPPZKZZWAKF-UHFFFAOYSA-N 2,3-dimethylbuta-1,3-diene Chemical compound CC(=C)C(C)=C SDJHPPZKZZWAKF-UHFFFAOYSA-N 0.000 description 2
- ZFFMLCVRJBZUDZ-UHFFFAOYSA-N 2,3-dimethylbutane Chemical group CC(C)C(C)C ZFFMLCVRJBZUDZ-UHFFFAOYSA-N 0.000 description 2
- RCJMVGJKROQDCB-UHFFFAOYSA-N 2-methylpenta-1,3-diene Chemical compound CC=CC(C)=C RCJMVGJKROQDCB-UHFFFAOYSA-N 0.000 description 2
- VXEGSRKPIUDPQT-UHFFFAOYSA-N 4-[4-(4-methoxyphenyl)piperazin-1-yl]aniline Chemical compound C1=CC(OC)=CC=C1N1CCN(C=2C=CC(N)=CC=2)CC1 VXEGSRKPIUDPQT-UHFFFAOYSA-N 0.000 description 2
- CJSBUWDGPXGFGA-UHFFFAOYSA-N 4-methylpenta-1,3-diene Chemical compound CC(C)=CC=C CJSBUWDGPXGFGA-UHFFFAOYSA-N 0.000 description 2
- ZCYVEMRRCGMTRW-UHFFFAOYSA-N 7553-56-2 Chemical compound [I] ZCYVEMRRCGMTRW-UHFFFAOYSA-N 0.000 description 2
- WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical compound [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 description 2
- FZSGSQRHSIHSJU-UHFFFAOYSA-N CCCCCCCCCCCCCN(C)C(C)C Chemical compound CCCCCCCCCCCCCN(C)C(C)C FZSGSQRHSIHSJU-UHFFFAOYSA-N 0.000 description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 2
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 2
- RGSFGYAAUTVSQA-UHFFFAOYSA-N Cyclopentane Chemical compound C1CCCC1 RGSFGYAAUTVSQA-UHFFFAOYSA-N 0.000 description 2
- 229910000722 Didymium Inorganic materials 0.000 description 2
- 241000224487 Didymium Species 0.000 description 2
- YNQLUTRBYVCPMQ-UHFFFAOYSA-N Ethylbenzene Chemical compound CCC1=CC=CC=C1 YNQLUTRBYVCPMQ-UHFFFAOYSA-N 0.000 description 2
- PXGOKWXKJXAPGV-UHFFFAOYSA-N Fluorine Chemical compound FF PXGOKWXKJXAPGV-UHFFFAOYSA-N 0.000 description 2
- CPELXLSAUQHCOX-UHFFFAOYSA-N Hydrogen bromide Chemical compound Br CPELXLSAUQHCOX-UHFFFAOYSA-N 0.000 description 2
- 239000002879 Lewis base Substances 0.000 description 2
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical group [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 2
- HVTZEGSRSGXTJR-UHFFFAOYSA-N N,N-di(propan-2-yl)icosan-1-amine Chemical compound CCCCCCCCCCCCCCCCCCCCN(C(C)C)C(C)C HVTZEGSRSGXTJR-UHFFFAOYSA-N 0.000 description 2
- PEXACFJGBVSUKG-UHFFFAOYSA-N N-ethyl-N-propan-2-yldecan-1-amine Chemical compound CCCCCCCCCCN(CC)C(C)C PEXACFJGBVSUKG-UHFFFAOYSA-N 0.000 description 2
- NZVDDYGBDVLZIF-UHFFFAOYSA-N N-ethyl-N-propan-2-yldodecan-1-amine Chemical compound CCCCCCCCCCCCN(CC)C(C)C NZVDDYGBDVLZIF-UHFFFAOYSA-N 0.000 description 2
- KAOMNVDHDWDGNZ-UHFFFAOYSA-N N-ethyl-N-propan-2-ylhexadecan-1-amine Chemical compound CCCCCCCCCCCCCCCCN(CC)C(C)C KAOMNVDHDWDGNZ-UHFFFAOYSA-N 0.000 description 2
- GVDAQBMVLIBAEA-UHFFFAOYSA-N N-ethyl-N-propan-2-ylicosan-1-amine Chemical compound CCCCCCCCCCCCCCCCCCCCN(CC)C(C)C GVDAQBMVLIBAEA-UHFFFAOYSA-N 0.000 description 2
- UWJQUCWDQGWIPD-UHFFFAOYSA-N N-ethyl-N-propan-2-yloctan-1-amine Chemical compound CC(C)N(CC)CCCCCCCC UWJQUCWDQGWIPD-UHFFFAOYSA-N 0.000 description 2
- BLUMOYUVFNNISI-UHFFFAOYSA-N N-ethyl-N-propan-2-ylpentadecan-1-amine Chemical compound CCCCCCCCCCCCCCCN(CC)C(C)C BLUMOYUVFNNISI-UHFFFAOYSA-N 0.000 description 2
- ARMRGMLLHCXVCU-UHFFFAOYSA-N N-ethyl-N-propan-2-yltridecan-1-amine Chemical compound CCCCCCCCCCCCCN(CC)C(C)C ARMRGMLLHCXVCU-UHFFFAOYSA-N 0.000 description 2
- LATCXSCEDIDGDS-UHFFFAOYSA-N N-ethyl-N-propan-2-ylundecan-1-amine Chemical compound CCCCCCCCCCCN(CC)C(C)C LATCXSCEDIDGDS-UHFFFAOYSA-N 0.000 description 2
- JSHRIMYKHAKPFA-UHFFFAOYSA-N N-methyl-N-propan-2-ylnonan-1-amine Chemical compound CCCCCCCCCN(C)C(C)C JSHRIMYKHAKPFA-UHFFFAOYSA-N 0.000 description 2
- JUZUZJHYUSQXCI-UHFFFAOYSA-N N-methyl-N-propan-2-yloctan-1-amine Chemical compound CCCCCCCCN(C)C(C)C JUZUZJHYUSQXCI-UHFFFAOYSA-N 0.000 description 2
- FAVNCHJSERDMAY-UHFFFAOYSA-N N-methyl-N-propan-2-ylpentadecan-1-amine Chemical compound CCCCCCCCCCCCCCCN(C)C(C)C FAVNCHJSERDMAY-UHFFFAOYSA-N 0.000 description 2
- DBUMGMIMDHRZLI-UHFFFAOYSA-N N-methyl-N-propan-2-yltetradecan-1-amine Chemical compound CCCCCCCCCCCCCCN(C)C(C)C DBUMGMIMDHRZLI-UHFFFAOYSA-N 0.000 description 2
- RNZNXEFADDWFPZ-UHFFFAOYSA-N N-methyl-N-propan-2-ylundecan-1-amine Chemical compound CCCCCCCCCCCN(C)C(C)C RNZNXEFADDWFPZ-UHFFFAOYSA-N 0.000 description 2
- 239000006057 Non-nutritive feed additive Substances 0.000 description 2
- 229910052772 Samarium Inorganic materials 0.000 description 2
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- 230000006866 deterioration Effects 0.000 description 1
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- GNPSMYTXIPVJDU-UHFFFAOYSA-N dioctylalumane Chemical compound C(CCCCCCC)[AlH]CCCCCCCC GNPSMYTXIPVJDU-UHFFFAOYSA-N 0.000 description 1
- QRQUTSPLBBZERR-UHFFFAOYSA-M dioctylalumanylium;chloride Chemical compound CCCCCCCC[Al](Cl)CCCCCCCC QRQUTSPLBBZERR-UHFFFAOYSA-M 0.000 description 1
- BUHQQXGTFKPOJT-UHFFFAOYSA-K diphenyl phosphate;neodymium(3+) Chemical compound [Nd+3].C=1C=CC=CC=1OP(=O)([O-])OC1=CC=CC=C1.C=1C=CC=CC=1OP(=O)([O-])OC1=CC=CC=C1.C=1C=CC=CC=1OP(=O)([O-])OC1=CC=CC=C1 BUHQQXGTFKPOJT-UHFFFAOYSA-K 0.000 description 1
- HIVRDDZUKVNKAO-UHFFFAOYSA-N diphenylalumane Chemical compound C1(=CC=CC=C1)[AlH]C1=CC=CC=C1 HIVRDDZUKVNKAO-UHFFFAOYSA-N 0.000 description 1
- BEQVQKJCLJBTKZ-UHFFFAOYSA-M diphenylphosphinate Chemical compound C=1C=CC=CC=1P(=O)([O-])C1=CC=CC=C1 BEQVQKJCLJBTKZ-UHFFFAOYSA-M 0.000 description 1
- ZOAWMLSXWXBXIN-UHFFFAOYSA-N dipropyl(tetradecyl)azanium;chloride Chemical compound [Cl-].CCCCCCCCCCCCCC[NH+](CCC)CCC ZOAWMLSXWXBXIN-UHFFFAOYSA-N 0.000 description 1
- FUSURKMRHXNBGD-UHFFFAOYSA-N dipropyl(tridecyl)azanium chloride Chemical compound [Cl-].C(CC)[NH+](CCCCCCCCCCCCC)CCC FUSURKMRHXNBGD-UHFFFAOYSA-N 0.000 description 1
- OWSOJHCWELAMIV-UHFFFAOYSA-N dipropyl(tridecyl)azanium octadecanoate Chemical compound CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCC[NH+](CCC)CCC OWSOJHCWELAMIV-UHFFFAOYSA-N 0.000 description 1
- NPOVDBWJAORNQJ-UHFFFAOYSA-N dipropyl(undecyl)azanium chloride Chemical compound [Cl-].C(CC)[NH+](CCCCCCCCCCC)CCC NPOVDBWJAORNQJ-UHFFFAOYSA-N 0.000 description 1
- AQEOJDQMTZLEIW-UHFFFAOYSA-N dipropyl(undecyl)azanium octadecanoate Chemical compound CCCCCCCCCCC[NH+](CCC)CCC.CCCCCCCCCCCCCCCCCC([O-])=O AQEOJDQMTZLEIW-UHFFFAOYSA-N 0.000 description 1
- XOCWTYIVWYOSGQ-UHFFFAOYSA-N dipropylalumane Chemical compound C(CC)[AlH]CCC XOCWTYIVWYOSGQ-UHFFFAOYSA-N 0.000 description 1
- ZMXPNWBFRPIZFV-UHFFFAOYSA-M dipropylalumanylium;chloride Chemical compound [Cl-].CCC[Al+]CCC ZMXPNWBFRPIZFV-UHFFFAOYSA-M 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- PEGCFRJASNUIPX-UHFFFAOYSA-L ditert-butyltin(2+);dichloride Chemical compound CC(C)(C)[Sn](Cl)(Cl)C(C)(C)C PEGCFRJASNUIPX-UHFFFAOYSA-L 0.000 description 1
- 239000012990 dithiocarbamate Substances 0.000 description 1
- SNRUBQQJIBEYMU-UHFFFAOYSA-N dodecane Chemical group CCCCCCCCCCCC SNRUBQQJIBEYMU-UHFFFAOYSA-N 0.000 description 1
- AEOMEXFKJXASDJ-UHFFFAOYSA-N dodecyl(diethyl)azanium octadecanoate Chemical compound CCCCCCCCCCCC[NH+](CC)CC.CCCCCCCCCCCCCCCCCC([O-])=O AEOMEXFKJXASDJ-UHFFFAOYSA-N 0.000 description 1
- NHXWPSYRAGWTFC-UHFFFAOYSA-N dodecyl(diethyl)azanium;chloride Chemical compound Cl.CCCCCCCCCCCCN(CC)CC NHXWPSYRAGWTFC-UHFFFAOYSA-N 0.000 description 1
- MUEWCPBDYXSWAM-UHFFFAOYSA-N dodecyl(dipropyl)azanium octadecanoate Chemical compound CCCCCCCCCCCC[NH+](CCC)CCC.CCCCCCCCCCCCCCCCCC([O-])=O MUEWCPBDYXSWAM-UHFFFAOYSA-N 0.000 description 1
- FADFFCDCBNIARV-UHFFFAOYSA-N dodecyl-di(propan-2-yl)azanium octadecanoate Chemical compound CCCCCCCCCCCC[NH+](C(C)C)C(C)C.CCCCCCCCCCCCCCCCCC([O-])=O FADFFCDCBNIARV-UHFFFAOYSA-N 0.000 description 1
- ALRQWGMVBWLZDU-UHFFFAOYSA-N dodecyl-ethyl-methylazanium octadecanoate Chemical compound CCCCCCCCCCCC[NH+](C)CC.CCCCCCCCCCCCCCCCCC([O-])=O ALRQWGMVBWLZDU-UHFFFAOYSA-N 0.000 description 1
- OKTZTMDSHBDGAZ-UHFFFAOYSA-N dodecyl-ethyl-propan-2-ylazanium chloride Chemical compound [Cl-].C(C)(C)[NH+](CCCCCCCCCCCC)CC OKTZTMDSHBDGAZ-UHFFFAOYSA-N 0.000 description 1
- YSXJYXUYDFEBHW-UHFFFAOYSA-N dodecyl-ethyl-propan-2-ylazanium octadecanoate Chemical compound CCCCCCCCCCCC[NH+](CC)C(C)C.CCCCCCCCCCCCCCCCCC([O-])=O YSXJYXUYDFEBHW-UHFFFAOYSA-N 0.000 description 1
- AFULEGNOGKLQCT-UHFFFAOYSA-N dodecyl-methyl-propan-2-ylazanium chloride Chemical compound [Cl-].CC([NH+](C)CCCCCCCCCCCC)C AFULEGNOGKLQCT-UHFFFAOYSA-N 0.000 description 1
- JOWVMYOORPELAB-UHFFFAOYSA-N dodecyl-methyl-propan-2-ylazanium octadecanoate Chemical compound C(CCCCCCCCCCCCCCCCC)(=O)[O-].C[NH+](CCCCCCCCCCCC)C(C)C JOWVMYOORPELAB-UHFFFAOYSA-N 0.000 description 1
- KBQHZAAAGSGFKK-UHFFFAOYSA-N dysprosium atom Chemical compound [Dy] KBQHZAAAGSGFKK-UHFFFAOYSA-N 0.000 description 1
- 229920005558 epichlorohydrin rubber Polymers 0.000 description 1
- UYAHIZSMUZPPFV-UHFFFAOYSA-N erbium Chemical compound [Er] UYAHIZSMUZPPFV-UHFFFAOYSA-N 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- OAGKEKIEPNLLIS-UHFFFAOYSA-N ethanolate neodymium(3+) Chemical compound [Nd+3].CC[O-].CC[O-].CC[O-] OAGKEKIEPNLLIS-UHFFFAOYSA-N 0.000 description 1
- HHFAWKCIHAUFRX-UHFFFAOYSA-N ethoxide Chemical compound CC[O-] HHFAWKCIHAUFRX-UHFFFAOYSA-N 0.000 description 1
- GCPCLEKQVMKXJM-UHFFFAOYSA-N ethoxy(diethyl)alumane Chemical compound CCO[Al](CC)CC GCPCLEKQVMKXJM-UHFFFAOYSA-N 0.000 description 1
- XGAIERUWZADBAO-UHFFFAOYSA-N ethoxy-bis(2-methylpropyl)alumane Chemical compound CCO[Al](CC(C)C)CC(C)C XGAIERUWZADBAO-UHFFFAOYSA-N 0.000 description 1
- QPADTPIHSPAZLQ-UHFFFAOYSA-N ethyl 5-nitronaphthalene-1-carboxylate Chemical compound C1=CC=C2C(C(=O)OCC)=CC=CC2=C1[N+]([O-])=O QPADTPIHSPAZLQ-UHFFFAOYSA-N 0.000 description 1
- UABOHUHCGKGGOJ-UHFFFAOYSA-N ethyl(dimethoxy)alumane Chemical compound [O-]C.[O-]C.CC[Al+2] UABOHUHCGKGGOJ-UHFFFAOYSA-N 0.000 description 1
- ODAHSCRBAKWZPS-UHFFFAOYSA-L ethyl(diphenoxy)alumane Chemical compound CC[Al+2].[O-]C1=CC=CC=C1.[O-]C1=CC=CC=C1 ODAHSCRBAKWZPS-UHFFFAOYSA-L 0.000 description 1
- SMCMEVQBOQDRPJ-UHFFFAOYSA-N ethyl(diphenyl)alumane Chemical compound C=1C=CC=CC=1[Al](CC)C1=CC=CC=C1 SMCMEVQBOQDRPJ-UHFFFAOYSA-N 0.000 description 1
- NEPIVOURWZEXGS-UHFFFAOYSA-N ethyl-bis(4-methylphenyl)alumane Chemical compound C=1C=C(C)C=CC=1[Al](CC)C1=CC=C(C)C=C1 NEPIVOURWZEXGS-UHFFFAOYSA-N 0.000 description 1
- JLYAMRGUEDPSLA-UHFFFAOYSA-N ethyl-hexadecyl-methylazanium chloride Chemical compound [Cl-].C[NH+](CCCCCCCCCCCCCCCC)CC JLYAMRGUEDPSLA-UHFFFAOYSA-N 0.000 description 1
- NVOUBFTZOFIEFP-UHFFFAOYSA-N ethyl-hexadecyl-methylazanium octadecanoate Chemical compound CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCC[NH+](C)CC NVOUBFTZOFIEFP-UHFFFAOYSA-N 0.000 description 1
- MKJNSQUZRZQQPX-UHFFFAOYSA-N ethyl-hexadecyl-propan-2-ylazanium chloride Chemical compound [Cl-].C(C)(C)[NH+](CCCCCCCCCCCCCCCC)CC MKJNSQUZRZQQPX-UHFFFAOYSA-N 0.000 description 1
- WEECRGZHTQMRAS-UHFFFAOYSA-N ethyl-hexadecyl-propan-2-ylazanium octadecanoate Chemical compound CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCC[NH+](CC)C(C)C WEECRGZHTQMRAS-UHFFFAOYSA-N 0.000 description 1
- FCDZOLUGJJCXJG-UHFFFAOYSA-N ethyl-methyl-nonylazanium octadecanoate Chemical compound CCCCCCCCC[NH+](C)CC.CCCCCCCCCCCCCCCCCC([O-])=O FCDZOLUGJJCXJG-UHFFFAOYSA-N 0.000 description 1
- PMACEWWLYJLGPE-UHFFFAOYSA-N ethyl-methyl-octylazanium octadecanoate Chemical compound CCCCCCCC[NH+](C)CC.CCCCCCCCCCCCCCCCCC([O-])=O PMACEWWLYJLGPE-UHFFFAOYSA-N 0.000 description 1
- ONFASKYYLBPIPU-UHFFFAOYSA-N ethyl-methyl-octylazanium;chloride Chemical compound [Cl-].CCCCCCCC[NH+](C)CC ONFASKYYLBPIPU-UHFFFAOYSA-N 0.000 description 1
- CXEPIJUWARGXNY-UHFFFAOYSA-N ethyl-methyl-pentadecylazanium chloride Chemical compound [Cl-].C[NH+](CCCCCCCCCCCCCCC)CC CXEPIJUWARGXNY-UHFFFAOYSA-N 0.000 description 1
- QMPFJYGBMITFJG-UHFFFAOYSA-N ethyl-methyl-pentadecylazanium octadecanoate Chemical compound CCCCCCCCCCCCCCC[NH+](C)CC.CCCCCCCCCCCCCCCCCC([O-])=O QMPFJYGBMITFJG-UHFFFAOYSA-N 0.000 description 1
- ANUINJZPWIQIKL-UHFFFAOYSA-N ethyl-methyl-tetradecylazanium chloride Chemical compound [Cl-].C[NH+](CCCCCCCCCCCCCC)CC ANUINJZPWIQIKL-UHFFFAOYSA-N 0.000 description 1
- NXVZYWCEIXZNQV-UHFFFAOYSA-N ethyl-methyl-tetradecylazanium octadecanoate Chemical compound CCCCCCCCCCCCCC[NH+](C)CC.CCCCCCCCCCCCCCCCCC([O-])=O NXVZYWCEIXZNQV-UHFFFAOYSA-N 0.000 description 1
- FBWMBEKKBNTHTC-UHFFFAOYSA-N ethyl-methyl-tridecylazanium chloride Chemical compound [Cl-].C[NH+](CCCCCCCCCCCCC)CC FBWMBEKKBNTHTC-UHFFFAOYSA-N 0.000 description 1
- LYYPUTQHFFZPPL-UHFFFAOYSA-N ethyl-methyl-tridecylazanium octadecanoate Chemical compound CCCCCCCCCCCCC[NH+](C)CC.CCCCCCCCCCCCCCCCCC([O-])=O LYYPUTQHFFZPPL-UHFFFAOYSA-N 0.000 description 1
- IXRCPOBSFWNERT-UHFFFAOYSA-N ethyl-methyl-undecylazanium chloride Chemical compound [Cl-].C[NH+](CCCCCCCCCCC)CC IXRCPOBSFWNERT-UHFFFAOYSA-N 0.000 description 1
- LHSQNWKJKIQSIO-UHFFFAOYSA-N ethyl-methyl-undecylazanium octadecanoate Chemical compound CCCCCCCCCCC[NH+](C)CC.CCCCCCCCCCCCCCCCCC([O-])=O LHSQNWKJKIQSIO-UHFFFAOYSA-N 0.000 description 1
- LSDXJQZVRUXJHL-UHFFFAOYSA-N ethyl-nonyl-propan-2-ylazanium chloride Chemical compound [Cl-].C(C)(C)[NH+](CCCCCCCCC)CC LSDXJQZVRUXJHL-UHFFFAOYSA-N 0.000 description 1
- XPJFYPPGULBTBW-UHFFFAOYSA-N ethyl-nonyl-propan-2-ylazanium octadecanoate Chemical compound CCCCCCCCC[NH+](CC)C(C)C.CCCCCCCCCCCCCCCCCC([O-])=O XPJFYPPGULBTBW-UHFFFAOYSA-N 0.000 description 1
- WUOVYMOMPYCYDI-UHFFFAOYSA-N ethyl-octyl-propan-2-ylazanium chloride Chemical compound [Cl-].C(C)(C)[NH+](CCCCCCCC)CC WUOVYMOMPYCYDI-UHFFFAOYSA-N 0.000 description 1
- DYWHNINIIHVNPR-UHFFFAOYSA-N ethyl-octyl-propan-2-ylazanium octadecanoate Chemical compound CCCCCCCC[NH+](CC)C(C)C.CCCCCCCCCCCCCCCCCC([O-])=O DYWHNINIIHVNPR-UHFFFAOYSA-N 0.000 description 1
- CNSPHECZLORCSL-UHFFFAOYSA-N ethyl-pentadecyl-propan-2-ylazanium chloride Chemical compound [Cl-].C(C)(C)[NH+](CCCCCCCCCCCCCCC)CC CNSPHECZLORCSL-UHFFFAOYSA-N 0.000 description 1
- NCPUIFZQGVEFCZ-UHFFFAOYSA-N ethyl-pentadecyl-propan-2-ylazanium octadecanoate Chemical compound CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCC[NH+](CC)C(C)C NCPUIFZQGVEFCZ-UHFFFAOYSA-N 0.000 description 1
- PFZYEVYVXOPEDB-UHFFFAOYSA-N ethyl-propan-2-yl-tetradecylazanium chloride Chemical compound [Cl-].C(C)(C)[NH+](CCCCCCCCCCCCCC)CC PFZYEVYVXOPEDB-UHFFFAOYSA-N 0.000 description 1
- BVYIVVQCVWNOKK-UHFFFAOYSA-N ethyl-propan-2-yl-tetradecylazanium octadecanoate Chemical compound CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCC[NH+](CC)C(C)C BVYIVVQCVWNOKK-UHFFFAOYSA-N 0.000 description 1
- XKMPDGZYFDJXQX-UHFFFAOYSA-N ethyl-propan-2-yl-tridecylazanium chloride Chemical compound [Cl-].C(C)(C)[NH+](CCCCCCCCCCCCC)CC XKMPDGZYFDJXQX-UHFFFAOYSA-N 0.000 description 1
- QWVZDSXNVCOCFX-UHFFFAOYSA-N ethyl-propan-2-yl-tridecylazanium octadecanoate Chemical compound CCCCCCCCCCCCC[NH+](CC)C(C)C.CCCCCCCCCCCCCCCCCC([O-])=O QWVZDSXNVCOCFX-UHFFFAOYSA-N 0.000 description 1
- ABNQGCTZGJMRIX-UHFFFAOYSA-N ethyl-propan-2-yl-undecylazanium chloride Chemical compound [Cl-].C(C)(C)[NH+](CCCCCCCCCCC)CC ABNQGCTZGJMRIX-UHFFFAOYSA-N 0.000 description 1
- RRIDACRKDICBPZ-UHFFFAOYSA-N ethyl-propan-2-yl-undecylazanium octadecanoate Chemical compound CCCCCCCCCCC[NH+](CC)C(C)C.CCCCCCCCCCCCCCCCCC([O-])=O RRIDACRKDICBPZ-UHFFFAOYSA-N 0.000 description 1
- UGUZZPBNTADPIT-UHFFFAOYSA-L ethylaluminum(2+);difluoride Chemical compound [F-].[F-].CC[Al+2] UGUZZPBNTADPIT-UHFFFAOYSA-L 0.000 description 1
- OGPBJKLSAFTDLK-UHFFFAOYSA-N europium atom Chemical compound [Eu] OGPBJKLSAFTDLK-UHFFFAOYSA-N 0.000 description 1
- 238000001125 extrusion Methods 0.000 description 1
- XDFDJBOEIDRBBG-UHFFFAOYSA-N fluoro hypofluorite;neodymium Chemical compound [Nd].FOF XDFDJBOEIDRBBG-UHFFFAOYSA-N 0.000 description 1
- GNTRBBGWVVMYJH-UHFFFAOYSA-M fluoro(dimethyl)alumane Chemical compound [F-].C[Al+]C GNTRBBGWVVMYJH-UHFFFAOYSA-M 0.000 description 1
- UIWYJDYFSGRHKR-UHFFFAOYSA-N gadolinium atom Chemical compound [Gd] UIWYJDYFSGRHKR-UHFFFAOYSA-N 0.000 description 1
- WXXZSFJVAMRMPV-UHFFFAOYSA-K gallium(iii) fluoride Chemical compound F[Ga](F)F WXXZSFJVAMRMPV-UHFFFAOYSA-K 0.000 description 1
- DWRNSCDYNYYYHT-UHFFFAOYSA-K gallium(iii) iodide Chemical compound I[Ga](I)I DWRNSCDYNYYYHT-UHFFFAOYSA-K 0.000 description 1
- 229940050410 gluconate Drugs 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- DMEGYFMYUHOHGS-UHFFFAOYSA-N heptamethylene Natural products C1CCCCCC1 DMEGYFMYUHOHGS-UHFFFAOYSA-N 0.000 description 1
- URXQDXAVUYKSCK-UHFFFAOYSA-N hexadecyl(dimethyl)azanium;chloride Chemical compound [Cl-].CCCCCCCCCCCCCCCC[NH+](C)C URXQDXAVUYKSCK-UHFFFAOYSA-N 0.000 description 1
- ROAHWKKYHPSQMC-UHFFFAOYSA-N hexadecyl(dipropyl)azanium chloride Chemical compound [Cl-].C(CC)[NH+](CCCCCCCCCCCCCCCC)CCC ROAHWKKYHPSQMC-UHFFFAOYSA-N 0.000 description 1
- PVNHQBMNTYMASD-UHFFFAOYSA-N hexadecyl(dipropyl)azanium octadecanoate Chemical compound CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCC[NH+](CCC)CCC PVNHQBMNTYMASD-UHFFFAOYSA-N 0.000 description 1
- FHQBPFUXMJHYET-UHFFFAOYSA-N hexadecyl-di(propan-2-yl)azanium chloride Chemical compound [Cl-].C(C)(C)[NH+](CCCCCCCCCCCCCCCC)C(C)C FHQBPFUXMJHYET-UHFFFAOYSA-N 0.000 description 1
- PTXNKBMFRGTAAI-UHFFFAOYSA-N hexadecyl-di(propan-2-yl)azanium octadecanoate Chemical compound CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCC[NH+](C(C)C)C(C)C PTXNKBMFRGTAAI-UHFFFAOYSA-N 0.000 description 1
- FMWLOPJGCSZXAL-UHFFFAOYSA-N hexadecyl-methyl-propan-2-ylazanium chloride Chemical compound [Cl-].C[NH+](CCCCCCCCCCCCCCCC)C(C)C FMWLOPJGCSZXAL-UHFFFAOYSA-N 0.000 description 1
- BKTHSTCAZATVSO-UHFFFAOYSA-N hexadecyl-methyl-propan-2-ylazanium octadecanoate Chemical compound CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCC[NH+](C)C(C)C BKTHSTCAZATVSO-UHFFFAOYSA-N 0.000 description 1
- KJZYNXUDTRRSPN-UHFFFAOYSA-N holmium atom Chemical compound [Ho] KJZYNXUDTRRSPN-UHFFFAOYSA-N 0.000 description 1
- 229920001519 homopolymer Polymers 0.000 description 1
- 229910000042 hydrogen bromide Inorganic materials 0.000 description 1
- IXCSERBJSXMMFS-UHFFFAOYSA-N hydrogen chloride Substances Cl.Cl IXCSERBJSXMMFS-UHFFFAOYSA-N 0.000 description 1
- 229910000041 hydrogen chloride Inorganic materials 0.000 description 1
- 229910000040 hydrogen fluoride Inorganic materials 0.000 description 1
- XMBWDFGMSWQBCA-UHFFFAOYSA-N hydrogen iodide Chemical compound I XMBWDFGMSWQBCA-UHFFFAOYSA-N 0.000 description 1
- 229910000043 hydrogen iodide Inorganic materials 0.000 description 1
- DWRCGBDFQMKJAM-UHFFFAOYSA-N icosyl-methyl-propan-2-ylazanium chloride Chemical compound [Cl-].CCCCCCCCCCCCCCCCCCCC[NH+](C)C(C)C DWRCGBDFQMKJAM-UHFFFAOYSA-N 0.000 description 1
- 150000002466 imines Chemical class 0.000 description 1
- 238000010348 incorporation Methods 0.000 description 1
- 229910003475 inorganic filler Inorganic materials 0.000 description 1
- 229940030980 inova Drugs 0.000 description 1
- 125000000959 isobutyl group Chemical group [H]C([H])([H])C([H])(C([H])([H])[H])C([H])([H])* 0.000 description 1
- 239000012948 isocyanate Substances 0.000 description 1
- 150000002513 isocyanates Chemical class 0.000 description 1
- 150000002540 isothiocyanates Chemical class 0.000 description 1
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 1
- 239000003350 kerosene Substances 0.000 description 1
- 150000002576 ketones Chemical class 0.000 description 1
- 239000006233 lamp black Substances 0.000 description 1
- 239000003446 ligand Substances 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 239000007791 liquid phase Substances 0.000 description 1
- OHSVLFRHMCKCQY-UHFFFAOYSA-N lutetium atom Chemical compound [Lu] OHSVLFRHMCKCQY-UHFFFAOYSA-N 0.000 description 1
- VTHJTEIRLNZDEV-UHFFFAOYSA-L magnesium dihydroxide Chemical compound [OH-].[OH-].[Mg+2] VTHJTEIRLNZDEV-UHFFFAOYSA-L 0.000 description 1
- 229910012375 magnesium hydride Inorganic materials 0.000 description 1
- 239000000347 magnesium hydroxide Substances 0.000 description 1
- 229910001862 magnesium hydroxide Inorganic materials 0.000 description 1
- HCWCAKKEBCNQJP-UHFFFAOYSA-N magnesium orthosilicate Chemical compound [Mg+2].[Mg+2].[O-][Si]([O-])([O-])[O-] HCWCAKKEBCNQJP-UHFFFAOYSA-N 0.000 description 1
- 239000000395 magnesium oxide Substances 0.000 description 1
- CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 description 1
- 239000000391 magnesium silicate Substances 0.000 description 1
- 229910052919 magnesium silicate Inorganic materials 0.000 description 1
- 235000019792 magnesium silicate Nutrition 0.000 description 1
- WRYKIHMRDIOPSI-UHFFFAOYSA-N magnesium;benzene Chemical compound [Mg+2].C1=CC=[C-]C=C1.C1=CC=[C-]C=C1 WRYKIHMRDIOPSI-UHFFFAOYSA-N 0.000 description 1
- KJJBSBKRXUVBMX-UHFFFAOYSA-N magnesium;butane Chemical compound [Mg+2].CCC[CH2-].CCC[CH2-] KJJBSBKRXUVBMX-UHFFFAOYSA-N 0.000 description 1
- QUXHCILOWRXCEO-UHFFFAOYSA-M magnesium;butane;chloride Chemical compound [Mg+2].[Cl-].CCC[CH2-] QUXHCILOWRXCEO-UHFFFAOYSA-M 0.000 description 1
- VXWPONVCMVLXBW-UHFFFAOYSA-M magnesium;carbanide;iodide Chemical compound [CH3-].[Mg+2].[I-] VXWPONVCMVLXBW-UHFFFAOYSA-M 0.000 description 1
- DLPASUVGCQPFFO-UHFFFAOYSA-N magnesium;ethane Chemical compound [Mg+2].[CH2-]C.[CH2-]C DLPASUVGCQPFFO-UHFFFAOYSA-N 0.000 description 1
- RVOYYLUVELMWJF-UHFFFAOYSA-N magnesium;hexane Chemical compound [Mg+2].CCCCC[CH2-].CCCCC[CH2-] RVOYYLUVELMWJF-UHFFFAOYSA-N 0.000 description 1
- LZFCBBSYZJPPIV-UHFFFAOYSA-M magnesium;hexane;bromide Chemical compound [Mg+2].[Br-].CCCCC[CH2-] LZFCBBSYZJPPIV-UHFFFAOYSA-M 0.000 description 1
- GBRJQTLHXWRDOV-UHFFFAOYSA-M magnesium;hexane;chloride Chemical compound [Mg+2].[Cl-].CCCCC[CH2-] GBRJQTLHXWRDOV-UHFFFAOYSA-M 0.000 description 1
- WCFJMDWWJOCLSJ-UHFFFAOYSA-N magnesium;methanidylbenzene Chemical compound [Mg+2].[CH2-]C1=CC=CC=C1.[CH2-]C1=CC=CC=C1 WCFJMDWWJOCLSJ-UHFFFAOYSA-N 0.000 description 1
- QGEFGPVWRJCFQP-UHFFFAOYSA-M magnesium;methanidylbenzene;bromide Chemical compound [Mg+2].[Br-].[CH2-]C1=CC=CC=C1 QGEFGPVWRJCFQP-UHFFFAOYSA-M 0.000 description 1
- AXZKOIWUVFPNLO-UHFFFAOYSA-N magnesium;oxygen(2-) Chemical compound [O-2].[Mg+2] AXZKOIWUVFPNLO-UHFFFAOYSA-N 0.000 description 1
- DQZLQYHGCKLKGU-UHFFFAOYSA-N magnesium;propane Chemical compound [Mg+2].C[CH-]C.C[CH-]C DQZLQYHGCKLKGU-UHFFFAOYSA-N 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- AUHZEENZYGFFBQ-UHFFFAOYSA-N mesitylene Substances CC1=CC(C)=CC(C)=C1 AUHZEENZYGFFBQ-UHFFFAOYSA-N 0.000 description 1
- 125000001827 mesitylenyl group Chemical group [H]C1=C(C(*)=C(C([H])=C1C([H])([H])[H])C([H])([H])[H])C([H])([H])[H] 0.000 description 1
- CBNHBSGOXOSEAO-UHFFFAOYSA-N methanolate neodymium(3+) Chemical compound [Nd+3].[O-]C.[O-]C.[O-]C CBNHBSGOXOSEAO-UHFFFAOYSA-N 0.000 description 1
- NEMYBHYAISOMTI-UHFFFAOYSA-N methanolate;2-methylpropylaluminum(2+) Chemical compound [O-]C.[O-]C.CC(C)C[Al+2] NEMYBHYAISOMTI-UHFFFAOYSA-N 0.000 description 1
- DKUIXLPCCDROFD-UHFFFAOYSA-N methanolate;methylaluminum(2+) Chemical compound [O-]C.[O-]C.[Al+2]C DKUIXLPCCDROFD-UHFFFAOYSA-N 0.000 description 1
- BQBCXNQILNPAPX-UHFFFAOYSA-N methoxy(dimethyl)alumane Chemical compound [O-]C.C[Al+]C BQBCXNQILNPAPX-UHFFFAOYSA-N 0.000 description 1
- QQHNGZNHRRLNKI-UHFFFAOYSA-N methyl carbonobromidate Chemical compound COC(Br)=O QQHNGZNHRRLNKI-UHFFFAOYSA-N 0.000 description 1
- XMJHPCRAQCTCFT-UHFFFAOYSA-N methyl chloroformate Chemical compound COC(Cl)=O XMJHPCRAQCTCFT-UHFFFAOYSA-N 0.000 description 1
- 239000005055 methyl trichlorosilane Substances 0.000 description 1
- GYNNXHKOJHMOHS-UHFFFAOYSA-N methyl-cycloheptane Natural products CC1CCCCCC1 GYNNXHKOJHMOHS-UHFFFAOYSA-N 0.000 description 1
- SZEAAZSJJACXKD-UHFFFAOYSA-N methyl-nonyl-propan-2-ylazanium chloride Chemical compound [Cl-].C[NH+](CCCCCCCCC)C(C)C SZEAAZSJJACXKD-UHFFFAOYSA-N 0.000 description 1
- HNVCSONPHNGBOT-UHFFFAOYSA-N methyl-nonyl-propan-2-ylazanium octadecanoate Chemical compound CCCCCCCCC[NH+](C)C(C)C.CCCCCCCCCCCCCCCCCC([O-])=O HNVCSONPHNGBOT-UHFFFAOYSA-N 0.000 description 1
- OQVHEQWAOPGKPW-UHFFFAOYSA-N methyl-octyl-propan-2-ylazanium chloride Chemical compound [Cl-].C[NH+](CCCCCCCC)C(C)C OQVHEQWAOPGKPW-UHFFFAOYSA-N 0.000 description 1
- USLJZOWKIQSMJN-UHFFFAOYSA-N methyl-octyl-propan-2-ylazanium octadecanoate Chemical compound CCCCCCCC[NH+](C)C(C)C.CCCCCCCCCCCCCCCCCC([O-])=O USLJZOWKIQSMJN-UHFFFAOYSA-N 0.000 description 1
- NWOQVSIXZADDIE-UHFFFAOYSA-N methyl-pentadecyl-propan-2-ylazanium chloride Chemical compound [Cl-].C[NH+](CCCCCCCCCCCCCCC)C(C)C NWOQVSIXZADDIE-UHFFFAOYSA-N 0.000 description 1
- PFXIPLAQJFOFSI-UHFFFAOYSA-N methyl-pentadecyl-propan-2-ylazanium octadecanoate Chemical compound CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCC[NH+](C)C(C)C PFXIPLAQJFOFSI-UHFFFAOYSA-N 0.000 description 1
- NXWDOURUOIKKJT-UHFFFAOYSA-N methyl-propan-2-yl-tetradecylazanium octadecanoate Chemical compound CCCCCCCCCCCCCC[NH+](C)C(C)C.CCCCCCCCCCCCCCCCCC([O-])=O NXWDOURUOIKKJT-UHFFFAOYSA-N 0.000 description 1
- OPOKPJBCZRNOOX-UHFFFAOYSA-N methyl-propan-2-yl-tridecylazanium chloride Chemical compound [Cl-].C[NH+](CCCCCCCCCCCCC)C(C)C OPOKPJBCZRNOOX-UHFFFAOYSA-N 0.000 description 1
- ZKTGHEVAGAFVRG-UHFFFAOYSA-N methyl-propan-2-yl-tridecylazanium octadecanoate Chemical compound CCCCCCCCCCCCC[NH+](C)C(C)C.CCCCCCCCCCCCCCCCCC([O-])=O ZKTGHEVAGAFVRG-UHFFFAOYSA-N 0.000 description 1
- DJENUVPCARYJIA-UHFFFAOYSA-N methyl-propan-2-yl-undecylazanium chloride Chemical compound [Cl-].C[NH+](CCCCCCCCCCC)C(C)C DJENUVPCARYJIA-UHFFFAOYSA-N 0.000 description 1
- NMFUBZBODNAQBN-UHFFFAOYSA-N methyl-propan-2-yl-undecylazanium octadecanoate Chemical compound CCCCCCCCCCC[NH+](C)C(C)C.CCCCCCCCCCCCCCCCCC([O-])=O NMFUBZBODNAQBN-UHFFFAOYSA-N 0.000 description 1
- XBKBZMOLSULOEA-UHFFFAOYSA-L methylaluminum(2+);dibromide Chemical compound C[Al](Br)Br XBKBZMOLSULOEA-UHFFFAOYSA-L 0.000 description 1
- YSTQWZZQKCCBAY-UHFFFAOYSA-L methylaluminum(2+);dichloride Chemical compound C[Al](Cl)Cl YSTQWZZQKCCBAY-UHFFFAOYSA-L 0.000 description 1
- UEBCFKSPKUURKQ-UHFFFAOYSA-L methylaluminum(2+);difluoride Chemical compound [F-].[F-].[Al+2]C UEBCFKSPKUURKQ-UHFFFAOYSA-L 0.000 description 1
- FCUCJXXFUVRUTR-UHFFFAOYSA-L methylaluminum(2+);diphenoxide Chemical compound [Al+2]C.[O-]C1=CC=CC=C1.[O-]C1=CC=CC=C1 FCUCJXXFUVRUTR-UHFFFAOYSA-L 0.000 description 1
- JLUFWMXJHAVVNN-UHFFFAOYSA-N methyltrichlorosilane Chemical compound C[Si](Cl)(Cl)Cl JLUFWMXJHAVVNN-UHFFFAOYSA-N 0.000 description 1
- 239000010445 mica Substances 0.000 description 1
- 229910052618 mica group Inorganic materials 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 239000003607 modifier Substances 0.000 description 1
- 238000000465 moulding Methods 0.000 description 1
- 238000010068 moulding (rubber) Methods 0.000 description 1
- 229920006030 multiblock copolymer Polymers 0.000 description 1
- SQUOJZZETZQEOF-UHFFFAOYSA-K n,n-di(propan-2-yl)carbamodithioate;neodymium(3+) Chemical compound [Nd+3].CC(C)N(C(C)C)C([S-])=S.CC(C)N(C(C)C)C([S-])=S.CC(C)N(C(C)C)C([S-])=S SQUOJZZETZQEOF-UHFFFAOYSA-K 0.000 description 1
- UPNYKWFNXKJNKI-UHFFFAOYSA-N n,n-di(propan-2-yl)dodecan-1-amine;hydrochloride Chemical compound Cl.CCCCCCCCCCCCN(C(C)C)C(C)C UPNYKWFNXKJNKI-UHFFFAOYSA-N 0.000 description 1
- XXBGWCVWYRXRMO-UHFFFAOYSA-K n,n-dibenzylcarbamodithioate;neodymium(3+) Chemical compound [Nd+3].C=1C=CC=CC=1CN(C(=S)[S-])CC1=CC=CC=C1.C=1C=CC=CC=1CN(C(=S)[S-])CC1=CC=CC=C1.C=1C=CC=CC=1CN(C(=S)[S-])CC1=CC=CC=C1 XXBGWCVWYRXRMO-UHFFFAOYSA-K 0.000 description 1
- UKJJHVZVXZCPRF-UHFFFAOYSA-K n,n-dibutylcarbamodithioate;neodymium(3+) Chemical compound [Nd+3].CCCCN(C([S-])=S)CCCC.CCCCN(C([S-])=S)CCCC.CCCCN(C([S-])=S)CCCC UKJJHVZVXZCPRF-UHFFFAOYSA-K 0.000 description 1
- APRJFNLVTJWEPP-UHFFFAOYSA-M n,n-diethylcarbamate Chemical compound CCN(CC)C([O-])=O APRJFNLVTJWEPP-UHFFFAOYSA-M 0.000 description 1
- SZBUPRSARRAZQN-UHFFFAOYSA-K n,n-diethylcarbamodithioate;neodymium(3+) Chemical compound [Nd+3].CCN(CC)C([S-])=S.CCN(CC)C([S-])=S.CCN(CC)C([S-])=S SZBUPRSARRAZQN-UHFFFAOYSA-K 0.000 description 1
- DWLVWMUCHSLGSU-UHFFFAOYSA-M n,n-dimethylcarbamate Chemical compound CN(C)C([O-])=O DWLVWMUCHSLGSU-UHFFFAOYSA-M 0.000 description 1
- DXENBISLKDEHAN-UHFFFAOYSA-K n,n-dimethylcarbamodithioate;neodymium(3+) Chemical compound [Nd+3].CN(C)C([S-])=S.CN(C)C([S-])=S.CN(C)C([S-])=S DXENBISLKDEHAN-UHFFFAOYSA-K 0.000 description 1
- PTFXSPOKTOSTLD-UHFFFAOYSA-N n,n-dimethyldodecan-1-amine;octadecanoic acid Chemical compound CCCCCCCCCCCCN(C)C.CCCCCCCCCCCCCCCCCC(O)=O PTFXSPOKTOSTLD-UHFFFAOYSA-N 0.000 description 1
- WRHAWYCRVJWVDC-UHFFFAOYSA-N n,n-dimethylhexadecan-1-amine;octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCN(C)C.CCCCCCCCCCCCCCCCCC(O)=O WRHAWYCRVJWVDC-UHFFFAOYSA-N 0.000 description 1
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- WSITXTIRYQMZHM-UHFFFAOYSA-N tris(4-methylphenyl)alumane Chemical compound C1=CC(C)=CC=C1[Al](C=1C=CC(C)=CC=1)C1=CC=C(C)C=C1 WSITXTIRYQMZHM-UHFFFAOYSA-N 0.000 description 1
- RTAKQLTYPVIOBZ-UHFFFAOYSA-N tritert-butylalumane Chemical compound CC(C)(C)[Al](C(C)(C)C)C(C)(C)C RTAKQLTYPVIOBZ-UHFFFAOYSA-N 0.000 description 1
- 239000001993 wax Substances 0.000 description 1
- 239000008096 xylene Substances 0.000 description 1
- NAWDYIZEMPQZHO-UHFFFAOYSA-N ytterbium Chemical compound [Yb] NAWDYIZEMPQZHO-UHFFFAOYSA-N 0.000 description 1
- 239000011592 zinc chloride Substances 0.000 description 1
- 235000005074 zinc chloride Nutrition 0.000 description 1
- UAYWVJHJZHQCIE-UHFFFAOYSA-L zinc iodide Chemical compound I[Zn]I UAYWVJHJZHQCIE-UHFFFAOYSA-L 0.000 description 1
- 239000004711 α-olefin Substances 0.000 description 1
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Abstract
Description
ポリマー特性
産業上の利用性
式中、R1、R2、及びR3は、それぞれ独立して一価の有機基である。1又は複数の実施形態では、R1、R2、及び/又はR3は、約8〜約20個の炭素原子、他の実施形態では約10〜約18個の炭素原子、他の実施形態では約12〜約16個の炭素原子を有する炭化水素基であってもよい。これらの又は他の実施形態では、炭化水素基は直鎖炭化水素基であってよい。当業者には理解されるように、第三級アミン塩は、例えば、第三級アミンを酸と反応させることによって調製されてもよい。これらの又は他の実施形態では、第三級アミンは、対イオン、具体的には酸の共役塩基を含み得る。
タイヤの製造方法
シス−1,4ブロックコポリマーの合成
ランタニド含有化合物
有機アルミニウム化合物
以下の一般式によって表すことができるオリゴマー環式アルミノキサン
(式中、xは1〜約100、又は約10〜約50の範囲の整数であってもよく、yは2〜約100、又は約3〜約20の範囲の整数であってもよく、各Rは独立して、アルミニウム原子に炭素原子を介して結合される一価の有機基であってもよい)と、を含めることができる。一実施形態では、各Rは独立して、ヒドロカルビル基、例えば、限定するものではないが、アルキル、シクロアルキル、置換シクロアルキル、アルケニル、シクロアルケニル、置換シクロアルケニル、アリール、置換アリール、アラルキル、アルカリル、アリル、及びアルキニル基であってもよく、各基は、1個の炭素原子(又は基を形成するのに適切な最小数の炭素原子)から最大で約20個の炭素原子を含有している。これらのヒドロカルビル基はまた、へテロ原子、例えば、限定するものではないが、窒素原子、酸素原子、ホウ素原子、ケイ素原子、硫黄原子、及びリン原子を含有していてもよい。なお、本出願で用いるアルミノキサンのモル数とは、オリゴマーアルミノキサン分子のモル数ではなく、アルミニウム原子のモル数を指すことに留意すべきである。この慣習は、アルミノキサンを用いる触媒系の技術分野において広く用いられている。特定の実施形態では、オリゴマー直鎖アルミノキサンとオリゴマー環状アルミノキサンの混合物を使用してもよい。
有機マグネシウム化合物
ハロゲン源
非配位アニオン/非配位アニオン前駆体
特定の触媒
量
触媒系の調製
添加の順序
溶媒の使用
触媒系形成の条件
触媒系の熟成
重合混合物
疑似リビングポリマー
末端官能化反応
官能化剤
ポリマーの回収
実施例1.1
触媒の調製
重合
実施例1.2
触媒の調製
重合
実施例1.3
触媒の調製
重合
Claims (33)
- ゴム成分と、
充填剤と、
硬化剤と、を含み、
前記ゴム成分が、ポリブタジエンとポリイソプレンとのブロックコポリマーを含み、前記ブロックコポリマーが少なくとも90%のシス含量を有する、加硫性組成物。 - 前記ポリブタジエンとポリイソプレンとのブロックコポリマーが、前記ゴム成分の少なくとも50重量%である、請求項1に記載の加硫性組成物。
- 前記ポリブタジエンとポリイソプレンとのブロックコポリマーが、前記ゴム成分の100重量%である、請求項1に記載の加硫性組成物。
- 前記ブロックコポリマーが、約1,000g/モル〜約1,200,000g/モルの数平均分子量を有する、請求項1に記載の加硫性組成物。
- 前記ブロックコポリマーが、約10,000g/モル〜約1,000,000g/モルの数平均分子量を有する、請求項1に記載の加硫性組成物。
- 前記ブロックコポリマーが、150,000g/モル〜約800,000g/モルの数平均分子量を有する、請求項1に記載の加硫性組成物。
- 前記ブロックコポリマーが、約90:10〜約10:90のポリブタジエン対ポリイソプレンの比を有する、請求項1〜3のいずれか一項に記載の加硫性組成物。
- 前記充填剤の量が、ゴム100重量部当たり約5〜約200重量部である、請求項1〜3のいずれか一項に記載の加硫性組成物。
- 前記充填剤の量が、ゴム100重量部当たり約10〜約50重量部である、請求項1〜3のいずれか一項に記載の加硫性組成物。
- 請求項1〜9のいずれか一項に記載の加硫性組成物から調製されるタイヤ部品。
- 前記タイヤ部品が、タイヤトレッドである、請求項10に記載のタイヤ部品。
- ポリブタジエンとポリイソプレンとの高1,4−シスブロックコポリマーを調製する方法であって、
(i)第1のモノマーとランタニド系触媒とを組み合わせることによって、疑似リビングポリマーを含む重合混合物を形成することであって、前記ランタニド系触媒が、
(a)ランタニド含有化合物と、
(b)アルミノキサンと、
(c)式AlRnX3−nによって定義され、式中、各Rは、独立して、炭化水素基又は置換炭化水素基であり、各Xは、独立して、水素原子、カルボキシレート基、アルコキシド基、又はアリールオキシド基であり、nは1〜3の整数である、有機アルミニウム化合物と、
(d)ハロゲン含有化合物と、を含む、ことと、
(ii)疑似リビングポリブタジエンポリマーを含む前記重合混合物に、第2のモノマーを添加することと、を含み、
前記第1のモノマーは1,3−ブタジエン又はイソプレンのいずれかであり、前記第2のモノマーは、前記第1のモノマーと同じではなく、かつ1,3−ブタジエン又はイソプレンのいずれかである、方法。 - 前記ランタニド系触媒が予備形成された触媒である、請求項12に記載の方法。
- 前記ランタニド系触媒が安定剤の存在下で予備形成されている、請求項13に記載の方法。
- 前記安定剤が1,3−ブタジエンである、請求項14に記載の方法。
- 前記有機アルミニウム化合物が第1の有機アルミニウム化合物であり、前記ランタニド系触媒が、式AlRnX3−nによって定義され、式中、各Rは、独立して、炭化水素基又は置換炭化水素基であり、各Xは、独立して、水素原子、カルボキシレート基、アルコキシド基、又はアリールオキシド基であり、nは1〜3の整数である、第2の有機アルミニウム化合物を更に含む、請求項12〜15のいずれか一項に記載の方法。
- 前記第1の有機アルミニウム化合物がジヒドロカルビルアルミニウムヒドリド化合物である、請求項16に記載の方法。
- 前記第2の有機アルミニウム化合物がトリヒドロカルビルアルミニウム化合物である、請求項16に記載の方法。
- 前記ランタニド含有化合物がランタニドカルボキシレートである、請求項16に記載の方法。
- 前記ハロゲン含有化合物が有機金属ハライドである、請求項16に記載の方法。
- 前記アルミノキサン化合物がオリゴマー直鎖アルミノキサンである、請求項16に記載の方法。
- 前記オリゴマー直鎖アルミノキサンが次式によって定義され、
式中、xは1〜約100であり、各Rは、独立して、炭素原子を介してアルミニウム原子に結合している一価の有機基である、請求項21に記載の方法。 - 前記第2のモノマーを疑似リビングポリマーを含む前記重合混合物に添加する工程が、前記第1のモノマーの相当部分が重合した後に行われる、請求項12に記載の方法。
- 疑似リビングポリマーを含む前記重合混合物に前記第2のモノマーを添加する工程が、前記第1のモノマーの90%が重合した後に予備形成される、請求項12に記載の方法。
- 前記方法が、前記第2のモノマーが実質的に重合された後に、追加量の前記第1のモノマーを添加する工程を更に含む、請求項12に記載の方法。
- 前記得られたブロックコポリマーが、約1,000g/モル〜約1,200,000g/モルの数平均分子量を有する、請求項12に記載の方法。
- 前記得られたブロックコポリマーが、約10,000g/モル〜約1,000,000g/モルの数平均分子量を有する、請求項12に記載の方法。
- 前記得られたブロックコポリマーブロックコポリマーが、150,000g/モル〜約800,000g/モルの数平均分子量を有する、請求項12に記載の方法。
- 前記得られたブロックコポリマーブロックコポリマーが、約90:10〜約10:90のポリブタジエン対ポリイソプレンの比を有する、請求項12に記載の方法。
- 前記得られたブロックコポリマーが、少なくとも90%のシス含量を有する、請求項12に記載の方法。
- 前記第1のモノマーが1,3−ブタジエンであり、前記第2のモノマーがイソプレンである、請求項12に記載の方法。
- 前記第1のモノマーがイソプレンであり、前記第2のモノマーが1,3−ブタジエンである、請求項12に記載の方法。
- ポリブタジエンとポリイソプレンとの高1,4−シスブロックコポリマーを調製する方法であって、
(i)1,3−ブタジエンをランタニド系触媒と重合して疑似リビングポリマーを形成することであって、前記ランタニド系触媒が、
(a)ランタニド含有化合物と、
(b)アルミノキサンと、
(c)式AlRnX3−nによって定義され、式中、各Rは、独立して、炭化水素基又は置換炭化水素基であり、各Xは、独立して、水素原子、カルボキシレート基、アルコキシド基、又はアリールオキシド基であり、nは1〜3の整数である、有機アルミニウム化合物と、
(d)ハロゲン含有化合物と、を含む、ことと、
(ii)前記疑似リビングポリマーをイソプレンと反応させることと、を含む、方法。
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WO2018089635A1 (en) | 2018-05-17 |
RU2720010C1 (ru) | 2020-04-23 |
JP6928102B2 (ja) | 2021-09-01 |
US11884767B2 (en) | 2024-01-30 |
US11230622B2 (en) | 2022-01-25 |
CN110139882A (zh) | 2019-08-16 |
US20220119573A1 (en) | 2022-04-21 |
US20190359755A1 (en) | 2019-11-28 |
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