JP2018111693A - 毛髪用組成物、及び毛髪処理方法 - Google Patents
毛髪用組成物、及び毛髪処理方法 Download PDFInfo
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- JP2018111693A JP2018111693A JP2018016202A JP2018016202A JP2018111693A JP 2018111693 A JP2018111693 A JP 2018111693A JP 2018016202 A JP2018016202 A JP 2018016202A JP 2018016202 A JP2018016202 A JP 2018016202A JP 2018111693 A JP2018111693 A JP 2018111693A
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Classifications
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/60—Sugars; Derivatives thereof
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/34—Alcohols
- A61K8/345—Alcohols containing more than one hydroxy group
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
- A61Q5/02—Preparations for cleaning the hair
Abstract
Description
(A)トレハロース、キシロース、キシリトール及びマルチトールから選ばれた一種又は二種以上
(B)酸化エチレンの平均付加モル数が6以上であるポリエチレングリコール
(C)イソノナン酸イソトリデシル及び/又はイソノナン酸イソデシル
本実施形態に係る毛髪用組成物は、下記成分(A)及び(B)が配合されたものである。
(A)トレハロース、キシロース、キシリトール及びマルチトールから選ばれた一種又は二種以上
(B)酸化エチレンの平均付加モル数が6以上であるポリエチレングリコール
(C)イソノナン酸イソトリデシル及び/又はイソノナン酸イソデシル
実施例1〜3及び比較例1a、1b、2、3の毛髪用組成物を、下記表1〜3に記載の通り、トレハロース、PEG−20、及び水を用いて製造した。また、実施例4a、4b及び比較例4の毛髪用組成物を、下記表4に記載の通り、ポリオキシエチレン硬化ヒマシ油(30E.O.)、ポリオキシエチレンポリオキシプロピレンセチルエーテル(10E.0.)(4P.O.)、1,3−ブチレングリコール、トレハロース、PEG−20、イソノナン酸イソトリデシル、及び水を用いて製造した。なお、下記表1〜4における配合量の単位は、「質量%」である。
熱による毛髪損傷の抑制の評価を、次の通り行った。酸化染毛剤による処理履歴がある毛髪を日本人女性から採取し、長さ20〜30cm、0.5g程度の毛束を作成した。この毛束に対して、次の(1)〜(2)の処理を7回行った。(1)実施例1、比較例1a、又は比較例1bの毛髪用組成物に3分間浸漬した後、水洗し、更にドライヤーを用いて乾燥。(2)市販のヘアアイロン(株式会社ティ.アイ.プロス製ヘアアイロン「TIPシェイプアイロンSL」)における一対の発熱体の設定温度を180℃とし、その発熱体間で上記乾燥後の毛髪を10秒間加熱。そして、処理後の各毛束における毛髪30本について、初期弾性率を測定し、平均値を算出した。
アルカリ性脱色剤による毛髪損傷の抑制の評価を、次の通り行った。酸化染毛剤による処理履歴がある毛髪を日本人女性から採取し、長さ20〜30cm、3g程度の毛束を作成した。この毛束に対して、次の(1)〜(3)の処理を行った。(1)実施例2又は比較例2の毛髪用組成物に5分間浸漬した後、水洗し、更にドライヤーを用いて乾燥。(2)9g程度の脱色剤(ミルボン社製「パウダーブリーチ」1質量部とミルボン社製「オルディーブ OXIDANT 6%」3質量部の混合液)を毛束に塗布後、30分間放置。(3)水洗により脱色剤を毛束から除去した後に、ドライヤーを用いて乾燥。そして、処理後の各毛束における毛髪44本又は56本について、初期弾性率を測定し、平均値を算出した。
酸化染毛剤による処理履歴がある毛髪を日本人女性から採取し、長さ20〜30cm、2g程度の毛束を作成した。この毛束を、実施例3又は比較例3の毛髪用組成物に5分間浸漬した後、水洗し、更にドライヤーを用いて乾燥させた。そして、乾燥後の各毛束における毛髪40本について、初期弾性率を測定し、平均値を算出した。
酸化染毛剤による処理履歴がある毛髪を日本人女性から採取し、長さ20〜30cm、1g程度の毛束を作成した。この毛束を、実施例4a、4b又は比較例4の毛髪用組成物に4時間浸漬した後、水洗し、更に室温で放置して乾燥させた。そして、乾燥後の各毛束における毛髪29本について、初期弾性率を測定し、平均値を算出した。
上記「毛髪補修の評価」、「損傷抑制の評価1」、「損傷抑制の評価2」における初期弾性率の測定を、次の通り行った。毛髪一本につき、20mmの長さでカットし、両端にテープを貼りつけた。その毛髪の毛径を測定した後、この毛髪試料を、蒸留水を入れたシャーレに終夜浸漬した。その後、初期弾性率をTENSILON YTM−II−20(ORIENTEC社製)を用いて、2mm/minの速度で延伸したときの応力を測定し、得られたデータを解析プログラム(X軸を延伸率、Y軸を応力としたときの初期の傾き、いわゆるフックの傾きを算出)を使って求めた。
参考例1〜4の毛髪用組成物を、下記表5に記載の通り、イソノナン酸イソデシル、イソノナン酸イソトリデシル、イソノナン酸イソノニル、及びシクロペンタシロキサンを用いて製造した。なお、下記表5における配合量の単位は、「質量%」である。
酸化染毛剤による処理履歴がある毛髪を日本人女性から採取し、1.0g程度の毛束を作成した。この毛束に対して、参考例1〜4のいずれかの毛髪用組成物に5分間浸漬した後、毛髪表面のその組成物をふき取って一晩放置して、乾燥させた。この乾燥させた毛束を裁断後、毛髪のα-結晶が融解するときの吸熱ピークを、昇温速度10℃/分の条件でDSC測定装置(島津製作所社製「SC-60 Plus」)を使用して測定した。測定は、裁断した毛髪から2回採取し、2回の測定値の平均値を算出した。
Claims (8)
- 下記成分(A)及び(B)が配合されたことを特徴とする毛髪用組成物。
(A)トレハロース、キシロース、キシリトール及びマルチトールから選ばれた一種又は二種以上
(B)酸化エチレンの平均付加モル数が6以上であるポリエチレングリコール - 前記成分(A)として、トレハロースが配合された請求項1に記載の毛髪用組成物。
- 前記成分(B)として、酸化エチレンの平均付加モル数が12以上であるポリエチレングリコールが配合された請求項1又は2に記載の毛髪用組成物。
- 前記成分(B)として、酸化エチレンの平均付加モル数が100以下である請求項1〜3のいずれか1項に記載の毛髪用組成物。
- 前記成分(A)の配合量が前記成分(B)の配合量よりも多い請求項1〜4のいずれか1項に記載の毛髪用組成物。
- 下記成分(C)が配合された請求項1〜5のいずれか1項に記載の毛髪用組成物。
(C)イソノナン酸イソトリデシル及び/又はイソノナン酸イソデシル - 洗い流すトリートメント、洗い流さないトリートメント、又は毛髪洗浄剤として用いられる請求項1〜6のいずれか1項に記載の毛髪用組成物。
- 請求項1〜7のいずれか1項に記載の毛髪用組成物を使用することを特徴とする毛髪処理方法。
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