JP2018072828A - 感光性樹脂組成物及びこれを用いたドライフィルムレジスト - Google Patents
感光性樹脂組成物及びこれを用いたドライフィルムレジスト Download PDFInfo
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- JP2018072828A JP2018072828A JP2017204858A JP2017204858A JP2018072828A JP 2018072828 A JP2018072828 A JP 2018072828A JP 2017204858 A JP2017204858 A JP 2017204858A JP 2017204858 A JP2017204858 A JP 2017204858A JP 2018072828 A JP2018072828 A JP 2018072828A
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- 239000002253 acid Substances 0.000 description 2
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- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
- C08G18/72—Polyisocyanates or polyisothiocyanates
- C08G18/74—Polyisocyanates or polyisothiocyanates cyclic
- C08G18/76—Polyisocyanates or polyisothiocyanates cyclic aromatic
- C08G18/7657—Polyisocyanates or polyisothiocyanates cyclic aromatic containing two or more aromatic rings
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
- C08G18/72—Polyisocyanates or polyisothiocyanates
- C08G18/74—Polyisocyanates or polyisothiocyanates cyclic
- C08G18/76—Polyisocyanates or polyisothiocyanates cyclic aromatic
- C08G18/7657—Polyisocyanates or polyisothiocyanates cyclic aromatic containing two or more aromatic rings
- C08G18/7685—Polyisocyanates or polyisothiocyanates cyclic aromatic containing two or more aromatic rings containing two or more non-condensed aromatic rings directly linked to each other
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- H05K—PRINTED CIRCUITS; CASINGS OR CONSTRUCTIONAL DETAILS OF ELECTRIC APPARATUS; MANUFACTURE OF ASSEMBLAGES OF ELECTRICAL COMPONENTS
- H05K3/00—Apparatus or processes for manufacturing printed circuits
- H05K3/22—Secondary treatment of printed circuits
- H05K3/28—Applying non-metallic protective coatings
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Abstract
Description
<一般式(I)>
R1は下記一般式(II)〜(IV)より選ばれた1種、又は1種以上の混合である。
<一般式(II)>
<一般式(V)>
<構造式>
R3−1〜3−4はそれぞれ独立して同一または相違し、水素、C4−C12のアルキル、アルケニル、シクロアルキル、アリール、ポリエーテル基であり、R3−1〜3−4の少なくとも一つが不飽和二重結合含有基を含む。
<一般式(I)>
R1は下記一般式(II)〜(IV)より選ばれた1種、又は1種以上の混合であり、
<一般式(II)>
<一般式(V)>
<構造式>
R3−1〜3−4はそれぞれ独立して同一または相違し、水素、C4−C12のアルキル、アルケニル、シクロアルキル、アリール、ポリエーテル基であり、R3−1〜3−4の少なくとも一つが不飽和二重結合含有基を含むことを特徴とするヒドロキシウレタン化合物を提供する。
<一般式(I)>
R1は下記一般式(II)〜(IV)より選ばれた1種、又は1種以上の混合である。
<一般式(II)>
<一般式(V)>
<構造式>
R3−1〜3−4はそれぞれ独立して同一または相違し、水素、C4−C12のアルキル、アルケニル、シクロアルキル、アリール、ポリエーテル基であり、R3−1〜3−4の少なくとも一つが不飽和二重結合含有基を含む。
<一般式(I)>
R1は下記一般式(II)〜(IV)より選ばれた1種、又は1種以上の混合である。
<一般式(II)>
<一般式(V)>
<構造式>
R3−1〜3−4はそれぞれ独立して同一または相違し、水素、C4−C12のアルキル、アルケニル、シクロアルキル、アリール、ポリエーテル基であり、R3−1〜3−4の少なくとも一つが不飽和二重結合含有基を含む。
ビスフェノールAのポリグリシジルエーテル,BE180:長春人造樹脂廠が生産したビスフェノールAのポリグリシジルエーテルであり、エポキシ当量は170〜180g/eq。
ポリエーテルアミン,ジェファーミンD230:ハンツマン(Huntsman)社が生産したポリエーテルアミン。
メタクリル酸グリシジル(GMA):サートマー(Sartomer)社提供。
ヒドロキノンモノメチルエーテル(MEHQ):ボレガード(Borregaard)社提供。
メチルエチルケトン。
R1中のR4を(V)に代入し、(V)中のR5に
<一般式(1)>
<一般式(4)>
R3−1及びR3−4:
<一般式(5)>
<一般式(6)>
R4=C4をR1の式(II)〜(IV)に代入
<一般式(7)>
<一般式(4)>
R3−1及びR3−4:
<一般式(5)>
<一般式(6)>
BCIM:2,2’−ビス(2−クロロフェニル)−4,4’,5,5’−テトラフェニル−1,2’−ビイミダゾール
ITX:2−イソプロピルチオキサントン
AMG:ロイコマラカイトグリーン
PM:プロピレングリコールメチルエーテル
Claims (11)
- (a)光重合性不飽和化合物 、(b)ヒドロキシウレタン化合物及び(c)光重合開始剤を含むことを特徴とする感光性樹脂組成物。
- 前記(b)ヒドロキシウレタン化合物は不飽和二重結合を有するヒドロキシウレタン化合物であり、下記一般式(I)で表わされる構造を有し、
<一般式(I)>
R1は下記一般式(II)〜(IV)より選ばれた1種、又は1種以上の混合であり、
<一般式(II)>
<一般式(V)>
<構造式>
R3−1〜3−4はそれぞれ独立して同一または相違し、水素、C4−C12のアルキル、アルケニル、シクロアルキル、アリール、ポリエーテル基であり、R3−1〜3−4の少なくとも一つが不飽和二重結合含有基を含むことを特徴とする請求項1に記載の感光性樹脂組成物。 - 前記(b)ヒドロキシウレタン化合物は、[CC]/[NH2]が0.5〜0.9であることを特徴とする請求項1又は2に記載の感光性樹脂組成物。
- 前記(b)ヒドロキシウレタン化合物は、[CC]/[NH2]が0.5〜0.75であることを特徴とする請求項3に記載の感光性樹脂組成物。
- 前記(b)ヒドロキシウレタン化合物は、[EPOXY]/[AHEW]が0.125〜1であることを特徴とする請求項1又は2に記載の感光性樹脂組成物。
- 前記感光性樹脂組成物は、さらに溶剤を含むことを特徴とする請求項1又は2に記載の感光性樹脂組成物。
- 前記溶剤は、アルコール類、エーテル類及びケトン類からなる群から選択される1種又は2種以上であることを特徴とする請求項6に記載の感光性樹脂組成物。
- 前記(a)光重合性不飽和化合物 100質量部に対し、前記(b)ヒドロキシウレタン化合物が5〜50質量部であることを特徴とする請求項1又は2に記載の感光性樹脂組成物。
- 前記感光性樹脂組成物は、フォトレジストコーティングとして使用することを特徴とする請求項1又は2に記載の感光性樹脂組成物。
- キャリアフィルム、請求項1〜9のいずれかに記載の感光性樹脂組成物が形成するレジスト層及びカバーフィルムを含むことを特徴とするドライフィルムレジスト。
- ヒドロキシウレタン化合物であって、下記一般式(I)で表わされる構造を有し、
<一般式(I)>
R1は下記一般式(II)〜(IV)より選ばれた1種、又は1種以上の混合であり、
<一般式(II)>
<一般式(V)>
<構造式>
R3−1〜3−4はそれぞれ独立して同一または相違し、水素、C4−C12のアルキル、アルケニル、シクロアルキル、アリール、ポリエーテル基であり、R3−1〜3−4の少なくとも一つが不飽和二重結合含有基を含むことを特徴とするヒドロキシウレタン化合物。
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US20160238929A1 (en) * | 2013-10-01 | 2016-08-18 | Covestro Deutschland Ag | Uv-patternable hard-coating for transparent conductive film |
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JPS63113450A (ja) * | 1986-05-19 | 1988-05-18 | Fuji Photo Film Co Ltd | 感光性組成物 |
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