CN104163884A - 可固化的丙烯酸类组合物、丙烯酸类胶带、丙烯酸类胶辊以及制备该丙烯酸类胶辊的方法 - Google Patents

可固化的丙烯酸类组合物、丙烯酸类胶带、丙烯酸类胶辊以及制备该丙烯酸类胶辊的方法 Download PDF

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CN104163884A
CN104163884A CN201310187526.0A CN201310187526A CN104163884A CN 104163884 A CN104163884 A CN 104163884A CN 201310187526 A CN201310187526 A CN 201310187526A CN 104163884 A CN104163884 A CN 104163884A
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acrylic acid
acrylic
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rubber roll
acrylic composition
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CN104163884B (zh
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姚荣霞
孙宇
吴庆
滕超
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3M Innovative Properties Co
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Priority to US14/891,728 priority patent/US20160083491A1/en
Priority to KR1020157035522A priority patent/KR20160009649A/ko
Priority to BR112015029052A priority patent/BR112015029052A2/pt
Priority to PCT/US2014/037970 priority patent/WO2014189734A1/en
Priority to MX2015015823A priority patent/MX2015015823A/es
Priority to JP2016515361A priority patent/JP2016522856A/ja
Priority to EP14801109.1A priority patent/EP2999724A4/en
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Abstract

本发明提供一种可固化的丙烯酸类组合物、丙烯酸类胶带、丙烯酸类胶辊以及制备该丙烯酸类胶辊的方法。所述丙烯酸类组合物包含50-77重量％丙烯酸2-乙基己酯、2-10重量％丙烯酸、20-40重量％丙烯酸2-羟乙酯、0.1-0.5重量％固化剂以及0.1-0.2重量％光聚合引发剂。由该丙烯酸类组合物制备的丙烯酸类胶辊能够在无需清洁剂的情况下直接用清水清洗即可恢复粘性并且具有优异的清洁效果和耐洗性。

Description

可固化的丙烯酸类组合物、丙烯酸类胶带、丙烯酸类胶辊以及制备该丙烯酸类胶辊的方法
技术领域
本发明涉及一种可固化的丙烯酸类组合物、丙烯酸类胶带、丙烯酸类胶辊以及制备该丙烯酸胶辊的方法。 
背景技术
目前，已经将粘性除尘胶带、胶辊应用于软性家装以及服饰表面的清洁和维护。可抛弃性粘性除尘胶带和胶辊使用方便，但每次使用的成本较高，可反复使用的水洗型除尘胶辊日益受到众多价格敏感型以及环保型消费者的喜爱。市场上绝大多数的可水洗粘性清洁辊筒都是由天然橡胶、合成橡胶、硅胶或者PVC等基材构成，其自粘性弹性体材料本身作为粘性胶层且表面大多为疏水表面，单纯用水清洗效果不佳，需要借助清洁剂或者温水进行清洗减低表面摩擦力。并且很多清洁剂都是碱性或者酸性，长期使用会对粘性表面造成损伤。因此，少用或不用清洁剂将更加符合绿色、环保、不伤手的理念。另外，大多数的市售水洗随手粘由于表面摩擦力大，滚动困难，进而难以达到良好的清洁效果，更有可能会造成滚轮支持轴脱落或断裂，影响使用效果。 
发明内容
为了解决现有技术的问题，本发明提供了一种可固化的丙烯酸类组合物以及由该可固化的丙烯酸类组合物制备的丙烯酸类胶带和包括该丙烯酸类胶带的丙烯酸类胶辊，所述丙烯酸类胶辊能够在无需清洁剂的情况下直接用清水清洗即可恢复粘性并且具有优异的清洁效果和耐洗性。 
在一个实施例中，提供一种可固化的丙烯酸类组合物，所述丙烯酸类组合物包含50-77重量％丙烯酸2-乙基己酯、2-10重量％丙烯酸、20-40重量％丙烯酸2-羟乙酯、0.1-0.5重量％固化剂以及0.1-0.2重量％光聚合引 发剂。 
在一个实施例中，该光聚合引发剂包括2，2-二甲氧基-苯基甲酮。 
在一个实施例中，所述固化剂为双官能丙烯酸酯。该双官能丙烯酸酯可以包括己二醇二丙烯酸酯或三丙二醇二丙烯酸酯。 
在一个实施例中，该丙烯酸类组合物还包括防霉剂、抗菌剂、香味剂、增塑剂、和气相法二氧化硅中的一种或多种。 
在一个实施例中，提供一种通过固化上述的丙烯酸类组合物而制备的丙烯酸类胶带。 
在一个实施例中，所述固化包括紫外光固化。 
在一个实施例中，提供一种丙烯酸类胶辊，所述丙烯酸类胶辊包括辊筒和卷绕在辊筒上的上述丙烯酸类胶带。 
在一个实施例中，提供一种制造丙烯酸类胶辊的方法，该方法包括：在常温下，将50-77重量％丙烯酸2-乙基己酯、2-10重量％丙烯酸、20-40重量％丙烯酸2-羟乙酯、0.1-0.5重量％固化剂进行混合并搅拌；在所得的混合物中加入0.1-0.2重量％光聚合引发剂，并继续进行搅拌，直至所述光聚合引发剂完全溶解，得到丙烯酸类组合物；用紫外光照射所述丙烯酸类组合物，使其发生交联固化，得到丙烯酸类胶带；将丙烯酸类胶带模切至与塑料胶辊轴相应的尺寸，并将其均匀无气泡地贴合到可自由旋转的塑料胶辊上，得到所述丙烯酸类胶辊。 
在所述制造丙烯酸类胶辊的方法实施例中，在用紫外光照射所述丙烯酸类组合物之前，在所述丙烯酸类组合物中加入防霉剂、抗菌剂、香味剂、增塑剂、和气相法二氧化硅中的一种或多种。 
在所述制造丙烯酸类胶辊的方法实施例中，所述固化剂包括双官能丙烯酸酯。 
在所述制造丙烯酸类胶辊的方法实施例中，所述光聚合引发剂包括2，2-二甲氧基-苯基甲酮。 
有益效果 
本发明与传统的可反复使用的水洗型胶辊相比有很大的优势。根据本发明的丙烯酸类胶辊能够在无需清洁剂的情况下直接用清水清洗即可恢 复粘性并且具有优异的清洁效果和耐洗性，可以很容易清洁软性表面，去除附着在家纺制品等软性表面的毛发、皮屑、灰尘、纤维屑等，从而减少家纺制品特别是衣物的清洁频率。特别是，所公开的胶辊由于其表面特性，遇水其表面很快失去粘性并变得顺滑，在不需要借助清洁剂的情况下用清水即可轻松清除所粘附在表面的污物，且在去除其表面水分后即可快速恢复粘性，再次重复使用，从而减少对环境的污染并且使用方便。数次使用循环后，仍保持良好粘性以及胶面外观，胶面与贴附塑料辊之间粘结良好，水洗不容易发生胶面脱落。 
具体实施方式
在一个实施例中，提供一种可固化的丙烯酸类组合物，所述可固化的丙烯酸类组合物包含50-77重量％丙烯酸2-乙基己酯、2-10重量％丙烯酸、20-40重量％丙烯酸2-羟乙酯、0.1-0.5重量％固化剂以及0.1-0.2重量％光聚合引发剂。 
该丙烯酸类组合物还可以包含其他添加剂，例如防霉剂、抗菌剂，香味剂，例如气相法二氧化硅A-200。 
该固化剂没有特别的限制。其实例可以包括双官能丙烯酸酯单体，例如己二醇二丙烯酸酯，三丙二醇二丙烯酸酯等。 
该光聚合引发剂没有特别的限制。例如，其实例可以为Irgacure651。 
本发明的可固化的丙烯酸类组合物通过将丙烯酸2-乙基己酯、丙烯酸、丙烯酸2-羟乙酯、固化剂以及光聚合引发剂等根据比例混合而制备。 
此外，通过将可固化的丙烯酸类组合物固化，可以制备该丙烯酸类胶带。固化可以通过紫外光固化进行。 
在一个实施例中，通过将丙烯酸类胶带卷绕在辊筒上，可以制备丙烯酸类胶辊。该丙烯酸类胶辊可以用于清洁家纺制品的表面。 
在一个实施例中，可以将该丙烯酸类组合物直接施加于该辊筒上，然后将该丙烯酸类组合物进行交联固化而得到用于清洁家纺制品的表面的丙烯酸类胶辊。 
实施例 
以下参考实施例详细描述本发明，然而，本发明并不限于以下具体实施例。 
下面所列为实施例和比较例中所用到的典型原料： 
1)2-EHA结构  2)HEA结构 
3)HDDA结构  4)AA结构 
5)Irgacure651(2，2-二甲氧基-苯基甲酮)结构 
实施例1 
将2-EHA、AA、HEA、固化剂HDDA及光引发剂Irgacure651按照表1 所示的配比混合均匀，以得到可固化的丙烯酸类组合物。具体地，将液体状原材料2-EHA、AA、HEA、固化剂HDDA在常温条件下倒入玻璃容器中，用搅拌器匀速搅拌后加入粉末状光引发剂Irgacure651，继续匀速搅拌直至光引发剂完全溶解。 
将所得到的丙烯酸类组合物在紫外灯照射下进行固化交联，确保配方中单体交联反应完全以制得丙烯酸类胶带。 
将丙烯酸类胶带模切至与塑料胶辊轴相应的尺寸，均匀无气泡地贴合到可自由旋转的塑料胶辊上，即制得用于除尘和粘毛的丙烯酸类胶辊。 
比较例1-2 
以与实施例1相同的方法配制可固化的丙烯酸类组合物，不同之处在于如表1所示改变2-EHA、AA和HEA的比例。采用所得到的可固化的丙烯酸类组合物以与实施例1相同的方法制造丙烯酸类胶带和丙烯酸类胶辊。 
实施例2-4 
以与实施例1相同的方法配制可固化的丙烯酸类组合物，不同之处在于如表1所示改变2-EHA、AA和HEA的比例。采用所得到的可固化的丙烯酸类组合物以与实施例1相同的方法制造丙烯酸类胶带和丙烯酸类胶辊。 
表1 
以下对实施例和比较例中制造的胶带和胶辊进行测试，测试方法如下： 
水洗测试方法： 
选取等量的毛发，将其平铺于平坦表面，将新鲜测试胶面与毛发轻微接触并快速将胶样提起，观察胶样是否能轻易将毛发粘起。 
将粘附毛发的胶样放置于水龙头下，用缓和的流水冲洗胶面并且用手指轻轻拂拭胶粘剂表面所粘附的毛发，将时间控制在15秒钟之内，然后关上水龙头，观察胶粘剂表面是否还有残留的毛发。结果如表2所示。 
表2-水洗测试结果 
初粘性测试方法： 
初粘性测试方法参照G1ASTM D6195标准，样品分为新鲜胶样和水浸后胶样，水浸后样品的制备方法为将胶样整体浸于清水中，静置30分钟后取出，放置于温度为22摄氏度及湿度为50％的房间中，待胶样完全干燥后待测。结果如表3所示。 
表3-初粘性测试结果： 
样品 新鲜样品(N/inch) 水浸后样品(N/inch)
实施例-1 19.31 11.32
比较例-1 15 7.36
实施例-2 18.97 9.44
实施例-3 16.26 9.2
比较例-2 14.32 5.6
实施例-4 18.92 7.4
在水洗型胶辊的实际应用中，初粘性是其性能最为直接的评判方法，由于在使用中还涉及到水洗及重复使用的概念，因此水浸后的胶样的初粘性保持性能也相当重要，通过新鲜样品及水浸后样品的初粘性测试，可以模拟出水洗胶辊在实际应用中的性能。 
在实际应用中，初粘性过大或过小都会影响实际使用效果，从测试结果可以看出样品实施例-1、实施例-2和实施例-3有着较为不错的新鲜样品初粘性和水浸后样品初粘性的保持性，水洗测试效果和初粘性测试效果。 
耐洗性测试： 
测试样尺寸为1英寸×8英寸，粘满标准灰，自来水下用手洗涤约15秒，轻轻甩干表面水珠，在22摄氏度和50％相对湿度条件下，静置1分钟，重复以上粘满灰尘、洗涤、清洗步骤至150个循环后，晾干5分钟，按照G1ASTMD6195标准测试本发明实施例1、比较例1和竞品(竞品大多采用合成橡胶、聚氨酯、硅胶等弹性材料通过模具浇注成型于塑料辊轴上，通用的商品名常见于粘毛滚、粘毛器等)。 
经过150个循环后，本发明实施例1胶带初粘性几乎保持不变，而竞品的初粘性下降近50％。除此之外，本发明实施例1的胶带初粘性是竞品初粘性的5倍左右，这表明，本发明胶带更具有持久的粘附灰尘以及毛发等污物的清洁能力。比较例1的耐洗性数据与本发明实施例1对比，性能略有下降。 
表4-耐洗性对比测试 
粘性恢复时间测试： 
胶辊辊筒直径：56mm，长度为98mm。水洗之后自然晾干的时间即为胶辊的粘性恢复时间。 
表5-粘性恢复时间 
表5中的1#-5#是对实施例1的5次取样测试结果。 
实际使用过程中，消费者可以在胶带表面半干状态下，约1～3分钟即可重复使用，其粘性足以抓取毛发等污物，不需要等待胶面完全干燥。用不掉屑的软布、纸张拭去水珠，可以加速胶面粘性恢复。 
洗涤难易性测试结果： 
表6 

Claims (12)

1.一种可固化的丙烯酸类组合物，所述丙烯酸类组合物包含50-77重量％丙烯酸2-乙基己酯、2-10重量％丙烯酸、20-40重量％丙烯酸2-羟乙酯、0.1-0.5重量％固化剂以及0.1-0.2重量％光聚合引发剂。
2.根据权利要求1所述的丙烯酸类组合物，其中所述固化剂包括双官能丙烯酸酯。
3.根据权利要求1所述的丙烯酸类组合物，其中所述光聚合引发剂包括2，2-二甲氧基-苯基甲酮。
4.根据权利要求2所述的丙烯酸类组合物，其中所述双官能丙烯酸酯包括己二醇二丙烯酸酯或三丙二醇二丙烯酸酯。
5.根据权利要求1至4中任一项所述的丙烯酸类组合物，其中所述丙烯酸类组合物还包括防霉剂、抗菌剂、香味剂、增塑剂、和气相法二氧化硅中的一种或多种。
6.一种通过固化根据权利要求1所述的丙烯酸类组合物而制备的丙烯酸类胶带。
7.如权利要求6所述的丙烯酸类胶带，其中所述固化包括紫外光固化。
8.一种丙烯酸类胶辊，所述丙烯酸类胶辊包括辊筒和卷绕在辊筒上的根据权利要求6所述的丙烯酸类胶带。
9.一种制造丙烯酸类胶辊的方法，包括：
在常温下，将50-77重量％丙烯酸2-乙基己酯、2-10重量％丙烯酸、20-40重量％丙烯酸2-羟乙酯、0.1-0.5重量％固化剂进行混合并搅拌；
在所得的混合物中加入0.1-0.2重量％光聚合引发剂，并继续进行搅拌，直至所述光聚合引发剂完全溶解，得到丙烯酸类组合物；
用紫外光照射所述丙烯酸类组合物，使其发生交联固化，得到丙烯酸类胶带；
将丙烯酸类胶带模切至与塑料胶辊轴相应的尺寸，并将其均匀无气泡地贴合到可自由旋转的塑料胶辊上，得到所述丙烯酸类胶辊。
10.根据权利要求9所述的制造丙烯酸类胶辊的方法，还包括：
在用紫外光照射所述丙烯酸类组合物之前，在所述丙烯酸类组合物中加入防霉剂、抗菌剂、香味剂、增塑剂、和气相法二氧化硅中的一种或多种。
11.根据权利要求9所述的制造丙烯酸类胶辊的方法，其中所述固化剂包括双官能丙烯酸酯。
12.根据权利要求9所述的制造丙烯酸类胶辊的方法，其中所述光聚合引发剂包括2，2-二甲氧基-苯基甲酮。
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