CN1260316C - Uv固化可剥离压敏胶膜 - Google Patents
Uv固化可剥离压敏胶膜 Download PDFInfo
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- CN1260316C CN1260316C CN 200410022029 CN200410022029A CN1260316C CN 1260316 C CN1260316 C CN 1260316C CN 200410022029 CN200410022029 CN 200410022029 CN 200410022029 A CN200410022029 A CN 200410022029A CN 1260316 C CN1260316 C CN 1260316C
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- acrylate
- parts
- dipentaerythritol
- adhesive film
- pressure sensitive
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- 238000002360 preparation method Methods 0.000 title abstract description 20
- 238000000576 coating method Methods 0.000 title description 9
- 239000011248 coating agent Substances 0.000 title description 4
- 239000004820 Pressure-sensitive adhesive Substances 0.000 claims abstract description 22
- 229920001577 copolymer Polymers 0.000 claims abstract description 22
- 239000000203 mixture Substances 0.000 claims abstract description 20
- 239000000178 monomer Substances 0.000 claims abstract description 16
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims abstract description 12
- CQEYYJKEWSMYFG-UHFFFAOYSA-N butyl acrylate Chemical compound CCCCOC(=O)C=C CQEYYJKEWSMYFG-UHFFFAOYSA-N 0.000 claims abstract description 8
- -1 acrylic ester Chemical class 0.000 claims abstract description 7
- 239000002253 acid Substances 0.000 claims abstract description 5
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 claims description 33
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 claims description 31
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 claims description 21
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 claims description 18
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims description 18
- 229910021529 ammonia Inorganic materials 0.000 claims description 17
- 150000002148 esters Chemical class 0.000 claims description 17
- TXBCBTDQIULDIA-UHFFFAOYSA-N 2-[[3-hydroxy-2,2-bis(hydroxymethyl)propoxy]methyl]-2-(hydroxymethyl)propane-1,3-diol Chemical compound OCC(CO)(CO)COCC(CO)(CO)CO TXBCBTDQIULDIA-UHFFFAOYSA-N 0.000 claims description 14
- 238000006243 chemical reaction Methods 0.000 claims description 13
- SSOONFBDIYMPEU-UHFFFAOYSA-N [3-hydroxy-2-[[3-hydroxy-2,2-bis(hydroxymethyl)propoxy]methyl]-2-(hydroxymethyl)propyl] prop-2-enoate Chemical compound OCC(CO)(CO)COCC(CO)(CO)COC(=O)C=C SSOONFBDIYMPEU-UHFFFAOYSA-N 0.000 claims description 11
- DLUPHJKQEIIYAM-UHFFFAOYSA-N 1-(2-ethoxyphenyl)-2-hydroxy-2-phenylethanone Chemical compound CCOC1=CC=CC=C1C(=O)C(O)C1=CC=CC=C1 DLUPHJKQEIIYAM-UHFFFAOYSA-N 0.000 claims description 5
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 5
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 claims description 5
- HVVWZTWDBSEWIH-UHFFFAOYSA-N [2-(hydroxymethyl)-3-prop-2-enoyloxy-2-(prop-2-enoyloxymethyl)propyl] prop-2-enoate Chemical compound C=CC(=O)OCC(CO)(COC(=O)C=C)COC(=O)C=C HVVWZTWDBSEWIH-UHFFFAOYSA-N 0.000 claims description 4
- 150000001875 compounds Chemical class 0.000 claims description 4
- JEIPFZHSYJVQDO-UHFFFAOYSA-N ferric oxide Chemical compound O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 claims description 4
- 239000012948 isocyanate Substances 0.000 claims description 4
- 150000002513 isocyanates Chemical class 0.000 claims description 4
- 238000006116 polymerization reaction Methods 0.000 claims description 4
- 125000004805 propylene group Chemical class [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 claims description 4
- 238000009833 condensation Methods 0.000 claims description 3
- 230000005494 condensation Effects 0.000 claims description 3
- 239000002904 solvent Substances 0.000 claims description 3
- DVKJHBMWWAPEIU-UHFFFAOYSA-N toluene 2,4-diisocyanate Chemical compound CC1=CC=C(N=C=O)C=C1N=C=O DVKJHBMWWAPEIU-UHFFFAOYSA-N 0.000 claims description 2
- 239000003292 glue Substances 0.000 abstract description 6
- OMIGHNLMNHATMP-UHFFFAOYSA-N 2-hydroxyethyl prop-2-enoate Chemical compound OCCOC(=O)C=C OMIGHNLMNHATMP-UHFFFAOYSA-N 0.000 abstract description 4
- 238000002474 experimental method Methods 0.000 abstract description 3
- 238000009281 ultraviolet germicidal irradiation Methods 0.000 abstract description 3
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 abstract description 2
- 238000005260 corrosion Methods 0.000 abstract description 2
- 230000007797 corrosion Effects 0.000 abstract description 2
- 125000004386 diacrylate group Chemical group 0.000 abstract description 2
- 239000002313 adhesive film Substances 0.000 abstract 2
- RXQKKPDQYISKHD-UHFFFAOYSA-N 2-ethylhexyl prop-2-enoate;prop-2-enoic acid Chemical compound OC(=O)C=C.CCCCC(CC)COC(=O)C=C RXQKKPDQYISKHD-UHFFFAOYSA-N 0.000 abstract 1
- 239000003344 environmental pollutant Substances 0.000 abstract 1
- IJDNQMDRQITEOD-UHFFFAOYSA-N n-butane Chemical compound CCCC IJDNQMDRQITEOD-UHFFFAOYSA-N 0.000 abstract 1
- 231100000719 pollutant Toxicity 0.000 abstract 1
- 238000005286 illumination Methods 0.000 description 9
- 230000000052 comparative effect Effects 0.000 description 5
- 238000001035 drying Methods 0.000 description 5
- 238000003756 stirring Methods 0.000 description 5
- 238000004026 adhesive bonding Methods 0.000 description 4
- 229920006267 polyester film Polymers 0.000 description 4
- KHOUKKVJOPQVJM-UHFFFAOYSA-N 2,2-bis(hydroxymethyl)propane-1,3-diol;prop-2-enoic acid Chemical compound OC(=O)C=C.OCC(CO)(CO)CO KHOUKKVJOPQVJM-UHFFFAOYSA-N 0.000 description 2
- BAPJBEWLBFYGME-UHFFFAOYSA-N Methyl acrylate Chemical compound COC(=O)C=C BAPJBEWLBFYGME-UHFFFAOYSA-N 0.000 description 2
- 238000003848 UV Light-Curing Methods 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 238000004140 cleaning Methods 0.000 description 2
- 238000005538 encapsulation Methods 0.000 description 2
- 230000003628 erosive effect Effects 0.000 description 2
- 239000003999 initiator Substances 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 229920000728 polyester Polymers 0.000 description 2
- 238000010526 radical polymerization reaction Methods 0.000 description 2
- 150000003254 radicals Chemical class 0.000 description 2
- 230000002194 synthesizing effect Effects 0.000 description 2
- 229920002126 Acrylic acid copolymer Chemical group 0.000 description 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- JIGUQPWFLRLWPJ-UHFFFAOYSA-N Ethyl acrylate Chemical compound CCOC(=O)C=C JIGUQPWFLRLWPJ-UHFFFAOYSA-N 0.000 description 1
- 108010010803 Gelatin Proteins 0.000 description 1
- 239000005058 Isophorone diisocyanate Substances 0.000 description 1
- XBDQKXXYIPTUBI-UHFFFAOYSA-N Propionic acid Chemical class CCC(O)=O XBDQKXXYIPTUBI-UHFFFAOYSA-N 0.000 description 1
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 description 1
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 1
- 239000006096 absorbing agent Substances 0.000 description 1
- 230000004888 barrier function Effects 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 239000011889 copper foil Substances 0.000 description 1
- 238000005520 cutting process Methods 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 1
- 150000002009 diols Chemical class 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 1
- UHESRSKEBRADOO-UHFFFAOYSA-N ethyl carbamate;prop-2-enoic acid Chemical compound OC(=O)C=C.CCOC(N)=O UHESRSKEBRADOO-UHFFFAOYSA-N 0.000 description 1
- 239000005357 flat glass Substances 0.000 description 1
- 238000010528 free radical solution polymerization reaction Methods 0.000 description 1
- 229920000159 gelatin Polymers 0.000 description 1
- 239000008273 gelatin Substances 0.000 description 1
- 235000019322 gelatine Nutrition 0.000 description 1
- 235000011852 gelatine desserts Nutrition 0.000 description 1
- NIMLQBUJDJZYEJ-UHFFFAOYSA-N isophorone diisocyanate Chemical compound CC1(C)CC(N=C=O)CC(C)(CN=C=O)C1 NIMLQBUJDJZYEJ-UHFFFAOYSA-N 0.000 description 1
- 239000010410 layer Substances 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 239000012528 membrane Substances 0.000 description 1
- 125000005395 methacrylic acid group Chemical class 0.000 description 1
- PNJWIWWMYCMZRO-UHFFFAOYSA-N pent‐4‐en‐2‐one Natural products CC(=O)CC=C PNJWIWWMYCMZRO-UHFFFAOYSA-N 0.000 description 1
- 238000000016 photochemical curing Methods 0.000 description 1
- 239000005056 polyisocyanate Substances 0.000 description 1
- 229920001228 polyisocyanate Polymers 0.000 description 1
- 239000002244 precipitate Substances 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- VVWRJUBEIPHGQF-UHFFFAOYSA-N propan-2-yl n-propan-2-yloxycarbonyliminocarbamate Chemical compound CC(C)OC(=O)N=NC(=O)OC(C)C VVWRJUBEIPHGQF-UHFFFAOYSA-N 0.000 description 1
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 1
- DCKVNWZUADLDEH-UHFFFAOYSA-N sec-butyl acetate Chemical compound CCC(C)OC(C)=O DCKVNWZUADLDEH-UHFFFAOYSA-N 0.000 description 1
- 229910000077 silane Inorganic materials 0.000 description 1
- 229910052710 silicon Inorganic materials 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
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- Adhesives Or Adhesive Processes (AREA)
- Adhesive Tapes (AREA)
Abstract
Description
用量(克) | ||||||
成份 | 实施例1 | 实施例2 | 实施例3 | 实施例4 | 比较例1 | 比较例2 |
丙烯酸酯共聚物 | 100 | 100 | 100 | 100 | 100 | 100 |
氨酯丙烯酸酯 | 10 | 10 | 10 | 15 | 10 | 10 |
混合单体 | 20 | 10 | 10 | 20 | - | - |
季戊四醇三丙烯酸酯 | - | - | 10 | - | - | 10 |
乙氧基苯偶姻 | 3 | 3 | 3 | 3 | 3 | 3 |
压敏胶粘结力 克/25mm | ||||||
UV光照后 | 400 | 350 | 350 | 400 | 200 | 250 |
UV光照后 | 10 | 15 | 12 | 12 | 50 | 40 |
Claims (3)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN 200410022029 CN1260316C (zh) | 2004-03-11 | 2004-03-11 | Uv固化可剥离压敏胶膜 |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN 200410022029 CN1260316C (zh) | 2004-03-11 | 2004-03-11 | Uv固化可剥离压敏胶膜 |
Publications (2)
Publication Number | Publication Date |
---|---|
CN1560166A CN1560166A (zh) | 2005-01-05 |
CN1260316C true CN1260316C (zh) | 2006-06-21 |
Family
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Application Number | Title | Priority Date | Filing Date |
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CN 200410022029 Expired - Fee Related CN1260316C (zh) | 2004-03-11 | 2004-03-11 | Uv固化可剥离压敏胶膜 |
Country Status (1)
Country | Link |
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CN (1) | CN1260316C (zh) |
Families Citing this family (20)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP5047556B2 (ja) * | 2006-07-26 | 2012-10-10 | リンテック株式会社 | 光学機能性フィルム貼合用粘着剤、粘着剤付き光学機能性フィルム及びその製造方法 |
JP5089201B2 (ja) * | 2007-03-12 | 2012-12-05 | 日東電工株式会社 | アクリル系粘着テープ又はシート、およびその製造方法 |
CN101275059B (zh) * | 2007-03-28 | 2012-05-23 | 深圳丹邦科技股份有限公司 | 耐热可剥离微粘性压敏胶膜及其制备方法 |
CN101649165B (zh) * | 2009-08-31 | 2011-12-28 | 广东达美新材料有限公司 | 一种聚乙烯保护膜用紫外光固化压敏胶及其制备方法 |
JP5123991B2 (ja) * | 2010-06-09 | 2013-01-23 | 株式会社オートネットワーク技術研究所 | 防食剤、端子付き被覆電線およびワイヤーハーネス |
CN101979162B (zh) * | 2010-09-26 | 2012-04-11 | 昆山博益鑫成高分子材料有限公司 | 一种粘尘滚筒及其制造方法 |
CN101982248B (zh) * | 2010-09-26 | 2012-05-23 | 昆山博益鑫成高分子材料有限公司 | 一种绒面清洁滚筒的制造方法 |
CN104163884B (zh) * | 2013-05-20 | 2016-12-28 | 3M创新有限公司 | 可固化的丙烯酸类组合物、丙烯酸类胶带、丙烯酸类胶辊以及制备该丙烯酸类胶辊的方法 |
CN103434300B (zh) * | 2013-08-29 | 2015-04-15 | 郑州东港安全印刷有限公司 | 可变密码防伪票据 |
CN103633740B (zh) * | 2013-11-29 | 2015-08-19 | 国家电网公司 | 远动通道故障监测装置 |
CN103615927B (zh) * | 2013-11-29 | 2015-08-19 | 国家电网公司 | 风机电机外置阀水冷系统冷却塔 |
TWI527863B (zh) * | 2014-12-17 | 2016-04-01 | 奇美實業股份有限公司 | 可剝膠組成物與可剝膠帶 |
CN104497925A (zh) * | 2014-12-23 | 2015-04-08 | 安徽助成信息科技有限公司 | 基于光热的uv固化压敏胶制备方法 |
CN105086730B (zh) * | 2015-09-16 | 2017-03-22 | 广州申威新材料科技有限公司 | 一种双组分固化uv减粘胶 |
CN108611033A (zh) * | 2016-12-17 | 2018-10-02 | 黄志萍 | 一种uv减粘胶 |
CN106752987B (zh) * | 2016-12-27 | 2020-09-08 | 宁波卓胜新材料有限公司 | 一种紫外光固化压敏胶及其制备方法 |
JP6998585B2 (ja) * | 2017-10-20 | 2022-01-18 | 日榮新化株式会社 | 粘着シート及びその製造方法 |
CN109749672B (zh) * | 2018-12-27 | 2021-07-09 | 苏州赛伍应用技术股份有限公司 | 一种uv固化热减粘胶及其制备方法和应用 |
CN110305588A (zh) * | 2019-07-12 | 2019-10-08 | 太仓斯迪克新材料科技有限公司 | 一种紫外解离压敏粘合剂及胶带 |
CN112646537B (zh) * | 2020-11-18 | 2022-04-22 | 河北科技大学 | 一种用于硅晶片切割工艺的蓖麻油基全交联uv光致可剥离胶的制备方法 |
-
2004
- 2004-03-11 CN CN 200410022029 patent/CN1260316C/zh not_active Expired - Fee Related
Also Published As
Publication number | Publication date |
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CN1560166A (zh) | 2005-01-05 |
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