JP2018135336A - メルドラム酸のフッ素化誘導体、その調製方法、および溶媒添加剤としてのそれらの使用 - Google Patents
メルドラム酸のフッ素化誘導体、その調製方法、および溶媒添加剤としてのそれらの使用 Download PDFInfo
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- JP2018135336A JP2018135336A JP2018045302A JP2018045302A JP2018135336A JP 2018135336 A JP2018135336 A JP 2018135336A JP 2018045302 A JP2018045302 A JP 2018045302A JP 2018045302 A JP2018045302 A JP 2018045302A JP 2018135336 A JP2018135336 A JP 2018135336A
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- Prior art keywords
- compound
- formula
- fluorine
- acid
- halogen
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- 239000000654 additive Substances 0.000 title claims abstract description 30
- GXHFUVWIGNLZSC-UHFFFAOYSA-N meldrum's acid Chemical class CC1(C)OC(=O)CC(=O)O1 GXHFUVWIGNLZSC-UHFFFAOYSA-N 0.000 title claims abstract description 8
- 239000002904 solvent Substances 0.000 title claims description 42
- 238000000034 method Methods 0.000 title claims description 18
- 230000000996 additive effect Effects 0.000 title claims description 14
- 238000002360 preparation method Methods 0.000 title description 17
- 229910001416 lithium ion Inorganic materials 0.000 claims abstract description 19
- UMBWWNIKAJSCLR-UHFFFAOYSA-N 2,2-bis(trifluoromethyl)-1,3-dioxane-4,6-dione Chemical compound FC(F)(F)C1(C(F)(F)F)OC(=O)CC(=O)O1 UMBWWNIKAJSCLR-UHFFFAOYSA-N 0.000 claims abstract description 4
- DYQLTJKSPZLVBF-UHFFFAOYSA-N 2,2-difluoro-1,3-dioxane-4,6-dione Chemical compound FC1(F)OC(=O)CC(=O)O1 DYQLTJKSPZLVBF-UHFFFAOYSA-N 0.000 claims abstract 2
- 150000001875 compounds Chemical class 0.000 claims description 60
- 229910052731 fluorine Inorganic materials 0.000 claims description 41
- 239000003792 electrolyte Substances 0.000 claims description 40
- 239000000203 mixture Substances 0.000 claims description 37
- 239000011737 fluorine Substances 0.000 claims description 36
- 125000004435 hydrogen atom Chemical class [H]* 0.000 claims description 28
- 125000000217 alkyl group Chemical group 0.000 claims description 24
- 229910052739 hydrogen Inorganic materials 0.000 claims description 24
- -1 monofluoromethyl Chemical group 0.000 claims description 23
- 150000003839 salts Chemical class 0.000 claims description 23
- PXGOKWXKJXAPGV-UHFFFAOYSA-N Fluorine Chemical compound FF PXGOKWXKJXAPGV-UHFFFAOYSA-N 0.000 claims description 22
- 239000001257 hydrogen Substances 0.000 claims description 22
- 125000001153 fluoro group Chemical group F* 0.000 claims description 21
- OFOBLEOULBTSOW-UHFFFAOYSA-N Malonic acid Chemical compound OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 claims description 18
- 125000005843 halogen group Chemical group 0.000 claims description 18
- 229910052736 halogen Inorganic materials 0.000 claims description 17
- 150000002367 halogens Chemical class 0.000 claims description 17
- 239000002253 acid Substances 0.000 claims description 14
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims description 11
- RBCXEDQEZDUMHD-UHFFFAOYSA-N 2-fluoropropanedioic acid Chemical compound OC(=O)C(F)C(O)=O RBCXEDQEZDUMHD-UHFFFAOYSA-N 0.000 claims description 10
- 238000006243 chemical reaction Methods 0.000 claims description 9
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 claims description 7
- 229910052744 lithium Inorganic materials 0.000 claims description 7
- 238000004519 manufacturing process Methods 0.000 claims description 7
- HBBGRARXTFLTSG-UHFFFAOYSA-N Lithium ion Chemical compound [Li+] HBBGRARXTFLTSG-UHFFFAOYSA-N 0.000 claims description 6
- 150000002576 ketones Chemical class 0.000 claims description 6
- 125000001424 substituent group Chemical group 0.000 claims description 6
- JDZCKJOXGCMJGS-UHFFFAOYSA-N [Li].[S] Chemical compound [Li].[S] JDZCKJOXGCMJGS-UHFFFAOYSA-N 0.000 claims description 5
- 125000001028 difluoromethyl group Chemical group [H]C(F)(F)* 0.000 claims description 4
- 125000002023 trifluoromethyl group Chemical group FC(F)(F)* 0.000 claims description 4
- 239000003638 chemical reducing agent Substances 0.000 claims description 2
- 229910052717 sulfur Inorganic materials 0.000 abstract description 6
- 239000011593 sulfur Substances 0.000 abstract description 6
- YVHNAOVYVIYGGQ-UHFFFAOYSA-N 2-methyl-2-(trifluoromethyl)-1,3-dioxane-4,6-dione Chemical compound FC(F)(F)C1(C)OC(=O)CC(=O)O1 YVHNAOVYVIYGGQ-UHFFFAOYSA-N 0.000 abstract description 2
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 abstract description 2
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 15
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 14
- 239000007858 starting material Substances 0.000 description 13
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 9
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 9
- 125000004432 carbon atom Chemical group C* 0.000 description 9
- 229910012258 LiPO Inorganic materials 0.000 description 7
- 239000000460 chlorine Substances 0.000 description 7
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 7
- WFDIJRYMOXRFFG-UHFFFAOYSA-N Acetic anhydride Chemical compound CC(=O)OC(C)=O WFDIJRYMOXRFFG-UHFFFAOYSA-N 0.000 description 6
- WEVYAHXRMPXWCK-UHFFFAOYSA-N Acetonitrile Chemical compound CC#N WEVYAHXRMPXWCK-UHFFFAOYSA-N 0.000 description 6
- ZMANZCXQSJIPKH-UHFFFAOYSA-N Triethylamine Chemical compound CCN(CC)CC ZMANZCXQSJIPKH-UHFFFAOYSA-N 0.000 description 6
- OOYYGNJJGDSKFX-UHFFFAOYSA-N 2,2,5-trifluoro-1,3-dioxane-4,6-dione Chemical compound FC1C(=O)OC(F)(F)OC1=O OOYYGNJJGDSKFX-UHFFFAOYSA-N 0.000 description 5
- ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 description 5
- 239000012025 fluorinating agent Substances 0.000 description 5
- 238000006467 substitution reaction Methods 0.000 description 5
- 125000006273 (C1-C3) alkyl group Chemical group 0.000 description 4
- 125000004169 (C1-C6) alkyl group Chemical group 0.000 description 4
- DLFVBJFMPXGRIB-UHFFFAOYSA-N Acetamide Chemical compound CC(N)=O DLFVBJFMPXGRIB-UHFFFAOYSA-N 0.000 description 4
- ZHNUHDYFZUAESO-UHFFFAOYSA-N Formamide Chemical compound NC=O ZHNUHDYFZUAESO-UHFFFAOYSA-N 0.000 description 4
- 229910013870 LiPF 6 Inorganic materials 0.000 description 4
- JUJWROOIHBZHMG-UHFFFAOYSA-N Pyridine Chemical compound C1=CC=NC=C1 JUJWROOIHBZHMG-UHFFFAOYSA-N 0.000 description 4
- 238000009835 boiling Methods 0.000 description 4
- 238000006482 condensation reaction Methods 0.000 description 4
- 125000000753 cycloalkyl group Chemical group 0.000 description 4
- IEJIGPNLZYLLBP-UHFFFAOYSA-N dimethyl carbonate Chemical compound COC(=O)OC IEJIGPNLZYLLBP-UHFFFAOYSA-N 0.000 description 4
- 150000002148 esters Chemical class 0.000 description 4
- 125000000468 ketone group Chemical group 0.000 description 4
- 125000004433 nitrogen atom Chemical group N* 0.000 description 4
- 229920006395 saturated elastomer Chemical class 0.000 description 4
- DWFDQVMFSLLMPE-UHFFFAOYSA-N (2-fluorophenyl)-phenylmethanone Chemical compound FC1=CC=CC=C1C(=O)C1=CC=CC=C1 DWFDQVMFSLLMPE-UHFFFAOYSA-N 0.000 description 3
- GETTZEONDQJALK-UHFFFAOYSA-N (trifluoromethyl)benzene Chemical compound FC(F)(F)C1=CC=CC=C1 GETTZEONDQJALK-UHFFFAOYSA-N 0.000 description 3
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 description 3
- OIFBSDVPJOWBCH-UHFFFAOYSA-N Diethyl carbonate Chemical compound CCOC(=O)OCC OIFBSDVPJOWBCH-UHFFFAOYSA-N 0.000 description 3
- ZMXDDKWLCZADIW-UHFFFAOYSA-N N,N-Dimethylformamide Chemical compound CN(C)C=O ZMXDDKWLCZADIW-UHFFFAOYSA-N 0.000 description 3
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 3
- 125000002947 alkylene group Chemical group 0.000 description 3
- 150000001412 amines Chemical class 0.000 description 3
- 150000004649 carbonic acid derivatives Chemical class 0.000 description 3
- 238000001816 cooling Methods 0.000 description 3
- 150000002170 ethers Chemical class 0.000 description 3
- 239000007789 gas Substances 0.000 description 3
- 239000003960 organic solvent Substances 0.000 description 3
- 125000004430 oxygen atom Chemical group O* 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
- BWQOPMJTQPWHOZ-UHFFFAOYSA-N (2,3-difluorophenyl)-phenylmethanone Chemical compound FC1=CC=CC(C(=O)C=2C=CC=CC=2)=C1F BWQOPMJTQPWHOZ-UHFFFAOYSA-N 0.000 description 2
- 125000006552 (C3-C8) cycloalkyl group Chemical group 0.000 description 2
- BKJABVBFDOILQH-UHFFFAOYSA-N 1,3-dioxane-2,4,6-trione Chemical compound O=C1CC(=O)OC(=O)O1 BKJABVBFDOILQH-UHFFFAOYSA-N 0.000 description 2
- OLYKCPDTXVZOQF-UHFFFAOYSA-N 2,2-difluoro-1-phenylethanone Chemical compound FC(F)C(=O)C1=CC=CC=C1 OLYKCPDTXVZOQF-UHFFFAOYSA-N 0.000 description 2
- GQHTUMJGOHRCHB-UHFFFAOYSA-N 2,3,4,6,7,8,9,10-octahydropyrimido[1,2-a]azepine Chemical compound C1CCCCN2CCCN=C21 GQHTUMJGOHRCHB-UHFFFAOYSA-N 0.000 description 2
- SBLRHMKNNHXPHG-UHFFFAOYSA-N 4-fluoro-1,3-dioxolan-2-one Chemical compound FC1COC(=O)O1 SBLRHMKNNHXPHG-UHFFFAOYSA-N 0.000 description 2
- YOSFSHDCKQJNPJ-UHFFFAOYSA-N 5-fluoro-1,3-dioxane-2,4,6-trione Chemical compound FC1C(=O)OC(=O)OC1=O YOSFSHDCKQJNPJ-UHFFFAOYSA-N 0.000 description 2
- QRJPDKWBAWCFLY-UHFFFAOYSA-N 5-fluoro-2,2-bis(trifluoromethyl)-1,3-dioxane-4,6-dione Chemical compound FC1C(=O)OC(C(F)(F)F)(C(F)(F)F)OC1=O QRJPDKWBAWCFLY-UHFFFAOYSA-N 0.000 description 2
- XLNMSDVPHBAUKN-UHFFFAOYSA-N 5-fluoro-2,2-dimethyl-1,3-dioxane-4,6-dione Chemical compound CC1(C)OC(=O)C(F)C(=O)O1 XLNMSDVPHBAUKN-UHFFFAOYSA-N 0.000 description 2
- VCYFFUQTWAJOJY-UHFFFAOYSA-N 5-fluoro-2-methyl-2-(trifluoromethyl)-1,3-dioxane-4,6-dione Chemical compound FC(F)(F)C1(C)OC(=O)C(F)C(=O)O1 VCYFFUQTWAJOJY-UHFFFAOYSA-N 0.000 description 2
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
- KMTRUDSVKNLOMY-UHFFFAOYSA-N Ethylene carbonate Chemical compound O=C1OCCO1 KMTRUDSVKNLOMY-UHFFFAOYSA-N 0.000 description 2
- 229910013063 LiBF 4 Inorganic materials 0.000 description 2
- DTQVDTLACAAQTR-UHFFFAOYSA-N Trifluoroacetic acid Chemical compound OC(=O)C(F)(F)F DTQVDTLACAAQTR-UHFFFAOYSA-N 0.000 description 2
- HXELGNKCCDGMMN-UHFFFAOYSA-N [F].[Cl] Chemical group [F].[Cl] HXELGNKCCDGMMN-UHFFFAOYSA-N 0.000 description 2
- 150000001408 amides Chemical class 0.000 description 2
- 150000001450 anions Chemical class 0.000 description 2
- 150000004657 carbamic acid derivatives Chemical class 0.000 description 2
- 229910052799 carbon Inorganic materials 0.000 description 2
- 229910052801 chlorine Inorganic materials 0.000 description 2
- 125000004122 cyclic group Chemical group 0.000 description 2
- CSJLBAMHHLJAAS-UHFFFAOYSA-N diethylaminosulfur trifluoride Chemical compound CCN(CC)S(F)(F)F CSJLBAMHHLJAAS-UHFFFAOYSA-N 0.000 description 2
- 238000004821 distillation Methods 0.000 description 2
- 239000008151 electrolyte solution Substances 0.000 description 2
- 238000003682 fluorination reaction Methods 0.000 description 2
- 125000004216 fluoromethyl group Chemical group [H]C([H])(F)* 0.000 description 2
- 230000007062 hydrolysis Effects 0.000 description 2
- 238000006460 hydrolysis reaction Methods 0.000 description 2
- VDVLPSWVDYJFRW-UHFFFAOYSA-N lithium;bis(fluorosulfonyl)azanide Chemical compound [Li+].FS(=O)(=O)[N-]S(F)(=O)=O VDVLPSWVDYJFRW-UHFFFAOYSA-N 0.000 description 2
- 150000002825 nitriles Chemical class 0.000 description 2
- 229910052757 nitrogen Inorganic materials 0.000 description 2
- 150000004812 organic fluorine compounds Chemical class 0.000 description 2
- FDPIMTJIUBPUKL-UHFFFAOYSA-N pentan-3-one Chemical compound CCC(=O)CC FDPIMTJIUBPUKL-UHFFFAOYSA-N 0.000 description 2
- SSOLNOMRVKKSON-UHFFFAOYSA-N proguanil Chemical compound CC(C)\N=C(/N)N=C(N)NC1=CC=C(Cl)C=C1 SSOLNOMRVKKSON-UHFFFAOYSA-N 0.000 description 2
- RUOJZAUFBMNUDX-UHFFFAOYSA-N propylene carbonate Chemical compound CC1COC(=O)O1 RUOJZAUFBMNUDX-UHFFFAOYSA-N 0.000 description 2
- UMJSCPRVCHMLSP-UHFFFAOYSA-N pyridine Natural products COC1=CC=CN=C1 UMJSCPRVCHMLSP-UHFFFAOYSA-N 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- 239000000243 solution Substances 0.000 description 2
- JGKUAQBKVQNKMP-UHFFFAOYSA-N (1,3-dimethylimidazol-2-ylidene)-dimethylazanium Chemical compound CN(C)C=1N(C)C=C[N+]=1C JGKUAQBKVQNKMP-UHFFFAOYSA-N 0.000 description 1
- SLARRTIBTVWHPF-UHFFFAOYSA-N (2-acetyloxy-5-fluorophenyl)methyl acetate Chemical compound CC(=O)OCC1=CC(F)=CC=C1OC(C)=O SLARRTIBTVWHPF-UHFFFAOYSA-N 0.000 description 1
- PUNIIEHHUHGISF-UHFFFAOYSA-N (2-fluorophenyl) acetate Chemical compound CC(=O)OC1=CC=CC=C1F PUNIIEHHUHGISF-UHFFFAOYSA-N 0.000 description 1
- IAWZWMGUTKRLQB-UHFFFAOYSA-N (3-fluorophenyl) acetate Chemical compound CC(=O)OC1=CC=CC(F)=C1 IAWZWMGUTKRLQB-UHFFFAOYSA-N 0.000 description 1
- YXGCBJYOUJQVJP-SNAWJCMRSA-N (3e)-5,6-difluoroocta-3,7-dien-2-one Chemical compound CC(=O)\C=C\C(F)C(F)C=C YXGCBJYOUJQVJP-SNAWJCMRSA-N 0.000 description 1
- ZNOREXRHKZXVPC-UHFFFAOYSA-N (4-fluorophenyl) acetate Chemical compound CC(=O)OC1=CC=C(F)C=C1 ZNOREXRHKZXVPC-UHFFFAOYSA-N 0.000 description 1
- OGTSHGYHILFRHD-UHFFFAOYSA-N (4-fluorophenyl)-phenylmethanone Chemical compound C1=CC(F)=CC=C1C(=O)C1=CC=CC=C1 OGTSHGYHILFRHD-UHFFFAOYSA-N 0.000 description 1
- 125000004178 (C1-C4) alkyl group Chemical group 0.000 description 1
- SFEKJPRYZMFTFH-OWOJBTEDSA-N (e)-1,1,1,2,2,3,3,4,4,5,5,6,6,9,9,10,10,11,11,12,12,13,13,14,14,14-hexacosafluorotetradec-7-ene Chemical group FC(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)\C=C\C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)F SFEKJPRYZMFTFH-OWOJBTEDSA-N 0.000 description 1
- OLXJWIOOAUUDHX-UHFFFAOYSA-N 1,1,1,2,2,3,3-heptafluoro-4-prop-2-enoxybutane Chemical compound FC(F)(F)C(F)(F)C(F)(F)COCC=C OLXJWIOOAUUDHX-UHFFFAOYSA-N 0.000 description 1
- GRVMOMUDALILLH-UHFFFAOYSA-N 1,1,1,2,4,5,5,5-octafluoro-2,4-bis(trifluoromethyl)pentan-3-one Chemical compound FC(F)(F)C(F)(C(F)(F)F)C(=O)C(F)(C(F)(F)F)C(F)(F)F GRVMOMUDALILLH-UHFFFAOYSA-N 0.000 description 1
- FHUDAMLDXFJHJE-UHFFFAOYSA-N 1,1,1-trifluoropropan-2-one Chemical compound CC(=O)C(F)(F)F FHUDAMLDXFJHJE-UHFFFAOYSA-N 0.000 description 1
- MPMWFMRRLDGGDN-UHFFFAOYSA-N 1,2,4,5-tetrafluoro-3,6-bis[(2-methylpropan-2-yl)oxy]benzene Chemical compound CC(C)(C)OC1=C(F)C(F)=C(OC(C)(C)C)C(F)=C1F MPMWFMRRLDGGDN-UHFFFAOYSA-N 0.000 description 1
- NWUYHJFMYQTDRP-UHFFFAOYSA-N 1,2-bis(ethenyl)benzene;1-ethenyl-2-ethylbenzene;styrene Chemical compound C=CC1=CC=CC=C1.CCC1=CC=CC=C1C=C.C=CC1=CC=CC=C1C=C NWUYHJFMYQTDRP-UHFFFAOYSA-N 0.000 description 1
- CQPIMIJDRWLFGV-UHFFFAOYSA-N 1,3-difluoro-5-prop-2-enylbenzene Chemical compound FC1=CC(F)=CC(CC=C)=C1 CQPIMIJDRWLFGV-UHFFFAOYSA-N 0.000 description 1
- WNXJIVFYUVYPPR-UHFFFAOYSA-N 1,3-dioxolane Chemical compound C1COCO1 WNXJIVFYUVYPPR-UHFFFAOYSA-N 0.000 description 1
- VEKYDKPRZVBKTD-UHFFFAOYSA-N 1,4-bis(1,1,2,2-tetrafluoroethoxy)benzene 2,4-bis(trifluoromethyl)benzaldehyde Chemical compound FC(C1=C(C=O)C=CC(=C1)C(F)(F)F)(F)F.FC(C(F)F)(OC1=CC=C(C=C1)OC(C(F)F)(F)F)F VEKYDKPRZVBKTD-UHFFFAOYSA-N 0.000 description 1
- XCSRDHYEONHVMI-UHFFFAOYSA-N 1-(2,2,3,3-tetrafluoro-1,4-benzodioxin-6-yl)ethanone Chemical compound O1C(F)(F)C(F)(F)OC2=CC(C(=O)C)=CC=C21 XCSRDHYEONHVMI-UHFFFAOYSA-N 0.000 description 1
- FXQWZAIGWRETAQ-UHFFFAOYSA-N 1-(2,2-difluoro-1,3-benzodioxol-4-yl)ethanone Chemical compound CC(=O)C1=CC=CC2=C1OC(F)(F)O2 FXQWZAIGWRETAQ-UHFFFAOYSA-N 0.000 description 1
- LQASUDVYVOFKNK-UHFFFAOYSA-N 1-(3-fluoro-4-methoxyphenyl)ethanone Chemical compound COC1=CC=C(C(C)=O)C=C1F LQASUDVYVOFKNK-UHFFFAOYSA-N 0.000 description 1
- OWEIAGSMFHSSES-UHFFFAOYSA-N 1-[1,1,1,3,3,3-hexafluoro-2-(4-methylphenyl)propan-2-yl]-4-methylbenzene Chemical compound C1=CC(C)=CC=C1C(C(F)(F)F)(C(F)(F)F)C1=CC=C(C)C=C1 OWEIAGSMFHSSES-UHFFFAOYSA-N 0.000 description 1
- ZXYHOZFIJPZMTE-UHFFFAOYSA-N 1-[3-phenyl-5-(trifluoromethyl)pyrazol-1-yl]ethanone Chemical compound C1=C(C(F)(F)F)N(C(=O)C)N=C1C1=CC=CC=C1 ZXYHOZFIJPZMTE-UHFFFAOYSA-N 0.000 description 1
- AQFXIWDRLHRFIC-UHFFFAOYSA-N 1-[5-phenyl-3-(trifluoromethyl)pyrazol-1-yl]ethanone Chemical compound CC(=O)N1N=C(C(F)(F)F)C=C1C1=CC=CC=C1 AQFXIWDRLHRFIC-UHFFFAOYSA-N 0.000 description 1
- AODSTUBSNYVSSL-UHFFFAOYSA-N 1-fluoro-4-phenoxybenzene Chemical compound C1=CC(F)=CC=C1OC1=CC=CC=C1 AODSTUBSNYVSSL-UHFFFAOYSA-N 0.000 description 1
- NRKYWOKHZRQRJR-UHFFFAOYSA-N 2,2,2-trifluoroacetamide Chemical compound NC(=O)C(F)(F)F NRKYWOKHZRQRJR-UHFFFAOYSA-N 0.000 description 1
- 125000004206 2,2,2-trifluoroethyl group Chemical group [H]C([H])(*)C(F)(F)F 0.000 description 1
- DGCOGZQDAXUUBY-UHFFFAOYSA-N 2,2-difluoro-1,3-benzodioxole Chemical compound C1=CC=C2OC(F)(F)OC2=C1 DGCOGZQDAXUUBY-UHFFFAOYSA-N 0.000 description 1
- NIBFJPXGNVPNHK-UHFFFAOYSA-N 2,2-difluoro-1,3-benzodioxole-4-carbaldehyde Chemical compound C1=CC(C=O)=C2OC(F)(F)OC2=C1 NIBFJPXGNVPNHK-UHFFFAOYSA-N 0.000 description 1
- LRTRRTZWJXMMGS-UHFFFAOYSA-N 2,2-difluoroethyl ethenyl carbonate Chemical compound FC(F)COC(=O)OC=C LRTRRTZWJXMMGS-UHFFFAOYSA-N 0.000 description 1
- WXVCMUWGHFXASO-UHFFFAOYSA-N 2,2-difluoroethyl ethyl carbonate Chemical compound CCOC(=O)OCC(F)F WXVCMUWGHFXASO-UHFFFAOYSA-N 0.000 description 1
- VGKKQOMMALQKIC-UHFFFAOYSA-N 2,2-difluoroethyl fluoromethyl carbonate Chemical compound FCOC(=O)OCC(F)F VGKKQOMMALQKIC-UHFFFAOYSA-N 0.000 description 1
- 125000004778 2,2-difluoroethyl group Chemical group [H]C([H])(*)C([H])(F)F 0.000 description 1
- QOARFWDBTJVWJG-UHFFFAOYSA-N 2,2-difluoroethyl methyl carbonate Chemical compound COC(=O)OCC(F)F QOARFWDBTJVWJG-UHFFFAOYSA-N 0.000 description 1
- ZJVUKUFQQGRGIJ-UHFFFAOYSA-N 2,2-difluoroethyl phenyl carbonate Chemical compound FC(F)COC(=O)OC1=CC=CC=C1 ZJVUKUFQQGRGIJ-UHFFFAOYSA-N 0.000 description 1
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- BGMWVJKEILRZEL-UHFFFAOYSA-N 2,6-bis(2,2,2-trifluoroacetyl)cyclohexan-1-one Chemical compound FC(F)(F)C(=O)C1CCCC(C(=O)C(F)(F)F)C1=O BGMWVJKEILRZEL-UHFFFAOYSA-N 0.000 description 1
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- XVUMEEAIPCCPHI-UHFFFAOYSA-N 2-fluoroethyl fluoromethyl carbonate Chemical compound FCCOC(=O)OCF XVUMEEAIPCCPHI-UHFFFAOYSA-N 0.000 description 1
- NOLGJZJMWUDWQW-UHFFFAOYSA-N 2-fluoroethyl methyl carbonate Chemical compound COC(=O)OCCF NOLGJZJMWUDWQW-UHFFFAOYSA-N 0.000 description 1
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- APOYTRAZFJURPB-UHFFFAOYSA-N 2-methoxy-n-(2-methoxyethyl)-n-(trifluoro-$l^{4}-sulfanyl)ethanamine Chemical group COCCN(S(F)(F)F)CCOC APOYTRAZFJURPB-UHFFFAOYSA-N 0.000 description 1
- QDFXRVAOBHEBGJ-UHFFFAOYSA-N 3-(cyclononen-1-yl)-4,5,6,7,8,9-hexahydro-1h-diazonine Chemical compound C1CCCCCCC=C1C1=NNCCCCCC1 QDFXRVAOBHEBGJ-UHFFFAOYSA-N 0.000 description 1
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- BUPLCMMXKFWTTA-UHFFFAOYSA-N 4-methylidene-1,3-dioxetan-2-one Chemical compound C=C1OC(=O)O1 BUPLCMMXKFWTTA-UHFFFAOYSA-N 0.000 description 1
- WVPPBVAMKNQXJA-UHFFFAOYSA-N 5-fluoro-2,3-dihydroinden-1-one Chemical compound FC1=CC=C2C(=O)CCC2=C1 WVPPBVAMKNQXJA-UHFFFAOYSA-N 0.000 description 1
- IKHGUXGNUITLKF-UHFFFAOYSA-N Acetaldehyde Chemical compound CC=O IKHGUXGNUITLKF-UHFFFAOYSA-N 0.000 description 1
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 description 1
- 229910017008 AsF 6 Inorganic materials 0.000 description 1
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- BTBUEUYNUDRHOZ-UHFFFAOYSA-N Borate Chemical compound [O-]B([O-])[O-] BTBUEUYNUDRHOZ-UHFFFAOYSA-N 0.000 description 1
- 229910020366 ClO 4 Inorganic materials 0.000 description 1
- XDTMQSROBMDMFD-UHFFFAOYSA-N Cyclohexane Chemical compound C1CCCCC1 XDTMQSROBMDMFD-UHFFFAOYSA-N 0.000 description 1
- OTMSDBZUPAUEDD-UHFFFAOYSA-N Ethane Chemical compound CC OTMSDBZUPAUEDD-UHFFFAOYSA-N 0.000 description 1
- RNMKRUMRQFBXDF-UHFFFAOYSA-N FC=1C=CC2=C(C(CCS2)=O)C1.FC1=C(C=CC=C1)C1=CC=C(C=C1)C(CC)=O Chemical compound FC=1C=CC2=C(C(CCS2)=O)C1.FC1=C(C=CC=C1)C1=CC=C(C=C1)C(CC)=O RNMKRUMRQFBXDF-UHFFFAOYSA-N 0.000 description 1
- SMFNIURNBQXLJX-UHFFFAOYSA-N FNS(=O)=O Chemical compound FNS(=O)=O SMFNIURNBQXLJX-UHFFFAOYSA-N 0.000 description 1
- 101000801643 Homo sapiens Retinal-specific phospholipid-transporting ATPase ABCA4 Proteins 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- 229910015015 LiAsF 6 Inorganic materials 0.000 description 1
- 229910013684 LiClO 4 Inorganic materials 0.000 description 1
- FXHOOIRPVKKKFG-UHFFFAOYSA-N N,N-Dimethylacetamide Chemical compound CN(C)C(C)=O FXHOOIRPVKKKFG-UHFFFAOYSA-N 0.000 description 1
- XCOBLONWWXQEBS-KPKJPENVSA-N N,O-bis(trimethylsilyl)trifluoroacetamide Chemical compound C[Si](C)(C)O\C(C(F)(F)F)=N\[Si](C)(C)C XCOBLONWWXQEBS-KPKJPENVSA-N 0.000 description 1
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 1
- 229910019142 PO4 Inorganic materials 0.000 description 1
- ABLZXFCXXLZCGV-UHFFFAOYSA-N Phosphorous acid Chemical class OP(O)=O ABLZXFCXXLZCGV-UHFFFAOYSA-N 0.000 description 1
- 102100033617 Retinal-specific phospholipid-transporting ATPase ABCA4 Human genes 0.000 description 1
- 229910018540 Si C Inorganic materials 0.000 description 1
- LSNNMFCWUKXFEE-UHFFFAOYSA-N Sulfurous acid Chemical compound OS(O)=O LSNNMFCWUKXFEE-UHFFFAOYSA-N 0.000 description 1
- VUBHUFOPOIRUMQ-UHFFFAOYSA-N [4-(2,2,2-trifluoroethoxy)phenyl] benzoate Chemical compound C1=CC(OCC(F)(F)F)=CC=C1OC(=O)C1=CC=CC=C1 VUBHUFOPOIRUMQ-UHFFFAOYSA-N 0.000 description 1
- KOYQRASDYYHQSU-UHFFFAOYSA-N [5-methyl-3-(trifluoromethyl)pyrazol-1-yl]-phenylmethanone Chemical compound CC1=CC(C(F)(F)F)=NN1C(=O)C1=CC=CC=C1 KOYQRASDYYHQSU-UHFFFAOYSA-N 0.000 description 1
- WLLIXJBWWFGEHT-UHFFFAOYSA-N [tert-butyl(dimethyl)silyl] trifluoromethanesulfonate Chemical compound CC(C)(C)[Si](C)(C)OS(=O)(=O)C(F)(F)F WLLIXJBWWFGEHT-UHFFFAOYSA-N 0.000 description 1
- 150000003869 acetamides Chemical class 0.000 description 1
- 238000005903 acid hydrolysis reaction Methods 0.000 description 1
- 230000002378 acidificating effect Effects 0.000 description 1
- 125000004448 alkyl carbonyl group Chemical group 0.000 description 1
- 239000000010 aprotic solvent Substances 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 150000004982 aromatic amines Chemical class 0.000 description 1
- 150000001491 aromatic compounds Chemical class 0.000 description 1
- 125000003118 aryl group Chemical group 0.000 description 1
- 125000004429 atom Chemical group 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- KOFHHTAACWXRFQ-UPHRSURJSA-N bis(1,1,1,3,3,3-hexafluoropropan-2-yl) (z)-but-2-enedioate Chemical compound FC(F)(F)C(C(F)(F)F)OC(=O)\C=C/C(=O)OC(C(F)(F)F)C(F)(F)F KOFHHTAACWXRFQ-UPHRSURJSA-N 0.000 description 1
- OICRDFIVTSEVJJ-UHFFFAOYSA-N bis(1,1,1,3,3,3-hexafluoropropan-2-yl) 2-methylidenebutanedioate Chemical compound FC(F)(F)C(C(F)(F)F)OC(=O)CC(=C)C(=O)OC(C(F)(F)F)C(F)(F)F OICRDFIVTSEVJJ-UHFFFAOYSA-N 0.000 description 1
- OGBKVDKHMNTXID-OWOJBTEDSA-N bis(1,1,2,2,3,3,4,4,5,5,6,6,7,7,8,8,8-heptadecafluorooctyl) (e)-but-2-enedioate Chemical compound FC(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)OC(=O)\C=C\C(=O)OC(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)F OGBKVDKHMNTXID-OWOJBTEDSA-N 0.000 description 1
- KZTDZFZLDVZRCF-UPHRSURJSA-N bis(2,2,2-trifluoroethyl) (z)-but-2-enedioate Chemical compound FC(F)(F)COC(=O)\C=C/C(=O)OCC(F)(F)F KZTDZFZLDVZRCF-UPHRSURJSA-N 0.000 description 1
- WLLOZRDOFANZMZ-UHFFFAOYSA-N bis(2,2,2-trifluoroethyl) carbonate Chemical compound FC(F)(F)COC(=O)OCC(F)(F)F WLLOZRDOFANZMZ-UHFFFAOYSA-N 0.000 description 1
- UYFISINJOLGYBJ-UHFFFAOYSA-N bis(2,2-difluoroethyl) carbonate Chemical compound FC(F)COC(=O)OCC(F)F UYFISINJOLGYBJ-UHFFFAOYSA-N 0.000 description 1
- IOVVFSGCNWQFQT-UHFFFAOYSA-N bis(2,3,4,5,6-pentafluorophenyl) carbonate Chemical compound FC1=C(F)C(F)=C(F)C(F)=C1OC(=O)OC1=C(F)C(F)=C(F)C(F)=C1F IOVVFSGCNWQFQT-UHFFFAOYSA-N 0.000 description 1
- YZWIIIGEQKTIMS-UHFFFAOYSA-N bis(2-fluoroethyl) carbonate Chemical compound FCCOC(=O)OCCF YZWIIIGEQKTIMS-UHFFFAOYSA-N 0.000 description 1
- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 150000001732 carboxylic acid derivatives Chemical class 0.000 description 1
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- 150000001768 cations Chemical class 0.000 description 1
- 239000003153 chemical reaction reagent Substances 0.000 description 1
- 238000004587 chromatography analysis Methods 0.000 description 1
- 150000005676 cyclic carbonates Chemical class 0.000 description 1
- MHKHJIJXMVHRAJ-UHFFFAOYSA-N cyclopropyl-(4-fluorophenyl)methanone Chemical compound C1=CC(F)=CC=C1C(=O)C1CC1 MHKHJIJXMVHRAJ-UHFFFAOYSA-N 0.000 description 1
- 238000006114 decarboxylation reaction Methods 0.000 description 1
- 239000012024 dehydrating agents Substances 0.000 description 1
- 150000005690 diesters Chemical class 0.000 description 1
- UBMQHNSEGKYMTP-UHFFFAOYSA-N diethyl 2,2,3,3,4,4,5,5-octafluorohexanedioate Chemical compound CCOC(=O)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(=O)OCC UBMQHNSEGKYMTP-UHFFFAOYSA-N 0.000 description 1
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- 125000001664 diethylamino group Chemical group [H]C([H])([H])C([H])([H])N(*)C([H])([H])C([H])([H])[H] 0.000 description 1
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 1
- BOMPXIHODLVNMC-UHFFFAOYSA-N difluoro(diphenyl)silane Chemical compound C=1C=CC=CC=1[Si](F)(F)C1=CC=CC=C1 BOMPXIHODLVNMC-UHFFFAOYSA-N 0.000 description 1
- PBWZKZYHONABLN-UHFFFAOYSA-M difluoroacetate Chemical compound [O-]C(=O)C(F)F PBWZKZYHONABLN-UHFFFAOYSA-M 0.000 description 1
- 125000004786 difluoromethoxy group Chemical group [H]C(F)(F)O* 0.000 description 1
- VWCDXEKXDIWXKI-UHFFFAOYSA-N difluoromethyl ethyl carbonate Chemical compound CCOC(=O)OC(F)F VWCDXEKXDIWXKI-UHFFFAOYSA-N 0.000 description 1
- VDGKFLGYHYBDQC-UHFFFAOYSA-N difluoromethyl methyl carbonate Chemical compound COC(=O)OC(F)F VDGKFLGYHYBDQC-UHFFFAOYSA-N 0.000 description 1
- PMUJBDOVBQRNLP-UHFFFAOYSA-N dimethyl-bis(2,3,4,5,6-pentafluorophenyl)silane Chemical compound FC=1C(F)=C(F)C(F)=C(F)C=1[Si](C)(C)C1=C(F)C(F)=C(F)C(F)=C1F PMUJBDOVBQRNLP-UHFFFAOYSA-N 0.000 description 1
- 150000002009 diols Chemical class 0.000 description 1
- 125000004185 ester group Chemical group 0.000 description 1
- DPGXGQNEWAAUKM-UHFFFAOYSA-N ethenyl 2,2,2-trifluoroethyl carbonate Chemical compound FC(F)(F)COC(=O)OC=C DPGXGQNEWAAUKM-UHFFFAOYSA-N 0.000 description 1
- JCBADTLNWNTCNV-UHFFFAOYSA-N ethenyl 2-fluoroethyl carbonate Chemical compound FCCOC(=O)OC=C JCBADTLNWNTCNV-UHFFFAOYSA-N 0.000 description 1
- BDNXATXQVYVLCI-UHFFFAOYSA-N ethenyl fluoromethyl carbonate Chemical compound FCOC(=O)OC=C BDNXATXQVYVLCI-UHFFFAOYSA-N 0.000 description 1
- 125000002573 ethenylidene group Chemical group [*]=C=C([H])[H] 0.000 description 1
- NIQAXIMIQJNOKY-UHFFFAOYSA-N ethyl 2,2,2-trifluoroethyl carbonate Chemical compound CCOC(=O)OCC(F)(F)F NIQAXIMIQJNOKY-UHFFFAOYSA-N 0.000 description 1
- XLHKMGHXUXYDQJ-UHFFFAOYSA-N ethyl 2-fluoroethyl carbonate Chemical compound CCOC(=O)OCCF XLHKMGHXUXYDQJ-UHFFFAOYSA-N 0.000 description 1
- UHHPUKUEMKPCII-UHFFFAOYSA-N ethyl fluoromethyl carbonate Chemical compound CCOC(=O)OCF UHHPUKUEMKPCII-UHFFFAOYSA-N 0.000 description 1
- JBTWLSYIZRCDFO-UHFFFAOYSA-N ethyl methyl carbonate Chemical compound CCOC(=O)OC JBTWLSYIZRCDFO-UHFFFAOYSA-N 0.000 description 1
- ZPBVUMUIOIGYRV-UHFFFAOYSA-N ethyl trifluoromethyl carbonate Chemical compound CCOC(=O)OC(F)(F)F ZPBVUMUIOIGYRV-UHFFFAOYSA-N 0.000 description 1
- 238000000605 extraction Methods 0.000 description 1
- PIQRQRGUYXRTJJ-UHFFFAOYSA-N fluoromethyl methyl carbonate Chemical compound COC(=O)OCF PIQRQRGUYXRTJJ-UHFFFAOYSA-N 0.000 description 1
- KUPHFFIERSZZDV-UHFFFAOYSA-N fluoromethyl phenyl carbonate Chemical compound FCOC(=O)OC1=CC=CC=C1 KUPHFFIERSZZDV-UHFFFAOYSA-N 0.000 description 1
- 125000001207 fluorophenyl group Chemical group 0.000 description 1
- 125000000524 functional group Chemical group 0.000 description 1
- 125000000623 heterocyclic group Chemical class 0.000 description 1
- VBZWSGALLODQNC-UHFFFAOYSA-N hexafluoroacetone Chemical compound FC(F)(F)C(=O)C(F)(F)F VBZWSGALLODQNC-UHFFFAOYSA-N 0.000 description 1
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- 239000011261 inert gas Substances 0.000 description 1
- 239000012442 inert solvent Substances 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- 239000003456 ion exchange resin Substances 0.000 description 1
- 229920003303 ion-exchange polymer Polymers 0.000 description 1
- 150000002596 lactones Chemical class 0.000 description 1
- 229910003473 lithium bis(trifluoromethanesulfonyl)imide Inorganic materials 0.000 description 1
- QSZMZKBZAYQGRS-UHFFFAOYSA-N lithium;bis(trifluoromethylsulfonyl)azanide Chemical compound [Li+].FC(F)(F)S(=O)(=O)[N-]S(=O)(=O)C(F)(F)F QSZMZKBZAYQGRS-UHFFFAOYSA-N 0.000 description 1
- 150000002690 malonic acid derivatives Chemical class 0.000 description 1
- 230000003446 memory effect Effects 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 229910001512 metal fluoride Inorganic materials 0.000 description 1
- GBPVMEKUJUKTBA-UHFFFAOYSA-N methyl 2,2,2-trifluoroethyl carbonate Chemical compound COC(=O)OCC(F)(F)F GBPVMEKUJUKTBA-UHFFFAOYSA-N 0.000 description 1
- OJURWUUOVGOHJZ-UHFFFAOYSA-N methyl 2-[(2-acetyloxyphenyl)methyl-[2-[(2-acetyloxyphenyl)methyl-(2-methoxy-2-oxoethyl)amino]ethyl]amino]acetate Chemical compound C=1C=CC=C(OC(C)=O)C=1CN(CC(=O)OC)CCN(CC(=O)OC)CC1=CC=CC=C1OC(C)=O OJURWUUOVGOHJZ-UHFFFAOYSA-N 0.000 description 1
- CXHHBNMLPJOKQD-UHFFFAOYSA-M methyl carbonate Chemical compound COC([O-])=O CXHHBNMLPJOKQD-UHFFFAOYSA-M 0.000 description 1
- YSYBYIDPNZPQLJ-UHFFFAOYSA-N methyl trifluoromethyl carbonate Chemical compound COC(=O)OC(F)(F)F YSYBYIDPNZPQLJ-UHFFFAOYSA-N 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- PYLWMHQQBFSUBP-UHFFFAOYSA-N monofluorobenzene Chemical compound FC1=CC=CC=C1 PYLWMHQQBFSUBP-UHFFFAOYSA-N 0.000 description 1
- BNTFCVMJHBNJAR-UHFFFAOYSA-N n,n-diethyl-1,1,2,3,3,3-hexafluoropropan-1-amine Chemical compound CCN(CC)C(F)(F)C(F)C(F)(F)F BNTFCVMJHBNJAR-UHFFFAOYSA-N 0.000 description 1
- RQUXJBKONYSFAU-UHFFFAOYSA-N n,n-diethyl-2,3,3,3-tetrafluoropropanamide Chemical compound CCN(CC)C(=O)C(F)C(F)(F)F RQUXJBKONYSFAU-UHFFFAOYSA-N 0.000 description 1
- AJFDBNQQDYLMJN-UHFFFAOYSA-N n,n-diethylacetamide Chemical compound CCN(CC)C(C)=O AJFDBNQQDYLMJN-UHFFFAOYSA-N 0.000 description 1
- 125000004971 nitroalkyl group Chemical group 0.000 description 1
- QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical group [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 description 1
- 150000005677 organic carbonates Chemical class 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- XNLICIUVMPYHGG-UHFFFAOYSA-N pentan-2-one Chemical compound CCCC(C)=O XNLICIUVMPYHGG-UHFFFAOYSA-N 0.000 description 1
- 229960004624 perflexane Drugs 0.000 description 1
- 125000005010 perfluoroalkyl group Chemical group 0.000 description 1
- ZJIJAJXFLBMLCK-UHFFFAOYSA-N perfluorohexane Chemical compound FC(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)F ZJIJAJXFLBMLCK-UHFFFAOYSA-N 0.000 description 1
- OHTYZZYAMUVKQS-UHFFFAOYSA-N phenyl-[4-(trifluoromethyl)phenyl]methanone Chemical compound C1=CC(C(F)(F)F)=CC=C1C(=O)C1=CC=CC=C1 OHTYZZYAMUVKQS-UHFFFAOYSA-N 0.000 description 1
- 235000021317 phosphate Nutrition 0.000 description 1
- AQSJGOWTSHOLKH-UHFFFAOYSA-N phosphite(3-) Chemical class [O-]P([O-])[O-] AQSJGOWTSHOLKH-UHFFFAOYSA-N 0.000 description 1
- 150000003013 phosphoric acid derivatives Chemical class 0.000 description 1
- 238000004237 preparative chromatography Methods 0.000 description 1
- HNJBEVLQSNELDL-UHFFFAOYSA-N pyrrolidin-2-one Chemical compound O=C1CCCN1 HNJBEVLQSNELDL-UHFFFAOYSA-N 0.000 description 1
- 230000035484 reaction time Effects 0.000 description 1
- 229910010271 silicon carbide Inorganic materials 0.000 description 1
- HXJUTPCZVOIRIF-UHFFFAOYSA-N sulfolane Chemical compound O=S1(=O)CCCC1 HXJUTPCZVOIRIF-UHFFFAOYSA-N 0.000 description 1
- 150000003462 sulfoxides Chemical class 0.000 description 1
- 239000000725 suspension Substances 0.000 description 1
- ILMRJRBKQSSXGY-UHFFFAOYSA-N tert-butyl(dimethyl)silicon Chemical group C[Si](C)C(C)(C)C ILMRJRBKQSSXGY-UHFFFAOYSA-N 0.000 description 1
- 125000005270 trialkylamine group Chemical group 0.000 description 1
- 239000008096 xylene Substances 0.000 description 1
Classifications
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/05—Accumulators with non-aqueous electrolyte
- H01M10/056—Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes
- H01M10/0564—Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes the electrolyte being constituted of organic materials only
- H01M10/0566—Liquid materials
- H01M10/0567—Liquid materials characterised by the additives
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D319/00—Heterocyclic compounds containing six-membered rings having two oxygen atoms as the only ring hetero atoms
- C07D319/04—1,3-Dioxanes; Hydrogenated 1,3-dioxanes
- C07D319/06—1,3-Dioxanes; Hydrogenated 1,3-dioxanes not condensed with other rings
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/05—Accumulators with non-aqueous electrolyte
- H01M10/052—Li-accumulators
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/05—Accumulators with non-aqueous electrolyte
- H01M10/052—Li-accumulators
- H01M10/0525—Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodes; Lithium-ion batteries
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/05—Accumulators with non-aqueous electrolyte
- H01M10/056—Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes
- H01M10/0564—Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes the electrolyte being constituted of organic materials only
- H01M10/0566—Liquid materials
- H01M10/0569—Liquid materials characterised by the solvents
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M12/00—Hybrid cells; Manufacture thereof
- H01M12/02—Details
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
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Abstract
Description
(式中、R1およびR2は、独立して、水素、ハロゲン、または1個または複数個のハロゲン原子によって任意選択的に置換されている直鎖もしくは分枝鎖アルキル基を示し、かつR3およびR4は、独立して、水素、ハロゲン、または1個または複数個のハロゲン原子によって任意選択的に置換されている直鎖もしくは分枝鎖アルキル基を示すが、ただし、R1〜R4の少なくとも1個は、フッ素またはフッ素化置換基である)によって表される化合物に関する。
の化合物である。
を有するメルドラム酸のフッ素化誘導体である化合物の調製プロセス、方法であって、式HO(O)C−CR1R2−C(O)OH(式中、R1およびR2は、独立して、水素、ハロゲン、または1個または複数個のハロゲン原子によって任意選択的に置換されている直鎖もしくは分枝鎖アルキル基を示す)を有するマロン酸またはフルオロマロン酸と、式R3−C(O)−R4(式中、R3およびR4は、独立して、1個または複数個のハロゲン原子によって任意選択的に置換されている直鎖または分枝鎖アルキル基を示す)を有するケトンとの反応を含んでなる方法であるか、式HO(O)C−CR1R2−C(O)OH(式中、R1およびR2は、独立して、水素、ハロゲン、または1個または複数個のハロゲン原子によって任意選択的に置換されている直鎖もしくは分枝鎖アルキル基を示す)を有するマロン酸またはフルオロマロン酸を、C(O)Cl2またはC(O)F2と反応させ、そして中間体の2,4,6−トリオン化合物をSF4と反応させることによって、R3およびR4がFである式(I)の化合物を製造するための方法であるか、式HO(O)C−CR1R2−C(O)OH(式中、R1およびR2は、独立して、水素、ハロゲン、または1個または複数個のハロゲン原子によって任意選択的に置換されている直鎖もしくは分枝鎖アルキル基を示す)を有するマロン酸またはフルオロマロン酸を、C(O)Cl2またはC(O)F2と反応させ、中間体の2,4,6−トリオン化合物を還元剤、特に水素と反応させて、それぞれのC4−ヒドロキシ化合物を製造し、そして上記C4−ヒドロキシ化合物をSF4と反応させて、R3がFであり、かつR4がHである式(I)の化合物を得ることによって、R3がFであり、かつR4がHである式(I)の化合物を製造するための方法を提供する。
5−フルオロ−2,2−ビストリフルオロメチル−1,3−ジオキサン−4,6−ジオンの製造:
2−メチル−2−トリフルオロメチル−1,3−ジオキサン−4,6−ジオンの製造:
2,2−ビストリフルオロメチル−1,3−ジオキサン−4,6−ジオンの製造:
(式中、R1〜R4は、独立して、水素、ハロゲン、または1個または複数個のハロゲン原子によって任意選択的に置換されている直鎖もしくは分枝鎖アルキル基を示すが、ただし、R1〜R4の少なくとも1個は、フッ素またはフッ素化置換基である)の化合物の、再充電可能な電池、特に、導電性塩としてLi+イオンを含有する再充電可能な電池、特にLiイオン電池、Li空気電池およびLi硫黄電池のために有用な溶媒として、または好ましくは添加剤溶媒もしくは電解質組成物としての使用に関する。
の化合物が使用される。
ビス(ペンタフルオロフェニル)ジメチルシラン、1,2−ビス[ジフルオロ(メチル)シリル]エタン、N,O−ビス(トリメチルシリル)トリフルオロアセトアミド、N−(t−ブチルジメチルシリル)−N−メチルトリフルオロアセトアミド、t−ブチルジメチルシリルトリフルオロメタンスルホネート、2−ジメチルアミノ−1,3−ジメチルイミダゾリウムトリメチルジフルオロシリコネート、ジフェニルジフルオロシランからなるSi−C結合を有する化合物の群、
ビス(1,1,1,3,3,3−ヘキサフルオロプロプ−2−イル)2−メチレンスクシネート、ビス(1,1,1,3,3,3−ヘキサフルオロプロプ−2−イル)マレエート、ビス(2,2,2−トリフルオロエチル)マレエート、ビス(ペルフルオロオクチル)フマレート、ビス(ペルフルオロイソプロピル)ケトン、2,6−ビス(2,2,2−トリフルオロアセチル)シクロヘキサノン、ブチル2,2−ジフルオロアセテート、シクロプロピル−4−フルオロフェニルケトン、ジエチルペルフルオロアジペート、N,N−ジエチル−2,3,3,3−テトラフルオロプロピオンアミドからなるC=O結合を有する化合物の群、
アリル1H,1H−ヘプタフルオロブチルエーテル、トランス−1,2−ビス(ペルフルオロヘキシル)エチレン、(E)−5,6−ジフルオロオクタ−3,7−ジエン−2−オンからなるC=C結合を有する化合物の群、
N,N−ジエチル−1,1,2,3,3,3−ヘキサフルオロプロピルアミンからなるアミンの群
から選択される電解質組成物である。
RO−[(CH2)mO]n−CF2−CFH−X (A)
(式中、
Rは、1〜10C原子を有する直鎖アルキル基、または3〜10C原子を有する分枝鎖アルキル基であり、
Xは、フッ素、塩素、または1〜6C原子を有し、エーテル酸素を含んでもよいペルフルオロアルキル基であり、
mは2〜6の整数であり、かつ
nは1〜8の整数である)
および/または、式(II)
X−CFH−CF2O−[(CH2)mO]n−CF2−CFH−X (II)
(式中、X、mおよびnは、上記で与えられた意味を有する)
の部分的にフッ素化されたエーテルである。
(式中、R1〜R4は、独立して、水素、ハロゲン、または1個または複数個のハロゲン原子によって任意選択的に置換されている直鎖もしくは分枝鎖アルキル基を示すが、ただし、R1〜R4の少なくとも1個は、フッ素またはフッ素化置換基である)を有するメルドラム酸の少なくとも1種のフッ素化誘導体;ならびにLiイオン電池、Li空気電池およびLi硫黄電池の溶媒として適切な少なくとも1種の溶媒;ならびに任意選択的に、少なくとも1種の溶媒添加剤をさらに含有する、リチウムイオン電池、リチウム空気電池またはリチウム硫黄電池のための溶媒組成物に関する。好ましい溶媒および溶媒添加剤は、上記で与えられる。溶媒組成物中、少なくとも1種の式(I)の化合物の量は、しばしば、6重量%以上であり、少なくとも1種の式(I)の化合物の量は、しばしば、12重量%以下である。添加剤の量は、存在する場合、好ましくは1重量%以上であり、かつ好ましくは12重量%以下である。100重量%までの残量は、少なくとも1種の溶媒である。
(式中、R1〜R4は、独立して、水素、ハロゲン、または1個または複数個のハロゲン原子によって任意選択的に置換されている直鎖もしくは分枝鎖アルキル基を示すが、ただし、R1〜R4の少なくとも1個は、フッ素またはフッ素化置換基である)の化合物;電解質塩、ならびに任意選択的に少なくとも1種のさらなる溶媒および任意選択的に少なくとも1種のさらなる添加剤を含んでなる電解質組成物である。好ましくは、電解質組成物は、少なくとも1種の式(I)の化合物、少なくとも1種の電解質塩、ならびに少なくとも1種の溶媒および少なくとも1種のさらなる添加剤を含んでなる。好ましい式(I)の化合物、好ましい電解質塩、好ましい溶媒および好ましい添加剤は、上記で与えられるものである。
2−フルオロマロン酸ジエチルエステルは、米国特許第7,145,046号明細書の実施例2に記載の通り、80℃付近で、2−クロロマロン酸ジエチルエステルおよび1,8−ジアザビシクロ[5,4,0]ウンデク−7−エン・1,37HFから製造する。未加工の生成物を、DE−Offenlegungsschrift 4120704の実施例1と同様に、水中NaOH(NaOHの濃度:30重量%)と接触させることによって加水分解する。得られるエタノールを蒸留によって除去し、そして得られる溶液を、H型(すなわち、酸性H+を含んでなる)Lewatit S 100と接触させる。フルオロマロン酸の水溶液をトルエンと混合し、そして減圧(400mbar)下、水/トルエン混合物を除去する。
第1の工程において、フルオロマロン酸(実施例1に記載される通りに得られてもよい)を、0℃まで冷却下、トリエチルアミンの存在下でC(O)Cl2と反応させる。ジエチルエーテルを添加し、固体(ヒドロクロリド)を濾去し、低沸騰成分(主にジエチルエーテル)を蒸発させ、そして得られる2−フルオロ−1,3−ジオキサン−2,4,6−トリオンを、15時間、オートクレーブ中でSF4と接触させる。低沸騰内容物、例えば、SOF2は、真空下でオートクレーブから除去され、そして2,2,5−トリフルオロ−1,3−ジオキサン−4,6−ジオンが単離され得る。
第1の工程において、マロン酸を、0℃まで冷却下、トリエチルアミンの存在下でC(O)Cl2と反応させる。ジエチルエーテルを添加し、固体(ヒドロクロリド)を濾去し、低沸騰成分(主にジエチルエーテル)を蒸発させ、そして得られる1,3−ジオキサン−2,4,6−トリオンを、ペルフルオロヘキサン中で懸濁させる。N2中F2の気体混合物(F2対N2の体積比1:4)を、約−20℃の温度で、F2:1,3−ジオキサン−2,4,6−トリオンのモル比が約3:1になるまで、懸濁液に通過させる。F2/N2気体の流れを停止し、そして低沸騰成分(特にHF)を除去するために真空を適用する。
実施例1を繰り返すが、アセトンの代わりに1,1,1−トリフルオロアセトンを開始材料として利用する。
実施例1を繰り返すが、アセトンの代わりにヘキサフルオロアセトンを開始材料として利用する。
実施例5を繰り返すが、フルオロマロン酸の代わりにマロン酸を開始材料として利用する。
略語:
EC=エチレンカーボネート
DMC=ジメチルカーボネート
PC=プロピレンカーボネート
F1EC=フルオロエチレンカーボネート
LiPOF=LiPO2F2
Claims (14)
- 式(I):
(式中、R1およびR2は、独立して、水素、ハロゲン、または1個または複数個のハロゲン原子によって任意選択的に置換されている直鎖もしくは分枝鎖アルキル基を示し、かつR3およびR4は、独立して、水素、ハロゲン、または1個または複数個のハロゲン原子によって任意選択的に置換されている直鎖もしくは分枝鎖アルキル基を示すが、ただし、前記R1〜R4の少なくとも1個は、フッ素またはフッ素化置換基である)を有するメルドラム酸のフッ素化誘導体である化合物。 - 前記ハロゲンがフッ素である、請求項1に記載の化合物。
- R1がフッ素である、請求項1または2に記載の化合物。
- R2が水素またはフッ素である、請求項3に記載の化合物。
- R3およびR4が、独立して、フッ素、メチル、モノフルオロメチル、ジフルオロメチルおよびトリフルオロメチルからなる群から選択される、請求項2〜4のいずれか一項に記載の化合物。
- 前記化合物が式(I−1)、(I−2)、(I−3)または(I−4)
を有する、請求項1〜5のいずれか一項に記載の化合物。 - 式(I)
を有するメルドラム酸のフッ素化誘導体である化合物の調製方法であって、式HO(O)C−CR1R2−C(O)OH(式中、R1およびR2は、独立して、水素、ハロゲン、または1個または複数個のハロゲン原子によって任意選択的に置換されている直鎖もしくは分枝鎖アルキル基を示す)を有するマロン酸またはフルオロマロン酸と、式R3−C(O)−R4(式中、R3およびR4は、独立して、1個または複数個のハロゲン原子によって任意選択的に置換されている直鎖または分枝鎖アルキル基を示す)を有するケトンとの反応による方法であるか、式HO(O)C−CR1R2−C(O)OH(式中、R1およびR2は、独立して、水素、ハロゲン、または1個または複数個のハロゲン原子によって任意選択的に置換されている直鎖もしくは分枝鎖アルキル基を示す)を有するマロン酸またはフルオロマロン酸を、C(O)Cl2またはC(O)F2と反応させ、そして中間体の2,4,6−トリオン化合物をSF4と反応させることによって、R3およびR4がFである式(I)の化合物を製造するための方法であるか、式HO(O)C−CR1R2−C(O)OH(式中、R1およびR2は、独立して、水素、ハロゲン、または1個または複数個のハロゲン原子によって任意選択的に置換されている直鎖もしくは分枝鎖アルキル基を示す)を有するマロン酸またはフルオロマロン酸を、C(O)Cl2またはC(O)F2と反応させ、中間体の2,4,6−トリオン化合物を還元剤、特に水素と反応させて、それぞれのC4−ヒドロキシ化合物を製造し、そして前記C4−ヒドロキシ化合物をSF4と反応させて、R3がFであり、かつR4がHである式(I)の化合物を得ることによって、R3がFであり、かつR4がHである式(I)の化合物を製造するための方法。 - 前記ハロゲンがフッ素である、請求項7に記載の方法。
- R1がフッ素であり、かつ好ましくはR2が水素またはフッ素であり、かつ好ましくはR3およびR4が、独立して、フッ素、メチル、モノフルオロメチル、ジフルオロメチルおよびトリフルオロメチルからなる群から選択される、請求項7または8に記載の方法。
- 前記調製される化合物が、2,2−ジフルオロ−1,3−ジオキサン−4,6−ジオン、2,2−ビストリフルオロメチル−1,3−ジオキサン−4,6−ジオン、2−メチル−2−トリフルオロメチル−1,3−ジオキサン−4,6−ジオンであるか、または前記化合物が式(I−1)、(I−2)、(I−3)もしくは(I−4)
の1つを有する、請求項7〜9のいずれか一項に記載の方法。 - 請求項1〜10のいずれか一項に記載のメルドラム酸のフッ素化誘導体の、リチウムイオン電池、リチウム空気電池およびリチウム硫黄電池のための添加剤として、または電解質溶媒としての使用。
- Liイオン電池のための少なくとも1種の溶媒を含有し、さらに請求項1〜6のいずれか一項に記載の少なくとも1種のメルドラム酸のフッ素化誘導体を含有する、リチウムイオン電池、リチウム空気電池またはリチウム硫黄電池のための溶媒組成物。
- 請求項1〜6のいずれか一項に記載のメルドラム酸のフッ素化誘導体、少なくとも1種の溶媒および少なくとも1種の電解質塩を含有する、リチウムイオン電池、リチウム空気電池またはリチウム硫黄電池のための電解質組成物。
- 請求項1〜6のいずれか一項に記載のメルドラム酸のフッ素化誘導体を含有するリチウムイオン電池。
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KR20220157007A (ko) * | 2021-05-20 | 2022-11-29 | 주식회사 엘지에너지솔루션 | 리튬-황 이차전지용 전해액 및 이를 포함하는 리튬-황 이차전지 |
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US9825331B2 (en) | 2017-11-21 |
EP2785703A1 (en) | 2014-10-08 |
EP2785703B1 (en) | 2017-01-11 |
CN104080780A (zh) | 2014-10-01 |
JP2015505825A (ja) | 2015-02-26 |
KR20190075162A (ko) | 2019-06-28 |
CN104080780B (zh) | 2018-04-13 |
KR20140106602A (ko) | 2014-09-03 |
WO2013079397A1 (en) | 2013-06-06 |
US20140322618A1 (en) | 2014-10-30 |
JP6542936B2 (ja) | 2019-07-10 |
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