JP2018524441A - フッ化オレフィンおよびポリオールエステルを含む作業流体 - Google Patents
フッ化オレフィンおよびポリオールエステルを含む作業流体 Download PDFInfo
- Publication number
- JP2018524441A JP2018524441A JP2017566095A JP2017566095A JP2018524441A JP 2018524441 A JP2018524441 A JP 2018524441A JP 2017566095 A JP2017566095 A JP 2017566095A JP 2017566095 A JP2017566095 A JP 2017566095A JP 2018524441 A JP2018524441 A JP 2018524441A
- Authority
- JP
- Japan
- Prior art keywords
- pentaerythritol
- working fluid
- olefin
- refrigerant
- ester
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- -1 polyol esters Chemical class 0.000 title claims abstract description 108
- 239000012530 fluid Substances 0.000 title claims abstract description 66
- 229920005862 polyol Polymers 0.000 title claims abstract description 56
- 150000001336 alkenes Chemical class 0.000 title claims abstract description 30
- 239000003507 refrigerant Substances 0.000 claims abstract description 85
- 239000000203 mixture Substances 0.000 claims abstract description 68
- WXZMFSXDPGVJKK-UHFFFAOYSA-N pentaerythritol Chemical compound OCC(CO)(CO)CO WXZMFSXDPGVJKK-UHFFFAOYSA-N 0.000 claims abstract description 33
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 claims abstract description 19
- PTJWCLYPVFJWMP-UHFFFAOYSA-N 2-[[3-hydroxy-2-[[3-hydroxy-2,2-bis(hydroxymethyl)propoxy]methyl]-2-(hydroxymethyl)propoxy]methyl]-2-(hydroxymethyl)propane-1,3-diol Chemical compound OCC(CO)(CO)COCC(CO)(CO)COCC(CO)(CO)CO PTJWCLYPVFJWMP-UHFFFAOYSA-N 0.000 claims abstract description 12
- 239000000314 lubricant Substances 0.000 claims description 86
- 229940059574 pentaerithrityl Drugs 0.000 claims description 60
- 125000005157 alkyl carboxy group Chemical group 0.000 claims description 24
- PGJHURKAWUJHLJ-UHFFFAOYSA-N 1,1,2,3-tetrafluoroprop-1-ene Chemical compound FCC(F)=C(F)F PGJHURKAWUJHLJ-UHFFFAOYSA-N 0.000 claims description 7
- 229930195733 hydrocarbon Natural products 0.000 claims description 5
- 150000002430 hydrocarbons Chemical class 0.000 claims description 5
- 150000005828 hydrofluoroalkanes Chemical class 0.000 claims description 5
- 150000001345 alkine derivatives Chemical class 0.000 claims description 4
- 229910052799 carbon Inorganic materials 0.000 claims description 3
- 125000004432 carbon atom Chemical group C* 0.000 claims description 3
- NDMMKOCNFSTXRU-UHFFFAOYSA-N 1,1,2,3,3-pentafluoroprop-1-ene Chemical compound FC(F)C(F)=C(F)F NDMMKOCNFSTXRU-UHFFFAOYSA-N 0.000 claims description 2
- FDMFUZHCIRHGRG-UHFFFAOYSA-N 3,3,3-trifluoroprop-1-ene Chemical class FC(F)(F)C=C FDMFUZHCIRHGRG-UHFFFAOYSA-N 0.000 claims description 2
- 239000004215 Carbon black (E152) Substances 0.000 claims description 2
- 125000001153 fluoro group Chemical group F* 0.000 claims 2
- CDOOAUSHHFGWSA-OWOJBTEDSA-N (e)-1,3,3,3-tetrafluoroprop-1-ene Chemical compound F\C=C\C(F)(F)F CDOOAUSHHFGWSA-OWOJBTEDSA-N 0.000 description 30
- 239000002253 acid Substances 0.000 description 15
- 150000002148 esters Chemical class 0.000 description 15
- 238000005057 refrigeration Methods 0.000 description 13
- 239000003921 oil Substances 0.000 description 9
- 235000019198 oils Nutrition 0.000 description 9
- 238000005191 phase separation Methods 0.000 description 9
- 239000000654 additive Substances 0.000 description 8
- 125000005599 alkyl carboxylate group Chemical group 0.000 description 8
- 150000007942 carboxylates Chemical group 0.000 description 8
- 238000012546 transfer Methods 0.000 description 8
- 150000001335 aliphatic alkanes Chemical class 0.000 description 7
- 239000007788 liquid Substances 0.000 description 7
- 238000000034 method Methods 0.000 description 7
- LVGUZGTVOIAKKC-UHFFFAOYSA-N 1,1,1,2-tetrafluoroethane Chemical compound FCC(F)(F)F LVGUZGTVOIAKKC-UHFFFAOYSA-N 0.000 description 6
- 150000007513 acids Chemical class 0.000 description 6
- 150000001735 carboxylic acids Chemical class 0.000 description 6
- 230000000052 comparative effect Effects 0.000 description 6
- RWRIWBAIICGTTQ-UHFFFAOYSA-N difluoromethane Chemical compound FCF RWRIWBAIICGTTQ-UHFFFAOYSA-N 0.000 description 6
- 238000010790 dilution Methods 0.000 description 6
- 239000012895 dilution Substances 0.000 description 6
- 229920000728 polyester Polymers 0.000 description 6
- 239000007791 liquid phase Substances 0.000 description 5
- 239000000463 material Substances 0.000 description 5
- 239000012071 phase Substances 0.000 description 5
- 238000012360 testing method Methods 0.000 description 5
- XPDWGBQVDMORPB-UHFFFAOYSA-N Fluoroform Chemical compound FC(F)F XPDWGBQVDMORPB-UHFFFAOYSA-N 0.000 description 4
- 229910019142 PO4 Inorganic materials 0.000 description 4
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 4
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 4
- 239000003963 antioxidant agent Substances 0.000 description 4
- GHVNFZFCNZKVNT-UHFFFAOYSA-N decanoic acid Chemical compound CCCCCCCCCC(O)=O GHVNFZFCNZKVNT-UHFFFAOYSA-N 0.000 description 4
- 230000032050 esterification Effects 0.000 description 4
- 238000005886 esterification reaction Methods 0.000 description 4
- 238000005461 lubrication Methods 0.000 description 4
- WWZKQHOCKIZLMA-UHFFFAOYSA-N octanoic acid Chemical compound CCCCCCCC(O)=O WWZKQHOCKIZLMA-UHFFFAOYSA-N 0.000 description 4
- 235000021317 phosphate Nutrition 0.000 description 4
- 230000008569 process Effects 0.000 description 4
- NQPDZGIKBAWPEJ-UHFFFAOYSA-N valeric acid Chemical compound CCCCC(O)=O NQPDZGIKBAWPEJ-UHFFFAOYSA-N 0.000 description 4
- 229910052725 zinc Inorganic materials 0.000 description 4
- 239000011701 zinc Substances 0.000 description 4
- OILUAKBAMVLXGF-UHFFFAOYSA-N 3,5,5-trimethyl-hexanoic acid Chemical compound OC(=O)CC(C)CC(C)(C)C OILUAKBAMVLXGF-UHFFFAOYSA-N 0.000 description 3
- 125000000217 alkyl group Chemical group 0.000 description 3
- 239000002518 antifoaming agent Substances 0.000 description 3
- 230000008859 change Effects 0.000 description 3
- 238000001816 cooling Methods 0.000 description 3
- 238000006073 displacement reaction Methods 0.000 description 3
- 238000005227 gel permeation chromatography Methods 0.000 description 3
- 238000010438 heat treatment Methods 0.000 description 3
- 239000010687 lubricating oil Substances 0.000 description 3
- 150000003077 polyols Chemical class 0.000 description 3
- 229920006395 saturated elastomer Polymers 0.000 description 3
- ZBKIRWGFFLBFDX-UHFFFAOYSA-N 1,1,1,4,4,4-hexafluoro-2-(trifluoromethyl)but-2-ene Chemical compound FC(F)(F)C=C(C(F)(F)F)C(F)(F)F ZBKIRWGFFLBFDX-UHFFFAOYSA-N 0.000 description 2
- UJPMYEOUBPIPHQ-UHFFFAOYSA-N 1,1,1-trifluoroethane Chemical compound CC(F)(F)F UJPMYEOUBPIPHQ-UHFFFAOYSA-N 0.000 description 2
- WXGNWUVNYMJENI-UHFFFAOYSA-N 1,1,2,2-tetrafluoroethane Chemical compound FC(F)C(F)F WXGNWUVNYMJENI-UHFFFAOYSA-N 0.000 description 2
- QAERDLQYXMEHEB-UHFFFAOYSA-N 1,1,3,3,3-pentafluoroprop-1-ene Chemical compound FC(F)=CC(F)(F)F QAERDLQYXMEHEB-UHFFFAOYSA-N 0.000 description 2
- YXIWHUQXZSMYRE-UHFFFAOYSA-N 1,3-benzothiazole-2-thiol Chemical compound C1=CC=C2SC(S)=NC2=C1 YXIWHUQXZSMYRE-UHFFFAOYSA-N 0.000 description 2
- VXNZUUAINFGPBY-UHFFFAOYSA-N 1-Butene Chemical compound CCC=C VXNZUUAINFGPBY-UHFFFAOYSA-N 0.000 description 2
- WLAMNBDJUVNPJU-BYPYZUCNSA-N 2-Methylbutanoic acid Natural products CC[C@H](C)C(O)=O WLAMNBDJUVNPJU-BYPYZUCNSA-N 0.000 description 2
- TXBCBTDQIULDIA-UHFFFAOYSA-N 2-[[3-hydroxy-2,2-bis(hydroxymethyl)propoxy]methyl]-2-(hydroxymethyl)propane-1,3-diol Chemical compound OCC(CO)(CO)COCC(CO)(CO)CO TXBCBTDQIULDIA-UHFFFAOYSA-N 0.000 description 2
- WLAMNBDJUVNPJU-UHFFFAOYSA-N 2-methylbutyric acid Chemical compound CCC(C)C(O)=O WLAMNBDJUVNPJU-UHFFFAOYSA-N 0.000 description 2
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 2
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 2
- 239000004593 Epoxy Substances 0.000 description 2
- 239000005069 Extreme pressure additive Substances 0.000 description 2
- XQVWYOYUZDUNRW-UHFFFAOYSA-N N-Phenyl-1-naphthylamine Chemical compound C=1C=CC2=CC=CC=C2C=1NC1=CC=CC=C1 XQVWYOYUZDUNRW-UHFFFAOYSA-N 0.000 description 2
- KEQFTVQCIQJIQW-UHFFFAOYSA-N N-Phenyl-2-naphthylamine Chemical compound C=1C=C2C=CC=CC2=CC=1NC1=CC=CC=C1 KEQFTVQCIQJIQW-UHFFFAOYSA-N 0.000 description 2
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 2
- 238000004378 air conditioning Methods 0.000 description 2
- 239000007866 anti-wear additive Substances 0.000 description 2
- IOJUPLGTWVMSFF-UHFFFAOYSA-N benzothiazole Chemical compound C1=CC=C2SC=NC2=C1 IOJUPLGTWVMSFF-UHFFFAOYSA-N 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 238000005187 foaming Methods 0.000 description 2
- 239000007789 gas Substances 0.000 description 2
- 239000003317 industrial substance Substances 0.000 description 2
- 238000005259 measurement Methods 0.000 description 2
- 150000002763 monocarboxylic acids Chemical class 0.000 description 2
- 229910052757 nitrogen Inorganic materials 0.000 description 2
- GTLACDSXYULKMZ-UHFFFAOYSA-N pentafluoroethane Chemical compound FC(F)C(F)(F)F GTLACDSXYULKMZ-UHFFFAOYSA-N 0.000 description 2
- 239000010452 phosphate Substances 0.000 description 2
- 150000003013 phosphoric acid derivatives Chemical class 0.000 description 2
- 229920000570 polyether Polymers 0.000 description 2
- GUEIZVNYDFNHJU-UHFFFAOYSA-N quinizarin Chemical compound O=C1C2=CC=CC=C2C(=O)C2=C1C(O)=CC=C2O GUEIZVNYDFNHJU-UHFFFAOYSA-N 0.000 description 2
- 239000010726 refrigerant oil Substances 0.000 description 2
- 229910052717 sulfur Inorganic materials 0.000 description 2
- 239000011593 sulfur Substances 0.000 description 2
- 150000003568 thioethers Chemical class 0.000 description 2
- PYOKUURKVVELLB-UHFFFAOYSA-N trimethyl orthoformate Chemical compound COC(OC)OC PYOKUURKVVELLB-UHFFFAOYSA-N 0.000 description 2
- 235000015112 vegetable and seed oil Nutrition 0.000 description 2
- 239000008158 vegetable oil Substances 0.000 description 2
- 238000010792 warming Methods 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- VKKBJZFVPNUYQL-OWOJBTEDSA-N (E)-1,1,1,4,4-pentafluorobut-2-ene Chemical compound FC(F)\C=C\C(F)(F)F VKKBJZFVPNUYQL-OWOJBTEDSA-N 0.000 description 1
- PXINDCPNVPPLOD-OWOJBTEDSA-N (e)-1,1,1,5,5,5-hexafluoro-4-(trifluoromethyl)pent-2-ene Chemical compound FC(F)(F)\C=C\C(C(F)(F)F)C(F)(F)F PXINDCPNVPPLOD-OWOJBTEDSA-N 0.000 description 1
- FFTOUVYEKNGDCM-OWOJBTEDSA-N (e)-1,3,3-trifluoroprop-1-ene Chemical compound F\C=C\C(F)F FFTOUVYEKNGDCM-OWOJBTEDSA-N 0.000 description 1
- HVOUHYGSLBPLGT-NSCUHMNNSA-N (e)-4,4,5,5,6,6,6-heptafluorohex-2-ene Chemical compound C\C=C\C(F)(F)C(F)(F)C(F)(F)F HVOUHYGSLBPLGT-NSCUHMNNSA-N 0.000 description 1
- YIFLMZOLKQBEBO-UPHRSURJSA-N (z)-1,1,1,2,4,4,4-heptafluorobut-2-ene Chemical compound FC(F)(F)C(/F)=C/C(F)(F)F YIFLMZOLKQBEBO-UPHRSURJSA-N 0.000 description 1
- DDKFHEFCVPCJKU-UPHRSURJSA-N (z)-1,1,2,4,4-pentafluorobut-2-ene Chemical compound FC(F)\C=C(/F)C(F)F DDKFHEFCVPCJKU-UPHRSURJSA-N 0.000 description 1
- RFYFRYQYXJPKMF-UHFFFAOYSA-N 1,1,1,2,2,3,4,5,5,6,6,6-dodecafluorohex-3-ene Chemical compound FC(F)(F)C(F)(F)C(F)=C(F)C(F)(F)C(F)(F)F RFYFRYQYXJPKMF-UHFFFAOYSA-N 0.000 description 1
- QAQXDIFHMWHZAL-UHFFFAOYSA-N 1,1,1,2,2,3,4-heptafluorohex-3-ene Chemical compound CCC(F)=C(F)C(F)(F)C(F)(F)F QAQXDIFHMWHZAL-UHFFFAOYSA-N 0.000 description 1
- WSJULBMCKQTTIG-UHFFFAOYSA-N 1,1,1,2,3,4,4,4-octafluorobut-2-ene Chemical compound FC(F)(F)C(F)=C(F)C(F)(F)F WSJULBMCKQTTIG-UHFFFAOYSA-N 0.000 description 1
- VVMQLAKDFBLCHB-UHFFFAOYSA-N 1,1,1,2,3,4,4,5,5,5-decafluoropent-2-ene Chemical compound FC(F)(F)C(F)=C(F)C(F)(F)C(F)(F)F VVMQLAKDFBLCHB-UHFFFAOYSA-N 0.000 description 1
- BLNWTWDBKNPDDJ-UHFFFAOYSA-N 1,1,1,2,3,4,4-heptafluorobut-2-ene Chemical compound FC(F)C(F)=C(F)C(F)(F)F BLNWTWDBKNPDDJ-UHFFFAOYSA-N 0.000 description 1
- JSADPKAWAKXUTE-UHFFFAOYSA-N 1,1,1,2,3,4-hexafluorobut-2-ene Chemical compound FCC(F)=C(F)C(F)(F)F JSADPKAWAKXUTE-UHFFFAOYSA-N 0.000 description 1
- JBYVVEFBYYDZIM-UHFFFAOYSA-N 1,1,1,2,4,4,4-heptafluoro-3-methylbut-2-ene Chemical compound FC(F)(F)C(C)=C(F)C(F)(F)F JBYVVEFBYYDZIM-UHFFFAOYSA-N 0.000 description 1
- JZSOMBFGZXZIJI-UHFFFAOYSA-N 1,1,1,2,4-pentafluorobut-2-ene Chemical compound FCC=C(F)C(F)(F)F JZSOMBFGZXZIJI-UHFFFAOYSA-N 0.000 description 1
- HHDLUXLBJXTFHQ-UHFFFAOYSA-N 1,1,1,2,5,5,5-heptafluoro-4-methylpent-2-ene Chemical compound FC(F)(F)C(C)C=C(F)C(F)(F)F HHDLUXLBJXTFHQ-UHFFFAOYSA-N 0.000 description 1
- MMJXXOIUVNOFPL-UHFFFAOYSA-N 1,1,1,2-tetrafluorobut-2-ene Chemical compound CC=C(F)C(F)(F)F MMJXXOIUVNOFPL-UHFFFAOYSA-N 0.000 description 1
- JVLWJKWBKARHRQ-UHFFFAOYSA-N 1,1,1,3,4,4-hexafluorobut-2-ene Chemical compound FC(F)C(F)=CC(F)(F)F JVLWJKWBKARHRQ-UHFFFAOYSA-N 0.000 description 1
- RGYWQQYKFBYEHS-UHFFFAOYSA-N 1,1,1,3,4,5,5,5-octafluoro-4-(trifluoromethyl)pent-2-ene Chemical compound FC(F)(F)C=C(F)C(F)(C(F)(F)F)C(F)(F)F RGYWQQYKFBYEHS-UHFFFAOYSA-N 0.000 description 1
- YCBCLGNNEUTCEC-UHFFFAOYSA-N 1,1,1,3,4-pentafluorobut-2-ene Chemical compound FCC(F)=CC(F)(F)F YCBCLGNNEUTCEC-UHFFFAOYSA-N 0.000 description 1
- CGLWHABLUPITJQ-UHFFFAOYSA-N 1,1,1,3-tetrafluoro-2-(trifluoromethyl)but-2-ene Chemical compound CC(F)=C(C(F)(F)F)C(F)(F)F CGLWHABLUPITJQ-UHFFFAOYSA-N 0.000 description 1
- LRUCMYWNQPGVEL-UHFFFAOYSA-N 1,1,1,3-tetrafluoro-2-(trifluoromethyl)pent-2-ene Chemical compound CCC(F)=C(C(F)(F)F)C(F)(F)F LRUCMYWNQPGVEL-UHFFFAOYSA-N 0.000 description 1
- VSPVOSOCAZPIJQ-UHFFFAOYSA-N 1,1,1,3-tetrafluorobut-2-ene Chemical compound CC(F)=CC(F)(F)F VSPVOSOCAZPIJQ-UHFFFAOYSA-N 0.000 description 1
- CUKJWRYRLCTJNJ-UHFFFAOYSA-N 1,1,1,4,4,4-hexafluoro-2,3-bis(trifluoromethyl)but-2-ene Chemical compound FC(F)(F)C(C(F)(F)F)=C(C(F)(F)F)C(F)(F)F CUKJWRYRLCTJNJ-UHFFFAOYSA-N 0.000 description 1
- FOLBRSGQGGTARP-UHFFFAOYSA-N 1,1,1,4,4,4-hexafluoro-2-methyl-3-(trifluoromethyl)but-2-ene Chemical compound FC(F)(F)C(C)=C(C(F)(F)F)C(F)(F)F FOLBRSGQGGTARP-UHFFFAOYSA-N 0.000 description 1
- OBHAZHXFTQWCKY-UHFFFAOYSA-N 1,1,1,4,4,4-hexafluoro-2-methylbut-2-ene Chemical compound FC(F)(F)C(C)=CC(F)(F)F OBHAZHXFTQWCKY-UHFFFAOYSA-N 0.000 description 1
- QSPZQCQWYKPYJI-UHFFFAOYSA-N 1,1,1,4,4,5,5,5-octafluoro-2-(trifluoromethyl)pent-2-ene Chemical compound FC(F)(F)C(C(F)(F)F)=CC(F)(F)C(F)(F)F QSPZQCQWYKPYJI-UHFFFAOYSA-N 0.000 description 1
- JBKYCTFEBKECDW-UHFFFAOYSA-N 1,1,1,4,4-pentafluoro-2-(trifluoromethyl)pent-2-ene Chemical compound CC(F)(F)C=C(C(F)(F)F)C(F)(F)F JBKYCTFEBKECDW-UHFFFAOYSA-N 0.000 description 1
- FQJHHXBFDDKSEP-UHFFFAOYSA-N 1,1,1,4-tetrafluoro-2-(trifluoromethyl)but-2-ene Chemical compound FCC=C(C(F)(F)F)C(F)(F)F FQJHHXBFDDKSEP-UHFFFAOYSA-N 0.000 description 1
- QQXUXJCUYPLLIK-UHFFFAOYSA-N 1,1,1-trifluoro-2-(trifluoromethyl)but-2-ene Chemical compound CC=C(C(F)(F)F)C(F)(F)F QQXUXJCUYPLLIK-UHFFFAOYSA-N 0.000 description 1
- LTCNHAYYQPIMNJ-UHFFFAOYSA-N 1,1,1-trifluoropent-2-ene Chemical compound CCC=CC(F)(F)F LTCNHAYYQPIMNJ-UHFFFAOYSA-N 0.000 description 1
- ZVJOQYFQSQJDDX-UHFFFAOYSA-N 1,1,2,3,3,4,4,4-octafluorobut-1-ene Chemical compound FC(F)=C(F)C(F)(F)C(F)(F)F ZVJOQYFQSQJDDX-UHFFFAOYSA-N 0.000 description 1
- PBWHQPOHADDEFU-UHFFFAOYSA-N 1,1,2,3,3,4,4,5,5,5-decafluoropent-1-ene Chemical compound FC(F)=C(F)C(F)(F)C(F)(F)C(F)(F)F PBWHQPOHADDEFU-UHFFFAOYSA-N 0.000 description 1
- RMHCWMIZBMGHKV-UHFFFAOYSA-N 1,1,2,3,3,4,4,5,5,6,6,6-dodecafluorohex-1-ene Chemical compound FC(F)=C(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)F RMHCWMIZBMGHKV-UHFFFAOYSA-N 0.000 description 1
- NUPBXTZOBYEVIR-UHFFFAOYSA-N 1,1,2,3,3,4,4-heptafluorobut-1-ene Chemical compound FC(F)C(F)(F)C(F)=C(F)F NUPBXTZOBYEVIR-UHFFFAOYSA-N 0.000 description 1
- SXKNYNUXUHCUHX-UHFFFAOYSA-N 1,1,2,3,3,4-hexafluorobut-1-ene Chemical compound FCC(F)(F)C(F)=C(F)F SXKNYNUXUHCUHX-UHFFFAOYSA-N 0.000 description 1
- HQMMBTYEDVZZOA-UHFFFAOYSA-N 1,1,2,3,3-pentafluorobut-1-ene Chemical compound CC(F)(F)C(F)=C(F)F HQMMBTYEDVZZOA-UHFFFAOYSA-N 0.000 description 1
- PNVHHLZXQBHKNX-UHFFFAOYSA-N 1,1,2,3,4-pentafluorobut-2-ene Chemical compound FCC(F)=C(F)C(F)F PNVHHLZXQBHKNX-UHFFFAOYSA-N 0.000 description 1
- HSHAILBKIPODRY-UHFFFAOYSA-N 1,1,2,4,4,4-hexafluoro-3-(trifluoromethyl)but-1-ene Chemical compound FC(F)=C(F)C(C(F)(F)F)C(F)(F)F HSHAILBKIPODRY-UHFFFAOYSA-N 0.000 description 1
- LNGDLROYEAUMEQ-UHFFFAOYSA-N 1,1,2-trifluoroprop-1-ene Chemical compound CC(F)=C(F)F LNGDLROYEAUMEQ-UHFFFAOYSA-N 0.000 description 1
- WEYCUBLCUXRXRQ-UHFFFAOYSA-N 1,1,3,3,3-pentafluoro-2-methylprop-1-ene Chemical compound FC(F)=C(C)C(F)(F)F WEYCUBLCUXRXRQ-UHFFFAOYSA-N 0.000 description 1
- GCNWWRIQEJNUIF-UHFFFAOYSA-N 1,1,3,3,4,4,4-heptafluorobut-1-ene Chemical compound FC(F)=CC(F)(F)C(F)(F)F GCNWWRIQEJNUIF-UHFFFAOYSA-N 0.000 description 1
- UHFBOQDBBVRSGL-UHFFFAOYSA-N 1,1,3,3-tetrafluoro-2-methylprop-1-ene Chemical compound FC(F)C(C)=C(F)F UHFBOQDBBVRSGL-UHFFFAOYSA-N 0.000 description 1
- BNYODXFAOQCIIO-UHFFFAOYSA-N 1,1,3,3-tetrafluoroprop-1-ene Chemical compound FC(F)C=C(F)F BNYODXFAOQCIIO-UHFFFAOYSA-N 0.000 description 1
- UDLSJLBLIOSNHV-UHFFFAOYSA-N 1,1,3,4,4,4-hexafluoro-3-(trifluoromethyl)but-1-ene Chemical compound FC(F)=CC(F)(C(F)(F)F)C(F)(F)F UDLSJLBLIOSNHV-UHFFFAOYSA-N 0.000 description 1
- URZZGOOCQOQVOC-UHFFFAOYSA-N 1,1,3-trifluoroprop-1-ene Chemical compound FCC=C(F)F URZZGOOCQOQVOC-UHFFFAOYSA-N 0.000 description 1
- PABTUKMXOXSGHV-UHFFFAOYSA-N 1,1,4,4,4-pentafluoro-2-(trifluoromethyl)but-1-ene Chemical compound FC(F)=C(C(F)(F)F)CC(F)(F)F PABTUKMXOXSGHV-UHFFFAOYSA-N 0.000 description 1
- HQKGXDFRQODSDD-UHFFFAOYSA-N 1,1,4,4,4-pentafluoro-3-(trifluoromethyl)but-1-ene Chemical compound FC(F)=CC(C(F)(F)F)C(F)(F)F HQKGXDFRQODSDD-UHFFFAOYSA-N 0.000 description 1
- PVYYRPAHXQUHAW-UHFFFAOYSA-N 1,2,3,3,4,4,4-heptafluorobut-1-ene Chemical compound FC=C(F)C(F)(F)C(F)(F)F PVYYRPAHXQUHAW-UHFFFAOYSA-N 0.000 description 1
- OUXZWOASPZPWJQ-UHFFFAOYSA-N 1,2,3,3,4,4,5,5-octafluoropent-1-ene Chemical compound FC=C(F)C(F)(F)C(F)(F)C(F)F OUXZWOASPZPWJQ-UHFFFAOYSA-N 0.000 description 1
- ZUAQTIHDWIHCSV-UHFFFAOYSA-N 1,2,3,3-tetrafluoroprop-1-ene Chemical compound FC=C(F)C(F)F ZUAQTIHDWIHCSV-UHFFFAOYSA-N 0.000 description 1
- DQXNKOLPOICZKZ-UHFFFAOYSA-N 1,2,3,4,4,4-hexafluoro-3-(trifluoromethyl)but-1-ene Chemical compound FC=C(F)C(F)(C(F)(F)F)C(F)(F)F DQXNKOLPOICZKZ-UHFFFAOYSA-N 0.000 description 1
- ZEDVIYBBMGBWDN-UHFFFAOYSA-N 1,2,3,4,4,4-hexafluorobut-1-ene Chemical compound FC=C(F)C(F)C(F)(F)F ZEDVIYBBMGBWDN-UHFFFAOYSA-N 0.000 description 1
- TXHNVFGQJAAUNB-UHFFFAOYSA-N 1,2,3-trifluoroprop-1-ene Chemical compound FCC(F)=CF TXHNVFGQJAAUNB-UHFFFAOYSA-N 0.000 description 1
- FYDLLXJLGCDGFH-UHFFFAOYSA-N 1,3,3,3-tetrafluoro-2-(trifluoromethyl)prop-1-ene Chemical compound FC=C(C(F)(F)F)C(F)(F)F FYDLLXJLGCDGFH-UHFFFAOYSA-N 0.000 description 1
- FPWXPJYOCIDGEH-UHFFFAOYSA-N 1,3,3,3-tetrafluoro-2-methylprop-1-ene Chemical compound FC=C(C)C(F)(F)F FPWXPJYOCIDGEH-UHFFFAOYSA-N 0.000 description 1
- CDOOAUSHHFGWSA-UHFFFAOYSA-N 1,3,3,3-tetrafluoropropene Chemical compound FC=CC(F)(F)F CDOOAUSHHFGWSA-UHFFFAOYSA-N 0.000 description 1
- LYSWMVUQFULFQU-UHFFFAOYSA-N 1,3,3,4,4,4-hexafluorobut-1-ene Chemical compound FC=CC(F)(F)C(F)(F)F LYSWMVUQFULFQU-UHFFFAOYSA-N 0.000 description 1
- HMAHQANPHFVLPT-UHFFFAOYSA-N 1,3,3-trifluoroprop-1-yne Chemical compound FC#CC(F)F HMAHQANPHFVLPT-UHFFFAOYSA-N 0.000 description 1
- SKQJYUPAFGVYKS-UHFFFAOYSA-N 1,3,4,4,4-pentafluoro-3-(trifluoromethyl)but-1-ene Chemical compound FC=CC(F)(C(F)(F)F)C(F)(F)F SKQJYUPAFGVYKS-UHFFFAOYSA-N 0.000 description 1
- FVLJAHBUWGQLBO-UHFFFAOYSA-N 1,3,4,4,4-pentafluorobut-1-ene Chemical compound FC=CC(F)C(F)(F)F FVLJAHBUWGQLBO-UHFFFAOYSA-N 0.000 description 1
- WNXJIVFYUVYPPR-UHFFFAOYSA-N 1,3-dioxolane Chemical compound C1COCO1 WNXJIVFYUVYPPR-UHFFFAOYSA-N 0.000 description 1
- FHKSBNVLMZMYCI-UHFFFAOYSA-N 1,4,4,4-tetrafluoro-3-(trifluoromethyl)but-1-ene Chemical compound FC=CC(C(F)(F)F)C(F)(F)F FHKSBNVLMZMYCI-UHFFFAOYSA-N 0.000 description 1
- AAKKZDBDOJWNQA-UHFFFAOYSA-N 1,4-dioctylcyclohexa-2,4-dien-1-amine Chemical compound C(CCCCCCC)C1(CC=C(C=C1)CCCCCCCC)N AAKKZDBDOJWNQA-UHFFFAOYSA-N 0.000 description 1
- WJFKNYWRSNBZNX-UHFFFAOYSA-N 10H-phenothiazine Chemical compound C1=CC=C2NC3=CC=CC=C3SC2=C1 WJFKNYWRSNBZNX-UHFFFAOYSA-N 0.000 description 1
- KGRVJHAUYBGFFP-UHFFFAOYSA-N 2,2'-Methylenebis(4-methyl-6-tert-butylphenol) Chemical compound CC(C)(C)C1=CC(C)=CC(CC=2C(=C(C=C(C)C=2)C(C)(C)C)O)=C1O KGRVJHAUYBGFFP-UHFFFAOYSA-N 0.000 description 1
- FXRLMCRCYDHQFW-UHFFFAOYSA-N 2,3,3,3-tetrafluoropropene Chemical compound FC(=C)C(F)(F)F FXRLMCRCYDHQFW-UHFFFAOYSA-N 0.000 description 1
- FAOACLKUNWKVPH-UHFFFAOYSA-N 2,3,3,4,4,4-hexafluorobut-1-ene Chemical compound FC(=C)C(F)(F)C(F)(F)F FAOACLKUNWKVPH-UHFFFAOYSA-N 0.000 description 1
- ZTRDINUYDYRXAA-UHFFFAOYSA-N 2,3,3,4,4,5,5,5-octafluoropent-1-ene Chemical compound FC(=C)C(F)(F)C(F)(F)C(F)(F)F ZTRDINUYDYRXAA-UHFFFAOYSA-N 0.000 description 1
- ZHKVUSSHABANQG-UHFFFAOYSA-N 2,3,3,4,4,5,5-heptafluoropent-1-ene Chemical compound FC(F)C(F)(F)C(F)(F)C(F)=C ZHKVUSSHABANQG-UHFFFAOYSA-N 0.000 description 1
- RDIZQSPNUCXZQY-UHFFFAOYSA-N 2,3,3,5,5,5-hexafluoro-4-(trifluoromethyl)pent-1-ene Chemical compound FC(=C)C(F)(F)C(C(F)(F)F)C(F)(F)F RDIZQSPNUCXZQY-UHFFFAOYSA-N 0.000 description 1
- JMRIJKGIVGYIAD-UHFFFAOYSA-N 2,3,3-trifluoroprop-1-ene Chemical compound FC(F)C(F)=C JMRIJKGIVGYIAD-UHFFFAOYSA-N 0.000 description 1
- NHGSUDHIUKAWHN-UHFFFAOYSA-N 2,4,4,4-tetrafluoro-3-(trifluoromethyl)but-1-ene Chemical compound FC(=C)C(C(F)(F)F)C(F)(F)F NHGSUDHIUKAWHN-UHFFFAOYSA-N 0.000 description 1
- MMZARORJGNLKAW-UHFFFAOYSA-N 2-(difluoromethyl)-3,3,3-trifluoroprop-1-ene Chemical compound FC(F)C(=C)C(F)(F)F MMZARORJGNLKAW-UHFFFAOYSA-N 0.000 description 1
- IYOLYUNUVFIFIE-UHFFFAOYSA-N 2-(difluoromethyl)-3,3-difluoroprop-1-ene Chemical compound FC(F)C(=C)C(F)F IYOLYUNUVFIFIE-UHFFFAOYSA-N 0.000 description 1
- ODJQKYXPKWQWNK-UHFFFAOYSA-N 3,3'-Thiobispropanoic acid Chemical class OC(=O)CCSCCC(O)=O ODJQKYXPKWQWNK-UHFFFAOYSA-N 0.000 description 1
- QMIWYOZFFSLIAK-UHFFFAOYSA-N 3,3,3-trifluoro-2-(trifluoromethyl)prop-1-ene Chemical compound FC(F)(F)C(=C)C(F)(F)F QMIWYOZFFSLIAK-UHFFFAOYSA-N 0.000 description 1
- NTJPBRSQUATARU-UHFFFAOYSA-N 3,3,4,4,4-pentafluoro-2-(trifluoromethyl)but-1-ene Chemical compound FC(F)(F)C(=C)C(F)(F)C(F)(F)F NTJPBRSQUATARU-UHFFFAOYSA-N 0.000 description 1
- IZHPSCJEIFFRLN-UHFFFAOYSA-N 3,3,4,4,4-pentafluorobut-1-ene Chemical compound FC(F)(F)C(F)(F)C=C IZHPSCJEIFFRLN-UHFFFAOYSA-N 0.000 description 1
- BFXXIYDHWYGSGO-UHFFFAOYSA-N 3,3,4,4,5,5,5-heptafluoro-2-methylpent-1-ene Chemical compound CC(=C)C(F)(F)C(F)(F)C(F)(F)F BFXXIYDHWYGSGO-UHFFFAOYSA-N 0.000 description 1
- LQAPOTKKMIZDGP-UHFFFAOYSA-N 3,3,4,4,5,5,5-heptafluoropent-1-ene Chemical compound FC(F)(F)C(F)(F)C(F)(F)C=C LQAPOTKKMIZDGP-UHFFFAOYSA-N 0.000 description 1
- BNLLWAALHYCOQM-UHFFFAOYSA-N 3,3,4,4-tetrafluorobut-1-ene Chemical compound FC(F)C(F)(F)C=C BNLLWAALHYCOQM-UHFFFAOYSA-N 0.000 description 1
- RBMOVUILDUBRGH-UHFFFAOYSA-N 3,3,4,5,5,5-hexafluoropent-1-ene Chemical compound FC(F)(F)C(F)C(F)(F)C=C RBMOVUILDUBRGH-UHFFFAOYSA-N 0.000 description 1
- YOIHZDOLVJDWDY-UHFFFAOYSA-N 3,4,4,4-tetrafluoro-3-(trifluoromethyl)but-1-ene Chemical compound FC(F)(F)C(F)(C=C)C(F)(F)F YOIHZDOLVJDWDY-UHFFFAOYSA-N 0.000 description 1
- YCJCPOBHORUPPD-UHFFFAOYSA-N 3,4,4,5,5,5-hexafluoropent-2-ene Chemical compound CC=C(F)C(F)(F)C(F)(F)F YCJCPOBHORUPPD-UHFFFAOYSA-N 0.000 description 1
- SCFVSGJMZBDUNL-UHFFFAOYSA-N 3,4,4,5,5,6,6,6-octafluorohex-2-ene Chemical compound CC=C(F)C(F)(F)C(F)(F)C(F)(F)F SCFVSGJMZBDUNL-UHFFFAOYSA-N 0.000 description 1
- STGFANHLXUILNY-UHFFFAOYSA-N 3,7-dioctyl-10h-phenothiazine Chemical compound C1=C(CCCCCCCC)C=C2SC3=CC(CCCCCCCC)=CC=C3NC2=C1 STGFANHLXUILNY-UHFFFAOYSA-N 0.000 description 1
- MDWVSAYEQPLWMX-UHFFFAOYSA-N 4,4'-Methylenebis(2,6-di-tert-butylphenol) Chemical compound CC(C)(C)C1=C(O)C(C(C)(C)C)=CC(CC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)=C1 MDWVSAYEQPLWMX-UHFFFAOYSA-N 0.000 description 1
- OMHQNXCLPDUMDM-UHFFFAOYSA-N 4,4,4-trifluoro-3,3-bis(trifluoromethyl)but-1-ene Chemical compound FC(F)(F)C(C=C)(C(F)(F)F)C(F)(F)F OMHQNXCLPDUMDM-UHFFFAOYSA-N 0.000 description 1
- DVQRFCKQKDQEER-UHFFFAOYSA-N 4,5,5,5-tetrafluoro-4-(trifluoromethyl)pent-1-ene Chemical compound FC(F)(F)C(F)(C(F)(F)F)CC=C DVQRFCKQKDQEER-UHFFFAOYSA-N 0.000 description 1
- CMGDVUCDZOBDNL-UHFFFAOYSA-N 4-methyl-2h-benzotriazole Chemical compound CC1=CC=CC2=NNN=C12 CMGDVUCDZOBDNL-UHFFFAOYSA-N 0.000 description 1
- XZOYHFBNQHPJRQ-UHFFFAOYSA-N 7-methyloctanoic acid Chemical compound CC(C)CCCCCC(O)=O XZOYHFBNQHPJRQ-UHFFFAOYSA-N 0.000 description 1
- RGCKGOZRHPZPFP-UHFFFAOYSA-N Alizarin Natural products C1=CC=C2C(=O)C3=C(O)C(O)=CC=C3C(=O)C2=C1 RGCKGOZRHPZPFP-UHFFFAOYSA-N 0.000 description 1
- NLZUEZXRPGMBCV-UHFFFAOYSA-N Butylhydroxytoluene Chemical compound CC1=CC(C(C)(C)C)=C(O)C(C(C)(C)C)=C1 NLZUEZXRPGMBCV-UHFFFAOYSA-N 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 241000018344 Ehrlichia sp. 'CGE agent' Species 0.000 description 1
- 239000004386 Erythritol Substances 0.000 description 1
- UNXHWFMMPAWVPI-UHFFFAOYSA-N Erythritol Natural products OCC(O)C(O)CO UNXHWFMMPAWVPI-UHFFFAOYSA-N 0.000 description 1
- UAYSMVXWICOBPT-UHFFFAOYSA-N FC(=C)C(C(F)F)(F)F.FC(C(=C(C)F)F)(F)F Chemical compound FC(=C)C(C(F)F)(F)F.FC(C(=C(C)F)F)(F)F UAYSMVXWICOBPT-UHFFFAOYSA-N 0.000 description 1
- MXMJXZRTAIQGMG-UHFFFAOYSA-N FC=C(C(F)F)F.FC(=C(C(F)F)F)F Chemical compound FC=C(C(F)F)F.FC(=C(C(F)F)F)F MXMJXZRTAIQGMG-UHFFFAOYSA-N 0.000 description 1
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- 206010021580 Inadequate lubrication Diseases 0.000 description 1
- OFOBLEOULBTSOW-UHFFFAOYSA-N Malonic acid Chemical compound OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 1
- CBENFWSGALASAD-UHFFFAOYSA-N Ozone Chemical compound [O-][O+]=O CBENFWSGALASAD-UHFFFAOYSA-N 0.000 description 1
- FQYUMYWMJTYZTK-UHFFFAOYSA-N Phenyl glycidyl ether Chemical class C1OC1COC1=CC=CC=C1 FQYUMYWMJTYZTK-UHFFFAOYSA-N 0.000 description 1
- GLOYGJPNNKTDIG-UHFFFAOYSA-N SC=1N=NSC=1S Chemical class SC=1N=NSC=1S GLOYGJPNNKTDIG-UHFFFAOYSA-N 0.000 description 1
- YSMRWXYRXBRSND-UHFFFAOYSA-N TOTP Chemical compound CC1=CC=CC=C1OP(=O)(OC=1C(=CC=CC=1)C)OC1=CC=CC=C1C YSMRWXYRXBRSND-UHFFFAOYSA-N 0.000 description 1
- 239000012190 activator Substances 0.000 description 1
- OQIQSTLJSLGHID-WNWIJWBNSA-N aflatoxin B1 Chemical group C=1([C@@H]2C=CO[C@@H]2OC=1C=C(C1=2)OC)C=2OC(=O)C2=C1CCC2=O OQIQSTLJSLGHID-WNWIJWBNSA-N 0.000 description 1
- 238000013019 agitation Methods 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- HFVAFDPGUJEFBQ-UHFFFAOYSA-M alizarin red S Chemical compound [Na+].O=C1C2=CC=CC=C2C(=O)C2=C1C=C(S([O-])(=O)=O)C(O)=C2O HFVAFDPGUJEFBQ-UHFFFAOYSA-M 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- 229910021529 ammonia Inorganic materials 0.000 description 1
- 230000003254 anti-foaming effect Effects 0.000 description 1
- JPNZKPRONVOMLL-UHFFFAOYSA-N azane;octadecanoic acid Chemical class [NH4+].CCCCCCCCCCCCCCCCCC([O-])=O JPNZKPRONVOMLL-UHFFFAOYSA-N 0.000 description 1
- QRUDEWIWKLJBPS-UHFFFAOYSA-N benzotriazole Chemical compound C1=CC=C2N[N][N]C2=C1 QRUDEWIWKLJBPS-UHFFFAOYSA-N 0.000 description 1
- 239000012964 benzotriazole Substances 0.000 description 1
- LUFPJJNWMYZRQE-UHFFFAOYSA-N benzylsulfanylmethylbenzene Chemical class C=1C=CC=CC=1CSCC1=CC=CC=C1 LUFPJJNWMYZRQE-UHFFFAOYSA-N 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- 150000001639 boron compounds Chemical class 0.000 description 1
- 230000005587 bubbling Effects 0.000 description 1
- 235000010354 butylated hydroxytoluene Nutrition 0.000 description 1
- 150000001721 carbon Chemical group 0.000 description 1
- 229910002092 carbon dioxide Inorganic materials 0.000 description 1
- 239000001569 carbon dioxide Substances 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- KYKAJFCTULSVSH-UHFFFAOYSA-N chloro(fluoro)methane Chemical compound F[C]Cl KYKAJFCTULSVSH-UHFFFAOYSA-N 0.000 description 1
- UUAGAQFQZIEFAH-UHFFFAOYSA-N chlorotrifluoroethylene Chemical group FC(F)=C(F)Cl UUAGAQFQZIEFAH-UHFFFAOYSA-N 0.000 description 1
- 230000006835 compression Effects 0.000 description 1
- 238000007906 compression Methods 0.000 description 1
- 230000001010 compromised effect Effects 0.000 description 1
- 238000009833 condensation Methods 0.000 description 1
- 230000005494 condensation Effects 0.000 description 1
- 238000012937 correction Methods 0.000 description 1
- 230000001419 dependent effect Effects 0.000 description 1
- 238000013461 design Methods 0.000 description 1
- AFZSMODLJJCVPP-UHFFFAOYSA-N dibenzothiazol-2-yl disulfide Chemical compound C1=CC=C2SC(SSC=3SC4=CC=CC=C4N=3)=NC2=C1 AFZSMODLJJCVPP-UHFFFAOYSA-N 0.000 description 1
- IYYZUPMFVPLQIF-UHFFFAOYSA-N dibenzothiophene Chemical class C1=CC=C2C3=CC=CC=C3SC2=C1 IYYZUPMFVPLQIF-UHFFFAOYSA-N 0.000 description 1
- 239000004205 dimethyl polysiloxane Substances 0.000 description 1
- 235000013870 dimethyl polysiloxane Nutrition 0.000 description 1
- JRBPAEWTRLWTQC-UHFFFAOYSA-N dodecylamine Chemical class CCCCCCCCCCCCN JRBPAEWTRLWTQC-UHFFFAOYSA-N 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- UNXHWFMMPAWVPI-ZXZARUISSA-N erythritol Chemical compound OC[C@H](O)[C@H](O)CO UNXHWFMMPAWVPI-ZXZARUISSA-N 0.000 description 1
- 229940009714 erythritol Drugs 0.000 description 1
- 235000019414 erythritol Nutrition 0.000 description 1
- 150000002170 ethers Chemical class 0.000 description 1
- 230000001747 exhibiting effect Effects 0.000 description 1
- 239000011737 fluorine Substances 0.000 description 1
- 229910052731 fluorine Inorganic materials 0.000 description 1
- 150000002222 fluorine compounds Chemical class 0.000 description 1
- 239000004088 foaming agent Substances 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 150000002314 glycerols Chemical class 0.000 description 1
- 239000010439 graphite Substances 0.000 description 1
- 229910002804 graphite Inorganic materials 0.000 description 1
- 150000008282 halocarbons Chemical class 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 239000003112 inhibitor Substances 0.000 description 1
- GWYFCOCPABKNJV-UHFFFAOYSA-N isovaleric acid Chemical compound CC(C)CC(O)=O GWYFCOCPABKNJV-UHFFFAOYSA-N 0.000 description 1
- 150000002576 ketones Chemical class 0.000 description 1
- 230000007246 mechanism Effects 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 239000006078 metal deactivator Substances 0.000 description 1
- 239000002480 mineral oil Substances 0.000 description 1
- 239000003607 modifier Substances 0.000 description 1
- CWQXQMHSOZUFJS-UHFFFAOYSA-N molybdenum disulfide Chemical compound S=[Mo]=S CWQXQMHSOZUFJS-UHFFFAOYSA-N 0.000 description 1
- 229910052982 molybdenum disulfide Inorganic materials 0.000 description 1
- RQVGZVZFVNMBGS-UHFFFAOYSA-N n-octyl-n-phenylaniline Chemical compound C=1C=CC=CC=1N(CCCCCCCC)C1=CC=CC=C1 RQVGZVZFVNMBGS-UHFFFAOYSA-N 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- UJMWVICAENGCRF-UHFFFAOYSA-N oxygen difluoride Chemical class FOF UJMWVICAENGCRF-UHFFFAOYSA-N 0.000 description 1
- 125000005010 perfluoroalkyl group Chemical group 0.000 description 1
- 239000010702 perfluoropolyether Substances 0.000 description 1
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N phenol group Chemical group C1(=CC=CC=C1)O ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 1
- 229950000688 phenothiazine Drugs 0.000 description 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 1
- AQSJGOWTSHOLKH-UHFFFAOYSA-N phosphite(3-) Chemical class [O-]P([O-])[O-] AQSJGOWTSHOLKH-UHFFFAOYSA-N 0.000 description 1
- 150000003014 phosphoric acid esters Chemical class 0.000 description 1
- OJMIONKXNSYLSR-UHFFFAOYSA-N phosphorous acid Chemical compound OP(O)O OJMIONKXNSYLSR-UHFFFAOYSA-N 0.000 description 1
- 150000003018 phosphorus compounds Chemical class 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 230000036314 physical performance Effects 0.000 description 1
- 229920000435 poly(dimethylsiloxane) Polymers 0.000 description 1
- 229920001515 polyalkylene glycol Polymers 0.000 description 1
- 229920013639 polyalphaolefin Polymers 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 229920001296 polysiloxane Polymers 0.000 description 1
- 239000005077 polysulfide Substances 0.000 description 1
- 229920001021 polysulfide Polymers 0.000 description 1
- 150000008117 polysulfides Polymers 0.000 description 1
- 239000002516 radical scavenger Substances 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 230000004044 response Effects 0.000 description 1
- 238000005096 rolling process Methods 0.000 description 1
- 239000000565 sealant Substances 0.000 description 1
- 238000007789 sealing Methods 0.000 description 1
- 150000004760 silicates Chemical class 0.000 description 1
- 229920002545 silicone oil Polymers 0.000 description 1
- 239000008137 solubility enhancer Substances 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- GKASDNZWUGIAMG-UHFFFAOYSA-N triethyl orthoformate Chemical compound CCOC(OCC)OCC GKASDNZWUGIAMG-UHFFFAOYSA-N 0.000 description 1
- 150000003752 zinc compounds Chemical class 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K5/00—Heat-transfer, heat-exchange or heat-storage materials, e.g. refrigerants; Materials for the production of heat or cold by chemical reactions other than by combustion
- C09K5/02—Materials undergoing a change of physical state when used
- C09K5/04—Materials undergoing a change of physical state when used the change of state being from liquid to vapour or vice versa
- C09K5/041—Materials undergoing a change of physical state when used the change of state being from liquid to vapour or vice versa for compression-type refrigeration systems
- C09K5/044—Materials undergoing a change of physical state when used the change of state being from liquid to vapour or vice versa for compression-type refrigeration systems comprising halogenated compounds
- C09K5/045—Materials undergoing a change of physical state when used the change of state being from liquid to vapour or vice versa for compression-type refrigeration systems comprising halogenated compounds containing only fluorine as halogen
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M105/00—Lubricating compositions characterised by the base-material being a non-macromolecular organic compound
- C10M105/08—Lubricating compositions characterised by the base-material being a non-macromolecular organic compound containing oxygen
- C10M105/32—Esters
- C10M105/38—Esters of polyhydroxy compounds
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M171/00—Lubricating compositions characterised by purely physical criteria, e.g. containing as base-material, thickener or additive, ingredients which are characterised exclusively by their numerically specified physical properties, i.e. containing ingredients which are physically well-defined but for which the chemical nature is either unspecified or only very vaguely indicated
- C10M171/008—Lubricant compositions compatible with refrigerants
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K2205/00—Aspects relating to compounds used in compression type refrigeration systems
- C09K2205/10—Components
- C09K2205/104—Carboxylic acid esters
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K2205/00—Aspects relating to compounds used in compression type refrigeration systems
- C09K2205/10—Components
- C09K2205/12—Hydrocarbons
- C09K2205/126—Unsaturated fluorinated hydrocarbons
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/28—Esters
- C10M2207/283—Esters of polyhydroxy compounds
- C10M2207/2835—Esters of polyhydroxy compounds used as base material
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2020/00—Specified physical or chemical properties or characteristics, i.e. function, of component of lubricating compositions
- C10N2020/01—Physico-chemical properties
- C10N2020/02—Viscosity; Viscosity index
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2020/00—Specified physical or chemical properties or characteristics, i.e. function, of component of lubricating compositions
- C10N2020/01—Physico-chemical properties
- C10N2020/071—Branched chain compounds
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2020/00—Specified physical or chemical properties or characteristics, i.e. function, of component of lubricating compositions
- C10N2020/09—Characteristics associated with water
- C10N2020/097—Refrigerants
- C10N2020/101—Containing Hydrofluorocarbons
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
- C10N2030/02—Pour-point; Viscosity index
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
- C10N2030/74—Noack Volatility
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2040/00—Specified use or application for which the lubricating composition is intended
- C10N2040/30—Refrigerators lubricants or compressors lubricants
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- General Chemical & Material Sciences (AREA)
- Materials Engineering (AREA)
- Physics & Mathematics (AREA)
- Thermal Sciences (AREA)
- Combustion & Propulsion (AREA)
- Health & Medical Sciences (AREA)
- Emergency Medicine (AREA)
- Lubricants (AREA)
Abstract
【解決手段】 ヒドロフルオロ−オレフィン冷媒などのフッ化オレフィン冷媒と、ペンタエリトリトール、ジ−ペンタエリトリトールおよびトリ−ペンタエリトリトールおよびペンタエリトリトールオリゴマーのアルキルカルボキシエステルの選択混合物を含む高粘度ポリオールエステルと、を含む高粘度作業流体が提供される。
【選択図】なし
Description
a)モノ−ペンタエリトリトールのC5〜12アルキルカルボキシエステル25〜40重量%、
b)ジ−ペンタエリトリトールのC5〜12アルキルカルボキシエステル15〜25重量%、ならびに
c)トリ−ペンタエリトリトールおよびトリ以上のペンタエリトリトールオリゴマーのC5〜12アルキルカルボキシエステル40〜55重量%、
を含み、
そのアルキルカルボキシ基の55〜100モル%が、C7〜10アルキルカルボキシから選択され、かつすべてのアルキルカルボキシ基の50〜80モル%、例えば55〜80モル%が分岐状である、作業流体を提供する。
a)モノ−ペンタエリトリトールのC5〜12アルキルカルボキシエステル25〜40重量%、
b)ジ−ペンタエリトリトールのC5〜12アルキルカルボキシエステル15〜25重量%、ならびに
c)トリ−ペンタエリトリトールおよびトリ以上のペンタエリトリトールオリゴマーのC5〜12アルキルカルボキシエステル40〜55重量%、
を含み、
そのアルキルカルボキシ基の55〜100モル%が、C7〜10アルキルカルボキシから選択され、かつすべてのアルキルカルボキシ基の50〜80モル%が分岐状である。多くの実施形態において、アルキルカルボキシ基の55〜80モル%が分岐状である。
a)モノ−ペンタエリトリトールのアルキルカルボキシエステル28〜40重量%、例えば30〜40重量%または33〜40重量%、
b)ジ−ペンタエリトリトールのアルキルカルボキシエステル15〜25重量%、16〜24または17〜22重量%、ならびに
c)トリ−ペンタエリトリトールおよびトリ以上のペンタエリトリトールオリゴマーのアルキルカルボキシエステル40〜54重量%、42〜54重量%または40〜50重量%、
を含む。
a)モノ−ペンタエリトリトールのアルキルカルボキシエステル25〜40重量%、
b)ジ−ペンタエリトリトールのアルキルカルボキシエステル15〜25重量%、および
c)トリ−ペンタエリトリトールおよびトリ以上のペンタエリトリトールオリゴマーのアルキルカルボキシエステル40〜55重量%、
を含む。
1,2,3,3,3−ペンタフルオロ−1−プロペン;1,1,3,3,3−ペンタフルオロ−1−プロペン;1,1,2,3,3−ペンタフルオロ−1−プロペン;1,2,3,3−テトラフルオロ−1−プロペン;2,3,3,3−テトラフルオロ−1−プロペン;1,3,3,3−テトラフルオロ−1−プロペン;1,1,2,3−テトラフルオロ−1−プロペン;1,1,3,3−テトラフルオロ−1−プロペン;1,2,3,3−テトラフルオロ−1−プロペン;3,3,3−トリフルオロ−1−プロペン;2,3,3−トリフルオロ−1−プロペン;1,1,2−トリフルオロ−1−プロペン;1,2,3−トリフルオロ−1−プロペン;1,1,3−トリフルオロ−1−プロペン;1,3,3−トリフルオロ−1−プロペン;
1,1,1,2,4,4,4−ヘプタフルオロ−2−ブテン;1,2,3,3,4,4,4−ヘプタフルオロ−1−ブテン;1,1,1,2,3,4,4−ヘプタフルオロ−2−ブテン:1,1,3,3,4,4,4−ヘプタフルオロ−1−ブテン;1,1,2,3,4,4,4−ヘプタフルオロ−1−ブテン;1,1,2,3,3,4,4−ヘプタフルオロ−1−ブテン;2,3,3,4,4,4−ヘキサフルオロ−1−ブテン;1,3,3,4,4,4−ヘキサフルオロ−1−ブテン;1,2,3,4,4,4−ヘキサフルオロ−1−ブテン;1,2,3,3,4,4−ヘキサフルオロ−1−ブテン;1,1,2,3,4,4−ヘキサフルオロ−2−ブテン;1,1,1,2,3,4−ヘキサフルオロ−2−ブテン;1,1,1,2,4,4−ヘキサフルオロ−2−ブテン;1,1,1,3,4,4−ヘキサフルオロ−2−ブテン;1,1,2,3,3,4−ヘキサフルオロ−1−ブテン;1,1,2,3,4,4−ヘキサフルオロ−1−ブテン;1,1,1,2,4−ペンタフルオロ−2−ブテン;1,1,1,3,4−ペンタフルオロ−2−ブテン;3,3,4,4,4−ペンタフルオロ−1−ブテン;1,1,1,4,4−ペンタフルオロ−2−ブテン;1,1,1,2,3−ペンタフルオロ−2−ブテン;2,3,3,4,4−ペンタフルオロ−1−ブテン;1,1,2,4,4−ペンタフルオロ−2−ブテン;1,1,2,3,3−ペンタフルオロ−1−ブテン;1,1,2,3,4−ペンタフルオロ−2−ブテン;2,3,4,4,4−ペンタフルオロ−1−ブテン;1,2,4,4,4−ペンタフルオロ−1−ブテン;1,3,4,4,4−ペンタフルオロ−1−ブテン;1,3,3,4,4−ペンタフルオロ−1−ブテン;1,2,3,4,4−ペンタフルオロ−1−ブテン;3,3,4,4−テトラフルオロ−1−ブテン;1,1,1,2−テトラフルオロ−2−ブテン;1,1,1,3−テトラフルオロ−2−ブテン;
3,3,3−トリフルオロ−2−(トリフルオロメチル)−1−プロペン;1,1−ジフルオロ−2−(ジフルオロメチル)−1−プロペン;1,3,3,3−テトラフルオロ−2−メチル−1−プロペン;3,3−ジフルオロ−2−(ジフルオロメチル)−1−プロペン;1,1,3,3,3−ペンタフルオロ−2−メチル−1−プロペン;2−(ジフルオロメチル)−3,3,3−トリフルオロ−1−プロペン;1,3,3,3−テトラフルオロ−2−(トリフルオロメチル)−1−プロペン;
1,1,1,2,4,4,5,5,5−ナノフルオロ−2−ペンテン;1,1,1,3,4,4,5,5,5−ナノフルオロ−2−ペンテン;1,2,3,3,4,4,5,5,5−ナノフルオロ−1−ペンテン;1,1,3,3,4,4,5,5,5−ナノフルオロ−1−ペンテン;1,1,2,3,3,4,4,5,5−ナノフルオロ−1−ペンテン;1,1,2,3,4,4,5,5,5−ナノフルオロ−2−ペンテン;1,1,1,2,3,4,4,5,5−ナノフルオロ−2−ペンテン;1,1,1,2,3,4,5,5,5−ナノフルオロ−2−ペンテン;
2,3,3,4,4,5,5,5−オクタフルオロ−1−ペンテン;1,2,3,3,4,4,5,5−オクタフルオロ−1−ペンテン;
3,3,4,4,5,5,5−ヘプタフルオロ−1−ペンテン;2,3,3,4,4,5,5−ヘプタフルオロ−1−ペンテン;1,1,3,3,5,5,5−ヘプタフルオロ−1−ペンテン;3,4,4,5,5,5−ヘキサフルオロ−2−ペンテン;3,3,4,5,5,5−ヘキサフルオロ−1−ペンテン;
1,1,1,4,4,4−ヘキサフルオロ−2−(トリフルオロメチル)−2−ブテン;1,2,3,4,4,4−ヘキサフルオロ−3−(トリフルオロメチル)−1−ブテン;1,1,2,4,4,4−ヘキサフルオロ−3−(トリフルオロメチル)−1−ブテン;1,1,1,4,4,4−ヘキサフルオロ−2−(トリフルオロメチル)−2−ブテン;1,1,3,4,4,4−ヘキサフルオロ−3−(トリフルオロメチル)−1−ブテン;3,3,4,4,4−ペンタフルオロ−2−(トリフルオロメチル)−1−ブテン;1,1,4,4,4−ペンタフルオロ−3−(トリフルオロメチル)−1−ブテン;1,3,4,4,4−ペンタフルオロ−3−(トリフルオロメチル)−1−ブテン;1,1,4,4,4−ペンタフルオロ−2−(トリフルオロメチル)−1−ブテン;3,4,4,4−テトラフルオロ−3−(トリフルオロメチル)−1−ブテン;1,1,1,2,4,4,4−ヘプタフルオロ−3−メチル−2−ブテン;2,4,4,4−テトラフルオロ−3−(トリフルオロメチル)−1−ブテン;1,4,4,4−テトラフルオロ−3−(トリフルオロメチル)−1−ブテン;1,1,1,4−テトラフルオロ−2−(トリフルオロメチル)−2−ブテン;1,1,1,3−テトラフルオロ−2−(トリフルオロメチル)−2−ブテン;1,1,1−トリフルオロ−2−(トリフルオロメチル)−2−ブテン;1,1,1,4,4,4−ヘキサフルオロ−2−メチル−2−ブテン;4,4,4−トリフルオロ−2−(トリフルオロメチル)−1−ブテン;
3,3,4,4,5,5,6,6,6−ナノフルオロ−1−ヘキセン;3,4,4,5,5,6,6,6−オクタフルオロ−2−ヘキセン;3,3,4,4,5,5,6,6−オクタフルオロ−1−ヘキセン;4,4,5,5,6,6,6−ヘプタフルオロ−2−ヘキセン;4,4,5,5,6,6,6−ヘプタフルオロ−1−ヘキセン;1,1,1,2,2,3,4−ヘプタフルオロ−3−ヘキセン;
1,1,1,4,4,5,5,5−オクタフルオロ−2−(トリフルオロメチル)−2−ペンテン;1,1,1,3,4,5,5,5−オクタフルオロ−4−(トリフルオロメチル)−2−ペンテン;4,4,4−トリフルオロ−3,3−ビス(トリフルオロメチル)−1−ブテン;1,1,1,4,4,4−ヘキサフルオロ−3−メチル−2−(トリフルオロメチル)−2−ブテン;2,3,3,5,5,5−ヘキサフルオロ−4−(トリフルオロメチル)−1−ペンテン;1,1,1,2,4,4,5,5,5−ナノフルオロ−3−メチル−2−ペンテン;1,1,1,5,5,5−ヘキサフルオロ−4−(トリフルオロメチル)−2−ペンテン;1,1,1,4,4−ペンタフルオロ−2−(トリフルオロメチル)−2−ペンテン;,4,5,5,5−ペンタフルオロ−2−(トリフルオロメチル)−1−ペンテン;3,3,4,4,5,5,5−ヘプタフルオロ−2−メチル−1−ペンテン;
4,5,5,5−テトラフルオロ−4−(トリフルオロメチル)−1−ペンテン;1,1,1,2,5,5,5−ヘプタフルオロ−4−メチル−2−ペンテン;
1,1,1,3−テトラフルオロ−2−(トリフルオロメチル)−2−ペンテン;等
のEおよびZ異性体が挙げられる。
過フッ素化オレフィンとしては:
1,1,1,2,3,4,4,4−オクタフルオロ−2−ブテン;1,1,2,3,3,4,4,4−オクタフルオロ−1−ブテン、1,1,1,2,3,4,4,5,5,5−デカフルオロ−2−ペンテン;1,1,2,3,3,4,4,5,5,5−デカフルオロ−1−ペンテン;1,1,2,3,3,4,4,5,5,6,6,6−ドデカフルオロ−1−ヘキセン;1,1,1,2,2,3,4,5,5,6,6,6−ドデカフルオロ−3−ヘキセン;1,1,1,4,4,4−ヘキサフルオロ−2,3−ビス(トリフルオロメチル)−2−ブテン;1,1,1,2,3,4,5,5,5−ナノフルオロ−4−(トリフルオロメチル)−2−ペンテン等が挙げられる。
上記の方法を用いて、以下のポリオールエステル組成物を調製した。モノ−ペンタエリトリトールエステルとジ−ペンタエリトリトールエステルとトリ−ペンタエリトリトールエステルとトリ以上のペンタエリトリトールエステルの割合は、GPCによって決定される、すべてのかかるエステルに対する重量%として報告し、カルボキシレート基は、使用される酸の総モル数に対して、エステル化プロセスに添加される各酸のモルパーセントで報告され;i−C5は、2−メチルブタン酸約34%およびn−ペンタン酸66%の混合物である、イソペンタン酸と呼ばれる工業化学生成物であり;i−C9は、工業的にイソノナン酸として知られる、3,5,5−トリメチルヘキサン酸であり;n−C8C10は、主にn−オクタン酸とn−デカン酸の混合物であり、かつ例えば、Proctor and Gamble Chemicals社からC−810(NA)として市販されている、工業化学生成物である。
Claims (15)
- i)フッ化オレフィン冷媒と、
ii)40℃での動粘度150〜360cStを有するポリオールエステル潤滑剤組成物であって、
a)モノ−ペンタエリトリトールのC5〜12アルキルカルボキシエステル25〜40重量%、
b)ジ−ペンタエリトリトールのC5〜12アルキルカルボキシエステル15〜25重量%、ならびに
c)トリ−ペンタエリトリトールおよびトリ以上のペンタエリトリトールオリゴマーのC5〜12アルキルカルボキシエステル40〜55重量%、
を含むポリオールエステル潤滑剤組成物と、を含む作業流体であって、
前記アルキルカルボキシ基の55〜100モル%が、C7〜10アルキルカルボキシから選択され、かつすべてのアルキルカルボキシ基の50〜80モル%が分岐状である、作業流体。 - 前記アルキルカルボキシ基の70〜100モル%が、C7〜10アルキルカルボキシから選択される、請求項1に記載の作業流体。
- 前記アルキルカルボキシ基の55〜80モル%が、分岐状である、請求項1に記載の作業流体。
- 前記ポリオールエステル潤滑剤組成物の28〜39重量%が、モノ−ペンタエリトリトールのアルキルカルボキシエステルからなる、請求項1に記載の作業流体。
- 前記ポリオールエステル潤滑剤組成物が、
a)モノ−ペンタエリトリトールのC5〜12アルキルカルボキシエステル28〜40重量%、
b)ジ−ペンタエリトリトールのC5〜12アルキルカルボキシエステル16〜24重量%、ならびに
c)トリ−ペンタエリトリトールおよびトリ以上のペンタエリトリトールオリゴマーのC5〜12アルキルカルボキシエステル42〜54重量%、
を含む、請求項1に記載の作業流体。 - 前記分岐状アルキルカルボキシ基の51〜100%が、3,5,5−トリメチルヘキサノイルまたは2,2,4,4−テトラメチルブタノイルである、請求項1に記載の作業流体。
- 前記ポリオールエステル潤滑剤組成物が、少なくとも160cStの40℃での動粘度を有する、請求項1に記載の作業流体。
- 前記ポリオールエステル潤滑剤組成物が、194〜340cStの40℃での動粘度を有する、請求項1に記載の作業流体。
- フッ化オレフィン冷媒が、炭素原子2〜7個のヒドロフルオロ−オレフィンまたはパーフルオロ−オレフィンを含む、請求項1に記載の作業流体。
- 前記ヒドロフルオロ−オレフィンまたはパーフルオロ−オレフィンが、3個以上のフッ素原子を含有する、請求項9に記載の作業流体。
- 前記ヒドロフルオロ−オレフィンまたはパーフルオロ−オレフィンが、4個以上のフッ素原子を含有する、請求項10に記載の作業流体。
- 前記ヒドロフルオロ−オレフィンまたはパーフルオロ−オレフィンが、ペンタフルオロ−、テトラフルオロ−、またはトリフルオロ−プロペン異性体を含む、請求項10に記載の作業流体。
- 前記フッ化オレフィン冷媒が、テトラフルオロ−プロペン異性体を含む、請求項1に記載の作業流体。
- 前記フッ化オレフィン冷媒が、ヒドロフルオロ−オレフィンおよび/またはパーフルオロ−オレフィン、および炭化水素、フッ素化アルキン、ヒドロフルオロ−アルカンおよび/またはパーフルオロアルカン冷媒を含む混合物である、請求項1に記載の作業流体。
- 前記フッ化オレフィン冷媒が、ヒドロフルオロ−オレフィンおよびヒドロフルオロ−アルカンを含む混合物である、請求項15に記載の作業流体。
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US201562185341P | 2015-06-26 | 2015-06-26 | |
US62/185,341 | 2015-06-26 | ||
PCT/US2016/034947 WO2016209560A1 (en) | 2015-06-26 | 2016-05-31 | Working fluids comprising fluorinated olefins and polyol esters |
Publications (2)
Publication Number | Publication Date |
---|---|
JP2018524441A true JP2018524441A (ja) | 2018-08-30 |
JP6741696B2 JP6741696B2 (ja) | 2020-08-19 |
Family
ID=56133076
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP2017566095A Active JP6741696B2 (ja) | 2015-06-26 | 2016-05-31 | フッ化オレフィンおよびポリオールエステルを含む作業流体 |
Country Status (5)
Country | Link |
---|---|
US (1) | US9683158B2 (ja) |
EP (1) | EP3313965B1 (ja) |
JP (1) | JP6741696B2 (ja) |
CN (1) | CN107810258B (ja) |
WO (1) | WO2016209560A1 (ja) |
Families Citing this family (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP6605016B2 (ja) * | 2015-02-20 | 2019-11-13 | Jxtgエネルギー株式会社 | 冷凍機油及び冷凍機用作動流体組成物 |
FR3077822B1 (fr) | 2018-02-15 | 2020-07-24 | Arkema France | Compositions de transfert de chaleur en remplacement du r-134a |
FR3077773B1 (fr) | 2018-02-15 | 2023-05-26 | Arkema France | Procede de chauffage et / ou de climatisation d’un vehicule |
Citations (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH08505160A (ja) * | 1992-06-03 | 1996-06-04 | ヘンケル・コーポレイション | 高温で運転する冷凍コンプレッサー用ポリオールエステル潤滑剤 |
JP2003531279A (ja) * | 2000-04-26 | 2003-10-21 | コグニス コーポレーション | 金属表面の磨耗を減らし運転中の冷蔵機器中の環境を加水分解に安定な状態に維持する方法 |
JP2005533149A (ja) * | 2002-07-12 | 2005-11-04 | ハトコ・コーポレーション | 高粘度合成エステル潤滑剤ベースストック |
JP2012515834A (ja) * | 2009-01-26 | 2012-07-12 | ケムチュア コーポレイション | 冷蔵システムのためのポリオールエステル潤滑剤の製造 |
JP2013523978A (ja) * | 2010-04-06 | 2013-06-17 | ケムチュア コーポレイション | 冷凍油及び二酸化炭素冷媒組成物 |
JP2013529717A (ja) * | 2010-06-30 | 2013-07-22 | アルケマ フランス | 2,3,3,3−テトラフルオロプロペンを含む組成物 |
JP2015507060A (ja) * | 2013-02-05 | 2015-03-05 | ケムチュア コーポレイション | 炭化水素冷媒を有する冷凍オイルおよび組成物 |
JP2015508842A (ja) * | 2012-02-15 | 2015-03-23 | ケムチュア コーポレイション | ジフルオロメタンおよびジペンタエリトリトールエステルを含む動作流体 |
JP2015508841A (ja) * | 2012-02-15 | 2015-03-23 | ケムチュア コーポレイション | ジフルオロメタンを含む動作流体用のポリエステル潤滑剤 |
Family Cites Families (15)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3670013A (en) | 1969-10-16 | 1972-06-13 | Hercules Inc | Synthesis of partial esters of certain poly(neopentyl polyols) and aliphatic monocarboxylic acids |
JP2967574B2 (ja) | 1990-11-16 | 1999-10-25 | 株式会社日立製作所 | 冷凍装置 |
US5895778A (en) | 1997-08-25 | 1999-04-20 | Hatco Corporation | Poly(neopentyl polyol) ester based coolants and improved additive package |
US7759532B2 (en) | 2006-01-13 | 2010-07-20 | E.I. Du Pont De Nemours And Company | Refrigerant additive compositions containing perfluoropolyethers |
JP5139665B2 (ja) | 2006-11-02 | 2013-02-06 | 出光興産株式会社 | 冷凍機用潤滑油組成物 |
US20100181523A1 (en) | 2009-01-16 | 2010-07-22 | Chemtura Corporation | Carbon dioxide-based working fluids for refrigeration and air conditioning systems |
EP2585550A4 (en) | 2010-06-22 | 2014-10-08 | Arkema Inc | Heat transfer compositions of liquid hydrocarbons and a hydrofluoroolefin |
BR112013000242A2 (pt) | 2010-07-06 | 2016-05-17 | Arkema Inc | composições de um tetrafluoropropeno e lubrificantes de éster de poliol |
US9187682B2 (en) * | 2011-06-24 | 2015-11-17 | Emerson Climate Technologies, Inc. | Refrigeration compressor lubricant |
FR2986236B1 (fr) * | 2012-01-26 | 2014-01-10 | Arkema France | Compositions de transfert de chaleur presentant une miscibilite amelioree avec l'huile de lubrification |
US8685271B2 (en) * | 2012-02-08 | 2014-04-01 | Chemtura Corporation | Refrigeration oil and compositions with hydrocarbon refrigerants |
JP5914066B2 (ja) * | 2012-03-12 | 2016-05-11 | 出光興産株式会社 | 冷凍機用潤滑油組成物 |
JP6067103B2 (ja) * | 2013-03-25 | 2017-01-25 | Jxエネルギー株式会社 | 冷凍機用作動流体組成物 |
US9505967B2 (en) * | 2014-07-14 | 2016-11-29 | Chemtura Corporation | Working fluids comprising fluorinated olefins/fluorinated saturated hydrocarbon blends and polyol esters |
TWI522456B (zh) * | 2015-03-27 | 2016-02-21 | Novel refrigeration oil |
-
2016
- 2016-05-24 US US15/162,671 patent/US9683158B2/en active Active
- 2016-05-31 EP EP16729708.4A patent/EP3313965B1/en active Active
- 2016-05-31 JP JP2017566095A patent/JP6741696B2/ja active Active
- 2016-05-31 WO PCT/US2016/034947 patent/WO2016209560A1/en unknown
- 2016-05-31 CN CN201680037550.8A patent/CN107810258B/zh active Active
Patent Citations (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH08505160A (ja) * | 1992-06-03 | 1996-06-04 | ヘンケル・コーポレイション | 高温で運転する冷凍コンプレッサー用ポリオールエステル潤滑剤 |
JP2003531279A (ja) * | 2000-04-26 | 2003-10-21 | コグニス コーポレーション | 金属表面の磨耗を減らし運転中の冷蔵機器中の環境を加水分解に安定な状態に維持する方法 |
JP2005533149A (ja) * | 2002-07-12 | 2005-11-04 | ハトコ・コーポレーション | 高粘度合成エステル潤滑剤ベースストック |
JP2012515834A (ja) * | 2009-01-26 | 2012-07-12 | ケムチュア コーポレイション | 冷蔵システムのためのポリオールエステル潤滑剤の製造 |
JP2013523978A (ja) * | 2010-04-06 | 2013-06-17 | ケムチュア コーポレイション | 冷凍油及び二酸化炭素冷媒組成物 |
JP2013529717A (ja) * | 2010-06-30 | 2013-07-22 | アルケマ フランス | 2,3,3,3−テトラフルオロプロペンを含む組成物 |
JP2015508842A (ja) * | 2012-02-15 | 2015-03-23 | ケムチュア コーポレイション | ジフルオロメタンおよびジペンタエリトリトールエステルを含む動作流体 |
JP2015508841A (ja) * | 2012-02-15 | 2015-03-23 | ケムチュア コーポレイション | ジフルオロメタンを含む動作流体用のポリエステル潤滑剤 |
JP2015507060A (ja) * | 2013-02-05 | 2015-03-05 | ケムチュア コーポレイション | 炭化水素冷媒を有する冷凍オイルおよび組成物 |
Also Published As
Publication number | Publication date |
---|---|
US9683158B2 (en) | 2017-06-20 |
EP3313965A1 (en) | 2018-05-02 |
CN107810258B (zh) | 2021-02-09 |
CN107810258A (zh) | 2018-03-16 |
EP3313965B1 (en) | 2021-07-07 |
WO2016209560A1 (en) | 2016-12-29 |
JP6741696B2 (ja) | 2020-08-19 |
US20160376485A1 (en) | 2016-12-29 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
JP5462977B2 (ja) | 冷凍油及び二酸化炭素冷媒組成物 | |
DK1979432T3 (en) | REFRIGERANT ADDITIVE COMPOSITIONS CONTAINING PERFLUOROUS POLYETHERS | |
JP6063486B2 (ja) | 冷凍機油および冷凍機用作動流体組成物 | |
TWI640617B (zh) | 包含氟化烯烴/氟化飽和烴摻和物及聚醇酯之工作流體 | |
JP6021948B2 (ja) | ジフルオロメタンを含む動作流体用のポリエステル潤滑剤 | |
JP5848465B2 (ja) | 炭化水素冷媒を有する冷凍オイルおよび組成物 | |
JPWO2018052088A1 (ja) | 冷凍機油及び冷凍機用作動流体組成物 | |
WO2013062058A1 (ja) | 冷凍機用作動流体組成物及び冷凍機油 | |
US20160068731A1 (en) | Methods and apparatus using refrigerant compositions comprising refrigerant and lubricant comprising perfluoropolyether and non-fluorinated lubricant | |
JP6021949B2 (ja) | ジフルオロメタンおよびジペンタエリトリトールエステルを含む動作流体 | |
JP2012515251A (ja) | 冷蔵及び空調システム用の二酸化炭素をベースとする作動流体 | |
JP6605015B2 (ja) | 冷凍機油及び冷凍機用作動流体組成物 | |
US8685271B2 (en) | Refrigeration oil and compositions with hydrocarbon refrigerants | |
JP6624486B2 (ja) | 冷凍機潤滑油及び冷凍機用混合組成物 | |
JP6741696B2 (ja) | フッ化オレフィンおよびポリオールエステルを含む作業流体 | |
JP6925323B2 (ja) | 冷凍機油 | |
WO2024009684A1 (ja) | 冷凍機油及び作動流体組成物 | |
JP6763511B2 (ja) | 冷凍機用潤滑油組成物、冷凍機用組成物、潤滑方法及び冷凍機 | |
BRPI0706862B1 (pt) | Compositions, method of cooling production, method of producing heat, process of heat transfer, process of replacement of refrigerant or heat transfer fluid, refrigeration system, air conditioning appliances and heating pumps with transfer surfaces of heat | |
MX2008008927A (en) | Refrigerant additive compositions containing perfluoropolyethers |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
A621 | Written request for application examination |
Free format text: JAPANESE INTERMEDIATE CODE: A621 Effective date: 20190220 |
|
A131 | Notification of reasons for refusal |
Free format text: JAPANESE INTERMEDIATE CODE: A131 Effective date: 20191121 |
|
A977 | Report on retrieval |
Free format text: JAPANESE INTERMEDIATE CODE: A971007 Effective date: 20191127 |
|
A521 | Request for written amendment filed |
Free format text: JAPANESE INTERMEDIATE CODE: A523 Effective date: 20200221 |
|
TRDD | Decision of grant or rejection written | ||
A01 | Written decision to grant a patent or to grant a registration (utility model) |
Free format text: JAPANESE INTERMEDIATE CODE: A01 Effective date: 20200709 |
|
A61 | First payment of annual fees (during grant procedure) |
Free format text: JAPANESE INTERMEDIATE CODE: A61 Effective date: 20200727 |
|
R150 | Certificate of patent or registration of utility model |
Ref document number: 6741696 Country of ref document: JP Free format text: JAPANESE INTERMEDIATE CODE: R150 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
S111 | Request for change of ownership or part of ownership |
Free format text: JAPANESE INTERMEDIATE CODE: R313111 |
|
R350 | Written notification of registration of transfer |
Free format text: JAPANESE INTERMEDIATE CODE: R350 |