JP2017529254A - 積層ポリマー構造及び方法 - Google Patents
積層ポリマー構造及び方法 Download PDFInfo
- Publication number
- JP2017529254A JP2017529254A JP2016574283A JP2016574283A JP2017529254A JP 2017529254 A JP2017529254 A JP 2017529254A JP 2016574283 A JP2016574283 A JP 2016574283A JP 2016574283 A JP2016574283 A JP 2016574283A JP 2017529254 A JP2017529254 A JP 2017529254A
- Authority
- JP
- Japan
- Prior art keywords
- layer
- resin
- sio
- linear
- composition
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 229920000642 polymer Polymers 0.000 title claims description 78
- 238000000034 method Methods 0.000 title claims description 18
- 230000003287 optical effect Effects 0.000 claims abstract description 137
- 239000000203 mixture Substances 0.000 claims description 234
- 125000005375 organosiloxane group Chemical group 0.000 claims description 94
- 229920005989 resin Polymers 0.000 claims description 89
- 239000011347 resin Substances 0.000 claims description 89
- 229920001400 block copolymer Polymers 0.000 claims description 73
- 229910004298 SiO 2 Inorganic materials 0.000 claims description 41
- 238000007789 sealing Methods 0.000 claims description 39
- 125000004469 siloxy group Chemical group [SiH3]O* 0.000 claims description 17
- 125000003118 aryl group Chemical group 0.000 claims description 16
- 230000007246 mechanism Effects 0.000 claims description 16
- 239000007787 solid Substances 0.000 claims description 14
- 238000004519 manufacturing process Methods 0.000 claims description 10
- 125000006659 (C1-C20) hydrocarbyl group Chemical group 0.000 claims description 9
- 125000005372 silanol group Chemical group 0.000 claims description 8
- 125000004169 (C1-C6) alkyl group Chemical group 0.000 claims description 7
- 125000001183 hydrocarbyl group Chemical group 0.000 claims description 7
- 238000000576 coating method Methods 0.000 claims description 5
- 238000000748 compression moulding Methods 0.000 claims description 5
- 238000010030 laminating Methods 0.000 claims description 5
- 239000011342 resin composition Substances 0.000 claims description 5
- 239000011248 coating agent Substances 0.000 claims description 4
- KBXJHRABGYYAFC-UHFFFAOYSA-N octaphenylsilsesquioxane Chemical compound O1[Si](O2)(C=3C=CC=CC=3)O[Si](O3)(C=4C=CC=CC=4)O[Si](O4)(C=5C=CC=CC=5)O[Si]1(C=1C=CC=CC=1)O[Si](O1)(C=5C=CC=CC=5)O[Si]2(C=2C=CC=CC=2)O[Si]3(C=2C=CC=CC=2)O[Si]41C1=CC=CC=C1 KBXJHRABGYYAFC-UHFFFAOYSA-N 0.000 claims description 4
- 239000003566 sealing material Substances 0.000 abstract description 22
- 239000000463 material Substances 0.000 abstract description 21
- 239000010410 layer Substances 0.000 description 284
- 229920001296 polysiloxane Polymers 0.000 description 75
- 238000001723 curing Methods 0.000 description 40
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 36
- 239000012943 hotmelt Substances 0.000 description 33
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 27
- 239000000758 substrate Substances 0.000 description 24
- 239000011701 zinc Substances 0.000 description 23
- 125000000217 alkyl group Chemical group 0.000 description 22
- -1 dimethylsiloxanes Chemical class 0.000 description 22
- 239000011572 manganese Substances 0.000 description 22
- 229920000435 poly(dimethylsiloxane) Polymers 0.000 description 20
- 239000003054 catalyst Substances 0.000 description 19
- 239000004205 dimethyl polysiloxane Substances 0.000 description 19
- 229910052950 sphalerite Inorganic materials 0.000 description 19
- 229910052984 zinc sulfide Inorganic materials 0.000 description 19
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 18
- 229910052725 zinc Inorganic materials 0.000 description 18
- 238000006459 hydrosilylation reaction Methods 0.000 description 17
- 239000010949 copper Substances 0.000 description 15
- 230000003993 interaction Effects 0.000 description 13
- 229910052748 manganese Inorganic materials 0.000 description 13
- 239000002904 solvent Substances 0.000 description 13
- 229910052684 Cerium Inorganic materials 0.000 description 12
- 229910052771 Terbium Inorganic materials 0.000 description 12
- 229910052802 copper Inorganic materials 0.000 description 12
- 239000008247 solid mixture Substances 0.000 description 12
- 239000000243 solution Substances 0.000 description 11
- 229910052782 aluminium Inorganic materials 0.000 description 10
- 235000013870 dimethyl polysiloxane Nutrition 0.000 description 10
- KPUWHANPEXNPJT-UHFFFAOYSA-N disiloxane Chemical class [SiH3]O[SiH3] KPUWHANPEXNPJT-UHFFFAOYSA-N 0.000 description 10
- 239000004698 Polyethylene Substances 0.000 description 9
- 125000003342 alkenyl group Chemical group 0.000 description 9
- 229910052793 cadmium Inorganic materials 0.000 description 9
- 125000004432 carbon atom Chemical group C* 0.000 description 9
- 229920001577 copolymer Polymers 0.000 description 9
- 238000004987 plasma desorption mass spectroscopy Methods 0.000 description 9
- 229920000573 polyethylene Polymers 0.000 description 9
- 229910052712 strontium Inorganic materials 0.000 description 9
- 238000009833 condensation Methods 0.000 description 8
- 230000005494 condensation Effects 0.000 description 8
- 239000011133 lead Substances 0.000 description 8
- 238000002156 mixing Methods 0.000 description 8
- 238000010992 reflux Methods 0.000 description 8
- 229910004283 SiO 4 Inorganic materials 0.000 description 7
- 238000006243 chemical reaction Methods 0.000 description 7
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 7
- 238000006116 polymerization reaction Methods 0.000 description 7
- 229910052709 silver Inorganic materials 0.000 description 7
- 239000011135 tin Substances 0.000 description 7
- GQHTUMJGOHRCHB-UHFFFAOYSA-N 2,3,4,6,7,8,9,10-octahydropyrimido[1,2-a]azepine Chemical compound C1CCCCN2CCCN=C21 GQHTUMJGOHRCHB-UHFFFAOYSA-N 0.000 description 6
- 229910052787 antimony Inorganic materials 0.000 description 6
- 229910052791 calcium Inorganic materials 0.000 description 6
- 229910052801 chlorine Inorganic materials 0.000 description 6
- 229910052749 magnesium Inorganic materials 0.000 description 6
- 229920002620 polyvinyl fluoride Polymers 0.000 description 6
- 150000003254 radicals Chemical class 0.000 description 6
- 229920002050 silicone resin Polymers 0.000 description 6
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 6
- 239000004812 Fluorinated ethylene propylene Substances 0.000 description 5
- 230000000712 assembly Effects 0.000 description 5
- 238000000429 assembly Methods 0.000 description 5
- 230000007613 environmental effect Effects 0.000 description 5
- 125000000962 organic group Chemical group 0.000 description 5
- 239000003960 organic solvent Substances 0.000 description 5
- 229920009441 perflouroethylene propylene Polymers 0.000 description 5
- 229920003255 poly(phenylsilsesquioxane) Polymers 0.000 description 5
- 239000011541 reaction mixture Substances 0.000 description 5
- 239000000565 sealant Substances 0.000 description 5
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 4
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 4
- 229910052788 barium Inorganic materials 0.000 description 4
- 230000008859 change Effects 0.000 description 4
- 125000000753 cycloalkyl group Chemical group 0.000 description 4
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 4
- 239000011229 interlayer Substances 0.000 description 4
- 239000007788 liquid Substances 0.000 description 4
- 238000002844 melting Methods 0.000 description 4
- 230000008018 melting Effects 0.000 description 4
- 239000008188 pellet Substances 0.000 description 4
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 4
- 229920000515 polycarbonate Polymers 0.000 description 4
- 239000004417 polycarbonate Substances 0.000 description 4
- 230000008569 process Effects 0.000 description 4
- 238000012545 processing Methods 0.000 description 4
- 239000000047 product Substances 0.000 description 4
- SCPYDCQAZCOKTP-UHFFFAOYSA-N silanol Chemical compound [SiH3]O SCPYDCQAZCOKTP-UHFFFAOYSA-N 0.000 description 4
- 229910052710 silicon Inorganic materials 0.000 description 4
- 239000010703 silicon Substances 0.000 description 4
- 238000012360 testing method Methods 0.000 description 4
- 239000010936 titanium Substances 0.000 description 4
- 239000013598 vector Substances 0.000 description 4
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 3
- 229910052693 Europium Inorganic materials 0.000 description 3
- 229910052688 Gadolinium Inorganic materials 0.000 description 3
- 239000004642 Polyimide Substances 0.000 description 3
- 229910052777 Praseodymium Inorganic materials 0.000 description 3
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 3
- 230000008901 benefit Effects 0.000 description 3
- 230000005540 biological transmission Effects 0.000 description 3
- 239000002041 carbon nanotube Substances 0.000 description 3
- 229910021393 carbon nanotube Inorganic materials 0.000 description 3
- 239000003795 chemical substances by application Substances 0.000 description 3
- 230000006835 compression Effects 0.000 description 3
- 238000007906 compression Methods 0.000 description 3
- 238000013005 condensation curing Methods 0.000 description 3
- 230000001419 dependent effect Effects 0.000 description 3
- 230000006870 function Effects 0.000 description 3
- 229910052733 gallium Inorganic materials 0.000 description 3
- 238000010438 heat treatment Methods 0.000 description 3
- 150000002430 hydrocarbons Chemical group 0.000 description 3
- 238000002347 injection Methods 0.000 description 3
- 239000007924 injection Substances 0.000 description 3
- XEEYBQQBJWHFJM-UHFFFAOYSA-N iron Substances [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 3
- 229920002521 macromolecule Polymers 0.000 description 3
- 229910052751 metal Inorganic materials 0.000 description 3
- 239000002184 metal Substances 0.000 description 3
- 229910052757 nitrogen Inorganic materials 0.000 description 3
- 150000002978 peroxides Chemical class 0.000 description 3
- 238000000016 photochemical curing Methods 0.000 description 3
- 229920000139 polyethylene terephthalate Polymers 0.000 description 3
- 239000005020 polyethylene terephthalate Substances 0.000 description 3
- 229920001721 polyimide Polymers 0.000 description 3
- 238000005507 spraying Methods 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- 229910052718 tin Inorganic materials 0.000 description 3
- 229910052719 titanium Inorganic materials 0.000 description 3
- OXBLVCZKDOZZOJ-UHFFFAOYSA-N 2,3-Dihydrothiophene Chemical compound C1CC=CS1 OXBLVCZKDOZZOJ-UHFFFAOYSA-N 0.000 description 2
- 229910018072 Al 2 O 3 Inorganic materials 0.000 description 2
- 238000006596 Alder-ene reaction Methods 0.000 description 2
- 125000000041 C6-C10 aryl group Chemical group 0.000 description 2
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 2
- 229910020068 MgAl Inorganic materials 0.000 description 2
- KJTLSVCANCCWHF-UHFFFAOYSA-N Ruthenium Chemical compound [Ru] KJTLSVCANCCWHF-UHFFFAOYSA-N 0.000 description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
- 229920002125 Sokalan® Polymers 0.000 description 2
- 229910003668 SrAl Inorganic materials 0.000 description 2
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 2
- 239000004809 Teflon Substances 0.000 description 2
- 229920006362 Teflon® Polymers 0.000 description 2
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 2
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 2
- 229920004482 WACKER® Polymers 0.000 description 2
- 239000000853 adhesive Substances 0.000 description 2
- 230000001070 adhesive effect Effects 0.000 description 2
- 125000001931 aliphatic group Chemical group 0.000 description 2
- 150000001345 alkine derivatives Chemical class 0.000 description 2
- 125000003545 alkoxy group Chemical group 0.000 description 2
- 125000002877 alkyl aryl group Chemical group 0.000 description 2
- MWPLVEDNUUSJAV-UHFFFAOYSA-N anthracene Chemical compound C1=CC=CC2=CC3=CC=CC=C3C=C21 MWPLVEDNUUSJAV-UHFFFAOYSA-N 0.000 description 2
- 125000005428 anthryl group Chemical group [H]C1=C([H])C([H])=C2C([H])=C3C(*)=C([H])C([H])=C([H])C3=C([H])C2=C1[H] 0.000 description 2
- 239000003849 aromatic solvent Substances 0.000 description 2
- 238000010533 azeotropic distillation Methods 0.000 description 2
- 150000001540 azides Chemical class 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 2
- 238000004891 communication Methods 0.000 description 2
- 230000008878 coupling Effects 0.000 description 2
- 238000010168 coupling process Methods 0.000 description 2
- 238000005859 coupling reaction Methods 0.000 description 2
- 238000004132 cross linking Methods 0.000 description 2
- 239000003431 cross linking reagent Substances 0.000 description 2
- 239000006185 dispersion Substances 0.000 description 2
- 239000000428 dust Substances 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 229920001971 elastomer Polymers 0.000 description 2
- 238000001941 electron spectroscopy Methods 0.000 description 2
- 239000008393 encapsulating agent Substances 0.000 description 2
- 150000002118 epoxides Chemical class 0.000 description 2
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 2
- 229920000840 ethylene tetrafluoroethylene copolymer Polymers 0.000 description 2
- 239000005038 ethylene vinyl acetate Substances 0.000 description 2
- 238000001704 evaporation Methods 0.000 description 2
- 239000012530 fluid Substances 0.000 description 2
- 229910052731 fluorine Inorganic materials 0.000 description 2
- 125000000524 functional group Chemical group 0.000 description 2
- 239000007789 gas Substances 0.000 description 2
- 239000011521 glass Substances 0.000 description 2
- 125000004051 hexyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 2
- 229920001519 homopolymer Polymers 0.000 description 2
- 150000002500 ions Chemical group 0.000 description 2
- 229910052746 lanthanum Inorganic materials 0.000 description 2
- 125000001624 naphthyl group Chemical group 0.000 description 2
- 229910052754 neon Inorganic materials 0.000 description 2
- GKAOGPIIYCISHV-UHFFFAOYSA-N neon atom Chemical compound [Ne] GKAOGPIIYCISHV-UHFFFAOYSA-N 0.000 description 2
- 239000012299 nitrogen atmosphere Substances 0.000 description 2
- 239000003921 oil Substances 0.000 description 2
- 239000013307 optical fiber Substances 0.000 description 2
- 229920000620 organic polymer Polymers 0.000 description 2
- 125000001147 pentyl group Chemical group C(CCCC)* 0.000 description 2
- 229920003023 plastic Polymers 0.000 description 2
- 239000004033 plastic Substances 0.000 description 2
- 229910052697 platinum Inorganic materials 0.000 description 2
- 229920000728 polyester Polymers 0.000 description 2
- 239000000843 powder Substances 0.000 description 2
- 238000010248 power generation Methods 0.000 description 2
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 description 2
- 229910052707 ruthenium Inorganic materials 0.000 description 2
- 239000004590 silicone sealant Substances 0.000 description 2
- 238000003756 stirring Methods 0.000 description 2
- 229910052727 yttrium Inorganic materials 0.000 description 2
- 125000006273 (C1-C3) alkyl group Chemical group 0.000 description 1
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 1
- 229910016066 BaSi Inorganic materials 0.000 description 1
- 229910004261 CaF 2 Inorganic materials 0.000 description 1
- 229910004762 CaSiO Inorganic materials 0.000 description 1
- 239000004215 Carbon black (E152) Substances 0.000 description 1
- 229910005793 GeO 2 Inorganic materials 0.000 description 1
- 239000004831 Hot glue Substances 0.000 description 1
- 241000282346 Meles meles Species 0.000 description 1
- 229910017857 MgGa Inorganic materials 0.000 description 1
- 229910017639 MgSi Inorganic materials 0.000 description 1
- 238000006845 Michael addition reaction Methods 0.000 description 1
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 1
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 description 1
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 1
- 229920002396 Polyurea Polymers 0.000 description 1
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 description 1
- 229910002808 Si–O–Si Inorganic materials 0.000 description 1
- 229910010413 TiO 2 Inorganic materials 0.000 description 1
- 230000006750 UV protection Effects 0.000 description 1
- KXJLGCBCRCSXQF-UHFFFAOYSA-N [diacetyloxy(ethyl)silyl] acetate Chemical compound CC(=O)O[Si](CC)(OC(C)=O)OC(C)=O KXJLGCBCRCSXQF-UHFFFAOYSA-N 0.000 description 1
- TVJPBVNWVPUZBM-UHFFFAOYSA-N [diacetyloxy(methyl)silyl] acetate Chemical compound CC(=O)O[Si](C)(OC(C)=O)OC(C)=O TVJPBVNWVPUZBM-UHFFFAOYSA-N 0.000 description 1
- 125000003668 acetyloxy group Chemical group [H]C([H])([H])C(=O)O[*] 0.000 description 1
- 230000002378 acidificating effect Effects 0.000 description 1
- 230000009471 action Effects 0.000 description 1
- 239000012190 activator Substances 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 239000012790 adhesive layer Substances 0.000 description 1
- 125000002947 alkylene group Chemical group 0.000 description 1
- 230000004075 alteration Effects 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 150000001408 amides Chemical class 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- 230000003667 anti-reflective effect Effects 0.000 description 1
- 229910052785 arsenic Inorganic materials 0.000 description 1
- 125000004429 atom Chemical group 0.000 description 1
- 150000001541 aziridines Chemical class 0.000 description 1
- 230000004888 barrier function Effects 0.000 description 1
- 230000001588 bifunctional effect Effects 0.000 description 1
- 238000007664 blowing Methods 0.000 description 1
- 230000001680 brushing effect Effects 0.000 description 1
- MTAZNLWOLGHBHU-UHFFFAOYSA-N butadiene-styrene rubber Chemical compound C=CC=C.C=CC1=CC=CC=C1 MTAZNLWOLGHBHU-UHFFFAOYSA-N 0.000 description 1
- 239000006227 byproduct Substances 0.000 description 1
- BDOSMKKIYDKNTQ-UHFFFAOYSA-N cadmium atom Chemical compound [Cd] BDOSMKKIYDKNTQ-UHFFFAOYSA-N 0.000 description 1
- CREMABGTGYGIQB-UHFFFAOYSA-N carbon carbon Chemical compound C.C CREMABGTGYGIQB-UHFFFAOYSA-N 0.000 description 1
- 239000011203 carbon fibre reinforced carbon Substances 0.000 description 1
- 239000007809 chemical reaction catalyst Substances 0.000 description 1
- 238000004587 chromatography analysis Methods 0.000 description 1
- 230000001427 coherent effect Effects 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 238000006482 condensation reaction Methods 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 238000006352 cycloaddition reaction Methods 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 238000009792 diffusion process Methods 0.000 description 1
- 229920005645 diorganopolysiloxane polymer Polymers 0.000 description 1
- 238000007598 dipping method Methods 0.000 description 1
- 238000004821 distillation Methods 0.000 description 1
- 239000000806 elastomer Substances 0.000 description 1
- QHSJIZLJUFMIFP-UHFFFAOYSA-N ethene;1,1,2,2-tetrafluoroethene Chemical group C=C.FC(F)=C(F)F QHSJIZLJUFMIFP-UHFFFAOYSA-N 0.000 description 1
- HQQADJVZYDDRJT-UHFFFAOYSA-N ethene;prop-1-ene Chemical group C=C.CC=C HQQADJVZYDDRJT-UHFFFAOYSA-N 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 230000009969 flowable effect Effects 0.000 description 1
- 229920002313 fluoropolymer Polymers 0.000 description 1
- 239000004811 fluoropolymer Substances 0.000 description 1
- 239000011888 foil Substances 0.000 description 1
- 230000014509 gene expression Effects 0.000 description 1
- 229910052732 germanium Inorganic materials 0.000 description 1
- 230000009477 glass transition Effects 0.000 description 1
- 229910052737 gold Inorganic materials 0.000 description 1
- 150000004820 halides Chemical class 0.000 description 1
- 230000017525 heat dissipation Effects 0.000 description 1
- 125000000623 heterocyclic group Chemical group 0.000 description 1
- 238000007731 hot pressing Methods 0.000 description 1
- 150000007857 hydrazones Chemical class 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- NYMPGSQKHIOWIO-UHFFFAOYSA-N hydroxy(diphenyl)silicon Chemical class C=1C=CC=CC=1[Si](O)C1=CC=CC=C1 NYMPGSQKHIOWIO-UHFFFAOYSA-N 0.000 description 1
- 238000005342 ion exchange Methods 0.000 description 1
- 229920000554 ionomer Polymers 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 238000003475 lamination Methods 0.000 description 1
- 229910052745 lead Inorganic materials 0.000 description 1
- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 description 1
- 239000000155 melt Substances 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 150000004767 nitrides Chemical class 0.000 description 1
- 230000000269 nucleophilic effect Effects 0.000 description 1
- 230000005693 optoelectronics Effects 0.000 description 1
- 230000001590 oxidative effect Effects 0.000 description 1
- 150000002923 oximes Chemical class 0.000 description 1
- UJMWVICAENGCRF-UHFFFAOYSA-N oxygen difluoride Chemical group FOF UJMWVICAENGCRF-UHFFFAOYSA-N 0.000 description 1
- 238000010422 painting Methods 0.000 description 1
- 239000006072 paste Substances 0.000 description 1
- 230000035515 penetration Effects 0.000 description 1
- 238000005502 peroxidation Methods 0.000 description 1
- 238000005191 phase separation Methods 0.000 description 1
- 229910052698 phosphorus Inorganic materials 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 229920001200 poly(ethylene-vinyl acetate) Polymers 0.000 description 1
- 229920000058 polyacrylate Polymers 0.000 description 1
- 229920002959 polymer blend Polymers 0.000 description 1
- 229920001451 polypropylene glycol Polymers 0.000 description 1
- 230000004224 protection Effects 0.000 description 1
- 239000002096 quantum dot Substances 0.000 description 1
- 238000007348 radical reaction Methods 0.000 description 1
- 229910001404 rare earth metal oxide Inorganic materials 0.000 description 1
- 238000007142 ring opening reaction Methods 0.000 description 1
- 150000003346 selenoethers Chemical class 0.000 description 1
- 239000004065 semiconductor Substances 0.000 description 1
- 229910000077 silane Inorganic materials 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 239000004332 silver Substances 0.000 description 1
- 230000000707 stereoselective effect Effects 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 150000004763 sulfides Chemical class 0.000 description 1
- 239000013589 supplement Substances 0.000 description 1
- 238000001029 thermal curing Methods 0.000 description 1
- 229920002725 thermoplastic elastomer Polymers 0.000 description 1
- 238000012546 transfer Methods 0.000 description 1
- 230000007704 transition Effects 0.000 description 1
- 238000002834 transmittance Methods 0.000 description 1
- ZQTYRTSKQFQYPQ-UHFFFAOYSA-N trisiloxane Chemical compound [SiH3]O[SiH2]O[SiH3] ZQTYRTSKQFQYPQ-UHFFFAOYSA-N 0.000 description 1
- 229910052720 vanadium Inorganic materials 0.000 description 1
- 239000008096 xylene Substances 0.000 description 1
- 238000004383 yellowing Methods 0.000 description 1
Images
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L33/00—Semiconductor devices having potential barriers specially adapted for light emission; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof
- H01L33/48—Semiconductor devices having potential barriers specially adapted for light emission; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof characterised by the semiconductor body packages
- H01L33/52—Encapsulations
- H01L33/56—Materials, e.g. epoxy or silicone resin
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/06—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material
- B32B27/08—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/18—Layered products comprising a layer of synthetic resin characterised by the use of special additives
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/28—Layered products comprising a layer of synthetic resin comprising synthetic resins not wholly covered by any one of the sub-groups B32B27/30 - B32B27/42
- B32B27/283—Layered products comprising a layer of synthetic resin comprising synthetic resins not wholly covered by any one of the sub-groups B32B27/30 - B32B27/42 comprising polysiloxanes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G77/00—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
- C08G77/42—Block-or graft-polymers containing polysiloxane sequences
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J3/00—Processes of treating or compounding macromolecular substances
- C08J3/24—Crosslinking, e.g. vulcanising, of macromolecules
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J3/00—Processes of treating or compounding macromolecular substances
- C08J3/24—Crosslinking, e.g. vulcanising, of macromolecules
- C08J3/243—Two or more independent types of crosslinking for one or more polymers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
- C08J5/18—Manufacture of films or sheets
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J7/00—Chemical treatment or coating of shaped articles made of macromolecular substances
- C08J7/04—Coating
- C08J7/042—Coating with two or more layers, where at least one layer of a composition contains a polymer binder
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J7/00—Chemical treatment or coating of shaped articles made of macromolecular substances
- C08J7/04—Coating
- C08J7/0427—Coating with only one layer of a composition containing a polymer binder
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J7/00—Chemical treatment or coating of shaped articles made of macromolecular substances
- C08J7/04—Coating
- C08J7/043—Improving the adhesiveness of the coatings per se, e.g. forming primers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J7/00—Chemical treatment or coating of shaped articles made of macromolecular substances
- C08J7/04—Coating
- C08J7/046—Forming abrasion-resistant coatings; Forming surface-hardening coatings
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2307/00—Properties of the layers or laminate
- B32B2307/40—Properties of the layers or laminate having particular optical properties
- B32B2307/402—Coloured
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2307/00—Properties of the layers or laminate
- B32B2307/40—Properties of the layers or laminate having particular optical properties
- B32B2307/412—Transparent
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2307/00—Properties of the layers or laminate
- B32B2307/40—Properties of the layers or laminate having particular optical properties
- B32B2307/418—Refractive
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2307/00—Properties of the layers or laminate
- B32B2307/40—Properties of the layers or laminate having particular optical properties
- B32B2307/422—Luminescent, fluorescent, phosphorescent
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2307/00—Properties of the layers or laminate
- B32B2307/70—Other properties
- B32B2307/748—Releasability
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2551/00—Optical elements
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2551/00—Optical elements
- B32B2551/08—Mirrors
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2581/00—Seals; Sealing equipment; Gaskets
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2327/00—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers
- C08J2327/02—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers not modified by chemical after-treatment
- C08J2327/12—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers not modified by chemical after-treatment containing fluorine atoms
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L2224/00—Indexing scheme for arrangements for connecting or disconnecting semiconductor or solid-state bodies and methods related thereto as covered by H01L24/00
- H01L2224/01—Means for bonding being attached to, or being formed on, the surface to be connected, e.g. chip-to-package, die-attach, "first-level" interconnects; Manufacturing methods related thereto
- H01L2224/42—Wire connectors; Manufacturing methods related thereto
- H01L2224/47—Structure, shape, material or disposition of the wire connectors after the connecting process
- H01L2224/48—Structure, shape, material or disposition of the wire connectors after the connecting process of an individual wire connector
- H01L2224/4805—Shape
- H01L2224/4809—Loop shape
- H01L2224/48091—Arched
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L2224/00—Indexing scheme for arrangements for connecting or disconnecting semiconductor or solid-state bodies and methods related thereto as covered by H01L24/00
- H01L2224/01—Means for bonding being attached to, or being formed on, the surface to be connected, e.g. chip-to-package, die-attach, "first-level" interconnects; Manufacturing methods related thereto
- H01L2224/42—Wire connectors; Manufacturing methods related thereto
- H01L2224/47—Structure, shape, material or disposition of the wire connectors after the connecting process
- H01L2224/48—Structure, shape, material or disposition of the wire connectors after the connecting process of an individual wire connector
- H01L2224/481—Disposition
- H01L2224/48151—Connecting between a semiconductor or solid-state body and an item not being a semiconductor or solid-state body, e.g. chip-to-substrate, chip-to-passive
- H01L2224/48221—Connecting between a semiconductor or solid-state body and an item not being a semiconductor or solid-state body, e.g. chip-to-substrate, chip-to-passive the body and the item being stacked
- H01L2224/48225—Connecting between a semiconductor or solid-state body and an item not being a semiconductor or solid-state body, e.g. chip-to-substrate, chip-to-passive the body and the item being stacked the item being non-metallic, e.g. insulating substrate with or without metallisation
- H01L2224/48227—Connecting between a semiconductor or solid-state body and an item not being a semiconductor or solid-state body, e.g. chip-to-substrate, chip-to-passive the body and the item being stacked the item being non-metallic, e.g. insulating substrate with or without metallisation connecting the wire to a bond pad of the item
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L2224/00—Indexing scheme for arrangements for connecting or disconnecting semiconductor or solid-state bodies and methods related thereto as covered by H01L24/00
- H01L2224/73—Means for bonding being of different types provided for in two or more of groups H01L2224/10, H01L2224/18, H01L2224/26, H01L2224/34, H01L2224/42, H01L2224/50, H01L2224/63, H01L2224/71
- H01L2224/732—Location after the connecting process
- H01L2224/73251—Location after the connecting process on different surfaces
- H01L2224/73265—Layer and wire connectors
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L2924/00—Indexing scheme for arrangements or methods for connecting or disconnecting semiconductor or solid-state bodies as covered by H01L24/00
- H01L2924/15—Details of package parts other than the semiconductor or other solid state devices to be connected
- H01L2924/181—Encapsulation
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Manufacturing & Machinery (AREA)
- Microelectronics & Electronic Packaging (AREA)
- Computer Hardware Design (AREA)
- Power Engineering (AREA)
- Materials Engineering (AREA)
- Laminated Bodies (AREA)
- Silicon Polymers (AREA)
- Structures Or Materials For Encapsulating Or Coating Semiconductor Devices Or Solid State Devices (AREA)
- Led Device Packages (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
Description
ΔGm=ΔHm−TΔSm<0
TΔSm=−k[n1lnΦ1+n2lnΦ2]
ΔHm=kTX12NΦ1Φ2
X12=[Vref(δ1−δ2)2]/RT
(R3 3SiO1/2)a(R3 2SiO2/2)b(R3SiO3/2)c(SiO4/2)d(R4O1/2)e
R5 3SiO(R5 2SiO)mSiR5 3
500mLの4つ口丸底フラスコに、Dow Corning 217フレーク(45.0g、0.329モルSi)及びトルエン(Fisher Scientific製、70.38g)を入れた。フラスコに、温度計、Teflon撹拌棒、及び水冷凝縮器に取り付けたディーンスターク装置を備えた。窒素ブランケットを適用し、ディーンスターク装置にはトルエンを予め満たし、加熱には油浴を用いた。反応混合物を加熱して30分間還流させた。反応混合物を108℃まで冷却後、ジアセトキシ末端PhMeシロキサン溶液を素早く添加した。ジアセトキシ末端PhMeシロキサンは、50/50重量% MTA/ETA(1.21g、0.00523モルSi)混合物を、トルエン(29.62g)に溶解した140dpシラノール末端PhMeシロキサン(55.0g、0.404モルSi)の溶液に添加することにより調製した。溶液を、窒素雰囲気下、室温で2時間混合した。ジアセトキシ末端PhMeシロキサンを添加した後、反応混合物を加熱して2時間還流させた。この段階で、50/50重量% MTA/ETA(7.99g、0.0346モルSi)を108℃で添加した。反応混合物を加熱して更に1時間還流させた。これを90℃まで冷却し、次にイオン交換水(12mL)を添加した。温度を上げて還流させ、次に水を共沸蒸留により除去した。反応混合物を再び90℃まで冷却し、更にイオン交換水(12mL)を添加した。これを加熱し還流させ、再び水を除去した。次に、トルエンの一部(56.9g)を蒸留により除去し、固体含有率を高めた。材料を室温まで冷却し、その後、5.0μmのフィルタで加圧濾過した。キャストシート(溶液を型枠に注ぎ、溶媒を蒸発させることにより作製)は光学的に透明であった。
3Lの4つ口丸底フラスコに、Dow Corning 217フレーク(378.0g、2.77モルSi)及びトルエン(Fisher Scientific製、1011.3g)を入れた。フラスコに、温度計、Teflon撹拌棒、及び水冷凝縮器に取り付けたディーンスターク装置を備えた。窒素ブランケットを適用し、ディーンスターク装置にはトルエンを予め満たし、加熱には油浴を用いた。混合物を加熱して30分間還流させた。ボトルに、シラノール末端PDMS(462.0gのシロキサン、6.21モルSi)及びトルエン(248.75g)を入れた。これを、50/50メチルトリアセトキシシラン/エチルトリアセトキシシシラン(MTA/ETA)(31.12g、0.137モルSi)を用い、グローブボックス内で(同日中に)窒素雰囲気下、この50/50MTA/ETAをPDMSに添加し、室温で1時間混合することにより保護した。保護したPDMSを、217フレーク溶液に素早く添加し、加熱して2時間還流させた。溶液を108℃まで冷却し、28.4gのMTA/ETA 5/5比のものを添加後、1時間還流させた。溶液を90℃まで冷却し、89.3gのイオン交換水を添加した。温度を上げて還流させ、水を共沸蒸留により除去した。トルエン(884.6g)を留去し、固体含有率を約70%まで高めた。キャストシート(溶液を型枠に注ぎ、溶媒を蒸発させることにより作製)は光学的に透明であった。
実施例1の組成物、次いで20ppmの1,8−ジアザビシクロ[5.4.0]ウンデカ−7−エン(DBU)触媒を、FlackTek Inc.製DAC150 FV2軸高速ミキサを用い、高速ミキサのカップに供給し、2回、3000rpmで30秒間混合した。次に30重量%の燐光体(NYAG 4454−S燐光体、〜100μm)を添加し、再び2回、3000rpmで30秒間混合した後、以下の記載のとおりコーティングし、シリコーンホットメルトフィルムを作製した。実施例2の組成物、次いで10ppmのDBU触媒を、高速ミキサのカップ内に供給し、2回、3000rpmで30秒間混合した後、以下の記載のとおりコーティングし、別のシリコーンホットメルトフィルムを作製した。
組成式[R1 2SiO2/2]の単位及び組成式[R2SiO3/2]の単位を有する樹脂ブロック並びに直鎖状ブロックを有する第1の樹脂−直鎖状オルガノシロキサンブロックコポリマーを含み、第1の主要面及び第2の主要面を有する、第1層と、
組成式[R1 2SiO2/2]の単位及び組成式[R2SiO3/2]の単位を有する樹脂ブロック並びに直鎖状ブロックを有する第2の樹脂−直鎖状オルガノシロキサンブロックコポリマーを含み、第1の主要面及び第2の主要面を有する、第2層と、組成式[R1 2SiO2/2]の単位及び組成式[R2SiO3/2]の単位を有するオルガノシロキサン樹脂を含み、第1層の第2の主要面及び第2層の第1の主要面と直接的に接触している、第3層と、
を有する、封止フィルムに関する。
(式中、R1は独立して、C1〜C30のヒドロカルビルであり、
R2は独立して、C1〜C20のヒドロカルビルである。)
第1層の第1の樹脂−直鎖状オルガノシロキサンブロックコポリマー及び第2層の第2の樹脂−直鎖状オルガノシロキサンブロックコポリマーのうちの少なくとも1つの樹脂ブロックの、組成式[R1 2SiO2/2]の単位のR1基及び組成式[R2SiO3/2]の単位のR2基のうちの少なくとも1つの約20〜約100モル%が、C6−C16のアリール基であり、第3層のオルガノシロキサン樹脂の、組成式[R1 2SiO2/2]の単位のR1基及び組成式[R2SiO3/2]の単位のR2基のうちの少なくとも1つの約20〜約100モル%が、C6−C16のアリール基である、実施形態1に記載の封止フィルムに関する。
第1層の第1の樹脂−直鎖状オルガノシロキサンブロックコポリマー及び第2層の第2の樹脂−直鎖状オルガノシロキサンブロックコポリマーのうちの少なくとも1つの樹脂ブロックの、組成式[R1 2SiO2/2]の単位のR1基及び組成式[R2SiO3/2]の単位のR2基のうちの少なくとも1つの約20〜約100モル%が、C1−C6のアルキル基であり、第3層のオルガノシロキサン樹脂の、組成式[R1 2SiO2/2]の単位のR1基及び組成式[R2SiO3/2]の単位のR2基のうちの少なくとも1つの約20〜約100モル%が、C1−C6のアルキル基である、実施形態1に記載の封止フィルムに関する。
40〜90モル%の組成式[R1 2SiO2/2]の単位、
10〜60モル%の組成式[R2SiO3/2]の単位、
0.5〜25モル%のシラノール基
(式中、R1は独立して、C1〜C30のヒドロカルビルであり、
R2は独立して、C1〜C20のヒドロカルビルであり、
[R1 2SiO2/2]の単位は、直鎖状ブロック当たり平均10〜400の[R1 2SiO2/2]の単位が、直鎖状ブロックに配置され、[R2SiO3/2]の単位は、少なくとも500g/モルの分子量を有する非直鎖状ブロックに配置される)を有する樹脂−直鎖状オルガノシロキサンブロックコポリマーを含み、非直鎖状ブロックの少なくとも30%が、互いに架橋し、大部分がナノドメイン内で一緒になって凝集し、各直鎖状ブロックが少なくとも1つの非直鎖状ブロックに連結し、樹脂−直鎖状オルガノシロキサンブロックコポリマーが少なくとも20,000g/モルの重量平均分子量を有し、25℃で固体である、実施形態1〜3のいずれか一つに記載の封止フィルムに関する。
第1層を形成することと、
第2層を形成することと、
オルガノシロキサン樹脂組成物を、第1層の第2の主要面及び第2層の第1の主要面のうちの少なくとも1つに適用することと、
第1層の第2の主要面と第2層の第1の主要面との間に第3層を形成し、積層ポリマー構造を形成するため、第1層の第2の主要面、適用したオルガノシロキサン樹脂組成物、及び第2層の第1の主要面を一緒にして接触させることと、積層ポリマー構造をラミネートすること又は圧縮成型することと、を含む、実施形態16に記載の光学アセンブリの作製方法に関する。
Claims (16)
- 組成式[R1 2SiO2/2]の単位及び組成式[R2SiO3/2]の単位を有する樹脂ブロック並びに直鎖状ブロックを有する第1の樹脂−直鎖状オルガノシロキサンブロックコポリマーを含み、第1の主要面及び第2の主要面を有する、第1層と、
組成式[R1 2SiO2/2]の単位及び組成式[R2SiO3/2]の単位を有する樹脂ブロック並びに直鎖状ブロックを有する第2の樹脂−直鎖状オルガノシロキサンブロックコポリマーを含み、第1の主要面及び第2の主要面を有する、第2層と、
組成式[R1 2SiO2/2]の単位及び組成式[R2SiO3/2]の単位を有するオルガノシロキサン樹脂を含み、前記第1層の前記第2の主要面及び前記第2層の前記第1の主要面と直接的に接触している、第3層と、
を有する、封止フィルム。
(式中、R1は独立して、C1〜C30のヒドロカルビルであり、
R2は独立して、C1〜C20のヒドロカルビルである。) - 前記第1層の前記第1の樹脂−直鎖状オルガノシロキサンブロックコポリマー及び前記第2層の前記第2の樹脂−直鎖状オルガノシロキサンブロックコポリマーのうちの少なくとも1つの前記樹脂ブロックの、組成式[R1 2SiO2/2]の前記単位の前記R1基及び組成式[R2SiO3/2]の前記単位の前記R2基のうちの少なくとも1つの約20〜約100モル%が、C6−C16のアリール基であり、
前記第3層の前記オルガノシロキサン樹脂の、組成式[R1 2SiO2/2]の前記単位の前記R1基及び組成式[R2SiO3/2]の前記単位の前記R2基のうちの少なくとも1つの約20〜約100モル%が、C6−C16のアリール基である、請求項1に記載の封止フィルム。 - 前記第1層の前記第1の樹脂−直鎖状オルガノシロキサンブロックコポリマー及び前記第2の樹脂−直鎖状オルガノシロキサンブロックコポリマーのうちの少なくとも1つの前記樹脂ブロックの、組成式[R1 2SiO2/2]の前記単位の前記R1基及び組成式[R2SiO3/2]の前記単位の前記R2基のうちの少なくとも1つの約20〜約100モル%が、C1−C6のアルキル基であり、
前記第3層の前記オルガノシロキサン樹脂の、組成式[R1 2SiO2/2]の前記単位の前記R1基及び組成式[R2SiO3/2]の前記単位の前記R2基のうちの少なくとも1つの約20〜約100モル%が、C1−C6のアルキル基である、請求項1に記載の封止フィルム。 - 前記第1の樹脂−直鎖状オルガノシロキサンブロックコポリマー及び前記第2の樹脂−直鎖状オルガノシロキサンブロックコポリマーのうちの少なくとも1つが、
40〜90モル%の組成式[R1 2SiO2/2]の単位、
10〜60モル%の組成式[R2SiO3/2]の単位、
0.5〜25モル%のシラノール基
(式中、
R1は独立して、C1〜C30のヒドロカルビルであり、
R2は独立して、C1〜C20のヒドロカルビルであり、
[R1 2SiO2/2]の前記単位は、直鎖状ブロック当たり平均10〜400の[R1 2SiO2/2]の単位が、直鎖状ブロックに配置され、
[R2SiO3/2]の前記単位は、少なくとも500g/モルの分子量を有する非直鎖状ブロックに配置される)
を有する樹脂−直鎖状オルガノシロキサンブロックコポリマーを含み、
前記非直鎖状ブロックの少なくとも30%が、互いに架橋し、大部分がナノドメイン内で一緒になって凝集し、
各直鎖状ブロックが、少なくとも1つの非直鎖状ブロックに連結し、
前記樹脂−直鎖状オルガノシロキサンブロックコポリマーが、少なくとも20,000g/モルの重量平均分子量を有し、25℃で固体である、請求項1に記載の封止フィルム。 - 前記オルガノシロキサン樹脂が、少なくとも60モル%の[R2SiO3/2]のシロキシ単位をその組成式中に有する、請求項1に記載の封止フィルム。
- R2が各々独立して、C1〜C20のヒドロカルビルである、請求項5に記載の封止フィルム。
- 前記オルガノシロキサン樹脂がシルセスキオキサン樹脂である、請求項1に記載の封止フィルム。
- 前記オルガノシロキサン樹脂がフェニルシルセスキオキサン樹脂である、請求項7に記載の封止フィルム。
- 前記封止フィルムの厚さが、約0.5μm〜約5000μmである、請求項1に記載の封止フィルム。
- 前記第1層又は前記第2層のうちの少なくとも1つが、1つ以上の燐光体を含む、請求項1に記載の封止フィルム。
- 光学表面を有する光学デバイス、及び請求項1に記載の封止フィルムを有し、
前記封止フィルムが前記光学表面を実質的に又は全体的に被覆する、光学アセンブリ。 - 光学デバイスの光学表面を、請求項1に記載の封止フィルムにより、実質的に又は全体的に被覆することを含む、光学アセンブリの作製方法。
- 前記被覆することの前に、前記封止フィルムを予備形成することを更に含む、請求項12に記載の光学アセンブリの作製方法。
- 前記予備形成することが、
前記第1層を形成することと、
前記第2層を形成することと、
オルガノシロキサン樹脂組成物を、前記第1層の前記第2の主要面及び前記第2層の前記第1の主要面のうちの少なくとも1つに適用することと、
前記第1層の前記第2の主要面と前記第2層の前記第1の主要面との間に前記第3層を形成し、積層ポリマー構造を形成するため、前記第1層の前記第2の主要面、前記適用したオルガノシロキサン樹脂組成物、及び前記第2層の前記第1の主要面を一緒にして接触させることと、
前記積層ポリマー構造をラミネートすること又は圧縮成型することと、
を含む、請求項13に記載の光学アセンブリの作製方法。 - 前記第1層、前記第2層、及び前記第3層のうちの少なくとも1つを硬化することを更に含む、請求項14に記載の光学アセンブリの作製方法。
- 前記第1層、前記第2層、及び前記第3層のうちの少なくとも1つが、それらのうちの他の少なくとも1つの硬化機構と、同じ又は異なる硬化機構を有する、請求項15に記載の光学アセンブリの作製方法。
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US201462016959P | 2014-06-25 | 2014-06-25 | |
US62/016,959 | 2014-06-25 | ||
PCT/US2015/037617 WO2015200587A1 (en) | 2014-06-25 | 2015-06-25 | Layered polymer structures and methods |
Publications (2)
Publication Number | Publication Date |
---|---|
JP2017529254A true JP2017529254A (ja) | 2017-10-05 |
JP6599909B2 JP6599909B2 (ja) | 2019-10-30 |
Family
ID=54938798
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP2016574283A Active JP6599909B2 (ja) | 2014-06-25 | 2015-06-25 | 積層ポリマー構造及び方法 |
Country Status (7)
Country | Link |
---|---|
US (1) | US20170194539A1 (ja) |
EP (1) | EP3161881A4 (ja) |
JP (1) | JP6599909B2 (ja) |
KR (1) | KR20170042282A (ja) |
CN (1) | CN106796978B (ja) |
TW (1) | TWI661036B (ja) |
WO (1) | WO2015200587A1 (ja) |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2020533428A (ja) * | 2017-08-16 | 2020-11-19 | ダウ シリコーンズ コーポレーション | ポリシロキサン−ポリエステルブロックコポリマー、その製造方法、及びその使用 |
JP2021502695A (ja) * | 2017-11-08 | 2021-01-28 | 廈門市三安光電科技有限公司 | 紫外ledパッケージ構造 |
Families Citing this family (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US10874604B2 (en) * | 2016-10-04 | 2020-12-29 | Dow Toray Co., Ltd. | Cosmetic composition or external composition, and cosmetic raw material composition |
TW201911610A (zh) * | 2017-07-27 | 2019-03-16 | 美商羅門哈斯電子材料有限公司 | 聚矽氧組合物及控制光之物件 |
CN110728078B (zh) * | 2019-11-14 | 2022-11-25 | 吉林大学 | 一种基于胶粘剂化学特性的粘接结构在全服役温度区间下的力学性能的预测方法 |
Family Cites Families (16)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3175994A (en) * | 1962-04-06 | 1965-03-30 | Gen Electric | Process for preparing organo-polysiloxanes |
US5075103A (en) * | 1990-07-06 | 1991-12-24 | Dow Corning Corporation | Hair fixatives comprising nonpolar silsesquioxanes |
US5164461A (en) * | 1991-03-14 | 1992-11-17 | General Electric Company | Addition-curable silicone adhesive compositions |
JPH09183908A (ja) * | 1995-12-28 | 1997-07-15 | Toray Dow Corning Silicone Co Ltd | 硬化性オルガノポリシロキサン組成物および該組成物を使用して基材と被着体を接着させる方法 |
US6596404B1 (en) * | 2001-07-26 | 2003-07-22 | Dow Corning Corporation | Siloxane resins |
US7314770B2 (en) * | 2004-11-18 | 2008-01-01 | 3M Innovative Properties Company | Method of making light emitting device with silicon-containing encapsulant |
EP1963409A2 (en) * | 2005-10-05 | 2008-09-03 | Dow Corning Corporation | Coated substrates and methods for their preparation |
WO2007120197A2 (en) * | 2005-11-04 | 2007-10-25 | Dow Corning Corporation | Encapsulation of photovoltaic cells |
US8283025B2 (en) * | 2007-02-22 | 2012-10-09 | Dow Corning Corporation | Reinforced silicone resin films |
JP2011042732A (ja) * | 2009-08-20 | 2011-03-03 | Kaneka Corp | Led封止剤 |
WO2012102540A2 (ko) * | 2011-01-24 | 2012-08-02 | (주)Lg화학 | 광전지 모듈 |
US9650472B2 (en) * | 2011-12-14 | 2017-05-16 | Dow Corning Corporation | Curable compositions of resin-linear organosiloxane block copolymers |
WO2013109607A1 (en) * | 2012-01-16 | 2013-07-25 | Dow Corning Corporation | Optical article and method of forming |
JP5583703B2 (ja) * | 2012-01-18 | 2014-09-03 | 信越化学工業株式会社 | 光半導体装置の製造方法 |
CN104220902B (zh) * | 2012-02-09 | 2018-06-26 | 美国陶氏有机硅公司 | 梯度聚合物结构和方法 |
JP2013214716A (ja) * | 2012-03-06 | 2013-10-17 | Nitto Denko Corp | 蛍光封止シート、発光ダイオード装置およびその製造方法 |
-
2015
- 2015-06-25 KR KR1020177001671A patent/KR20170042282A/ko unknown
- 2015-06-25 WO PCT/US2015/037617 patent/WO2015200587A1/en active Application Filing
- 2015-06-25 CN CN201580042273.5A patent/CN106796978B/zh not_active Expired - Fee Related
- 2015-06-25 EP EP15812008.9A patent/EP3161881A4/en not_active Withdrawn
- 2015-06-25 JP JP2016574283A patent/JP6599909B2/ja active Active
- 2015-06-25 TW TW104120486A patent/TWI661036B/zh not_active IP Right Cessation
- 2015-06-25 US US15/316,670 patent/US20170194539A1/en not_active Abandoned
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2020533428A (ja) * | 2017-08-16 | 2020-11-19 | ダウ シリコーンズ コーポレーション | ポリシロキサン−ポリエステルブロックコポリマー、その製造方法、及びその使用 |
US11566109B2 (en) | 2017-08-16 | 2023-01-31 | Dow Silicones Corporation | Polysiloxane-polyester block copolymer, method for producing the same, and use thereof |
JP2021502695A (ja) * | 2017-11-08 | 2021-01-28 | 廈門市三安光電科技有限公司 | 紫外ledパッケージ構造 |
JP7130745B2 (ja) | 2017-11-08 | 2022-09-05 | 廈門市三安光電科技有限公司 | 紫外ledパッケージ構造 |
Also Published As
Publication number | Publication date |
---|---|
TW201606059A (zh) | 2016-02-16 |
EP3161881A4 (en) | 2018-02-21 |
JP6599909B2 (ja) | 2019-10-30 |
WO2015200587A1 (en) | 2015-12-30 |
US20170194539A1 (en) | 2017-07-06 |
TWI661036B (zh) | 2019-06-01 |
KR20170042282A (ko) | 2017-04-18 |
CN106796978B (zh) | 2019-09-17 |
EP3161881A1 (en) | 2017-05-03 |
CN106796978A (zh) | 2017-05-31 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
JP6387355B2 (ja) | 層状ポリマー構造及び方法 | |
JP6599909B2 (ja) | 積層ポリマー構造及び方法 | |
TWI628237B (zh) | 粉末樹脂直鏈有機聚矽氧烷組成物 | |
JP6309898B2 (ja) | 光学物品及び形成方法 | |
KR102067384B1 (ko) | 고체 조명 장치 및 형성 방법 | |
CN104220902B (zh) | 梯度聚合物结构和方法 | |
CN105960437A (zh) | 反应性有机硅组合物、由其制成的热熔材料和可固化热熔组合物 | |
TW201815974A (zh) | 硬化性樹脂組成物、其硬化物、及半導體裝置 | |
JP7032052B2 (ja) | シリコーン樹脂フィルムおよびその製造方法、並びに半導体デバイスの製造方法 | |
JP5830000B2 (ja) | 接着性シリコーン組成物シート及びそのシート状硬化物 | |
WO2020241369A1 (ja) | 硬化性オルガノポリシロキサン組成物、及びその硬化物からなる光学部材 | |
CN105051114A (zh) | 含磷光剂的可固化有机硅组合物及由其制得的可固化热熔膜 | |
JP6514148B2 (ja) | 縮合硬化型シリコーン樹脂組成物及び半導体装置 |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
A521 | Request for written amendment filed |
Free format text: JAPANESE INTERMEDIATE CODE: A523 Effective date: 20170221 |
|
RD02 | Notification of acceptance of power of attorney |
Free format text: JAPANESE INTERMEDIATE CODE: A7422 Effective date: 20170307 |
|
RD03 | Notification of appointment of power of attorney |
Free format text: JAPANESE INTERMEDIATE CODE: A7423 Effective date: 20170307 |
|
RD04 | Notification of resignation of power of attorney |
Free format text: JAPANESE INTERMEDIATE CODE: A7424 Effective date: 20170522 |
|
A621 | Written request for application examination |
Free format text: JAPANESE INTERMEDIATE CODE: A621 Effective date: 20180611 |
|
A977 | Report on retrieval |
Free format text: JAPANESE INTERMEDIATE CODE: A971007 Effective date: 20190523 |
|
A131 | Notification of reasons for refusal |
Free format text: JAPANESE INTERMEDIATE CODE: A131 Effective date: 20190528 |
|
A521 | Request for written amendment filed |
Free format text: JAPANESE INTERMEDIATE CODE: A523 Effective date: 20190723 |
|
TRDD | Decision of grant or rejection written | ||
A01 | Written decision to grant a patent or to grant a registration (utility model) |
Free format text: JAPANESE INTERMEDIATE CODE: A01 Effective date: 20190903 |
|
A61 | First payment of annual fees (during grant procedure) |
Free format text: JAPANESE INTERMEDIATE CODE: A61 Effective date: 20191003 |
|
R150 | Certificate of patent or registration of utility model |
Ref document number: 6599909 Country of ref document: JP Free format text: JAPANESE INTERMEDIATE CODE: R150 |
|
S802 | Written request for registration of partial abandonment of right |
Free format text: JAPANESE INTERMEDIATE CODE: R311802 |
|
R350 | Written notification of registration of transfer |
Free format text: JAPANESE INTERMEDIATE CODE: R350 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |