JP2016522856A - 硬化性アクリル組成物、アクリルテープ、アクリルゴムロール、及びアクリルゴムロールの製造方法 - Google Patents
硬化性アクリル組成物、アクリルテープ、アクリルゴムロール、及びアクリルゴムロールの製造方法 Download PDFInfo
- Publication number
- JP2016522856A JP2016522856A JP2016515361A JP2016515361A JP2016522856A JP 2016522856 A JP2016522856 A JP 2016522856A JP 2016515361 A JP2016515361 A JP 2016515361A JP 2016515361 A JP2016515361 A JP 2016515361A JP 2016522856 A JP2016522856 A JP 2016522856A
- Authority
- JP
- Japan
- Prior art keywords
- acrylic
- rubber roll
- composition
- tape
- acrylic composition
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 title claims abstract description 70
- 239000000203 mixture Substances 0.000 title claims abstract description 41
- 229920000800 acrylic rubber Polymers 0.000 title claims abstract description 31
- 229920000058 polyacrylate Polymers 0.000 title claims abstract description 31
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 12
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 13
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 claims abstract description 7
- GOXQRTZXKQZDDN-UHFFFAOYSA-N 2-Ethylhexyl acrylate Chemical compound CCCCC(CC)COC(=O)C=C GOXQRTZXKQZDDN-UHFFFAOYSA-N 0.000 claims abstract description 7
- OMIGHNLMNHATMP-UHFFFAOYSA-N 2-hydroxyethyl prop-2-enoate Chemical compound OCCOC(=O)C=C OMIGHNLMNHATMP-UHFFFAOYSA-N 0.000 claims abstract description 7
- 229920001971 elastomer Polymers 0.000 claims description 33
- 239000005060 rubber Substances 0.000 claims description 32
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 7
- 230000001588 bifunctional effect Effects 0.000 claims description 7
- 239000000796 flavoring agent Substances 0.000 claims description 6
- 235000013355 food flavoring agent Nutrition 0.000 claims description 6
- 238000000034 method Methods 0.000 claims description 6
- FIHBHSQYSYVZQE-UHFFFAOYSA-N 6-prop-2-enoyloxyhexyl prop-2-enoate Chemical compound C=CC(=O)OCCCCCCOC(=O)C=C FIHBHSQYSYVZQE-UHFFFAOYSA-N 0.000 claims description 5
- -1 acrylic ester Chemical class 0.000 claims description 5
- 229910021485 fumed silica Inorganic materials 0.000 claims description 5
- ZDHCZVWCTKTBRY-UHFFFAOYSA-N omega-Hydroxydodecanoic acid Natural products OCCCCCCCCCCCC(O)=O ZDHCZVWCTKTBRY-UHFFFAOYSA-N 0.000 claims description 5
- 239000004033 plastic Substances 0.000 claims description 5
- 229920003023 plastic Polymers 0.000 claims description 5
- 238000003756 stirring Methods 0.000 claims description 5
- ZTQIQRKFHJRLAX-UHFFFAOYSA-N COC1(C(C=CC=C1)C(=O)C1C(C=CC=C1)(OC)OC)OC Chemical compound COC1(C(C=CC=C1)C(=O)C1C(C=CC=C1)(OC)OC)OC ZTQIQRKFHJRLAX-UHFFFAOYSA-N 0.000 claims description 4
- 239000003242 anti bacterial agent Substances 0.000 claims description 4
- 230000001678 irradiating effect Effects 0.000 claims description 4
- 239000003755 preservative agent Substances 0.000 claims description 4
- 238000004132 cross linking Methods 0.000 claims description 3
- 239000004014 plasticizer Substances 0.000 claims description 3
- 238000005520 cutting process Methods 0.000 claims description 2
- 125000005396 acrylic acid ester group Chemical group 0.000 claims 1
- 238000006116 polymerization reaction Methods 0.000 claims 1
- 230000002335 preservative effect Effects 0.000 claims 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract description 13
- 238000004140 cleaning Methods 0.000 abstract description 11
- 239000003599 detergent Substances 0.000 abstract 1
- 238000012360 testing method Methods 0.000 description 12
- 239000000853 adhesive Substances 0.000 description 8
- 230000001070 adhesive effect Effects 0.000 description 7
- 239000000428 dust Substances 0.000 description 5
- KWVGIHKZDCUPEU-UHFFFAOYSA-N 2,2-dimethoxy-2-phenylacetophenone Chemical compound C=1C=CC=CC=1C(OC)(OC)C(=O)C1=CC=CC=C1 KWVGIHKZDCUPEU-UHFFFAOYSA-N 0.000 description 4
- 230000000052 comparative effect Effects 0.000 description 4
- 230000002860 competitive effect Effects 0.000 description 4
- 239000000463 material Substances 0.000 description 4
- 238000010998 test method Methods 0.000 description 4
- 239000004753 textile Substances 0.000 description 4
- 238000011084 recovery Methods 0.000 description 3
- 239000002390 adhesive tape Substances 0.000 description 2
- 230000008901 benefit Effects 0.000 description 2
- 238000001035 drying Methods 0.000 description 2
- 230000014759 maintenance of location Effects 0.000 description 2
- 239000000178 monomer Substances 0.000 description 2
- 239000004848 polyfunctional curative Substances 0.000 description 2
- 239000002994 raw material Substances 0.000 description 2
- 229910002027 silica gel Inorganic materials 0.000 description 2
- 239000000741 silica gel Substances 0.000 description 2
- 229920003051 synthetic elastomer Polymers 0.000 description 2
- 239000005061 synthetic rubber Substances 0.000 description 2
- 238000005406 washing Methods 0.000 description 2
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 description 1
- 208000001840 Dandruff Diseases 0.000 description 1
- 244000043261 Hevea brasiliensis Species 0.000 description 1
- 230000002378 acidificating effect Effects 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 239000012790 adhesive layer Substances 0.000 description 1
- 230000000844 anti-bacterial effect Effects 0.000 description 1
- 229940088710 antibiotic agent Drugs 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 239000013013 elastic material Substances 0.000 description 1
- 239000000806 elastomer Substances 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 238000003912 environmental pollution Methods 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- 239000000417 fungicide Substances 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 230000002209 hydrophobic effect Effects 0.000 description 1
- 238000007654 immersion Methods 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 230000005923 long-lasting effect Effects 0.000 description 1
- 229920003052 natural elastomer Polymers 0.000 description 1
- 229920001194 natural rubber Polymers 0.000 description 1
- 229920002635 polyurethane Polymers 0.000 description 1
- 239000004814 polyurethane Substances 0.000 description 1
- 239000004800 polyvinyl chloride Substances 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 230000002035 prolonged effect Effects 0.000 description 1
- 238000005070 sampling Methods 0.000 description 1
- 238000004804 winding Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2/00—Processes of polymerisation
- C08F2/46—Polymerisation initiated by wave energy or particle radiation
- C08F2/48—Polymerisation initiated by wave energy or particle radiation by ultraviolet or visible light
-
- A—HUMAN NECESSITIES
- A47—FURNITURE; DOMESTIC ARTICLES OR APPLIANCES; COFFEE MILLS; SPICE MILLS; SUCTION CLEANERS IN GENERAL
- A47L—DOMESTIC WASHING OR CLEANING; SUCTION CLEANERS IN GENERAL
- A47L25/00—Domestic cleaning devices not provided for in other groups of this subclass
- A47L25/005—Domestic cleaning devices not provided for in other groups of this subclass using adhesive or tacky surfaces to remove dirt, e.g. lint removers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F220/04—Acids; Metal salts or ammonium salts thereof
- C08F220/06—Acrylic acid; Methacrylic acid; Metal salts or ammonium salts thereof
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F220/10—Esters
- C08F220/12—Esters of monohydric alcohols or phenols
- C08F220/16—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms
- C08F220/18—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms with acrylic or methacrylic acids
- C08F220/1808—C8-(meth)acrylate, e.g. isooctyl (meth)acrylate or 2-ethylhexyl (meth)acrylate
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F220/10—Esters
- C08F220/20—Esters of polyhydric alcohols or phenols, e.g. 2-hydroxyethyl (meth)acrylate or glycerol mono-(meth)acrylate
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
- C08J5/12—Bonding of a preformed macromolecular material to the same or other solid material such as metal, glass, leather, e.g. using adhesives
- C08J5/124—Bonding of a preformed macromolecular material to the same or other solid material such as metal, glass, leather, e.g. using adhesives using adhesives based on a macromolecular component
- C08J5/128—Adhesives without diluent
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L33/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
- C08L33/04—Homopolymers or copolymers of esters
- C08L33/06—Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, which oxygen atoms are present only as part of the carboxyl radical
- C08L33/062—Copolymers with monomers not covered by C08L33/06
- C08L33/066—Copolymers with monomers not covered by C08L33/06 containing -OH groups
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J133/00—Adhesives based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Adhesives based on derivatives of such polymers
- C09J133/04—Homopolymers or copolymers of esters
- C09J133/06—Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, the oxygen atom being present only as part of the carboxyl radical
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J133/00—Adhesives based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Adhesives based on derivatives of such polymers
- C09J133/04—Homopolymers or copolymers of esters
- C09J133/06—Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, the oxygen atom being present only as part of the carboxyl radical
- C09J133/062—Copolymers with monomers not covered by C09J133/06
- C09J133/066—Copolymers with monomers not covered by C09J133/06 containing -OH groups
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J4/00—Adhesives based on organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond ; adhesives, based on monomers of macromolecular compounds of groups C09J183/00 - C09J183/16
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J7/00—Adhesives in the form of films or foils
- C09J7/10—Adhesives in the form of films or foils without carriers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F220/10—Esters
- C08F220/12—Esters of monohydric alcohols or phenols
- C08F220/16—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms
- C08F220/18—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms with acrylic or methacrylic acids
- C08F220/1806—C6-(meth)acrylate, e.g. (cyclo)hexyl (meth)acrylate or phenyl (meth)acrylate
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2810/00—Chemical modification of a polymer
- C08F2810/20—Chemical modification of a polymer leading to a crosslinking, either explicitly or inherently
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2321/00—Characterised by the use of unspecified rubbers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2433/00—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Derivatives of such polymers
- C08J2433/04—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Derivatives of such polymers esters
- C08J2433/06—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Derivatives of such polymers esters of esters containing only carbon, hydrogen, and oxygen, the oxygen atom being present only as part of the carboxyl radical
- C08J2433/08—Homopolymers or copolymers of acrylic acid esters
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2312/00—Crosslinking
- C08L2312/06—Crosslinking by radiation
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J133/00—Adhesives based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Adhesives based on derivatives of such polymers
- C09J133/04—Homopolymers or copolymers of esters
- C09J133/06—Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, the oxygen atom being present only as part of the carboxyl radical
- C09J133/08—Homopolymers or copolymers of acrylic acid esters
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J2433/00—Presence of (meth)acrylic polymer
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Materials Engineering (AREA)
- Manufacturing & Machinery (AREA)
- Engineering & Computer Science (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Adhesives Or Adhesive Processes (AREA)
- Rolls And Other Rotary Bodies (AREA)
- Graft Or Block Polymers (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Processes Of Treating Macromolecular Substances (AREA)
- Manufacture Of Macromolecular Shaped Articles (AREA)
- Polymerisation Methods In General (AREA)
- Cleaning In Electrography (AREA)
- Detergent Compositions (AREA)
Abstract
Description
表1に示す比率に応じて2−EHA、AA、HEA、硬化剤HDDA及び光開始剤Irgacure 651を均一に混合して、硬化性アクリル組成物を得る。具体的には、室温で、2−EHA、AA、HEA及び硬化剤HDDAを含む液体原料をガラス容器に注ぎ入れ、この材料をスターラーを用いて一定速度で撹拌し、次いで光開始剤Irgacure 651粉末を添加し、光開始剤Irgacure 651が完全に溶解するまで一定速度でこの材料を撹拌し続ける。
硬化性アクリル組成物は、実施形態1と同じ方法で調製してもよい。表1に示す2−EHA、AA及びHEAの比率の変化に違いがある。実施形態1と同じ方法で調製した硬化性アクリル組成物を用いて、アクリルテープ及びアクリルゴムロールを調製する。
実施形態1と同じ方法を用いて、硬化性アクリル組成物を調製する。表1に示す2−EHA、AA及びHEAの比率の変化に違いがある。実施形態1と同じ方法で調製した硬化性アクリル組成物を用いて、アクリルテープ及びアクリルゴムロールを調製する。
好適な量のリントを選択し、このリントを平らな表面上に置く。試験済みの新しいゴムの表面をそっとリントに接触させ、次いで迅速にサンプルを持ち上げる。リントが容易にゴムサンプルによって持ち上げられたかどうかを観察する。
初期接着試験方法に、G1 ASTM D6195の規格を参照する。サンプルは、新しいゴムサンプル及び浸漬したゴムサンプルを含む。浸漬したサンプルの製造方法は、ゴムサンプル全体を清浄水に浸漬させ、浸漬から30分後に取り出すものである。ゴムサンプルが試験用に完全に乾燥するまで、ゴムサンプルを22℃、湿度50%の室内に置く。
試験サンプルを2.54センチ×20センチ(1インチ×8インチ)に測定し、標準の埃で覆う。水を流しながら手でサンプルを約15秒間洗い、次いで水滴をそっと振り落とし、サンプルを22℃、相対湿度50%の環境下で1分間放置させておく。次いで、これらの工程(埃の添加、洗浄、及び濯ぎ)を150回繰り返した後、5分間乾燥させる。次いで、G1 ASTM D6195にしたがって、実施形態1、比較ケース1及び競合製品(競合製品は、ほとんどが、合成ゴム、ポリウレタン、及びシリカゲル等の弾性材料をプラスチックロール軸上に、型を用いてキャスティングすることによって製造され、粘着リントローラー及びリントクリーナー等の名称を有する)について試験を実施する。
ゴムローラーのロール直径は56mmであり、ロールの長さは98mmである。洗浄後の自然乾燥時間は、ゴムロールの接着性回復時間である。
Claims (12)
- 50〜77重量%の2−エチルヘキシルアクリレート、2〜10重量%のアクリル酸、20〜40重量%の2−ヒドロキシエチルアクリレート、0.1〜0.5重量%の硬化剤、及び0.1〜0.2重量%の光開始剤を含む、硬化性アクリル組成物。
- 前記硬化剤が、二官能性アクリル酸エステルを含む、請求項1に記載のアクリル組成物。
- 前記光開始剤が、2,2−ジメトキシフェニルケトンを含む、請求項1に記載のアクリル組成物。
- 前記二官能性アクリル酸エステルが、HDDA又はTPGDAを含む、請求項2に記載のアクリル組成物。
- 前記アクリル組成物が、防腐剤、抗菌剤、香味剤、可塑剤及びヒュームドシリカのうち1つ以上をさらに含む、請求項1〜4のいずれか一項に記載のアクリル組成物。
- 請求項1に記載のアクリル組成物を硬化させることによって形成された、アクリルテープ。
- 前記硬化が、紫外線重合を含む、請求項6に記載のアクリルテープ。
- ローラーと、前記ローラーに巻き付けられている請求項6に記載のアクリルテープとを含む、アクリルゴムロール。
- アクリルゴムロールを製造する方法であって、
50〜77重量%の2−エチルヘキシルアクリレート、2〜10重量%のアクリル酸、20〜40重量%の2−ヒドロキシエチルアクリレート、及び0.1〜0.5重量%の硬化剤を室温で混合し、撹拌する工程と、
1〜0.2重量%の光開始剤を前記混合物に添加し、前記光開始剤が完全に溶解するまで撹拌し続けて、アクリル組成物を形成する工程と、
前記アクリル組成物に紫外線を照射し、前記アクリル組成物を架橋硬化させて、アクリルテープを得る工程と、
前記アクリルテープモデルをプラスチックゴムロール軸のサイズに応じて切断し、前記アクリルゴムロールを得るように、前記アクリルテープを、気泡を回避しながら、自由に回転できるゴムロールに均一に貼り付ける工程と、
を含む、方法。 - 前記アクリル組成物に紫外線を照射する工程の前に、防腐剤、抗菌剤、香味剤、可塑剤、及びヒュームドシリカのうちの1つ以上を前記アクリル組成物中に添加する工程を更に含む、請求項9に記載のアクリルゴムロールを製造する方法。
- 前記硬化剤が、二官能性アクリル酸エステルをさらに含む、請求項9に記載のアクリルゴムロールを製造する方法。
- 前記光開始剤が、2,2−ジメトキシフェニルケトンを含む、請求項9に記載のアクリルゴムロールを製造する方法。
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201310187526.0A CN104163884B (zh) | 2013-05-20 | 2013-05-20 | 可固化的丙烯酸类组合物、丙烯酸类胶带、丙烯酸类胶辊以及制备该丙烯酸类胶辊的方法 |
CN201310187526.0 | 2013-05-20 | ||
PCT/US2014/037970 WO2014189734A1 (en) | 2013-05-20 | 2014-05-14 | Curable acrylic composition, acrylic tape, acrylic rubber roll and method for preparing the acrylic rubber roll |
Publications (2)
Publication Number | Publication Date |
---|---|
JP2016522856A true JP2016522856A (ja) | 2016-08-04 |
JP2016522856A5 JP2016522856A5 (ja) | 2017-06-22 |
Family
ID=51907879
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP2016515361A Pending JP2016522856A (ja) | 2013-05-20 | 2014-05-14 | 硬化性アクリル組成物、アクリルテープ、アクリルゴムロール、及びアクリルゴムロールの製造方法 |
Country Status (9)
Country | Link |
---|---|
US (2) | US20160083491A1 (ja) |
EP (1) | EP2999724A4 (ja) |
JP (1) | JP2016522856A (ja) |
KR (1) | KR20160009649A (ja) |
CN (1) | CN104163884B (ja) |
BR (1) | BR112015029052A2 (ja) |
MX (1) | MX2015015823A (ja) |
TW (1) | TW201500434A (ja) |
WO (1) | WO2014189734A1 (ja) |
Families Citing this family (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
KR101687872B1 (ko) * | 2013-09-30 | 2016-12-19 | 주식회사 엘지화학 | 라디칼 경화형 접착제 조성물 및 이를 포함하는 편광판 |
KR101620188B1 (ko) * | 2013-09-30 | 2016-05-12 | 주식회사 엘지화학 | 편광판 및 이를 포함하는 화상표시장치 |
JP2016116795A (ja) * | 2014-12-22 | 2016-06-30 | 株式会社ニトムズ | 抗菌処理用粘着クリーナー |
KR101987441B1 (ko) * | 2015-06-22 | 2019-06-11 | 주식회사 엘지화학 | 광학용 점착 시트 |
JP6651553B2 (ja) * | 2016-02-01 | 2020-02-19 | 株式会社巴川製紙所 | クリーナ |
WO2017179497A1 (ja) * | 2016-04-13 | 2017-10-19 | 東亞合成株式会社 | アクリルゴムの製造方法 |
CN114921200A (zh) * | 2022-04-29 | 2022-08-19 | 深圳市中升薄膜材料有限公司 | 一种化合物粘尘胶及其成分、制备方法和应用 |
Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS63132913A (ja) * | 1986-11-26 | 1988-06-04 | Japan Synthetic Rubber Co Ltd | ホース材、被覆材、あるいはロール用アクリルゴム組成物 |
JP2006188687A (ja) * | 2004-12-29 | 2006-07-20 | Natl Starch & Chem Investment Holding Corp | 感圧接着剤用の光開始剤及びuv架橋性アクリルポリマー |
JP2010163591A (ja) * | 2008-04-11 | 2010-07-29 | Three M Innovative Properties Co | 透明粘着シート及びそれを含む画像表示装置 |
JP2012046677A (ja) * | 2010-08-30 | 2012-03-08 | Denki Kagaku Kogyo Kk | 粘着性アクリル系熱伝導シート |
Family Cites Families (14)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3682690A (en) * | 1970-06-17 | 1972-08-08 | Homer C Amos | Article coated with a water-washable tacky elastomer |
US6735806B2 (en) * | 1999-05-04 | 2004-05-18 | Eggs In The Pipeline, Llc | Tacky roller for improved surface cleaning |
JP4756127B2 (ja) * | 2003-10-30 | 2011-08-24 | 綜研化学株式会社 | (メタ)アクリル系重合体の製造方法 |
US7238732B2 (en) * | 2004-02-18 | 2007-07-03 | Eastman Chemical Company | Radiation-curable adhesive compositions |
CN1260316C (zh) * | 2004-03-11 | 2006-06-21 | 刘萍 | Uv固化可剥离压敏胶膜 |
CA2544709C (en) * | 2005-04-28 | 2012-12-04 | Nitto Denko Corporation | Adhesive and laminate |
US8242185B2 (en) * | 2009-08-03 | 2012-08-14 | Morgan Adhesives Company | Adhesive compositions for easy application and improved durability |
CN101979162B (zh) * | 2010-09-26 | 2012-04-11 | 昆山博益鑫成高分子材料有限公司 | 一种粘尘滚筒及其制造方法 |
KR101621993B1 (ko) * | 2010-11-08 | 2016-05-19 | 주식회사 엘지화학 | 점착제 조성물 |
US20120315476A1 (en) * | 2011-06-08 | 2012-12-13 | Hiroshi Ogawa | Adhesive composition and surface protection film using the same |
KR101534898B1 (ko) * | 2012-06-19 | 2015-07-07 | (주)엘지하우시스 | 기포 안정성이 향상된 점착제 조성물 및 그의 제조방법 |
KR101523817B1 (ko) * | 2012-07-10 | 2015-05-28 | (주)엘지하우시스 | 기포 안정성이 향상된 난연용 점착제 조성물 및 그의 제조방법 |
CN103725203B (zh) * | 2012-10-10 | 2016-08-17 | 第一毛织株式会社 | 粘结剂膜、用于它的粘结剂组合物和包含它的显示部件 |
KR101566060B1 (ko) * | 2012-12-27 | 2015-11-04 | 제일모직주식회사 | 점착 필름, 이를 위한 점착제 조성물 및 이를 포함하는 디스플레이 부재 |
-
2013
- 2013-05-20 CN CN201310187526.0A patent/CN104163884B/zh active Active
-
2014
- 2014-05-14 KR KR1020157035522A patent/KR20160009649A/ko not_active Application Discontinuation
- 2014-05-14 MX MX2015015823A patent/MX2015015823A/es unknown
- 2014-05-14 JP JP2016515361A patent/JP2016522856A/ja active Pending
- 2014-05-14 US US14/891,728 patent/US20160083491A1/en not_active Abandoned
- 2014-05-14 BR BR112015029052A patent/BR112015029052A2/pt not_active Application Discontinuation
- 2014-05-14 WO PCT/US2014/037970 patent/WO2014189734A1/en active Application Filing
- 2014-05-14 EP EP14801109.1A patent/EP2999724A4/en not_active Withdrawn
- 2014-05-19 TW TW103117507A patent/TW201500434A/zh unknown
-
2017
- 2017-05-18 US US15/599,093 patent/US20170253682A1/en not_active Abandoned
Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS63132913A (ja) * | 1986-11-26 | 1988-06-04 | Japan Synthetic Rubber Co Ltd | ホース材、被覆材、あるいはロール用アクリルゴム組成物 |
JP2006188687A (ja) * | 2004-12-29 | 2006-07-20 | Natl Starch & Chem Investment Holding Corp | 感圧接着剤用の光開始剤及びuv架橋性アクリルポリマー |
JP2010163591A (ja) * | 2008-04-11 | 2010-07-29 | Three M Innovative Properties Co | 透明粘着シート及びそれを含む画像表示装置 |
JP2012046677A (ja) * | 2010-08-30 | 2012-03-08 | Denki Kagaku Kogyo Kk | 粘着性アクリル系熱伝導シート |
Also Published As
Publication number | Publication date |
---|---|
TW201500434A (zh) | 2015-01-01 |
KR20160009649A (ko) | 2016-01-26 |
CN104163884A (zh) | 2014-11-26 |
EP2999724A4 (en) | 2017-01-25 |
US20160083491A1 (en) | 2016-03-24 |
WO2014189734A1 (en) | 2014-11-27 |
MX2015015823A (es) | 2016-03-04 |
EP2999724A1 (en) | 2016-03-30 |
US20170253682A1 (en) | 2017-09-07 |
BR112015029052A2 (pt) | 2017-07-25 |
CN104163884B (zh) | 2016-12-28 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
JP2016522856A (ja) | 硬化性アクリル組成物、アクリルテープ、アクリルゴムロール、及びアクリルゴムロールの製造方法 | |
JP6181225B2 (ja) | プレート表面用粘着クリーナー | |
KR102140999B1 (ko) | 유기질 오염 제거용 점착 클리너 | |
TWI604898B (zh) | Organic dirt removal adhesive cleaner | |
CN108285762A (zh) | 一种丙烯酸胶粘剂和一种泡棉胶带 | |
TWI687193B (zh) | 黏著清潔器 | |
CN105348936A (zh) | 一种疏水型弹性水性乳胶漆及其制备方法 | |
WO2016104394A1 (ja) | 抗菌処理用粘着クリーナー | |
CN105754501B (zh) | 一种硅胶表面处理方法 | |
CN103027854A (zh) | 一种净手胶及其制备方法和用途 | |
JP2021025009A (ja) | 布地、皮革又は紙用接着剤、布地、皮革又は紙の接着方法、及び布地、皮革又は紙製品の製造方法 | |
JPH0770527A (ja) | 両面粘着テープ | |
TWM527304U (zh) | 雙面型擦拭用手套 | |
JPS6062361A (ja) | 繊維質上塗り壁の剥離方法 | |
CN104893564A (zh) | 一种用于建筑物的防粘贴纤维涂料 | |
CN114993929A (zh) | 一种装饰膜应用性能测试方法 | |
JP3122848U (ja) | 配線カバー用両面粘着テープ | |
CN103786495A (zh) | 环保黑板 | |
JPS6014917A (ja) | エア−フイルタ− | |
JP2012223535A (ja) | 表面処理液含浸布材 | |
JPH0411156A (ja) | 目地ます工法用特殊糊及び目地ます工法 | |
WO2001021749A1 (fr) | Detachant liquide et detachant en feuilles | |
JP2006342312A (ja) | 樹脂ワックス皮膜層などの除去剤組成物およびその除去方法 |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
A521 | Request for written amendment filed |
Free format text: JAPANESE INTERMEDIATE CODE: A523 Effective date: 20170511 |
|
A621 | Written request for application examination |
Free format text: JAPANESE INTERMEDIATE CODE: A621 Effective date: 20170511 |
|
A977 | Report on retrieval |
Free format text: JAPANESE INTERMEDIATE CODE: A971007 Effective date: 20180314 |
|
A131 | Notification of reasons for refusal |
Free format text: JAPANESE INTERMEDIATE CODE: A131 Effective date: 20180320 |
|
A02 | Decision of refusal |
Free format text: JAPANESE INTERMEDIATE CODE: A02 Effective date: 20181120 |