JP2017538741A - パラ−フェニレンジアミン酸化ベース酸化ベース及び追加の塩基を含む染料組成物 - Google Patents
パラ−フェニレンジアミン酸化ベース酸化ベース及び追加の塩基を含む染料組成物 Download PDFInfo
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- JP2017538741A JP2017538741A JP2017532856A JP2017532856A JP2017538741A JP 2017538741 A JP2017538741 A JP 2017538741A JP 2017532856 A JP2017532856 A JP 2017532856A JP 2017532856 A JP2017532856 A JP 2017532856A JP 2017538741 A JP2017538741 A JP 2017538741A
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- aminophenol
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- 239000000203 mixture Substances 0.000 title claims abstract description 154
- 230000003647 oxidation Effects 0.000 title claims abstract description 20
- 238000007254 oxidation reaction Methods 0.000 title claims abstract description 20
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- CBCKQZAAMUWICA-UHFFFAOYSA-N 1,4-phenylenediamine Chemical compound NC1=CC=C(N)C=C1 CBCKQZAAMUWICA-UHFFFAOYSA-N 0.000 title description 5
- 239000000126 substance Substances 0.000 claims abstract description 44
- 150000003839 salts Chemical class 0.000 claims abstract description 31
- 239000012453 solvate Substances 0.000 claims abstract description 25
- 239000007800 oxidant agent Substances 0.000 claims abstract description 24
- 239000002253 acid Substances 0.000 claims abstract description 22
- 239000002610 basifying agent Substances 0.000 claims abstract description 22
- 230000001590 oxidative effect Effects 0.000 claims abstract description 22
- PLIKAWJENQZMHA-UHFFFAOYSA-N 4-aminophenol Chemical compound NC1=CC=C(O)C=C1 PLIKAWJENQZMHA-UHFFFAOYSA-N 0.000 claims abstract description 18
- 239000000835 fiber Substances 0.000 claims abstract description 18
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- 102000011782 Keratins Human genes 0.000 claims abstract description 15
- 108010076876 Keratins Proteins 0.000 claims abstract description 15
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- 238000000034 method Methods 0.000 claims abstract description 10
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- 125000004432 carbon atom Chemical group C* 0.000 claims description 12
- 150000004665 fatty acids Chemical class 0.000 claims description 12
- 150000001413 amino acids Chemical class 0.000 claims description 11
- 229910021529 ammonia Inorganic materials 0.000 claims description 11
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- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 claims description 6
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- HWWIVWKTKZAORO-UHFFFAOYSA-N 3,4-dihydro-2h-1,4-benzoxazin-6-ol Chemical compound O1CCNC2=CC(O)=CC=C21 HWWIVWKTKZAORO-UHFFFAOYSA-N 0.000 claims description 3
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- YGRFRBUGAPOJDU-UHFFFAOYSA-N 5-(2-hydroxyethylamino)-2-methylphenol Chemical compound CC1=CC=C(NCCO)C=C1O YGRFRBUGAPOJDU-UHFFFAOYSA-N 0.000 claims description 3
- DBFYESDCPWWCHN-UHFFFAOYSA-N 5-amino-2-methylphenol Chemical compound CC1=CC=C(N)C=C1O DBFYESDCPWWCHN-UHFFFAOYSA-N 0.000 claims description 3
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- 125000004169 (C1-C6) alkyl group Chemical group 0.000 claims description 2
- 125000003161 (C1-C6) alkylene group Chemical group 0.000 claims description 2
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- 125000006577 C1-C6 hydroxyalkyl group Chemical group 0.000 claims description 2
- 229910000288 alkali metal carbonate Inorganic materials 0.000 claims description 2
- 150000008041 alkali metal carbonates Chemical class 0.000 claims description 2
- 125000005842 heteroatom Chemical group 0.000 claims description 2
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims description 2
- 229960003742 phenol Drugs 0.000 claims description 2
- 239000010773 plant oil Substances 0.000 claims description 2
- 150000002171 ethylene diamines Chemical class 0.000 claims 1
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- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 12
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- 235000000346 sugar Nutrition 0.000 description 9
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- 239000000975 dye Substances 0.000 description 7
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- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 6
- CZMRCDWAGMRECN-UGDNZRGBSA-N Sucrose Chemical compound O[C@H]1[C@H](O)[C@@H](CO)O[C@@]1(CO)O[C@@H]1[C@H](O)[C@@H](O)[C@H](O)[C@@H](CO)O1 CZMRCDWAGMRECN-UGDNZRGBSA-N 0.000 description 6
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- 239000005720 sucrose Substances 0.000 description 6
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- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 5
- 229920006395 saturated elastomer Polymers 0.000 description 5
- 239000002453 shampoo Substances 0.000 description 5
- 150000005691 triesters Chemical class 0.000 description 5
- 239000004215 Carbon black (E152) Substances 0.000 description 4
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 4
- 125000002091 cationic group Chemical group 0.000 description 4
- 235000013870 dimethyl polysiloxane Nutrition 0.000 description 4
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- 125000000524 functional group Chemical group 0.000 description 4
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- 241000894007 species Species 0.000 description 4
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- 125000000217 alkyl group Chemical group 0.000 description 3
- 125000003277 amino group Chemical group 0.000 description 3
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- 239000002537 cosmetic Substances 0.000 description 3
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- IPCSVZSSVZVIGE-UHFFFAOYSA-M hexadecanoate Chemical compound CCCCCCCCCCCCCCCC([O-])=O IPCSVZSSVZVIGE-UHFFFAOYSA-M 0.000 description 3
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- A61K2800/59—Mixtures
- A61K2800/592—Mixtures of compounds complementing their respective functions
- A61K2800/5922—At least two compounds being classified in the same subclass of A61K8/18
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/80—Process related aspects concerning the preparation of the cosmetic composition or the storage or application thereof
- A61K2800/88—Two- or multipart kits
- A61K2800/882—Mixing prior to application
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/31—Hydrocarbons
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/34—Alcohols
- A61K8/347—Phenols
Abstract
Description
a)少なくとも1種の酸化ベース3-(2,5-ジアミノフェニル)-1-プロパノール及び/又はその酸性塩及び/又はその溶媒和物、例えば水和物と、
b)パラ-アミノフェノール、3-メチル-4-アミノフェノール及びN,N-ビス(β-ヒドロキシエチル)-パラ-フェニレンジアミン、その付加塩、その溶媒和物、並びにそれらの混合物から選択される少なくとも1種の酸化ベースと、
c)少なくとも1種のカプラーと、
d)任意の、好ましくは組成物の総質量に対して少なくとも10%の量の、好ましくは液体の非シリコーン系である、少なくとも1種の脂肪物質と、
e)任意の、少なくとも1種の塩基性化剤と、
f)任意の、少なくとも1種の化学的酸化剤と
を含む、組成物である。
本発明の組成物は、a)次式
本発明の組成物は、b)以下:
- 次式のパラ-アミノフェノール:
本発明による組成物は、上記の酸化ベースa)及びb)以外に、1種又は複数の追加の酸化ベースを含み得る。
本発明の組成物は、少なくとも1種のカプラーを含む。これらのカプラーの中でも、特に、メタ-フェニレンジアミン類、メタ-アミノフェノール類、メタ-ジフェノール類、ナフタレン系カプラー及び複素環式カプラー、並びにその付加塩又は溶媒和物を挙げることができる。
本発明の組成物は、1種又は複数の直接染料も含み得る。直接染料は、より具体的には、イオン性又は非イオン性種、好ましくはカチオン性又は非イオン性種から選択される。これらの直接染料は、合成起源であっても天然起源であってもよい。直接染料は、存在する場合、より詳細には、組成物の総質量に対して0.0001質量%〜10質量%、好ましくは0.005質量%〜5質量%を占める。
本発明の組成物は、前述の通り、d)1種又は複数の脂肪物質を含み得る。
- Crodesta社によってF160、F140、F110、F90、F70及びSL40の名称で販売されている、それぞれモノエステル73%とジエステル及びトリエステル27%、モノエステル61%とジエステル、トリエステル及びテトラエステル39%、モノエステル52%とジエステル、トリエステル及びテトラエステル48%、モノエステル45%とジエステル、トリエステル及びテトラエステル55%、モノエステル39%とジエステル、トリエステル及びテトラエステル61%から形成されるパルミトステアリン酸スクロース、並びにモノラウリン酸スクロースを示す製品、
- モノエステル20%及びジ-トリエステル-ポリエステル80%から形成されるベヘン酸スクロースに相当する、例えばB370で参照される、Ryoto Sugar Estersの名称で販売されている製品、
- Goldschmidt社によりTegosoft(登録商標)PSEの名称で販売されているモノパルミトステアリン酸スクロース-ジパルミトステアリン酸スクロース
が挙げられる。
- Rhodia社により販売されているSilbione(登録商標)油の47及び70 047シリーズ又はMirasil(登録商標)油、例えば70 047 V 500 000油、
- Rhodia社により販売されているMirasil(登録商標)シリーズの油、
- Dow Corning社製の200シリーズの油、例えば粘度が60000mm2/sであるDC200、
- General Electric社製のViscasil(登録商標)油、及びGeneral Electric社製のSFシリーズのある種の油(SF 96、SF 18)。
- Rhodia社製のSilbione(登録商標)油の70 641シリーズ、
- Rhodia社製のRhodorsil(登録商標)70 633及び763シリーズの油、
- Dow Corning社製のDow Corning 556 Cosmetic Grade Fluid油、
- Bayer社製のPKシリーズのシリコーン、例えばPK20製品、
- Bayer社製のPN及びPHシリーズのシリコーン、例えば製品PN1000及びPH1000、
- General Electric社製のSFシリーズのある種の油、例えばSF 1023、SF 1154、SF 1250及びSF 1265。
- 置換又は非置換アミノ基、例えばGenesee社によりGP 4 Silicone Fluid及びGP 7100の名称で販売されている製品又はDow Corning社によりQ2 8220及びDow Corning 929若しくは939の名称で販売されている製品。置換アミノ基は特にC1〜C4アミノアルキル基である、
- アルコキシ基、例えばSWS Silicones社からSilicone Copolymer F-755の名称で販売されている製品、並びにGoldschmidt社からAbil Wax(登録商標)2428、2434及び2440の名称で販売されている製品。
本発明の組成物は、1種又は複数の塩基性化剤も含み得る。塩基性化剤は、無機若しくは有機又は混成物であり得る。
の化合物から選択される。
本発明の組成物は、1種又は複数の化学的酸化剤も含み得る。用語「化学的酸化剤」は、大気中の酸素以外の酸化剤を意味する。より具体的には、化学的酸化剤は、過酸化水素、過酸化尿素、アルカリ金属臭素酸塩、過酸化塩、例えば過硫酸塩又は過ホウ酸塩、過酸及びその前駆体、並びにアルカリ金属又はアルカリ土類金属の過炭酸塩から選択される。
本発明による組成物は、1種又は複数の有機溶媒も含み得る。
また、本発明による組成物は、従来から毛髪染料組成物中で使用されている種々の成分、例えば、アニオン性、カチオン性、非イオン性、両性若しくは双性イオン性ポリマー又はそれらの混合物;無機増粘剤、特に粘土又はタルク等のフィラー;有機増粘剤、特にアニオン性、カチオン性、非イオン性及び両性ポリマー性の会合性増粘剤;抗酸化剤;浸透剤;金属イオン封鎖剤;香料;分散剤;皮膜形成剤;セラミド;保存剤;透明化剤;アニオン性、カチオン性、両性及び/若しくは非イオン性界面活性剤も含有し得る。
本発明による組成物は、湿った又は乾燥したケラチン繊維に適用される。組成物は、一般に1分〜1時間、好ましくは5分〜30分間、繊維上に置かれる。好ましい実施形態によれば、適用した組成物は、少なくとも1種の塩基性化剤及び少なくとも1種の酸化剤を含有する。
- 組成物(A)又は(B)のうちの少なくとも1つは、組成物(A)+(B)の混合から得られる組成物の脂肪物質の含有率が、(A)+(B)の混合から誘導される組成物の質量に対して、少なくとも10質量%、好ましくは25質量%超、好ましくは30質量%超になるように、前述の脂肪物質を少なくとも1種含むことを理解されたい。
以下の組成物を調製し、その活性材料の量をグラム単位で表す。
Minolta CM2006D分光光度計(光源D65、角度10°、正反射光を含む)で、CIE L*a*b*系を使用して毛髪の色を決定した。
に従ってΔE変化を計算することによって求める。
Claims (15)
- a)少なくとも1種の第1の酸化ベース3-(2,5-ジアミノフェニル)-1-プロパノール及び/又はその酸性塩及び/又はその溶媒和物、例えば水和物と、
b)パラ-アミノフェノール、3-メチル-4-アミノフェノール及びN,N-ビス(β-ヒドロキシエチル)-パラ-フェニレンジアミン、その付加塩、その溶媒和物、並びにその混合物から選択される少なくとも1種の第2の酸化ベースと、
c)少なくとも1種のカプラーと、
d)任意の、少なくとも1種の脂肪物質と、
e)任意の、少なくとも1種の塩基性化剤と、
f)任意の、少なくとも1種の化学的酸化剤と
を含む、組成物。 - カプラーが、メタ-フェニレンジアミン類、メタ-アミノフェノール類、メタ-ジフェノール類、ナフタレン系カプラー及び複素環式カプラー、並びにその付加塩から選択される、請求項1に記載の組成物。
- カプラーが、レゾルシノール(1,3-ヒドロキシベンゼン)、4-クロロレゾルシノール、2-メチルレゾルシノール、メタ-アミノフェノール、2-メチル-5-アミノフェノール、2-メチル-5-ヒドロキシエチルアミノフェノール、5-アミノ-6-クロロ-2-メチルフェノール、2,4-ジアミノフェノキシエタノール、6-ヒドロキシベンゾモルホリン、6-ヒドロキシインドール、2-アミノ-3-ヒドロキシピリジン、その酸付加塩又はその溶媒和物、及びその混合物から選択される、請求項1又は2に記載の組成物。
- 酸化ベースa)及びb)が、それぞれ、組成物の総質量に対して0.0001質量%〜20質量%、好ましくは組成物の総質量に対して0.005質量%〜10質量%、特に0.01質量%〜10質量%の範囲の量である、請求項1から3のいずれか一項に記載の組成物。
- C6〜C16炭化水素、16個超の炭素原子を含有する炭化水素、動物起源の非シリコーン油、トリグリセリドタイプの植物油、合成トリグリセリド、フルオロ油、脂肪アルコール、トリグリセリド以外の脂肪酸及び/又は脂肪アルコールのエステル、並びに植物ワックス、非シリコーンワックス並びにシリコーンから選択される少なくとも1種の脂肪物質を含むことを特徴とする、請求項1から4のいずれか一項に記載の組成物。
- 前記脂肪物質が、室温及び大気圧で液体であり、好ましくは非シリコーン系であることを特徴とする、請求項1から5のいずれか一項に記載の組成物。
- 前記脂肪物質が、C6〜C16炭化水素、16個超の炭素原子を含有する炭化水素、トリグリセリド、脂肪アルコール、トリグリセリド以外の脂肪酸及び/若しくは脂肪アルコールのエステル、又はそれらの混合物から選択され、好ましくは流動ワセリンゼリー、ポリデセン、液体脂肪アルコール、脂肪酸及び/若しくは脂肪アルコールの液体エステル、又はそれらの混合物から選択されることを特徴とする、請求項1から6のいずれか一項に記載の組成物。
- 脂肪物質が、組成物の総質量に対して、10質量%以上、好ましくは20質量%以上、更により良好には、25質量%以上の量で存在することを特徴とする、請求項1から7のいずれか一項に記載の組成物。
- 脂肪物質の濃度が、組成物の総質量に対して15質量%〜80質量%、好ましくは25質量%〜75質量%、特に30質量%〜70質量%、有利には30質量%〜60質量%の範囲であることを特徴とする、請求項1から8のいずれか一項に記載の組成物。
- アンモニア、アルカリ金属炭酸塩若しくは重炭酸塩、水酸化ナトリウム若しくは水酸化カリウム、アルカノールアミン、オキシエチレン化及び/若しくはオキシプロピレン化エチレンジアミンから選択される有機アミン、アミノ酸、並びに式(II)
の化合物、又はそれらの混合物から選択される少なくとも1種の塩基性化剤を含む、請求項1から9のいずれか一項に記載の組成物。 - 前記塩基性化剤が、アンモニア又はアルカノールアミン、好ましくはモノエタノールアミン、及び中性又はイオン型アミノ酸から選択される、請求項1から10のいずれか一項に記載の組成物。
- 化学的酸化剤、好ましくは過酸化水素を含む、請求項1から11のいずれか一項に記載の組成物。
- ケラチン繊維、特に毛髪を染色する方法であって、請求項1から12のいずれか一項に規定記載の組成物をケラチン繊維に適用する工程を含む、方法。
- 請求項1から11のいずれか一項に規定の組成物が、少なくとも2つの組成物、酸化ベース3-(2,5-ジアミノフェニル)-1-プロパノール及び/又はその酸性塩若しくはその溶媒和物、並びにパラ-アミノフェノール、3-メチル-4-アミノフェノール、N,N-ビス(β-ヒドロキシエチル)-パラ-フェニレンジアミン、その付加塩、その溶媒和物、及びそれらの混合物から選択される酸化ベース並びに少なくとも1種のカプラーを含む第1の組成物(A)と、少なくとも1種の化学的酸化剤を含む第2の組成物(B)とを混合することによって得られる、請求項13に記載の方法。
- 酸化ベース3-(2,5-ジアミノフェニル)-1-プロパノール及び/又はその酸性塩若しくはその溶媒和物、並びにパラ-アミノフェノール、3-メチル-4-アミノフェノール、N,N-ビス(β-ヒドロキシエチル)-パラ-フェニレンジアミン、その付加塩、その溶媒和物、及びそれらの混合物から選択される1種又は複数の酸化ベース、並びに少なくとも1種のカプラーを含む組成物(A)を含有する第1の区画と、少なくとも1種の化学的酸化剤を含む組成物(B)を含有する第2の区画とを含む多区画装置。
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FR1462635 | 2014-12-17 | ||
PCT/EP2015/079434 WO2016096655A1 (en) | 2014-12-17 | 2015-12-11 | Dye composition comprising a para-phenylenediamine oxidation base and an additional base |
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FR3030244B1 (fr) | 2014-12-17 | 2018-07-06 | L'oreal | Composition de coloration comprenant une base d'oxydation para-phenylenediamine et un coupleur particulier |
FR3030237B1 (fr) | 2014-12-17 | 2017-07-14 | Oreal | Composition de coloration comprenant une base d'oxydation para-phenylenediamine, un tensio actif amphotere dans un milieu riche en corps gras |
FR3030255B1 (fr) | 2014-12-17 | 2016-12-23 | Oreal | Composition de coloration comprenant une base d'oxydation para-phenylenediamine, un epaississant polysaccharide dans un milieu riche en corps gras |
FR3030234B1 (fr) | 2014-12-17 | 2018-05-18 | Oreal | Composition de coloration comprenant une base d'oxydation para-phenylenediamine, un tensio actif non ionique dans un milieu riche en corps gras |
FR3030243B1 (fr) | 2014-12-17 | 2018-11-09 | L'oreal | Composition de coloration comprenant une base d'oxydation para-phenylenediamine et une base d'oxydation heterocyclique |
FR3030233B1 (fr) | 2014-12-17 | 2016-12-09 | Oreal | Composition de coloration comprenant une base d'oxydation para-phenylenediamine, et un polymere amphotere ou cationique dans un milieu riche en corps gras |
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2014
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- 2015-12-11 BR BR112017011247-7A patent/BR112017011247B1/pt active IP Right Grant
- 2015-12-11 CN CN201580069508.XA patent/CN106999387B/zh active Active
- 2015-12-11 US US15/536,991 patent/US10639254B2/en active Active
- 2015-12-11 EP EP15808224.8A patent/EP3233037B1/en active Active
- 2015-12-11 JP JP2017532856A patent/JP6804450B2/ja active Active
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Patent Citations (2)
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JP2001055316A (ja) * | 1999-07-12 | 2001-02-27 | L'oreal Sa | 1−アセトキシ−2−メチルナフタレンからなる第1カップラーと二種の異なる酸化ベースと第2カップラーを含有する染色組成物及び染色方法 |
JP2002060328A (ja) * | 2000-07-01 | 2002-02-26 | Wella Ag | ケラチン繊維を染色するための薬剤及び方法 |
Also Published As
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JP6804450B2 (ja) | 2020-12-23 |
FR3030239B1 (fr) | 2016-12-09 |
US20190091123A1 (en) | 2019-03-28 |
EP3233037A1 (en) | 2017-10-25 |
US10639254B2 (en) | 2020-05-05 |
WO2016096655A1 (en) | 2016-06-23 |
FR3030239A1 (fr) | 2016-06-24 |
BR112017011247B1 (pt) | 2021-03-30 |
BR112017011247A2 (pt) | 2018-04-03 |
CN106999387A (zh) | 2017-08-01 |
EP3233037B1 (en) | 2019-04-10 |
ES2731438T3 (es) | 2019-11-15 |
CN106999387B (zh) | 2021-09-07 |
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