JP2016518249A5 - - Google Patents
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- Publication number
- JP2016518249A5 JP2016518249A5 JP2016510707A JP2016510707A JP2016518249A5 JP 2016518249 A5 JP2016518249 A5 JP 2016518249A5 JP 2016510707 A JP2016510707 A JP 2016510707A JP 2016510707 A JP2016510707 A JP 2016510707A JP 2016518249 A5 JP2016518249 A5 JP 2016518249A5
- Authority
- JP
- Japan
- Prior art keywords
- catalyst
- weight
- zeolite
- shaped
- silica
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Ceased
Links
- 239000003054 catalyst Substances 0.000 claims description 28
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 claims description 21
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 20
- 239000010457 zeolite Substances 0.000 claims description 19
- 229910021536 Zeolite Inorganic materials 0.000 claims description 18
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 claims description 18
- 238000000034 method Methods 0.000 claims description 13
- 229910052697 platinum Inorganic materials 0.000 claims description 9
- 239000011230 binding agent Substances 0.000 claims description 7
- 238000001354 calcination Methods 0.000 claims description 6
- 238000005342 ion exchange Methods 0.000 claims description 6
- 230000008021 deposition Effects 0.000 claims description 5
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 4
- 229910052799 carbon Inorganic materials 0.000 claims description 4
- 239000000203 mixture Substances 0.000 claims description 4
- 238000001125 extrusion Methods 0.000 claims description 3
- 238000010438 heat treatment Methods 0.000 claims description 3
- 238000005899 aromatization reaction Methods 0.000 claims description 2
- 239000000377 silicon dioxide Substances 0.000 claims 8
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 claims 6
- 229910052792 caesium Inorganic materials 0.000 claims 5
- 238000000151 deposition Methods 0.000 claims 5
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 claims 4
- 239000008119 colloidal silica Substances 0.000 claims 3
- TVFDJXOCXUVLDH-UHFFFAOYSA-N caesium atom Chemical compound [Cs] TVFDJXOCXUVLDH-UHFFFAOYSA-N 0.000 claims 2
- NCMHKCKGHRPLCM-UHFFFAOYSA-N caesium(1+) Chemical group [Cs+] NCMHKCKGHRPLCM-UHFFFAOYSA-N 0.000 claims 2
- 238000004519 manufacturing process Methods 0.000 claims 2
- 239000002994 raw material Substances 0.000 claims 2
- 150000001491 aromatic compounds Chemical class 0.000 claims 1
- 230000003197 catalytic effect Effects 0.000 claims 1
- 238000006243 chemical reaction Methods 0.000 claims 1
- 150000001875 compounds Chemical class 0.000 claims 1
- 229910052732 germanium Inorganic materials 0.000 claims 1
- GNPVGFCGXDBREM-UHFFFAOYSA-N germanium atom Chemical compound [Ge] GNPVGFCGXDBREM-UHFFFAOYSA-N 0.000 claims 1
- 238000000465 moulding Methods 0.000 claims 1
- 239000007787 solid Substances 0.000 claims 1
- 230000015572 biosynthetic process Effects 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 238000005470 impregnation Methods 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 229920002401 polyacrylamide Polymers 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 239000010970 precious metal Substances 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US13/868,296 US9782758B2 (en) | 2013-04-23 | 2013-04-23 | Method of preparing hydrocarbon aromatization catalyst, the catalyst, and the use of the catalyst |
| US13/868,296 | 2013-04-23 | ||
| PCT/US2014/034504 WO2014176111A1 (en) | 2013-04-23 | 2014-04-17 | Method of preparing hydrocarbon aromatization catalyst, the catalyst, and the use of the catalyst |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JP2016518249A JP2016518249A (ja) | 2016-06-23 |
| JP2016518249A5 true JP2016518249A5 (enExample) | 2018-01-25 |
Family
ID=50733438
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2016510707A Ceased JP2016518249A (ja) | 2013-04-23 | 2014-04-17 | 炭化水素芳香族化触媒を調製する方法、その触媒、およびその触媒の使用 |
Country Status (5)
| Country | Link |
|---|---|
| US (1) | US9782758B2 (enExample) |
| EP (1) | EP2988869A1 (enExample) |
| JP (1) | JP2016518249A (enExample) |
| CN (1) | CN105142786B (enExample) |
| WO (1) | WO2014176111A1 (enExample) |
Families Citing this family (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105636693B (zh) * | 2013-11-22 | 2019-12-13 | 沙特基础工业公司 | 用于轻石脑油芳构化的具有改善的活性/选择性的催化剂 |
| CN106316744B (zh) * | 2015-06-19 | 2019-04-12 | 中国石油化工股份有限公司 | 四氢呋喃类化合物芳构化制芳烃的方法 |
| CN110088244A (zh) | 2016-10-17 | 2019-08-02 | 沙特基础全球技术有限公司 | 由c5-c12烃混合物生产btx的方法 |
| CN108726534B (zh) * | 2018-06-07 | 2021-08-10 | 西安工程大学 | 一种微介孔zsm-5分子筛的制备方法 |
| WO2020044309A1 (en) * | 2018-08-30 | 2020-03-05 | Sabic Global Technologies B.V. | Aromatization catalyst with improved isomerization, process of making and using thereof |
| CN111377792B (zh) * | 2018-12-29 | 2023-04-18 | 国家能源投资集团有限责任公司 | 低碳烷烃芳构化的方法 |
| JP7547902B2 (ja) * | 2019-10-08 | 2024-09-10 | 東ソー株式会社 | 新規銀含有ゼオライト及びそれを含む芳香族炭化水素製造用触媒 |
| KR102844575B1 (ko) * | 2019-11-20 | 2025-08-08 | 에스케이이노베이션 주식회사 | 탈수소화 성형 촉매 및 이를 이용하여 파라핀을 올레핀으로 전환시키는 방법 |
| US11529617B2 (en) * | 2020-08-12 | 2022-12-20 | Chevron Phillips Chemical Company, Lp | Catalyst supports and catalyst systems and methods |
| US11465950B2 (en) | 2020-09-03 | 2022-10-11 | Saudi Arabian Oil Company | Aromatization of light hydrocarbons using metal-doped zeolite catalysts with enhanced mesoporosity |
| US11673845B2 (en) | 2020-09-03 | 2023-06-13 | Saudi Arabian Oil Company | Aromatization of light hydrocarbons using metal-modified zeolite catalysts |
| US20220389334A1 (en) * | 2021-06-04 | 2022-12-08 | Saudi Arabian Oil Company | Conversion of light naphtha to enhanced value products in an integrated reactor process |
| US11548842B1 (en) | 2022-06-01 | 2023-01-10 | Saudi Arabian Oil Company | Conversion of light naphtha to enhanced value aromatics in an integrated reactor process |
Family Cites Families (48)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB1305137A (enExample) | 1969-02-10 | 1973-01-31 | ||
| US3702886A (en) | 1969-10-10 | 1972-11-14 | Mobil Oil Corp | Crystalline zeolite zsm-5 and method of preparing the same |
| DE2125691A1 (de) | 1970-05-25 | 1971-12-02 | Asahi Chemical Ind | Verfahren zum Reaktivieren von Platin und Blei enthaltenden Reforming-Katalysatoren |
| FR2323664A1 (fr) | 1975-09-10 | 1977-04-08 | Erap | Procede de deshydrocyclisation d'hydrocarbures aliphatiques |
| JPS55129232A (en) | 1979-03-29 | 1980-10-06 | Teijin Yuka Kk | Isomerization of xylenes |
| US4278827A (en) * | 1980-04-07 | 1981-07-14 | Mobil Oil Corporation | Shape selective reactions with zeolite catalyst modified with group IVB metal |
| FR2484401A1 (fr) | 1980-05-09 | 1981-12-18 | Elf France | Procede de deshydrocyclisation des paraffines a tres basse pression |
| US4435283A (en) | 1982-02-01 | 1984-03-06 | Chevron Research Company | Method of dehydrocyclizing alkanes |
| US4517306A (en) | 1982-02-01 | 1985-05-14 | Chevron Research Company | Composition and a method for its use in dehydrocyclization of alkanes |
| US4645586A (en) | 1983-06-03 | 1987-02-24 | Chevron Research Company | Reforming process |
| US4595669A (en) | 1983-11-10 | 1986-06-17 | Exxon Research And Engineering Co. | Method of preparing an improved catalyst |
| US4925819A (en) | 1983-11-10 | 1990-05-15 | Exxon Research & Engineering Company | Method of regenerating a deactivated catalyst |
| CA1231699A (en) | 1983-11-10 | 1988-01-19 | Samuel J. Tauster | Zeolite catalyst and process for using said catalyst |
| US4652360A (en) | 1985-07-22 | 1987-03-24 | Mobil Oil Corporation | Base-exchanged zeolite compositions with shape-selective metal functions |
| US5053374A (en) | 1987-05-01 | 1991-10-01 | Mobil Oil Corporation | Method for preparing a zeolite catalyst bound with a refractory oxide of low acidity |
| DE3883988T2 (de) | 1987-11-17 | 1994-01-05 | Mobil Oil Corp | Katalytisches reformierungsverfahren. |
| US4839027A (en) | 1987-12-03 | 1989-06-13 | Mobil Oil Corp. | Catalytic reforming process |
| US4867864A (en) | 1988-12-13 | 1989-09-19 | Dessau Ralph M | Dehydrogenation, dehydrocyclization and reforming catalyst |
| WO1991004943A2 (en) | 1989-09-29 | 1991-04-18 | Exxon Research And Engineering Company | Zeolite aggregates and catalysts |
| US5114565A (en) | 1990-01-26 | 1992-05-19 | Chevron Research And Technology Company | Reforming naphtha with boron-containing large-pore zeolites |
| US5169813A (en) | 1990-03-02 | 1992-12-08 | Chevron Research And Technology Company | Dehydrocyclization or catalytic reforming sulfur tolerant zeolite catalyst |
| WO1992013045A1 (en) | 1991-01-25 | 1992-08-06 | Chevron Research And Technology Company | Reforming naphtha with large-pore zeolites |
| FI952954A0 (fi) | 1992-12-16 | 1995-06-15 | Chevron Res & Tech | Alumosilikaattizeoliittien valmistus |
| US5378671A (en) | 1993-06-03 | 1995-01-03 | Mobil Oil Corp. | Method for preparing catalysts comprising zeolites |
| US6063724A (en) | 1998-04-06 | 2000-05-16 | The Board Of Regents Of The University Of Oklahoma | Sulfur-tolerant aromatization catalysts |
| ES2204159T3 (es) | 1998-09-22 | 2004-04-16 | Exxonmobil Chemical Patents Inc. | Preparacion de zeolitas de elevado contenido en silice que estan unidas por zeolita y su uso. |
| US6365767B1 (en) * | 1999-05-28 | 2002-04-02 | Exxonmobil Chemical Patents Inc. | Process for co-production of dialkyl carbonate and alkanediol |
| US6709570B1 (en) * | 1999-09-27 | 2004-03-23 | Shell Oil Company | Method for preparing a catalyst |
| US6784333B2 (en) | 2002-08-06 | 2004-08-31 | Saudi Basic Industries Corporation | Catalyst for aromatization of alkanes, process of making and using thereof |
| US7153801B2 (en) | 2003-06-18 | 2006-12-26 | Chevron Phillips Chemical Company Lp | Aromatization catalyst and methods of making and using same |
| DE102004029544A1 (de) | 2004-06-18 | 2006-01-05 | Basf Ag | Formkörper enthaltend ein mikroporöses Material und mindestens ein siliciumhaltiges Bindemittel, Verfahren zu seiner Herstellung und seine Verwendung als Katalysator, insbesondere in einem Verfahren zur Herstellung von Triethylendiamin (TEDA) |
| US7572749B2 (en) | 2004-08-31 | 2009-08-11 | Exxonmobil Research And Engineering Company | Structured bodies with siliceous binder |
| CN100384735C (zh) | 2005-08-15 | 2008-04-30 | 中国石油化工股份有限公司 | 小晶粒zsm-5无粘结剂成型沸石的制备方法 |
| EP1935865B1 (en) | 2005-09-16 | 2016-11-16 | Asahi Kasei Kabushiki Kaisha | Process for production of ethylene and propylene |
| DE102005059711A1 (de) | 2005-12-12 | 2007-06-14 | Basf Ag | Formkörper enthaltend ein mikroporöses Material und mindestens ein siliciumhaltiges Bindemittel, Verfahren zu seiner Herstellung und seine Verwendung als Katalysator, insbesondere in einem Verfahren zur kontinuierlichen Synthese von Methylaminen |
| CN101134171B (zh) | 2006-08-31 | 2010-12-08 | 中国石油化工股份有限公司 | 一种c8芳烃异构化催化剂的制备方法 |
| US7745675B2 (en) * | 2006-12-20 | 2010-06-29 | Saudi Basic Industries Corporation | Regeneration of platinum-germanium zeolite catalyst |
| US7906696B2 (en) | 2007-01-22 | 2011-03-15 | Saudi Basic Industries Corporation | Process of using zeolite catalyst for hydrocarbon conversion |
| US7902413B2 (en) * | 2007-04-12 | 2011-03-08 | Saudi Basic Industries Corporation | Aromatization of alkanes using a germanium-zeolite catalyst |
| US9221723B2 (en) | 2007-05-24 | 2015-12-29 | Saudi Basic Industries Corporation | Catalyst for conversion of hydrocarbons, process of making and process of using thereof—incorporation-1 |
| US8993468B2 (en) | 2007-05-24 | 2015-03-31 | Saudi Basic Industries Corporation | Catalyst for conversion of hydrocarbons, process of making and process of using thereof—Ge zeolites |
| US8263518B2 (en) | 2007-12-13 | 2012-09-11 | Chevron Phillips Chemical Company Lp | Catalyst having an improved crush strength and methods of making and using same |
| CN102039168B (zh) | 2009-10-13 | 2012-06-27 | 中国石油化工股份有限公司 | 无粘结剂zsm-5/丝光沸石共生分子筛催化剂的制备方法 |
| US20110132804A1 (en) | 2009-12-04 | 2011-06-09 | Saudi Basic Industries Corporation | Increasing octane number of light naphtha using a germanium-zeolite catalyst |
| US8119551B2 (en) | 2010-01-14 | 2012-02-21 | Saudi Basic Industries Corporation | Zeolite catalyst with deposited germanium, aluminum and platinum for aromatization of alkanes, process of making and process of using thereof |
| US8840779B2 (en) | 2010-02-09 | 2014-09-23 | Exxonmobil Research And Engineering Company | Dewaxing catalysts |
| US9242233B2 (en) * | 2012-05-02 | 2016-01-26 | Saudi Basic Industries Corporation | Catalyst for light naphtha aromatization |
| US9180441B2 (en) | 2012-09-20 | 2015-11-10 | Saudi Basic Industries Corporation | Method of forming zeolite shaped body with silica binder |
-
2013
- 2013-04-23 US US13/868,296 patent/US9782758B2/en not_active Expired - Fee Related
-
2014
- 2014-04-17 JP JP2016510707A patent/JP2016518249A/ja not_active Ceased
- 2014-04-17 CN CN201480022798.8A patent/CN105142786B/zh not_active Expired - Fee Related
- 2014-04-17 WO PCT/US2014/034504 patent/WO2014176111A1/en not_active Ceased
- 2014-04-17 EP EP14724970.0A patent/EP2988869A1/en not_active Withdrawn
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